DE19800704A1 - Production of hydrogen - Google Patents
Production of hydrogenInfo
- Publication number
- DE19800704A1 DE19800704A1 DE19800704A DE19800704A DE19800704A1 DE 19800704 A1 DE19800704 A1 DE 19800704A1 DE 19800704 A DE19800704 A DE 19800704A DE 19800704 A DE19800704 A DE 19800704A DE 19800704 A1 DE19800704 A1 DE 19800704A1
- Authority
- DE
- Germany
- Prior art keywords
- hydrogen
- oxygen
- briquettes
- gas
- separated
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
- C10J3/02—Fixed-bed gasification of lump fuel
- C10J3/06—Continuous processes
- C10J3/08—Continuous processes with ash-removal in liquid state
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/08—Purifying combustible gases containing carbon monoxide by washing with liquids; Reviving the used wash liquors
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/20—Purifying combustible gases containing carbon monoxide by treating with solids; Regenerating spent purifying masses
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K1/00—Purifying combustible gases containing carbon monoxide
- C10K1/32—Purifying combustible gases containing carbon monoxide with selectively adsorptive solids, e.g. active carbon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/001—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by thermal treatment
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10K—PURIFYING OR MODIFYING THE CHEMICAL COMPOSITION OF COMBUSTIBLE GASES CONTAINING CARBON MONOXIDE
- C10K3/00—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide
- C10K3/02—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment
- C10K3/04—Modifying the chemical composition of combustible gases containing carbon monoxide to produce an improved fuel, e.g. one of different calorific value, which may be free from carbon monoxide by catalytic treatment reducing the carbon monoxide content, e.g. water-gas shift [WGS]
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0903—Feed preparation
- C10J2300/0906—Physical processes, e.g. shredding, comminuting, chopping, sorting
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
- C10J2300/092—Wood, cellulose
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0946—Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
- C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
- Y02P20/145—Feedstock the feedstock being materials of biological origin
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Processing Of Solid Wastes (AREA)
Abstract
Description
Die Erfindung bezieht sich auf ein Verfahren aus Hausmüll, hausmüllähnlichen Abfällen, Biomasse, auch in Verbindung mit anderen organischen Materialien oder Abfällen durch biologisch-mechanische Abläufe, Vergasung mit Sauerstoff, CO-Konvertierung technisch reinen Wasserstoff zu erzeugen.The invention relates to a method of household waste, similar to household waste Waste, biomass, whether or not in combination with other organic materials or Waste through biological-mechanical processes, gasification with oxygen, CO conversion to produce technically pure hydrogen.
Weltweit, aber hauptsächlich in den Industrieländern, fallen jährlich große Mengen an Hausmüll etc. an, ohne das bisher dafür ein vernünftiges, verwertendes Versorgungskonzept bestünde. Die Hauptbeseitigungsarten sind bis heute die Verbrennung, sowie die Deponie. Beide mit all ihren weitreichenden, negativen Mängeln.Worldwide, but mainly in the industrialized countries, large quantities fall annually to household waste etc., without this being a sensible, recyclable one Supply concept would exist. The main types of disposal are still today Incineration, as well as the landfill. Both with all their far-reaching, negative Defects.
Zur Entsorgung von Hausmüll etc. sind schon sehr viele Verfahren entwickelt worden, hier nur einige: Die Kompostierung im Großen und Ganzen. Das Andoc-Torrax-Verfahren, Vergasung mit vorgewärmter Luft im Pyrolator bei 1.600°C, das SFW-Funke-Verfahren, Vergasung mit Luft unter Zugabe von Sauerstoff im Schachtofen bei 1.000°C, sowie das PUROX-Verfahren, Hochtemperaturvergasung im Vertikalkonverter mit teils vorzerkleinertem Müll, der bei langsamem Absinken im Gegenstrom eine Trockenzone und eine Pyrolysezone durchläuft, um anschließend in einer Oxydations- und Schmelzzone mit Sauerstoff bei 1.550°C oxydiert zu werden, Abzug der Schlacken unten und das Pyrolysegas oben und Reinigung desselben. Keine dieser Verfahren konnte sich bisher in Großanlagen durchsetzen.Many methods have already been developed for the disposal of household waste etc. just a few: Composting on the whole. The Andoc-Torrax process, gasification with preheated air in the pyrolator at 1,600 ° C, the SFW spark process, gasification with air with the addition of oxygen in the Shaft furnace at 1,000 ° C, as well as the PUROX process, high-temperature gasification in the vertical converter with partially pre-shredded garbage, which slowly descends passes through a drying zone and a pyrolysis zone in counterflow then in an oxidation and melting zone with oxygen at 1,550 ° C to be oxidized, removal of the slags below and the pyrolysis gas above and Cleaning the same. So far, none of these processes have been found in large plants push through.
