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DD263890A3 - PROCESS FOR OBTAINING 2-ALKOXYPROPENES - Google Patents

PROCESS FOR OBTAINING 2-ALKOXYPROPENES Download PDF

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Publication number
DD263890A3
DD263890A3 DD85281267A DD28126785A DD263890A3 DD 263890 A3 DD263890 A3 DD 263890A3 DD 85281267 A DD85281267 A DD 85281267A DD 28126785 A DD28126785 A DD 28126785A DD 263890 A3 DD263890 A3 DD 263890A3
Authority
DD
German Democratic Republic
Prior art keywords
πρκ
henpe
cmech
atm
alkoxypropenes
Prior art date
Application number
DD85281267A
Other languages
German (de)
Inventor
Boris A Agre
Anatolij M Taber
Aleksandr E Presnov
Oleg N Temkin
Gennadij K Sestakov
Marija A Miropolskaja
Gleb I Samochvalov
Valerij V Beregovych
Igor V Kalecic
Sergej P Cerhych
Original Assignee
Boris A Agre
Anatolij M Taber
Aleksandr E Presnov
Oleg N Temkin
Gennadij K Sestakov
Marija A Miropolskaja
Gleb I Samochvalov
Valerij V Beregovych
Igor V Kalecic
Sergej P Cerhych
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Boris A Agre, Anatolij M Taber, Aleksandr E Presnov, Oleg N Temkin, Gennadij K Sestakov, Marija A Miropolskaja, Gleb I Samochvalov, Valerij V Beregovych, Igor V Kalecic, Sergej P Cerhych filed Critical Boris A Agre
Priority to BG71894A priority Critical patent/BG48384A1/en
Priority to DD85281267A priority patent/DD263890A3/en
Priority to CS857310A priority patent/CS266243B1/en
Publication of DD263890A3 publication Critical patent/DD263890A3/en

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Abstract

Das Verfahren zur Gewinnung von 2-Alkoxypropenen besteht in der Wechselwirkung von aliphatischen C1C2-Alkoholen mit Allen oder Allen im Gemisch mit Methylacetylen in Gegenwart von Aetzalkali bei 190...240C und 41...62 atm im Laufe von 2,5...4 h.The process for obtaining 2-alkoxypropenes consists in the interaction of C1 -C2 aliphatic alcohols with allene or allene in admixture with methyl acetylene in the presence of caustic alkali at 190-240C and 41-62 atm over 2.5 hours. .4 h.

Description

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HdU 9SBIfHOiSB HOW9hlOIBhBH S HÖH (W gO'O) J /,Ί H ΒΗΘΜϋθϊΙΒ -IfHi9W (W 21gΌ) Ί 9*21 'BidHUO 0J0S0IfHi9W (W 2Ig'O) Ί OI W9HHBS9dJBH iOKIfSiOOlllÄOO BH9U0dUH0H0i9W~gHdU 9SBIfHOiSB HOW9hlOIBhBH S HÖH (W gO'O) J /, Ί H ΒΗΘΜϋθϊΙΒ -IfHi9W (W 21gΌ) Ί 9 * 21 'BidHUO 0J0S0IfHi9W (W 2Ig'O) Ί OI W9HHBS9dJBH iOKIfSiOOlllÄOO BH9U0dUH0H0i9W ~ g

t9Zt9Z

ΠρΗΜβρ 5ΠρΗΜβρ 5

Cnoooö nojiy^eHHfl 2-MeTOKCHnponeHa npOBOflHT ksik β npn-Mepe 4, ho oepyT 12,5 r azuieHa. CocTaB pearajHOHHOH CMecn/r/: ajuieH - 4,30Cnoooö nojiy ^ eHHfl 2-MeTOKCHnponeHa npOBOflHT ksik β npn-Mepe 4, ho oepyT 12,5 r azuieHa. CocTaB pearajHOHHOH CMecn / r /: ajuieH - 4.30

