DE2210956A1 - Intermediate carriers, their production and use for dry dyeing and printing by means of heat - Google Patents

Description

SUBLISTATIC HOLDING S.A., Glarus (Switzerland)

(Case 1-7406 / PRO 5/1 + 2)

Germany

22, 25%

"Subcarriers, their manufacture and use for Heat dry dyeing and printing ".

The present invention relates to intermediate carriers and their use for printing and dyeing synthetic materials.

Eb started that one could use textiles and other flat surfaces made of synthetic materials.

209840/0995

BATH ORIGINAL

that you can use the motif or design that preceded you generally made of paper if necessary an aluminum foil was glued or printed with this reinforced intermediate carrier, transferred by means of heat. When using aqueous printing inks in this process, certain difficult-to-solve printing problems arise of the paper on how the dosage of the dispersant of the dyes in water, which by the provisorischen.stark mit The water-soaked vehicle caused a delay in drying it and the difficulty of localizing it Printing patterns as a result of the lack of dimensional stability of papers in the presence of water. From all of these For reasons and others, the process with aqueous printing inks has been abandoned in favor of a process in which Printing inks with organic solvents can be used. This method brings significant advantages, mainly with regard to the drying of the temporary supports, the recovery and reuse of excess Printing inks, with regard to the local classification of the colors, etc. This method, in which one is water-free or almost The use of water-free printing inks is also possible on printing machines with large widths (up to 180 cm instead of 80 to 100 cm in the process with aqueous printing inks), and the printing speeds can as a result the reduced calorie requirement, which is necessary for drying, can be increased considerably. In addition, the water-

BATH ORIGINAL

2038 4 0/0995

ge process often sticky and moisture-sensitive intermediate carriers, which can be seen in the slight moistening the hands of the personnel handling these carriers, while that in the French patent specification 1 585 119 described method non-sticky and insensitive to moisture Provides carriers that do not tend to be subject to destruction even after prolonged storage.

However, if one uses the above-mentioned methods, it can be seen that the quality of the transmission, i. H. the Quantity of paint that is effectively transferred from the intermediate carrier to the final carrier, largely by nature of the intermediate carrier depends. Accordingly, the present invention has, among other advantages, the purpose of to improve the carrier quality with simple means. Accordingly, here is the use of new civil carriers for the Printing and dyeing by means of heat is described.

As with the known supports, the supports according to the invention have a single-colored layer or a motif printed on with the aid of one or more dyes and / or optical brighteners, the dyes used and / or optics. Brighteners zv / ischen 160 and 220 ⁰ C at atmospheric pressure are sublimable or evaporable. But they differ from the known carriers in that they continue to have at least one for the vapors of the dye used ·; or optical brighteners undruer-ringliche

BATH

8 ^ 0/093 "

have, these in the form of a base coat (primer) that separates the specified print from the carrier and / or in the form of an overcoat (top layer) which partially covers the colored layer. These Novel intermediate carriers thus have one as a web, or film, strip on at least one of the two surfaces or tape formed carrier material, which is inert to heat and stable, for example on paper, which optionally reinforced by an aluminum foil, or is glued to it, at least two in any order thin layers of organic materials (which cover this area in whole or in part), one of which highly volatile or sublimable color materials (and / or optical brighteners) that form the design to be transferred, and the other layer is formed by an albuminoid material or by another protein-containing material which is stable to heat and in water, or in a mixture of water and organic solvents, for example alcohol, is soluble or dispersible. To form this layer that is responsible for the vapors of the dye and the optical brightener is opaque, one uses. preferably gelatin, for example bone gelatin. However, you can also use gelatins of other origins, such as glue materials, isinglass, grenetin, light-colored gelatins or gelatinous egg / ice or protein substances such as albumin, Ovalbumin, possibly even casein, zein, even

BATH 209840/0995

Use lecithin or their mixtures.

The present invention further relates to a method for producing the civil carriers defined above. That The method consists in that by any suitable means at least on one of the surfaces of a web or film or a strip that is inert and stable to heat, for example on a paper or cellophane hand, one after the other a preferably defect-free layer of a substance that is responsible for dye and optical brightener vapors is impermeable, for example a layer of albuminoid material, and a layer of color is applied. Under the Color layer is to be understood here as a layer that is uniform or in the form of a design or pattern one or more Contains dyes or optical brighteners, which are bsi temperatures between 160 and 220 G and preferably between Volatilize or sublime at 180 and 210 ° C at atmospheric pressure.

