DE102007056525A1 - Polyoxyalkylenamine for improved perfume yield - Google Patents

Abstract

The present invention relates to a textile or surface treatment agent containing at least one fragrance and at least one particular polyoxyalkyleneamine. The invention also relates to the use of the textile or surface treatment agents and a process for their preparation.

Description

The The present invention relates to a textile or surface treatment agent, containing at least one perfume and at least one particular Polyoxyalkylene. The invention also relates to the use of Textile or surface treatment agent and a method for their production.

textile and surface treatment agents usually contain fragrances, which give the agents a pleasant and fresh smell. The fragrances, both synthetic and natural Most of the time the kind of scent can be masked the other content levels in the media. Cosmetics, soaps, sanitary articles, Textile and surface treatment agents and other products are therefore perfumed so that they enter the consumer create a pleasant and clean sense of smell. In the area Detergents are particularly important ingredients of the fragrances Composition. The laundry should be both wet and dry have a pleasant and fresh fragrance even when dry.

Therefore it is expedient that fragrances a good Aufziehvermögen have on the fiber and stick to it, then to Releasing the fragrances again, so that the laundry over a longer period gives a pleasant smell.

The Demands on fragrances are therefore quite high. The fundamental problem with the use of fragrances is that fragrances volatile substances are. This property, however, also causes its scent effect.

you is therefore the use of fragrances in textile and surface treatment agents to challenge these volatile perfumes to stabilize long enough so that they are not all within the shortest possible time Vaporizing time and no more smell effect. The perfumes should evaporate controlled while a long-lasting and effect as constant as possible perfume effect.

Farther problematic is the fact that the scent of a Perfumes changed over time because of the Perfumes that give the fresh and light notes of the perfume evaporate faster due to their high vapor pressure the fragrances that represent the heart and base notes.

in the The prior art already has some suggestions To modify fragrances so that they are controlled via to be released for a longer period of time.

For example Fragrances are applied to substrates, encapsulated or incorporated into compounds to provide controlled perfume release to achieve.

A Another variant is fragrances to other molecules chemically bind.

The Binding between perfume and molecule is subsequently z. B. cleaved hydrolytically, whereby the fragrance then delayed is released again. The esterification of perfume alcohols is an example of such a chemical modification of perfume molecules. Such compounds are in the state the technique often with profragrances, pro-accords and the like designated. There is a broad state of the art to the same different proposals.

So are in the U.S. Patent 6,861,402 Pro-Fragrances containing a fragrance aldehyde or a fragrance ketone bound in the form of an oxazolidine described. In this case, for example, N-benzene is reacted with a perfume to give a monocyclic oxazolidine

DE-A-1 133 847 For example, the use of the condensation products of aldehydes and ketones with oxiamines in perfumery. For this, the aldehydes and ketones are reacted with ethanolamine or diethanolamine

In the aforementioned patents is trying the controlled Fragrance release over a longer period of time through the concept of a precursor in the form of so-called profragrances or Pro-accords to solve.

The Profragrances, however, are quite elaborate to synthesize and it is difficult the cleavage kinetics of the substances described therein to control, so that the release of fragrances is still right done early.

task The present invention was therefore to provide a textile or surface treatment agent which is characterized by characterized by a prolonged fragrance sensation in the consumer, without the fragrances used in advance in a chemically complex Procedures are modified.

Surprisingly It has now been found that the present task by providing a textile or surface treatment agent solved can be, in addition to at least one perfume also certain Contains polyoxyalkyleneamines.

Without to be bound by a certain theory, it can be assumed be that interaction between the polyoxyalkyleneamines and the fragrances occurs. This interaction leads to a delayed release of the fragrances, by in interaction with the polyoxyalkyleneamines according to the invention, better on the respective surfaces raise and / or better adhered to the surfaces mentioned.

in der
R für H und/oder CH₃ und
A für H, einen Alkylrest mit 1 bis 6 C-Atomen oder H₂NCH(CH₃)CH₂-* steht,
x eine ganze oder gebrochene Zahl zwischen 3 und 300 bedeutet und das genannte Polyoxyalkylenamin mindestens eine Wiederholungseinheit mit R = CH₃ umfasst.The present invention therefore relates to a textile or surface treatment agent containing at least one fragrance and at least one polyoxyalkyleneamine of the general formula (I),

in the
R for H and / or CH ₃ and
A is H, an alkyl radical having 1 to 6 C atoms or H ₂ NCH (CH ₃ ) CH ₂ - *,
x is an integer or fraction between 3 and 300 and said polyoxyalkylene amine comprises at least one repeating unit with R = CH ₃ .

The fractional or integer x indicates the number of polymer building up Repeating units or building blocks. In this case, x is preferably a whole or fractional number between 4 and 100 and especially preferably between 5 and 50.

Under The said surfaces may be both understood keratinic fibers as well as hard surfaces become. Hard surfaces are, for example, without themselves confine it to dishes, glass, ceramics, plastic and / or metal.

• – zum Waschen von Textilien,
• – zur lang anhaltenden Beduftung von Textilien, vorzugsweise während des maschinellen Wasch- und/oder Trocknungsprozesses,
• – zur verbesserten Duftstoffausbeute auf Textilien und/oder
• – zur Behandlung und/oder Reinigung von Oberflächen, insbesondere von harten Oberflächen oder keratinischen Fasern.

Further objects of the present invention are the use of the textile or surface treatment agent

• - for washing textiles,
• For the long-lasting scenting of textiles, preferably during the automatic washing and / or drying process,
• For improved perfume yield on textiles and / or
• For the treatment and / or cleaning of surfaces, in particular of hard surfaces or keratinic fibers.

One Another object of the present invention is a method for the long-lasting scenting of textiles, in which an inventive Agent applied to the surface of textiles to be scented is, preferably during the automatic washing and / or Drying process.

in der
R für H und/oder CH₃ und
A für H, einen Alkylrest mit 1 bis 6 C-Atomen oder H₂NCH(CH₃)CH₂-* steht,
x eine ganze oder gebrochene Zahl zwischen 3 und 300 bedeutet und das genannte Polyoxyalkylenamin mindestens eine Wiederholungseinheit mit R = CH₃ umfasst, miteinander vermischt werden.Likewise provided by the present invention is a process for preparing the textile or surface treatment agent according to the invention by reacting at least one perfume and at least one polyoxyalkyleneamine of the general formula (I)

in the
R for H and / or CH ₃ and
A is H, an alkyl radical having 1 to 6 C atoms or H ₂ NCH (CH ₃ ) CH ₂ - *,
x is an integer or fraction between 3 and 300, and said polyoxyalkylene amine comprises at least one repeat unit with R = CH ₃ , are mixed together.

The Chemical structure of the polyoxyalkyleneamine according to the invention is highly advantageous for the described Properties of the textile or textile according to the invention Surface treatment agent responsible.

In addition to at least one primary amino group, which depending on the composition of the textile or surface treatment agent according to the invention may also be in protonated form, ie as ammonium group, the polyoxyalkyleneamine according to the invention is characterized in that in the polymer backbone at least one repeat unit based on propylene oxide (R = CH ₃ in formula (I)) is present. It is known that the hydrophilicity or hydrophobicity of polyethers can be easily controlled, for example, by the ratio of ethylene oxide-based units (R = H in formula (I)) (EO) to propylene oxide-based units (PO). Without being bound by any particular theory, it has been found in the context of this invention that the presence of at least one PO unit positively influences the properties of the polyoxyalkyleneamine according to the invention with respect to the interaction with the at least one perfume.

In a particularly preferred embodiment of the invention, the ratio of the repeat units with R = CH ₃ (PO) to repeat units with R = H (EO) in the polyoxyalkyleneamine according to the invention is between 30: 1 and 1:30, preferably between 10: 1 and 1:10 and most preferably between 6: 1 and 1: 6. In the abovementioned ranges, the hydrophilicity or hydrophobicity of the polyoxyalkyleneamine according to the invention is effectively changed, as a result of which an improved specific interaction between the polyoxyalkyleneamine according to the invention and the at least one perfume used in each case is obtained.

An improvement of the specific interaction is also achieved via the change in the molecular weight of the polyoxyalkyleneamine according to the invention. In a preferred embodiment of the invention, the weight-average molecular weight "M _w " of the polyoxyalkyleneamine according to formula (I) is in the range from 220 to 10 000 g / mol, preferably in the range from 380 to 2200 g / mol. The number average molecular weight is determined by gel permeation chromatography (GPC) with polystyrene as standard.

In further preferred embodiments of the invention, the polyoxyalkyleneamine according to the invention consists exclusively of repeat units with R =CH ₃ and / or A in the polyoxyalkyleneamine according to the invention is a methyl or ethyl radical or a H ₂ NCH (CH ₃ ) CH ₂ - radical.

invention Textile or surface treatment agents containing a mixture several different polyoxyalkyleneamines according to the invention are also preferred.

The polyoxyalkyleneamine according to the invention are commercially available and are prepared by known methods by the reaction of polyoxyalkylene alcohols recovered with ammonia under pressure.

The Polyoxyalkylene alcohols are prepared by addition of an alkylene oxide, essentially propylene oxide, ethylene oxide or a mixture of Both, using a conventional method to a Compound containing one or more active hydrogen atoms or by polymerization of alkylene oxides.

