DD295307A5 - FIBER CONDITIONING COMPOSITION, METHOD FOR THE PRODUCTION AND USE THEREOF - Google Patents

Abstract

A fiber conditioning composition with improved fiber conditioning properties contains an aminodimethicone type aminosilicone of a particular formula and an aqueous medium for the aminosilicone, which acts as a carrier for the same. Preferably, the carrier is a wet anionic shampoo medium which also contains a cationic surface active fiber conditioning agent such as a quaternary ammonium salt, with particular preference also being given to hydrocarbon components such as microcrystalline wax and petrolatum and / or polyethylene and mineral oil containing To further improve the conditioning action of human hair. The invention also includes fiber conditioning methods and methods for combined shampooing and conditioning of hair and methods of making the conditioning shampoos of the present invention.

Description

Field of application of the invention

The invention relates to fiber conditioning compositions. In particular, it relates to such compositions which are shampoos and which contain certain aminosilicones which, together with cationic surfactant fiber conditioning agents such as quaternary ammonium salts, significantly improve fiber conditioning and, especially in the case of anionic surfactant-containing shampoos, provide excellent conditioning of human hair in its purification ,

Fiber conditioning compositions such as fabric conditioning detergent compositions and non-detergent conditioning compositions for treating washed fiber materials containing the launded fabrics

conditioning, making them softer and less receptive to electrostatic charges after drying in an automatic drier, are already on the market and contain cationic conditioning substances such as quaternary ammonium salts, and such quaternary ammonium compounds have also been incorporated into hair rinses. Aminosilicones and amodimethicones have been proposed as hair conditioning components of shampoos as well as various hydrocarbons such as petrolatum and mineral oils. Anionic surfactants such as higher fatty alcohol sulfates and higher fatty alcohol polyethoxysulfates (polyethoxylated higher fatty alcohol sulfates) have been used in shampoos, sometimes in conjunction with ammonium halides. Also, a co-pending patent application (Attorney Docket No. 29521 corresponding to US Pat. No. 4,326,444) describes fiber conditioning compositions containing solubilized poly-lower-alkylene shampoos containing anionic surfactant, cationic fiber conditioning surfactant, polyethylene and solubilizing liquid hydrocarbon (mineral oil). this combination of polyethylene and mineral oil improves the hair conditioning action of the shampoo. The condition according to the invention! However, rshampoos based on anionic surfactant or anionic surfactants and cationic hair conditioning surfactants were not known prior to the present invention, nor were the surprising improved conditioning effects resulting from this combination.

Characteristic of the known technical solutions

The closest prior art is described in US Pat. Nos. 4,559,227, 455,334, 4,660,192, 4,704,272, 4,710,314 and 4,747,732. U.S. Patent 4,559,227 discloses aminosilicone polymers of similar structure to those of the invention (see Example 7 of the specification), U.S. Patent 4,710,314 discloses hair conditioning shampoos containing amooimethicone (an aminosilicone) and a cationic surfactant conditioner. The preferred aminosilones according to the invention are nowhere described and nowhere is it suggested that the compositions according to the invention are significantly better hair-conditioning shampoos than similar compositions based on aminosilicones of similar but different structure.

Object of the invention

The object of the invention is to make available novel fiber conditioning compositions, in particular shampoos.

Explanation of the essence of the invention

The object of the invention is to provide fiber conditioning compositions having improved properties.

This object is achieved according to the invention by a fiber conditioning composition having improved fiber conditioning properties comprising an aminosilicone of the formula

R ¹ CH ₃ CH ₃ R ⁵ I I I I Si-O- (Si-O) _x - (Si - O) _y - Si - R ⁶ I I I I R ³ CH ₃ R * R ^v

wherein R ¹ , R ² , R ³ , R ⁶ , R "and R ^{7 are} alkyl of from 1 to 6 carbon atoms and most preferably each of one carbon atom, R ⁴ is R 1 is NH-CH ₂ CH ₂ -NH ₂ , R ^{8 is} alkylene of 3 to 6 carbon atoms, and most preferably an isobutyl group, χ is an average number in the range of 200 to 10,000, and most preferably 750 to 800, and y is an average number in the range of 1 to 10, and more preferably of is less than 5, and most preferably 1, having an amine equivalent in the range of 4,000 to 60,000 and a carrier for aminosilicone The carrier is normally liquid and often a detergent composition, preferably a shampoo, and if it is a shampoo, it preferably contains a cationic fiber-conditioning agent such as a quaternary ammonium salt The presence of the quaternary ammonium salt apparently promotes emulsification of the aminosilicone in the aqueous system carried here It also helps to make the aminosilicone more effective in hair conditioning, despite the presence of anionic surfactant, which is usually present in such a shampoo in a much greater proportion than the conditioning substances. The aminosilicones of the invention (see above formula) preferably have amine equivalents in the range of 4,000 to 60,000, more preferably such amine equivalent is 10,000 or 20,000 to 40,000, the average numbers χ being in the range of 200 to 10,000 and more preferably more than 500 less than 10,000 and most preferably between 750 and 800, and wherein the average numbers y are in the range of 1 to 10, and preferably less than 5, and most preferably 1. They may also contain up to 25% of cyclomethicone, which is used as a process aid in their preparation, but may desirably contain less than that amount, since cyclomethicone is used in the formulations of

Invention is not desirable. The amine equivalent is numerically equal to the weight in grams of the polymer containing 14 g of amine nitrogen. In the preferred compositions of the invention, the aminosilicone polymer is one from Dow-Corning Corporation, which is referred to below as aminosilicone B in Table 2 below. Such an aminosilicone is of low charge density and amine content, with the amine equivalent being 30,000. In this polymer, whose structure is shown above, R ', R ⁷ , R ³ , R ⁶ , R * and R ^{7 are} all methyl groups, and R ⁸ is an isobutyl group. The viscosity of this material is 7 500 ± 10OOcps. Another such aminosilicone, referred to herein as Table 2 below as Dow-Corniiig-Aniinosilicone A, is also useful but not as effective as Aminosilicone B, which has a larger molecular weight and a lower charge density. Other Dow-Corning aminosilicones, referred to as C, D and E silicones in Table 2 below, have the same formulas but different charge densities (charge density is opposite to the amine equivalent) are less effective and hair conditioning agents in the compositions of this invention not suitable.

