DE102007038453A1 - Use of polycarbonate, polyurethane and/or polyurea polyorganosiloxane compounds or their acid addition compound and (1,3)-dioxolan-2-one or (1,3)-diazepan-2-one compound and polymer for fixing fragrance on hard and/or soft surfaces - Google Patents

Abstract

Use of polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compounds (I) or its acid addition compound and/or salts and (1,3)-dioxolan-2-one compound (IV) or (1,3)-diazepan-2-one compound (V) and a polymer, which is obtained by the reaction of a polymer substrate (that modifies the functional groups of hydroxy-, primary and secondary amino-group) with (IV) or (V), for fixing fragrances on hard- and/or soft surfaces, is claimed. Use of polycarbonate-, polyurethane- and/or polyurea-polyorganosiloxane compound of formula (-Y 1>-A-(C=O)-A-) (I) or its acid addition compound and/or salts and (1,3)-dioxolan-2-one compound of formula (IV) or (1,3)-diazepan-2-one compound of formula (V) and polymer which is obtained by the reaction of a polymer substrate (that modifies the functional groups of hydroxy-, primary and secondary amino- group) with (IV) or (V), for fixing fragrances on hard- and/or soft surfaces, is claimed. Either A : S, O or NR 1>; and Y 1>bivalent to polyvalent, preferably tetravalent, optionally saturated or aromatic up to 1000C hydrocarbon containing one or more NR 2>, N +>R 2>R 3> (both preferred), O, (CO), NH, 2-1000 polyorganosiloxane unit with silicon atom (optionally substituted), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); or Y 1>A : nitrogen containing heterocyclic ring; R 1>H, optionally saturated or aromatic up to 40C hydrocarbon containing one or more O, (CO), NH, NR 2>, ), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); R 2>optionally saturated, aromatic up to 40C hydrocarbon containing one or more O, (CO), NH, ), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); R 3>optionally saturated, aromatic up to 100C-hydrocarbon containing one or more O, (CO), NH, a bivalent residue, which forms cyclic structures within the Y 1>, ), preferably oligoethoxy and/or oligopropoxy (where its oligomerization degree is preferably 2-60) or oligoethylene imine (where its oligomerization degree is preferably 10-150000); R : 1-12C-alky; X : CO-CH=CH 2, CO-C(CH 3)=CH 2, CO-O-aryl, 2-6C-alkylene-SO 2-CH=CH 2 or CO-NH-R1a; R1a : 1-30C-alkyl, 1-30C-haloalkyl, 1-30C-hydroxyalkyl, 1-6C-alkyloxy-1-30C-alkyl, 1-6C-alkylcarbonyloxy-1-30C-alkyl, amino-1-30C-alkyl, mono- or di(1-6C-alkyl)amino-1-30C-alkyl, ammonio-1-30C-alkyl, polyoxyalkylene-1-30C-alkyl, polysiloxanyl-1-30C-alkyl, (meth)acryloyloxy-1-30C-alkyl, sulfono-1-30C-alkyl, phosphono-1-30C-alkyl, di(1-6C-alkyl)-phosphono-1-30C-alkyl, phosphonato-1-30C-alkyl, di(1-6C-alkyl) phosphonato-1-30Calkyl or a saccharide; and k : greater than 0. Provided that: in formula (I) A, Y 1>, R 1>, R 2>, R 3> are not same when at least one of the remainders of Y 1> is polyorganosiloxane unit with 2-1000 silicon atom; in formula (IV) when k is 1, X has the above variable or when k is greater than 1 X is: (i) polyamine bounded with ((CO)-NH) or (ii) polymer skeleton bounded with (CO)-, NH-2-6C-alkylene-O(CO)- or (CO)-O-2-6C-alkylene-O(CO)- or (iii) polymer skeleton bounded with (CO)-polysiloxanyl-1-30C-alkyl-groups. Independent claims are included for: (1) fixing the fragrances comprising reacting the surface of the fragrance and (I) or its acid addition compound and/or salts or (IV) and/or (V) and/or the polymer, in the presence of water for 2-90 minutes at 95[deg] C; and (2) a washing- or cleaning agent comprising the fragrances, preferably aroma materials of ester, ether, aldehyde, ketone, alcohols and/or hydrocarbons and (I), or its acid addition compound and/or salts or (IV) or (V) and/or the polymer. [Image].

Description

The The present invention relates to the use of polycarbonate, Polyurethane and / or polyurea-polyorganosiloxane compounds for the fixation of fragrances on hard and soft surfaces, such as for example, on textiles, especially in their laundry.

at the laundry of textiles or cleaning hard surfaces such as bathroom tiles expected Not only a visually perfect cleanliness, but also the absence of any unpleasant odors on the cleaned up textile or hard surface. On the contrary There is often a lingering odor coming out of the Cleaning, washing or laundry aftertreatment originate, perceived as pleasant and reinforces the cleanliness impression. For example, when washing textiles manually, normally Being carried in the sink is used by many users the residual smell in the pelvis as well as on the hands felt as pleasant. Consumers want for washed laundry a scent that is not only on the product even and directly after washing is still noticeable, but even noticeable over several days or even weeks is.

Indeed is the amount of perfume that comes from the washing or rinsing process from aqueous solution to textiles, often too low to become a long time too perceptible fragrance impression. Because perfumes high quality Ingredients of detergents and cleaners are, if one strives to use them only in small quantities. The loss of these ingredients (for example in a washing machine) is for the manufacturer and the consumers of such funds equally unsatisfactory.

From the international patent application WO 95/04809 is a method for perfuming textiles when washing with lipase-containing detergents known, wherein certain ester-group-containing fragrances are used. The European patent application EP 0 430 315 relates to lipase-containing detergents containing fragrances, wherein certain fragrance components should not exceed a certain upper limit, while other fragrance components must not fall below a certain minimum salary limit. This is intended to cover both the lipase intrinsic odor and the odor of lipolytic products produced from fats.

Surprisingly it has now been found that through the use of certain polycarbonate, polyurethane and / or polyurea polyorganosiloxane compounds adhesion perfumes on surfaces, for example textiles, hard objects or the human body, Can be improved when using these compounds and fragrances used together during washing or cleaning.

The present invention therefore provides the use of polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compounds containing at least one structural element of the formula (I): -YA- (C = O) -A- (I), where each A independently is selected from S, O and NR ¹ ,
Y is selected from bivalent to polyvalent, especially tetravalent, straight chain, cyclic or branched, saturated, unsaturated or aromatic, substituted or unsubstituted hydrocarbon radicals of up to 1000 carbon atoms (excluding the carbon atoms of any polyorganosiloxane unit optionally included) containing one or more May contain groups selected from -O-, - (CO) -, -NH-, -NR ² -, - (N ⁺ R ² R ³ ) - and a polyorganosiloxane unit having 2 to 1000 silicon atoms,
R ^{1 is} hydrogen or a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms and having one or more groups selected from -O-, - (CO) -, -NH- and -NR ² - can contain
R ^{2 is} a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms and which may contain one or more groups selected from -O-, - (CO) - and -NH-,
R ^{3 is} a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 100 carbon atoms, which may contain one or more groups selected from -O-, - (CO) - and -NH-, or a bivalent radical is that forms cyclic structures within the radical Y, or one or both of Y adjacent radicals A radicals with the radical Y between them a stick can form a heterocyclic radical containing
and in the entire compound not all radicals A or Y or R ¹ or R ² or R ³ given in formula (I) must be identical, with the proviso that in the entire compound at least one of the radicals Y is a polyorganosiloxane unit 2 to 1000 silicon atoms, or their acid addition compounds and / or salts for the fixation of fragrances on hard and / or soft surfaces.

