DE131641C - - Google Patents
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- Publication number
- DE131641C DE131641C DENDAT131641D DE131641DA DE131641C DE 131641 C DE131641 C DE 131641C DE NDAT131641 D DENDAT131641 D DE NDAT131641D DE 131641D A DE131641D A DE 131641DA DE 131641 C DE131641 C DE 131641C
- Authority
- DE
- Germany
- Prior art keywords
- mixed
- briquetted
- insoluble
- solutions
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000243 solution Substances 0.000 claims description 11
- 239000002244 precipitate Substances 0.000 claims description 8
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 239000011435 rock Substances 0.000 claims description 5
- 239000011230 binding agent Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical class [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 150000003863 ammonium salts Chemical class 0.000 claims description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000000428 dust Substances 0.000 claims description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 239000011707 mineral Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 159000000001 potassium salts Chemical class 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 239000000463 material Substances 0.000 description 11
- CSNNHWWHGAXBCP-UHFFFAOYSA-L mgso4 Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L sodium carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical group [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 3
- 239000001110 calcium chloride Substances 0.000 description 3
- 229910001628 calcium chloride Inorganic materials 0.000 description 3
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 3
- 235000019341 magnesium sulphate Nutrition 0.000 description 3
- 239000001187 sodium carbonate Substances 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N Sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 235000015450 Tilia cordata Nutrition 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- 239000011776 magnesium carbonate Substances 0.000 description 2
- 235000014380 magnesium carbonate Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L na2so4 Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Chemical compound [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- IZMHKHHRLNWLMK-UHFFFAOYSA-M Aluminium monochloride Chemical compound Cl[Al] IZMHKHHRLNWLMK-UHFFFAOYSA-M 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H Aluminium sulfate Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229960005069 Calcium Drugs 0.000 description 1
- 229960003563 Calcium Carbonate Drugs 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate dianion Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- FOSCDBCOYQJHPN-UHFFFAOYSA-M Cl[Mg] Chemical compound Cl[Mg] FOSCDBCOYQJHPN-UHFFFAOYSA-M 0.000 description 1
- -1 Magnesium chlorine Chemical compound 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H Tricalcium phosphate Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000001066 destructive Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B1/00—Preliminary treatment of ores or scrap
- C22B1/14—Agglomerating; Briquetting; Binding; Granulating
- C22B1/24—Binding; Briquetting ; Granulating
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Geology (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
Gegenstand vorliegender Erfindung ist ein Verfahren zum Brikettiren von Erz-, Mineral-, Gesteins- und Metallklein, Hochofenstaub, Schlackensand und ähnlichen Materialien und beruht darauf, dafs in den zu brikettirenden Stoffen ein unlöslicher, die Bindung bedingender Nied„erschlag dadurch erzeugt wird, dafs dem Material Lösungen, die sich sofort unter Bildung eines unlöslichen Körpers umsetzen, zugesetzt werden.The present invention is a method for briquetting of ore, mineral, Rock and metal small, blast furnace dust, slag sand and similar materials and is based on the fact that in the substances to be briquetted there is an insoluble one that determines the bond Niederlag is produced by the fact that the material creates solutions which are immediately formed convert an insoluble body, are added.
In dem Buche von Krätzer, »Wasserglas und Infusorienerde«, Wien 1887, S. 53 und 55, findet sich ein Verfahren beschrieben, demzufolge künstliche, aus Sand und Wasserglaslösung geformte Steine zwecks Ueberziehens mit einer festen Deckschicht mit Lösungen behandelt werden, welche mit dem Wasserglas einen unlöslichen Körper bilden. Die fertigen Steine werden zu dem Zwecke mit einer Chlorcalciumlösung, und zwar vortheilhafterweise in der Witrme — bei ioo° — behandelt. Der sich ausscheidende kieselsaure Kalk versetzt die Poren, überzieht also die Oberfläche der Steine mit einer festen undurchlässigen Schicht und verhindert dadurch das Eindringen des zerstörenden Einflusses der Atmosphäre in das Innere.In the book by Krätzer, "Wasserglas und Infusorienerde", Vienna 1887, pp. 53 and 55, a method is described, according to which artificial, from sand and water glass solution shaped stones treated with solutions for the purpose of covering them with a solid top layer which form an insoluble body with the water glass. The finished stones are mixed with a calcium chloride solution for the purpose and that advantageously in the Witrme - at 100 ° - treated. Of the Silicic acid lime which precipitates out displaces the pores and thus coats the surface of the stones with a solid impermeable layer, thereby preventing the penetration of the destructive Influence of the atmosphere in the interior.