When Compounds containing one or more active hydrogen atoms, For example, monoalcohols such as methanol can be ethanol, Isopropanol and / or butanol, but especially methanol or ethanol be used.

The Further conversion to the amines is carried out by methods known per se by aminolysis of the free hydroxyl groups or their esters, in particular the sulfuric acid ester. For higher alcohols the replacement of the OH group takes place against the amino group means homogeneous, but especially heterogeneous catalysis on fixed contacts.

Extensive literature references are available on the influence of temperature or pressure and excess ammonia, as well as the required residence times (see Houben-Weyl, Methods of Organic Chemistry, Georg Thieme Verlag, Stuttgart 1957, Volume 11/1 pp. 108ff and GB-PS 384 714 . U.S. Patent 2,017,051 . U.S. Patent 2,078,922 ).

Particularly preferred polyoxyalkyleneamines according to the invention are available from Huntsman Corp. Texas ^® under the trade name Jeffamine ^® M-600, Jeffamine M-1000, Jeffamine ^® M-2005, Jeffamine ^® M-2070, Jeffamine ^® D-230, Jeffamine ^® D-400, Jeffamine ^® D-2000, Jeffamine ^® D-4000, Jeffamine ^® HK-511, Jeffamine ^® ED-600 and / or Jeffamine ^® ED-2003 sold.

In Another preferred embodiment the total amount of the polyoxyalkyleneamine according to the invention between 0.1 and 5% by weight, preferably between 0.2 and 3% by weight, particularly preferably between 0.5 and 2 wt .-%, each based on the total amount of textile or surface treatment agent.

Of the at least one perfume (perfume oil) that the textile or surface treatment agents according to the invention contains no restrictions. Thus, as at least one fragrance, individual fragrance compounds, both synthetic or natural compounds of the type esters, ethers, aldehydes, ketones, alcohols, hydrocarbons, Acids, carbonates, aromatic hydrocarbons, aliphatic hydrocarbons, saturated and / or unsaturated Hydrocarbons and mixtures thereof can be used.

When Duftaldehyde or Duftketone can all usual Fragrance aldehydes and fragrance ketones are used, which are typically used to bring about a pleasant scent sensation become. Suitable fragrance aldehydes and fragrance ketones are those skilled in the art well known.

The Fragrance ketones may include all ketones that are desired Give fragrance or a sense of freshness. It can also mixtures of different ketones can be used. For example, can the ketone can be selected from the group consisting of Buccoxim, Iso jasmon, Methyl beta naphthyl ketone, Musk indanon, Tonalid / Musk Plus, Alpha Damascon, Beta Damascon, Delta Damascon, Iso-Damascon, Damascenon, Damarose, Methyl dihydrojasmonate, Menthon, Carvon, Camphor, Fenchon, Alpha-Ion, Beta-Ionone, Dihydro-Beta-Ionone, Gamma-methyl so called Ionon, Fleuramon, Dihydrojasmon, Cis-Jasmon, Iso-E-Super, methyl cedryl ketone or methyl cedrylon, acetophenone, Methyl acetophenone, para-methoxy acetophenone, methyl beta-naphthyl ketone, Benzyl acetone, benzophenone, para-hydroxyphenyl butanone, Celery ketone or livescone, 6-isopropyldecahydro-2-naphthone, dimethyloctenone, Freskomenth, 4- (I-ethoxyvinyl) -3,3,5,5-tetramethylcyclohexanone, Methyl heptenone, 2- (2- (4-methyl-3-cyclohexen-1-yl) propyl) cyclopentanone, 1- (p-menthene-6 (2) -yl) -1-propanone, 4- (4-hydroxy-3-methoxyphenyl) -2-butanone, 2-acetyl-3,3-dimethyl-norbornane, 6,7-dihydro-1,1,2,3,3-pentamethyl-4 (5H) -indanone, 4-Damascol, Dulcinyl or Cassion, Gelson, Hexalon, Isocyclone E, Methyl-cyclocitron, methyl-lavender-ketone, Orivon, para-tert-butyl-cyclohexanone, Verdon, Delphon, Muscone, Neobutenon, Plicaton, Velouton, 2,4,4,7-tetramethyl-oct-6-en-3-one, Tetrameran, hedione and mixtures thereof. Preferred may the ketones are selected from Alpha Damascon, Delta Damascon, Iso Damascon, Carvone, gamma-methyl-ionone, Iso-E-Super, 2,4,4,7-tetramethyl-oct-6-en-3-one, Benzylacetone, beta damascone, damascenone, methyldihydrojasmonate, Methylcedrylon, hedione and mixtures thereof.

Suitable fragrance aldehydes may be any aldehydes which, in accordance with the fragrance ketones, impart a desired fragrance or sensation of freshness. In turn, they may be individual aldehydes or aldehyde mixtures. Suitable aldehydes are, for example, Melonal, Triplal, Ligustral, Adoxal, Anisaldehyde, Cymal, Ethylvanillin, Florhydral, Floralozon, Helional, Heliotropin, Hydroxycitronellal, Koavon, Laurinaldehyde, Canthoxal, Lyral, Lilial, Adoxal, Anisaldehyde, Cumal Methyl-nonyl-acetaldehyde, Citronellal , Citronellyloxy-acetaldehyde, Cyclamenaldehyde, Bourgeonal, p, t-Bucinal, Phenylacetaldehyde, Undecylenaldehyde, Vanillin; 2,6,10-trimethyl-9-undecenal, 3-dodecene-I-al, alpha-n-amylcinnamaldehyde, 4-methoxybenzaldehyde, benzaldehyde, 3- (4-tert-butylphenyl) -propanal, 2-methyl-3- (para-methoxyphenylpropanal), 2-methyl-4- (2,6,6-trimethyl-2 (1) -cyclohexen-1-yl) butanal, 3-phenyl-2-propenal, cis- / trans-3,7 Dimethyl 2,6-octadiene-1-al, 3,7-dimethyl-6-octene-1-al, [(3,7-dimethyl-6-octenyl) oxy] acetaldehyde, 4-isopropylbenzyaldehyde, 1,2 , 3,4,5,6,7,8-octahydro-8,8-dimethyl-2-naphthaldehyde, 2,4-dimethyl-3-cyclohexene-1-carboxyaldehyde, 2-methyl-3- (isopropylphenyl) propanal, Decyl aldehyde, 2,6-dimethyl-5-heptenal; 4- (tricyclo [5.2.1.0.2,6)] decylidene-8) -butanal; Octahydro-4,7-methano-IH-indenecarboxaldehyd; 3-ethoxy-4-hydroxybenzaldehyde, para-ethyl-alpha, alpha-dimethylhydrocinnamaldehyde, alpha-methyl-3,4- (methylenedioxy) hydrocinnamaldehyde, 3,4-methylenedioxybenzaldehyde, alpha-n-hexylcinnamaldehyde, m-cymene-7-carboxaldehyde , alpha-methylphenylacetaldehyde, 7-hydroxy-3,7-dimethyl-octanal, undecenal, 2,4,6-trimethyl-3-cyclohexene-1-carboxaldehyde, 4- (3) (4-methyl-3-pentenyl) -3 cyclohexene-carboxaldehyde, 1-dodecanal, 2,4-dimethylcyclohexene-3-carboxaldehyde, 4- (4-hydroxy-4-methylpentyl) -3-cyclohexene-1-carboxaldehyde, 7-methoxy-3,7-dimethyloctane 1-al, 2-methyl undecanal, 2-methyl decanal, 1-nonanal, 1-octanal, 2,6,10-trimethyl-5,9-undecadienal, 2-methyl-3- (4-tert-butyl) propanal, 3- (4-ethylphenyl) -2,2-dimethylpropanal, 3- (4-methoxyphenyl) -2-methylpropanal, methylnonylacetaldehyde, 2-phenylpropan-1-al, 3-phenylprop-2-en-1-al, 3 Phenyl-2-pentylprop-2-en-1-al, 3-phenyl-2-hexylprop-2-enal, 3- (4-isopropylphenyl) -2-methylpropan-1-al, 3- (4-ethylphenyl) - 2,2-dimethylpropan-1-al, 3- (4-tert-butylphenyl) -2-me ethyl-propanal, 3- (3,4-methylenedioxyphenyl) -2-methylpropan-1-al, 3- (4-ethylphenyl) -2,2-dimethylpropanal, 3- (3-isopropylphenyl) butan-1-al, 2 , 6-dimethylhept-5-en-1-al, dihydrocinnamaldehyde, 1-methyl-4- (4-methyl-3-pentenyl) -3-cyclohexene-1-carboxaldehyde, 5 or 6 methoxyhexahydro-4,7-methanoindan 1 or 2-carboxaldehyde, 3,7-dimethyloctan-1-al, 1-undecanal, 10-undecene-1-al, 4-hydroxy-3-methoxybenzaldehyde, 1-methyl-3- (4-methylpentyl) -3- cyclohexenecarboxyaldehyde, 7-hydroxy-3,7-dimethyl-octanal; trans-4-decenal, 2,6-nonadienal, para-tolylacetaldehyde; 4-methylphenylacetaldehyde, 2-methyl-4- (2,6,6-trimethyl-1-cyclohexen-1-yl) -2-butenal, ortho-methoxycinnamaldehyde, 3,5,6-trimethyl-3-cyclohexenecarboxaldehyde, 3, 7-dimethyl-2-methylene-6-octenal, phenoxyacetaldehyde; 5,9-dimethyl-4,8-decadienal, peony-aldehyde (6,10-dimethyl-3-oxa-5,9-undecadiene-1-al), hexahydro-4,7-methanoindan-1-carboxaldehyde, octanal, 2-methyl octanal, alpha-methyl-4- (1-methylethyl) benzene acetaldehyde, 6,6-dimethyl-2-norpinene-2-propionaldehyde, para methyl phenoxyacetaldehyde, 2-methyl-3-phenyl-2-propene-1 -al, 3,5,5-trimethylhexanal, hexahydro-8,8-dimethyl-2-naphthaldehyde, 3-propyl-bicyclo [2.2.1] -hept-5-ene-2-carbaldehyde, 9-decenal, 3 Methyl 5-phenyl-1-pentanal, methylnonylacetaldehyde, 1-p-menthene-q-carboxaldehyde, citral or mixtures thereof, lilial citral, 1-decanal, n-undecanal, n-dodecanal, florhydral, 2,4-dimethyl 3-cyclohexene-1-carboxaldehyde 4-methoxybenzaldehydes, 3-methoxy-4-hydroxybenzaldehydes, 3-ethoxy-4-hydroxybenzaldehydes, 3,4-methylenedioxybenzaldehyde and 3,4-dimethoxybenzaldehyde, and mixtures thereof.

