DE1929211A1 - Device powered by a metal / air battery - Google Patents
Device powered by a metal / air batteryInfo
- Publication number
- DE1929211A1 DE1929211A1 DE19691929211 DE1929211A DE1929211A1 DE 1929211 A1 DE1929211 A1 DE 1929211A1 DE 19691929211 DE19691929211 DE 19691929211 DE 1929211 A DE1929211 A DE 1929211A DE 1929211 A1 DE1929211 A1 DE 1929211A1
- Authority
- DE
- Germany
- Prior art keywords
- open
- battery
- dea
- air
- metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910052751 metal Inorganic materials 0.000 title description 11
- 239000002184 metal Substances 0.000 title description 11
- 238000009423 ventilation Methods 0.000 claims description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910052725 zinc Inorganic materials 0.000 claims description 3
- 239000011701 zinc Substances 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 7
- 229910052760 oxygen Inorganic materials 0.000 description 7
- 239000001301 oxygen Substances 0.000 description 7
- 239000003792 electrolyte Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- -1 polytetrafluoroethylene Polymers 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 230000028161 membrane depolarization Effects 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 241000220010 Rhode Species 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000010411 electrocatalyst Substances 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229920001600 hydrophobic polymer Polymers 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000002655 kraft paper Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 229920002620 polyvinyl fluoride Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21L—LIGHTING DEVICES OR SYSTEMS THEREOF, BEING PORTABLE OR SPECIALLY ADAPTED FOR TRANSPORTATION
- F21L4/00—Electric lighting devices with self-contained electric batteries or cells
- F21L4/005—Electric lighting devices with self-contained electric batteries or cells the device being a pocket lamp
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V31/00—Gas-tight or water-tight arrangements
- F21V31/03—Gas-tight or water-tight arrangements with provision for venting
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F21—LIGHTING
- F21V—FUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
- F21V23/00—Arrangement of electric circuit elements in or on lighting devices
- F21V23/04—Arrangement of electric circuit elements in or on lighting devices the elements being switches
- F21V23/0414—Arrangement of electric circuit elements in or on lighting devices the elements being switches specially adapted to be used with portable lighting devices
Landscapes
- Engineering & Computer Science (AREA)
- General Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Hybrid Cells (AREA)
- Toys (AREA)
Description
REICHENBACHSTR. 51
TEL 163151REICHENBACHSTR. 51
TEL 163151
ΡΜ-292Λ0Θ
R/VΡΜ-292Λ0Θ
R / V
Die Erfindung betrifft Vorrichtungen» die von einer Metall/Luft-Batterie gespeist werden« wie Taaohenlampen, Spielzeuge, elektrieche Rasierapparate, elektrische Werkzeuge, tragbare elektronische oder VachrlohtenUbernlttlungsgerKte u.dgl. und insbesondere die Ausbildung des Schalters sum Unterbrechen des Stromkreises einer solchen Vorrichtung.The invention relates to devices "fed by a metal / air battery" such as Taaohen lamps, Toys, electric razors, electrical tools, portable electronic or corrugated heat exchangers, and the like, and in particular the formation of the switch sum breaking the circuit of such a device.
Metall/Luft-Batterien sind in neuerer Zelt so durch*· entwickelt worden» dad sie schon für eine Verwendung in einer Ansah! von Geritten, in denen derzeit die herkömmlichen Blei/Säure-, Silber/Quecksilber- oder Nlokel/Dadaium-Batterlen verwendet werden, geeignet sind. Insbesondere 1st bei diesen neuen Batterien das Verhlltnis von.Oewloht zu Volumen und Energie zu Volumen besser als bei den herkömmlichen Batterien, bei denen das gesamte Depolar isationenitΐel von Beginn an in der Zelle selbst enthalten ist. Bei den Met»11/Luft-Batterien ist dagegen das Depolarieationaolttel LuftMetal / air batteries are so through in the newer tent * · has been developed »because it has already been used in a view! of ridden in which currently the conventional lead / acid, silver / mercury or Nlokel / Dadaium batteries are used. In particular, in these new batteries, the ratio of oewloht to volume and energy to volume better than the conventional batteries where the entire depolarization energy from the start in contained in the cell itself. With the Met »11 / air batteries on the other hand, the depolarization voltage is air
90 9 85 1 /129 790 9 85 1/129 7
bzw. Sauerstoff» mid diese Batterien ntlesen daher so ausgebildet sein« daß Luft oder Sauerstoff in sie eintreten kann. Wenn jedoch auoh in den Zelten» in denen das Gerät nicht arbeitet« d.h. keinen St roe verbraucht, Luft eintritt» so komt es su unerwünschten eheaisohen und physikalischen Veränderungen in den Zellen» beispielsweise su einer Verdampfung von Wasser aus des Elektrolyten, wenn dieser ein« wtferlge Lösung ist, einer Oxydation der netallisohen Anode durch in den Elektrolyten gelüsten Sauerstoff» und bxw. oder es bildet sieh» wenn der Elektrolyt eine Alkalllusung, beispielsweise eine Kaliunhydroxydlusung ist» duroh Absorption des Kohlendioxyde der Luft unlösliche» Carbonat.or oxygen "and these batteries must therefore be designed" in such a way that air or oxygen enter them can. If, however, also in the tents »in which that Device does not work «i.e. no power is consumed, Air enters »so it comes to undesirable eheaisohen and physical changes in the cells »for example evaporation of water from the Electrolytes, if this is a substantial solution, an oxidation of the metallic anode by oxygen in the electrolyte and bxw. or it forms see when the electrolyte is an alkali solution, for example a potassium hydroxide solution, duroh Absorption of carbon dioxide from the air - insoluble carbonate.
