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DE102008000685A1 - Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections - Google Patents

Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections Download PDF

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Publication number
DE102008000685A1
DE102008000685A1 DE200810000685 DE102008000685A DE102008000685A1 DE 102008000685 A1 DE102008000685 A1 DE 102008000685A1 DE 200810000685 DE200810000685 DE 200810000685 DE 102008000685 A DE102008000685 A DE 102008000685A DE 102008000685 A1 DE102008000685 A1 DE 102008000685A1
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Germany
Prior art keywords
interlayer film
colored
polyvinyl acetal
perylene pigments
colorless
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DE200810000685
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German (de)
Inventor
Uwe Dr. Keller
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Kuraray Europe GmbH
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Kuraray Europe GmbH
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Priority to DE200810000685 priority Critical patent/DE102008000685A1/en
Publication of DE102008000685A1 publication Critical patent/DE102008000685A1/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10009—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets
    • B32B17/10036—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the number, the constitution or treatment of glass sheets comprising two outer glass sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/10165—Functional features of the laminated safety glass or glazing
    • B32B17/10339—Specific parts of the laminated safety glass or glazing being colored or tinted
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10651—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments
    • B32B17/1066—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising colorants, e.g. dyes or pigments imparting a tint in certain regions only, i.e. shade band
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10678—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer comprising UV absorbers or stabilizers, e.g. antioxidants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10697—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer being cross-linked
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10761—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing vinyl acetal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B32B17/10005—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing
    • B32B17/1055—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer
    • B32B17/10788—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin laminated safety glass or glazing characterized by the resin layer, i.e. interlayer containing ethylene vinylacetate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B60—VEHICLES IN GENERAL
    • B60J—WINDOWS, WINDSCREENS, NON-FIXED ROOFS, DOORS, OR SIMILAR DEVICES FOR VEHICLES; REMOVABLE EXTERNAL PROTECTIVE COVERINGS SPECIALLY ADAPTED FOR VEHICLES
    • B60J3/00—Antiglare equipment associated with windows or windscreens; Sun visors for vehicles
    • B60J3/007—Sunglare reduction by coatings, interposed foils in laminar windows, or permanent screens
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
    • C08K5/3432—Six-membered rings
    • C08K5/3437—Six-membered rings condensed with carbocyclic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols

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  • Chemical & Material Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Biochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Joining Of Glass To Other Materials (AREA)
  • Laminated Bodies (AREA)

Abstract

The completely or partially colored interlayer film comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections, where 1-80% of a visible surface is colored and contains a mixture of plasticizer-containing polyvinyl acetal, perylene pigments and UV-absorber and 99-20% of the visible surface is colorless and contains a transparent mixture on the basis of plasticizer-containing polyvinyl acetal without perylene pigments. The interlayer film or the colored sections have a transparency difference (delta D) of 20%. The completely or partially colored interlayer film comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections, where 1-80% of a visible surface is colored and contains a mixture of plasticizer-containing polyvinyl acetal, perylene pigments and UV-absorber and 99-20% of the visible surface is colorless and contains a transparent mixture on the basis of plasticizer-containing polyvinyl acetal without perylene pigments. The interlayer film or the colored sections have a transparency difference (delta D) of 20% for near-infrared radiation with 880 nm less than the transparency for sunlight radiation on thermoluminescence with 380-780 nm.

Description

Technisches GebietTechnical area

Die vorliegende Erfindung betrifft ganz oder teilweise gefärbte Folien für Verbundverglasungen, insbesondere Windschutzscheiben, die eine hohe Transparenz für IR-Strahlung aufweisen.The The present invention relates wholly or partially colored Films for laminated glazing, in particular windscreens, which have a high transparency for IR radiation.

Stand der TechnikState of the art

PVB-Folien als Zwischenschicht für Verbundverglasungen werden entweder transparent oder ganz oder teilweise eingefärbt angeboten. Insbesondere Zwischenschichtfolien für Kfz-Windschutzscheiben werden häufig teilgefärbt, d. h. mit einem so genannten Farbband oder Farbkeil im oberen Bereich der Scheibe ausgerüstet, um die Blendwirkung durch Sonnenstrahlung zu minimierenPVB films as an intermediate layer for composite glazing be either transparent or wholly or partially dyed offered. In particular, interlayer films for automotive windscreens are often partially colored, d. H. with one like that equipped ribbon or color wedge in the upper region of the disc, to minimize the glare from solar radiation

Bei gleichmäßig eingefärbten PVB-Folien wird das farbgebende Mittel (Pigment oder Farbstoff) vor der Extrusion der PVB-Masse zugesetzt. Bei der Herstellung von Folien mit Farbband wird üblicherweise ein transparenter Hauptstrom und ein eingefärbter Seitenstrom über zwei entsprechend dimensionierte Extruder im Extrusionswerkzeug zusammen geführt und koextrudiert. Verfahren dieser Art sind bekannt und z. B. in EP 0 111 678 B1 , US 4,316,868 oder US 4,476,075 offenbart.For evenly colored PVB films, the colorant (pigment or dye) is added to the PVB mass prior to extrusion. In the production of films with ribbon, a transparent main stream and a colored side stream is usually led together and coextruded via two appropriately dimensioned extruders in the extrusion die. Methods of this type are known and z. In EP 0 111 678 B1 . US 4,316,868 or US 4,476,075 disclosed.