As exemplified above, the Duftaldehyde and Duftketone an aliphatic, cycloaliphatic, aromatic, ethylenically unsaturated structure or a Combination of these structures. It can also further heteroatoms or polycyclic structures are present. The Structures may contain suitable substituents such as hydroxyl or amino groups.

For other suitable fragrances selected from aldehydes and ketones, is based on Steffen Arctander Published 1960 and 1969 respectively, Reprinted 2000 ISBN: Aroma Chemicals Vol. 1: 0-931710-37-5, Aroma Chemicals Vol. 2: 0-931710-38-3.

suitable Fragrance compounds of the ester type are, for example, benzyl acetate, Phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, Dimethylbenzylcarbinylacetate (DMBCA), phenylethylacetate, benzylacetate, Ethylmethylphenylglycinate, allylcyclohexylpropionate, styrallylpropionate, Benzyl salicylate, cyclohexyl salicylate, floramate, melusate and jasmacycate.

fragrance compounds the type of hydrocarbons are z. B. terpenes such as limonene and Pinene.

suitable Fragrances of the ether type are, for example, benzyl ethyl ether and AMBROXAN.RTM. Suitable fragrance alcohols are, for example, 10-undecen-1-ol, 2,6-dimethylheptan-2-ol, 2-methylbutanol, 2-methylpentanol, 2-phenoxyethanol, 2-phenylpropanol, 2-tert-butylcyclohexanol, 3,5,5-trimethylcyclohexanol, 3-hexanol, 3-methyl-5-phenylpentanol, 3-octanol, 1-octen-3-ol, 3-phenylpropanol, 4-heptenol, 4-isopropylcyclohexanol, 4-tert-butycyclohexanol, 6,8-dimethyl-2-nonanol, 6-nonen-1-ol, 9-decen-1-ol, alpha-methylbenzylalcohol, alpha-terpineol, Amyl salicylate, benzyl alcohol, benzyl salicylate, beta-terpineol, butyl salicylate, Citronellol, cyclohexyl salicylate, decanol, dihydromyrcenol, dimethylbenzylcarbinol, Dimethylheptanol, dimethyloctanol, ethylsalicylate, ethylvanilin, Anethole, eugenol, geraniol, heptanol, hexyl salicylate, isoborneol, Isoeugenol, isopulegol, linalool, menthol, myrtenol, n-hexanol, Nero, nonanol, octanol, para-menthane-7-ol, phenylethyl alcohol, phenol, Phenyl salicylate, tetrahydrogeraniol, tetrahydrolinalool, thymol, trans-2-cis-6-nonadienol, trans-2-nonen-1-ol, trans-2-octenol, undecanol, Vanillin, cinnamyl alcohol, wherein, if more fragrance alcohols present are selected independently of each other could be.

fragrances or perfume oils can also be natural Fragrance mixtures are as available from plant sources are, for. Pine, citrus, jasmine, patchouly, rose or ylang-ylang oil. Also suitable are muscatel sage oil, chamomile oil, Clove oil, lemon balm oil, mint oil, cinnamon leaf oil, Lime blossom oil, juniper berry oil, vetiver oil, Olibanum oil, galbanum oil and labdanum oil and orange blossom oil, neroli oil, orange peel oil and sandalwood oil.

Essential oils such as angelica root oil, aniseed oil, arnica blossom oil, basil oil, bay oil, champa blossom oil, fir pine oil, pinecone oil, elemi oil, eucalyptus oil, fennel oil, spruce needle oil, galbanum oil, geranium oil, ginger grass oil, guaiac wood oil, guriuri balm oil, helichrysum oil, hol oil, ginger oil, iris oil, cajeput oil, calamus oil , Chamomile oil, camphor oil, kanga oil, cardamom oil, cassia oil, pine oil, copaiba balsam, coriander oil, spearmint oil, caraway oil, cumin oil, lavender oil, lemongrass oil, lime oil, tangerine oil, lemon balm oil, musk kernel oil, myrrh oil, clove oil, neroli oil, niaouli oil, olibanum oil, origanum oil, palmarosa oil, patchouli oil , Peruvian balsam oil, Petitgrain oil, Pepper oil, Peppermint oil, Pimento oil, Pine oil, Rose oil, Rosemary oil, Sandalwood oil, Celery oil, Spik oil, Star aniseed oil, Turpentine oil, Thuja oil, Thyme oil, Verbena oil, Vetiver oil, Juniper berry oil, Vermouth oil, Wintergreen oil, ylang-ylang oil, hyssop oil, cinnamon oil, cinnamon oil, lemon oil, lemon oil and cypress oil are all possible.

The Total amount of the at least one perfume in the invention Textile or surface treatment agent preferably between 0.01 and 5 wt .-%, particularly preferably between 0.1 and 3 wt .-%, and most preferably between 0.5 and 2 wt .-% based on the total amount of the composition.

Prefers are mixtures of different fragrances (from the different above-mentioned fragrance classes), which together have an appealing Create a fragrance.

In In this case, the total amount of the at least one perfume the amount of all fragrances in the mixture related to the total amount of the agent.

In a highly preferred embodiment of Invention is the textile or surface treatment agent to a textile treatment agent in the form of a detergent, fabric softener, softening Detergent or washing aid, these preferably additionally at least one surfactant selected from the group consisting from anionic, cationic, nonionic, zwitterionic, amphoteric Containing surfactants or mixtures.

The Textile treatment agent may be solid or liquid, wherein liquid detergents are preferred.

For the case that the inventive agent a Detergent is, it is preferred that there is at least one surfactant selected from the group consisting of anionic, cationic, nonionic, zwitterionic and amphoteric surfactants.

For the case that the inventive agent a softening detergent ("2in1"), it is preferred that it is a plasticizing component and at least one surfactant selected from the group consisting of anionic, nonionic, zwitterionic and amphoteric surfactants.

Means for washing are used for selective pretreatment of the laundry before washing used for stains or heavy soiling. To the washing aids include, for example, pretreatment, soaking, Decolorizer and stain remover.

For the case that the inventive agent a Softener is, it is preferred that it is a softening Component contains.

softener are preferred as agents according to the invention, since only in the last step of a conventional textile washing process, the rinse, come into contact with the textiles and thus the largest possible amount of the fragrances The textile can raise without the risk that the Fragrances removed in subsequent steps again become.

It is very particularly preferred that the plasticizing component an alkylated, quaternary ammonium compound, wherein interrupted at least one alkyl chain by an ester or amido group is.

The softening component includes, for example, quaternary Ammonium compounds such as monoalk (en) yltrimethylammonium compounds, Dialk (en) yldimethylammonium compounds, mono-, di- or triesters of fatty acids with alkanolamines.

wobei in (II) R für einen acyclischen Alkylrest mit 12 bis 24 Kohlenstoffatomen, R¹ für einen gesättigten C₁-C₄ Alkyl- oder Hydroxyalkylrest steht, R² und R³ entweder gleich R oder R¹ sind oder für einen aromatischen Rest stehen. X^– steht entweder für ein Halogenid-, Methosulfat-, Methophosphat- oder Phosphation sowie Mischungen aus diesen. Beispiele für kationische Verbindungen der Formel (II) sind Monotalgtrimethylammoniumchlorid, Monostearyltrimethylammoniumchlorid, Didecyldimethylammoniumchlorid, Ditalgdimethylammoniumchlorid oder Dihexadecylammoniumchlorid.Suitable examples of quaternary ammonium compounds are shown, for example, in formulas (II) and (III):

wherein in (II) R is an acyclic alkyl radical having 12 to 24 carbon atoms, R ^{1 is} a saturated C ₁ -C ₄ alkyl or hydroxyalkyl radical, R ² and R ^{3 are} either R or R ¹ , or an aromatic radical stand. X ^- is either a halide, methosulfate, methophosphate or phosphate ion and mixtures thereof. Examples of cationic compounds of the formula (II) are monotaltrimethylammonium chloride, monostearyltrimethylammonium chloride, didecyldimethylammonium chloride, ditallowdimethylammonium chloride or dihexadecylammonium chloride.