The carrier for the aminosilicone may be any suitable carrier, is preferably liquid and aqueous, and often contains a surfactant or a detergent which helps to keep the aminosilicone emulsified, dispersed or suspended in the aqueous medium and Helps to prevent phase separations and deposits of the aminosilicone and other components of the composition. It is highly preferred that the carrier be a shampoo, and such a shampoo is capable of washing and conditioning the hair such that it is not difficult to handle after washing (and removing hair oils), which is often observed after shampooing because, when shampooing the hair, substances having conditioning properties are removed. In lieu of shampoos serving as carriers for the aminosilicones, other compositions may also be employed including solvents, gels, pastes, creams, lotions, emulsions, sprays, etc., and the aminosilicones may be applied to the fiber materials and hair in any conventional manner. Since the basics of such forms of cosmetic materials are well known, they are not specifically illustrated here, since the skilled person knows them anyway and can identify them from texts such as modem cosmetology.

The cationic surfactant fiber conditioning agents which may be considered as secondary conditioning agents in the fiber conditioning compositions of the invention are preferably quaternary ammonium salts, although other surfactants having fiber conditioning properties may also be used, at least in part. Thus, at least a portion of the quaternary ammonium salt can be replaced by imidazolinium salts and betaines and such cationic materials as described in US Pat. No. 4,0000,777, as well as complexes of cationic and anionic surfactants as described in US Pat. No. 06 / 916,067.06 / 916068 and 06/916069.

The preferred quaternary ammonium salts have the formula R ⁹ , R ¹⁰ , R ¹¹ , R ¹² N ⁺ X ^- , wherein at least one of the R groups is lower alkyl and at least one higher alkyl, the others being higher and / or lower alkyl , Preferably, R ^{9 is} lower alkyl, for example, of 1 to 4 carbon atoms, R ¹⁰ and R ^{11 are} higher alkyls of 10 to 40 carbon atoms, R ' ^{2 is} such higher alkyl or lower alkyl and X - is a salt-forming anion, such as halide, lower alkosulfate or a lower carboxylic acid radical, e.g. As chloride, Brorn ^, methosulfate, ethosulfate, citrate or acetate. The lower alkyl preferably has from 1 to 3 carbon atoms, more preferably 1 or 2 carbon atoms and is most preferably methyl in most cases, the higher alkyl preferably has 10 to 22 carbon atoms, more preferably 12 to 18 or 20 carbon atoms, most preferably 14 to 18 carbon atoms, z. B. 16 or about 16 carbon atoms. The anion is preferably a halogen, such as chlorine, bromine or iodine, with chlorine and bromine being preferred and chlorine being most preferred.

The number of lower alkyls on the quaternary nitrogen is preferably 1 or 2, and the number of higher alkyls is usually 2 or 3. It has been found desirable to have at least 30 carbon atoms and preferably at least 34 carbon atoms in the quaternary ammonium salt , The most preferred higher alkyl is cetyl, the most preferred lower alkyl is methyl, the most preferred is quaternary ammonium halide tricetylmethylammonium chloride. Nevertheless, it is within the scope of the invention to use other quaternary ammonium halides, e.g. Distearyldimethylammonium chloride, dilauryldimethylammonium bromide, stearylcetyldimethylammonium chloride, trimyristylethylammonium bromide and trilaurylethylammonium chloride, and other fiber and hair conditioning canonic surfactants, at least as part of the content of the inventive compositions to fiber and hair conditioning cationic substances. (Surfactant is a shorthand for surfactant.) As indicated above, the fiber conditioning compositions of the present invention may be in various suitable forms, although they are preferred in aqueous liquid form. The compositions may be used directly or dissolved and / or dispersed in water or other aqueous medium. Preferred compositions are shampoos, which usually contain a detergent with an anionic surfactant and water, but the preferred aminosilicones can also be incorporated into non-cleansing formulations with suitable carriers, such as thickened aqueous media, emulsions, microemulsions and stable dispersions, preferably also cationic conditioning agents , Optionally, amphoteric, ampholytic, zwitterionic and nonionic surfactants and surfactants may be used in the aforementioned shampoos in place of or with the anionic surfactant (s). Various suitable such detergents or surfactants and surfactants are described in McCutcheon's Detergents and Emulsifiers, North American Edition, 1984.

The preferred anionic cleaning substances or surfactants also described in the McCutcheon book may be referred to as sulfonated or sulfated (sulfonated). These are water-soluble lipophilic sulfates and / or sulfonates of 8 to 22 carbon atoms, preferably 10 to 20 carbon atoms, more preferably 10 to 16 or 18 carbon atoms, and most preferably 12 to 16 or 18 carbon atoms. Among the anionic surfactants there can be exemplified higher (C) ₂ to C ") alkyl sulfates, higher paraffin sulfonates, higher olefin sulfonates, higher fatty acid monoglyceride sulfates, higher fatty alcohol lower alkoxy (and polyoxy) sulfates, linear higher alkyl alkylbenzenesulfonates and dialkyl sulfosuccinates. The most preferred of these anionic surfactants for the shampoos of the invention are the higher alkyl sulfates of 12 to 16 carbon atoms and the higher alkyl lower alkoxy sulfates of 16 to 18 carbon atoms (preferably the higher alkyl of which is lauryl with 2 or 3 ethoxy groups per mole). However, such alkyls may have 12 to 16 carbon atoms and the alkoxy content may be 1 to 20 per mole, such as 2 to 6 ethoxy radicals each

Mol. A most preferred higher fatty alcohol sulphate is lauryl sulphate, and a particularly preferred higher fatty alcohol polynediol alkoxysulphate is di- or triethoxylated lauryl alcohol sulphate. Most preferred as the anionic surfactant is a mixture of higher alkyl sulfate and higher alkyl ether sulfate, each in greater or equal proportion, and wherein the ratio of the amounts of these components is in the range of 10: 1 to 1:10 or 7 : 1 to 1: 7, eg 1: 5 to 5: 1, when these two anionic surfactants are present.

The anionic tonsides are used in the form of their water-soluble salts, which are usually the salts of alkali metals (sodium, potassium), ammonium, amines (such as dimethylamine and trimethylamine) or lower alkanolamines (such as triethanolamine, diethanolamine and monoethanolamine). Examples of useful surfactants are ammonium lauryl sulfate, sodium lauryl diethoxysulfate, ammonium lauryl triethoxysulfate, sodium alpha-cis-olefinsulfonate, sodium Cn paraffin sulfonate, sodium cocomonoglyceride sulfate, triethanolamine cetyl sulfate and dimethylamine myristyl sulphate. For best results, however, it is preferable to use higher alkyl sulfate, higher alkyl poly-lower alkoxysulfate, or a mixture of such higher alkyl sulfate and higher alkyl ether sulfate, such as lauryl sulfate and lauryl diethoxysulfate or lauryl triethoxy sulfite. obei the higher alkyl sulfate is often present in a larger proportionate amount and in ammonium, triethanolamine and / or sodium salt form.