When this process is used to make a release liner (or primer), it leads to formation a uniform varnish coating that is impermeable to vapors from the dyes and optical brighteners used, which is arranged between the support and these dyes or brighteners. In this way it is possible is to increase the color yield noticeably and any inequality in the print due to a possibly missing unit -

209840/0995

To avoid the smoothness of the intermediate carrier base material what is a major advantage with a plain print, whereby it is still possible to use cheaper papers and their. Quality, i.e. changing their origin in the course of production. It is also possible to have certain disadvantages Fix Storage: For example, when the temporary carrier is rolled up, the back and front come in Contact; stains can then form on the back side due to the dye on the front side and During the transfer, such spots of color penetrate the intermediate carrier (if this is not a glued-on aluminum foil has) and come to pressure on the end beam, causing an error.

For coating the carrier with the impermeable layer before printing the design or a uniform The layer of dye or optical brightener can be used on a conventional device. One can for example let the carrier pass through a separate lacquer application device and then the printing or, more precisely, the coloring effect on a printing machine with ordinary inking rollers. But you can also just have a single machine for printing provided that it has an additional roller located in front of the engraved rollers that print the design intended for transfer or in front of an ink roller that prints the uniform color layer. It will preferred to work on an independent device, or a special introduction roller for the impermeable

209840/0995

Layer to be provided, since the alburainoid materials used in anhydrous or almost anhydrous solvents are soluble. In this way one has the possibility of using an aqueous solution and this regardless of to apply the paint coat or bleach coat.

The albuminoid material is presented in proportion to the paper.

0.5 to 6 and preferably 1 to 3.5 g per m in solution or Dispersion applied in water to which an organic solvent, for example an alcohol, is optionally added will.

Intermediate drying, which is carried out after the application of the albuminoid material and before printing or coloring prevents the primer from affecting or affecting the final transfer. This drying v.nt facilitated when the aqueous colloidal solution to be applied an organic solvent, for example a Alcohol, is added.

The only modification of the device compared to those for known methods consists accordingly in the introduction an additional application roller or squeegee application machine, the intermediate or temporary carrier with a thin albuminoid layer with a thickness of 0.5 to 50 Microns (preferably 1 to 10 microns) coated. The coloring or the motif intended for transfer is then

209840/0995

according to the usual procedures, as will be described later, printed directly onto the impermeable layer. It can there is a significant amount of time between these two treatments. One can even use paper that is provided with the albuminoids Material is coated, for example, gelatinized paper and store much later by printing with the sublimable Dye (s) or the optical brightener (s) the intermediate carrier which is the subject matter of the present Make an invention, create it.

The method forming the subject of the present invention can be used in the same way to produce a to apply the reserving top layer (overcoating), as the albuminoid paint provides a shield against the vapors of the used dyes and optical brighteners forms, which is at least up to 220 C completely effective, this temperature represents the maximum at which the transfer is effected. In this case it is not a question of this overpainting to apply to the entire surface of the carrier, which would have no sense, but the overcoating in the form of a given motif, whereby one can easily effective and economical way to achieve color cutouts.

To create a motif with the help of albuminoid materials on the. To print a carrier that already has a layer of color, a conventional device can be used, whereby one

209840/0995

fold the corresponding application roller after the inking roller or rollers (n) that prints the color layer on the paper and provides a drying device. One can however, you can also use one of the numerous known mechanical printing machines, for example a roller application machine with "air brush", a machine for color photographic printing (heliogravure), rotary printing, etc .. As in the case of the It is preferable to use a primer to achieve color cutouts to work with a machine that is independent of the transfer of fixtures and is responsible for the application of the colored Layer is used, whereby it should be noted that aqueous solutions of albuminoid materials are used. These solutions have the same composition as those already defined in the case of the primer.

These color gaps or open spaces (reserves) can be printed onto substrates that already have a primer exhibit by means of albuminoid materials under the design intended for the transfer or the plain color layer.