3-ΜΘΤΟΚΟΗΠρθΠβΗ - 13,73-ΜΘΤΟΚΟΗΠρθΠβΗ - 13,7

- 0,1- 0.1

- 3,4- 3,4

- 0,2- 0.2

c μ ο λ a - 0,8c μ ο λ a - 0.8

Bee neperHaHHoft φρβκιμίΗ - 21,7 KoHBepcHH no MeTaHOJiy cooTaBJineT 66/?,Bee neperHaHHoft φρβκιμίΗ - 21,7 KoHBepcHH no MeTaHOJiy CooTaBJineT 66 / ?,

92,6$, bhxoä no 3-MeTOKCHnponeHy paßeH (>3 ΒΗΛβΛβΗΗΙιΙΟ 2^Λ6ΤΟΚΟΗΠρθΠβΗ Η,ΙίβΗΤΙΐφίΠμίρΟΒΒΗ KaK B$ 92.6, bhxoa no 3-MeTOKCHnponeHy paSSH (> 3 ΒΗΛβΛβΗΗΙιΙΟ 2 ^ Λ6ΤΟΚΟΗΠρθΠβΗ Η, ΙίβΗΤΙΐφίΠμίρΟΒΒΗ KaK B

Mepe I.Mepe I.

2-BTOKCHnponeH nojiy^aioT aHajronwHO npHMepy I β Te*ieHne HacoB npH TeivmepaType 21O0C n ,EtaBJieHHii 24 aTM c büxoäom 61,6^; T0KHn. = 620C, ^ 1,3929,2-BTOKCHnponeH nojiy ^ aioT aHajronwHO npHMepy I β Te * ieHne HacoB npH TeivmepaType 21O 0 C n, EtaBJieHHii 24 aTM c büxoäom 61,6 ^; T 0 KHn. = 62 0 C, ^ 1.2929,

IIpnMep 6 (CPaBHHTeJiLHIiM)IIpnMep 6 (CPaBHHTeJiLHIiM)

nojiyHeHHe 2-MeTOKCimponeHa ocymecTBJinioT HarpeBaHneM r (0,312 μ) MeTaHOJia, 12,5 r (0,312 μ) MeTiüiaqeTHjieHa η 1,7 r (0,03 μ) KOH β Ka^aiomßMCH aBTOKJiaBS πρκ 1900C β τβΗβΗΗβ 4 ^aCuB πρΗ ,ΠΕΒΛβΗΜΗ 41 aT. 3aTeM peaKiflioHHyK) Maccy H3BJieKaioT He aBTOKJiasa n pasjoHHWT. Πο λ&ηηημ ISX cocpeaKunoHHoß CMecHnojiyHeHHe 2-MeTOKCimponeHa ocymecTBJinioT HarpeBaHneM r (0.312 μ) MeTaHOJia, 12.5 r (0.312 μ) MeTiüiaqeTHjieHa η 1.7 r (0.03 μ) KOH β Ka ^ aiomβMCH aBTOKJiaBS πρκ 190 0 C β τβΗβΗΗβ 4 ^ aCuB πρΗ, ΗΜΗβΗΜΗ 41 aT. 3aTeM peaKiflioHHyK) Maccy H3BJieKaioT He aBTOKJiasa n pasjoHHWT. Λο λ & ηηημ ISX cocpeaKunoHHoss CMecH

we TKjiaue THjie Hwe Tkjiaue THjie H - 5,6- 5,6 3-ΜβΤΟΚΟΗΠρθΠ6Η3-ΜβΤΟΚΟΗΠρθΠ6Η - 10,8- 10,8 CUJLC X KJ ti CUJLC X KJ ti - 0,1- 0.1 IVkC/ JLd Γ* \Jw X IVkC / JLd Γ * \ Jw X - 4,5- 4,5 ,HHMe THJiKe TajiBaue το Ha, HHMe THJiKe TajiBuilding το Ha - ο,ΐ- ο, ΐ c μ ο Ji ac μ ο Ji a - 1,4- 1.4 Bee neperKaHHoii φρακακΗBee neperKaHHoii φρακακΗ - 21,1- 21.1

no MtiTaHOJiy cocTaBJiHeT 55%, οθλοκτηβηοοτβ no 2-MeTOKCHnponeHy - 47,9/>5.no MtiTaHOJiy cocTaBJiHeT 55%, οθλοκτηβηοοτβ no 2-MeTOKCHnponeHy - 47,9 /> 5.