für Geräte, die duroh Metall/taft-Batterlen gespeist werden» derart, daS Luft oder Sauerstoff nur dann in die Batterie eintreten kann» wenn sie Stroa liefernfor devices that are powered by duroh metal / taft batteries are "such that air or oxygen can only enter the battery" when they supply stroa
Gegenstand der Erfindung ist ein von einer MetallAuft-Batterle betriebenes OcrKt alt einen Oehtuse für die Batterie» das alt Vent Hat ions« it t ein versehen ist» Mitteln sue 8ohlie0en und Offnen des elektrischen Stronkreises und Mitteln sun SohlleSen und Offnen der Yentilationaaittel. Dan Oerit ist dadurch gekennzeichnet» daS die Mittel sum SohlleSen und Offnen des Stroakreises und die Mittel sub Sohließen und Offnen der Ventilations-■Ittel so ausgebildet und so su den QehKuse angeordnet sind, daS duroh SohlieSen und öffnen des Stronkreises gleichseitig die Yentllatlonsaittel gesehlossen bsw. geöffnet werden.The subject of the invention is one of a MetallAuft-Batterle operated OcrKt old an ophthalmologist for the Battery "the old vent hat ions" it is provided " Means to disconnect and open the electrical circuit and means sun soles and opening the Yentilationaittel. Dan Oerit is characterized by » that the means sum up and open the circle of the Stroak and the means of pouring the bottom and opening the ventilation system so designed and so arranged under the QehKuse that through the bottom and open the circuit on the same side the Yentllatlonsaittel closed bsw. be opened.
909851/1297909851/1297
QADQAD
Vorzugsweise sind die Mittel zum Schließen und Offnen des Stromkreiseε einetUckig mit Mitteln zum Abdecken oder Offnen von einem oder mehreren der Ventilation dienenden Offnungen in dem die Batterie umgebenden OehKuse ausgebildet« oder beide sind mechanisch fest miteinander verbunden. Insbesondere ist der elektrische Schalter ein auch dem Offnen oder Abdecken der Ventilationsöffnungen dienendes bewegliches Teil mit einem daran befestigten leitenden Teil, das, wenn der Schalter geschlossen ist, die Batterie mit dem Energie verbrauchenden Teil des Gerätes, beispielsweise der Birne einer Taschenlampe, verbindet.The means for closing and opening the circuit are preferably in one piece with means for covering or opening one or more ventilation openings in the area surrounding the battery OehKuse trained «or both are mechanically strong connected with each other. In particular, the electrical switch is also used to open or cover the Movable part serving ventilation openings with an attached conductive part which, when the Switch is closed, the battery with the energy-consuming part of the device, for example the Bulb of a flashlight that connects.
Figur 1 eine Taschenlampe gemKS der Erfindung, Figur 2 einen Querschnitt durch diese TaschenlampeFigure 1 shows a flashlight according to the invention, Figure 2 shows a cross section through this flashlight
IKnga der Linie 2-2 von Figur 1 und Figur 3 einen Querschnitt durch ein Spielzeug gemäß der Erfindung.IKnga of the line 2-2 of Figure 1 and Figure 3 shows a cross section through a toy according to the invention.