Furthermore, this method offers the possibility in the same way for printing a color motif over the top layer motif made of albuminoid materials, which makes it possible is to get islands of color or color motifs on a white recess (reserve) and in this way to achieve Transferring the intended design in a simple or adaptable manner. In addition to other advantages, it enables this way of working, the purity of printing color designs

209840/0995

~ 10 -

to be carried out in a bright recess. The pressure, the recess, then overprinting can be done several times. In this way, a Motif can later be modified or completed, a valuable advantage for items that meet the demands of fashion should be fair and whose production must quickly be based on an often unforeseeable requirement.

As in the case of the primer, accordingly lies the only one This differs from the well-known process in printing a motif that is already made with an albuminoid material the dyes and the brighteners, as they will be explained later, receives treated carrier.

In order to print these recesses on the Mitiv or the coloring intended for transfer, it is not necessary to For example, a heliogravure machine or an engraved roller according to the motif that you assign to the recesses give wishes to use. As in the case of the primer, the albuminoid varnish can be applied to the already treated with dyes or optical brighteners, which will be defined later, and primed if necessary Apply the carrier, then locally this lacquer according to the motif intended for the recess through one of the numerous known chemical or photochemical processes to make them insoluble, then wash out, in order for this motif to occur

209840/0995

to let and dry, thus making the the same result as in the previous paragraph was achieved. Of the procedures that have been known to get out of college If a latent image is obtained, it is preferable to choose those that show the effect of light on a sensitized, use albuminoid material for this effect, for example, one uses the insolubility of chrome gelatine, -albumin or -casein by means of light and then developed with lukewarm water (30 to 50) or with cold water, the for example urea, thiourea was added. in the On the other hand, another method is to make gelatin or casein soluble with light, as described above insoluble with iron (III) chloride, a diazonium compound, cellulose glycolate or cellulose oxyethane sodium sulfonate were made, after which one developed or washed out with acidified water.

For example, a gelatin coating containing 2 to 0% potassium dichromate can be exposed, the rays striking anywhere between 355 and 425 μm behind the negative on which the motif intended for the recess is present in transparency. The potassium dichromate can be combined with an iron (III) oxalate, or it can be replaced by ammonium, quinoline or pyridine dichromate. Since the maximum sensitivity is at the isoelectric point of the gelatin, it is preferable to work in the presence of an organic acid or one of its salts, preferably with

209840/0995

Potassium citrate. During the drying following the application one stops preferably at a humidity of about $ 14, whereby it avoids obtaining a brittle, brittle layer of reduced sensitivity or storability.

Since this method of working makes washing necessary to expose or develop the image obtained, it is first drawn, as an intermediate carrier paper that is mounted on aluminum foil or paper with an albuminoid primer that is insoluble under the developing conditions. This development is made possible by the use of Dispersion paints possible that are practically insoluble in water.

The possibility of several designs on the same end carrier by means of different, differently colored intermediate carriers to be applied on top of each other and also to obtain tints by increasing the thickness of the colloidal layer and thus their permeability to the dye vapors varies, enabling, for example, easy color photography Obtain reproduction on synthetic material. So you can, for example, if you have three carriers according to the present Invention used, each bearing a uniform layer of a single dye, yellow in the first case, red in the second and blue in the third, which are covered by a completely uniform layer of chrome gelatin ^ copies of Produce color photographs provided that one is customary and known in the photographic art

209840/0995

Filters used. It goes without saying that one sehi must ensure exact coordination, both in the exposure of the three inventive carriers, as well as in the Recovery of the image by subsequent transfer of the three color components to the final support. This can just as well be a piece of textile, such as a film or a sheet made of synthetic material, polyamide, polyacrylonitrile or preferably made of a linear polyester.

By applying albumin recesses, the use can be reduced or even avoided by engraved rollers. In this way one obtains through successive Coating of the carrier with a monolayer, then with a chromium albumin layer, which is exposed through a transparency which is made opaque according to the desired recess negative and then developed and dried and finally is transferred, a white recess on Unigrund, without the * an engraved roller is used. It is also sufficient to use a plain colored carrier according to the desired motif with a To print album ink and overprint it with the same engraved roller to create a two-tone design with a single engraved cylinder. Finally, it can be if the pattern intended for transfer is not large Difficulties

209H40 / 0995

j.

in terms of location makes it advantageous to transfer a two-tone pattern through it obtained that one has two intermediate carriers, which have a single-color print, the one with photoinchanically obtained recesses is overprinted, used and thus saves the engraving of two / one ink rollers.

