DE156597C - - Google Patents
Info
- Publication number
- DE156597C DE156597C DENDAT156597D DE156597DA DE156597C DE 156597 C DE156597 C DE 156597C DE NDAT156597 D DENDAT156597 D DE NDAT156597D DE 156597D A DE156597D A DE 156597DA DE 156597 C DE156597 C DE 156597C
- Authority
- DE
- Germany
- Prior art keywords
- stones
- colors
- coloring
- production
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003086 colorant Substances 0.000 claims description 8
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 7
- 239000004568 cement Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 239000004927 clay Substances 0.000 claims description 4
- 229910052570 clay Inorganic materials 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 150000001805 chlorine compounds Chemical class 0.000 claims description 2
- 238000000034 method Methods 0.000 claims description 2
- 230000029087 digestion Effects 0.000 claims 1
- 238000002156 mixing Methods 0.000 claims 1
- 238000005406 washing Methods 0.000 claims 1
- 239000004575 stone Substances 0.000 description 10
- 238000004040 coloring Methods 0.000 description 6
- 239000002969 artificial stone Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 239000011449 brick Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- -1 alkalis Chemical compound 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000011451 fired brick Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000717 retained Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B20/00—Use of materials as fillers for mortars, concrete or artificial stone according to more than one of groups C04B14/00 - C04B18/00 and characterised by shape or grain distribution; Treatment of materials according to more than one of the groups C04B14/00 - C04B18/00 specially adapted to enhance their filling properties in mortars, concrete or artificial stone; Expanding or defibrillating materials
- C04B20/02—Treatment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
- C04B41/5076—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with masses bonded by inorganic cements
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Aftertreatments Of Artificial And Natural Stones (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Description
PATEN TA MT.PATEN TA MT.
M 156597 KLASSE 80 h. M 156597 CLASS 80 h.
in BRESLAU.in BRESLAU.
Zum Färben von Kunststeinen kann man nur Farben gebrauchen, welche gegen chemische Einflüsse und gegen die Wirkungen der Temperatur, der Atmosphäre und des Wetters widerstandsfähig sind, also Erdfarben. Diese müssen auch noch an der Unterlage fest haften, so daß sie durch mechanische Einwirkung, wie Stoß, Schlag, Frost usw., nicht losgetrennt werden können. Deshalb setzteFor coloring artificial stones you can only use colors that are against chemical ones Influences and against the effects of temperature, atmosphere and weather are resistant, i.e. earth colors. These must also be attached to the base adhere so that they are not due to mechanical effects such as impact, shock, frost, etc. can be separated. Therefore continued
ίο man häufig dem Material, aus dem die Kunststeine hergestellt wurden, gleich den notwendigen Farbstoff zu; man färbte in der Masse (englisches Patent 3972/1896). Eine solche Färbung ist natürlich dauerhaft, denn sie verschwindet nur mit dem Stein selbst, aber sie verlangt sehr viel Farbstoff, so daß ein derartiger Zusatz die Festigkeit des Steines beeinträchtigt.ίο one often uses the material from which the artificial stones were made, equal to the necessary dye; one colored in the Mass (English patent 3972/1896). Such coloring is of course permanent because it only disappears with the stone itself, but it requires a lot of dye, so that such an addition adversely affects the strength of the stone.
Ein anderes Verfahren (D. R. P. 61552) benutzt als Grundkörper geschlämmtes Pulver aus farbigen gebrannten Tonen und verbindet es durch Kalk und Gips. Dasselbe dient allerdings nicht zur Herstellung von Baumaterialien, sondern zur Imitation von Terrakotten. Für Bausteine würden die Kosten des Verfahrens zu groß sein, denn man wird nicht Steine brennen, mahlen, das Pulver schlämmen, um nachher minderwertige Steine daraus zu machen; es ist dann bequemer und billiger, die gebrannten Steine direkt zu vermauern. Endlich benutzt man zum Färben von sogenannten Zementverblendern gewöhnliche Erdfarben, die man gemischt mit trockenem Zement auf die noch nicht abgebundenen feuchten Zementsteine aufsiebt und in diese einrieb (vergl. D. R. P. 49671).Another method (D. R. P. 61552) uses slurried powder as the base body from colored baked clays and connects it with lime and gypsum. The same serves however not for the production of building materials, but for the imitation of terracottas. For building blocks, the cost of the process would be too great because you will not burn the stones, grind the powder mud in order to make inferior stones out of them afterwards; it is then more convenient and cheaper to wall up the fired bricks directly. Finally you use it for dyeing ordinary earth colors from so-called cement facing bricks, mixed with dry ones Sift cement on the not yet set, damp cement stones and put in this rubbed in (see D. R. P. 49671).