Compounds of formula (III), (IV) and (V) are so-called ester quats. Esterquats are characterized by excellent biodegradability. In formula (III) R ^{4 is} an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds and / or optionally with substituents; R ⁵ is H, OH or O (CO) R ⁷ , R ⁶ is, independently of R ^5, H, OH or O (CO) R ⁸ , where R ⁷ and R ⁸ are each independently an aliphatic alk (ene) ylrest having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. m, n and p can each independently be 1, 2 or 3. X ^- may be either a halide, methosulfate, methophosphate or phosphate ion as well as mixtures of these anions. Preference is given to compounds in which R ^{5 represents} the group O (CO) R ⁷ . Particular preference is given to compounds in which R ^{5 is} the group O (CO) R ⁷ and R ⁴ and R ^{7 are} alk (en) yl radicals having 16 to 18 carbon atoms. Particularly preferred are compounds in which R ^{6 is} also OH. Examples of compounds of the formula (I) are methyl N- (2-hydroxyethyl) -N, N-di (tallow acyloxyethyl) ammonium methosulfate, bis (palmitoyloxyethyl) hydroxyethyl methyl ammonium methosulfate, 1,2-bis - [tallowloxy] -3-trimethylammonium propane chloride or methyl N, N-bis (stearoyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulphate.

If quaternized compounds of the formula (III) are used which have unsaturated alkyl chains, the acyl groups are preferred whose corresponding fatty acids have an iodine number between 1 and 100, preferably between 5 and 80, more preferably between 10 and 60 and in particular between 15 and 45 and which have a cis / trans isomer ratio (in% by weight) of greater than 30:70, preferably greater than 50:50 and in particular equal to or greater than 60:40. Commercial examples are sold by Stepan under the tradename Stepantex ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under Dehyquart ^® Cognis products, known under Rewoquat ^® products from Degussa or those known under Tetranyl ^® products of Kao. Further preferred compounds are the diesterquats corresponding to formula (IV) which are obtainable under the name Rewoquat ^® 3099 W 222 LM or CR.

R ²¹ and R ²² are each independently an aliphatic radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds.

Instead of the ester group O (CO) R, where R is a long-chain Alk (en) ylrest can, softening compounds can be used, which have the following groups: RO (CO), N (CO) R or RN (CO), of which N (CO) R groups are preferred are.

wobei R⁹ für H oder einen gesättigten Alkylrest mit 1 bis 4 Kohlenstoffatomen, R¹⁰ und R¹¹ unabhängig voneinander jeweils für einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen, R¹⁰ alternativ auch für O(CO)R²⁰ stehen kann, wobei R²⁰ einen aliphatischen, gesättigten oder ungesättigten Alkylrest mit 12 bis 18 Kohlenstoffatomen bedeutet, und Z eine NH-Gruppe oder Sauerstoff bedeutet und X^– ein Anion ist. q kann ganzzahlige Werte zwischen 1 und 4 annehmen.In addition to the quaternary compounds described above, it is also possible to use other compounds as softening components, for example quaternary imidazolinium compounds of the formula (V)

where R ^{9 is} H or a saturated alkyl radical having 1 to 4 carbon atoms, R ¹⁰ and R ¹¹ are each independently an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, R ^{10 may} alternatively be O (CO) R ²⁰ wherein R ^{20 is} an aliphatic, saturated or unsaturated alkyl radical having 12 to 18 carbon atoms, and Z is an NH group or oxygen and X ^{- is} an anion. q can take integer values between 1 and 4.

wobei R¹², R¹³ und R¹⁴ unabhängig voneinander für eine C_1-4-Alkyl-, Alkenyl- oder Hydroxyalkylgruppe steht, R¹⁵ und R¹⁶ jeweils unabhängig ausgewählt eine C_8-28-Alkylgruppe darstellt, X^– ein Anion ist und r eine Zahl zwischen 0 und 5 ist. Ein bevorzugtes Beispiel einer kationischen Abscheidungshilfe gemäß Formel (VI) ist 2,3-Bis[talgacyloxy]-3-trimethylammoniumpropanchlorid.Further particularly preferred plasticizing compounds are described by formula (VI),

wherein R ¹² , R ¹³ and R ¹⁴ independently represent a C _1-4 alkyl, alkenyl or hydroxyalkyl group, each of R ¹⁵ and R ¹⁶ independently represents a C _8-28 alkyl group, X ^{- is} an anion and r is a number between 0 and 5. A preferred example of a cationic deposition aid according to formula (VI) is 2,3-bis [tallowacyloxy] -3-trimethylammoniumpropane chloride.

Further Softening components which can be used according to the invention provide quaternized protein hydrolysates or protonated amines represents.

Furthermore, cationic polymers are also suitable softening component. Suitable cationic polymers include the polyquaternium polymers as described in the CTFA Cosmetic Ingredient Dictionary (The Cosmetic, Toiletry and Fragrance, Inc., 1997), in particular the Polyquaternium-6, Polyquaternium-7, Polyquaternium, also referred to as Merquats. 10 polymers (Polymer JR, LR and KG series from Amerchol), polyquaternium-4 copolymers such as graft copolymers having a cellulose backbone and quaternary ammonium groups attached via allyldimethylammonium chloride, cationic cellulose derivatives such as cationic guar such as guar hydroxypropyltriammonium chloride, and similar quaternized guar Derivatives (eg Cosmedia Guar from Cognis or the Jaguar series from Rhodia), cationic quaternary sugar derivatives (cationic alkyl polyglucosides), e.g. , The commercial product Glucquat ^® 100, according to CTFA nomenclature a "lauryl methyl Gluceth-10 Hydroxypropyl Dimonium Chloride", copolymers of PVP and dimethylaminomethacrylate, copolymers of vinylimidazole and vinylpyrrolidone, and copolymers Aminosiliconpolymere.

Polyquaternized polymers (for example Luviquat ^® Care from BASF.), And cationic biopolymers based on chitin and derivatives thereof, for example, under the trade designation chitosan ^® (manufacturer: Cognis) polymer obtainable.

Some said cationic polymers additionally have skin and / or textile care properties.

R¹⁷ kann ein aliphatischer Alk(en)ylrest mit 12 bis 22 Kohlenstoffatomen mit 0, 1,2 oder 3 Doppelbindungen sein. s kann Werte zwischen 0 und 5 annehmen. R¹⁸ und R¹⁹ stehen unabhängig voneinander jeweils für H, C_1-4-Alkyl oder Hydroxyalkyl und X^– ist ein Anion.It is likewise possible to use compounds of the formula (VII)

R ¹⁷ may be an aliphatic alk (en) yl radical having 12 to 22 carbon atoms with 0, 1, 2 or 3 double bonds. s can take values between 0 and 5. R ¹⁸ and R ¹⁹ are each independently H, C _1-4 alkyl or hydroxyalkyl and X ^- is an anion.

Further Suitable softening components include protonated or quaternized Polyamines.

Especially preferred plasticizing components are alkylated quaternary Ammonium compounds, of which at least one alkyl chain an ester group and / or amido group is interrupted. Most notably preferred are N-methyl-N- (2-hydroxyethyl) -N, N- (ditalgacyloxyethyl) ammonium methosulfate or bis (palmitoyloxyethyl) hydroxyethyl methyl ammonium methosulfate.

The Composition according to the invention in the form of fabric softeners may also contain nonionic softening components, especially polyoxyalkylene glycol alkanoates, polybutylenes, long chain Fatty acids, ethoxylated fatty acid ethanolamides, Alkyl polyglucosides, in particular sorbitan mono, di- and triesters, and fatty acid esters of polycarboxylic acids.

In the fabric softeners according to the invention as agent according to the invention is the plasticizing agent Component in amounts of 0.1 to 80 wt .-%, usually 1 to 40 wt .-%, preferably 2 to 20 wt .-% and in particular 3 up to 15% by weight and the fragrance composite in amounts of from 0.1 to 20% by weight, preferably 1 to 13% by weight and in particular 2 to 8% by weight, respectively based on the total amount of the agent according to the invention, contain.

When further component may be the inventive Optionally, in the form of fabric softeners, one or contain several nonionic surfactants, where used which can also be used in detergents be used.

It it is further preferred that the agent is additional conventional Ingredients of textile or surface treatment agents contains.

So In addition, the textile treatment agents can to the surfactants and / or softening compounds further ingredients included, which are the performance and / or aesthetic Properties of the textile treatment agent further improve. in the The present invention includes preferred textile treatment agents additionally one or more substances from the group of Builders, bleaches, bleach activators, enzymes, Electrolytes, nonaqueous solvents, pH adjusters, Perfumes, perfume carriers, fluorescers, Dyes, hydrotopes, foam inhibitors, silicone oils, anti redeposition agents, optical brighteners, grayness inhibitors, shrinkage inhibitors, Anti-crease agents, color transfer inhibitors, antimicrobial Active ingredients, germicides, fungicides, antioxidants, preservatives, Corrosion inhibitors, antistatic agents, bittering agents, ironing auxiliaries, Repellents and impregnating agents, swelling and anti-sticking agents, neutral filling salts and UV absorbers.