Diesem Verfahren gegenüber ist der Zweck der Erfindung nicht, die fertigen Briketts oder Steine mit einer undurchlässigen Deckschicht zu überziehen, sondern vielmehr die Briketts selbst in der Weise herzustellen, dafs sie weder beim Transport, noch durch mechanische oder atmosphärische Einflüsse zerfallen und deren einzelne Theilchen durch die ganze Masse hindurch gleichmäfsig mit einander verkittet sind. Zu diesem Zwecke wird ein Bindemittel verwandt, welches in dem zu brikettirenden Material erst, und zwar in äufserst feiner Vertheilung erzeugt wird, indem man nämlich das Material nach einander mit zwei Lösungen tränkt, welche sich unter Bildung eines unlöslichen Körpers umsetzen. Es ist klai', dafs selbst mit den besten mechanischen Hülfsmitteln nicht eine so innige Mischung zweier Körper erzielt werden kann, wie dies nach dem vorliegenden Verfahren möglich ist. Der in den allerfeinsten Poren und Zwischenräumen des Materials sich bildende feste Niederschlag liefert ein Bindemittel, welches alle anderen dadurch an Bindekraft übertrifft, dafs es· die kleinsten Theilchen mit einander verkittet.Against this method, the purpose of the invention is not the finished briquettes or To cover stones with an impermeable top layer, but rather the briquettes even to produce them in such a way that they can be removed neither during transport, nor by mechanical or atmospheric influences disintegrate and their individual particles through the whole mass are evenly cemented to each other. A binding agent is used for this purpose, which only in the material to be briquetted, and indeed in extremely fine distribution is produced by soaking the material one after the other with two solutions, which dissolve to form an insoluble one Implement body. It is clear that even with the best mechanical aids such an intimate mixture of two bodies cannot be achieved as after the present proceedings is possible. The one in the finest pores and spaces The solid precipitate that forms on the material provides a binder which all others by the fact that it cemented the smallest particles together.
Die Materialien sind in dem überall entstandenen Niederschlage gewissermafsen wie in einer Grundmasse eingebettet, welche bereits unter ziemlich geringem Druck Prefsstücke liefert, die an natürliche Steine oder Gesteinsconglomerate erinnern. Der Vorgang im vorliegenden Falle ist ähnlichen Vorgängen in der Natur gleich. Auch hier werden durch Reactionen von Salzlösungen auf einander Niederschläge gebildet, welche, zwischen losen Materialien entstehend, diese zusammenkitten. Nur entstehen in der Natur auf diese Weise dieIn the precipitate that has arisen everywhere, the materials are to a certain extent as in embedded in a base material, which is already under relatively low pressure Prefsstück that are reminiscent of natural stones or rock conglomerates. The process in the present Trap is the same as similar processes in nature. Here, too, reactions formed by salt solutions on each other precipitates, which, between loose materials arising from cementing these together. Only in this way do they arise in nature
Gesteine bezw. Gesteinsconglomerate meist erst im Laufe eines sehr grofsen Zeitraumes, da der Druck vielfach gering ist.Rocks resp. Rock conglomerates usually only in the course of a very long period of time, since the Pressure is often low.
Als solche Lösungen kommen in Betracht die wässrigen Lösungen eines Magnesium-, Calcium- oder Aluminiumsalzes einerseits und die wässrigen Lösungen von Kalium-, Natriumoder Ammoniumsalzen andererseits. Wird beispielsweise Magnesiumsulfat und Natriumcarbonat verwendet, so bildet sich ein Niederschlag von basischem Magnesiümcarbonat nach der folgenden Gleichung:The aqueous solutions of a magnesium, Calcium or aluminum salt on the one hand and the aqueous solutions of potassium, sodium or Ammonium salts on the other hand. For example, it uses magnesium sulfate and sodium carbonate is used, a precipitate of basic magnesium carbonate forms according to the following equation:
2 Mg SO4 + 2 Na2 CO3 + H2O = Mg CO3 Mg H2O2 + 2 Na2 SO4 + CO2. 2 Mg SO 4 + 2 Na 2 CO 3 + H 2 O = Mg CO 3 Mg H 2 O 2 + 2 Na 2 SO 4 + CO 2 .