Aufgabe der Erfindung ist ein Verfahren zur Umweltneutralen Abfall- sowie Biomassenverwertung, auch durch Zumischen anderer organischer Stoffe mit maximaler Energiegewinnung in Form von Wasserstoff zu schaffen. Gelöst wird diese Aufgabe dadurch: Einem Müllstrom, der durch Sackaufreißer, sowie durch Zerkleinern des Überkorns, größer als 200 mm, homogenisiert ist, kann in einem Mischsystem fäkaler Klärschlamm, Biomüll, Stroh etc. zugemischt werden. Das Gemisch wird in einen an sich bekannten, großen Schnellkomposter eingegeben, in dem durch ständiges Wenden und Zugabe von Luft im Komposter eine Temperatur von bis zu 75°C erreicht wird. Durch die hohe Temperatur ist eine Trocknung des Materials auf 15% Restfeuchte sowie eine Hygienisierung erreicht. Das ausgetragene Material wird einer Absiebung bei ca. 30-50 mm zugeführt und das Feingut durch eine Briketierpresse zu Briketts verarbeitet. Sie sind ein hochwertiger Brennstoff. Das hygienisierte Grobkorn wird in Schwer- und Leichtgut getrennt. Das Schwergut manuell in seine Fraktionen sortiert und einer Verwertung oder der Deponie zugeführt. Das Leichtgut bestehend aus Holz, Kunststoff, Gummi etc., das gut brennbar ist, wird zusammen mit den Briketts und anderen organischen Materialien, wie Stroh, Schwach- und Altholz, Altreifen, Restpapier, Altteppichen etc. vorzugsweise in einem modifizierten Abstichgenerator (P 44 36 226) mit Sauerstoff bei ca. 1.550°C und flüssigem Schlackenabzug, vergast, wobei die Schlacke ein hochwertiger Grundstoff für die Bauindustrie ist. Das durch die Vergasung gebildete Rohgas wird über eine Heißgasleitung einem Kraeckreaktor zugeführt. In einer vorgelagerten, kleinen Brennkammer wird das Rohgas durch Zugabe von Sauerstoff auf 1.200-1.300°C aufgeheizt. Der Kraeckreaktor ist im Unterteil mit Koks oder Holzkohle gefüllt, so daß ein glühendes Koksbett entsteht, durch das die im Rohgas enthaltenen Pyrolyseprodukte, Öle und Wässer gekraeckt werden. Oberhalb des Koksbetts im Kraeckreaktor das ständig ergänzt werden muß ist eine CO-Konvertierung mit Katalysator angeordnet, durch die das CO in CO2 und H2 umgesetzt wird. Das Gasgemisch wird nun über eine Membranstufe oder auch Molekularsieb geführt und der Wasserstoff abgetrennt. Das Restgas, das hauptsächlich aus CO2 besteht, durchläuft eine Trockenreinigung und wird anschließend in die Hochtemperaturzone des Vergasers als Kühlmittel zurückgeführt. Als vorteilhaft hat sich erwiesen, immer drei Vergaser mit einem Kraeckreaktor zu verbinden. Der Wasserstoff wird in absehbarer Zeit für den Betrieb von Brennstoff zellen im Kommunalen Bereich (Nebus, Daimler Benz, Müllfahrzeuge und Busse oder auch Brennstoffzellen-Kraftwerke (BHKW)) dringend gebraucht, denn dies ist die neue Zeit oder auch Zukunft. Dieses Verfahren hat gegenüber der Müllverbrennung mindestens zwei entscheidende Verteile: Gasreinigung Müllverbrennung per Tonne ca. 5000 m/3 Abgas, Vergasung per Tonne ca. 600 m/3 Synthesegas. Müllverbrennung kann aus Kostengründen nur Müll verarbeiten, bei der Vergasung ist Müll nur ein Teilbereich in der Anwendung.The object of the invention is a method for environmentally neutral waste and Biomass utilization, also by adding other organic substances to create maximum energy in the form of hydrogen. This task is solved by: A waste stream, which is opened by sack rippers, and homogenized by crushing the oversize grain larger than 200 mm fecal sewage sludge, organic waste, straw etc. are added in a mixing system become. The mixture is placed in a large, fast composter known per se entered by constantly turning and adding air in the composter a temperature of up to 75 ° C is reached. Due to the high temperature is a Drying of the material to 15% residual moisture and hygienization achieved. The discharged material is fed to a screening at approx. 