The water used in the aqueous compositions of the invention including preferred shampoos is preferably demineralized water having a hardness gel less than 10 ppm as CaCO ₃ , but other water may also be used if circumstances require. In order for the compositions of the present invention to be free of microorganisms, it is preferred to use irradiated demineralized water and to maintain the various mixing vessels, tanks, tubes and containers used in a clean condition.

In addition to the necessary ingredients of the conditioning compositions of the present invention, including shampoos which are preferred embodiments thereof, various adjuvants known in the art for this purpose or as discovered by the Applicant may also be used in these compositions show desirable effects in the compositions of the invention. Among these excipients may be mentioned: paraffins, petrolatum types, microcrystalline waxes, isoparaffins, mineral oils and polyethylenes, all of which are contained in co-pending patent application law file 29520 (corresponding to USSN 07/369361, of which the above-mentioned US SN 432952 is a continuation-in-part ) as well as in the aforementioned co-pending patent application corresponding to Attorney Docket No. 29251 and which are valuable for further improving the conditioning effects of the base compositions of the invention. These materials, while not necessary ingredients of the base compositions of the invention, are very valuable adjuvants and significantly improve the conditioning effects of the compositions of the present invention. When the polyethylene is used it is accompanied by a solubilizing hydrocarbon such as a mineral oil, although other liquid or near liquid hydrocarbons may also be used for this purpose. Other useful excipients or unnecessary ingredients of the conditioning compositions and shampoos include lower fatty acid esters of lower fatty acids, lower fatty acid esters of higher alcohols and higher fatty acid esters of higher alcohols, and mixtures thereof as described in US Pat. No. 07 / 365,391; Thickeners such as lower alkylcelluloses and hydroxy-lower alkylcelluloses, eg, methylcellulose and hydroxypropylmethylcellulose, and gums such as xanthan gum, which may also act as stabilizers for the aqueous compositions; Foam modifiers, such as betaines, higher fatty acid triglycerides, and higher fatty acid alkanolamides. For example, cocoamidopropyl betaine, C ₁ to C 6 acid triglycerides and lauric monoethanolamide; pearlescent appearance imparting agents such as ethylene glycol mono- and distearates; anti-scale substances such as zinc pyrithione; viscosity controlling substances such as propylene glycol and sodium chloride; Protective substances and antioxidants; Antifreeze agents such as ethylene glycol; Sequestering agents such as EDTA; PH adjusting agents such as citric acid and citrates; coloring substances (dyes and water-dispersible pigments); and solvents such as ethanol and isopropanol.

The proportions of the various components of the compositions of the invention are such as to provide the desired fiber conditioning effects and increases in potency. Such improvements are achieved when the proportionate amount of cationic fiber conditioning surfactant is sufficient to add conditioning to the conditioning effect of the aminosilicone and also sufficient to enhance the dispersion of the Aininosiükons to be stabilized in the aqueous medium. The amount of anionic surfactant is such that the hair or other fiber is thoroughly cleaned, but also such that the aminosilicone and the cationic conditioning surfactant on the fiber or hair can be precipitated from the comparatively strong aqueous cleanser. The level of carbon material is such as to enhance the conditioning effects of the aminosilicone and the cationic conditioning agent. Finally, the proportions are such as to allow the composition to be stable upon storage, not settle and not separate, and that the water content be sufficient to form such a continuous aqueous medium in which the other components are maintained in a stable form ,

In the case of conditioning compositions other than shampoos, the proportions of aminosilicone, cationic surfactant and water are normally in the ranges of 0.1 to 10%, 0.1 to 10% and 50 to 99%, respectively, with arbitrarily different amounts of excipient ( en) and surfactant, if present. When surfactant is present in these compositions, it is present in an amount in the range of 0.5 to 20%.

For shampoos and other cleansers that desirably condition fiber, the level of aminosilicone is usually in the range of 0.3 to 5%, preferably 0.5 to 5% and most preferably 1 to 3%, e.g. B. about 1,1,5,2 or 3%. The percentage ranges for the cationic surfactant conditioner are usually 0.1 to 5%, preferably 0.1 to 3%, more preferably 0.2 to 2%, and most preferably 0.3 to 1%, e.g. B. 0.5%. The percentage of anionic surfactant is normally 5 to 30%, preferably 8 to 25%, more preferably 10 to 20% and most preferably 12 to 18%, e.g. 15%. When a mixture of alkyl sulfate and alkyloxysulfate is present as the anionic surfactant, the amounts are usually 10 to 15% alkyl sulfate and 2 to 5% alkyl ether sulfate, although the proportions may be reversed in some cases. The water content is usually in the range of 50 to 85%, preferably 60 to 90%, and more preferably 65 to 80%, e.g. At about 70.73 or 75%. The content of auxiliaries is normally 0.1 to 30%, preferably 0.5 to 30%, preferably 0.5 to 20% and particularly preferably 3 to 15%, e.g. about 8 or 9%.

When a supplemental hydrocarbon conditioning agent is present, the percentage thereof is in the range of 0.5 to 20%, preferably 1 to 10%, and more preferably 1.5 to 5%. Preferred ranges of the hydrocarbon component are 0.1 to 5% microcrystalline wax with 0.1 to 3% paraffin, more preferably in each case 0.5 to 3% and 0.5 to 2%. When polyethylene and mineral oil are present to add their supplemental conditioning effect, the amounts are usually in the range of 0.2 to 5% polyethylene and 0.1 to 10% mineral oil, preferably 0.2 to 2% and 0.2 to 0.2 respectively 8%, and more preferably 0.3 to 1% and 0.5 to 5%, respectively.

For non-aqueous compositions, the necessary, optional and auxiliary ingredients are normally present in the same ranges of amounts as in the aqueous compositions when the water is removed. The aqueous medium may be omitted or replaced by another solvent or liquid medium, e.g. Ethanol or isopropanol be replaced in whole or in part.

As indicated above, the fiber conditioning, hair conditioning compositions of the invention may be in various physical forms and are preferably in liquid form, with a preferred mode of forming the invention being a hair conditioning shampoo. Such compositions should be chemically and physically stable in order to be accepted in the marketplace. They should not deteriorate to an unacceptable extent during storage, separate out any ingredients or separate them into phases. Also, the shampoos should have desirable viscosities to be pourable and still not be so thin that they run uncontrollably. The desired viscosity range is 1000 to 15000cps at room temperature (25 ⁰ C), preferably 3000 to 6000cps and more preferably the viscosity is about 3500 or 4000cps at room temperature. The shampoos according to the invention are non-settling and non-separating, they do not deteriorate during storage, as determined by accelerated aging tests at elevated temperature. The shampoo viscosity may change slightly during storage, but it does affect it! such an increase does not enhance the properties of the shampoo. Also, the desired application viscosity may be planned and the shampoo may be concentrated to have the desired viscosity when used as normally expected by the consumer.

