DE202007003056U1 - Combination set for the decorative care of the skin - Google Patents

Abstract

Comprising a cosmetic combination kit
a.) a multi-chamber applicator for simultaneously and separately applying at least two preparations contained separately in the applicator, comprising a closure device which hermetically separates the preparations from each other and / or the environment and which comprises separate dispensing openings for each chamber,
b.) wherein at least one of the preparations is a skin care preparation and
c.) at least one other preparation is a decorative preparation and
d.) the skin-care and decorative preparations differ from each other in at least one ingredient, and
e.) the skin-care and the decorative preparations are selected so that they mix homogeneously during distribution, in particular on the skin,
characterized in that
the skin-care preparation in each case one or more constituents selected from the group of skin-care active ingredients, polymers with film-forming properties, emulsifiers, sensory additives and / or UV filters and
the decorative preparation in each case comprises one or more constituents selected from the group of dyes, pigments, emulsifiers, fillers, sensory additives and / or film formers.

Description

The The invention comprises a combination kit for the decorative care of A skin comprising a multi-chamber applicator and at least two cosmetic formulations, wherein at least one preparation for Care and at least one preparation intended for make-up of the skin is.

The Type of composition of cosmetic preparations finds its natural Limits caused by the compatibility the individual components together and the stability of individual components in the carrier medium be determined. For example, skin regenerating enzymes and vitamins in cosmetic preparations can not last indefinitely. The combination of differently charged polymers also results in cosmetic Formulations of clumping and precipitation.

There has been no lack of attempts to make such preparations available to the consumer. Most sub-components of the formulations are then packaged and stored separately. As a rule, so-called two-chamber packagings (dual chamber) are used for this purpose, in which the part preparations can be stored in separate storage vessels and taken out of the packaging container at the same time via a common opening. Such two-chamber packaging materials are described for example in WO 2005058272, WO 2003015739, WO 2002022103, WO 2005058259, WO 96/02230, WO 96/37420, WO 98/33477 and the EP 048703 described. In many cases, however, only cleaning preparations, whitening or hair dyes are suitably packaged herein.

conventional However, two-chamber packaging has a number of disadvantages, the their possible uses limited in the cosmetics industry.

The DE 103 42 211 describes a cosmetic, which is formed from a packaging with two separate pantries, the contents of which can be removed simultaneously by means of two coupled feed pumps via a common outlet opening and characterized in that the ratio of the subsidized by the two pumps cosmetic preparations to each other can be freely adjusted by means of a control mechanism, as well as two cosmetic preparations, which are each in one of the two storage chambers of the packaging and characterized in that they differ in their viscosity and / or concentration of cosmetic and / or dermatological agents from each other.

• – Verfahren und Produkt zur Behandlung der Haut, umfassend
• – eine erste Zusammensetzung, enthaltend mindestens einen ersten Wirkstoff
• – eine zweite Zusammensetzung, enthaltend mindestens einen zweiten Wirkstoff
• – einen ersten Behälter zum Aufbewahren der ersten Zusammensetzung,
• – einen zweiten Behälter zum Aufbewahren der zweiten Zusammensetzung, wobei der erste und der zweite Behälter zusammengefügt sind,
• – an den Behältern oder der zugehörigen Verpackung Verbrauchsanweisungen angebracht sind, über die Verwendung
• – der ersten und zweiten Zusammensetzung in Kombination miteinander in aufeinander folgender Reihenfolge,

um den ersten und den zweiten Vorteil der Behandlungsvorschrift zu erreichen.The US 6531116 and EP 828670 describe an application method and a cosmetic treatment product with the following features:

• - Method and product for the treatment of the skin, comprising
• A first composition containing at least one first active ingredient
• A second composition containing at least one second active ingredient
• A first container for storing the first composition,
• A second container for storing the second composition, wherein the first and second containers are assembled,
• - on the containers or the associated packaging instructions for use are attached, on the use
• The first and second compositions in combination with each other in successive order,

to achieve the first and second benefits of the treatment regimen.

EP 755243 and EP 966264 describe aqueous, liquid, cleansing and moisturizing compositions comprising mandatory surfactants, ie surfactants.

EP 916334 also describes a cleansing and make-up removing composition in a two-chamber package

US 5848732 discloses a 2-component dispenser with mixing device, wherein the mixing ratios of the two components can be variably adjusted.

EP 1541496 describes a multi-chamber dispenser for the simultaneous application of two separately stored preparations. The advantage of this packaging is that it is easy to manufacture and to design. The main advantage of this dispenser is a closure device, the hermetic Absi the separate components.

task The present invention is an easy-to-use cosmetic available too make it possible for the user at the same time, with a single application of two different unmixed ones Components have a skin-care as well as decorative effect to achieve.

Desirable In particular, it is a cosmetic to provide that no contains irritating substances or ingredients that negatively affect the skin can. It is therefore desirable to provide a cosmetic without detergent, both nourishing and simultaneously decorative effects unfolded.

Desirable In addition, the preparations are oil-free to formulate.

Farther would it be advantageous alternative cosmetic kits for decorative care the skin available to deliver.

object The invention is a cosmetic combination according to set Claim 1. In the dependent claims are preferred embodiments set of the set. The set can be used for concurrent care and decorative cosmetic treatment (make-up) of the skin can be used.

• – Einsatz zur Straffung der Haut
• – Einsatz zur Festigung der Haut
• – Einsatz zur Antifaltenpflege
• – Einsatz zu dekorativen Zwecken, wie insbesondere Abdecken von Hautunreinheiten oder Augenringen, Erzielung eines ebenmäßigen Teint und/oder eines natürlichen und strahlenden Teint und jugendliches Aussehens.

A preferred use of the kit according to the invention is:

• - Use to tighten the skin
• - Use to strengthen the skin
• - Use for anti-wrinkle care
• - Use for decorative purposes, such as especially covering blemishes or dark circles, achieving an even complexion and / or a natural and radiant complexion and youthful appearance.

These uses can be surprisingly good with the set according to the invention implement.

Advantageous showed that with the set according to the invention a long-lasting make-up, i. a make-up order, with up to 16 hours and more can be achieved.

• a.) einen Mehrkammerapplikator zur zeitgleichen und getrennten Ausbringung mindestens zwei im Applikator getrennt enthaltener Zubereitungen, umfassend eine Verschlussvorrichtung, die die Zubereitungen hermetisch voneinander und/oder der Umgebung trennt und die getrennte Ausgabeöffnungen für jede Kammer vorsieht.
• b.) Mindestens eine der Zubereitungen ist eine hautpflegende Zubereitung, bevorzugt auf Basis einer O/W-Emulsion, einer Hydrodispersion oder Hydrogel, und
• c.) mindestens eine andere Zubereitung eine dekorative Zubereitung, eine sogenannte Foundation, bevorzugt auf Basis einer W/S- oder O/W-Emulsion.
• d.) Die hautpflegenden und die dekorativen Zubereitungen unterscheiden sich in mindestens einem Inhaltstoff voneinander und
• e.) die hautpflegenden und die dekorativen Zubereitungen so gewählt werden, dass sie sich bei beim Verteilen, insbesondere auf der Haut, homogen mischen.

The combination set includes

• a.) a multi-chamber applicator for the simultaneous and separate application at least two preparations contained separately in the applicator, comprising a closure device which hermetically separates the preparations from each other and / or the environment and provides the separate discharge openings for each chamber.
• b.) At least one of the preparations is a skin-care preparation, preferably based on an O / W emulsion, a hydrodispersion or hydrogel, and
• c.) at least one other preparation is a decorative preparation, a so-called foundation, preferably based on a W / S or O / W emulsion.
• d.) The skin-care and the decorative preparations differ in at least one ingredient from each other and
• e.) the skin care and the decorative preparations are chosen so that they mix homogeneously when distributed, especially on the skin.

Under Homogeneous mixing is understood to mean that the preparations to a consistent phase (both color and texture) unite. For example, ethanol and water mix homogeneously, but oil and not water.

That With the naked eye, a phase boundary after distribution is not recognizable.

By the set according to the invention merge the preparations formally to a nourishing and at the same time preferred toning cosmetics.

The skin-care preparation comprises in each case one or more constituents selected from the group of skin-care active ingredients, polymers with film-forming properties, emulsifiers or hydrocolloids, sensory additives and / or UV filters and the decorative preparation comprises one or more Rere ingredients selected from the group of dyes, pigments, emulsifiers, fillers, sensor additives and / or film formers.

The Significant advantages of the kit according to the invention are as follows represent. According to the invention the sets a multi-chamber applicator, in particular a Doppelkammerapplikator with only one container which is divided into at least two chambers, each one Chamber a preparation - separately from the second or further preparations - absorbs. That that the applicator from a container with at least two separate preparation stores.

