DE123863C - - Google Patents
Info
- Publication number
- DE123863C DE123863C DENDAT123863D DE123863DA DE123863C DE 123863 C DE123863 C DE 123863C DE NDAT123863 D DENDAT123863 D DE NDAT123863D DE 123863D A DE123863D A DE 123863DA DE 123863 C DE123863 C DE 123863C
- Authority
- DE
- Germany
- Prior art keywords
- wood
- solution
- painted
- painting
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002023 wood Substances 0.000 claims description 20
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 claims description 10
- 238000010422 painting Methods 0.000 claims description 10
- 239000004744 fabric Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 229920000159 gelatin Polymers 0.000 claims description 7
- 235000019322 gelatine Nutrition 0.000 claims description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 6
- 239000003086 colorant Substances 0.000 claims description 6
- SURQXAFEQWPFPV-UHFFFAOYSA-L iron(2+) sulfate heptahydrate Chemical compound O.O.O.O.O.O.O.[Fe+2].[O-]S([O-])(=O)=O SURQXAFEQWPFPV-UHFFFAOYSA-L 0.000 claims description 6
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 6
- 108010010803 Gelatin Proteins 0.000 claims description 5
- 239000008273 gelatin Substances 0.000 claims description 5
- 235000011852 gelatine desserts Nutrition 0.000 claims description 5
- 239000010985 leather Substances 0.000 claims description 2
- 239000007788 liquid Substances 0.000 claims description 2
- 238000010186 staining Methods 0.000 claims 1
- 239000000975 dye Substances 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L Iron(II) sulfate Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 2
- RGCKGOZRHPZPFP-UHFFFAOYSA-N Alizarin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC=C3C(=O)C2=C1 RGCKGOZRHPZPFP-UHFFFAOYSA-N 0.000 description 2
- 239000001828 Gelatine Substances 0.000 description 2
- 239000005569 Iron sulphate Substances 0.000 description 2
- 229940042115 Methylene blue Drugs 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000358 iron sulfate Inorganic materials 0.000 description 2
- 229960000907 methylthioninium chloride Drugs 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- XKTMIJODWOEBKO-UHFFFAOYSA-M sodium;3-[[N-ethyl-4-[[4-[ethyl-[(3-sulfonatophenyl)methyl]azaniumylidene]cyclohexa-2,5-dien-1-ylidene]-phenylmethyl]anilino]methyl]benzenesulfonate Chemical compound [Na+].C=1C=C(C(=C2C=CC(C=C2)=[N+](CC)CC=2C=C(C=CC=2)S([O-])(=O)=O)C=2C=CC=CC=2)C=CC=1N(CC)CC1=CC=CC(S([O-])(=O)=O)=C1 XKTMIJODWOEBKO-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- RODRRGLLKPAFKI-CCEZHUSRSA-N 2-amino-5-[(E)-(4-sulfophenyl)diazenyl]benzenesulfonic acid Chemical compound C1=C(OS(O)=O)C(N)=CC=C1\N=N\C1=CC=C(OS(O)=O)C=C1 RODRRGLLKPAFKI-CCEZHUSRSA-N 0.000 description 1
- -1 B. methylene blue Chemical compound 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241000978776 Senegalia senegal Species 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 230000001464 adherent Effects 0.000 description 1
- 230000005591 charge neutralization Effects 0.000 description 1
- 235000019233 fast yellow AB Nutrition 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001264 neutralization Effects 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000005554 pickling Methods 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 210000001519 tissues Anatomy 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K5/00—Treating of wood not provided for in groups B27K1/00, B27K3/00
- B27K5/02—Staining or dyeing wood; Bleaching wood
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/16—Inorganic impregnating agents
- B27K3/26—Compounds of iron, aluminium, or chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/34—Organic impregnating agents
- B27K3/38—Aromatic compounds
- B27K3/42—Aromatic compounds nitrated, or nitrated and halogenated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B27—WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
- B27K—PROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
- B27K3/00—Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
- B27K3/52—Impregnating agents containing mixtures of inorganic and organic compounds
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Forests & Forestry (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
Description
KAISERLICHESIMPERIAL
PATENTAMT.PATENT OFFICE.
- JVr 123863 KLASSE 22g. - JVr 123863 CLASS 22g.
Anilinfarben.Aniline colors.
Vorliegende Erfindung betrifft ein Verfahren zum Bemalen und Färben von Holz, Geweben, Leder u. dgl. mittels wasserlöslicher Anilinfarben, und zwar sollen letztere licht- und luftbeständig gemacht und so fest fixirt werden, dafs z. B. die bemalten Holzgegenstände oder Stoffe u. s. w. gereinigt bezw. gebürstet werden können.The present invention relates to a method for painting and dyeing wood, fabrics, Leather and the like by means of water-soluble aniline dyes, the latter being said to be light and air-resistant made and fixed so firmly that z. B. the painted wooden objects or fabrics and so on. be brushed can.