Under soft surfaces are meant in this context both human skin as well as hair and textiles, also different Composition, for example of cotton, wool, silk, polyester, Polyamide, viscose and blended fabrics of any kind, to be understood.

links of the general formula (I) can be obtained by reacting diisocyanates, Bis-chloroformates or amides or Phosgene containing the structural element Y thiols, alcohols or amines. To obtain polymeric structures have these structural element Y having starting compounds at least 2 of the said functional groups. As end groups compounds come into consideration that are otherwise the structural element Y, but only monofunctional.

Among the preferred polycarbonate and / or polyurethane-polyorganosiloxane compounds are those which contain at least one structural element of the formula (II) or (III): -AYA- (CO) -OZ- (CHORO) -ZO- (CO) - (II), -AYA- (CO) -O- (CHCH ₂ OH) -ZO- (CO) - (III), in which A and Y have the abovementioned meanings and
Z is selected from the divalent, straight-chain, cyclic or branched, saturated or unsaturated, optionally substituted hydrocarbon radicals having 1 to 12 carbon atoms. These structural elements can be obtained by ring opening of cyclic carbonates (carbonic acid esters of vicinal diols) with the thiols, alcohols or amines containing the structural element Y.

The polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compound preferably has the structural element of the formula (I) several times in succession, the multiply occurring in each case corresponding radicals A or Y or Z or R ¹ or R ² or R ^{3 may be the} same or different.

Of the Term acid addition compound means a salt type Compound formed by protonation of basic groups in the molecule, in particular the optionally present amino groups, for example by reaction with inorganic or organic acids can be obtained. The acid addition compounds can used as such or under conditions of use optionally form the compounds defined above.

If the polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compound contains moieties - (N ⁺ R ² R ³ ) -, common counter anion ions, such as halide, hydroxide, sulfate, carbonate, are present in order to ensure charge neutrality.

When in the polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compounds present polyorganosiloxane structural element is preferably the structure - (SiR ⁴ ₂ O) _p - (SiR ⁴ ₂₎ -, wherein R ⁴ is a straight chain, cyclical or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 20 carbon atoms, and p = 1 to 999. The polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compounds preferably contain on average at least two, in particular at least three, of said polyorganosiloxane structural elements. R ⁴ is preferably a straight-chain or cyclic or branched, saturated or unsaturated or aromatic C ₁ - to C ₂₀ -, in particular C ₁ - to C ₉ -hydrocarbon radical, particularly preferably methyl or phenyl, and p is especially 1 to 199, particularly preferred 1 to 99. In a preferred embodiment, all radicals R ^{4 are the} same.

Preferred polycarbonate, polyurethane and / or polyurea polyorganosiloxane compounds used according to the invention are linear, ie all Y units in the structural element of the formula (I) are in each case divalent radicals. However, according to the invention, branched compounds are also included in which at least one of the radicals Y is branched or polyvalent, preferably tetravalent, so that branched structures with form linear repeat structures of structural elements of the formula (I).

In a further embodiment, in the polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compound used according to the invention, at least one of the Y units according to the structural element of the formula (I) has a grouping -NR ² - and / or at least one of the Y units according to structural element of the formula (I) a grouping - (N ⁺ R ² R ³ ) - on. R ² and R ³ are preferably methyl groups.

A further embodiment relates to the multiple regular occurrence of -O-groupings in at least one of the units Y, R ¹ , R ² and / or R ³ according to the structural element of the formula (I), preferably in the form of oligoethoxy and / or oligopropoxy groups their degrees of oligomerization are preferably in the range of 2 to 60.

In a further preferred embodiment, at least one of the units Y, R ¹ , R ² and / or R ³ according to the structural element of the formula (I) contains oligoethylenimine groups whose degrees of oligomerization are in particular in the range from 10 to 15 000.

The preparation of compounds having structural elements of the formula (I) starting from diisocyanates is disclosed in a German Patent Application filed on the same day by Momentive Performance Materials. Reactive cyclic carbonates and ureas, processes for their preparation and their reaction with polymeric substrates are described in the international patent application WO 2005/058863 described.

Preferably becomes the polycarbonate and / or polyurethane polyorganosiloxane compound in weight amounts, based on the perfume, in the range of 5: 1 to 0.5: 1, in particular from 2: 1 to 0.5: 1, more preferably from 1: 1 to 0.5: 1 used.

When suitable fragrances can be individual fragrance compounds, z. As the synthetic products of the ester, ether, aldehyde, Ketones, alcohols and hydrocarbons are used. fragrance compounds the type of ester are z. Benzyl acetate, phenoxyethyl isobutyrate, p-tert-butylcyclohexyl acetate, linalyl acetate, dimethylbenzylcarbinyl acetate, Phenylethyl acetate, linalyl benzoate, benzyl formate, ethylmethylphenyl glycinate, Allyl cyclohexyl propionate, styrallyl propionate and benzyl salicylate. The ethers include, for example, benzyl ethyl ether, too the aldehydes z. B. the linear alkanals with 8-18 C atoms, citral, Citronellal, citronellyloxyacetaldehyde, cyclamenaldehyde, hydroxycitronellal, Lilial and Bourgeonal, to the ketones z. As the Jonone, α-Isomethylionon and methyl cedryl ketone, to the alcohols anethole, citronellol, eugenol, geraniol, Linalool, phenylethyl alcohol and terpineol, to the hydrocarbons mainly include the terpenes and balms. However, preference is given to using mixtures of different fragrances, which together create an appealing scent. Such mixtures of individual substances are valid for the purposes of the present application as fragrances.

Such Fragrances can also be natural fragrance mixtures include, as accessible from plant or animal sources are, for. Pine, citrus, jasmine, lily, rose or ylang-ylang oil. Also essential oils of lower volatility, which are mostly used as aroma components, are suitable as perfume oils, z. B. sage oil, chamomile oil, clove oil, Lemon balm oil, mine oil, cinnamon oil, Lime blossom oil, juniper berry oil, vetiver oil, Olibanum oil, galbanum oil, labdanum oil and Lavender oil.