The Output of the preparations takes place simultaneously during application Activity, mostly pressing, one Actuating element, which acts on a valve and / or pump system, wherein for each chamber a Valve or valve / pump combination is present and the output Preparation streams via separate channels be led out of the chambers to the outside.

Of the Use of the multi-chamber applicators according to the invention Ensures easy handling not only in the application the consumer, but also in the production, in particular filling, benefits. In particular, the material costs compared to dispenser system of multipart containers lower. Due to the compact design is less storage space or Anbietungsfläche necessary. The simultaneous filling leads into all chambers in the further to shorter Machine cycles, which is a significant cost advantage over usual Dual chamber dispensers of the prior art, the in several items are delivered. The multi-chamber applicators according to the invention can be based on conventional Fill production lines and for prepare the shipping without the multiple containers united to a product Need to become.

• – Mehrkammerschleppkolbendispenser,
• – Bag-in-Bottle- bzw. Bag-in-Can-Systeme die mindestens zwei Compartments, insbesondere Folienbeutel, aufweisen und aus denen die Zubereitungen durch Druckbeaufschlagung oder Förderpumpen austragen werden oder
• – Mehrkammerpumpdispenser.

According to the invention are particularly suitable

• - multi-chamber centrifugal piston dispenser,
• Bag-in-bottle or bag-in-can systems which have at least two compartments, in particular foil bags, and from which the preparations are discharged by pressurization or feed pumps or
• - Multi-chamber pump dispenser.

All Particularly suitable are multi-chamber pump dispensers, as these in contrast be filled into multi-chamber tow-piston systems in conventional pot-filling can, which works faster and safer than the filling of below.

at Multi-chamber dispensers will be the container with the separate chambers preferably closed by a snap-on closure element. In the closure element are just as many pumps - preferably a riser and at least one valve comprising - as container chambers integrated, so that the closure of the Mehrkammersdispensers only a prefabricated part put on (cheated or pressed) must be. The closure element can be designed so that the flexible sealing elements, the chamber openings seal against each other. Such a multi-chamber dispensers are special prefers.

By the hermetic sealing of the chambers with each other or to the environment, a mixture of the products is prevented. The height Safety when closing guarantees such a functional Product.

all Inventive multi-chamber applicators is common, that also in the discharge of the preparations no Mixing can take place. Clogging of the transport channels or the output ports by mutually reactive preparation proportions of different Preparations are excluded.

The Mixing of the separately applied preparations takes place first in the application, in particular only with the trituration on the Skin.

Of the preferred according to the invention used containers also has a significant material savings over others Systems, as well as cost and ecological Advantages.

Prefers includes the skin care preparation, hereinafter referred to as preparation A, a W / S, an O / W emulsion, a hydrodispersion and / or a hydrogel.

When Component or parts are skin-care in the skin-care preparation Contain substances. Preference is given in the skin-care preparation in each case at least one or more constituents selected from Group of skin-care agents, polymers with film-forming Properties, emulsifiers, hydrocolloids, sensory additives and / or Includes UV filter.

• a.) hautpflegende Wirkstoffe, bevorzugt Ascorbinsäure und deren Derivate, Hyaluronsäure oder deren Salze, insbesondere Natriumhyaluronat, Kollagen und Wirkstoffe, die die Kollagensynthese stimulieren wie Ginkgo und/oder Mischungen daraus. Ebenso sind Feuchthaltemittel besonders bevorzugte hautpflegende Stoffe, wie z.B. Glycerin, Harnstoff (Urea) und/oder Pentylenglycol. Bevorzugte Kombinationen sind Ascorbinsäure, Hyaluronsäure, Soluble Collagen, Trehalose und Gingko. Bevorzugt in Einsatzanteilen von 0,01–2,5 Gew.%, vorteilhaft auch von 0,01–10 Gew.%, bezogen auf die Gesamtmasse der Zubereitung A. Die bevorzugte Kombination aus Ascorbinsäure und deren Derivaten, z.B. Vitamin C Phosphat, Hyaluronsäure und Gingko (GingkoGinglo Biloba) spricht verschiedene Mechanismen der Hautstraffung, wie Faltenfüllung, antioxidativer Schutz und Stimulation des hauteigenen Kollagens, an und stellt somit eine bevorzugte Verwendung des erfindungsgegemäßen Sets dar.
• b.) Polymere mit filmbildenden Eigenschaften, insbesondere VP/VA Copolymere, Natriumpolystyrensulfonat (Sodium Polystyrene Sulfonate), Trimethylsiloxysilikate, Acrylat/Dimethicon Copolyol und/oder Polyquaternium 51. Die Polymere werden vorteilhaft einzeln oder auch in Kombination in bevorzugten Anteilen von 0,1–10 Gew.%, besonders vorteilhaft 0,1–2,5 Gew.%, bezogen auf die Gesamtmasse der Zubereitung A eingesetzt. Die bevorzugten Polymere liefern durch die Filmbildung auf der Haut einen sofort spürbaren Straffungseffekt und erhöhen die Transfer-Resistance und den langanhaltenden Effekt der dekorativen Formulierung. Auch dadurch ist die bevorzugte Verwendung des Sets zur Hautstraffung gegeben und es zeigt sich die erstaunlicherweise vorteilhafte Lösung der gestellten Aufgaben.
• c.) Emulgatoren, wie insbesondere Sucrose Ester, bevorzugt Sucrosepalmitate in Abmischung mit Glycerylstearate und Glycerylstearatcitrate (Handelsname Arlatone V-175) oder Polyglyceryl-3 Disiloxan Dimethicon, Polyglyceryl-4 Isostearat und/oder Cetyl PEG/PPG-10/1 Dimethicon. Bevorzugte Anteile der Emulgatoren sind 0,01–10 Gew.%, besonders vorteilhaft 0,01–5 Gew.%, bezogen auf die Gesamtmasse der Zubereitung A. Im Falle von Hydrodispersionen/Hydrogelen bilden emulgatorfreie Zubereitung bevorzugt auf Basis von Hydrokolloiden wie Ammonium Polyacryloyldimethyl Taurate (kommerziell verfügbar z.B. als Aristoflex AMPS und/oder AVC von Clariant) und Polyacrylamide kommerziell verfügbar z.B. in Kombination mit C13-14 Isoparaffin und Laureth-7 als Sepigel 305 von SEPPIC, die Zubereitung A.
• d.) Als Lichtschutzfilter (UV-Filter) können eingesetzt werden bevorzugt Titandioxide (unbeschichtet) und/oder Ethylhexyl Methoxycinnamate.
• e.) Als Sensorikadditive können Effekt- bzw. Farbstoffe, wie Lauroyllysine, Polymethylsilesquioxane, Siloxane Elastomere wie Dimethicone Crosspolymer Polymethylmethacrylate Crosspolymer, Nylon, Talkum, Mica oder Stärkederivate eingestezt werden. Besonders bevorzugt als Sensorikadditive sind Lauroyl Lysine und/oder Polymethylsilesquioxane, Nylon und Siloxane Elastomere wie Dimethicone Crosspolymer der hautpflegenden Zubereitung zu zusetzen.

Preference is given in preparation A:

• a.) skin-care agents, preferably ascorbic acid and its derivatives, hyaluronic acid or its salts, in particular sodium hyaluronate, collagen and active ingredients which stimulate collagen synthesis such as ginkgo and / or mixtures thereof. Likewise, humectants are particularly preferred skin care substances, such as glycerol, urea (urea) and / or pentylene glycol. Preferred combinations are ascorbic acid, hyaluronic acid, soluble collagen, trehalose and gingko. Preferably in amounts of 0.01-2.5 wt.%, Preferably also 0.01-10 wt.%, Based on the total mass of the preparation A. The preferred combination of ascorbic acid and its derivatives, for example, vitamin C phosphate, hyaluronic acid and Gingko (GingkoGinglo Biloba) addresses various skin tightening mechanisms, such as wrinkle filling, antioxidant protection, and skin collagen stimulation, and thus represents a preferred use of the kit of the present invention.
• b.) Polymers having film-forming properties, in particular VP / VA copolymers, sodium polystyrene sulfonate, trimethylsiloxysilicates, acrylate / dimethicone copolyol and / or Polyquaternium 51. The polymers are advantageously used individually or in combination in preferred proportions of 0.1- 10 wt.%, Particularly advantageously 0.1-2.5 wt.%, Based on the total mass of the preparation A used. The preferred polymers provide an immediately noticeable tightening effect through the film formation on the skin and increase the transfer resistance and the long-lasting effect of the decorative formulation. Also, this is the preferred use of the set for skin tightening and it shows the amazingly advantageous solution of the tasks.
• c.) emulsifiers, in particular sucrose esters, preferably sucrose palmitates in admixture with glyceryl stearate and glyceryl stearate citrate (trade name Arlatone V-175) or polyglyceryl-3 disiloxane dimethicone, polyglyceryl-4 isostearate and / or cetyl PEG / PPG-10/1 dimethicone. Preferred proportions of the emulsifiers are 0.01-10% by weight, particularly advantageously 0.01-5% by weight, based on the total mass of the preparation A. In the case of hydrodispersions / hydrogels, emulsifier-free preparation preferably based on hydrocolloids such as ammonium forms polyacryloyldimethyl Taurate (commercially available eg as Aristoflex AMPS and / or AVC from Clariant) and polyacrylamides are commercially available eg in combination with C13-14 isoparaffin and Laureth-7 as Sepigel 305 from SEPPIC, the preparation A.
• d.) As light protection filters (UV filters) can be used preferably titanium dioxides (uncoated) and / or ethylhexyl Methoxycinnamate.
• e.) As effect additives, such as lauroyllysines, polymethylsilkenquioxanes, siloxane elastomers such as Dimethicone Crosspolymer Polymethylmethacrylate Crosspolymer, nylon, talc, mica or starch derivatives can be used. Particularly preferred as sensory additives are lauroyl lysines and / or polymethylsilkenquioxanes, nylon and siloxanes elastomers such as Dimethicone Crosspolymer add to the skin care preparation.

Further preferred components of the skin care preparations in more detail below described.

The Further preparation B, the decorative preparation, comprises at least a decorative ingredient. The preparation B is therefore also to refer to as a foundation or make-up formulation and is preferably characterized by at least one dye or Pigment content, preferably in a proportion of 2 wt.% And more, especially preferably 10% by weight and more, based on the total mass of the preparation B.

The Preparation B is advantageously colored, e.g. by dye or Pigments. The preparation B is preferably based on a W / S or O / W emulsion, characterized by at least one ingredient of the Preparation A is different.

Prefers in preparation B are each one or more ingredients chosen from the group of dyes or pigments, emulsifiers, fillers, Sensor additives and / or film formers included.

• a.) Farbstoffe und/oder Pigmente, bevorzugt sind pigmentäre Farbstoffe auf Basis Eisenoxide, Titandioxide, gecoatet oder nicht gecoatet. Zusätzlich können Effektpigmente wie beispielsweise Perlglanzpigmente oder Metalleffektpigmente enthalten sein.
• b.) Emulgatoren wie, z.B. Abil EM 90 (Cetyl PEG/PPG-10/1 Dimethicone) alleinig/oder in Kombination Polyglyceryl-3 Disiloxan Dimethicon, Polyglyceryl-4 Isostearat bei W/S-Emulsion, bevorzugt in Anteilen von 0,5–10 Gew.%, bevorzugt 2–6 Gew.%, bezogen auf die Gesamtmasse der Zubereitung B. Weiter bevorzugt sind Sucrose Ester, bevorzugt Sucrose Palmitate in Abmischung mit Glyceryl Stearate, Glyceryl Stearate Citrate (Arlatone V-175) bei einer O/W-Emulsion. Enthaltend sind dann vorteilhaft 0,01–3 Gew.%, besonders vorteilhaft 0,01–1.5 Gew.%, an Emulgatoren, bezogen auf die Gesamtmasse der Zubereitung B.
• c.) gegebenenfalls Füllstoffe, wie gecoatetes Silica (Silica LD-P),
• d.) Sensorikadditive wie Lauroyllysin, Polymethylsilesquioxane, Polymethylmethacrylate, Silica, Nylon, Talkum, Siloxane Elastomere wie beispielsweise Dimethicone Crosspolymer, Mica und/oder Stärkederivate.
• e.) Gegebenenfalls können auch Filmbildner wie Trimethylsiloxysilicate im Falle einer W/S-Emulsion enthalten sein.

Preferably, the constituents are selected from the groups of

• a.) dyes and / or pigments, preferred are pigmentary dyes based on iron oxides, titanium dioxides, coated or not coated. In addition, effect pigments such as pearlescent pigments or metallic effect pigments may be included.
• b.) emulsifiers such as, for example Abil EM 90 (Cetyl PEG / PPG-10/1 Dimethicone) alone or in combination polyglyceryl-3 disiloxane dimethicone, polyglyceryl-4 isostearate in W / S emulsion, preferably in amounts of 0.5 % By weight, preferably 2-6% by weight, based on the total mass of preparation B. Further preferred are sucrose esters, preferably sucrose palmitates in admixture with glyceryl stearate, glyceryl stearate citrate (Arlatone V-175) in an O / W emulsion. Containing are then advantageously 0.01-3 wt.%, Particularly advantageously 0.01-1.5 wt.% Of emulsifiers, based on the total mass of the preparation B.
• c.) optionally fillers, such as coated silica (Silica LD-P),
• d.) Sensory additives such as lauroyl lysine, polymethyl silsesquioxanes, polymethyl methacrylates, silica, nylon, talc, siloxane elastomers such as dimethicone crosspolymer, mica and / or starch derivatives.
• e.) Optionally, film formers such as trimethylsiloxysilicates may be included in the case of a W / S emulsion.

Especially preferred as sensor additives are lauroyl lysines, silica, nylon, Siloxane elastomers such as Dimethicone Crosspolymer, Silica LD-P or Polymethylsilesquioxane in proportions of 0.1-10 wt.%. the individual components, particularly preferably 0.5-5 wt.%, Based on the total mass the preparation B included.

optional can the Foundation also contains active ingredients or light filters as described in the skin care preparation.

Further preferred components of the decorative preparations are hereafter in detail described.

The listed preferably mentioned components of the skin care as well as the decorative preparations can be selected individually and independently depending on the application. However, it is important to note the compelling requirement that the two preparations differ by at least one ingredient and mixed together so that they mix homogeneously. The latter is just by the components mentioned as preferred and their shares guaranteed in particular.

The combination set therefore preferably comprises a dispenser for the simultaneous and separate application of at least two preparations stored separately in the dispenser, comprising a closure device which hermetically separates the preparations from one another and / or the environment, hyaluronic acid and / or salts thereof being present in at least one of the two preparations. TiO ₂ , nylon and / or cetyl PEG / PPG-10/1 dimethicone are included.

The Both preparations differ in at least one Ingredient and can be during distribution, in particular on the skin, mix homogeneously.

Prefers the cosmetic combination kit comprises one of the two preparations as W / Si emulsion, which in turn comprises cetyl PEG / PPG-10/1 dimethicone.

The inventive combination of at least two separately stored preparations which differ by at least one ingredient, wherein a skin-care formulation and the other is a foundation and both preparations are chosen so that they mix homogeneously during distribution, preferably on the skin, in a dispenser that ensures the simultaneous application of both preparations and beyond by a closure device that hermetically separates the preparations from each other and preferably also from the environment, and thus helps to avoid contamination and interference, represents a surprisingly simple and ingenious solution of the tasks and At the same time, in addition to applying make-up, it is also possible to care for the skin at the same time without the preparations interfering with each other, adversely affecting them or even rendering them ineffective. By providing a concentrated care formulation and at the same time a decorative formulation, the care performance (skin moisturizing, skin smoothing) of the decorative formulation is efficiently increased. The advantage lies in the simultaneous and thus time-saving application of skin care and decoration (make-up) in one. By providing a concentrated care formulation simultaneously with the decorative formulation, the care performance, such as skin moisturizing or skin smoothing, of the decorative formulation is effectively increased. It becomes a simultaneous effect from the inside, such as care and firming through cosmetic agents, with an immediate visible effect from the outside, like even, well-groomed skin through make-up, combined.

Of the set according to the invention used for the effects of skin tightening and / or firming of the skin, Anti-wrinkle effect, covering blemishes or dark circles, even complexion, more natural and radiant complexion, youthful appearance, long-lasting, lamination small wrinkles, to reach. That this invention succeeds and beyond also easier, time-saving and effective, in particular impressively confirmed by the following examples.

The inventive combination from dispensers and at least two cosmetic preparations, wherein one is at least one skin care and the other preparation develop a decorative effect on the skin, allows only the simple, user-friendly and formulated in the task simultaneous care and decoration of the skin.

Around no skin damage to cause the combination set according to the invention comprises no detergent, no surfactants and is not suitable for cleaning the skin.