The improved hair conditioning obtained by employing the compositions of the present invention as compared to control products omitting any aminosilicone and cationic conditioner or hydrocarbon conditioner is very clear to the occasional consumer of the shampoo or other conditioning composition of the present invention and is measurable in standard tests employed to assess conditioning and its factors, including ease of wet combing, ease of dry combing, handleability, electrostatic charge retention and flying away. The occasional shampoo user will find that the hair after shampooing is easier to comb both moist and dry as compared to control hair which is washed with a shampoo not falling within the scope of the invention (in which one or more ingredients are omitted were). Scientific tests also show that the force required to move a comb through a standard hair sample after treating (shampooing) the hair with a shampoo and rinsing according to the invention is measurably lower than when such a control product is used in the same manner. These results were confirmed by tests in which a panel of experienced reviewers using both the invention control and control products in blind tests tested for ease of combing, handleability, and electrostatic properties and effects.

The use of the compositions of the invention, including the shampoos, need not be different from conventional applications of hair conditioning shampoos and other conditioning compositions. Conditioning substances may be applied in normal amounts at room temperature or slightly elevated temperatures and left on the hair at different rates, depending on the degree of conditioning desired. Usually, the conditioning agents are the hair at a temperature in the range of 15 to 50 ° C, preferably 20 to 40 ° C, and the conditioner is in contact with the hair for 30 seconds to 10 minutes, preferably one to five minutes. The amount of applied. Composition is usually in the range of 0.1 to 25 g, often 0.2 to 10 g or 0.5 to 2 or 5 g, based on the non-aqueous and non-solvent components of the compositions. On the basis of the shampoo that can be used, such application rates or amounts are in the range of 0.5 to 50 g, often 2 to 15 or 20 g and often 5 or 10 g per application. The applied composition may be brushed and / or combed through the hair and then washed out, may be left on the hair or partially removed, for example by means of a terry toweling. When the shampoo is applied to wash and condition the hair, it is rinsed with water after remaining on the hair as an aqueous foam for a sufficient time, usually 1 to 5 minutes, to condition the hair satisfactorily then damp combed, dried, for example, by blow-drying and dry-combed or brushed into the desired shape.

For the preparation of the compositions according to the invention, including the shampoos, no complicated processes have to be carried out; however, in order to obtain the best stability and conditioning effect after the compositions of the present invention are stored, it is desirable to form a dispersion of the water-soluble lipophilic sulfate and / or sulfonate including adjuvants in water at elevated temperature such as 70 to 90 ^° C, the cationic one conditioning agent such. B. the quaternary ammonium salt with any lipophilic materials such as hydrocarbons including polyethylene, mineral oil, microcrystalline wax, petrolatum, paraffin and isoparaffin melt or liquid mixture at elevated temperature to ', 3n and / or to disperse, and the two premixes increased in such Mixing temperatures, after which the heated mixture aminosilicone can be added to the resulting mixture and wherein the various mixing operations take place with the parts to be mixed at about the same temperatures. It is important that the aminosilicone be mixed in after the main premix; otherwise, it may separate or form an erratic composition. When adjuvants are present, those which are soluble and / or dispersible in water may be mixed with the aqueous phase materials, and those which are not water soluble or dispersible in the aqueous medium may be mixed with the lipophilic materials such as the hydrocarbons be added, or in some cases the mixture of hydrophilic and lipophilic materials either before or after cooling to room temperature. Usually, perfume is added to the other ingredients after cooling to room temperature, and the aminosilicone is heated at elevated temperature and before

added to this cooling. The perfume is added to the cooled composition to avoid loss thereof by volatilization of the components and to prevent decomposition in the heat. Failure to follow the described procedure, for example, by blending the various constituents of the compositions indiscriminately, can result in fickle products that separate or settle on storage and such unstable products tend to have poorer crystallizing properties than the durable conditioning compositions and shampoos that are found in the prior art process according to the invention can be produced. The following examples illustrate the invention without limiting it. Unless otherwise stated, all parts are by weight and all temperatures are in centigrade.

example 1

ingredients A weight C D e TeIII 75.89 B 75.14 74.54 73.64 demineralized water 0.45 75.64 0.45 0.45 0.45 • Natrosol * 250HHR 0.15 0.45 0.15 0.15 0.15 "Natrosol330CS 12.50 0.15 12.50 12.50 12.50 ammonium lauryl 2.50 12.50 2.50 2.50 2.50 Natriumlauryldiethoxysulfat 2.50 Part 2 0.75 0.75 0.75 0.75 ··· C ₁₈ - to cae acid triglyceride 0.75 0.75 0.75 0.75 0.75 ethylene glycol 0.35 0.75 0.35 0.35 0.35 stearylstearate 0.50 0.35 0.50 0.50 0.50 Propylenglykol.U.S.P. 3.50 0.50 3.50 3.50 3.50 lauric 0.50 3.50 0.50 0.50 0.50 Triethylmethylammonium chloride 0.50 0.50 Other 0.50 0.50 0.50 0.50 · »·» Protective material (Gemaben II) 0.10 0.50 0.10 0.10 0.10 Dye (red aqueous solution) 0.30 0.10 0.30 0.30 0.30 + Sodium chloride 0.01 0.30 0.01 0.01 0.01 + + Citric acid 0.75 0.01 1.50 2.00 3.00 Dow-Corning * Silicone "B" 12:50 1.00 0.50 0.50 0.50 Perfume 100.00 0.50 100.00 100.00 100.00 100.00

* Hydroxyethyl Cellulose (Hercules Corp.) '* Hydroxyethyl Cellulose (Hercules Corp.)

* · · Syncrowachs HGC-L (manufactured by Crocia Corp.)

* "* manufactured by Sutton Laboratories, Inc.

+ Sodium Chloride (Vlskosititsregler, can be used up to 0.5% to increase the Shampoo Viekoiität)

+ + pH regulator, can be applied up to 0.1% to lower the pH, or sodium citrate can be applied up to 0.1% to increase the pH.