In der in den Figuren 1 und 2 gezeigten Taschenlampe besteht der Schalter aus einem Sohleber 13 aus einem leitenden Material, beispielsweise einem Metall, mit einem Griffteil 11 und Löchern 14 und 16. Wenn dieser Schalter so verschoben wird, daß die Batterien 27 und 29 mit dem stromverbrauohenden Tell des Oerites, in diesem Fall der Glühbirne, verbunden werden, wie durch die Darstellung des Schalters in gestrichelten Linien in Figur 2 gezeigt, so werden Löcher 14 und 16 in diesem Sohalter Über Löcher 17 und 19 in der Wand 24 des TaeohenlanpengehltuseB geschoben. Wenn dagegen duroh Versohleben des Schelters der Xontakt mit demIn the flashlight shown in Figures 1 and 2 the switch consists of a sole 13 of a conductive material, for example a metal, with a handle part 11 and holes 14 and 16. If this Switch is moved so that the batteries 27 and 29 with the power-consuming part of the Oerites, in this case the lightbulb, as shown by the illustration of the switch in dashed lines Lines shown in Figure 2 so holes 14 and 16 in this Sohalter over holes 17 and 19 in the Wall 24 of the TaeohenlanpengehltuseB pushed. If against duroh versohleben of the Schelters the Xontakt with the
90 9 8,5 1 / 129 790 9 8.5 1/129 7
elektrisch leitenden Reflektor 25 gelöst wird, deckt der Schieber die Löcher 17 und 19 in dem Taechenlampengehäuse wieder ab, so daß keine Luft mehr* an die Batterien gelangen kann. Ein enger Schlitz 21 in dem Gehäuse 24, durch den Griffteil 11 und Sohleber 13 miteinander verbunden sind, dient der Führung des Schieberselectrically conductive reflector 25 is released, covers the slide holes 17 and 19 in the lamp housing again so that no more air * can get to the batteries. A narrow slot 21 in that Housing 24, through the handle part 11 and sole ber 13 with each other are connected, is used to guide the slide
Figur 3 veranschaulicht ein Spielzeugfahrzeug mit einem Motor 33» der von einer Zink/Luft«Batterie 31 gespeist wird. Dieses Fahrzeug hat eine einzige Öffnung 37 in einer Wand 35 des Motor und Batterie umgebenden Gehäuses. Der Schalter 39 ist wiederum als Sohieber ausgebildet, der die Öffnung 37 abdeokt, wenn der Stromkreis geöffnet ist, wie in der Zeichnung dargestellt. Wenn der Schieber 39 den Stromkreis sahlieät, gleitet ein Loch in diesem Schieber Über das Loch 37 in dem Gehäuse. Das Schließen des Stromkreises erfolgt dadurch, dafl das Teil 30 dee Schiebers 39 auf das an der Gehäusewand befestigte Kontaktteil 32 geschoben wird.FIG. 3 illustrates a toy vehicle with a motor 33 “fed by a zinc / air” battery 31 will. This vehicle has a single opening 37 in a wall 35 surrounding the engine and battery Housing. The switch 39 is in turn designed as a Sohieber that abdeokt the opening 37 when the Circuit is open as shown in the drawing. When the slide 39 sahlieät the circuit, slides a hole in this slide via the hole 37 in the housing. The circuit is closed by that the part 30 of the slide 39 on the one on the housing wall attached contact part 32 is pushed.