The pressure of a plain colored layer or patterns on the carrier by means of dyestuffs or optical brighteners which are subliinier- and vaporizable at temperatures from 160 to 220 ⁰ C, according to the known method, for example, in French Patents 1,585,119, 1574 528 and 1 223 330 is described, preferably by applying anhydrous or almost anhydrous

Printing ink causes, i.e. with solutions, lacquers, emulsions, preferably with /

odea / dispersions that are completely or almost completely

a / advantageous /

are anhydrous, being / dissolved or / very finely dispersed disperse dye, which is at atmospheric Pressure between 160 and 220 C changes into the vapor state, an anhydrous or almost anhydrous organic solvent and a binder or thickener stable to heat. As sublimable dyes can here, as in the known method of dye, preferably disperse dyes, mentioned in atmospheric pressure between 160 and 220 C change into the vapor state. These dyes can for example » sublimable azo or anthraquinone dyes or other

2098AO / 0995

may be nitroarylamines, styryl dyes, derivatives of quinophthalone, perinones, etc. 1,4-Dimethylaminoanthraquinone, bromo- or chloro-1,5-diamino-4,8-dihydroxyanthraquinone, J-hydroxyquinophthalone, 1-hydroxy-3-phenoxy-4-arninoanthraquinone, 4- (4 '- I. Ethyl-2 'nitrophenylazo) -3-methyl-5-pyrazolone, 1-amino-2 ~ cyano-4-anilidoanthraquinone and dyes whose behavior at 180 to 210 ⁰ C is very similar, for example the propyl or butyl ester 1, 4-diaminoanthraquinone-2 ~ carboxylic acid, i-amino ^ -cyano ^ -cyclohexylaminoanthrachinon and 2-hydropentafluoropropylene; y-5-iaethyl ^{4-t-acetylamino} azobensol.

In the usual process, almost anhydrous organic solvents are used for the production of printing inks which are intended to form a color layer on the new carrier according to the invention. Under nearly anhydrous organic solvents are here solvents or mixtures of solvents which are miscible with ater v / or not to adjust, whose boiling point at atmospheric pressure below 120 ⁰ ^ and preferably below 105 ° C. The solvents should contain less ice $ 15 water. Such solvents are to be mentioned: optionally halogenated ¹ : ·, aliphatic or aromatic hydrocarbons, such as? Oluoü

pref else abe r / cyclohexane, petroleum ether / alcohols with low Molekulargswicht how !! ethanol, A'thyl-, propyl, isopropyl alcohols, esters of aliphatic acids such as ethyl acetate, ketones such as Lie thyläthylketon ups / ..

-16-209840 / 0995 _BAD ORIGINAL *

221095S

The thickeners or binders which are stable to heat, i.e., do not degrade in the heat at which the transfer of the present invention is advertised, are commercially available and are widely used for direct printing on textile materials. ends, but it is expedient to select from these those 'which have a low content of solid substances. They should be suitable for drying, forming a non-sticky film that retains the dye or dyes used. It is preferred to use inert and relatively little or completely non-decomposable binders which are limited to keeping the sublimable substances used on the paper without modifying them. For example, one can mention binders which are suitable, for example, to be dried by means of a poor air stream with the formation of a non-adhesive film on the foil of the printed carrier, such as, for example, nitrocellulose binders. Particularly suitable binders can be mentioned: the cellulose esters (for example acetato or acetobutyrate) and especially the cellulose ethers, which are soluble in the organic solvents used for the production of printing inks, such as hydroxypropyl, propyl, benzyl and ethoxyethyl celluloses as well their mixtures and especially ethyl cellulose and the mixtures of cellulose ethers containing ethyl or hydroxyp'ropyl cellulose.
The supports obtained make it possible to dye or print synthetic materials. This coloring or, the pressure,

2098A0 / 0995

Form the subject of the present invention, consist in that one of the previously described ,, printed, provisional Carrier at least in places with the material provided for coloring, preferably arranged on a carrier, brings into contact and after making contact to a temperature of the same order of magnitude as that in which the dyes pass into the vapor state, so that they do not simply condense on the surface. The coloring or the printing is accordingly effected simply by passing over a plate or a poor plate warm calender or any other device that supports the Bringing the temporary carrier into contact with the one for staining provided material, as well as bringing the Materials for the required time, allow.