When Builders contained in the textile treatment agents may be, in particular silicates, aluminum silicates (especially zeolites), carbonates, salts of organic di- and polycarboxylic acids and mixtures of these substances.

suitable crystalline, layered sodium silicates possess the general formula NaMSixO2x + 1 · H2O, where M is sodium or Hydrogen means x is a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x 2, 3 or 4 are. Preferred crystalline layered silicates of the formula given are those in which M stands for sodium and x the values 2 or 3. In particular, both β- and δ-sodium disilicates are Na 2 Si 2 O 5 .yH 2 O is preferred.

usable are also amorphous sodium silicates with a module Na2O: SiO2 of 1: 2 to 1: 3.3, preferably from 1: 2 to 1: 2.8 and in particular from 1: 2 to 1: 2.6, which are delay-delayed and secondary washing characteristics exhibit. The release delay opposite conventional amorphous sodium silicates can be up various ways, for example by surface treatment, Compounding, compaction / densification or overdrying be caused. In the context of this invention is under the term "amorphous" also means "X-ray amorphous". This means that the silicates in X-ray diffraction experiments do not deliver sharp X-ray reflections as they are crystalline substances are typical, but at most one or several maxima of the scattered X-rays, the one Have width of several degrees of the diffraction angle. However, it can very well even to very good builder properties lead if the silicate particles in electron diffraction experiments provide blurred or even sharp diffraction maxima. This is to interpret that the products microcrystalline areas from 10 to a few hundred nm in size, where values up to a maximum of 50 nm and in particular up to a maximum of 20 nm are preferred. Particularly preferred are compacted / compacted amorphous silicates, compounded amorphous silicates and overdried X-ray amorphous silicates.

The finely crystalline, synthetic and bound water-containing zeolite used is preferably zeolite A and / or P. As zeolite P, zeolite ^MAP® (commercial product from Crosfield) is particularly preferred. Also suitable, however, are zeolite X and mixtures of A, X and / or P. Commercially available and preferably usable in the context of the present invention is, for example, a cocrystal of zeolite X and zeolite A (about 80% by weight of zeolite X) which is sold by SASOL under the brand name VEGOBOND AX ^® and by the formula), nNa2O · (1-n) K2O · Al2O3 · (2 - 2.5) SiO2 · (3.5-5.5) H2O n = 0.90 - 1.0 can be described. The zeolite can be used as a spray-dried powder or else as undried, still moist, stabilized suspension of its preparation. In the event that the zeolite is used as a suspension, it may contain minor additions of nonionic surfactants as stabilizers, for example 1 to 3 wt .-%, based on zeolite, of ethoxylated C12-C18 fatty alcohols having 2 to 5 ethylene oxide groups, C12 C14-fatty alcohols with 4 to 5 ethylene oxide groups or ethoxylated isotridecanols. Suitable zeolites have an average particle size of less than 10 μm (volume distribution, measuring method: Counter Counter) and preferably contain 18 to 22% by weight, in particular 20 to 22 Wt .-% of bound water.

Of course it is also possible to use the generally known phosphates as builders, if such use is not for environmental reasons should be avoided. Particularly suitable are the sodium salts the orthophosphates, the pyrophosphates and in particular the tripolyphosphates.

organic Builders which may be present in the textile treatment agent include polycarboxylate polymers such as polyacrylates and acrylic acid / maleic acid copolymers, Polyaspartates and monomeric polycarboxylates such as citrates, gluconates, Succinates or malonates, which are preferably used as sodium salts.

Under the bleach-providing compounds which yield H2O2 in water have the sodium perborate tetrahydrate and the sodium perborate monohydrate special meaning. Other useful bleaching agents are, for example Sodium percarbonate, peroxypyrophosphates, citrate perhydrates as well H2O2-supplying peracid salts or peracids, such as perbenzoates, Peroxophthalates, diperazelaic acid, phthaloiminoperacid or Diperdodecanedioic.

Around when washing at temperatures of 60 ° C and below one To achieve improved bleaching action, bleach activators can be used be incorporated into the detergents and cleaners. As bleach activators may be compounds that are under perhydrolysis conditions aliphatic peroxycarboxylic acids with preferably 1 to 10 C-atoms, in particular 2 to 4 C-atoms, and / or optionally substituted perbenzoic acid, can be used. Suitable substances are the O- and / or N-acyl groups of said C atom number and / or optionally substituted benzoyl groups. Prefers are polyacylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, especially tetraacetylglycoluril (TAGU), N-acylimides, especially N-nonanoylsuccinimide (NOSI), acylated Phenolsulfonates, especially n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular Phthalic anhydride, acylated polyhydric alcohols, in particular Triacetin, ethylene glycol diacetate and 2,5-diacetoxy-2,5-dihydrofuran.

additionally to the conventional bleach activators or in their place also so-called bleach catalysts in the textile treatment agent be incorporated. These substances are bleach-enhancing transition metal salts respectively.

transition metal complexes such as Mn, Fe, Co, Ru or Mo saline complexes or carbonyl complexes. Also Mn, Fe, Co, Ru, Mo, Ti, V and Cu complexes with nitrogen-containing tripod ligands and Co, Fe, Cu and Ru ammine complexes are useful as bleach catalysts.

One Liquid textile treatment agent may be a thickener contain. The thickener may, for example, a polyacrylate thickener, Xanthan gum, gellan gum, guar gum, alginate, carrageenan, carboxymethyl cellulose, Bentonite, Wellan gum, locust bean gum, agar-agar, tragacanth, Gum arabic, pectins, polyoses, starch, dextrins, gelatin and casein. But also modified natural substances such as modified Starches and celluloses, examples being carboxymethylcellulose and other cellulose ethers, hydroxyethyl and propylcellulose as well Called Kernmehlether, can be used as a thickener become.

The polyacrylic and polymethacrylic thickeners include, for example, the high molecular weight homopolymers of acrylic acid crosslinked with a polyalkenyl polyether, in particular an allyl ether of sucrose, pentaerythritol or propylene (INCI name according to the International Dictionary of Cosmetic Ingredients of The Cosmetic, Toiletry and Fragrance Association (CTFA) ": carbomer), also referred to as carboxyvinyl polymers. Such polyacrylic acids are inter alia from the company. 3 V Sigma under the trade name Polygel ^® , z. B. Polygel DA, and from the company. BF Goodrich under the trade name Carbopol ^® available, z. Carbopol 940 (molecular weight about 4,000,000), Carbopol 941 (molecular weight about 1,250,000) or Carbopol 934 (molecular weight about 3,000,000). Furthermore, the following acrylic acid copolymers are included: (i) Copolymers of two or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with C1-4-alkanols formed esters (INCI acrylates copolymer), which include about the copolymers of Methacrylic acid, butyl acrylate and methyl methacrylate (CAS designation according to Chemical Abstracts Service: 25035-69-2) or of butyl acrylate and methyl methacrylate (CAS 25852-37-3) belong and, for example, the company Rohm & Haas under the trade names Aculyn ^® and Acusol ^® as well as from the company Degussa (Goldschmidt) under the trade name Tego ^® polymer are available, for. The anionic non-associative polymers Aculyn 22, Aculyn 28, Aculyn 33 (crosslinked), Acusol 810, Acusol 820, Acusol 823 and Acusol 830 (CAS 25852-37-3); (ii) crosslinked high molecular weight acrylic acid copolymers, such as those crosslinked with an allyl ether of sucrose or pentaerythritol copolymers of C10-30 alkyl acrylates with one or more monomers from the group of acrylic acid, methacrylic acid and their simple, preferably with C1-4 alkanols formed esters (INCI acrylates / C10-30 alkyl acrylate crosspolymer) and which are available, for example, from the company. BF Goodrich under the trade name Carbopol ^® , z. For example, the hydrophobized Carbopol ETD 2623 and Carbopol 1382 (INCI acrylates / C10-30 alkyl acrylate crosspolymer) and Carbopol Aqua 30 (formerly Carbopol EX 473).

One Another preferred polymeric thickener is to be used Xanthan gum, a microbial anionic heteropolysaccharide, which of Xanthomonas campestris and some other species under aerobic Conditions is produced and a molecular weight of 2 to 15 million Dalton has. Xanthan is made from a chain bound with β-1,4 Glucose (cellulose) with side chains formed. The structure of Subgroups consists of glucose, mannose, glucuronic acid, Acetate and pyruvate, where the number of pyruvate units is the viscosity of xanthan gum.

In particular, a fatty alcohol is also suitable as thickener. Fatty alcohols may be branched or unbranched, of native origin or of petrochemical origin. Preferred fatty alcohols have a C chain length of 10 to 20 C atoms, preferably 12 to 18. Preference is given to using mixtures of different C chain lengths, such as tallow fatty alcohol or coconut oil fatty alcohol. Examples are Lorol® ^® Special (C12-14 ROH) or Lorol® ^® Technical (C12-18 ROH) (both ex Cognis).

preferred Liquid textile treatment agents contain based on the entire fabric treatment agent is 0.01 to 3% by weight, and preferably 0.1 to 1 wt .-% thickener. The amount of thickener used depends on the type of thickener and the desired degree of thickening.