Die Erfindung 1st grundsätzlich auf alle Geräte mit Metall/Luft-Batterien anwendbar, insbesondere aber auf solche Geräte, die eine Metall/Luft -Batterie, wie sie in der USA-Patentanmeldung Serial No. 533 516 von 11. März 1966 (Oawin) beschrieben sind* Die Kathode einer solchen Batterie enthält ein luftdurchlässiges Teil aus einen hydrophoben Polymer, wie einen fluorierten Kohlenwasserstoff, beispielsweise Polytetrafluorethylen, Polytrifluorchlorethylen, Polyvinylfluorid« Polytrifluorethylen, Polyvinylidenfluorid» einen hydrophoben Copolymer von 2 oder mehreren der obigen Materialien oder einem dieser Materialien mit Acrylnitril,The invention is basically applicable to all devices Metal / air batteries are applicable, but especially to devices that use a metal / air battery, such as see US patent application serial no. 533 516 of March 11, 1966 (Oawin) are * The cathode Such a battery contains an air-permeable member made of a hydrophobic polymer such as a fluorinated one Hydrocarbons, for example polytetrafluoroethylene, polytrifluorochloroethylene, polyvinyl fluoride, polytrifluoroethylene, Polyvinylidene fluoride »a hydrophobic copolymer of two or more of the above materials or one of these materials with acrylonitrile,
9 0 9 8 5 1/12 9 79 0 9 8 5 1/12 9 7
Methacrylate Polyäthylen und dergleichen» In Kontakt alt einen Elektrokatalysator, wie eine« Metall, einer Legierung oder einem Oxyd« das eine elektrochemische tJtasetsung su beschleunigen ve mag, beispielsweise setallleohe* Niokel, Silber, Gold, Platin oder Palladius oder Kohlenstoff. Die Anode kann au« eines festen Leiter bestehen« wis er üblicherweise als Anode in einer Metall/Luftoder Metall/Sauerstoff-Zelle verwendet wird« wobei nur der Forderung genügt werden nuß, da8 das Material alt de« Elektrolyten su reagieren versag und elekt(«positiver sie Sauerstoff ist. Beispiele für solche Materialien sind Blei» Zink, Bisen« Cadsius, Alusinlus und Magnesite, insbesondere wird in solohen rillen eine poröse Inkanode verwendet. Der Elektrolyt kann sine Pasts au« de« AnodensAterlal und eines lonenleltfKhlgen Medius sein, und Anode und Kathode sind tweoksliig duroh eins hydrophil· lonendurchltssige Meabrane aus beispielsweise Kraftpapier, voneinander getrennt. Die hydrophobe Msabren der Kathode ist der Luft oder des Sauerstoff sugewandt. Der Aufbau einer solchen Zeil« 1st nicht Oegenstand der vorliegenden Erfindung.Methacrylate, polyethylene and the like »In contact old an electrocatalyst, like a «metal, one Alloy or an oxide that may accelerate an electrochemical reaction, for example setallleohe * Niokel, silver, gold, platinum or Palladius or carbon. The anode can consist of a solid conductor, as is usually the case as an anode in a metal / air or Metal / oxygen cells are used, where only the requirement that the material be old has to be satisfied de «electrolytes su react failure and elect (« more positive she is oxygen. Examples of such materials are lead »zinc, bisen« cadsius, alusinlus and magnesite, In particular, a porous incanode is used in single grooves used. The electrolyte can consist of the anode area and an ionic cold medium be, and anode and cathode are mutually duroh one hydrophilic ion-permeable membranes from, for example Kraft paper, separated from each other. The hydrophobic Msabren of the cathode is air or oxygen sugewandt. The structure of such a line is not Subject of the present invention.
9 0 9 8 51/12979 0 9 8 51/1297
Claims (4)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US73587168A | 1968-06-10 | 1968-06-10 |
Publications (1)
Publication Number | Publication Date |
---|---|
DE1929211A1 true DE1929211A1 (en) | 1969-12-18 |
Family
ID=24957567
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE19691929211 Pending DE1929211A1 (en) | 1968-06-10 | 1969-06-10 | Device powered by a metal / air battery |
Country Status (6)
Country | Link |
---|---|
BR (1) | BR6909526D0 (en) |
CH (1) | CH493105A (en) |
DE (1) | DE1929211A1 (en) |
FR (1) | FR2011914A1 (en) |
GB (1) | GB1234712A (en) |
NL (1) | NL6908707A (en) |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4493880A (en) * | 1983-12-19 | 1985-01-15 | Gould Inc. | Battery switch |
US4620111A (en) * | 1984-06-25 | 1986-10-28 | Duracell Inc. | Auxiliary portable power supply |
-
1969
- 1969-06-06 BR BR20952669A patent/BR6909526D0/en unknown
- 1969-06-06 NL NL6908707A patent/NL6908707A/xx unknown
- 1969-06-09 FR FR6918955A patent/FR2011914A1/fr not_active Withdrawn
- 1969-06-09 CH CH874069A patent/CH493105A/en not_active IP Right Cessation
- 1969-06-10 GB GB2922269A patent/GB1234712A/en not_active Expired
- 1969-06-10 DE DE19691929211 patent/DE1929211A1/en active Pending
Also Published As
Publication number | Publication date |
---|---|
CH493105A (en) | 1970-06-30 |
GB1234712A (en) | 1971-06-09 |
NL6908707A (en) | 1969-12-12 |
FR2011914A1 (en) | 1970-03-13 |
BR6909526D0 (en) | 1973-02-20 |
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