Die üblicherweise verwendeten Farbstoffe oder Pigmente müssen eine ausreichende Löslichkeit oder Dispergierbarkeit im weichmacherhaltigen PVB-Harz besitzen und gleichzeitig eine ausreichende UV-Stabilität aufweisen. Als ausgezeichnet Lichtstabiles Pigment wird insbesondere Farbruß zur Pigmentierung des Farbbandes von PVB-Folie eingesetzt. In blau oder grau eingefärbten Farbbändern überwiegt die Menge an Ruß in der Gesamtpigmentmischung, da zur Einstellung der geforderten Dunkelheit, genauer eines niedrigen L-Wertes im L,a,b-System, die eigentlich farbbestimmenden Pigmente bzw. Farbstoffe mit einer großen Menge Farbruß kombiniert werden müssen.The usual used dyes or pigments must have sufficient Solubility or dispersibility in the plasticizer-containing PVB resin and at the same time have sufficient UV stability. As excellent light-stable pigment is in particular color soot Pigmentation of the ribbon of PVB film used. In blue or gray colored ribbons outweighs the amount of carbon black in the total pigment mixture because of the adjustment the required darkness, more precisely a low L value in the L, a, b system, the actually color-determining pigments or dyes be combined with a large amount of color black have to.

Nachteilig ist, dass Ruß auch bis weit in den NIR- bzw. IR-Bereich hinein absorbiert.adversely is that soot also far into the NIR or IR range absorbed into it.

Moderne Fahrzeuge sind häufig mit Sensoren ausgerüstet, die z. B. Regentropfen auf der Windschutzscheibe durch die Absorption von Wasser im NIR-Bereich detektieren und somit eine automatische Regelung der Scheibenwischfunktion erlauben. Ebenfalls existieren bereits Nachtsichtsysteme, deren wesentlicher Bestandteil im Infraroten arbeitende Videokameras sind. Diese Systeme haben gemeinsam, dass dabei die Windschutzscheibe und damit auch die darin eingebettete PVB-Folie im IR- oder NIR-Bereich transparent sein müssen.modern Vehicles are often equipped with sensors the z. B. Raindrops on the windshield by the absorption of water in the NIR range and thus an automatic Allow regulation of the windscreen wiper function. Also exist already night vision systems, their essential component in the infrared working video cameras are. These systems have in common that while the windshield and thus the embedded therein PVB film in the IR or NIR range must be transparent.

Die Abschwächung von NIR- und IR-Strahlung durch Absorption von in der PVB-Folie befindlichem Farbruß beeinträchtigt die Funktion solcher Sensoren erheblich. Somit kann die Verbundglasscheibe weder vollständig eingefärbt noch das sicherheitsrelevante Ausstattungsmerkmal „Farbband" als Blendschutz mit den o. g. Ausstattungsmerkmalen die einen NIR-Sensor benötigen, kombiniert werden.The Attenuation of NIR and IR radiation by absorption affected by color black present in the PVB film the function of such sensors considerably. Thus, the laminated glass pane can neither fully colored nor the security relevant Feature "ribbon" as anti-glare with the o. g. Equipment features that require an NIR sensor, be combined.

Ein technischer Ausweg wäre, einen Ausschnitt im Farbband herzustellen, der dann wieder mit klarer PVB-Folie ausgefüllt wird. Alternativ müssten die Pigmente nachträglich lokal gebleicht werden. Beide Varianten sind sehr aufwendig.One technical solution would be to make a cutout in the ribbon, which is then filled again with clear PVB film. alternative would have the pigments subsequently bleached locally become. Both variants are very expensive.

Aufgabetask

Aufgabe der vorliegenden Erfindung war es daher, ganz oder teilweise gefärbte Zwischenschichtfolien für Verbundverglasungen bereit zu stellen, die einerseits eine ausreichende Absorption von Licht im UV/VIS-Bereich und andererseits eine hohe IR-/NIR-Transparenz aufweisen.task The present invention was therefore wholly or partially colored Interlayer films for composite glazing ready On the one hand, there is sufficient absorption of light in the UV / VIS range and on the other hand have high IR / NIR transparency.

Darstellung der ErfindungPresentation of the invention

Farbstoffe mit einer guten Absorption im sichtbaren Bereich des Sonnenlichts und einer gleichzeitig geringen Absorption im IR-/NIR-Bereich sind bekannt. So offenbart DE 102004007382 A1 die Verwendung von Perylenderivaten zur Einfärbung von Polymermassen wie Polyvinylalkohol oder Polyvinylbutyralen. Die Verwendung dieser Mischungen für Verbundverglasungen ist DE 10 2004 007 382 A1 nicht zu entnehmen.Dyes with a good absorption in the visible range of sunlight and a simultaneously low absorption in the IR / NIR range are known. So revealed DE 102004007382 A1 the use of perylene derivatives for coloring polymer compositions such as polyvinyl alcohol or polyvinyl butyrals. The use of these mixtures for composite glazing is DE 10 2004 007 382 A1 not to be taken.

