DE19601793A1 - Lubricant coating for internal surface of cylinders in stroke piston machines - Google Patents
Lubricant coating for internal surface of cylinders in stroke piston machinesInfo
- Publication number
- DE19601793A1 DE19601793A1 DE19601793A DE19601793A DE19601793A1 DE 19601793 A1 DE19601793 A1 DE 19601793A1 DE 19601793 A DE19601793 A DE 19601793A DE 19601793 A DE19601793 A DE 19601793A DE 19601793 A1 DE19601793 A1 DE 19601793A1
- Authority
- DE
- Germany
- Prior art keywords
- coating
- composite material
- spraying
- added
- light metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000576 coating method Methods 0.000 title claims description 16
- 239000011248 coating agent Substances 0.000 title claims description 15
- 239000000314 lubricant Substances 0.000 title claims description 5
- 150000001875 compounds Chemical class 0.000 claims abstract description 8
- 229910001092 metal group alloy Inorganic materials 0.000 claims abstract description 8
- 239000000843 powder Substances 0.000 claims abstract description 8
- 229910052742 iron Inorganic materials 0.000 claims abstract description 6
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 5
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 5
- 238000007751 thermal spraying Methods 0.000 claims abstract description 5
- 238000000034 method Methods 0.000 claims description 19
- 239000002131 composite material Substances 0.000 claims description 12
- 229910000838 Al alloy Inorganic materials 0.000 claims description 7
- 239000002245 particle Substances 0.000 claims description 7
- 239000011159 matrix material Substances 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 5
- 238000007750 plasma spraying Methods 0.000 claims description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- 229910052582 BN Inorganic materials 0.000 claims description 4
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229910018191 Al—Fe—Si Inorganic materials 0.000 claims description 3
- 230000015572 biosynthetic process Effects 0.000 claims description 3
- 239000007789 gas Substances 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 229910052739 hydrogen Inorganic materials 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000001681 protective effect Effects 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 238000005507 spraying Methods 0.000 claims description 2
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims 2
- 229910018084 Al-Fe Inorganic materials 0.000 claims 1
- 229910018192 Al—Fe Inorganic materials 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 229910052786 argon Inorganic materials 0.000 claims 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 229910000861 Mg alloy Inorganic materials 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- 238000010285 flame spraying Methods 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 238000007712 rapid solidification Methods 0.000 description 2
- 230000002787 reinforcement Effects 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- QYEXBYZXHDUPRC-UHFFFAOYSA-N B#[Ti]#B Chemical compound B#[Ti]#B QYEXBYZXHDUPRC-UHFFFAOYSA-N 0.000 description 1
- 229910052580 B4C Inorganic materials 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 229910001069 Ti alloy Inorganic materials 0.000 description 1
- 229910033181 TiB2 Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- CSDREXVUYHZDNP-UHFFFAOYSA-N alumanylidynesilicon Chemical compound [Al].[Si] CSDREXVUYHZDNP-UHFFFAOYSA-N 0.000 description 1
- INAHAJYZKVIDIZ-UHFFFAOYSA-N boron carbide Chemical compound B12B3B4C32B41 INAHAJYZKVIDIZ-UHFFFAOYSA-N 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000013016 damping Methods 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 238000005553 drilling Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013517 stratification Methods 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000012876 topography Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
Description
Die Erfindung betrifft ein Verfahren zum Beschichten von Oberflächen von Werkstücken aus Leichtmetallegierungen, insbesondere der Zylinderlaufflächen von Zylindergehäusen von Hubkolbenmaschinen, gemäß dem Oberbegriff des Patentanspruches 1.The invention relates to a method for coating surfaces of Workpieces made of light metal alloys, especially the cylinder surfaces of cylinder housings of reciprocating piston machines, according to the preamble of Claim 1.
Ein derartiges Verfahren beschreibt beispielsweise die DE 44 13 306 C1 anhand einer Bremsscheibe aus einer Leichtmetallegierung, bei der im Flammspritzverfahren als Metallegierungspulver Aluminium-, Magnesium- oder Titanlegierungen und als Verstärkungspartikel aus keramischem Material Siliziumkarbid, Aluminiumoxid, Borkarbid, Magnesiumoxid und/oder Titandiborid und ggf. als Gleitstoffpartikel Bornitrid oder Graphit zugesetzt werden. Die so gebildete Verstärkungsschicht soll mindestens 1 mm Dicke aufweisen. Als Leichtmetallegierungen kommen insbesondere Magnesium- oder Aluminiumlegierungen in Frage.Such a method is described, for example, in DE 44 13 306 C1 using a brake disc made of a light metal alloy, in which Flame spraying process as metal alloy powder aluminum, magnesium or Titanium alloys and as reinforcement particles made of ceramic material Silicon carbide, aluminum oxide, boron carbide, magnesium oxide and / or titanium diboride and optionally boron nitride or graphite can be added as lubricant particles. The so The reinforcement layer formed should be at least 1 mm thick. As Light metal alloys come in particular magnesium or Aluminum alloys in question.