The Textile treatment agent may be enzymes in encapsulated form and / or contained directly in the textile treatment agent. As enzymes come especially those from the classes of hydrolases such as proteases, Esterases, lipases or lipolytic enzymes, amylases, cellulases or other glycosyl hydrolases, hemicellulases, cutinases, β-glucanases, Oxidases, peroxidases, perhydrolases and / or laccases and mixtures the enzymes mentioned in question. All of these hydrolases carry in the Laundry to remove stains such as protein, grease and or starchy stains and grayness. Cellulases and other glycosyl hydrolases may be over it By removing pilling and microfibrils for color retention and to increase the softness of the textile. to Bleaching or to inhibit color transfer can also Oxireduktasen be used. Particularly well suited from bacterial strains or fungi such as Bacillus subtilis, Bacillus licheniformis, Streptomyceus griseus and Humicola insolens recovered enzymatic agents. Preferably, proteases of the subtilisin type and in particular proteases derived from Bacillus lentus are used. These are enzyme mixtures, for example from protease and amylase or protease and lipase or lipolytic enzymes or protease and cellulase or from cellulase and lipase or lipolytic enzymes or from protease, amylase and lipase or lipolytic enzymes or protease, lipase or lipolytic enzymes and cellulase, but in particular protease and / or lipase-containing mixtures or mixtures with lipolytic enzymes of particular Interest. Examples of such lipolytic acting Enzymes are the known cutinases. Also peroxidases or oxidases have proven to be suitable in some cases. To the suitable amylases include in particular α-amylases, Iso-amylases, pullulanases and pectinases. Being cellulases preferably cellobiohydrolases, endoglucanases and β-glucosidases, which are also called cellobiases, or mixtures of these used. Because different types of cellulase are affected by their CMCase and avicelase activities by targeted mixtures of cellulases the desired Activities are discontinued.

The Enzymes may be adsorbed to carriers, to protect against premature decomposition. The amount the enzymes, the enzyme liquid formulation (s) or the enzyme granules directly in the textile treatment agent, for example, about 0.01 to 5 wt .-%, preferably 0.12 to about 2.5 wt .-% amount.

It can, for example, special textile treatment agents for Consumers with allergies, but also be preferred that the textile treatment agent contains no enzymes.

When Electrolytes from the group of inorganic salts can be a broad Number of different salts can be used. Preferred cations are the alkali and alkaline earth metals, preferred anions are the Halides and sulfates. From manufacturing point of view is the Use of NaCl or MgCl2 in the textile treatment agents is preferred. The proportion of electrolytes in the textile treatment agent is usually 0.1 to 5 wt .-%.

non-aqueous Solvents found in liquid textile treatment products can be used, for example, come from the Group of monohydric or polyhydric alcohols, alkanolamines or glycol ethers, provided that they are miscible with water in the specified concentration range are. Preferably, the solvents are selected from ethanol, n- or i-propanol, butanols, glycol, propane or Butanediol, glycerol, diglycol, propyl or butyl diglycol, hexylene glycol, Ethylene glycol methyl ether, ethylene glycol ethyl ether, ethylene glycol propyl ether, Ethylene glycol mono-n-butyl ether, diethylene glycol methyl ether, diethylene glycol ethyl ether, Propylene glycol methyl, ethyl or propyl ether, dipropylene glycol monomethyl or ethyl ether, di-isopropylene glycol monomethyl or ethyl ether, Methoxy, ethoxy or butoxytriglycol, 1-butoxyethoxy-2-propanol, 3-methyl-3-methoxybutanol, propylene glycol t-butyl ether and mixtures this solvent. Non-aqueous solvents can in liquid textile treatment products in amounts of between 0.5 and 15% by weight, but preferably below 12% by weight and in particular be used below 9 wt .-%.

The Viscosity of the textile treatment agent in the form of liquid Detergents or fabric conditioners can with usual Standard methods (for example, Brookfield Viscometer LVT-II at 20 U / min and 20 ° C, spindle 3) are measured and is for liquid detergents preferably in the range from 500 to 5000 mPas. Preferred textile treatment agents in the form of liquid detergents have viscosities from 700 to 4000 mPas, with values between 1000 and 3000 mPas especially are preferred. The viscosity of textile treatment agents in the form of fabric softeners is preferably 20 to 4000 mPas, with values between 40 and 2000 mPas especially are preferred. Particularly preferred is the viscosity of fabric softeners from 40 to 1000 mPas.

Around the pH of the liquid textile treatment agent in the To bring desired range, the use of pH adjusting agents be displayed. Can be used here all known Acids or alkalis, provided that their use is not from application technology or ecological reasons or for reasons consumer protection. Usually exceeds the amount of these adjusting agents 7 wt .-% of the total formulation not.

Of the pH of the liquid textile treatment agent in the form a liquid detergent is preferably between 4 and 10, and preferably between 5.5 and 8.5. The pH of the liquid Textile treatment agent in the form of a fabric conditioner preferably between 1 and 6 and preferably between 1.5 and 3.5.

Around the aesthetic impression of textile treatment agents too they can be dyed with suitable dyes become. Preferred dyes, the selection of which the expert no Difficulty, possess a high storage stability and insensitivity to the other ingredients the textile treatment agent and against light and no pronounced Substantivity to textile fibers to this not to dye.

When Foam inhibitors used in textile treatment agents Soaps, paraffins, for example, come from or silicone oils, optionally on support materials can be applied.

suitable Soil-release polymers, also referred to as "anti-redeposition agents" are, for example, nonionic cellulose ethers such as methyl cellulose and methylhydroxypropylcellulose with a proportion of methoxy groups from 15 to 30% by weight and of hydroxypropyl groups from 1 to 15% by weight, in each case based on the nonionic cellulose ether and the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof, in particular Polymers of ethylene terephthalates and / or polyethylene and / or Polypropylene glycol terephthalates or anionic and / or nonionic modified derivatives of these. Suitable derivatives include the sulfonated derivatives of phthalic and terephthalic acid polymers.

Optical brighteners (so-called "whiteners") can be added to the textile treatment agents to eliminate graying and yellowing of the treated textile fabrics. These substances are absorbed by the fiber and cause brightening and fake bleaching by converting invisible ultraviolet radiation into visible longer wavelength light which absorbs from the sunlight te ultraviolet light is emitted as a faint bluish fluorescence and results in the yellow color of the gray or yellowed laundry pure white. Suitable compounds are derived, for example, from the substance classes of 4,4'-diamino-2,2'-stilbenedisulfonic acids (flavonic acids), 4,4'-distyrylbiphenyls, methylumbelliferones, coumarins, dihydroquinolinones, 1,3-diarylpyrazolines, naphthalimides, benzoxazole , Benzisoxazole and benzimidazole systems as well as heterocyclic substituted pyrene derivatives. The optical brighteners are usually used in amounts of between 0% and 0.3% by weight, based on the finished detergent and cleaner.

graying have the task, the detached from the fiber dirt to keep suspended in the fleet and so the recovery of the Prevent dirt. These are water-soluble colloids mostly organic nature suitable, for example, glue, gelatin, Salts of ether sulfonic acids of starch or Cellulose or salts of acidic sulfuric acid esters of Cellulose or starch. Also water-soluble, Acidic group-containing polyamides are for this purpose suitable. Furthermore, can be soluble starch preparations and use other than the above starch products, for example degraded starch, aldehyde starches etc. Also, polyvinylpyrrolidone is useful. However, preference is given Cellulose ethers such as carboxymethyl cellulose (Na salt), methyl cellulose, Hydroxyalkylcellulose and mixed ethers such as methylhydroxyethylcellulose, Methylhydroxypropylcellulose, methylcarboxymethylcellulose and their Mixtures in amounts of from 0.1 to 5% by weight, based on the textile treatment agents, used.

There textile fabrics, in particular of rayon, rayon, Cotton and its blends may tend to wrinkle, because the individual fibers against bending, bending, pressing and squeezing transverse to the fiber direction, the washing and detergents contain synthetic crease inhibitors. These include, for example, synthetic products the base of fatty acids, fatty acid esters, fatty acid amides, Alkylolestern, -alkylolamiden or fatty alcohols, usually with Ethylene oxide reacted or products based on lecithin or modified phosphoric acid ester.

to Control of microorganisms can be the textile treatment agents contain antimicrobial agents. Here one differentiates depending on the antimicrobial spectrum and mechanism of action between bacteriostatic agents and bactericides, fungistatics and fungicides, etc. Important substances from these groups are, for example, benzalkonium chlorides, alkylarylsulfonates, Halogenphenols and Phenolmercuriacetat, wherein in erfindungemäßen Detergents and cleaning agents also entirely on these compounds can be waived.