Preferably Bergamot oil, Dihydromyrcenol, Lilial, Lyral, Citronellol, Phenylethyl alcohol, α-hexyl cinnamaldehyde, geraniol, benzylacetone, Cyclamenaldehyde, Linalool, Boisambrene Forte, Ambroxan, Indole, Hedione, Sandelice, lemon oil, tangerine oil, orange oil, Allylamyl glycolate, cyclovertal, lavandin oil, muscatel Sage oil, β-damascone, geranium oil bourbon, Cyclohexyl salicylate, Vertofix Coeur, Iso-E-Super, fixolide NP, Evernyl, Iraldeine gamma, phenylacetic acid, geranyl acetate, benzyl acetate, Rose oxide, romilate, irotyl and floramate alone or in mixtures, used.

Another object of the invention is a method for fixing fragrances on hard and / or soft surfaces, especially textiles, which is characterized in that the surface with the fragrance and an active ingredient described above, in particular under the action of mechanical forces as they occur in household washing machines, in the presence of water over a period of 2 minutes to 90 minutes at a temperature below 95 ° C, in particular in the range of 20 ° C to 60 ° C, treated. Treatment times in the range of 5 minutes to 60 minutes are preferred. The temperature is preferably in the range from 20 ° C to 60 ° C, in particular from 20 ° C to 40 ° C, more preferably during the entire treatment time of the surface with the combination used in the invention, the temperature in the range of 20 ° C to 40 ° C is. The concentration of said action In the process according to the invention, the substance is preferably in the range from 0.05 g / l to 5 g / l, in particular from 0.1 g / l to 3 g / l, while the concentration of perfume in the aqueous treatment liquor is preferably in the range of 0, 01 g / l to 0.25 g / l, in particular from 0.05 g / l to 0.15 g / l. The process according to the invention can be carried out particularly advantageously with the aid of a washing or cleaning agent which contains a fragrance and the active substance defined above. Another object of the invention is therefore a detergent or cleaning agent containing a perfume, in particular selected from fragrance compounds of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons and mixtures thereof, and a polycarbonate and / or polyurethane polyorganosiloxane Connection. If desired, the agent may also contain a plurality of polycarbonate and / or polyurethane polyorganosiloxane compounds. In agents according to the invention preferably 1 wt .-% to 50 wt .-%, in particular 1 wt .-% to 10 wt .-%, more preferably 0.2 wt .-% to 1 wt .-% of perfumes present. An agent according to the invention can be used as such or after mixing or dilution with water in the process according to the invention or within the context of the use according to the invention.

at Such an agent may in particular be a laundry detergent or textile care products, which in particulate or liquid form, one in corresponding Mold for cleaning hard surfaces, for example, a tile, a bathroom or sanitary cleaner, or a cleanser for the human body, for example a hair shampoo, a cleansing lotion, a shower gel or a bar soap, act. In particular, the inventive Teaching can also be used in the personal care sector in conditioners. for hair dye, colorant or perm preparations and depilatories, and for agents which, e.g. For adjustment of the pH, lower amines.

additionally can according to the invention or used in the process according to the invention, as in particular powdered solids, in nachverdichteter Particle form, as homogeneous solutions or suspensions can have all the usual ingredients, as long as they do not contain the described active ingredient or in particular interact with the fragrance so that the desired effect the strengthening of the fragrance fixation on the surface absent.

invention Washing or cleaning agents may in particular be builders, surfactants, enzymes, organic and / or inorganic peroxygen compounds, peroxygen activators, water-miscible organic solvents, sequestering agents, Electrolytes, pH regulators, thickeners and other auxiliaries, such as soil release agents, optical brighteners, grayness inhibitors, dye transfer inhibitors, Foam regulators and dyes included.

The Agents of the invention may be surfactants in particular anionic surfactants, nonionic Surfactants and mixtures thereof, but also cationic surfactants in question come. Suitable nonionic surfactants are, in particular, ethoxylation and / or propoxylation products of alkyl glycosides and / or linear or branched alcohols each having 12 to 18 carbon atoms in the alkyl moiety and 3 to 20, preferably 4 to 10 alkyl ether groups. Farther are corresponding ethoxylation and / or propoxylation products of N-alkylamines, vicinal diols, fatty acid esters and Fatty acid amides which, with regard to the alkyl moiety, are those mentioned long-chain alcohol derivatives, as well as alkylphenols with 5 to 12 C-atoms in the alkyl radical useful.

suitable anionic surfactants are in particular soaps and those containing or sulfonate groups with preferably alkali ions as cations. Useful soaps are preferably the alkali salts of the saturated ones or unsaturated fatty acids having 12 to 18 carbon atoms. Such fatty acids may also be incomplete neutralized form can be used. Among the useful surfactants of the sulfate type include the salts of sulfuric acid half esters of fatty alcohols containing 12 to 18 carbon atoms and the sulfation products of mentioned nonionic surfactants with a low degree of ethoxylation. Suitable surfactants of the sulfonate type include linear ones Alkylbenzenesulfonates with 9 to 14 C atoms in the alkyl moiety, alkanesulfonates with 12 to 18 carbon atoms, as well as olefinsulfonates with 12 to 18 carbon atoms, in the implementation of corresponding monoolefins with sulfur trioxide arise as well as alpha-sulfo fatty acid esters, which in the Sulfonation of fatty acid methyl or ethyl esters arise.

Cationic surfactants are preferably selected from esterquats and / or quaternary ammonium compounds (QAV) according to the general formula (R ^I ) (R ^II ) (R ^III ) (R ^IV ) N ⁺ X ^- in which R ^I to R ^{II are} the same or different C _1-22 -alkyl, C _7-28 -Arylalkylreste or heterocyclic radicals, wherein two or in the case of an aromatic inclusion as in pyridine even three radicals together with the nitrogen atom, the heterocycle, z. A pyridinium or imidazolinium compound, and X ^{- represents} halide ions, sulfate ions, hydroxide ions or like anions. QACs are by reaction of tertiary amines with Alky lierungsmitteln such. As methyl chloride, benzyl chloride, dimethyl sulfate, dodecyl bromide, but also ethylene oxide produced. The alkylation of tertiary amines with a long alkyl radical and two methyl groups succeeds particularly easily, and the quaternization of tertiary amines with two long radicals and one methyl group can be carried out with the aid of methyl chloride under mild conditions. Amines which have three long alkyl radicals or hydroxy-substituted alkyl radicals are less reactive and are quaternized, for example, with dimethyl sulfate. Examples of suitable QACs are benzalkonium chloride (N-alkyl-N, N-dimethylbenzylammonium chloride), benzalkone B (m, p-dichlorobenzyl-dimethyl-C ₁₂ -alkylammonium chloride, benzoxonium chloride (benzyldodecyl-bis (2-hydroxyethyl) -ammonium chloride), Cetrimonium bromide (N-hexadecyl-N, N-trimethyl-ammonium bromide), Benzetonium chloride (N, N-dimethyl-N [2- [2- [p- (1,1,3,3-tetramethyl-butyl) -phenoxy] -ethoxy] -ethyl ] benzylammonium chloride), dialkyldimethylammonium chlorides such as di-n-decyldimethylammonium chloride, didecyldimethylammonium bromide, dioctyldimethylammonium chloride, 1-cetylpyridinium chloride and thiazoline iodide, and mixtures thereof Preferred QACs are the benzalkonium chlorides having C ₈ -C ₂₂ -alkyl radicals, in particular C ₁₂ -C ₁₄ -alkylbenzyl-dimethylammonium chloride.