Prefers the set is also oil-free, i.e. they are not oils which remain on the skin and leave an unpleasant, greasy film of oil.

Oil free means so that no low-volatile oils contain are.

Oil free means According to the invention that volatile oils, the after application in the shortest possible time volatilize not under the aforementioned oil fall.

at the volatile three oils like e.g. C13-14 isoparaffin, cyclopentasiloxanes are volatile oils which contained in "oil-free" products could be, because these evaporate on the skin and leave no oily film on the skin.

As well It is important that both combined preparations are not in succession following order, but applied at the same time become.

As well It is essential that the two preparations, the skin-care Preparation and the Foundation mix homogeneously when distributing. The distribution advantageously takes place directly on the skin. This surprisingly, it is particularly advantageous because of preferred named constituents.

to Application, the preparations of the invention in the usual for cosmetics Applied to the skin in sufficient quantity. The cosmetic according to the invention Preparations can as usual be composed and for treatment, i. for the care of the skin and serve as a make-up product in decorative cosmetics.

It is advantageous according to the invention if the care emulsion an O / W emulsion, a hydrodispersion and / or a hydrogel and the foundation is a water-in-silicon (W / S) Represent emulsion.

The cosmetic preparations according to the invention preferably represent emulsions.

It is particularly preferred in the context of the present invention, when one of the two chambers is a preparation for the care of the skin (Preparation A, also referred to below as a care emulsion) and the other of the two chambers a make-up preparation the skin (preparation B, also referred to as foundation in the following) contains.

It is particular to the invention beneficial if both the care emulsion and the foundation in the form of an oil-in-water emulsion (O / W emulsion) are present. In another advantageous according to the invention embodiment the care emulsion is an O / W emulsion and the foundation is a water-in-silicone (W / S) emulsion.

In the event that one or both of the preparations are in the form of an O / W emulsion, the O / W emulsifier (s) according to the invention are preferably selected from the following group, the emulsifiers mentioned above being preferred:
Sucrose esters - in particular sucrose palmitate - in combination with glyceryl stearate and glyceryl stearate citrate (available, for example, under the trade name Arlatone V-175 from Uniqema), but also Gly ceryl stearate in combination with ceteareth-20 and / or ceteareth-25, ceteareth-6 in combination with stearyl alcohol, cetylstearyl alcohol in combination with PEG-40 castor oil and sodium cetyl stearyl sulphate, triceteareth-4 phosphate, glyceryl stearate, sodium cetyl stearyl sulphate, lecithin trilaureth-4 phosphate, laureth -4 Phosphate, Stearic Acid, Propylene Glycol Stearate SE, PEG-25 Hydrogenated Castor Oil, PEG-54 Hydrogenated Castor Oil and / or PEG-6 Caprylic Acid / Capric Acid Glycerides, Glyceryl Oleate in Combination with Propylene Glycol, PEG-9 Stearate, PEG-20 Stearate, PEG -30 stearate, PEG-40 stearate, PEG-100 stearate, ceteth-2, ceteth-20, polysorbate-20, polysorbate-60, polysorbate-65 and / or polysorbate-100, glyceryl stearate in combination with PEG-100 Stearate, glyceryl myristate, glyceryl laurate, PEG-40 sorbitan peroleate, laureth-4, ceteareth-3 and / or isostearyl glyceryl ether, cetyl stearyl alcohol in combination with sodium cetyl stearyl sulfate, laureth-23 and / or steareth-2, glyceryl stearate in combination with PEG-30 stearate, PEG-40 stearate, glycol distearate, PEG-22 dodecyl glycol copolymer, polyglyceryl-2-PEG-4 stearate, ceteareth-12, ceteareth-20, ceteareth-30, methyl glucose sesquistearate, steareth- 10 and / or PEG-20 stearate, steareth-2 in combination with PEG-8 distearate, steareth-21, steareth-20, isosteareth-20, PEG-45 / dodecyl glycol copolymer, methoxy-PEG-22 / dodecyl glycol copolymer , PEG-40 sorbitan peroleate, PEG-40 sorbitan perisostearate, PEG-20 glyceryl stearate, PEG-20 glyceryl stearate, PEG-8 beeswax, polyglyceryl-2-laurate, isostearyl diglyceryl succinate, stearamidopropyl PG-dimonium chloride phosphate, glyceryl stearate SE, ceteth- 20, triethyl citrate, PEG-20 methyl glucose sesquistearate, glyceryl stearate citrate, cetyl phosphate, cetearyl sulfate, sorbitan sesquioleate, triceteareth-4-phosphate, trilaureth-4-phosphate, polyglyceryl methyl glucose distearate, potassium cetyl phosphate, polyglyceryl-3 methyl glucose distearate, isosteareth-10, polyglyceryl-2-sesquiisostearate , Ceteth-10, oleth-20 and / or isoceteth-20, eq yceryl stearate in combination with ceteareth-20, ceteareth-12, cetylstearyl alcohol and / or cetyl palmitate, cetylstearyl alcohol in combination with PEG-20 stearate, PEG-30 stearate, PEG-40 stearate and / or PEG-100 stearate.

Particularly according to the invention Advantageous O / W emulsifiers are sucrose esters - in particular sucrose palmitate - in combination with glyceryl stearate and glyceryl stearate citrate (available, for example, under the Trade name Arlatone V-175 from Uniqema) glyceryl stearate, PEG-40 stearate, triglycerol methyl glucose distearate, polyglyceryl-3 Methyl glucose distearate, polyethylene glycol (21) stearyl ether, polyethylene glycol (2) stearyl ether, Cetearyl glucoside, glyceryl stearate citrate, sodium cetearyl sulfate, Cetearyl alcohol and / or sorbitan stearate.

preferred Parts of the emulsifiers are 0.01-3 wt.%, Particularly advantageous 0.01-1.5 % By weight, based on the total mass of preparation A.

The Cosmetic preparation B, the foundations, can be beneficial one or contain more silicone emulsifiers, especially when in shape of W / S emulsions.

bei welcher X und Y unabhängig voneinander gewählt werden aus der Gruppe H sowie der verzweigten und unverzweigten Alkylgruppen, Acylgruppen und Alkoxygruppen mit 1–24 Kohlenstoffatomen, p eine Zahl von 0–200 darstellt, q eine Zahl von 1–40 darstellt, und r eine Zahl von 1–100 darstellt.According to the invention, the silicone emulsifier (s) can advantageously be selected from the group of surface-active substances from the group of alkyl methicone copolyols and / or alkyl dimethicone copolyols, in particular from the group of compounds characterized by the following chemical structure:

wherein X and Y are independently selected from the group H and the branched and unbranched alkyl groups, acyl groups and alkoxy groups having 1-24 carbon atoms, p is a number from 0-200, q is a number from 1-40, and r is one Represents number from 1-100.

An example of particularly advantageous for the purposes of the present invention to use silicone emulsifiers are dimethicone, which, by the company Degussa AG under the tradenames ABIL ^® B 8842, ABIL ^® B 8843, ABIL ^® B 8847, ABIL ^® B 8851, ABIL ^® B 8852 ABIL ^® B 8863, ABIL ^® B 8873 and ABIL ^® B sold the 88,183th

Another example of particularly advantageous to use in the context of the present invention, silicone emulsifiers, as already mentioned, the cetyl PEG / PPG-10 which is sold under the tradename ABIL ^® EM 90 from the company Degussa AG / 1 Dimethicone.

Another particularly advantageous for the purposes of the present invention to be used silicone emulsifier is a cyclomethicone dimethicone, which is sold under the trade name ABIL ^® EM 97 by the company Goldschmidt AG.

Furthermore, the emulsifier lauryl has proven to be particularly advantageous which, under the trade name Dow Corning ^® 5200 Formulation Aid by the company Dow Corning Ltd. is available.

The Total amount of silicone emulsifiers in or cosmetic according to the invention Preparations are advantageously from the range of 0.1 to 10.0 % By weight, preferably 0.5 to 5.0% by weight, more preferably 2-4% by weight, in each case based on the total weight of the decorative preparations.

The cosmetic preparations B according to the invention may furthermore advantageously contain one or more surface-active polyethers, in particular if the preparations are in the form of W / S emulsions:
Advantageous in the context of the present invention are the polyethers designated in the Chemical Abstracts with the registration number 78336-31-9, which carry the chemical name Polyethylenglycoldi (polydodecylene glycol) ether and, for example, as PEG-45 (dodecyl glycol) copolymer under the trademark Elfacos ^® ST 9 (average molecular weight about 4,000 g / mol) or as PEG-22 (dodecyl glycol) copolymer under the brand Elfacos ^® ST 37 (average molecular weight about 2 300 g / mol) are sold by the company Akzo Nobel Chemicals GmbH ,

The Total amount of surfactant Polyethers in the finished cosmetic preparations will be advantageous from the range of 0.1 to 10% by weight, preferably 0.25 to 5.0% by weight in particular 0.75 to 3.5 wt .-%, in each case based on the Total weight of decorative preparations B.