To prepare the shampoo of the invention, the formulation amount of water was added to a first mixing vessel, mixing started and slowly sprinkling the formulation amounts of the Natrosols. Mixing was continued until the Natrosole were dissolved while heating the medium at about 5O ⁰ C. The mixing was continued until the temperature was in the range of 80 to 85 ^° C, after which the heat was turned back and mixing was continued. Then, the formulation amounts of ammonium lauryl sulfate and sodium lauryl diethoxysulfate were added. During the manufacture of the part 1, the ingredients of Part 2, including C ₁₈ were - to C _3e -Säuretriglycerid, ethylene glycol distearate, stearyl stearate, propylene glycol, lauric and tricetyl ammonium chloride added separately or together in a separate vessel and heated with mixing in this until one at a uniform melt or solution was obtained at a temperature in the range of 80 to 85 ° C. After both parts 1 and 2 were at about the same elevated temperature, part 2 was added to part 1 in the main mixing vessel, ensuring that foaming occurred during After mixing was complete, heating was stopped and mixing was continued for a further 10 minutes, after which the aminosilicone (Dow-Corning Silicone "B") was blended and mixing continued for an additional 10 minutes. After cooling the mixture to 39 ° C, the formulation amounts of perfume, protective agent and dye solution were added with mixing and added to sodium chloride and citric acid (or sodium citrate) in amounts as required to bring the viscosity to about 4000cps at 25 Sodium citrate and citric acid (or sodium citrate) were added when the viscosity was too low, ie outside the 4000 to 6000 cps range (measured with a Brookfield RVTD viscometer, spindle # A ₁ at 20 rpm). and when the pH is out of line Iac, although in some circumstances the pH may be as low as 5 or as high as 8).

After the preparation of the products 1 / A, 1 / B, 1 IC, 1 / D and 1 / E, their hair conditioning properties were evaluated using standard dry and wet combing techniques as described in the copending application of fiber conditioning compositions, solubilized poly Lower alkylene are described. The results of these tests are shown in Table 1.

Table 1

Test 1 / A 1 / B 1 / C 1 / D 1 / E

·· "rating of ease 4-5 6-7 7-8 8-9 10-11 of wet combing ·· * »Rating of ease 3-4 5-6 5-6 6-7 7-8 of dry combing

** - Ratings were on a scale of 1 to 10, with 1 representing the minimum conditioning (maximum resistance to combing) and 10 the maximum conditioning (minimal resistance to combing).

Rating 11 of composition 1 / E indicates that the conditioning and ease of wet combing is better than anything previously considered achievable.

A control shampoo of the same formulation as in this example was prepared except that the aminosilicone was omitted and replaced with water. Both the wet combing and dry combing values for this control shampoo were 1 to 2, showing the great improvement in the conditioning effect achieved and its dependence on the presence of the particular aminosilicone described. When other aminosilicones were used in place of the silicone "B", such as the Dow-Corning silicones "C" and "D", which have a similar general formula but higher charge density and lower molecular weight in some cases, significantly lower values result Labeling evaluation Even though the formulations were modified by the addition of microcrystalline wax (mp = -82 ° C.) and petrolatum, 0.2 to 1% of microcrystalline wax, eg 0.5%, and 0.2 to 1 , 5% petrolatum, 0,7 B. 0.7%, used and lowered the water content for compensation, the dry comb values were significantly increased in the compositions 1 / C, 1 / D and 1 / E. More importantly, a significantly lower Wegflug in all of these hydrocarbon-containing compositions.

Example 2

ingredients A Wt .-% C 73.73 B 73.23 irradiated demineralised water 0.37 73.93 0.45 Natrosol250HHR 0.13 0.45 0.15 Natrosol330CS 12.50 0.45 12.50 ammonium lauryl 2.50 12.50 2.50 Natriumlauryldiethoxysulfat 1.00 2.50 0.20 microcrystalline wax (mp = 82 ° C) 0.75 0.20 0.75 CtS to cae acid triglycerides 1.00 0.75 0.20 snow-white petrolatum 0.50 0.20 0.50 tricetylmethylammonium chloride 0.75 0.50 0.75 ethylene glycol 0.50 0.75 0.50 Propylene Glycol U.S. P. 3.50 0.50 3.50 Laurinsäureethanolamid 0.35 3.50 0.35 stearylstearate 0.35 Other 1.00 3.00 Dow-Corning Silicone "B" 0.10 2.00 0.10 sodium chloride 0.50 0.10 0.50 protectant 0.01 0.50 0.01 citric acid 0.31 0.01 12:31 Dye solution (5% aqueous solution) 0.50 0.31 0.50 Perfume 100.0 0.50 100.0 100.0

Compositions 2 / A, 2 / B and 2 / C were prepared according to the procedures described in Example 1 and tested according to the methods also described therein. The products are durable shampoos that can be kept in normal conditions for a year or more without deteriorating or losing their conditioning power and without separating or settling the components. The three shampoos were each adjusted to a viscosity in the range of 3,500 to 4,000 cps at 25 ° C, with each adjustment made by adding sodium chloride to thicken the shampoo to the desired viscosity. Also, the pHs thereof were in the range of 6 to 7, normally about 6.5, with adjustment of the pH by addition of citric acid and / or sodium citrate as needed. When using the shampoos to wash and condition human hair at the same time, evaluations of this hair after washing and rinsing (and drying if desired) show that the products produced are excellent conditioning shampoos. The ratings (on the same basis as described in Example 1) for wet and dry combing are both for 2 / A and 2 / B 9-10 and the ratings for 2 / C are 10-11 for both wet and dry combing , Thus, these examples show that, using more of the specific aminosilicones of the invention, conditioning is improved. In addition, it is shown that in the presence of microcrystalline wax and petrolatum a smaller amount of amino silicone can be used, and that a

Conditioning can be obtained according to the composition containing more amino silicone and less microcrystalline wax. It might therefore be expected that by further increasing the level of microcrystalline wax and petrolatum in formula 2 / C, even better conditioning than 10-11 can be achieved, but care must be taken to avoid any excessively waxy feel of the conditioned one. Hair to avoid.

A further advantage of the invention is that the shampoos of the present invention, while having significant levels of very potent or effective anionic surfactant (s), do not prevent the deposition of the contained conditioning agents on the hair or other fibers to be conditioned. Also, the conditioners, while substantive to the hair and not removed from it by anionic surfactant during washing, are not prone to build up excessive deposits on the hair upon repeated shampooing of the hair with the conditioning shampoos and thereby do not render the hair in impermissibly fat. Overall, the conditioning agents, in particular the aminosilicones, from the aqueous solutions of the shampoo ingredients according to the invention during shampooing in an excellent manner on the hair for liability, but do not form complaining deposits on the hair, which make it fat or otherwise its physical Properties would affect.