verstanden werden, in der R⁵ für einen Alkyl- oder Alkenylrest mit 12 bis 22 Kohlenstoffatomen und 0, 1, 2 oder 3 Doppelbindungen, R⁶ und R⁷ unabhängig voneinander für H, OH oder O(CO)R⁵, s, t und u jeweils unabhängig voneinander für den Wert 1, 2 oder 3 und X^– für ein Anion, insbesondere Halogenid, Methosulfat, Methophosphat oder Phosphat sowie Mischungen aus diesen, steht. Bevorzugt sind Verbindungen, die für R⁶ die Gruppe O(CO)R⁵ und für R⁵ einen Alkylrest mit 16 bis 18 Kohlenstoffatomen enthalten. Besonders bevorzugt sind Verbindungen, bei denen R⁷ zudem für OH steht. Beispiele für Verbindungen der Formel (V) sind Methyl-N-(2-hydroxyethyl)-N,N-di(talgacyl-oxyethyl)ammonium-methosulfat, Bis-(palmitoyl)-ethylhydroxyethyl-methyl-ammonium-methosulfat oder Methyl-N,N-bis(acyloxyethyl)-N-(2-hydroxyethyl)ammonium-methosulfat. Werden quarternierte Verbindungen der Formel (V) eingesetzt, die ungesättigte Gruppen aufweisen, sind die Acylgruppen bevorzugt, deren korrespondierende Fettsäuren eine Jodzahl zwischen 5 und 80, vorzugsweise zwischen 10 und 60 und insbesondere zwischen 15 und 45 aufweisen und/oder die ein cis/trans-Isomerenverhältnis (in Mol-%) von größer als 30:70, vorzugsweise größer als 50:50 und insbesondere größer als 70:30 haben. Handelsübliche Beispiele sind die von der Firma Stepan unter dem Warenzeichen Stepantex^® vertriebenen Methylhydroxyalkyldialkoyloxyalkylammoniummethosulfate oder die unter dem Handelsnamen Dehyquart^® bekannten Produkte der Firma Cognis Deutschland GmbH beziehungsweise die unter der Bezeichnung Rewoquat^® bekannten Produkte des Herstellers Goldschmidt-Witco.Esterquats are here compounds of the general formula V,

in which R ^{5 is} an alkyl or alkenyl radical having 12 to 22 carbon atoms and 0, 1, 2 or 3 double bonds, R ⁶ and R ^{7 are} independently H, OH or O (CO) R ⁵ , s, t and u are each independently of the other the value 1, 2 or 3 and X ^{- is} an anion, in particular halide, methosulfate, methophosphate or phosphate and mixtures of these. Preference is given to compounds which contain the group O (CO) R ⁵ for R ⁶ and an alkyl radical having 16 to 18 carbon atoms for R ⁵ . Particularly preferred are compounds in which R ^{7 is} also OH. Examples of compounds of the formula (V) are methyl N- (2-hydroxyethyl) -N, N-di (tallowacyl-oxyethyl) ammonium methosulfate, bis (palmitoyl) -ethylhydroxyethyl-methyl-ammonium methosulfate or methyl-N , N-bis (acyloxyethyl) -N- (2-hydroxyethyl) ammonium methosulfate. If quaternized compounds of the formula (V) which have unsaturated groups are used, preference is given to the acyl groups whose corresponding fatty acids have an iodine number between 5 and 80, preferably between 10 and 60 and in particular between 15 and 45 and / or which have a cis / trans Isomer ratio (in mol%) of greater than 30:70, preferably greater than 50:50 and in particular greater than 70:30 have. Commercial examples are sold by Stepan under the trade name Stepantex® ^® methylhydroxyalkyldialkoyloxyalkylammonium or those known under the trade name Dehyquart® ^® products from Cognis Germany GmbH or the known under the name Rewoquat ^® products by manufacturer Goldschmidt-Witco.

surfactants are in the detergents according to the invention in Amounts of preferably 5 wt .-% to 50 wt .-%, in particular from 8% to 30% by weight. Especially in laundry aftertreatment agents are preferably up to 30 wt .-%, in particular 5 wt .-% to 15 wt .-% of surfactants, among these, preferably at least partially Cationic surfactants, used.

An agent according to the invention preferably contains at least one water-soluble and / or water-insoluble, organic and / or inorganic builder. The water-soluble organic builder substances include polycarboxylic acids, in particular citric acid and sugar acids, monomeric and polymeric aminopolycarboxylic acids, in particular methylglycinediacetic acid, nitrilotriacetic acid and ethylenediaminetetraacetic acid and polyaspartic acid, polyphosphonic acids, in particular aminotris (methylenephosphonic acid), ethylenediaminetetrakis (methylenephosphonic acid) and 1-hydroxyethane-1,1-diphosphonic acid, polymeric hydroxy compounds such as dextrin and polymeric (poly) carboxylic acids, in particular the accessible by oxidation of polysaccharides polycarboxylates of the European patent specification EP 0 609 273 , polymeric acrylic acids, methacrylic acids, maleic acids and copolymers thereof, which may also contain small amounts of polymerizable substances copolymerized without carboxylic acid functionality. The molecular weight of the homopolymers of unsaturated carboxylic acids is generally between 5,000 and 200,000, that of the copolymers between 2,000 and 200,000, preferably 50,000 to 120,000, in each case based on the free acid. A particularly preferred acrylic acid-maleic acid copolymer has a molecular weight of 50,000 to 100,000. Suitable, although less preferred, compounds of this class are copolymers of acrylic or methacrylic acid with vinyl ethers, such as vinylmethyl ethers, vinyl esters, ethylene, propylene and styrene, in which the acid content is at least 50% by weight. Terpolymers which are unsaturated as monomers may also be used as water-soluble organic builder substances te acids and / or salts thereof and as a third monomer vinyl alcohol and / or a vinyl alcohol derivative or a carbohydrate. The first acidic monomer or its salt is derived from a monoethylenically unsaturated C ₃ -C ₈ -carboxylic acid and preferably from a C ₃ -C ₄ -monocarboxylic acid, in particular from (meth) -acrylic acid. The second acidic monomer or its salt can be a derivative of a C ₄ -C ₈ -dicarboxylic acid, with maleic acid being particularly preferred. The third monomeric unit is formed in this case of vinyl alcohol and / or preferably an esterified vinyl alcohol. In particular, preferred are vinyl alcohol derivatives which are an ester of short-chain carboxylic acids, for example C ₁ -C ₄ carboxylic acids, with vinyl alcohol. Preferred polymers contain from 60% by weight to 95% by weight, in particular from 70% by weight to 90% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, and maleic acid or Maleinate and 5 wt .-% to 40 wt .-%, preferably 10 wt .-% to 30 wt .-% of vinyl alcohol and / or vinyl acetate. Very particular preference is given to polymers in which the weight ratio of (meth) acrylic acid or (meth) acrylate to maleic acid or maleate is between 1: 1 and 4: 1, preferably between 2: 1 and 3: 1 and in particular 2: 1 and 2 , 5: 1 lies. Both the amounts and the weight ratios are based on the acids. The second acidic monomer or its salt can also be a derivative of an allylsulfonic acid which is in the 2-position with an alkyl radical, preferably with a C ₁ -C ₄ -alkyl radical, or an aromatic radical which is preferably derived from benzene or benzene derivatives , is substituted. Preferred terpolymers contain from 40% by weight to 60% by weight, in particular from 45 to 55% by weight, of (meth) acrylic acid or (meth) acrylate, particularly preferably acrylic acid or acrylate, from 10% by weight to 30% by weight. %, preferably 15 wt .-% to 25 wt .-% methallylsulfonic acid or Methallylsulfonat and as the third monomer 15 wt .-% to 40 wt .-%, preferably 20 wt .-% to 40 wt .-% of a carbohydrate. This carbohydrate may be for example a mono-, di-, oligo- or polysaccharide, with mono-, di- or oligosaccharides are preferred. Particularly preferred is sucrose. The use of the third monomer presumably incorporates predetermined breaking points into the polymer which are responsible for the good biodegradability of the polymer. These terpolymers generally have a molecular weight between 1,000 and 200,000, preferably between 200 and 50,000 and in particular between 3,000 and 10,000. Further preferred copolymers are those which have as monomers acrolein and acrylic acid / acrylic acid salts or vinyl acetate. The organic builder substances can be used, in particular for the preparation of liquid agents, in the form of aqueous solutions, preferably in the form of 30 to 50 percent by weight aqueous solutions. All of the acids mentioned are generally used in the form of their water-soluble salts, in particular their alkali metal salts.