Aufgabe der Erfindung ist es, ein Verfahren der gattungsgemäßen Art auf zuzeigen, mit dem tribolobisch besonders günstige und fertigungstechnisch gut beherrschbare Beschichtungen geschaffen werden.The object of the invention is to provide a method of the generic type show, with the tribolobically particularly cheap and technically good controllable coatings can be created.
Diese Aufgabe wird erfindungsgemäß mit den kennzeichnenden Merkmalen des Patentanspruches 1 gelöst. Vorteilhafte Weiterbildungen der Erfindung sind den weiteren Patentansprüchen entnehmbar.This object is achieved with the characterizing features of claim 1 solved. Advantageous developments of the invention are the other claims.
Erfindungsgemäß wird vorgeschlagen, auf das Werkstück einen pulverförmigen Verbundwerkstoff mit Al-Fe-Si thermisch aufzuspritzen, wobei der Verbundwerkstoff bei einem Werkstück aus einer Aluminiumlegierung in eine Matrix aus einer Aluminiumlegierung eingebunden sein kann. Durch das thermische Aufspritzen, bevorzugt durch Plasmaspritzen, und die schnelle Erstarrung der Schmelze werden intermetallische AlFe-Verbindungen in im Matrixwerkstoff übereutektisch gelöste AlFeSi-Verbindungen (ohne Primärkristallausscheidungen) homogen eingebunden und bilden eine ho mogene Beschichtung, deren Wärmedehnungsverhalten und E-Modul dem Grundwerkstoff ähnlich ist (gute Thermoschockbeständigkeit), bei einer Härte von bis zu 600 HV. Die Beschichtung weist ferner eine hohe Zähigkeit, eine gute Zerspanbarkeit (Honbarkeit) und eine tribologisch vorteilhafte Topographie auf.According to the invention it is proposed to put a powder on the workpiece Thermally spray composite material with Al-Fe-Si, the Composite material for a workpiece made of an aluminum alloy in a Matrix made of an aluminum alloy can be integrated. By the thermal spraying, preferably by plasma spraying, and the rapid Solidification of the melt intermetallic AlFe compounds in Matrix material hypereutectically dissolved AlFeSi compounds (without Primary crystal deposits) homogeneously integrated and form a ho homogeneous coating, its thermal expansion behavior and modulus of elasticity Base material is similar (good thermal shock resistance), with a hardness up to 600 HV. The coating also has high toughness, a good machinability (honability) and a tribologically advantageous topography on.
Der pulverförmig aufgebrachte und beim thermischen Spritzen teilweise schmelzende Verbundwerkstoff wird bevorzugt gebildet durch AlSiFe-Ver bindungen, die in der angegebenen Zusammensetzung in übersättigter Form in einer Matrix aus einer Leichtmetallegierung, bevorzugt einer Aluminiumle gierung (Aluminium mit üblichen Zusätzen und/oder Verunreinigungen), ein geschlossen sind und beim Aufspritzen teilweise in Lösung gehen. Dabei ist das Verhältnis der AlFe-Verbindungen nach Partikelgröße und chemischer Zusammensetzung zur Bildung in der Beschichtung eingebetteter interme tallischer AlFe-Verbindungen entsprechend abgestimmt.The powder applied and partially during thermal spraying melting composite material is preferably formed by AlSiFe-Ver bonds in the specified composition in supersaturated form in a matrix made of a light metal alloy, preferably an aluminum alloy alloy (aluminum with usual additives and / or impurities) are closed and partially dissolve when sprayed on. It is the ratio of AlFe compounds by particle size and chemical Composition for forming interme embedded in the coating AlFe connections matched accordingly.
In Weiterbildung der Erfindung wird vorgeschlagen, der aufgebrachten Be schichtung Festschmierstoffe, insbesondere hexagonales Bornitrid, zuzugeben, um insbesondere bei Anwendung der Erfindung an Zylinderlaufflächen für Hubkolben-Brennkraftmaschinen eine weitere Steigerung der tribologischen Eigenschaften zu erzielen.In a development of the invention it is proposed that the applied Be add solid lubricants, especially hexagonal boron nitride, in particular when using the invention on cylinder running surfaces for Reciprocating internal combustion engines further increase the tribological To achieve properties.