It is also advantageous for the purposes of the present invention, polyethylene glycol-30 dipolyhydroxystearate (PEG-30 dipolyhydroxystearate), which is sold by the company Uniqema under the trade designation ARLACEL ^® P135 to use as surface-active substance, especially if the preparation in the form of a Water-in-oil emulsion is present. In addition, PEG-30 dipolyhydroxystearate - as well as other W / O emulsifiers - but also be used advantageously as a film former, for example, to improve the abrasion resistance (transfer resistance) of the preparations or to achieve long-lasting effects.

This Leaves effect by the standard methods known in the literature and Occupy home-in-use data.

The foundation according to the invention (preparation B) may, in a special embodiment, advantageously also be in the form of a water-in-oil emulsion (W / O emulsion). In this case, the following emulsifiers are preferred according to the invention:

All it is particularly preferred if the one or more W / O emulsifiers are selected from the group PEG-30 dipolyhydroxystearate, polyglyceryl-3-diisostearate, PEG-40 sorbitan perisostearate.

The oil phase components the preparations according to the invention A and / or B are advantageously selected from the group of fatty acid triglycerides, namely the triglycerol esters of saturated and / or unsaturated branched and / or unbranched alkanecarboxylic acids of a chain length of 8 to 24, in particular 12 to 18 carbon atoms. Especially advantageous in the context of the present invention is caprylic-capric triglyceride (INCI: Caprylic / capric triglycerides).

The fatty acid triglycerides can be advantageously selected from the group of synthetic, semi synthetic and natural oils such as olive oil, sunflower oil, soybean oil, peanut oil, rapeseed oil, almond oil, palm oil, coconut oil, castor oil, wheat germ oil, grapeseed oil, safflower oil, evening primrose oil, and the like.

The oil phase can in the context of the present invention also advantageous substances from the group of saturated esters and / or unsaturated, branched and / or unbranched alkanecarboxylic acids of a chain length of 3 to 30 carbon atoms and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of 3 to 30 carbon atoms and from the group of esters of aromatic carboxylic acids and saturated and / or unsaturated, branched and / or unbranched alcohols of a chain length of Contain 3 to 30 carbon atoms. Such ester oils can then be chosen advantageously from the group isopropyl palmitate, isopropyl stearate, n-butyl stearate, n-hexyl laurate, isooctyl stearate, isononyl stearate, isononyl isononanoate, 2-ethylhexyl palmitate, 2-hexyldecyl stearate, 2-octyldodecyl palmitate, erucylerucate, and the like synthetic, semi-synthetic and natural mixtures of such esters, such as. Jojoba oil.

It is also advantageous in the context of the present invention, when the preparations contain one or more volatile lipids, e.g. from the group phenyltrimethicone (INCI name: phenyl trimethicone, CAS 2116-84-9), Cyclomethicone (INCI name: Cyclomethicone, CAS 556-67-2 u. 69430-24-6) - in particular Octamethylcyclotetrasiloxane, Cyclomethicone D5 and / or Cyclomethicone D6 and C12-20 isoparaffin or isohexadecane.

Particularly according to the invention advantageous are silicone oils and silicone oil blends consisting of volatile silicone oils (such as cyclomethicones) and non-volatile silicone oils (dimethicones, Phenytrimethicone), especially if the preparation in the form of a W / S emulsion is present.

The Components of the oil phase can any mixtures of oil, Represent fat and / or wax components.

It is advantageous in the context of the present invention, when the preparations one or more glycerol esters, in particular glycerol esters of α-hydroxycarboxylic acids and saturated fatty acids containing the total amount of glycerol esters in the finished cosmetic preparations advantageously from the range of 0.1 to 10.0 wt .-%, preferably 0.5 to 6.0 wt .-% is selected, each based on the total weight of the preparations.

The cosmetic preparations according to the invention can contain cosmetic excipients, such as those commonly used in such preparations can be used, e.g. Preservatives, preservatives, Complexing agents, bactericides, perfumes, preventing substances or increasing the foaming, Thickeners, moisturizing and / or moisturizing substances, fillers, the skin feeling improve, or other usual Ingredients of a cosmetic formulation such as alcohols, polyols, Polymers, foam stabilizers, electrolytes, organic solvents or silicone derivatives.

Suitable preservatives for the purposes of the present invention are, for example, formaldehyde donors (such as DMDM hydantoin, which is obtainable for example under the trade name Glydant ^™ from the Fa. Lonza), Iodopropylbutylcarbamate (eg under the trade names Glycacil-L, Glycacil-S by the company. Lonza available and / or Dekaben LMB from Jan Dekker), parabens (ie p-Hydroxybenzoesäurealkylester, such as methyl, ethyl, propyl and / or Butylparaben), phenoxyethanol, ethanol, benzoic acid and the like. Usually, the preservation system according to the invention also advantageously also preservation aids, such as octoxyglycerol, glycine soy etc.

Even though the said preservatives per se in the preparations according to the invention can be used advantageously Very particular preference is given to those preparations which are free of parabens and / or free of formaldehyde releasing agents.

advantageous Complexing agents in the sense of the present invention are, for example EDTA, [S, S] -ethylenediamine disuccinate (EDDS), which is for example available under the trade name Octaquest from the company Octel, Pentasodium ethylenediamine, which e.g. under the trade name Dequest 2046 from the company Monsanto available is and / or iminodisuccinic acid, which u. a. from Bayer AG under the trade name Iminodisuccinat VP OC 370 (about 30% solution) and Baypure CX 100 available is.

Particularly advantageous preparations are also obtained when antioxidants are used as additives or active ingredients. According to the invention, the preparations advantageously contain one or more Antioxidants. As favorable, but nevertheless optional to be used antioxidants all suitable or common for cosmetic applications antioxidants can be used.

Especially For the purposes of the present invention, water-soluble antioxidants may be advantageous can be used, such as vitamins, e.g. Ascorbic acid (vitamin C) and their derivatives. These preferred components are mentioned are also chosen according to the invention as skin-care agents and are Therefore, it is preferable to use the skin care preparation.

preferred Antioxidants are also vitamin E and its derivatives as well as vitamin A and its derivatives.

The Amount of antioxidants (one or more compounds) in the Preparations is preferably from 0.001 to 30% by weight, particularly preferably from 0.05 to 20 Wt .-%, in particular 0.1 to 10 wt .-%, based on the total weight the preparation.

Provided Vitamin E or Vitamin C and / or its derivatives, the antioxidant (s) represent is advantageous, their respective concentrations the range of 0.001 to 10 wt .-%, based on the total weight the wording, to choose.

Provided Vitamin A or vitamin A derivatives, or carotenes or their derivatives the one or more antioxidants are advantageous, their respective Concentrations from the range of 0.001 to 10 wt .-%, based on the total weight of the formulation to choose.

It is particularly advantageous when the cosmetic preparation A according to the present Invention contain cosmetic skin care agents, wherein preferred active ingredients are antioxidants which make the skin more oxidative Protect stress can.

Further advantageous skin-care agents in the context of the present invention Invention are natural agents and / or derivatives thereof, e.g. Ginkgo biloba or ginkgo extracts, hyaluronic acid, Collagen, trehalose, alpha-lipoic acid, phytoene, D-biotin, coenzyme Q10, alpha-glucosylrutin, carnitine, carnosine, natural and / or synthetic isoflavonoids, creatine, taurine and / or β-alanine as well 8-hexadecene-1,16-dicarboxylic acid (Dioic acid, CAS number 20701-68-2, provisional INCI name Octadecendioic acid).

Preparations according to the invention, which e.g. known Faltenfüllwirkstoffe like hyaluronic acid and / or Derivatives and the like, are particularly advantageous for the cosmetic treatment of skin lesions, e.g. at aging (such as dryness wrinkles, Slackness and formation of wrinkles and wrinkles). Further advantageous Collagen or active ingredients that enhance collagen synthesis are like ginkgo biloba or ginkgo extracts, vitamin c, creatine, to the Firm and tone the skin.

Advantageous Furthermore, the use of preparations according to the invention which ascorbic acid and / or Derivatives and / or UV filter substances contain, for the cosmetic Treatment of skin aging phenomena (formation of dryness wrinkles, Slackness and formation of wrinkles and wrinkles).