The textile treatment agents according to the invention may contain preservatives, it being preferred to use only those which have no or only a low skin-sensitizing potential. Examples are sorbic acid and its salts, benzoic acid and its salts, salicylic acid and its salts, phenoxyethanol, 3-iodo-2-propynyl butylcarbamate, sodium N- (hydroxymethyl) glycinate, biphenyl-2-ol and mixtures thereof. A suitable preservative provides the solvent-free, aqueous combination of diazolidinyl urea, sodium benzoate and potassium sorbate (available as Euxyl K 500 ^® from Schuelke & Mayr), which can be used in a pH range up. 7 In particular, preservatives based on organic acids and / or their salts are suitable for preserving the skin-friendly textile treatment agents according to the invention.

Around undesirable, by oxygen action and other oxidative Processes caused changes to the textile treatment agents and / or to prevent the treated fabrics the detergents and cleaners contain antioxidants. To this Class of connection includes, for example, substituted ones Phenols, hydroquinones, catechols and aromatic amines as well organic sulfides, polysulfides, dithiocarbamates, phosphites, phosphonates and vitamin E.

One increased wearing comfort can from the additional Use of antistatic agents resulting in the detergents and cleaners additionally be attached. Enlarge antistatic agents the surface conductivity and allow thus an improved drainage of formed charges. Outer Antistatic agents are usually substances with at least one hydrophilic Molecule ligands and give on the surfaces a more or less hygroscopic film. These mostly surface-active Antistatic agents can be transformed into nitrogenous (amines, amides, quaternary Ammonium compounds), phosphorus-containing (phosphoric acid esters) and sulfur-containing (alkyl sulfonates, alkyl sulfates) antistatic agents. Lauryl (or stearyl) dimethylbenzylammonium chlorides are suitable as antistatics for textile fabrics or as an additive to textile treatment agents, in addition a softening effect is achieved.

To improve the rewettability of the treated fabrics and to Er To facilitate the ironing of the treated textile fabrics, it is possible, for example, to use silicone derivatives in the textile treatment compositions. These additionally improve the rinsing behavior of the detergents and cleaning agents by their foam-inhibiting properties. Preferred silicone derivatives are, for example, polydialkyl or alkylaryl siloxanes in which the alkyl groups have one to five carbon atoms and are completely or partially fluorinated. Preferred silicones are polydimethylsiloxanes, which may optionally be derivatized and are then amino-functional or quaternized or have Si-OH, Si-H and / or Si-Cl bonds. The viscosities of the preferred silicones are in the range between 100 and 100,000 mPas at 25 ° C, wherein the silicones in amounts between 0.2 and 5 wt .-%, based on the total washing and cleaning agent can be used.

After all the textile treatment agents may also contain UV absorbers, which are applied to the treated textile fabrics and improve the light fastness of the fibers. Links, which have these desired properties are, for example the compounds which are active by radiationless deactivation and Derivatives of benzophenone with substituents in the 2- and / or 4-position. Furthermore, substituted benzotriazoles, in the 3-position phenyl-substituted Acrylates (cinnamic acid derivatives), optionally with cyano groups in the 2-position, salicylates, organic Ni complexes and natural products like umbelliferone and the body's own urocanic acid suitable.

Around the catalyzed by heavy metals decomposition of certain detergent ingredients To avoid substances can be used, the heavy metals complex. Suitable heavy metal complexing agents are, for example the alkali metal salts of ethylenediaminetetraacetic acid (EDTA) or nitrilotriacetic acid (NTA) and alkali metal salts of anionic polyelectrolytes such as polymaleates and polysulfonates.

A preferred class of complexing agents are the phosphonates, which in preferred textile treatment agents in amounts of from 0.01 to 2.5 Wt .-%, preferably 0.02 to 2 wt .-% and in particular from 0.03 to 1.5 wt .-% are included. These preferred compounds include in particular organophosphonates such as, for example, 1-hydroxyethane-1,1-diphosphonic acid (HEDP), aminotri (methylenephosphonic acid) (ATMP), diethylenetriamine-penta (methylenephosphonic acid) (DTPMP or DETPMP) as well as 2-phosphonobutane-1,2,4-tricarboxylic acid (PBS-AM), which are mostly in the form of their ammonium or alkali metal salts be used.

firm Textile treatment agents can additionally neutral fillers such as sodium sulfate included.

The Textile treatment agents according to the invention can for cleaning and / or conditioning textile fabrics be used.

The Production of the fabric softener as a textile treatment agent may be any of the techniques known to those skilled in the art of fabric conditioners. This can be, for example by mixing the raw materials, if necessary using high shear mixing equipment, done. It is recommended Melting of the plasticizing component (s) and a subsequent Dispersing the melt in a solvent, preferably Water. The other ingredients can by simple Zumgleich be integrated into the fabric softener.

The Production of liquid detergents as textile treatment agents takes place by means of customary and known methods and methods in the example, the ingredients simply in stirred tanks be mixed with water, non-aqueous solvents and surfactants, are conveniently presented and the other ingredients z. B. Esterquats added in portions become. A separate heating in the production is not required, if it is desired, the temperature should be of the mixture does not exceed 80 ° C.

When Surface treatment agent may be the means of purification and / or treatment of surfaces, in particular hard Surfaces or keratinsic fibers are used. In the cleaning and / or treatment keratinsischer fibers can For example, the agent is a shampoo or hair conditioner act

For example, in cleaning and / or treating hard surfaces, the agent may be dishwashing detergents used to manually or mechanically clean dishes. It can also be common industrial or household cleaners, which are used to clean hard surfaces such as furniture surfaces, tiles, tiles, wall and floor coverings. In addition to crockery, hard surfaces also include all other hard surfaces, in particular glass, ceramics and plastics or metal, in household and commercial use.

there It may be the textile or surface treatment agents to be solid or liquid formulations, with solid Formulations as powder, granules, extrudate, in tab-form, as Tablet or as a pressed and / or melted shaped body may be present. For liquid formulations may be solutions, emulsions, dispersions suspensions, Microemulsions, gels or pastes.

When Surface treatment agent, the agent may accordingly conventional Ingredients of cleaning agents in usual amounts contain.

For example, surface treatment agents may contain as cleaning agents, alkyl ether sulfates, alkyl and / or aryl sulfonates, alkyl sulfates, amphoteric surfactants, anionic surfactants, nonionic surfactants, cationic surfactants, solvents, thickeners, dicarboxylic (salts) and other auxiliaries and additives. Some of these additional ingredients are already explained in more detail in the beginning and are also valid for use in detergents (see, for example, nonionic surfactants). B. Cutina ^® AGS of Henkel KGaA, or mixtures comprising, for example glycol distearate, z;., In particular UV stabilizers, perfumes, pearlescent agents, in particular in hand dishwashing detergents and cleaners for hard surfaces (INCI opacifying agents - as auxiliaries and additives. , z. B. the Euperlane ^® from. Henkel KGaA), SRP (soil repellent polymers), PEG-terephthalate, dyes, bleaching agents (eg., hydrogen peroxide), corrosion inhibitors, preservatives (e.g., as the technical as Bronopol Marked 2-bromo-2-nitropropane-1,3-diol (CAS 52-51-7), the), and skin feel-improving or caring additives is commercially available for example as Myacide ^® BT or BT as Boots Bronopol from Boots ( eg dermatologically active substances such as vitamin A, vitamin B2, vitamin B12, vitamin C, vitamin E, D-panthenol, sericerin, collagen partial hydrolyzate, various vegetable protein partial hydrolysates, protein hydrolytes sat fatty acid condensates, liposomes, polypropylene glycol, Nutrilan ^™ , Chitosan ^™ , cholesterol, vegetable and animal oils such as. As lecithin, soybean oil, etc., plant extracts such. Aloe vera, azulene, witch hazel extracts, algae extracts, etc., allantoin, AHA complexes) in amounts of usually not more than 5% by weight. To increase performance, small amounts of enzymes can be used. Preference is given to proteases (eg BLAP (Henkel), savinase (NOVO), durazym (NOVO), maxaperm, etc.), amylases (eg fermamyl (NOVO), etc.), lipases (eg. Lipolase (NOVO), etc.), peroxidases, gluconases, cellulases, mannases, etc., in amounts of preferably 0.001 to 1.5%, and more preferably less than 0.5%.

The Invention will be more apparent from the following examples explained.

1. Analytical determination of the perfume oil yield from detergents

a) perfume oil mixture

It will be a perfume oil mixture
Hexyl acetate, herbbavert, dihydromyrcenol, tetrahydromyrcenol, cyclovertal, linalool, phenylethyl alcohol, citronellol, citral, geraniol, hydroxycitronellal, isobornyl acetate, OTBCA (2-tert-butylcyclohexylacetate), PTBCA (4-tert-butylcyclohexylacetate), aldehyde C12 MNA (2-methylundecanal) , alpha-ionone, acyl, floramate, acetates PA (allylphenoxyacetate), lilial, norlimbanol, hedione, benzophenone, alpha-amylcinnamaldehyde, lyral, Iso E Super (7-acetyl-1,2,3,4,5,6,7 , 8-octahydro-1,1,6,7-tetramethylnaphthalene), cyclohexyl salicylate, habanolides, benzyl salicylate, ethylene brassilate.