Dieser Zweck wird erreicht, wenn man die zum Malen zu verwendenden wässerigen Anilinfarblösungen je nach dem gewünschten Farbenton mit einer wässerigen Eisenvitriollösung versetzt und die klaren Lösungen zum Malen benutzt. Hierbei ist es erforderlich, wenn es sich um das Bemalen von Holz handelt, letzteres zuvor mittels Gelatinelösung in geeigneter Weise zu imprägniren. Die bemalten Holzgegenstände kann man dann auch noch zweckmäfsig mit Ammoniakflüssigkeit behandeln, um die Malereien noch echter und unverwaschbarer zu machen, event, empfiehlt sich die Behandlung mit einem geeigneten Firnifs, dem Ammoniak zugesetzt sein kann, wenn nachträglich polirt werden soll. Auch kann man glanzlosen Lack zur Anwendung bringen, um die Bildfläche matt zu erhalten.This purpose is achieved by using the aqueous aniline dye solutions to be used for painting Depending on the desired shade of color, an aqueous iron vitriol solution is added and used the clear solutions for painting. Here it is necessary when it comes to painting wood, the latter to be impregnated beforehand in a suitable manner using gelatin solution. The painted wooden objects one can then also treat the paintings appropriately with ammonia liquid To make it even more real and indelible, treatment with an event is recommended suitable firnifs to which ammonia can be added if they are subsequently polished target. Dull varnish can also be used to make the picture surface matt to obtain.
In der Holzfärberei ist es bekannt, das Holz vor dem Färben bezw. Beizen, z. B. mit organischen Farbstoffen, mittels geeigneter Beizen, welche tief in die Poren des Holzes eindringen, z. B. mittels Eisenvitriols, zu imprägniren. Ebenso ist es bekannt, das Holz, welches mit organischen Farbstoffen, im Besonderen mit Alizarin färb en gefärbt worden ist, mit Ammoniak zu behandeln, um die Farbe zu entwickeln bezw. die freie Säure abzustumpfen. Auch hat man das Holz schon mit Leimlösung durchtränkt, um es zur Politur vorzubereiten.In wood dyeing, it is known to BEZW the wood before dyeing. Pickling, e.g. B. with organic Dyes, by means of suitable stains, which penetrate deep into the pores of the wood, z. B. by means of iron vitriol to impregnate. It is also known that the wood, which with organic dyes, especially alizarin dyes, with ammonia to treat to develop the color respectively. to blunt the free acid. Also has the wood is already saturated with glue solution in order to prepare it for polishing.
Vorliegendes Verfahren unterscheidet sich von den bekannten Verfahren dadurch, dafs das zu bemalende Holz zuvor nicht mit Eisensulfat, sondern mit Gelatinelösung oder dgl. behandelt wird, so dafs entgegen der bekannten Imprägnirung des Holzes mittels Eisenvitriols ein tiefes Eindringen der mit Eisensulfat versetzten Anilinfarblösungen in das Holz vermieden wird, wobei auch Eisensulfat nicht für sich, sondern in Mischungen mit den Anilinfarblösungen angewendet werden soll; ferner unterscheidet sich das neue Verfahren dadurch, dafs das Holz zum Zwecke der Bemalung und nicht behufs Polirens mit Gelatinelösung behandelt wird, und dafs Ammoniak nicht zum Entwickeln der Farben Anwendung findet, da mit Eisensulfat versetzte Anilinfarben keiner Entwickelung und keiner Neutralisirung bedürfen.The present process differs from the known process in that it leads to The wood that is being painted is not treated beforehand with iron sulfate, but with gelatin solution or the like so that, contrary to the known impregnation of wood by means of iron vitriol, a deep Penetration of the aniline dye solutions mixed with iron sulphate into the wood is avoided, Iron sulfate is also used not on its own, but in mixtures with the aniline dye solutions shall be; furthermore, the new process differs in that the wood is treated with gelatin solution for the purpose of painting and not for polishing, and that ammonia is not used to develop the colors, since it is used with iron sulphate mixed aniline dyes do not require any development or neutralization.
Zur Ausführung des vorliegenden Verfahrens verfährt man folgendermafsen.The following procedure is used to carry out the present method.