The Water phase of formulations A or B according to the present invention can be beneficial usual contain cosmetic excipients, such as alcohols, in particular such low C number, preferably ethanol and / or Isopropanol, polymers, foam stabilizers, electrolytes and in particular a or more thickening agents, which or which are advantageous chosen can be from the group silicon dioxide, aluminum silicates, magnesium aluminum Silicates, polysaccharides or their derivatives, e.g. Hyaluronic acid, xanthan gum, Hydroxypropylmethylcellulose, particularly advantageous from the group the polyacrylates, preferably a polyacrylate from the group of so-called Carbopols [from Noveon], for example Carbopols of the types 980, 981, 1382, 2984, 5984, ETD 2020, ETD 2050, Pemulen TR-1 or -2, Ultrez 10, each individually or in combination. Especially advantageous, especially for the case of hydrodispersions / hydrogels (emulsifier-free preparation) hydrocolloids are used, such as ammonium polyacryloyldimethyl Taurate (commercially available e.g. as Aristoflex AMPS and / or AVC from Clariant) and polyacrylamides commercially available e.g. in combination with C13-14 isoparaffin and laureth-7 as sepigel from SEPPIC.

Also so-called moisturizers are advantageous to use. Moisturizers are substances or mixtures of substances which give cosmetic preparations the property after application or distribution on the skin surface to reduce the moisture release of the horny layer (also called transepidermal water loss (TEWL)) and / or to influence the hydration of the horny layer positively.

advantageous Moisturizers for the purposes of the present invention are, for example Glycerol, lactic acid and / or Lactates, in particular sodium lactate, butylene glycol, propylene glycol, Biosaccaride gum-1, glycine soy, ethylhexyloxyglycerol, pyrrolidonecarboxylic acid and Urea.

The cosmetic preparations according to the invention may furthermore advantageously contain fillers which, for example, further improve the sensory and cosmetic properties of the formulations and, for example, cause or intensify a velvety or silky feel on the skin. Advantageous fillers for the purposes of the present invention are starch and starch derivatives (such as, for example, tapioca starch, distarch phosphate, aluminum or sodium starch, octenylsuccinate and the like), pigments which have neither predominantly UV filter nor coloring action (such as boron nitride, etc.). and / or Aerosils ^® (CAS no. 7631-86-9) and Lauroyl Lysine, Polymethylsilesquioxane, polymethyl methacrylates, polymethyl methacrylates crosspolymer, nylon, talc, mica, siloxanes elastomers such as Dimethicone Crosspolymer.

Particularly according to the invention preferred are lauroyl lysines, polymethyl silsesquioxanes, silica, nylon and / or Siloxane elastomers such as Dimethicone Crosspolymer to choose as a soorhoric additive.

Fine pucker one sees, because the light reflection on the skin surface of which differs in the wrinkles. It is therefore advantageous in the context of the present invention, to use light-scattering pigments, visually reduce the depth of fold by increasing the proportion of reduce diffuse reflected light in the fold, causing the Skin smoother and more natural looks. In this way can be also excessive shine optically reduce the skin. To be used advantageously for this purpose is specially coated silica - e.g. very particularly advantageous Silica LDP (Silica + Titanium Dioxide + Iron Oxides), which is available under the trade name Ronasphere LDP from Merck is available.

is It is therefore preferable to add Silica LDP to the decorative preparation.

It is preferred according to the invention, the content of UV filter substances (one or more compounds) less than 5 wt .-%, in particular less than 2 wt .-% to choose, respectively based on the total weight of the preparation. Especially advantageous are preparations for the purposes of the present invention, which are free of UV filter substances.

In the case, that a content of UV filter substances is desired, they are advantageous selected from one or more of the following groups: UV-A, UV-B and / or broadband filter substances as well as organic and / or inorganic pigments as UV filter substances.

inorganic Pigments such as titanium dioxide particularly preferred titanium dioxide AQ-IP of Fa. Unichema.

• • Dibenzoylmethanderivate, insbesondere das 4-(tert.-Butyl)-4'-methoxydibenzoylmethan (CAS-Nr. 70356-09-1), welches von Givaudan unter der Marke Parsol^® 1789 und von Merck unter der Handelsbezeichnung Eusolex^® 9020 verkauft wird.
• • Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure und ihre Salze, besonders die entsprechenden Natrium-, Kalium- oder Triethanolammonium-Salze, insbesondere das Phenylen-1,4-bis-(2-benzimidazyl)-3,3'-5,5'-tetrasulfonsäure-bis-natriumsalz mit der INCI-Bezeichnung Disodium Phenyl Dibenzimidazol Tetrasulfonat (CAS-Nr.: 180898-37-7), welches beispielsweise unter der Handelsbezeichnung Neo Heliopan AP bei Symrise erhältlich ist;
• • Salze der 2-Phenylbenzimidazol-5-sulfonsäure, wie ihr Natrium-, Kalium- oder ihr Triethanolammonium-Salz sowie die Sulfonsäure selbst mit der INCI Bezeichnung Phenylbenzimidazole Sulfonsäure (CAS.-Nr. 27503-81-7), welches beispielsweise unter der Handelsbezeichnung Eusolex 232 bei Merck oder unter Neo Heliopan Hydro bei Symrise erhältlich ist;
• • 1,4-di(2-oxo-10-Sulfo-3-bornylidenmethyl)-Benzol (auch: 3,3'-(1,4-Phenylendimethylene)-bis-(7,7-dimethyl-2-oxo-bicyclo-[2.2.1]hept-1-ylmethan Sulfonsäure) und dessen Salze (besonders die entprechenden 10-Sulfato-verbindungen, insbesondere das entsprechende Natrium-, Kalium- oder Triethanolammonium-Salz), das auch als Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) bezeichnet wird. Benzol-1,4-di(2-oxo-3-bornylidenmethyl-10-sulfonsäure) hat die INCI-Bezeichnung Terephtalidene Dicampher Sulfonsäure (CAS-Nr.: 90457-82-2) und ist beispielsweise unter dem Handelsnamen Mexoryl SX von der Fa. Chimex erhältlich;
• • Sulfonsäure-Derivate des 3-Benzylidencamphers, wie z.B. 4-(2-Oxo-3-bornylidenmethyl)benzolsulfonsäure, 2-Methyl-5-(2-oxo-3-bornylidenmethyl)sulfonsäure und deren Salze.
• • Benzoxazol-Derivate, wie z.B. das 2,4-bis-[5-1(dimethylpropyl)benzoxazol-2-yl-(4-phenyl)imino]-6-(2-ethylhexyl)-imino-1,3,5-triazin mit der CAS Nr. 288254-16-0, welches bei 3V Sigma unter der Handelsbezeichnung Uvasorb^® K2A erhältlich ist.
• • Hydroxybenzophenone, z.B. der 2-(4-Diethylamino-2-hydoxybenzoyl)-benzoesäurehexylester (auch: Aminobenzophenon), welcher unter der Handelsbezeichnung Uvinul A Plus bei der Fa. BASF erhältlich ist.
• • Triazinderivate, wie z.B. 2,4-Bis-{[4-(2-Ethyl-hexyloxy)-2-hydroxy]-phenyl}-6-(4-methoxyphenyl)-1,3,5-triazin (INCI: Bis-Ethylhexyloxylphenol Methoxyphenyl Triazin), welches unter der Handelsbezeichnung Tinosorb^® S bei der CIBA-Chemikalien GmbH erhältlich ist; Dioctylbutylamidotriazon (INCI: Diethylhexyl Butamido Triazone), welches unter der Handelsbezeichnung UVASORB HEB bei Sigma 3V erhältlich ist; 4,4',4'-(1,3,5-Triazin-2,4,6-triyltriimino)-tris-benzoësäure-tris(2-ethylhexylester), auch: 2,4,6-Tris-[anilino(p-carbo-2-ethyl-1-hexyloxy)]-1,3,5-triazin (INCI: Ethylhexyl Triazone), welches von der BASF Aktiengesellschaft unter der Warenbezeichnung UVINUL^® T 150 vertrieben wird; 2-[4,6-Bis(2,4-dimethylphenyl)-1,3,5-triazin-2-yl]-5-(octyloxy)phenol (CAS Nr.: 2725-22-6).
• • Benzotriazole, wie z.B. 2,2'-Methylen-bis-(6-(2H-benzotriazol-2-yl)-4-(1,1,3,3-tetramethylbutyl)-phenol) (INCI: Methylene Bis-Benztriazolyl Tetramethylbutylphenol), welches z.B. unter der Handelsbezeichnung Tinosorb^® M bei der CIBA-Chemikalien GmbH erhältlich ist.
• • 3-Benzylidencampher-Derivate, vorzugsweise 3-(4-Methylbenzyliden)campher, 3-Benzylidencampher;
• • 4-Aminobenzoesäure-Derivate, vorzugsweise 4-(Dimethylamino)-benzoesäure(2-ethylhexyl)ester, 4-(Dimethylamino)benzoesäureamylester;
• • Ester der Benzalmalonsäure, vorzugsweise 4-Methoxybenzalmalonsäuredi(2-ethylhexyl)ester;
• • Ester der Zimtsäure, vorzugsweise 4-Methoxyzimtsäure(2-ethylhexyl)ester, 4-Methoxyzimtsäureisopentylester;
• • Derivate des Benzophenons, vorzugsweise 2-Hydroxy-4-methoxybenzophenon, 2-Hydroxy-4-methoxy-4-methylbenzophenon, 2,2-Dihydroxy-4-methoxybenzophenon sowie
• • an Polymere gebundene UV-Filter
• • Ethylhexyl-2-cyano-3,3-diphenylacrylat (Octocrylen), welches von BASF unter der Bezeichnung Uvinul^® N 539 T erhältlich ist.
• • Ethylhexylmethoxycinnamate (Uvinol MC 80 von der Firma BASF)