No follow-up treatment, washing or steaming is necessary to ensure the fixation of the dye or to avoid its subsequent blooming or bleeding.

The present process enables the coloring of synthetic materials such as super polyamides (polymers

from £ ~ caprolactam or from hexamethylenediamine adipate), mainly linear polyesters, such as. Ethylenpolyyterenthalaten, such as polyacrylonitrile etc. .The ones intended for coloring Materials can be in the most varied of forms, for example in the form of foils or webs or films.

-18-

209840/0995

In the case of materials with a strong affinity, such as polyamides or polyesters, the fastness properties are opposite Water, washing and abrasion excellent and superior to those you can use on these materials even with the same dyes obtained by the dyeing and printing processes according to the state of the art. The clarity of the lines and the Design is remarkable "

In the following examples, which do not limit the scope of the invention, all parts and percentages, unless otherwise stated, relate to weight and the temperatures to ⁰ ° C.

example 1

Printing of a multicolored design on a surface of a film made of ethylene terephthalate polymer.

A thin layer of bone gelatin (approx. 2 g / m 2) is placed on a paper web with the help of a or miller Rollers and a solution of 10 g of gelatin in 100 parts of a mixture of 5 parts of ethyl alcohol with 100 parts of V / & 3-ser up and dry.

You make yellow, red and blue inks for what you do 6 parts of each of the dyes

-19-BATH ORIGINAL

2098A0 / 099S

(yellow)

- 19 -

(Red)

K3-.CH,

and

(blue)

UH- CH.

dispersed with 6 parts of ethyl cellulose in 88 parts of isopropyl or ethyl alcohol. By means of color light printing, these printing inks and several Parb rollers are used to print the paper surface coated with bone gelatin in such a way that a multicolored design is obtained and then dried.
A film or a fabric made of ethylene terephthalate polymer is placed on the paper web printed in this way and the whole thing is passed over a metal plate that is electrically heated to 200.degree. A second, unheated plate ensures correct contact. The contact time in the heat is 1 minute. In this way, a faithful replica of the design is obtained on the polymer, with the lines
stay clear.

Instead of the film or fabric made of ethylene terephthalate polymer one can use a polyamide film, fabric or

209840/0995

knitwear (hexamethylene polyadipamide or 6-caprolactam polymer) use.

One can continue to work continuously if one is on slightly higher temperature and the speed of the printed paper and the film intended for coloring regulates so that it is, for example, 25 seconds at 210 C in Be in contact.

With this method, the color yield is much better than when a paper is used that does not have a gelatin layer.

Example 2

The procedure is as in Example 1, but on a single printing machine whose first V7 roller applies a solution of 12 parts of bone gelatine in 100 parts of water to the paper over its entire width. After the paper has dried in between, it is passed over the other rollers of the machine, which print a multicolored design using the yellow, red and blue printing inks specified in Example 1.

The provisional carrier obtained in this way enables the same Way of printing on polyester or polyamide surfaces with remarkable clarity.

Ovoalburnin can also be used instead of gelatin.

ORIGINAL BATHROOM 209840/0995 - ■ - ■ "

- 21 -

Example 3

A green printing ink is produced by adding, in 88 parts of isopropyl alcohol, 7 parts of a preparation containing 50 $> ethyl cellulose and 50 $ blue dye, made from a mixture of dyes of the formula

• HO 0

(η = 0.1 and 2) 0 OH

is formed, contains and 5 parts of the preparation, the 50 <fa yellow dye, namely 2-kydroxy ~ 5-raethyl-4 ^l -acetylaminoazobenzene and 50 ^c ß> ethyl cellulose contains, dispersed.