30-50 mm and that Fines processed into briquettes by a briquetting press. You are a high quality Fuel. The hygienized coarse grain is separated into heavy and light goods. The Heavy goods manually sorted into their fractions and a recycling or the Landfill fed. The light goods consisting of wood, plastic, rubber etc., the is highly flammable, together with the briquettes and other organic Materials such as straw, weak and old wood, old tires, residual paper, old carpets etc. preferably in a modified rack generator (P 44 36 226) Oxygen at approx. 1,550 ° C and liquid slag removal, gasified, the Slag is a high quality raw material for the construction industry. That through the Gasification formed raw gas is a hot gas line to a cracking reactor fed. The raw gas is passed through in an upstream, small combustion chamber Addition of oxygen heated to 1,200-1,300 ° C. The cracking reactor is in the Bottom part filled with coke or charcoal so that a glowing coke bed is created by which the pyrolysis products, oils and water contained in the raw gas are cracked become. Above the coke bed in the cracking reactor, which has to be constantly supplemented is a CO conversion with a catalyst arranged by which the CO into CO2 and H2 is implemented. The gas mixture is now over a membrane stage or also molecular sieve and the hydrogen separated. The residual gas that consists mainly of CO2, undergoes dry cleaning and is then returned to the high temperature zone of the carburetor as a coolant. It has proven to be advantageous to always have three gasifiers with one cracking reactor connect. The hydrogen will be used for fuel in the foreseeable future cells in the municipal area (Nebus, Daimler Benz, garbage trucks and buses or also fuel cell power plants (CHP) urgently needed, because this is the new time or the future. This procedure has over the Waste incineration has at least two key distributions: gas cleaning Waste incineration per ton approx. 5000 m / 3 exhaust gas, gasification per ton approx. 600 m / 3 Synthesis gas. For cost reasons, waste incineration can only process waste at which Gassing is just a part of the application.
Claims (1)
- - ein Müllstrom, der durch Sackaufreißer, sowie Zerkleinern des Überkorns größer als 200 mm homogenisiert ist, in einem Mischsystem fäkaler Klär schlamm, Biomüll etc., zugemischt werden, in einen Schnellkomposter ein gegeben und durch Zugabe von Luft, sowie gegebenenfalls durch Wenden eine Temperatur von bis zu 75°C erreicht wird;
- - das ausgetragene Material, das noch eine Restfeuchte von bis zu 15% haben kann, durch Absiebung in Fein- und Grobgut getrennt, das Feingut zu Briketts verpreßt wird, während das hygienisierte Grobgut in eine Schwer- und eine Leicht fraktion aufgetrennt wird;
- - die Schwerfraktion durch manuelle Trennung in ihre Bestandteile zerlegt und diese einer Verwertung oder der Deponie zugeführt werden;
- - die Leichtfraktion mit den Briketts und anderen organischen Stoffen einer Vergasungsanlage, einem Abstichgenerator, vorzugsweise einem modifizierten Abstichgenerator zugeführt und mit Sauerstoff bei ca. 1.550°C, zu Rohgas mit den Hauptkomponenten CO/H2, bei flüssigem Schlackenabzug vergast wird;
- - das Rohgas durch Zugabe von Sauerstoff mit einer Temperatur von 1.200-1.300°C durch ein Glutbett in einem separaten Kraeckreaktor gezogen, anschließend einer CO-Konvertierung unterworfen wird;
- - der Wasserstoff durch ein Membranverfahren oder Molekularsieb abgetrennt wird;
- - das Restgas, welches nun hauptsächlich aus CO2 besteht, einer Trockenreinigung unterworfen und als Kühlgas in dem Vergaser zurückgeführt wird.