Example 3 Ingredients

Weight ⁰ /

Water (irradiated, demineralised) 73.13 68.13 68.13 70.03 73.13 73.13 69.13 71.13 Natrosol250HHR 0.37 0.37 0.37 0.37 0.37 0.37 0.37 0.37 Natrosol330CS 0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.13 ammonium lauryl 15.00 - - 2.50 - - 12.50 12.50 "Ammoniumlaurethoxysulfat - 20.00 - - - 7.50 - - Natriumlaurethoxy (2EtO) sulfate - - - - - 7.50 2.50 2.50 Sodium alpha C ₂ - to _{C) 6} olefin sulfonate - - - - 15.00 - - - cocoamidopropyl - - - - - - 3.50 - Sodium decethoxy (3 EtO) sulfate - - 20.00 15.00 - - - - microcrystalline wax (mp = 82 "C) 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Ct ₈ - to C ^ acid triglyceride 0.75 0.75 0.75 0.75 0.75 0.75 Petrolatum (snow white) 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 tricetylmethylammonium chloride 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 Ethylenglykoldistenrat 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 PropylenglykoLU.S.P. 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 lauric 3.50 3.50 3.50 3.50 3.50 3.50 3.50 3.50 stearylstearate 0.35 0.35 0.35 0.35 0.35 0.35 0.35 0.35 Amino silicone (Dow-Corning "B") 1.50 1.50 1.50 1.50 1.50 1.50 1.50 1.50 °° climbazol - - - - - _ _ 0.50 °°° piroctone olamine _ _ - _ _ _ 0.50 "" "Zinc pyrithione - - - - - - - .1,00 sodium chloride 0.20 0.20 0.20 0.20 0.20 0.20 0.20 0.20 Protectorate (Germaben II) 0.50 0.50 0.50 0.50 0.50 0.50 0.50 0.50 sodium citrate 0.01 0.01 0.01 0.01 0.01 0.01 0.01 U, 01 aqueous dye solution (1% solution) 0.31 0.31 0.31 0.31 0.31 0.31 0.31 0.31 Perfume 0.75 0.75 0.75 0.75 0.75 0.75 0.75 0.75 100.00 100.00 100.00 100.00 100.00 100.00 100.00 100.00

° with 1 to 3 ethoxy groups, e.g. B. 2 EtO

Shingling agent manufactured by Bayer

Antihalation agent manufactured by Hoechst as Octopirox

°°°° antiperspirant, manufactured by Olin Industries

Compositions A to H of this example were prepared according to the procedures previously described in Examples 1 and 2. The various compositions prepared, which are all compositions of the invention, all show improved hair conditioning properties including easier combing, better handling, less flight away (which is in part attributed to the presence of microcrystalline wax and petrolatum in all formulations), and repeated shampooing with the compositions does not objectionable rubbery deposits on the hair, which may result in the application of cationic rubber conditioners instead of the described aminosilicones.

ingredients , A Wt .-% -11- 295 307 Example 4 73.63 B irradiated demineralised water 0.37 73.53 Natro3ol250HR 0:13 0.45 C Natrosol330CS 12.50 0.15 73.13 ammonium lauryl 2.50 12.50 0.4 ^c , Natriumlauryldiethoxysulfat 1.00 2.50 0.15 microcrystalline wax (mp = 82 ^° C.) 0.75 - 12.50 C ₁₈ to Cse acid triglycerides 1.00 0.75 2.50 Petrolatum (white) 0.50 - 0.20 methosulfate 0.75 0.50 0.75 ethylene glycol 0.50 (5.75 0.20 propylene glycol 3.50 0.50 0.50 lauric 0.35 3.50 0.73 stearylstearate 1.00 0.35 0.50 Dow-Corning Silicone »B" 0.20 3.00 3.50 sodium chloride 0.50 0.20 0.35 Protective material (Garmaben II) 0.01 0.50 3.00 Sodium citrate or citric acid 0.31 0.01 0.20 aqueous dye solution (0.6% conc.) 0.50 0.31 0.50 Perfume 100.0 0J50 0.01 1000 0.31 0.50 100.0

The compositions of this example were prepared according to the method described in the previous examples and evaluated in a similar manner. The three shampoos produced are effective conditioning shampoos of the desired viscosity (4000 cps at 25 ° C) and pH (6.5). They are stable in storage and condition «ir ·«; · effectively shampooed hair. Shampoos 4 / B and A / C are more effective in improving the ease of wet combing than Shampoo 4 / A, however, despite the fact that it contains less amino silicone than the other shampoos, Shampoo 4 / A is characterized by improved (excellent ) Dry comb properties. To make consumer shampoo 4 / A even more acceptable, the amount of potrolatum in the formulation was reduced to 0.75% to avoid any trace of fat in the shampooed hair while still achieving satisfactory conditioning (including superior ease of dry combing) ,

Example 5 ingredients

Wt .-%

demineralized water 73.94 Natrosol250HHR 0.45 'Natrosol330AP 0.15 ammonium lauryl 12.50 Natriumlauryldiethoxysulfat 2.50 Ci ₈ - to Ca acid triglyceride 0.75 tricetylmethylammonium chloride 0.50 ethylene glycol 0.75 propylene glycol 0.50 lauric 3.50 stearylstearate 0.35 aqueous dye solution (0.6% conc.) 0.31 Germabenll 0.30 aminosilicone 3.00 Perfume 0.50

Hydoxyethyl Cellulose (Hercules Corp.)

100.00

Shampoos of the above formulation were prepared according to the previously described procedures using various aminosilicones to give shampoos identified as A, B, C, D and E. A control formulation or base formulation F was also prepared which did not contain silicone, but 3% demineralized water. Table 2 below identifies the aminosilicones in the various formulations (if present) and Table 3 gives the wet combing and dry combing ratings of these formulations.

Table 2

Identifications of the formulations

Identification of the Amlnosillkons

AmlnoSqulvalent

5 / A 5 / B 5 / C 5 / D 5 / E 5 / F

A B C D E F

4200 30000 2000 2000 1800

Table 3

properties 5 / A 5 / B 5 / C rating 5 / E 5 / F 5 / D Ease of the 4.5 8.5 2 1 2.5 wet combing 1 Ease of the 4.0 8.0 2 2 2.0 dry combs 2

From these data, it can be seen that some aminosilicones have a detrimental effect on hair conditioning or hardly affect them, whereas those of the invention, which are components of compositions A and B, measurably improve conditioning (as measured by ease of wet and dry combing has been). These compositions also improve the handleability of the hair.

Examples

In a modification of the formulations of the previous examples, omitting the various excipients so that the shampoos contained only the necessary ingredients, anionic surfactant (s), cationic surface-active conditioner (s), aminosilicone (s) and water, the preparations were less viscous than for commercial shampoos are desired, but they have been usefully applicable for shampooing and conditioning hair. When incorporating hydrocarbon ingredients such as microcrystalline wax and petrolatum, or polyethylene and mineral oil, with paraffin and / or isoparaffin also being added, into the formulations having the required base ingredients, the conditioning was further improved as indicated above.