Further, to an orange ink ago, "v / ozu to 6.5 or 6 parts of preparation 50 fo ethyl cellulose and 5O io yellow dye and 5C $ äes in Example 1 given red dyes (3-Hydroxychinophthaloris or 1 -Hydroxy-4-amino-3-phenoxyanthraquinone ^ contains, dispersed in 90 parts of isopropyl alcohol.

A green plain print is affixed to a provisional one Paper carrier with the help of an engraved cylinder with one Easter often ended in this process. Kan dries up. A motif, for example flowers, is then printed on this uni-green print using color light printing Preparation that

BATH ORIGINAL ^d ~

209840/0995

- 22 5 parts bone gelatin,

0.2 parts potassium dichromate,
95 parts of water and
5 parts of ethyl alcohol

contains.

You dry it, then print one with the orange printing ink Circle area in the center of the flowers. One dries.

The provisional support thus obtained makes it possible to transfer a print dry in the vapor phase with "remarkable clarity on white polyester, polyacrylonitrile or polyamide surfaces, with white flowers with an orange heart on a green background. In example 4

A uniform red print is produced on a paper carrier with the help of the following printing inks:

4 parts of a preparation containing 5O ^c /> ethyl cellulose and 50 io i-hydroxy-A-amino - ^ - phenoxysnthraquinone,

4 parts of ethyl cellulose,
92 parts isopropyl alcohol.

This print is then dried and coated uniformly with a colloidal layer

5 parts chrome gelatine (8 Gev / .jS xalium dichromate)

2098AO / 0995 ■

92 parts of water,
8 parts of ethyl alcohol.

It is dried in the darkroom and exposed through a Transparent that has the image to be transmitted. Han developed with a lukewarm (40 C) solution

80 parts of water and
20 parts of ethyl alcohol

and dries

The temporary support produced in this way has a more or less pronounced colloidal layer corresponding to de; lesser or greater opacity of the original on. This is not possible through dry transfer in the vapor phase he reproduces this original in red on any polyester, polyamide or polyacrylonitrile surface.

An organic solvent other than isopropyl alcohol, for example toluene, can be used in the same way.

Example 5

Using one of the printing inks described in the previous examples, nan creates a plain print a support covered by an ethylene poly terephthalate film with about 60 / u thickness and brings one

209840/0995

thin layer of bone gelatin according to the method described in Example 1 for a paper strip.

The carrier produced in this way enables a satisfactory dry transfer in the vapor phase to any polyester, Polyamide or polyacrylonitrile surface.

Similar good results are obtained if instead of the ethylene poly terephthalate film or the paper strip a cellophane film or a film made of cellulose acetate is coated with a thin layer of gelatin.

Claims

2098A0 / 0995

Claims (38)