Particularly advantageous UV filter substances in the sense of the present invention are:

• Which is sold by Givaudan under the trade name Parsol ^® 1789 and from Merck under the trade name Eusolex ^® 9020 • dibenzoylmethane derivatives, in particular 4- (tert-butyl) -4'-methoxydibenzoylmethane (CAS-Nr. 70356-09-1), ,
• Phenylene-1,4-bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid and its salts, especially the corresponding sodium, potassium or triethanolammonium salts, especially the phenylene-1,4 bis (2-benzimidazyl) -3,3'-5,5'-tetrasulfonic acid bis-sodium salt with the INCI name Disodium Phenyl Dibenzimidazole tetrasulfonate (CAS No .: 180898-37-7), which is available, for example, under the Trade name Neo Heliopan AP available at Symrise;
• Salts of 2-phenylbenzimidazole-5-sulfonic acid, such as its sodium, potassium or its triethanolammonium salt, and the sulfonic acid itself with the INCI name phenylbenzimidazole sulfonic acid (CAS No. 27503-81-7), which is available, for example, from Trade name Eusolex 232 available from Merck or Neo Heliopan Hydro from Symrise;
• 1,4-di (2-oxo-10-sulfo-3-bornylidenemethyl) benzene (also: 3,3 '- (1,4-phenylenedimethylene) -bis (7,7-dimethyl-2-oxo) bicyclo [2.2.1] hept-1-ylmethane sulfonic acid) and its salts (especially the corresponding 10-sulfato compounds, in particular the corresponding sodium, potassium or triethanolammonium salt), which is also known as benzene-1,4- Benzo-1,4-di (2-oxo-3-bomylidenemethyl-10-sulfonic acid) has the INCI name Terephtalidene Dicampher sulfonic acid (CAS no. : 90457-82-2) and is available, for example, under the trade name Mexoryl SX from Chimex;
• Sulfonic acid derivatives of 3-Benzylidencamphers, such as 4- (2-oxo-3-bomylidenemethyl) benzenesulfonic acid, 2-methyl-5- (2-oxo-3-bomylidenemethyl) sulfonic acid and salts thereof.
• Benzoxazole derivatives such as 2,4-bis [5-1 (dimethylpropyl) benzoxazol-2-yl- (4-phenyl) imino] -6- (2-ethylhexyl) -imino-1,3,5 triazine with the CAS no. 288254-16-0, which is available under the trade name Uvasorb K2A ^® from 3V Sigma.
• Hydroxybenzophenones, for example, the 2- (4-diethylamino-2-hydroxybenzoyl) -benzoesäurehexylester (also: aminobenzophenone), which is available under the trade name Uvinul A Plus from BASF.
• Triazine derivatives such as 2,4-bis - {[4- (2-ethyl-hexyloxy) -2-hydroxy] -phenyl} -6- (4-methoxyphenyl) -1,3,5-triazine (INCI: Bis , which is available under the trade name Tinosorb ^® S from CIBA-Chemikalien GmbH -Ethylhexyloxylphenol methoxyphenyl triazine); Dioctylbutylamidotriazone (INCI: Diethylhexyl Butamido Triazone), which is available under the trade name UVASORB HEB from Sigma 3V; 4,4 ', 4' - (1,3,5-triazine-2,4,6-triyltriimino) tris-benzoic acid tris (2-ethylhexyl ester), also: 2,4,6-tris [anilino ( p-carbo-2-ethyl-1-hexyloxy)] - 1,3,5-triazine (INCI: ethylhexyl Triazone), which is sold by BASF Aktiengesellschaft under the trade name UVINUL T 150 ^®; 2- [4,6-bis (2,4-dimethylphenyl) -1,3,5-triazin-2-yl] -5- (octyloxy) phenol (CAS No .: 2725-22-6).
• Benzotriazoles, such as, for example, 2,2'-methylenebis (6- (2H-benzotriazol-2-yl) -4- (1,1,3,3-tetramethylbutyl) -phenol) (INCI: Methylene bis-benztriazolyl Tetramethylbutylphenol), which, for example, under the trade name Tinosorb ^® M is available from CIBA-Chemikalien GmbH.
• 3-benzylidene camphor derivatives, preferably 3- (4-methylbenzylidene) camphor, 3-benzylidene camphor;
• 4-aminobenzoic acid derivatives, preferably 2-ethylhexyl 4- (dimethylamino) benzoate, 4- (dimethylamino) benzoic acid amyl ester;
• Esters of benzalmalonic acid, preferably di-2-ethylhexyl 4-methoxybenzalmalonate;
• Esters of cinnamic acid, preferably 4-methoxycinnamic acid (2-ethylhexyl) ester, 4-methoxycinnamic acid isopentyl ester;
• Derivatives of benzophenone, preferably 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-methoxy-4-methylbenzophenone, 2,2-dihydroxy-4-methoxybenzophenone and
• • polymer-bound UV filters
• • ethylhexyl-2-cyano-3,3-diphenylacrylate (octocrylene), which is available from BASF under the name Uvinul ^® N 539 T.
• Ethylhexyl methoxycinnamate (Uvinol MC 80 from BASF)

It is also advantageous in the context of the present invention, when at least one of the preparations one or more film formers or contains polymers, in particular, a comprehensible streamlining effect on the Skin, caused by its film-forming properties can be.

For this are suitable e.g.

Polyurethanes (for example, the Avalure ^® grades from Goodrich), dimethicone copolyol polyacrylates (Surface Silsoft ^® from Witco Organo Silicones Group), PVP / VA (VA = vinyl acetate) copolymer (Luviscol VA 64 Powder BASF), C _20-40 carboxylic acid with polyethylene (Performacid 350 from New Phase Technologies) and film formers from the group of polymers based on polyvinylpyrrolidone (PVP):

Especially Copolymers of polyvinylpyrrolidone are preferably used, for example, the PVP hexadecene copolymer and the PVP eicosene copolymer, which under the trade names Antaron V216 and Antaron V220 available from GAF Chemicals Cooperation, as well as the Tricontayl PVP and the like more.

Especially preferred are water-soluble Polymers such as vinylpyrrolidone / vinyl acetate (VP / VA) copolymers and Sodium polystyrene sulfonate.

Farther particularly preferred are oil-soluble polymers, the skin adhesion and thus the durability of the make-up (in preparation B) increase such as trimethylsiloxysilicates.

It is also advantageous for the purposes of the present invention, if at least one of the preparations - Particularly preferably the Foundation - contains one or more inorganic and / or organic pigments and / or one or more dyes.

in the Range of cosmetic products are used for coloring the product or for coloring of the "object" to be treated (skin, hair, lips) both soluble Colorants (in the context of the present description also as dyes designated) and insoluble Colorants (in the context of the present description also as pigments designated).

The Dyes can be both of synthetic and natural origin.

Prefers For the purposes of the present invention are pigment mixtures of white pigments (e.g., kaolin, titanium dioxide or zinc oxide) and inorganic pigments (e.g., iron oxide pigments, Chromium oxides), wherein the pigments may be coated ("coated") or uncoated.

at The color pigments are preferably the iron oxides for use

It come as well preferably white pigments For use, these are pigments whose optical effect predominantly based on non-selective light scattering (DIN 55944: 2003-11). Of the chemically often very similar fillers inorganic white pigments differ mainly by their generally higher Refractive index and, associated with it, their higher scattering power as well according to DIN 55943: 2001-10 their application.