such If desired, organic builders may be used in amounts up to 40 wt .-%, in particular up to 25 wt .-% and preferably from 1% by weight to 8% by weight. Quantities near the mentioned Upper limit are preferably in pasty or liquid, in particular hydrous, inventive Funds used. Laundry aftertreatment agent according to the invention may also be free of organic builder be.

Suitable water-soluble inorganic builder materials are, in particular, alkali metal silicates and polyphosphates, preferably sodium triphosphate. Crystalline or amorphous alkali metal aluminosilicates, in amounts of up to 50% by weight, preferably not more than 40% by weight, and in liquid agents, in particular from 1% by weight to 5% by weight, are particularly suitable as water-insoluble, water-dispersible inorganic builder materials. used. Among these, preferred are the detergent grade crystalline sodium aluminosilicates, especially zeolite A, P and optionally X. Amounts near the above upper limit are preferably used in solid, particulate agents. In particular, suitable aluminosilicates have no particles with a particle size greater than 30 .mu.m and preferably consist of at least 80% by weight of particles having a size of less than 10 .mu.m. Their calcium binding capacity, according to the information of the German Patent DE 24 12 837 can be determined, is usually in the range of 100 to 200 mg CaO per gram.

Suitable substitutes or partial substitutes for the said aluminosilicate are crystalline alkali silicates which may be present alone or in a mixture with amorphous silicates. The alkali metal silicates useful as builders in the middle of the invention preferably have a molar ratio of alkali oxide to SiO ₂ below 0.95, in particular from 1: 1.1 to 1:12 and can be present in amorphous or crystalline form. Preferred alkali metal silicates are the sodium silicates, in particular the amorphous sodium silicates, with a molar ratio of Na ₂ O: SiO ₂ of 1: 2 to 1: 2.8. Those with a molar ratio Na ₂ O: SiO ₂ of 1: 1.9 to 1: 2.8 can be prepared by the process of European patent application EP 0 425 427 getting produced. The crystalline silicates which may be present alone or in admixture with amorphous silicates, are crystalline layer silicates with the general formula Na ₂ Si _x O _{2x + 1} · are used yH ₂ O, in which x, the so-called module, a number from 1.9 to 4 and y is a number from 0 to 20 and preferred values for x are 2, 3 or 4. Preferred crystalline layered silicates are those in which x in the abovementioned general formula has the values 2 or 3 accepts. In particular, both β- and δ-sodium disilicates (Na ₂ Si ₂ O ₅ .yH ₂ O) are preferred. Also prepared from amorphous alkali metal silicates, practically anhydrous crystalline alkali metal silicates of the abovementioned general formula in which x is a number from 1.9 to 2.1, can be used in Mittein invention. In a further preferred embodiment of the composition according to the invention, a crystalline sodium layer silicate with a modulus of 2 to 3 is used, as can be prepared from sand and soda. Crystalline sodium silicates with a modulus in the range from 1.9 to 3.5 are used in a further preferred embodiment of compositions according to the invention. If alkali metal aluminosilicate, in particular zeolite, is also present as an additional builder substance, the weight ratio of aluminosilicate to silicate, based in each case on anhydrous active substances, is preferably 1:10 to 10: 1. In agents containing both amorphous and crystalline alkali metal silicates, the weight ratio of amorphous alkali metal silicate to crystalline alkali metal silicate is preferably 1: 2 to 2: 1 and especially 1: 1 to 2: 1.

builders are preferred in the detergents according to the invention in amounts of up to 60% by weight, in particular from 5% by weight to 40% by weight, contain. Laundry aftertreatment agent according to the invention are preferably free of inorganic builder.

When suitable peroxygen compounds are in particular organic Peracids or peracid salts of organic acids, such as phthalimidopercaproic acid, perbenzoic acid or salts of diperdodecanedioic acid, hydrogen peroxide and releasing hydrogen peroxide under the conditions of use inorganic salts, such as perborate, percarbonate and / or persilicate, into consideration. If solid peroxygen compounds are used should, in the form of powders or granules be used, which also enveloped in a manner known in principle could be. Particularly preferred is alkali metal percarbonate, Alkali perborate monohydrate or especially in liquid Means hydrogen peroxide in the form of aqueous solutions, containing 3 wt .-% to 10 wt .-% hydrogen peroxide used. If a detergent according to the invention peroxygen compounds these are in amounts of preferably up to 50 wt .-%, in particular from 5% to 30% by weight. The addition is lower Quantities of known bleach stabilizers such as from Phosphonates, bristles or metaborates and metasilicates and magnesium salts such as magnesium sulfate may be useful.