Nach vorliegender Erfindung stellt man zum Färben von Beton oder Kunststeinen vorzüglich geeignete Farben dadurch her, daß man gebrannten Ton verschiedener Farben, z. B. Ziegelton oder Verblendsteine oder Abfälle und Klamotten davon usw. als feinstes Mehl längere Zeit mit Salzsäure digeriert und dann die überschüssige Säure und die entstandenen Chloride vollständig mit Wasser auswäscht. Man entfernt auf diese Weise alle in Wasser und Salzsäure löslichen Stoffe, wie Alkalien, alkalische Erden, Carbonate usw., gleichzeitig werden die Silikate aufgeschlossen, so daß eine große Menge löslicher freier und reaktionsfähiger, also aktiver Kieselsäure in dem färbenden Rückstande bleibt. Eine Analyse zeigte folgende Ergebnisse: According to the present invention one provides for coloring concrete or artificial stones particularly suitable colors by using fired clay of different colors, z. B. Brick clay or facing bricks or waste and clothes thereof, etc. as the finest Flour digested with hydrochloric acid for a long time and then the excess acid and the washes out the resulting chlorides completely with water. You remove that way all substances soluble in water and hydrochloric acid, such as alkalis, alkaline earths, carbonates etc., at the same time the silicates are broken down, making a large amount more soluble free and reactive, i.e. active, silica in the coloring residue remain. An analysis showed the following results:
Vor dem Nach dem Behandeln mit Behandeln mit H Cl HCl Before After treatment with treatment with Cl H HCl
Glühverlust 1,32 0,76Loss on ignition 1.32 0.76
Unlösliches 73,77 55,43Insolubles 73.77 55.43
Eisen und Tonerde . . 16,56 13,80Iron and clay. . 16.56 13.80
Kalk 2,48 1,49Lime 2.48 1.49
Kieselsäure (löslich) . . 5,06 29,06Silicic acid (soluble). . 5.06 29.06
99,19. 100,54.99.19. 100.54.
Diese aktive Kieselsäure verleiht dem Rückstände seine wertvollen Eigenschaften alsThis active silica gives the residue its valuable properties as
Bindestoff. Die Färbekraft ist unvermindert erhalten; man braucht also verhältnismäßig geringe Mengen.Binder. The coloring power is retained undiminished; so you need proportionately small quantities.
Die Erhärtung erfolgt nicht langsamer als bei ungefärbten Kunststeinen, und die Festigkeit wird eher größer. Farbschicht und Stein, wachsen gewissermaßen ineinander, so daß.; es unmöglich ist, die Farben vom Steine wieder zu entfernen, ohne den Stein zu zerstören. The hardening is not slower than with uncolored artificial stones, and the strength tends to increase. Layer of paint and stone, grow into one another, so to speak, so that .; it is impossible to see the colors from the stones to be removed again without destroying the stone.
Für die Verwendung mischt man der Farbe ungefähr 25 Prozent Zement und so viel Wasser hinzu, daß ein gut streichfähiger Brei entsteht, und trägt diese Masse auf die zu färbenden, geformten, aber noch nicht' erhärteten Steine auf, so daß Steine und Farbe miteinander und gleichzeitig abbinden.To use it, mix about 25 percent cement and that much of the paint Add water to make a paste that is easy to spread and carry this mass to the coloring, shaped, but not yet 'hardened stones, so that stones and color bind with each other and at the same time.
Claims (1)
Publications (1)
Publication Number | Publication Date |
---|---|
DE156597C true DE156597C (en) |
Family
ID=422948
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DENDAT156597D Active DE156597C (en) |
Country Status (1)
Country | Link |
---|---|
DE (1) | DE156597C (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE941595C (en) * | 1951-05-09 | 1956-04-12 | Filter Tips Ltd | Device for producing a composite cigarette filling |
DE202010003487U1 (en) | 2009-10-12 | 2011-02-24 | rc-direct Unternehmergesellschaft (haftungsbeschränkt) | Electrically powered vehicle with hub motor |
-
0
- DE DENDAT156597D patent/DE156597C/de active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE941595C (en) * | 1951-05-09 | 1956-04-12 | Filter Tips Ltd | Device for producing a composite cigarette filling |
DE202010003487U1 (en) | 2009-10-12 | 2011-02-24 | rc-direct Unternehmergesellschaft (haftungsbeschränkt) | Electrically powered vehicle with hub motor |
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