Ideal white pigments show no absorption in the range of visible light, but high scattering power, which has high hiding power result. The scattering power is greater, the greater the difference between the refractive index of the white pigment and that of the surrounding medium. Table: Refractive indices and Color Index of various white pigments.

Prefers Titanium dioxides are used in the cosmetic preparation as white pigment.

Additionally advantageous can the cosmetic preparations contain effect pigments, in addition to color an additional Property, such as angular dependence the color (iridescent, flop), shine (not surface gloss) or texture.

The The most important group of effect pigments are the luster pigments to which, according to DIN 55944: 2003-11, the metallic effect pigments and the pearlescent pigments belong (see table below). Leave some special effect pigments do not associate with these two groups, e.g. platelet-shaped graphite, platelet-shaped iron oxide and micronized titanium dioxide. The latter does not produce a gloss effect, but an angle-dependent Light scattering effect.

at the luster pigments according to DIN 55943: 2001-10 are predominantly platelet-shaped effect pigments. Parallel oriented luster pigments show a characteristic Shine. The optical effect of luster pigments is based on the directional Reflection on metallic particles (metallic effect pigments), on transparent ones Particles with high refractive index (pearlescent pigments) or on the phenomenon of Interference (interference pigments) (DIN 55944: 2003-11).

Examples of preferred commercially available effect pigments are: Timiron® ^® from Merck, Iriodin ^® from Merck (pearlescent and color luster pigments for decorative technical applications), Xirallic ^® from Merck (Color intensive crystal effect pigments)

Farther can optionally organic dyes are used. These are in the Application medium practically insoluble organic colorants. According to DIN 55944: 1990-04, organic pigments can be obtained by chemical Aspects in azo pigments and polycyclic pigments and after coloristic aspects are divided into colored or black pigments become.

polycyclic Pigements include according to DIN 55944 p. P. all organic non-azo pigments, the characterized by aromatic and / or heteroaromatic ring systems are.

Separate or more of the aforementioned preferred ingredients are each according to purpose, i. for skin care or for decorative purposes, then according to the combination of the invention contained in at least one of the preparations, preferably only in one of the separately stored preparations available.

The The following examples are intended to illustrate the present invention, without restricting it. The Numerical values in the examples mean percentages by weight on the total weight of the respective preparations, if nothing is different.

Of the crucial difference between the at least two preparations is that it is the skin care formulation A no decorative product, i. in contrast to Preparation B, the Makeup, contains there are no dyes, which also beneficial to the coloring of two preparations can be seen. The skin care preparation A is whitish white or transparent and the decorative preparation B is not advantageous white but brownish, dyed beige, the coloring can take place in different nuances and characteristics.

Examples 1. Preparation for skin care (Formulation A) O / W emulsions / hydrodispersions or hydrogels

• ¹ Arlatone V-175 from Uniqema (phenoxyethanol + methylparaben + ethylparaben + butylparaben + isobutylparaben + propylparaben + sucrose palmitate + glyceryl stearate + sucrose + xanthan gum + mannan + glyceryl stearate citrate)
• ^{2 eg} Ronasphere LDP from Merck (Silica + Titanium Dioxide + Iron Oxides)
• ^{3 eg} Timiron von Merck (Mica & CI 77891)

2. Foundation (Preparation B) O / W emulsions

¹ Arlatone V-175 from Uniqema (phenoxyethanol + methylparaben + ethylparaben + butylparaben + isobutylparaben + propylparaben + sucrose palmitate + glyceryl stearate + sucrose + xanthan gum + mannan + glyceryl stearate citrate)

^{2 eg} Ronasphere LDP from Merck (Silica + Titanium Dioxide + Iron Oxides)

^{3 eg} Timiron von Merck (Mica & CI 77891)

3. Foundation (Preparation B) W / O emulsions

• ^{2 eg} Ronasphere LDP from Merck (Silica + Titanium Dioxide + Iron Oxides)
• ^{3 eg} Timiron von Merck (Mica & CI 77891)

The listed under 1. skin care preparations can be perfectly with the under 2. or 3. listed provide decorative preparations in a dispenser according to the invention.

Claims (11)

Cosmetic combination kit comprising a.) A multi-chamber applicator for simultaneous and separate application of at least two separate preparations contained in the applicator, comprising a closure device that hermetically separates the preparations from each other and / or the environment and the separate dispensing openings for each chamber, b.) At least one of the preparations is a skin care preparation and c.) at least one other preparation is a decorative preparation and d.) the skin care and the decorative preparations differ from each other in at least one ingredient and e.) the skin care and the decorative preparations are chosen such that they themselves during distribution, especially on the skin, mix homogeneously, characterized in that the skin-care preparation in each case one or more constituents selected from the group of skin-care agents, polymers with film-forming properties, emulsifiers, Sensorikadd Itive and / or UV filters and the decorative preparation each comprise one or more constituents selected from the group of dyes, pigments, emulsifiers, fillers, sensor additives and / or film formers. Cosmetic combination kit according to claim 1, characterized in that the skin-care preparation contains a W / S, O / W emulsion, a hydrodispersion and / or a hydrogel and the decorative preparation a W / S or O / W emulsion. Combination set according to one of the preceding claims, characterized characterized in that the applicator from a container with at least two separate preparation stores. Combination set according to one of the preceding claims, characterized characterized in that in the skin care preparation at least a, preferably at least one substance is contained, selected from the groups a.) the skin-care ingredients of ascorbic acid and / or their derivatives, hyaluronic acid and / or their salts, gingko biloba, collagen, trehalose and / or Agents that stimulate collagen synthesis, b.) Of the polymers having film-forming properties of VP / VA copolymers, sodium polystyrene sulfonates, Trimethylsiloxysilicates, acrylate / dimethicone copolyol and / or polyquaternium 51 c.) of the emulsifiers from sucrose esters, sucrose palmitates, Glyceryl stearates, glyceryl stearate citrate, polyglyceryl-3 disiloxane Dimethicone, polyglyceryl-4 isostearate and / or cetyl PEG / PPG-10/1 Dimethicon chosen be or d.) With emulsifier-free preparation such as hydrodispersions / hydrogels the hydrocolloids of ammonium polyacryloyldimethyl taurate and / or Polyacrylamides and / or e.) of the sensor additives from lauroyl lysine, Polymethylsilsquioxanes, polymethyl methacrylates. Crosspolymer, Nylon, Talc, mica, silica and / or siloxanes elastomers and / or starch derivatives chosen become. Combination set according to one of the preceding claims, characterized characterized in that in the decorative preparation at least one, preferably in each case a substance is contained, selected from the group a.) the dye or pigments of pigmentary dyes based on iron oxides and / or titanium dioxides, coated or uncoated, effect pigments, Pearlescent pigments and / or metallic effect pigments, b.) of the emulsifiers from Cetyl PEG / PPG-10/1 dimethicone in W / S emulsions or sucrose Ester, preferably sucrose palmitate in admixture with glyceryl stearate and glyceryl stearate citrates, in O / W emulsions, c.) the filler of silica and / or coated silica and / or d.) of the sensor additives Lauroyl lysines, polymethyl silsesquioxanes, polymethyl methacrylates, Nylon, talc, mica, silica and / or siloxane elastomers and / or starch derivatives chosen become. Combination set according to one of the preceding claims, characterized marked that the a.) skin-care agents to proportions from 0.01-10 % By weight, preferably from 0.01 to 2.5 % By weight, based on the total mass of the skin care preparation, are added, b.) Polymers with film-forming properties to 0.1-10 % By weight, in particular to 0.1-2.5 % By weight, based on the total mass of the skin care preparation, are added, c.) emulsifiers 0.01-10 wt.%, In particular to 0.01-5 % By weight, based on the total mass of the skin care preparation, are added. Combination set according to one of the preceding claims, characterized in that the a.) Dye or pigment content in a proportion of 2 wt.% And more, more preferably 10 wt.% And more, based on the total mass of the decorative preparation, are added and b.) emulsifiers to 0.01-10 wt %, in particular 0.01-6% by weight, more preferably 0.01-1.5% by weight, based on the total mass of the decorative preparation. Combination kit according to one of the preceding claims comprising comprising at least one of the two preparations as W / Si emulsion Cetyl PEG / PPG-10/1 dimethicone. Combination kit according to one of the preceding claims, comprising in at least one of the two preparations hyaluronic acid and / or salts thereof, TiO ₂ , nylon and / or cetyl PEG / PPG-10/1 dimethicone. Combination kit according to one of the preceding claims comprising no detergents and / or surfactants. oil-free Combination set according to one of the preceding claims.