When Bleach activators may be compounds that are under perhydrolysis conditions aliphatic peroxycarboxylic acids with preferably 1 to 10 C-atoms, in particular 2 to 4 C-atoms, and / or optionally substituted Perbenzoic acid, are used. Are suitable Substances which contain O- and / or N-acyl groups of said C atomic number and / or optionally substituted benzoyl groups. Preferred are multiply acylated alkylenediamines, in particular tetraacetylethylenediamine (TAED), acylated triazine derivatives, in particular 1,5-diacetyl-2,4-dioxohexahydro-1,3,5-triazine (DADHT), acylated glycolurils, especially tetraacetylglycoluril (TAGU), N-acylimides, especially N-nonanoylsuccinimide (NOSI), acylated Phenolsulfonates, especially n-nonanoyl or isononanoyloxybenzenesulfonate (n- or iso-NOBS), carboxylic anhydrides, in particular Phthalic anhydride, acylated polyhydric alcohols, in particular Triacetin, ethylene glycol diacetate, 2,5-diacetoxy-2,5-dihydrofuran and enol ester, as well as acetylated sorbitol and mannitol, respectively their mixtures (SORMAN), acylated sugar derivatives, in particular Pentaacetylglucose (PAG), Pentaacetylfruktose, Tetraacetylxylose and octaacetyl lactose and acetylated, optionally N-alkylated Glucamine and gluconolactone, and / or N-acylated lactams, for example N-benzoyl. Hydrophilic substituted acyl acetals and acyl lactams are also preferably used. Also combinations of conventional Bleach activators can be used. Such bleach activators are in the usual amount range, preferably in amounts from 1% by weight to 10% by weight, in particular from 2% by weight to 8% by weight, based on total resources.

additionally to the conventional bleach activators listed above or in their place may also be sulfonimines and / or bleach-enhancing transition metal salts or transition metal complexes as so-called Be included bleach catalysts. Among the candidate transition metal compounds In particular, manganese, iron, cobalt, ruthenium or molybdenum-salt complexes and their N-analogues, Manganese, iron, cobalt, ruthenium or molybdenum carbonyl complexes, manganese, Iron, cobalt, ruthenium, molybdenum, titanium, vanadium and copper complexes with nitrogen-containing tripod ligands, cobalt, Iron, copper and ruthenium-ammine complexes. Combinations of bleach activators and transition metal bleach catalysts also be used. Bleach-enhancing transition metal complexes, in particular with the central atoms Mn, Fe, Co, Cu, Mo, V, Ti and / or Ru, are in usual quantities, preferably in a quantity up to 1% by weight, in particular from 0.0025% by weight to 0.25% by weight and more preferably from 0.01% to 0.1% by weight, respectively based on total resources used.

When Enzymes useful in the compositions are those of the class of Proteases, cutinases, amylases, pullulanases, hemicellulases, cellulases, Lipases, oxidases and peroxidases and mixtures thereof in question. Particularly suitable are fungi or bacteria, such as Bacillus subtilis, Bacillus licheniformis, Streptomyces griseus, Humicola lanuginosa, Humicola insolens, Pseudomonas pseudoalcaligenes or Pseudomonas cepacia derived enzymatic agents. The optionally used enzymes can be adsorbed to carriers and / or embedded in encasing substances to counter them Protect premature inactivation. They are in the invention Detergents preferably not more than 5 wt .-%, in particular of 0.2 wt .-% to 2 wt .-%, contained.

The Agents can as optical brighteners, for example, derivatives the Diaminostilbendisulfonsäure or their alkali metal salts contain. For example, salts of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazinyl-6-amino) stilbene-2,2'-disulfonic acid are suitable or similar compounds, instead of the morpholino group a diethanolamino group, a methylamino group, an anilino group or carry a 2-methoxyethylamino group. Furthermore you can Brighteners of the type of substituted diphenylstyrene may be present for example, the alkali salts of 4,4'-bis (2-sulfostyryl) -diphenyl, 4,4'-bis (4-chloro-3-sulfostyryl) -diphenyl or 4- (4-chlorostyryl) -4 '- (2-sulfostyryl) -diphenyls. Also mixtures The aforementioned brightener can be used.

To The suitable foam inhibitors include, for example Organopolysiloxanes and their mixtures with microfine, optionally Silanized silica and paraffin waxes and their Mixtures with silanized silicic acid or bis-fatty acid alkylenediamides. With advantages are also mixtures of different foam inhibitors used, for example, those of silicones, paraffins or waxes. Preferably, the foam inhibitors, in particular silicone and / or Paraffin-containing foam inhibitors, on a granular, in water soluble or dispersible carrier substance bound. In particular, mixtures of paraffin waxes are and bistearylethylenediamides are preferred.

additionally the means may also contain components which and fatsauswaschbarkeit from textiles positively affect, so-called soil release agents. This effect becomes particularly clear when a textile is dirty, which has been repeatedly with a detergent according to the invention, which and fat-dissolving component, washed has been. Among the preferred oil and fat dissolving components include, for example, nonionic cellulose ethers such as Methylcellulose and methylhydroxypropylcellulose with a proportion to methoxyl groups from 15 to 30 wt .-% and hydroxypropoxyl groups of 1 to 15 wt .-%, each based on the nonionic cellulose ether, as well as the known from the prior art polymers of phthalic acid and / or terephthalic acid or derivatives thereof monomeric and / or polymeric diols, in particular polymers of ethylene terephthalates and / or polyethylene glycol terephthalates or anionic and / or nonionically modified derivatives of these.

The Agents may also be color transfer inhibitors, preferably in amounts of 0.1 wt .-% to 2 wt .-%, in particular 0.1 wt .-% to 1 wt .-%, which in a preferred embodiment of the Invention Polymers of vinylpyrrolidone, vinylimidazole, vinylpyridine-N-oxide or copolymers of these. Useful are both polyvinyl pyrrolidones with molecular weights of 15,000 to 50,000 as well as polyvinylpyrrolidones with molecular weights above 1 000 000, in particular from 1 500 000 to 4,000,000, N-vinylimidazole / N-vinylpyrrolidone copolymers, Polyvinyloxazolidones, copolymers based on vinyl monomers and Carbonsäureamiden, pyrrolidone group-containing polyester and Polyamides, grafted polyamidoamines and polyethyleneimines, polymers with amide groups from secondary amines, polyamine N-oxide polymers, Polyvinyl alcohols and copolymers based on acrylamidoalkenylsulfonic acids. But can also be used enzymatic systems, comprising a peroxidase and hydrogen peroxide or a hydrogen peroxide-yielding substance in water. The addition a mediator compound for the peroxidase, for example an acetosyringone, a phenol derivative or a phenotiazine or phenoxazine, is preferred in this case, in addition to above-mentioned polymeric dye transfer inhibiting agents can be used. Polyvinylpyrrolidone points to Use in agents according to the invention preferably an average molecular weight in the range of 10 000 to 60 000, especially in the range of 25,000 to 50,000. Among the copolymers are those of vinylpyrrolidone and vinylimidazole in the molar ratio 5: 1 to 1: 1 with an average molecular weight in the range of 5,000 to 50,000, in particular 10,000 to 20,000 are preferred.