Gegenstand der vorliegenden Erfindung sind daher ganz oder teilweise gefärbte Zwischenschichtfolien für Verbundverglasungen, enthaltend weichmacherhaltiges Polyvinylacetal, Perylenpigmente und UV-Absorber bzw. die aus mindestens zwei Glasscheiben mit mindestens einer solchen Zwischenschichtfolie hergestellten Verbundverglasungen oder Windschutzscheiben für Kraftfahrzeuge oder Flugzeuge.The present invention therefore wholly or partially colored Zwischenschichtfoli for composite glazings containing plasticizer-containing polyvinyl acetal, perylene pigments and UV absorbers or the composite glazings or windshields for motor vehicles or aircraft produced from at least two glass panes with at least one such interlayer film.

Erfindungsgemäße Zwischenschichtfolien, Verbundglaslaminate oder Windschutzscheiben weisen bevorzugt eine Differenztransparenz ΔD der Transparenz für NIR-Strahlung bei 880 nm abzüglich der Transparenz für Sonnenlichtstahlung TL bei 380–780 nm von mindestens 20%, bevorzugt von mindestens 30%, insbesondere von mindestens 50% auf, wobei die Obergrenze der Differenztransparenz ΔD 100% beträgt. Die Messungen der jeweiligen Transparenzen wird gemäß EN KCO durchgeführt.invention Interlayer films, laminated glass laminates or windshields preferably have a differential transparency ΔD of transparency for NIR radiation at 880 nm minus the transparency for sunlight directing TL at 380-780 nm from at least 20%, preferably at least 30%, in particular at least 50%, with the upper limit of the difference transparency ΔD 100%. The measurements of the respective transparencies is carried out according to EN KCO.

Die zur Herstellung von erfindungsgemäßen Folien eingesetzten Perylenpigmente sind mit vielen Substitutionsmustern z. B. aus DE 102004007382 A1 bekannt und werden als Lackzusatz und Farbstoff für Polymere eingesetzt. Bekannteste Vertreter dieser Stoffgruppe sind N,N'-Dimethylperylendicarbonsäurediimid (MPTCDI) oder Perylentetracarbonsäuredianhydrid (PTCDA), die kommerziell als LUMOGEN BLACK FK 4280 und LUMOGEN BLACK FK 4281 von der BASF AG erhältlich sind.The perylene pigments used for the production of films according to the invention are with many substitution patterns z. B. off DE 102004007382 A1 known and used as a paint additive and dye for polymers. Known representatives of this group of substances are N, N'-dimethylperylenedicarboxylic acid diimide (MPTCDI) or perylenetetracarboxylic dianhydride (PTCDA), which are commercially available as LUMOGEN BLACK FK 4280 and LUMOGEN BLACK FK 4281 from BASF AG.

Natürlich können solche NIR-transparenten Schwarzpigmente auch in Kombination mit als NIR- und IR-Filter wirkenden Nanopartikeln bzw. Pigmenten bzw. entsprechenden Gläsern kombiniert werden, so dass gegebenenfalls nur in einem engen Wellenlängenfenster, welches für die Funktion des Sensors maßgeblich ist, die Transparenz erhalten bleibt, im übrigen Wärmestrahlung im NIR- und IR-Bereich jedoch nicht durch das Verbundglas dringt. Dies ist insbesondere bei der Verwendung der erfindungsgemäßen Folien für Windschutzscheiben von Bedeutung, da so das Aufheizen des Fahrzeuginnenraums vermindert wird.Naturally Such NIR-transparent black pigments can also be used in Combination with nanoparticles acting as NIR and IR filters Pigments or corresponding glasses are combined, so that optionally only in a narrow wavelength window, which is decisive for the function of the sensor, the transparency is retained, otherwise heat radiation However, in the NIR and IR range does not penetrate through the laminated glass. This is especially true when using the invention Films for windshields of importance, since so the Heating the vehicle interior is reduced.

Zur Einstellung eines bestimmten Farbtones und der gewünschten Lichttransmission im sichtbaren Bereich können die NIR-transparenten Perylenpigmente mit weiteren Farbstoffen oder Pigmenten kombiniert werden.to Setting a specific color tone and the desired Visible light transmission can be the NIR transparent Perylene pigments are combined with other dyes or pigments.