Patent claim> smells: 1., sheets, foils or strips or tapes made of flexible Materials that are stable to heat, preferably made of Paper or paper which is glued to aluminum foil, characterized in that one of its surfaces wholly or partially in any order with at least 2 thin layers of organic Materials is covered, the one being a color layer, which is essentially dyes and / or optical brighteners that transform into a vapor state at temperatures between 160 and 220 C at atmospheric pressure and contains binders that are stable in this temperature range and in the organic, to produce the print The solvents used are soluble and the other layer is formed from albuminoid material, the opposite Heat is stable in this temperature range, which can be photosensitive if this layer is applied to a color layer and which is preferably not hardened when this layer is applied between the paper surface and the color layer is · 2. Carrier according to claim 1, characterized in that it has a layer without defects have albuminoid material between the paper surface and the color layer. 3. Carrier according to claim 1, characterized in that that they have a layer of color between the surface of the paper and the albumide layer. 2098A0 / 0995 4. Carrier according to claim 1, characterized in that that the color layer is between two layers of albuminoid material, one of which adheres to the paper and is free of errors. 5. Carrier according to one of claims 1 to 4, characterized in that the layer or the Layers of albuminoid materials that comprise them are formed essentially from gelatin. 6. Carrier according to one of claims 3 and 4, characterized in that the layer of albuminoid is marked i without t Material that is printed on the color layer is photosensitive. 7. Carrier according to claim 6, characterized in that that the photosensitive layer is essentially formed from chromium gelatin. 8. Carrier according to one of claims 3 and 4, characterized characterized in that the albuminoid layer printed on the color layer, in the form of a design or motif, which is regular or not, only applied over part of the surface of this paint layer is. 9. Carrier according to claim 8, characterized in that that the layer of albuminoid material 209840/0995 rial, which on the color layer in the form of a design or Motif printed regularly or not in cold or lukewarm water, or in a mixture of water and is insoluble in an organic solvent. 10. Carrier according to claim 9, characterized that the layer of albuminoid material, which on the color layer in the form of a design or Ι.Γο-tivs, whether or not regularly printed, contains essentially gelatin insolubilized by the action of a chemical agent or light in the presence of dichromate. 11. substrate according to one of claims 1 to 10, as like ur cf \ in that the color layer is present ERA either in direct contact with the carrier or insulated against the carrier by means of a layer of albuminoidem material having a single color. 12. Carrier according to one of claims 1 to 10, d a d u r cb characterized in that the color layer, be it that it is in direct contact with the carrier or that it is isolated from the carrier by a layer of albuminoid material, a design or a motif, that occurs regularly or not, by one or "several" Has colors. -28- 2098A0 / 0995 13. Carrier according to one of claims 1 to 12, characterized characterized in that the paint layer or layers of paint applied to them are, odjer rent a cellulose ether as a binder. 14 ·· Carrier according to one of Claims 1 to 13, characterized in that the Dyes and / or optical brighteners which are contained in the colored layer or layers and which are applied to these carriers have sublimation or evaporation curves, between 180 and 210 C at atmospheric pressure lie. ·. 15 · Carrier according to one of claims 13 or 14 »characterized in that the color layer or colored layers which they have contain one or more anthraquinone dyes. 16. Carrier according to one of claims 13 or H, characterized in that the color layer or color layers which they have contain one or more azo dyes. 17. Carrier according to one of claims 13 or 14, there- ¹ -29-BATH ORIGINAL 2098AO / 0995 characterized in that the color layer or layers which they have, an ode contain several quinophthalone dyes. 18. Carrier according to one of claims 13 or 14, characterized in that the color layer or at least the colored layers they have contain one of the following dyes: 1,4 ~ dimethylaminoanthraquinone, Mixtures of mono- and dibroin-1,5-diamino-4,8-dihydroxyanthraquinone, Mixtures of mono- and dichloro-1,5 ~ disKino-4,8-dihydroxyanthraquinone, 1-Amino-4-hydroxy-2-phenoxyanthraquinone, 4- (4'-methyl-2'-nitrophenylazo) -3-methyl-5-pyrazolone, 1-Amino-2-cyano ~ 4-anilide.oanthraquinone, 1-Amino ~ 2-cyano-4-cyclohexylaminoanthraquinone or one of the derivatives of the formula and where η is a specific number, preferably 3 or 4. -30- 209840 / 0-9 95 19 · Carrier according to one of claims 1 to 5, 11, 12, 14 to l8, characterized in that the colored layer or the colored layers that they have, ethyl and Contain hydroxypropyl cellulose as a binder. 20. A method for producing a carrier according to claim 1, characterized in that one wholly or partially on a film or a tape made of flexible heat-stable material, for example on a cellophane film or preferably on paper or paper that is glued to an aluminum foil, applies at least two thin layers of organic materials in any order, one layer being a color layer and essentially dyes and / or optical brighteners that are in the temperature range