In the various formulations of the examples, other materials mentioned in the description may be wholly or partially substituted for those mentioned in the examples and useful improvements in hair (and fiber) conditioning may be obtained. Thus, one can triethanolamine lauryl sulfate, sodium myristyl sulfate, Kaliumcetylsulfat, Triethanolaminmyristyldiethoxysulfat, sodium-C, 4 paraffin sulfonate, ammonium-C, o-olefinsulfonatoder Triethanolamincocomonoglyceridsulfat or mixtures use thereof as an anionic surfactant, and one can distearyldimethylammonium chloride, Trilaurylmethylammoniumchlorid, Stearylcetyldimethylammoniumchlorid or Dilauryldiethylammoniumchlorid instead of the cationic surfactant conditioning Agent and also receives improved conditioning. In the same way, instead of the specifically preferred amino silicones mentioned here, it is possible to use various aminosilicones (polymers) of the formula indicated and having the abovementioned molecular weights and amine equivalents. However, it is normally preferred to employ those in which R ¹ , R ² , R ³ , R ⁶ , R * and R ^{7 are} alkyls in the lower part of the carbon atom range of 1 to 6, for example 2 or less carbon atoms, and most preferred Have 1 carbon atom, and in which R ^{8 is} an alkyl group having 3 to 6 carbon atoms, preferably isobutyl. An important consideration in the choice of aminosilicone formulation is the feasibility and economics of production, so that R and the other alkyl substituents on the silicon atoms are often identical except for R ⁴ . The auxiliaries, various thickeners, viscosity regulators, foaming agents, foam modifiers, stabilizers, dispersants, protective agents, pH modifiers, etc. can also be replaced without impairing the achievable improved conditioning as stated in the description.

Further, the proportions of the components of the compositions of the Examples can also be changed by increasing or decreasing them by 10%, 20%, 30%, as long as these proportions are within the ranges given in the description, also achieving the mentioned improved conditioning effects , Finally, instead of the compositions of the examples, which are all shampoos, one can use the composition to clean and condition other materials, such as cotton, wool, and synthetic fibers, and modify the formulations by eliminating anionic surfactants, non-cleaning fiber and fiber To prepare hair conditioner preparations suitable for conditioning previously washed fibers and which may be used as hair rinses, foams or gels for conditioning gauze hair.

The various patent applications, patents and publications cited in the specification are intended to be included in the disclosure.

Claims (25)