Beispiele für diesen Zweck einsetzbare organische Farbstoffe sind z. B. Farbstoffe der Typenreihe Macrolex® der Firma Bayer, welche u. A. Anthrachinonabkömmlinge umfasst, oder Farbstoffe der Typenreihe Waxoline® der Firma Zeneca Colours, welche u. A. Chinolinabkömmlinge umfasst. Geeignete organische Pigmente sind z. B. Quinacridone oder Phthalocyanine verschiedener Hersteller. Als Beispiel für ein anorganisches Pigment sei neben den gängigen Metalloxidabkömmlingen Farbruß genannt, sofern dieser in solch kleiner Menge verwendet wird, dass eine ausreichend hohe Transmission im NIR-Bereich bzw. der bevorzugten Differenztransparenz ΔD erhalten bleibt. Weitere, geeignete Pigmente oder Farbstoffe sind eine oder mehrere Verbindungen der Gruppe Chinophthalone, Pyrazolone, Anthrachinone, Perinone, Monoazofarbstoffe, Phthalocyanine, Perylene, Azopigmente, Cromophtale, Thioindigopigmente, Dioxazine, Diketopyrrolopyrrole, Benzimidazolone, Isoindoline, Indanthrone, Metalloxide, -sulfide, -chromate und Kohlenstoff (Ruß).Examples of organic dyes which can be used for this purpose are, for example, B. dyes of the type series Macrolex ® the company Bayer, which u. A. Anthrachinonabkömmlinge includes, or dyes of the type series Waxoline ® Zeneca Colors, which u. A. Chinolinabkömmlinge includes. Suitable organic pigments are, for. As quinacridones or phthalocyanines from different manufacturers. As an example of an inorganic pigment, in addition to the common metal oxide derivatives, color black may be mentioned if it is used in such a small amount that a sufficiently high transmission in the NIR range or the preferred differential transparency ΔD is maintained. Other suitable pigments or dyes are one or more compounds of the group quinophthalones, pyrazolones, anthraquinones, perinones, monoazo dyes, phthalocyanines, perylenes, azo pigments, cromophtals, thioindigo pigments, dioxazines, diketopyrrolopyrroles, benzimidazolones, isoindolines, indanthrones, metal oxides, sulfides, chromates and carbon (soot).

Typische Einsatzkonzentrationen der Perylenpigmente bzw. aller eingesetzten farbgebenden Verbindungen bewegen sich in einem Bereich von 0,001 Gew.% bis 10 Gew.%, bevorzugt 0,001 Gew.% bis 5 Gew.% besonders bevorzugt 0,001 Gew.% bis 1,5 Gew.%, jeweils bezogen auf die gesamte Folienformulierung bzw. die gesamte Mischung.typical Use concentrations of perylene pigments or all used coloring compounds are in the range of 0.001 % By weight to 10% by weight, preferably 0.001% by weight to 5% by weight, especially preferably 0.001% by weight to 1.5% by weight, in each case based on the total Foil formulation or the entire mixture.

Zur Stabilisierung der im Farbband befindlichen Farbstoffe und Pigmente werden UV-Absorber wie Amine (insbesondere sterisch gehinderte Amine (HALS-Stabilisatoren), Benzophenonderivate und/oder wie Benzotriazolderivate (z. B. Tinuvin P, Tinuvin 326, 327, 328) oder Organophosphite eingesetzt.to Stabilization of the dyes and pigments in the ink ribbon UV absorbers such as amines (in particular sterically hindered amines (HALS stabilizers), benzophenone derivatives and / or as benzotriazole derivatives (eg Tinuvin P, Tinuvin 326, 327, 328) or organophosphites.

Die erfindungsgemäßen Folien enthalten bevorzugt unvernetztes Polyvinylacetal, insbesondere unvernetztes Polyvinylbutyral (PVB), das durch Acetalisierung von Polyvinylalkohol mit Butyraldehyd gewonnen wird.The Films according to the invention preferably contain uncrosslinked Polyvinyl acetal, in particular uncrosslinked polyvinyl butyral (PVB), which is obtained by acetalization of polyvinyl alcohol with butyraldehyde.

Der Einsatz von vernetzten Polyvinylacetalen, insbesondere vernetztem Polyvinylbutyral (PVB) ist ebenso möglich. Geeignete vernetzte Polyvinylacetale sind z. B. in EP 1527107 B1 und WO 2004/063231 A1 (thermische Selbstvernetzung von Carboxylgruppenhaltigen Polyvinylacetalen), EP 1606325 A1 (mit Polyaldehyden vernetzte Polyvinylacetale) und WO 03/020776 A1 (mit Glyoxylsäure vernetzte Polyvinylacetale) beschrieben. Auf die Offenbarung dieser Patentanmeldungen wird vollumfänglich Bezug genommen.The use of crosslinked polyvinyl acetals, especially crosslinked polyvinyl butyral (PVB) is also possible. Suitable crosslinked polyvinyl acetals are, for. In EP 1527107 B1 and WO 2004/063231 A1 (thermal self-crosslinking of carboxyl-containing polyvinyl acetals), EP 1606325 A1 (crosslinked with polyaldehydes polyvinyl acetals) and WO 03/020776 A1 (Crosslinked with glyoxylic polyvinyl acetals) described. The disclosure of these patent applications is fully incorporated by reference.

Es ist auch möglich, die Acetalisierung mit anderen oder weiteren Aldehyden mit 5–10 Kohlenstoffatomen wie z. B. Valeraldehyd durchzuführen.It it is also possible to acetalize with others or others Aldehydes having 5-10 carbon atoms, such as. B. valeraldehyde perform.

Als zu acetalisierender Polyvinylalkohol können im Rahmen der vorliegenden Erfindung auch Terpolymere aus hydrolysierten Vinylacetat/Ethylen-Copolymeren eingesetzt werden. Diese Verbindungen sind in der Regel zu mehr als 98% hydrolysiert und enthalten 1 bis 10 Gew. auf Ethylen basierende Einheiten (z. B. Typ „Exceval" der Kuraray Europe GmbH).When To be acetalized polyvinyl alcohol can in the context of present invention also terpolymers of hydrolyzed vinyl acetate / ethylene copolymers be used. These compounds are usually more as 98% hydrolyzed and contain 1 to 10 wt. based on ethylene Units (eg type "Exceval" of Kuraray Europe GmbH).