Graying inhibitors have the task of keeping suspended from the textile fiber dirt suspended in the fleet. Water-soluble colloids of mostly organic nature are suitable for this purpose, for example starch, glue, gelatin, salts of ether carboxylic acids or ether sulfonic acids of starch or of cellulose or salts of acidic sulfuric acid esters of cellulose or starch. Also, water-soluble polyamides containing acidic groups are suitable for this purpose. Furthermore, other than the above can be starch derivatives, for example aldehyde starches. Preference is given to using cellulose ethers, such as carboxymethylcellulose (Na salt), methylcellulose, hydroxyalkylcellulose and mixed ethers, such as methylhydroxyethylcellulose, methylhydroxypropylcellulose, methylcarboxymethylcellulose and mixtures thereof, for example in amounts of from 0.1 to 5% by weight, based on the compositions.

To in the inventive compositions, in particular if they are in liquid or pasty form, usable organic solvents Alcohols having 1 to 4 carbon atoms, in particular methanol, ethanol, isopropanol and tert-butanol, diols having 2 to 4 C atoms, in particular ethylene glycol and propylene glycol, as well as mixtures thereof and those mentioned Classes of derivable ether. Such water-miscible Solvents are in the inventive Detergents preferably in amounts of not more than 30% by weight, in particular from 6% to 20% by weight.

to Setting a desired, through the mixture the remaining components are not self-generating pH the agents according to the invention can be and environmentally friendly acids, in particular citric acid, Acetic acid, tartaric acid, malic acid, Lactic acid, glycolic acid, succinic acid, glutaric acid and / or adipic acid, but also mineral acids, especially sulfuric acid, or bases, in particular ammonium or alkali hydroxides. Such pH regulators are in the agents according to the invention preferably not over 20 wt .-%, in particular from 1.2 wt .-% to 17 wt .-%, contain.

The Preparation of solid inventive means prepares no difficulties and can in principle known manner, for Example by spray drying or granulation occur, wherein peroxygen compound and bleach catalyst optionally be added later. For the production according to the invention Agents with increased bulk density, in particular in the range of 650 g / l to 950 g / l, is one having an extrusion step Preferred method.

at body care compositions according to the invention it is in a first preferred embodiment to a permanent wave, in particular a Wellotion. Under one Wellotion is understood to mean the preparation containing the reducing agent contains. As a reducing agent are usually Mercapto compounds and / or salts of sulfurous acid used. Preferred mercapto compounds are thioglycolic acid, their physiologically acceptable salts and their esters. Further preferably used, albeit to a lesser extent, Cysteamine, cysteine, thiolactic acid, thiomalic acid, Colorful salts and α-mercaptoethanesulfonic acid.

To cover the inherent odor of these mercapto compounds usually contain the well lotions Perfume oils. However, there is the problem that Remains of Mercaptoverbindungen also after fixing the perm remain on the hair, in many cases even significantly longer as the perfume oils used. Become this hair later with a slightly perfumed agent, for example, a shampoo as part of the usual cleaning, treated, so these radicals of the mercapto compound dissolve with corresponding fragrance unfolding successively from the hair. this Problem can be solved by using the invention above defined active substances in the Wellotionen in outstanding Be prevented. The well lotions can further all ingredients known to those skilled in the art, such as anionic Surfactants, zwitterionic surfactants, ampholytic surfactants, non-ionic surfactants Surfactants, cationic surfactants, protein hydrolysates, thickeners, Structural, cationic, anionic, zwitterionic, amphoteric and nonionic polymers, solubilizers, substances for adjusting the pH, active ingredients such as allantoin, pyrrolidonecarboxylic acids and plant extracts, light stabilizers, complexing agents, source and penetrants, opacifiers, dyes, perfume oils, Pearlescing and blowing agents. These statements regarding Permanent waving agents apply equally to depilatories.

According to one Another preferred embodiment will be defined above Active ingredients according to the invention in such agents used, which contain volatile amines. Again, make it easier they cover the unwanted scents, which go back to these amines. Such means are, besides the above-mentioned permanent wave agents, for example, hair dyes.

According to one third preferred embodiment, the inventive Teaching to be used, the perfume part in washing, Significantly reduce cleaning and personal care products. Thereby It is also possible to perfumed products for to offer such particularly sensitive consumers as normal perfumed products due to special incompatibilities and irritations only limited or at all can not use. In this context are present all skin care products and deodorants, but also hand washing to call.

Examples

• a) Mischung aus Cellulase, Amylase und Protease

washing conditions Washer: Miele ^® Novotronic ^® W 308 Wash program: Einlaugenverfahren Normal program Koch-Farbwäsche Washing temperature: 40 ° C Fleet size: 17 l Water hardness: 16 ° dH filling laundry: 3.5 kg of clean laundry Tissue: Terry soap towels, 100% cotton Table 1: Detergent compositions used (contents by weight in% by weight) W1 V1 FAEOS 5 5 C _12/14 7 EO 12 12 C _12-14 alkyl polyglycoside 2 2 Fatty acid C _12-18 5 5 glycerin 5 5 Na citrate 1 1 Sodium polyacrylate 0.2 0.2 Enzymes ^a) + + Perfume 1 1 active substance 1 - water on 100

• a) Mixture of cellulase, amylase and protease

The Textiles were washed 3 times with a detergent W 1 of the above Composition containing 1 wt .-% of the active ingredient, under washed according to the conditions given above and after the last Laundry dried. In parallel, were under the same Conditions textiles with the detergent V1, that is in the absence of the active ingredient. The textiles were presented to an expert panel of 30 people and from these odoriferous assessed comparatively. The fragrance impression when using the invention The agent was both wet and dry Laundry more intense than when using W1.

QUOTES INCLUDE IN THE DESCRIPTION

This list The documents listed by the applicant have been automated generated and is solely for better information recorded by the reader. The list is not part of the German Patent or utility model application. The DPMA takes over no liability for any errors or omissions.

Cited patent literature

• WO 95/04809 [0004]
• - EP 0430315 [0004]
• WO 2005/058863 [0018]
• EP 0609273 [0032]
• - DE 2412837 [0034]
• EP 0425427 [0035]

Claims (17)