A fiber conditioning composition having improved fiber conditioning properties, characterized in that it is an aminosilicone of the formula R ^x CH ₃ CII ₃ R ^s I I I R ² -Si-O- (Si-O) _x - (Si-O) _v -Si-R ⁶ R ³ CH ₃ R ⁴ R ^v wherein R ¹ , R ² , R ³ , R ⁵ , R ⁶ and R ^{7 are} alkyls of 1 to 6 carbon atoms, R ⁴ is -R ⁸ -NH-CH ₂ CH ₂ -NH ₂ , R ^{8 is} alkylene of 3 to 6 is carbon atoms, χ is an average number in the range of 100 to 10,000, y is an average number in the range of 1 to 10, and has an amine equivalent in the range of 4,000 to 60,000 and contains a carrier for the aminosilicane. A fiber conditioning composition according to claim 1, characterized in that the average number χ of the aminosilicone formula is in the range of 300 to 10,000, the average number y is in the range of 1 to 8, the amine equivalent is in the range of 5,000 to 50,000 , and that the carrier is an aqueous medium. A fiber conditioning composition according to claim I _1, characterized in that the average number χ is in the range of 500 to 10,000, the average number y is less than 5, the amine equivalent is 10,000 or 20μ to 40,000, and the carrier is a liquid detergent Is medium in which the aminosilicone is in a dispersed, dissolved or emulsified state. The fiber conditioning composition of claim 3, which is an aqueous liquid solution, emulsion or dispersion of the aminosilicone in a liquid detergent medium, characterized by comprising a detergent amount of a synthetic organic surfactant, a fiber conditioning amount of the amino silicone, a fiber conditioning improving amount of cationic fiber-conditioning surfactant and water. 5. A fiber conditioning composition according to claim 2, which is a shampoo for human hair, which is in aqueous liquid solution, emulsion or dispersion form, characterized in that it contains a cleansing amount of anionic surfactant, a hair conditioning amount of the aminosilicone, a fiber conditioning containing an improving amount of the cationic hair conditioning surfactant, shampoo aids and water. 6. Hair conditioning shampoo according to claim 5, characterized in that it contains 5 to 30% of water-soluble anionic surfactant, 0.3 to 5% of the aminosilicone, 0.1 to 5% of the cationic, surface-active hair conditioning agent, 0.1 to 30% auxiliaries for the shampoo and contains up to 95% water. 7. hair conditioning shampoo according to claim 6, characterized in that it contains 5 to 30% of water-soluble, synthetic organic lipophilic sulfate and / or sulfonate anionic surfactant having 8 to 20 carbon atoms in the lipophilic group thereof, 0.3 to 5% of the aminosilicone, 0 , 1 to 5% quaternary ammonium salt as a cationic conditioning agent of the formula R ⁹ , R ¹⁰ , R ¹¹ , R ¹² N ⁺ X-, wherein R ^{9 is} lower alkyl of 1 to 4 carbon atoms, R ¹⁰ and R ^{11 are} higher alkyls of 10 to 14 carbon atoms, R ^{12 is} lower alkyl or higher alkyl, and X is a salt-forming anion, contains 0.1 to 30% shampoo and 50 to 95% water adjuncts. 8. hair conditioning shampoo according to claim 7, characterized in that it contains 8 to 25% of water-soluble sulfate and / or sulfonate surfactant having 8 to 18 carbon atoms in the lipophilic group thereof, 0.5 to 5% of the aminisilicone, 0.1 to 3% quaternary ammonium halide, wherein X in the formula given represents a halogen, chlorine, bromine or iodine or any one of them Mixture thereof, and wherein the sum of the numbers of carbon atoms is at least 30, 0.5 to 20% auxiliaries and 60 to 90% water. 9. hair conditioning shampoo according to claim 8, characterized in that it contains 10 to 20% of water-soluble lipophilic sulfate or a mixture thereof, 0.8 to 4% of the aminosilicone, 0.2 to 2% quaternary ammonium halide, wherein the halogen is chlorine or bromine or a mixture thereof, containing 3 to 15% of auxiliaries and 65 to 80% of water, and in that the shampoo has a viscosity in the range of 1500 to 100,000 cps at 25 ° C. 10. Hair conditioning shampoo according to claim 9, characterized in that it is 12 to 18% anionic surfactant, the alcohol sulfate of 10 to 18 carbon atoms in the alkyl thereof and / or alcohol ether sulfate of 10 to 18 carbon atoms, the 1 to 3 ethoxy groups in the ether moiety thereof, wherein the cations of these salts are alkali, ammonium and / or lower alkanolamine of 1 to 3 carbon atoms in the alkanol, 1 to 3% of the aminosilicone, 0.3 to 1% of quaternary ammonium chloride in which formula R ^{4 is} higher alkyl until 15% auxiliaries and 65-80% water, the shampoo has a viscosity in the range 3000 to 6000 cps at 25 ° C and a pH in the range 5 to 8. 11. A hair conditioning shampoo according to claim 10, characterized in that it contains about 13% ammonium lauryl sulfate, about 3% Natriumlauryldiethoxysulfat, about 3% of the aminosilicone, about 0.5% Tricetylmethylammoniumchlorid, about 8% auxiliaries and about 73% water that the viscosity about 3500 oder4000cps at 25 ⁰ C and in that the pH in the range of 6 to 7. 12. Hair conditioning shampoo according to claim 6, characterized in that it contains 0.5 to 20% of a hydrocarbon or a mixture of hydrocarbons of the group of normally solid polyethylene, mineral oil, paraffin, isoparaffin, petrolatum and microcrystalline wax. 13. Hair conditioning shampoo according to claim 7, characterized in that it contains 0.1 to 3% microcrystalline wax and 0.1 to 2% paraffin. 14. Hair conditioning shampoo according to claim 8, characterized in that it contains 0.5 to 2% microcrystalline wax and 0.5 to 1.5% paraffin. 15. Hair conditioning shampoo according to claim 6, characterized in that it contains 0.2 to 5% of a normally solid polyethylene and 0.1 to 10% of a normally liquid mineral oil, wherein the mineral oil makes the polyethylene dispersible, emulsifiable or soluble in water, and increases its hair conditioning effects. 16. Hair conditioning shampoo according to claim 7, characterized in that it contains 0.2 to 2% of a normally solid polyethylene and 0.2 to 8% of a normally liquid mineral oil, wherein the mineral oil makes the polyethylene dispersible, emulsifiable or soluble in water. 17. A method of conditioning fibers, characterized by applying to these fibers a conditioning amount of a composition according to claim 1 in such a way that this composition is distributed over these fibers. 18. A method according to claim 17, characterized in that the fibers to be conditioned are human hair and that the conditioning composition is a shampoo containing a cleansing amount of synthetic organic anionic surfactant, a hair conditioning amount of an aminosilicone of the formula R ¹ CH ₃ CH ₃ R ⁵ R ² - Si - O - (Si - O) _x - (Si - O) _y - Si - Ro, ι ι ι · R ³ CH ₃ R ⁴ R ⁷ wherein R ¹ , R ² , R ³ , R ⁵ , R ⁸ and R ^{7 are} alkyls of 1 to 6 carbon atoms, R ^{4 is} R 1 is NH-CH ₂ CH ₂ -NH ₂ , R ^{8 is} alkylene of 1 to 6 carbon atoms where χ is an average number in the range of 300 to 5,000, y is an average number in the range of 1 to 8 and has an amine equivalent in the range of 10,000 to 50,000, a hair conditioner-improving amount of cationic, surface active hair conditioning agent , and an aqueous shampoo medium comprising water and shampoo auxiliaries, wherein the Apply by shampooing the hair and then the hair is rinsed and dried and damp and dry combed. 19. The method according to claim 18, characterized in that the hair conditioning shampoo 5 to 30% lipophilic sulfate and / or Sulfonataniontensid of 8 to 20 carbon atoms in the lipophilic group, 0.3 to 5% of the aminosilicone, wherein χ in the range of 500 to 500G, y is less than 5, the amine equivalent is in the range of 20,000 to 40,000, 0.1 to 5% quaternary ammonium salt is a cationic conditioning agent of formula R ⁹ , R ¹⁰ , R ¹¹ , R ¹² N ⁺ X where R ^{9 is} lower alkyl of 1 to 4 carbon atoms, R ¹⁰ and R ^{11 are} higher alkyls of 10 to 40 carbon atoms, R ^{12 is} lower alkyl or higher alkyl, and X "is a salt-forming anion, 0.1 to 30% auxiliaries for the shampoo, and 50 to 95% water, that the conditioning shampoo applied to the hair on the head in an amount of 2 to 15 g per shampoo, in contact with the hair as an aqueous foam for 1 to 5 minutes held and rinsed w The hair is then combed, dried and combed dry. 20. The method according to claim 18, characterized in that the hair conditioning shampoo contains 0.5 to 20% of a hydrocarbon or a mixture of hydrocarbons of the group of normally solid polyethylene .. mineral oil, paraffin, isoparaffin, petrolatum and microcrystalline wax. 21. The method according to claim 19, characterized in that the hair conditioning shampoo contains 0.5 to 2% microcrystalline wax and 0.5 to 1.5% paraffin. 22. A method for producing a stable hair conditioning shampoo of the composition of claim 6, characterized in that mixing the components except the aminosilicone and heated to an elevated temperature at which the aminosilicone, when heated, by mixing with this composition and followed by cooling, forming an emulsion, solution or stable dispersion by heating the aminosilicone and mixing the aminosilicone and the aminosilicone-free composition for one minute to one hour to disperse the aminosilicone in the composition and to form the composition cools resistant emulsion, solution or dispersion form. 23. A process for producing a stable hair conditioning shampoo of the composition of claim 16, characterized in that the polyethylene and mineral oil are heated together to a temperature in the range of 70 to 90 ⁰ C to melt the polyethylene and / or in the mineral oil to dissolve and / or to disperse by processing the remainder of the ingredients, except the aminosilicone, for dispersing, emulsifying or dissolving, by mixing the ingredients thereof and heating to a temperature in the range of 70 to 90 ° C mixing the two premixes at this elevated temperature to each other, and that adding the aminosilicone at a temperature in the range of 70 to 9O ⁰ C, the combination of the premixes and the mixture is cooled to room temperature to obtain a stable hair conditioning shampoo that on storage does not deteriorate, separate or settle before use. 24. The method according to claim 19, characterized in that R ¹ , R ² , R ³ , R ⁵ , R ⁶ and R ^{7 are} each methyl groups, R ^{8 is} an isobutyl group and the χ is in the range of 750 to 800, y is 1 and the amine equivalent is 30000. 25. A fiber conditioning composition according to claim 3, characterized in that R ¹ , R ² , R ³ , R ⁵ , R ⁶ and R ^{7 are} each methyl groups, R ^{8 is} an isobutyl group and in that the average χ in the range of 750 to 800 is, the average y is 1, the amine equivalent is 30,000 and that the carrier is a liquid detergent medium in which the amino silicone is in a dispersed, dissolved or emulsified state.