Polyvinylacetale enthalten neben den Acetaleinheiten noch aus Vinylacetat und Vinylalkohol resultierende Einheiten. Die erfindungsgemäß verwendeten Polyvinylacetale weisen bevorzugt einen Polyvinylalkoholanteil von mindestens 14 Gew.%, bevorzugt mindestens 18 Gew.%, insbesondere 19,5 Gew.% auf. Ein Polyvinylalkoholanteil von 25 Gew.% sollte nicht überschritten werden.polyvinyl contain in addition to the acetal units still from vinyl acetate and vinyl alcohol resulting units. The inventively used Polyvinyl acetals preferably have a polyvinyl alcohol content of at least 14% by weight, preferably at least 18% by weight, in particular 19.5% by weight on. A polyvinyl alcohol content of 25% by weight should not be exceeded become.

Der Polyvinylacetatanteil liegt bevorzugt unter 5 Gew.%, bevorzugt unter 3 Gew.% und insbesondere unter 2 Gew.% Aus dem Polyvinylalkoholanteil und dem Restacetatgehalt kann der Acetalisierungsgrad rechnerisch ermittelt werden.Of the Polyvinyl acetate is preferably below 5 wt.%, Preferably below 3% by weight, and in particular less than 2% by weight, of the polyvinyl alcohol content and the residual acetate content, the degree of acetalization can be calculated be determined.

Bevorzugt weisen die erfindungsgemäßen Folien einen Weichmachergehalt von 15 bis 40 Gew.%, besonders bevorzugt 20 bis 40 Gew.% und insbesondere von 20 bis 30 Gew.% auf. Erfindungsgemäße Folien können einen oder mehrere Weichmacher enthalten.Prefers the films of the invention have a plasticizer content from 15 to 40% by weight, more preferably from 20 to 40% by weight, and especially from 20 to 30% by weight. Inventive films can contain one or more plasticizers.

Besonders geeignet als Weichmacher für die erfindungsgemäßen Folien ist mindestens eine Verbindung aus der Gruppe Di-2-ethylhexylsebacat, Di-2-ethylhexyladipat (DOA), Di-2-ethylhexylphthalat (DOP), Dihexyladipat (DHA), Dibutylsebacat (DBS), Di-2-butoxyethylsebacat (DBES), Triethylenglykol-bis-2-ethylhexanoat, Triethylenglykol-bis-n-heptanoat 3G7, Tetraethylenglykol-bis-n-heptanoat (4G7), Di-2-butoxyethyladipat (DBEA), Di-2-butoxyethoxyethyladipat (DBEEA).Especially suitable as a plasticizer for the inventive Foils is at least one compound from the group di-2-ethylhexyl sebacate, Di-2-ethylhexyl adipate (DOA), di-2-ethylhexyl phthalate (DOP), dihexyl adipate (DHA), dibutyl sebacate (DBS), di-2-butoxyethyl sebacate (DBES), triethylene glycol bis-2-ethylhexanoate, Triethylene glycol bis-n-heptanoate 3G7, tetraethylene glycol bis-n-heptanoate (4G7), di-2-butoxyethyl adipate (DBEA), di-2-butoxyethoxyethyl adipate (DBEEA).

Die genannten Weichmacher können alleine oder als Mischung eingesetzt werden.The Plasticizers mentioned can be used alone or as a mixture be used.

Das Haftungsvermögen von Polyvinylacetalfolien an Glas wird üblicherweise durch die Zugabe von Haftungsregulatoren wie z. B. die in WO 03/033583 A1 offenbarten Alkali- und/oder Erdalkalisalze von organischen Säuren eingestellt. Als besonders geeignet haben sich Magnesium-, Calzium- und/oder Zinksalze organischer Säuren insbesondere Kaliumacetat und/oder Magnesiumacetat herausgestellt. Diese Metallionen werden in bevorzugt einer Konzentration von 5–100 ppm, bezogen auf die Folienmischung eingesetzt.The adhesion of Polyvinylacetalfolien to glass is usually by the addition of adhesion regulators such. B. the in WO 03/033583 A1 disclosed alkali and / or alkaline earth metal salts of organic acids. Magnesium, calcium and / or zinc salts of organic acids, in particular potassium acetate and / or magnesium acetate, have proven to be particularly suitable. These metal ions are used in a preferred concentration of 5-100 ppm, based on the film mixture.

Die prinzipielle Herstellung und Zusammensetzung von Folien auf Basis von Polyvinylacetalen ist z. B. in EP 185 863 B1 , EP 1 118 258 B1 WO 02/102591 A1 , EP 1 118 258 B1 oder EP 387 148 B1 beschrieben. Die Gesamtdicke der Klebefolien liegt üblicherweise bei 0.38, 0.51, 0.76, 1.14, 1.52 oder 2.28 mm.The basic preparation and composition of films based on polyvinyl acetals is z. In EP 185 863 B1 . EP 1 118 258 B1 WO 02/102591 A1 . EP 1 118 258 B1 or EP 387 148 B1 described. The total thickness of the adhesive films is usually 0.38, 0.51, 0.76, 1.14, 1.52 or 2.28 mm.