Use of a polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compound containing at least one structural element of the formula (I): -YA- (C = O) -A- (I), wherein each A is independently selected from S, O and -NR ¹ -, Y is selected from bi- to polyvalent, especially tetravalent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic, substituted or unsubstituted hydrocarbon radicals having up to 1000 carbon atoms ( wherein the carbon atoms of an optionally contained polyorganosiloxane unit are not counted) which contain one or more groups selected from -O-, - (CO) -, -NH-, -NR ² -, - (N ⁺ R ² R ³ ) - and R ^{1 is} hydrogen or a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms which contains one or more groups selected from -O-, - (CO) -, -NH-, and -NR ² - may contain, R ² is a straight, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms, one or more groups selected from -O-, - and may contain -NH-, R ³ is a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to - (CO) 100 carbon atoms, which may contain one or more groups selected from -O-, - (CO) - and -NH-, or a bivalent radical which forms cyclic structures within the radical Y, or one or both of which are adjacent to Y. Residues A with the radical Y between them can form a nitrogen-containing heterocyclic radical, and in the entire compound not all of the radicals A or Y or R ¹ or R ² or R ³ indicated in formula (I) must be identical with the proviso that in the entire compound at least one of the radicals Y comprises a Polyorganosiloxaneinheit having 2 to 1000 silicon atoms, or their acid addition compound and / or salt for fixing fragrances to hard and / or soft Surfaces. Use according to claim 1, characterized that the surface is human skin, hair and / or textiles. Use according to claim 1 or 2, characterized in that the polyorganosiloxane structural element present in the polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compounds is the structure - (SiR ⁴ ₂ O) _p - (SiR ⁴ ₂ ) - wherein R ^{4 is} a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 20 carbon atoms, and p = 1 to 999. Use according to one of claims 1 to 3, characterized in that the polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compound on average at least two, in particular at least three of said polyorganosiloxane structural elements contains. Use according to one of claims 1 to 4, characterized in that in the polycarbonate and / or polyurethane-polyorganosiloxane compound at least one of the Y units according to the structural element of the formula (I) is a grouping -NR ² - and / or at least one of Y units according to structural element of the formula (I) has a grouping - (N ⁺ R ² R ³ ) -. Use according to one of claims 1 to 5, characterized in that oligoethoxy and / or oligopropoxy groups are present in at least one of the units Y, R ¹ , R ² and / or R ³ according to the structural element of the formula (I), the degrees of oligomerization thereof in particular ranging from 2 to 60. Use according to one of claims 1 to 6, characterized in that in at least one of the units Y, R ¹ , R ² and / or R ³ according to the structural element of the formula (I) Oligoethylenimingruppen are present whose degrees of oligomerization, in particular in the range of 10 to 15 0000 lie. Use according to one of claims 1 to 7, characterized in that the polycarbonate and / or polyurethane-polyorganosiloxane compound in weight amounts, based on the perfume, in the range of 5: 1 to 0.5: 1, in particular from 2: 1 to 0.5: 1, is used. Process for fixing fragrances to hard and / or soft surfaces, characterized in that the surface containing the fragrance and a polycarbonate, polyurethane and / or polyurea compound containing at least one structural element of the formula (I): -YA- (C = O) -A- (I), wherein each A is independently selected from S, O and -NR ¹ -, Y is selected from bi- to polyvalent, especially tetravalent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic, substituted or unsubstituted hydrocarbon radicals having up to 1000 carbon atoms ( wherein the carbon atoms of an optionally contained polyorganosiloxane unit are not counted) which contain one or more groups selected from -O-, - (CO) -, -NH-, -NR ² -, - (N ⁺ R ² R ³ ) - and R ^{1 is} hydrogen or a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms which contains one or more groups selected from -O-, - (CO) -, -NH-, and -NR ² - may contain, R ² is a straight, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms, one or more groups selected from -O-, - and may contain -NH-, R ³ is a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to - (CO) 100 carbon atoms, which may contain one or more groups selected from -O-, - (CO) - and -NH-, or a bivalent radical which forms cyclic structures within the radical Y, or one or both of which are adjacent to Y. Residues A with the radical Y between them can form a nitrogen-containing heterocyclic radical, and in the entire compound not all of the radicals A or Y or R ¹ or R ² or R ³ indicated in formula (I) must be identical with the proviso that in the entire compound at least one of the radicals Y comprises a polyorganosiloxane unit having 2 to 1000 silicon atoms, or their acid addition compounds and / or salt in the presence of water over a period of 2 min treated at a temperature below 95 ° C for up to 90 minutes. Method according to claim 9, characterized that treatment time ranges from 5 minutes to 60 minutes lies. Method according to claim 9 or 10, characterized that the temperature is in the range of 20 ° C to 60 ° C, especially from 20 ° C to 40 ° C. Method according to one of claims 9 to 11, characterized in that during the entire treatment time the temperature is in the range of 20 ° C to 40 ° C. Method according to one of claims 9 to 12, characterized in that the concentration of polycarbonate, Polyurethane and / or polyurea compound in the range of 0.05 g / l to 5 g / l, in particular from 0.1 g / l to 3 g / l. Method according to one of claims 9 to 13, characterized in that the concentration of perfume in the aqueous treatment liquor in the range of 0.01 g / l to 0.25 g / l, in particular from 0.05 g / l to 0.15 g / l. Detergents or cleaning compositions containing a perfume, in particular selected from perfume compounds of the ester type, ethers, aldehydes, ketones, alcohols and hydrocarbons and mixtures thereof, and a polycarbonate, polyurethane and / or polyurea polyorganosiloxane compound containing at least one Structural element of the formula (I): -YA- (C = O) -A- (I), wherein each A independently is selected from S, O and NR ¹ , Y is selected from bi- to polyvalent, especially tetravalent, straight-chain, cyclic or branched, saturated, unsaturated or aromatic, substituted or unsubstituted hydrocarbon radicals having up to 1000 carbon atoms (the Not counting carbon atoms of an optionally contained polyorganosiloxane unit) containing one or more groups selected from -O-, - (CO) -, -NH-, -NR ² -, - (N ⁺ R ² R ³ ) - and a polyorganosiloxane unit containing from 2 to 1000 silicon atoms R ^{1 can be} hydrogen or a straight, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms and having one or more groups selected from -O-, - (CO) -, -NH- and -NR ² - R ^{2 is} a straight, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 40 carbon atoms which may contain one or more groups selected from -O-, - (CO) - and -NH- , R ^{3 is} a straight-chain, cyclic or branched, saturated, unsaturated or aromatic hydrocarbon radical having up to 100 carbon atoms, which may contain one or more groups selected from -O-, - (CO) - and -NH-, or a divalent Rest is that forms the cyclic structures within the radical Y, or one or both of Y adjacent radicals A with the radical Y between them form a nitrogen-containing heterocyclic radical k ünnen, and in the entire compound not all in formula (I) given radicals A or Y or R ¹ or R ² or R ³ must be the same with the proviso that in the entire compound at least one of the radicals Y a Polyorganosiloxaneinheit comprising 2 to 1000 silicon atoms, or their acid addition compound and / or salt. Agent according to claim 15, characterized that the weight ratio of the polycarbonate, polyurethane and / or polyurea-polyorganosiloxane compound to perfume 5: 1 to 0.5: 1, in particular from 2: 1 to 0.5: 1, is. Composition, use or method according to one of the preceding claims, characterized in that the compound of formula (I) is a polycarbonate and / or polyurethane-polyorganosiloxane compounds containing at least one structural element of the formula (II) or formula (III) : -AYA- (CO) -OZ- (CHORO) -ZO- (CO) - (II), -AYA- (CO) -O- (CHCH ₂ OH) -ZO- (CO) - (III), in which A and Y have the meanings given for formula (I) and Z is selected from the divalent, straight-chain, cyclic or branched, saturated or unsaturated, optionally substituted hydrocarbon radicals having 1 to 12 carbon atoms