Eine besonders bevorzugte chemische Zusammensetzung der Beschichtung enthält 3 bis 20% Eisen, insbesondere 5 bis 8%, 13 bis 25% Silizium, ins besondere 14 bis 18% und 3 bis 40% hexagonales Bornitrid, insbesondere 12 bis 18%. Damit sind Zylinderlaufflächen erzielbar, die neben der erforderlichen Härte und Verschleißfestigkeit sowie sehr günstigen Gleiteigenschaften fertigungstechnisch gut bearbeitbar bzw. honbar sind. A particularly preferred chemical composition of the coating contains 3 to 20% iron, in particular 5 to 8%, 13 to 25% silicon, ins particularly 14 to 18% and 3 to 40% hexagonal boron nitride, in particular 12 up to 18%. This makes it possible to achieve cylinder running surfaces in addition to the required Hardness and wear resistance as well as very good sliding properties are technically easy to process or honable.
Bei bevorzugter Anwendung des Plasmaspritzens zum Aufbringen der Be schichtung wird ein Argon-Wasserstoff-Plasma verwendet, mit dem unter anderem unerwünschte Oxidbildungen in Grenzen gehalten werden.With preferred use of plasma spraying to apply the Be An argon-hydrogen plasma is used for the stratification other undesirable oxide formation can be kept within limits.
Die Beschichtung kann vorzugsweise eine Schichtdicke von 30 bis 500 µm, insbesondere 50 bis 200 µm und durch Variation des Eisengehaltes eine Vic kershärte von 250 bis 600 HV aufweisen. Eine derartige Beschichtung hat sich für Zylinderlaufflächen als besonders vorteilhaft und verschleißbeständig erwiesen.The coating can preferably have a layer thickness of 30 to 500 μm, in particular 50 to 200 microns and a Vic by varying the iron content have core hardness of 250 to 600 HV. Such a coating has for cylinder running surfaces as particularly advantageous and wear-resistant proven.
Ein Ausführungsbeispiel der Erfindung ist im folgenden mit weiteren Einzel heiten näher beschrieben.An embodiment of the invention is in the following with further details described in more detail.
Bei einem Zylinderkurbelgehäuse für eine Hubkolben-Brennkraftmaschine mit einer übereutektischen Aluminium-Silizium-Legierung mit 17% Silizium wurde nach dem Bohren der Zylinder auf ein definiertes Rohmaß durch Plasmaspritzen in einem Argon-Wasserstoff-Plasma und unter Schutzgas (Stickstoff) eine Laufflächenbeschichtung aufgebracht.With a cylinder crankcase for a reciprocating piston internal combustion engine a hypereutectic aluminum-silicon alloy with 17% silicon after drilling the cylinders to a defined size Plasma spraying in an argon-hydrogen plasma and under protective gas (Nitrogen) applied a tread coating.
Dabei wurde ein Verbundwerkstoff in Pulverform mit einer Partikelgröße von 60
µm und folgender chemischer Zusammensetzung verwendet:
Fe 10%
Si 15%
BN (hexagonal) 15%
Rest Aluminium und übliche Beimengungen.A composite material in powder form with a particle size of 60 µm and the following chemical composition was used:
Fe 10%
Si 15%
BN (hexagonal) 15%
Rest of aluminum and usual additions.
Dieser Verbundwerkstoff ist gebildet aus Al-Fe-Si-Verbindungen, die übersättigt in der Aluminiummatrix unter teilweiser Bildung von intermetallischen AlFe-Verbindungen eingeschlossen sind.This composite material is formed from Al-Fe-Si compounds that are oversaturated in the aluminum matrix with partial formation of intermetallic AlFe connections are included.
Beim Plasmaspritzen dieses Verbundwerkstoffes unter Schutzgas wird aufgrund der teilweisen Schmelzung und der schnellen Erstarrung auf dem Grundwerkstoff (Zylinderkurbelgehäuse) eine homogene Beschichtung ohne Ausscheidung von Si-Kristallen gebildet, wobei Si und Fe in übersättigter Lö sung mit dem Matrixwerkstoff vorliegen.When plasma spraying this composite material under protective gas is due to partial melting and rapid solidification on the Base material (cylinder crankcase) a homogeneous coating without Precipitation of Si crystals formed, with Si and Fe in supersaturated Lö solution with the matrix material.