Erfindungsgemäße Zwischenschichtfolien können farbige und farblose Abschnitte aufweisen, wobei

  • a) 1 bis 80% der Aufsichtfläche farbig ist und eine Mischung aus weichmacherhaltigem Polyvinylacetal, Perylenpigmenten und UV-Absorber enthält
  • b) 99 bis 20% der Aufsichtfläche farblos ist und eine transparente Mischung auf von Basis weichmacherhaltigem Polyvinylacetal ohne Perylenpigmente enthält.
Interlayer films of the invention may have colored and colorless sections, wherein
  • a) 1 to 80% of the surface is colored and contains a mixture of plasticized polyvinyl acetal, perylene pigments and UV absorbers
  • b) 99 to 20% of the top surface is colorless and contains a transparent mixture based on plasticized polyvinyl acetal without perylene pigments.

Als transparentes Material für die farblose Fläche b) wird bevorzugt die identische Mischung wie für die farbige Fläche gemäß a), allerdings ohne Perylenpigmente, eingesetzt.When transparent material for the colorless surface b) is preferably the same mixture as for the colored Surface according to a), but without perylene pigments, used.

Bevorzugt befindet sich zwischen den farbigen und farblosen Abschnitten der Folien ein Übergangsbereich, der einen kontinuierlichen Gradienten der Inhaltsstoffe der genannten Flächen a und b aufweist. Der Übergangsbereich kann ebenfalls in weiten Grenzen eingestellt werden und umfasst bevorzugt 1 bis 15% der Gesamtaufsichtfläche der Folie. Als Übergangsbereich wird der Bereich mit einer 40–80%-igen Lichttransmission nach ECE 43, bezogen auf den Bereich mit der maximalen Lichttransmission (sog. Transparentteil) definiert.Prefers is located between the colored and colorless sections of the Foils a transitional area that is a continuous Gradients of the constituents of said areas a and b. The transition area can also be in wide Limits are set and preferably comprises 1 to 15% of the total supervisory area the foil. As a transition area, the area with a 40-80% light transmission according to ECE 43, based on the area with the maximum light transmission (so-called transparent part) Are defined.

Weiterer Gegenstand der Erfindung sind Verbundverglasungen aus mindestens zwei Glasscheiben mit mindestens einer zwischengelegten, wie oben beschriebenen Zwischenschichtfolie und/oder Windschutzscheiben für Kraftfahrzeuge oder Flugzeuge aus mindestens zwei Glasscheiben mit mindestens einer zwischengelegten, wie oben beschriebenen Folie.Another The invention relates to composite glazings of at least two glass panes with at least one interposed, as above described interlayer film and / or windscreens for Motor vehicles or aircraft made from at least two glass panes at least one interleaved, as described above.

BeispieleExamples

Es wurden Testfolien einer Zusammensetzung gemäß Tab. 1 durch Kalandrieren eines Dryblends aus PVB-Polymer, Weichmacher und Additiven samt Farbstoffen/Pigmenten und anschließendem Pressen auf eine Stärke von 0.38 mm erhalten. 0.38 entspricht ungefähr der Schichtdicke der im Farbbandbereich üblicher koextrudierter Farbbandfolien (der Gesamtdicke 0.76 mm) eingebetteten gefärbten Schicht. Tabelle 1: Vergleichsversuch 1 Beispiel 1 Beispiel 2 PVB-Polymer Gew.-% 72,5 72,5 72,5 Weichmacher 3G8 Gew.-% 27,5 27,5 27,5 Farbruß FW1 Gew.-% 0,04 - - SICOFLUSH K BLAU 69-1147 Gew.-% 0,3 0,3 0,3 Lumogen Schwarz FK 4280 Gew.-% - 0,2 - Lumogen Schwarz FK 4281 Gew.-% - - 0,2 ISOCOLOR-ROSA-PV-20779/3121 Gew.-% 0,1 0,1 0,1 0.38 mm Folienlage laminiert zwischen 2 × 2 mm Klarglas Lichtdurchlässigkeit TL (380–780 nm) % 2,9 0,2 0,8 Lichttransmission bei 880 nm % 17,9 53,4 27,2 Differenz (Transmission bei 880 nm – Lichtdurchlässigkeit TL % 15 53 26 Farbeindruck visuell blaugrün schwarzviolett blauviolett Test films of a composition according to Tab. 1 were obtained by calendering a dry blend PVB polymer, plasticizers and additives including dyes / pigments and subsequent pressing to a thickness of 0.38 mm. 0.38 corresponds approximately to the layer thickness of the dyed layer embedded in the ribbon region of conventional coextruded ribbon films (total thickness 0.76 mm). Table 1: Comparative experiment 1 example 1 Example 2 PVB Polymer Wt .-% 72.5 72.5 72.5 Plasticizer 3G8 Wt .-% 27.5 27.5 27.5 Color black FW1 Wt .-% 0.04 - - SICOFLUSH K BLUE 69-1147 Wt .-% 0.3 0.3 0.3 Lumogen Black FK 4280 Wt .-% - 0.2 - Lumogen Black FK 4281 Wt .-% - - 0.2 ISOCOLOR PINK PV-20779/3121 Wt .-% 0.1 0.1 0.1 0.38 mm film layer laminated between 2 × 2 mm clear glass light transmission TL (380-780 nm) % 2.9 0.2 0.8 Light transmission at 880 nm % 17.9 53.4 27.2 Difference (transmission at 880 nm - light transmission TL % 15 53 26 Color impression visually blue green black violet blue violet