- - A waste stream, which is homogenized by sack ripper and crushing oversize grain larger than 200 mm, mixed in a mixing system of faecal sewage sludge, organic waste etc., put into a quick composter and by adding air, and if necessary by turning a temperature is reached up to 75 ° C;
- - The discharged material, which can still have a residual moisture of up to 15%, is separated by sieving into fine and coarse material, the fine material is pressed into briquettes, while the hygienized coarse material is separated into a heavy and a light fraction;
- - the heavy fraction is broken down into its components by manual separation and these are sent for recycling or landfill;
- - The light fraction with the briquettes and other organic substances is fed to a gasification plant, a tapping generator, preferably a modified tapping generator and gasified with oxygen at approx. 1,550 ° C, to raw gas with the main components CO / H2, with liquid slag removal;
- - The raw gas is drawn through the addition of oxygen at a temperature of 1,200-1,300 ° C through an ember bed in a separate cracking reactor, then subjected to a CO conversion;
- - The hydrogen is separated off by a membrane process or molecular sieve;
- - The residual gas, which now mainly consists of CO2, is subjected to dry cleaning and is returned as cooling gas in the gasifier.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19800704A DE19800704A1 (en) | 1997-08-27 | 1998-01-10 | Production of hydrogen |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19737278 | 1997-08-27 | ||
DE19800704A DE19800704A1 (en) | 1997-08-27 | 1998-01-10 | Production of hydrogen |
Publications (1)
Publication Number | Publication Date |
---|---|
DE19800704A1 true DE19800704A1 (en) | 1999-04-01 |
Family
ID=7840300
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19800704A Withdrawn DE19800704A1 (en) | 1997-08-27 | 1998-01-10 | Production of hydrogen |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE19800704A1 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7666383B2 (en) | 2005-04-06 | 2010-02-23 | Cabot Corporation | Method to produce hydrogen or synthesis gas and carbon black |
DE102009018350A1 (en) * | 2009-04-23 | 2010-10-28 | Aimes Gmbh | Conversion apparatus for converting biomass into hydrocarbon compounds, methods for at least partially converting biomass to hydrocarbon compounds, useful gas and solid, and methods for at least partially converting contaminated matter to CO2 |
-
1998
- 1998-01-10 DE DE19800704A patent/DE19800704A1/en not_active Withdrawn
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7666383B2 (en) | 2005-04-06 | 2010-02-23 | Cabot Corporation | Method to produce hydrogen or synthesis gas and carbon black |
DE102009018350A1 (en) * | 2009-04-23 | 2010-10-28 | Aimes Gmbh | Conversion apparatus for converting biomass into hydrocarbon compounds, methods for at least partially converting biomass to hydrocarbon compounds, useful gas and solid, and methods for at least partially converting contaminated matter to CO2 |
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Legal Events
Date | Code | Title | Description |
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OP8 | Request for examination as to paragraph 44 patent law | ||
8125 | Change of the main classification |
Ipc: C10J 3/08 |
|
8127 | New person/name/address of the applicant |
Owner name: GREUL, ARTUR, 60431 FRANKFURT, DE |
|
8139 | Disposal/non-payment of the annual fee |