All Perfume oils are present in equal proportions and are analytically detectable.

b) Textile used:

For the textile equipment became terry cloth (bile) used. 1.8 kg of the material was mixed with 30 g of commercial Heavy duty detergent in a washing machine of the company Miele type Novotronic W 363 prewashed at 95 ° C in a Koch program. Subsequently was rinsed 5 times. The terry material was on the Leash hanging at 20 ° C and 65% relative humidity dried.

c) Textile equipment:

Out the prewashed terry material became size samples 10 x 10 cm cut (4.8 g textile). There were 3 candidates each (moist and dry) per product prepared.

The liquor ratio substance: treatment solution was 1: 5, whereby the treatment solution on the calculation basis 36 ml softener consisting of
11% by weight Esterquat, Rewoquat WE 18 ex. Degussa
0.9% by weight of perfume oil mixture according to point a),
1% by weight of polyoxyalkyleneamine
0.2 wt.% MgCl ₂ .6H ₂ O and
Water ad. 100%
was set to 5 L of water.

As a comparison, a treatment solution without the polyoxyalkyleneamines according to the invention on the basis of calculation 36 ml fabric softener consisting of
11% by weight Esterquat, Rewoquat WE 18 ex. Degussa
0.9% by weight of perfume oil mixture according to point a),
0.2 wt .-% MgCl2 · 6 H ₂ O and
Water ad. 100%
set to 5 L of water and the above liquor ratio observed.

The prepared specimens were individually in flat glass dishes inserted, filled in the previously 24 g treatment solution and then the treated toweling samples were one minute in a household laundry sling (1400 revolutions / min.) spun. The specimens that are examined wet should be individually in glass bottles immediately after spinning packed up. The rest were lying flat on metal grates, in the climatic room at 20 ° C and 65% relative humidity for Stored for 24 hours and then individually in glass bottles packed up.

d) analytics:

The Towels were directly obtained by ASE extraction (ASE = accelerated solvent extraction) extracted with pentane and at Approximately 30 ° C under vacuum to about 2 ml concentrated, with no Loss of volatile perfume oil components occurred. Subsequently, the samples were placed on a 30 m DB5MS column (1 μm film thickness) by GC-MS coupling investigated in EI mode and in parallel FID.

The Quantification was carried out by means of an external calibration with the perfume oil mixture used each individual ion traces. During calibration, the contents were of the individual perfume oil components as 3.3 / 100 considered.

The subsequent experiments show that by the method described above certain total quantitative concentration of the perfume oil mixture (see point a) on the textile depending on the used Polyoxyalkylene.

Trial 1

Jeffamine ^® ED-2003 polyether amine (XTJ-502) ex Huntsman Corp. Texas as inventive polyoxyalkyleneamine

• Molekulargewicht ca. 2000 g/mol

After the above-described protocol, the fabric was brought into contact with a treatment solution containing Jeffamine ^® ED-2003 polyetheramine (XTJ-502), and as compared with a treatment solution without Jeffamine ^® ED-2003 polyetheramine (XTJ-502). Subsequently, the amount of perfume oil on the textile was determined quantitatively.

• Molecular weight about 2000 g / mol

concentration Perfume oil mixture on textile [μ g / g] Without ED 2003 With ED 2003 difference Moist spin Textile 45.3 μg / g 55.0 μg / g + 21.3% dried Textile 9.8 μg / g 11.8 μg / g + 19.6%

Trial 2

Jeffamine ^® D-400 polyether amine ex Huntsman Corp. Texas as inventive polyoxyalkyleneamine

After the above-described protocol, the fabric was brought ED-400 polyether amine into contact with a treatment solution containing Jeffamine ^® ED-400 polyetheramine, and as compared with a treatment solution without Jeffamine ^®.

• Molekulargewicht ca. 430 g/mol

Subsequently, the amount of perfume oil on the textile was determined quantitatively.

• Molecular weight about 430 g / mol

concentration Perfume oil mixture on textile [μg / g] Without ED-400 With ED-400 difference Moist spin Textile 45.3 μg / g 51.3 μg / g + 13.3% dried Textile 9.8 μg / g 12.8 μg / g + 30.4%

Trial 3

Jeffamine ^® M-1000 polyether amine ex Huntsman Corp. Texas as inventive polyoxyalkyleneamine

According to the above rule, the textile with a treatment solution containing Jeffamine ^® M-1000 polyether amine, and as compared with a treatment solution without Jeffamine ^® M-1000 polyether amine has been contacted.

• Molekulargewicht ca. 1000 g/mol

Subsequently, the amount of perfume oil on the textile was determined quantitatively.

• Molecular weight about 1000 g / mol

concentration Perfume oil mixture on textile [μg / g] Without M-1000 With M-1000 difference Moist spin Textile 45.3 μg / g 53.7 μg / g + 18.4% dried Textile 9.8 μg / g 14.3 μg / g + 44.8%

It shows that by the addition of the invention Polyoxyalkylenamine in all cases the perfume oil yield on the textile is significantly increased. At the same time is a significant to observe the odor-deadening effect without having a targeted chemical modification of the perfume oils took place would have.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• US 6861402 [0011]
• DE 1133847 A [0012]
• GB 384714 [0034]
• US 2017051 [0034]
• - US 2078922 [0034]

Claims (20)

Textile or surface treatment composition containing at least one fragrance and at least one polyoxyalkyleneamine of the general formula (I),

in which R is H and / or CH ₃ and A is H, an alkyl radical having 1 to 6 C atoms or H ₂ NCH (CH ₃ ) CH ₂ - *, x is an integer or fraction between 3 and 300 and said polyoxyalkyleneamine comprises at least one repeating unit with R = CH ₃ . Composition according to claim 1, characterized in that the ratio of repeat units with R = CH ₃ to repeat units with R = H in the polyoxyalkyleneamine according to formula (I) between 30: 1 and 1:30, preferably between 10: 1 and 1:10 and most preferably between 6: 1 and 1: 6. Composition according to claim 1, characterized in that the polyoxyalkylene amine according to formula (I) consists exclusively of repeating units with R = CH ₃ . Means according to at least one of the claims 1 to 3, characterized in that A in Polyoxyalkylenamin according to formula (I) represents a methyl or ethyl radical. Composition according to at least one of claims 1 to 3, characterized in that A in the polyoxyalkyleneamine according to formula (I) is H ₂ NCH (CH ₃ ) CH ₂ - *. Composition according to at least one of claims 1 to 5, characterized in that the weight average molecular weight "M _w " of the polyoxyalkyleneamine according to formula (I) in the range of 220 to 10,000 g / mol, preferably in the range of 380 to 2200 g / mol. Means according to at least one of the claims 1 to 6, characterized in that the total amount of the polyoxyalkylenamine according to formula (I) between 0.1 and 5 wt .-%, preferably between 0.2 and 3 wt .-%, more preferably between 0.5 and 2 wt .-% based on the total amount of the composition. Means according to at least one of the claims 1 to 7, characterized in that the total amount of at least a perfume between 0.01 and 5 wt .-%, preferably between 0.1 and 3 wt .-% and particularly preferably between 0.5 and 2 wt .-% based on the total amount of the agent. Means according to at least one of the claims 1 to 8, characterized in that the fragrance selected is from the group consisting of synthetic or natural Compounds of the ester type, ethers, aldehydes, ketones, alcohols, Hydrocarbons, acids, carbonates, aromatic hydrocarbons, aliphatic hydrocarbons, saturated and / or unsaturated hydrocarbons and mixtures thereof. Means according to at least one of the claims 1 to 9, characterized in that the agent is a textile treatment agent in the form of a detergent, softener, softening Detergent or detergent is. Agent according to claim 10, characterized that the textile treatment agent is a fabric softener which preferably contains a plasticizing component. Means according to at least one of the claims 1 to 11, characterized in that the textile treatment agent additionally at least one surfactant selected from the group consisting of anionic, cationic, nonionic, zwitterionic, amphoteric surfactants or mixtures thereof. Means according to at least one of the claims 1 to 12, characterized in that the agent is in solid form, preferably as a powder, granules, extrudate, in tab form, as a tablet or is present as a pressed and / or molten molded body. Means according to at least one of the claims 1 to 12, characterized in that the agent in liquid Form, in particular as a solution, emulsion, dispersion, suspension, Microemulsion, gel or paste is present. Use of an agent according to at least one of Claims 1 to 14 for washing textiles. Use of an agent according to at least one of Claims 1 to 14 for the long-lasting scenting of textiles, preferably during the automatic washing and / or drying process. Use of an agent according to at least one of Claims 1 to 14 for improved perfume yield Textiles. Use of an agent according to at least one of Claims 1 to 14 for the treatment and / or purification of Surfaces, especially of hard surfaces or keratinic fibers. Process for the long-lasting scenting of textiles, characterized in that a means according to at least one of Claims 1 to 14 on the surface to be scented is applied by textiles, preferably during the mechanical washing and / or drying process. Process for the preparation of an agent according to at least one of Claims 1 to 14, characterized in that at least one perfume and at least one polyoxyalkyleneamine of the general formula (I)

in which R is H and / or CH ₃ and A is H, an alkyl radical having 1 to 6 C atoms or H ₂ NCH (CH ₃ ) CH ₂ - *, x is an integer or fraction between 3 and 300 and said polyoxyalkylene amine comprises at least one repeating unit with R = CH ₃ , are mixed together.