Zunächst bereitet man sich eine ca. 20 proc. Eisenvitriollösung und giebt von dieser Lösung je nach dem gewünschten Farbenton mehr oder weniger viel zu den in Wasser aufgelösten Anilinfarben. Um Blätter zu malen, löst man z. B. je 5 g Säuregelb und Guineagrün in 50 ecm heifsem Wasser und giebt z. B. je 100 ecm klare 20 proc. Eisenvitriollösung zu diesen Lösungen hinzu. Je nach dem gewünschten Farbenton vermischt man nun mehrFirst you prepare an approx. 20 proc. Iron vitriol solution and give of this solution depending on the desired shade of color, more or less much to those dissolved in water Aniline colors. To paint leaves, one solves z. B. 5 g each of acid yellow and guinea green in 50 ecm of hot water and give z. B. 100 ecm clear 20 proc. Add iron vitriol solution to these solutions. Depending on what you want Color tone is now mixed more
oder weniger von der klaren Sä'uregelblösung mit der Guineagrünlösung. In gleicher Weise stellt man eine Modebraun-, Ponceau-, Eosin-, Nigrosin-, Methylenblaulösung u. s. w. her.or less of the clear acid gel solution with the guinea green solution. In the same way a fashion brown, Ponceau, eosin, nigrosine, methylene blue solution and so on are produced.
Will man mit diesen so hergestellten Farblösüngen auf Holz malen, so ist es, wie bereits erwähnt, erforderlich, das Holz zuvor mit Gelatinelösung u. dgl. zu behandeln. Zu diesem Zwecke löst man z. B. zweckmä'fsig 5 Tafeln /Gelatine in 250 ecm heifsem Wasser und be-/ streicht mit dieser heifsen Lösung das Holz; ' alsdann reibt man es nach dem Erkalten mit einem reinen Tuche gut ab und läfst es trocknen. Fourniere müssen auf beiden Seiten behandelt werden. Ist die Malerei fertig, so ist es zweckmäfsig, das bemalte Holz mit Ammoniak zu bestreichen und mit einem geeigneten glänzenden oder glanzlosen Firnifs zu versehen, worauf es event, polirt werden kann.If you want to paint on wood with these color solutions produced in this way, then it is as before mentioned, it is necessary to treat the wood beforehand with gelatin solution and the like. To this Purposes one solves z. B. expediently 5 tablets / gelatine in 250 ecm hot water and paint the wood with this hot solution; 'then rub it in after it has cooled down a clean cloth and let it dry. Fourniere must be dealt on both sides will. When the painting is done, it is useful to cover the painted wood with ammonia coat and apply a suitable glossy or lackluster firnif, whereupon it event can be polished.
Handelt es sich um das Bemalen von Stoffen, so ist eine vorangehende Behandlung mit Gelatine nicht erforderlich, dagegen ist es zweckmäfsig, den Farben Gummi arabicum zuzusetzen. If it is a question of painting fabrics, a previous treatment with gelatine is required not necessary, but it is advisable to add gum arabic to the colors.
Die Contouren des zu bemalenden Bildes u. s. w. zeichnet man entweder mittels Bleistifts oder mit der betreffenden Farbe mittels Feder, Pinsels oder Schablonen.The contours of the picture to be painted and so on are either drawn with a pencil or with the relevant color using a pen, brush or stencil.
: Die Vorzüge des vorliegenden Verfahrens bestehen gegenüber den bekannten Malverfahren darin, dafs die bemalten Stoffe gereinigt und selbst gebürstet werden können, was bisher bei der Verwendung von gewöhnlichen Aquarellfarben nicht möglich war, und dafs Stoffe nicht imprägnirt zu werden brauchen, wie z.B. beim Bemalen mit Oelfarben, um Oelrä'nder zu vermeiden, ferner, dafs der manchen Anilinfarben, wie z. B. Methylenblau, anhaftende schillernde Glanz beseitigt wird und dafs die Structur des Holzes bezw. das Gewebe des Stoffes an den bemalten Stellen sichtbar ist.: The advantages of the present process are compared to the known painting processes in that the painted fabrics can be cleaned and brushed, which has been the case up to now the use of ordinary watercolors was not possible, and fabrics were not need to be impregnated, e.g. when painting with oil paints, in order to create oil borders avoid, furthermore, that some aniline dyes, such as B. methylene blue, adherent iridescent sheen is removed and that the structure of the wood resp. the tissue of the The fabric is visible in the painted areas.
Das Reinigen der nach vorliegendem Verfahren hergestellten Malereien kann bei Holz mit Wasser, bei Stoffen u. dgl. zweckmäfsig mit Benzin geschehen.The cleaning of the paintings produced according to the present process can be done with wood with water, in the case of substances and the like, it is expedient to use gasoline.
In allen Fällen ist es natürlich erforderlich, stets vor dem Gebrauch der Farben erst auf einem Stückchen desselben Stoffes bezw. Holzes die Farbe zu probiren, um sich zu vergewissern, dafs die Farben auch den gewünschten Ton und die gewünschte Consistenz besitzen.In all cases it is of course necessary to always use the paints first a piece of the same substance respectively. Wood to try the color to make sure that the colors also have the desired tone and consistency.
Claims (2)
Publications (1)
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DE123863C true DE123863C (en) |
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ID=392689
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