between 160 and 220 G at atmospheric pressure in the vapor state and binders that are stable in this temperature range and soluble in the organic solvents used for the production of printing inks and the other layer contains an albuminoid material that is stable in this temperature range, the can be photosensitive if this
Layer on a layer of color and which is preferably not hardened if this layer is between the paper surface and the
Color layer is applied. - 21. The method according to claim 20 for producing a carrier according to claim 2, characterized in that a defect-free layer of albuminoid material is applied to the carrier on at least one of its surfaces
and this layer is then printed with a layer of color. 2098A0 / 099S 22. The method according to claim 20 for producing a carrier according to claim 3 »characterized in that one on the carrier first Printing a layer of color and then applying a layer of albuminoid material. 23 · Method according to claim 20, characterized that a flawless layer of albumino can be applied to a paper web over its entire surface idem material, then first prints a layer of color and then a second layer of albuminoid material brings up. 24 «Method according to any one of claims 20 to 23 for production of a carrier according to Claim 5, characterized in that the albuminoid material Gelatin used. 25 · Method according to one of Claims 22 and 23 for production a carrier according to claim 8, characterized in characterized in that the layer of albuminoid material applied to the color layer is in shape Designs or motifs that recur regularly ... . · Λ; or not, only part of the surface is applied. 26. Yerf & hren according to one of claims 22 and 23 for the production a carrier according to claim 9> thereby -32- 2098A0 / 0995 marked that after printing a photosensitive, cover the entire surface of the support the albuminoid layer on the color layer, this upper albuminoid layer is exposed, with one between them and the light source turns on the negative of the motif to be omitted, and then the albuminoid which has not been made insoluble Material removed by simply washing it out. 27. The method according to claim 26 for the production of a carrier according to claim 10, characterized in that that one uses chrome gelatine as albuminoid material and then developing with lukewarm or cold Water to which a solvent has been added. 28. The method according to any one of claims 20 to 27, characterized in that the carrier base, which is coated with an albuminoid layer or not, coated with a single color layer. 29 · The method according to any one of claims 20 to 27, characterized characterized in that the carrier base is coated with an albuminoid layer is or not, printed with a layer of ink, which is a. 209840/0 9-9 Design or a motif that is regular or not and that is monochrome or multicolored. 30. The method according to any one of claims 20 to 29, characterized in that there are color preparations used, which contain a cellulose ether as a binder. 31. The method according to claim 20 to 29, characterized characterized in that one uses color preparations that contain one or more dyes and / or optical Brighteners whose sublimation or evaporation curves are between 180 and 210 C at atmospheric pressure, contain. 32. The method according to claim 28 and 29, characterized marked that one can color preparations used which contain one or more anthraquinone dyes. 33. The method according to claim 28 and 29, characterized labeled that you can color preparations used which contain one or more azo dyes. 34. The method according to any one of claims 28 and 29, characterized in that color is added 209840/0995 uses preparations containing one or more quinophthalein dyes contain. 35. The method according to claim 28 and 29, characterized gekennzei chnet that one color preparations verv / ends the at least one of the following dyes contain: 1,4-dimethylaminoanthraquinone, mixtures of llono- and dibromo-1,5-diamino-4,8-dihydroxyanthraquinone, mixtures of mono- and dichloro-1,5-diamino-4,8-dihydroxyanthraquinone, i-Amino - ^ - hydroxy - ^ - phenoxyanthraquinone, 4- (4'-Kethyl-2'-nitrophenylazo) -3-methyl-5-pyrazolone, 1-Amino-2-cyano-4-anilidoanthraquinone, 1-Amino-2-cyano-4-cyclohexylamino-enthrone quinone or one of the derivatives of the 3? OH and where η is an integer, preferably 3 or 4. " 36. The method according to any one of claims 20 to 29 and 31 55 »characterized in that -35- 209840/0995 one uses color preparations that additionally act as a binder in organic solvents used for the production of Printing inks used for printing on paper contain soluble cellulose esters or ethers. 37 · Process for dry dyeing of synthetic materials using supports made of flexible material facing Heat stable, preferably made of paper or paper that is glued to aluminum foil, 'with one of its surfaces completely or partly in any order with at least 2 thin layers of organic materials is covered, one of which is a color layer 3 st, which is essentially dyes and / or optical brighteners that operate at temperatures between 160 and 220 C change into the vapor state at atmospheric pressure and contains binders which are stable in this temperature range and the other layer of albuminoid material is formed, which is stable to heat in this temperature range, characterized in that the support or supports are applied to the material intended for dyeing or printing and the whole thing at 180 to 210 ° C heated so long that an evaporation or sublimation of the dyes or brighteners and their penetration into the color intended material is effected. 38. The method according to claim 37 , characterized in that textiles are treated. 209840/0995 39 · Method according to claim 37> characterized in that the top surface of non-textile, synthetic materials is provided with dry printing. 209840/0995