Diese intermetallische AlFe-Verbindungen enthaltende Beschichtung kann je nach deren Fe-Gehalt eine Vickershärte von bis zu 600 HV aufweisen, bei einer gezielten Porösität, die sich unter anderem durch die gewählte Pulver- Partikelgröße bestimmt.This coating containing intermetallic AlFe compounds can each have a Vickers hardness of up to 600 HV according to their Fe content, with a targeted porosity, which is characterized, among other things, by the selected powder Particle size determined.
Nach dem Aufbringen der Beschichtung wurde die Zylinderlauffläche mit Diamanthonleisten zur Herstellung der geforderten geometrischen Genauigkeit und Oberflächenbeschaffenheit gehont.After the coating was applied, the cylinder tread became with Diamond honing stones for the production of the required geometrical accuracy and surface texture honed.
Die so gebildeten Laufflächen weisen eine hohe Härte sowie Zähigkeit auf, bei hervorragenden tribologischen Eigenschaften. Sie sind gut zerspanbar bzw. honbar, so daß eine geringe Mikrorauhigkeit bei einer gezielten Porösität vorliegt. Ferner weisen die Laufflächen gute Dämpfungseigenschaften auf. Aufgrund des volumenmäßig geringen Fe-Gehaltes ist ein Recycling des Zylindergehäuses problemlos möglich. Zudem ist der vorgeschlagene Verbundwerkstoff kostengünstiger, gut beherrschbar in seiner Spritzbarkeit (Prozeßsicher) und ermöglicht eine hohe Pulverausbeute.The treads thus formed have a high hardness and toughness excellent tribological properties. They are easy to machine or honable, so that a low micro-roughness with a targeted porosity is present. Furthermore, the treads have good damping properties. Due to the low Fe content, recycling of the Cylinder housing possible without any problems. In addition, the proposed one Composite material cheaper, easy to control in its sprayability (Process reliable) and enables a high powder yield.
Die Erfindung ist nicht auf das beschriebene Ausführungsbeispiel beschränkt. Als thermisches Spritzverfahren kann auch Flammspritzen, Laserspritzen, etc. eingesetzt sein. Anstelle von Zylinderlaufflächen können auch andere aus Leichtmetall hergestellte Bauteile, z. B. Tassenstößel der Ventilsteuerung, Ölpumpengehäuse, etc. beschichtet werden. Anstelle einer Aluminiumlegierung als Substrat kann auch eine Magnesiumlegierung verwendet sein.The invention is not limited to the exemplary embodiment described. Flame spraying, laser spraying, etc. can also be used as a thermal spraying method. be used. Instead of cylinder treads, others can also Components made of light metal, e.g. B. tappet of the valve control, Oil pump housing, etc. are coated. Instead of an aluminum alloy A magnesium alloy can also be used as the substrate.
Claims (12)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19601793A DE19601793B4 (en) | 1996-01-19 | 1996-01-19 | Process for coating surfaces |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19601793A DE19601793B4 (en) | 1996-01-19 | 1996-01-19 | Process for coating surfaces |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| DE19601793A1 true DE19601793A1 (en) | 1997-07-24 |
| DE19601793B4 DE19601793B4 (en) | 2004-11-18 |
Family
ID=7783151
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DE19601793A Expired - Lifetime DE19601793B4 (en) | 1996-01-19 | 1996-01-19 | Process for coating surfaces |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE19601793B4 (en) |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19822936A1 (en) * | 1998-05-22 | 1999-11-25 | Daimler Chrysler Ag | Applying a lubricating layer to the surface of a cylinder face |
| US6030577A (en) * | 1995-09-01 | 2000-02-29 | Erbsloh Aktiengesellschaft | Process for manufacturing thin pipes |
| EP0987339A1 (en) * | 1998-09-11 | 2000-03-22 | DaimlerChrysler AG | Metallizing wire for making surface coatings |
| DE19936393A1 (en) * | 1999-08-03 | 2001-02-08 | Volkswagen Ag | Method and device for applying or introducing a material onto or into a surface |
| FR2848575A1 (en) * | 2002-12-13 | 2004-06-18 | Snecma Moteurs | POWDER MATERIAL FOR ABRADABLE SEAL |