Weiter eignen sich beispielsweise Chlormagnesium und Natronlauge. Chlorcalcium und kohlensaures Kali, Chloraluminium oder Aluminiumsulfat und Ammoniak, Chlorcalcium und schwefelsaures Natron; durch Mischen dieser genannten Körper in wässrigen Lösungen entstehen ebenfalls unlösliche Niederschläge, welche als Bindemittel dienen.Magnesium chlorine and sodium hydroxide solution are also suitable. Calcium chloride and carbonate of potash, chloroaluminum or aluminum sulfate and ammonia, calcium chloride and sodium sulphate; by mixing these named bodies in aqueous solutions also insoluble precipitates, which serve as binders.
Das Verfahren wird beispielsweise in folgender Weise ausgeführt:The procedure is carried out, for example, in the following way:
Die zu brikettirende Masse wird mit einer wässrigen Lösung von Magnesiumsulfat innig gemischt und diese Mischung sodann mit einer wässrigen' Lösung von Natriumcarbonat verrührt, wobei die Menge Natriumcarbonat der angewendeten Menge Magnesiumsulfat entsprechen mufs.The mass to be briquetted becomes intimate with an aqueous solution of magnesium sulphate mixed and this mixture then stirred with an aqueous' solution of sodium carbonate, the amount of sodium carbonate being equal to the amount of magnesium sulfate used must.
Durch die Einwirkung der beiden Lösungen entsteht das in der obigen Gleichung angegebene unlösliche basische Magnesiümcarbonat, welches in dem zu brikettirenden Material in feinster Weise vertheilt wird.The effect of the two solutions results in the one given in the above equation insoluble basic magnesium carbonate, which is extremely fine in the material to be briquetted Is distributed wisely.
Bereits in dem schwedischen Patent 8458 finden sich Andeutungen, ein unlösliches Salz in der zu brikettirenden Masse zu erzeugen, jedoch nicht zum Zwecke der Bindung, sondern hierzu benutzt der Inhaber jenes Patentes Magnesit und Chlormagnesium und giebt den fertigen Prefsstücken ein kohlensaures oder phosphörsaures Salz in Lösung nur aus dem Grunde hinzu, um etwa vorhandenen Kalk in unlösliches Calciumcarbonat oder Calciumphosphat überzuführen und ein Zerfallen an feuchter Luft zu verhüten.Already in the Swedish patent 8458 there are references to an insoluble salt to be produced in the mass to be briquetted, but not for the purpose of binding, but for this purpose the proprietor of that patent uses magnesite and chloromagnesium and gives the manufacture a carbonate or phosphate salt in solution only from the Prefsstücks Reasons to add any existing lime to insoluble calcium carbonate or calcium phosphate and to prevent disintegration in humid air.
Auch bei sonst vorgeschlagenen Zusätzen von Lösungen oder Flüssigkeiten (brit. Patent 29865/1896, brit. Patent 9610/1898) handelt es sich nicht um die Erzeugung von an sich bindungsfähigen Niederschlägen in dem zu brikettirenden Material, sondern darum, das Material hauptsächlich vor Verfall durch Verwittern zu bewahren.Even with any other suggested additions of solutions or liquids (British patent 29865/1896, British Patent 9610/1898) it is not a question of the production of per se bindable precipitates in the material to be briquetted, but about the material mainly to prevent deterioration through weathering.
Claims (1)
Verfahren zum Brikettiren von Erz-, Mineral-, Gesteins-, Metallklein, Hochofenstaub, Schlackensand u. dgl., für sich allein oder gemischt, dadurch gekennzeichnet, dafs als Bindemitter der Niederschlag benutzt wird, welcher entsteht, wenn das mit einer wässrigen Lösung eines Magnesium-, Calcium- oder ,Aluminiumsalzes gemischte Gut mit einer Lösung eines Kalium-, Natrium- oder Ammoniumsalzes versetzt wird, worauf das Gemenge in bekannter Weise brikettirt wird.Patent claim:
Process for briquetting of ore, mineral, rock, metal, blast furnace dust, slag sand and the like, alone or mixed, characterized in that the precipitate is used as the binding agent, which occurs when this is mixed with an aqueous solution Magnesium, calcium or aluminum salt is mixed with a solution of a potassium, sodium or ammonium salt, whereupon the mixture is briquetted in a known manner.
Publications (1)
| Publication Number | Publication Date |
|---|---|
| DE131641C true DE131641C (en) |
Family
ID=399956
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| DENDAT131641D Active DE131641C (en) |
Country Status (1)
| Country | Link |
|---|---|
| DE (1) | DE131641C (en) |
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0
- DE DENDAT131641D patent/DE131641C/de active Active
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