Die erfindungsgemäßen Folien mit einem NIR-transparenten Pigment zeichnen sich gegenüber den üblichen Folien mit Farbruß dadurch aus, dass ihre Transmission bei einer Wellenlänge von 880 nm bezogen auf die Lichttransmission TL im sichtbaren Bereich des Wellenlängenspektrums, gemessen im Verbundglas aus 2 × 2 mm Klarglas + Folie, viel höher ist. Die Lichttransmission ist an einer Stelle im Farbbandbereich am Laminat gemäß EN 410 zu bestimmen. Als Farbbandbereich sind solche Bereiche der Folie definiert, deren Lichttransmission TL um mindestens absolut 10% geringer ist, als jene anderer entweder ungefärbter oder schwach gefärbter Bereiche der Folie.The Films according to the invention with an NIR-transparent Pigment are distinguished from the usual films with carbon black characterized by their transmission at a Wavelength of 880 nm based on the light transmission TL in the visible range of the wavelength spectrum, measured in laminated glass of 2 × 2 mm clear glass + foil, much higher is. The light transmission is at a point in the ribbon area to be determined on the laminate according to EN 410. As a ribbon area are defined areas of the film whose light transmission TL is at least absolutely 10% lower than those of others either uncoloured or weakly colored areas of the Foil.

ZITATE ENTHALTEN IN DER BESCHREIBUNGQUOTES INCLUDE IN THE DESCRIPTION

Diese Liste der vom Anmelder aufgeführten Dokumente wurde automatisiert erzeugt und ist ausschließlich zur besseren Information des Lesers aufgenommen. Die Liste ist nicht Bestandteil der deutschen Patent- bzw. Gebrauchsmusteranmeldung. Das DPMA übernimmt keinerlei Haftung für etwaige Fehler oder Auslassungen.This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Zitierte PatentliteraturCited patent literature

  • - EP 0111678 B1 [0003] - EP 0111678 B1 [0003]
  • - US 4316868 [0003] US 4316868 [0003]
  • - US 4476075 [0003] US 4476075 [0003]
  • - DE 102004007382 A1 [0010, 0010, 0013] - DE 102004007382 A1 [0010, 0010, 0013]
  • - EP 1527107 B1 [0020] - EP 1527107 B1 [0020]
  • - WO 2004/063231 A1 [0020] WO 2004/063231 A1 [0020]
  • - EP 1606325 A1 [0020] EP 1606325 A1 [0020]
  • - WO 03/020776 A1 [0020] WO 03/020776 A1 [0020]
  • - WO 03/033583 A1 [0028] WO 03/033583 A1 [0028]
  • - EP 185863 B1 [0029] - EP 185863 B1 [0029]
  • - EP 1118258 B1 [0029, 0029] - EP 1118258 B1 [0029, 0029]
  • - WO 02/102591 A1 [0029] WO 02/102591 A1 [0029]
  • - EP 387148 B1 [0029] - EP 387148 B1 [0029]

Claims (9)