| DE19733205B4 (en) * | 1997-08-01 | 2005-06-09 | Daimlerchrysler Ag | Coating for a cylinder surface of a reciprocating engine of a hypereutectic aluminum / silicon alloy, spray powder for their production and their use |
| DE19733204B4 (en) * | 1997-08-01 | 2005-06-09 | Daimlerchrysler Ag | Coating of a hypereutectic aluminum / silicon alloy, spray powder for their production and their use |
| DE19705628B4 (en) * | 1997-02-14 | 2005-07-28 | Audi Ag | Method and device for thermal coating of bores |
| DE102006010190A1 (en) * | 2006-03-06 | 2007-09-13 | Federal-Mogul Burscheid Gmbh | Aluminum-steel cylinder liner for internal combustion engine is produced entirely by thermal injection using light arc and wire |
| WO2013174547A1 (en) * | 2012-05-02 | 2013-11-28 | Peak-Werkstoff Gmbh | Method for producing a light-weight metal component; light-weight metal component, and internal combustion engine comprising a cylinder liner consisting of a light-weight metal component |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991010755A2 (en) * | 1990-01-18 | 1991-07-25 | Allied-Signal Inc. | Plasma spraying of rapidly solidified aluminum base alloys |
| EP0487273A1 (en) * | 1990-11-19 | 1992-05-27 | Sulzer Plasma Technik, Inc. | Thermal spray powder |
| DE4341537A1 (en) * | 1992-12-07 | 1994-06-09 | Ford Werke Ag | Composite wire and process for its manufacture |
-
1996
- 1996-01-19 DE DE19601793A patent/DE19601793B4/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1991010755A2 (en) * | 1990-01-18 | 1991-07-25 | Allied-Signal Inc. | Plasma spraying of rapidly solidified aluminum base alloys |
| EP0487273A1 (en) * | 1990-11-19 | 1992-05-27 | Sulzer Plasma Technik, Inc. | Thermal spray powder |
| DE4341537A1 (en) * | 1992-12-07 | 1994-06-09 | Ford Werke Ag | Composite wire and process for its manufacture |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6030577A (en) * | 1995-09-01 | 2000-02-29 | Erbsloh Aktiengesellschaft | Process for manufacturing thin pipes |
| DE19705628B4 (en) * | 1997-02-14 | 2005-07-28 | Audi Ag | Method and device for thermal coating of bores |
| DE19733204B4 (en) * | 1997-08-01 | 2005-06-09 | Daimlerchrysler Ag | Coating of a hypereutectic aluminum / silicon alloy, spray powder for their production and their use |
| DE19733205B4 (en) * | 1997-08-01 | 2005-06-09 | Daimlerchrysler Ag | Coating for a cylinder surface of a reciprocating engine of a hypereutectic aluminum / silicon alloy, spray powder for their production and their use |
| DE19822936A1 (en) * | 1998-05-22 | 1999-11-25 | Daimler Chrysler Ag | Applying a lubricating layer to the surface of a cylinder face |
| DE19822936C2 (en) * | 1998-05-22 | 2001-11-22 | Daimler Chrysler Ag | Process for the adhesive application of a lubricant layer to an exposed and tribologically stressed surface of a cylinder running surface and cylinder running surface with a lubricant layer adhering to an exposed surface |
| EP0987339A1 (en) * | 1998-09-11 | 2000-03-22 | DaimlerChrysler AG | Metallizing wire for making surface coatings |
| US6329021B1 (en) | 1998-09-11 | 2001-12-11 | Daimlerchrysler Ag | Method for producing a surface coating on a substrate using a material wire |
| DE19936393A1 (en) * | 1999-08-03 | 2001-02-08 | Volkswagen Ag | Method and device for applying or introducing a material onto or into a surface |
| FR2848575A1 (en) * | 2002-12-13 | 2004-06-18 | Snecma Moteurs | POWDER MATERIAL FOR ABRADABLE SEAL |
| US7160352B2 (en) | 2002-12-13 | 2007-01-09 | Snecma Moteurs | Powder material for an abradable seal |
| DE102006010190A1 (en) * | 2006-03-06 | 2007-09-13 | Federal-Mogul Burscheid Gmbh | Aluminum-steel cylinder liner for internal combustion engine is produced entirely by thermal injection using light arc and wire |
| WO2013174547A1 (en) * | 2012-05-02 | 2013-11-28 | Peak-Werkstoff Gmbh | Method for producing a light-weight metal component; light-weight metal component, and internal combustion engine comprising a cylinder liner consisting of a light-weight metal component |
Also Published As
| Publication number | Publication date |
|---|---|
| DE19601793B4 (en) | 2004-11-18 |
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