Ganz oder teilweise gefärbte Zwischenschichtfolie für Verbundverglasungen, enthaltend weichmacherhaltiges Polyvinylacetal, Perylenpigmente und UV-Absorber.Fully or partially colored interlayer film for laminated glazing, containing plasticizer-containing Polyvinyl acetal, perylene pigments and UV absorbers. Zwischenschichtfolie nach Anspruch 1, dadurch gekennzeichnet, dass die Zwischenschichtfolie farbige und farblose Abschnitte aufweist, wobei – 1 bis 80% der Aufsichtfläche farbig ist und eine Mischung aus weichmacherhaltigem Polyvinylacetal, Perylenpigmenten und UV-Absorber enthält und – 99 bis 20% der Aufsichtfläche farblos ist und eine transparente Mischung auf Basis weichmacherhaltigem Polyvinylacetal ohne Perylenpigmente enthält.Interlayer film according to claim 1, characterized in that the interlayer film has colored and colorless sections, in which - 1 to 80% of the surface colored is and a mixture of plasticized polyvinyl acetal, perylene pigments and UV absorber contains and - 99 to 20% the surface is colorless and a transparent mixture based on plasticized polyvinyl acetal without perylene pigments contains. Zwischenschichtfolie nach Anspruch 1 oder 2, dadurch gekennzeichnet, dass die Zwischenschichtfolie oder die farbigen Abschnitte der Zwischenschichtfolie eine Differenztransparenz ΔD der Transparenz für NIR-Strahlung bei 880 nm abzüglich der Transparenz für Sonnenlichtstahlung TL bei 380–780 nm von mindestens 20% aufweisen.Interlayer film according to claim 1 or 2, characterized characterized in that the interlayer film or the colored Sections of the interlayer film a differential transparency .DELTA.D the transparency for NIR radiation at 880 nm minus Transparency for Sunlighting TL at 380-780 nm of at least 20%. Zwischenschichtfolie nach einem der Ansprüche 1 bis 3, dadurch gekennzeichnet, dass als Perylenpigmente N,N'-Dimethylperylendicarbonsäurediimid (MPTCDI) oder Perylentetracarbonsäuredianhydrid (PTCDA) eingesetzt werden.Interlayer film according to one of the claims 1 to 3, characterized in that as perylene P N, N'-Dimethylperylendicarbonsäurediimid (MPTCDI) or perylenetetracarboxylic dianhydride (PTCDA) be used. Zwischenschichtfolie nach einem der Ansprüche 1 bis 4, dadurch gekennzeichnet, dass als Polyvinylacetal unvernetztes oder vernetztes Polyvinylbutyral (PVB) oder durch Teilacetalisierung von hydrolysierten Vinylacetat/Ethylen-Copolymeren gewonnene Polymere eingesetzt werden.Interlayer film according to one of the claims 1 to 4, characterized in that as polyvinyl acetal uncrosslinked or cross-linked polyvinyl butyral (PVB) or by partial acetalization polymers derived from hydrolyzed vinyl acetate / ethylene copolymers be used. Zwischenschichtfolie nach einem der Ansprüche 1 bis 5, dadurch gekennzeichnet, dass als Weichmacher mindestens einer Verbindung aus der Gruppe Di-2-ethylhexylsebacat, Di-2-ethylhexyladipat (DOA), Di-2-ethylhexylphthalat (DOP), Dihexyladipat (DHA), Dibutylsebacat (DBS), Di-2-butoxyethylsebacat (DBES), Triethylenglykol-bis-2-ethylhexanoat, Triethylenglykol-bis-n-heptanoat 3G7, Tetraethylenglykol-bis-n-heptanoat (4G7), Di-2-butoxyethyladipat (DBEA), Di-2-butoxyethoxyethyladipat (DBEEA) eingesetzt wirdInterlayer film according to one of the claims 1 to 5, characterized in that at least as plasticizer a compound from the group di-2-ethylhexyl sebacate, di-2-ethylhexyl adipate (DOA), di-2-ethylhexyl phthalate (DOP), dihexyl adipate (DHA), dibutyl sebacate (DBS), di-2-butoxyethyl sebacate (DBES), triethylene glycol bis-2-ethylhexanoate, Triethylene glycol bis-n-heptanoate 3G7, tetraethylene glycol bis-n-heptanoate (4G7), di-2-butoxyethyl adipate (DBEA), di-2-butoxyethoxyethyl adipate (DBEEA) is used Zwischenschichtfolie nach einem der Ansprüche 1 bis 6, dadurch gekennzeichnet, dass als UV-Absorber Amine, sterisch gehinderte Amine (HALS-Stabilisatoren), Benzotriazolderivate oder Organophosphite eingesetzt werden.Interlayer film according to one of the claims 1 to 6, characterized in that as UV absorber amines, steric hindered amines (HALS stabilizers), benzotriazole derivatives or Organophosphites are used. Verbundverglasungen aus mindestens zwei Glasscheiben mit mindestens einer zwischengelegten Zwischenschichtfolie nach einem der Ansprüche 1 bis 7.Laminated glazing of at least two glass panes with at least one intermediate layer film interposed one of claims 1 to 7. Windschutzscheiben für Kraftfahrzeuge oder Flugzeuge aus mindestens zwei Glasscheiben mit mindestens einer zwischengelegten Zwischenschichtfolie nach einem der Ansprüche 1 bis 7.Windshields for motor vehicles or Aircraft of at least two panes of glass with at least one intermediate layered film according to one of the claims 1 to 7.
DE200810000685 2008-03-14 2008-03-14 Completely or partially colored interlayer film for laminated glazings, comprises plasticizer-containing polyvinyl acetal, perylene pigments, UV-absorber, and colored and colorless sections Withdrawn DE102008000685A1 (en)

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EP3604250A4 (en) * 2017-03-31 2021-01-06 Sekisui Chemical Co., Ltd. Thermoplastic resin film and glass plate-containing laminate
US11084254B2 (en) * 2017-06-07 2021-08-10 Sekisui Chemical Co., Ltd. Interlayer for laminated glass, and laminated glass
EP3912807A1 (en) 2020-05-19 2021-11-24 Kuraray Europe GmbH Printed interlayer films for laminated glazing with improved nir transparency
US11376819B2 (en) 2017-06-07 2022-07-05 Sekisui Chemical Co., Ltd. Interlayer for laminated glass, and laminated glass
EP4042185A1 (en) * 2019-10-11 2022-08-17 AGC Glass Europe Lidar detection device provided with a laminated protective layer
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CN116925488A (en) * 2017-03-31 2023-10-24 积水化学工业株式会社 Thermoplastic resin film and laminate comprising glass plate
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