2-ΜβτοκοϋπροπβΗ HfleHTH^HpoBaH KaK β πρκ-Mepe I.2-ΜβτοκοϋπροπβΗ HfleHTH ^ HpoBaH KaK β πρκ-Mepe I.

ΠρΗΜβρ 7ΠρΗΜβρ 7

2-MeTOKCHnponeHa προΒο,ζνϊτ aHanorHHHO2-MeTOKCHnponeHa προΒο, ζνϊτ aHanorHHHO

-6-py 6, ho oepyT 12,5 r ΜΑΦ. CocTaB peaKimoHHOä ομθοη/γ/;-6-py 6, ho oepyT 12.5 r ΜΑΦ. CocTaB peaKimoHHOä ομθοη / γ /;

ΜΑΦ - 3,4ΜΑΦ - 3,4

3-MeTOKCHnponeH - 16,23-MECHANICS - 16,2

aqeTOH - 0,0aqeTOH - 0.0

MeTaHOJi -2,8MeTaHOJi -2.8

,HHMe TiijiKe TajiBaije το he -0,1, HHMe TiijiKe TajiBaije το he -0,1

CMOJia - 0,9CMOJia - 0.9

Bee neperHaHHOH φραΐοίΗΗ - 21,6Bee neperHaHHOH φραΐοίΗΗ - 21,6

KoHBepcHH no MeTaHOJiy cocTäBjiffeT 72$, cejieKTHBHocTB 04,2$, BHXO1H no 2-MeTOKCHnponeHy paseH 67,8$.KoHBepcHH no MeTaHOJiy cocTäBjiffeT $ 72, $ cejieKTHBHocTB 04.2, BHXO 1H no 2-MeTOKCHnponeHy Paseh 67.8 $.

BH^ejieHHofi 2-ΜβΤ0Κ0ΗΠρθΠβΗ ΗΛβΗΤΗφΗΙίΗρΟΒβΗ KaK BBH ^ ejieHHofi 2-ΜβΤ0Κ0ΗΠρθΠβΗ ΗΛβΗΤΗφΗΙίΗρΟΒβΗ KaK B

Mepe I.Mepe I.

ΠρΗΜβρ 8ΠρΗΜβρ 8

Cnocoö nojijraenHH 2-MeTOKCHnponeHa ocymecTB.iflifOT HO npHMepy 6, ho Hcnoji&3yioT 12,5 r ajuiena. CocTaB CMecü/r/:Cnocoö nojijraenHH 2-MeTOKCHnponeHa ocymecTB.iflifOT HO npHMepy 6, ho Hcnoji & 3yioT 12.5 r ajuiena. CocTaB CMecu / r /:

- 0,2- 0.2

- 20,98- 20,98

- 0,1- 0.1

- 0,16- 0,16

- 0,1- 0.1

GMOJia - 0,94GMOJia - 0.94

Be neperHaHHofi φpaκ^ίIH - 21,56 KoHBepcHH no MeTaHOJiy cocTaBJiHeT 98,4^,Be neperHaHHofi φpaκ ^ ίIH - 21.56 KoHBepcHH no MeTaHOJiy cocTaBJiHeT 98.4 ^,

- 94,9$, BHXOfl no 3-MeTOKCHnponeHy paßeH 93,4^.- 94.9 $, BHXOfl no 3-MeTOKCHnponeHy fits 93.4 ^.

Bu,neΛβΗΗυίί 3-MeTOKCHnponeH ηρβϋτκφκιιμροΒαΗ KäK β πρκ-Mepe I.Bu, neΛβΗΗυίί 3-MeTOKCHnponeH ηρβϋτκφκιιμροΒαΗ KäK β πρκ-Mepe I.

flpHMepu noKasHBaioT, ^το MsuccmaajiBHuft B:a.xo.Ji β npe,zyiaraeMOM cnocoöe ,HocTHraioT πρκ HcnojiBaoBaHHH 62,6% ajmena. h BpeMeHH peaKUHH 2,5, jihöo 93,4^ ajuieHa η ΒρβΜβΗΗ η, ÄajiBHeHiiiee j^ejimieHne npo^ojiEiiTejiBHOcTH ripouecca 5j6 ν BejTGT κ cMojiooÖpasor.aiöiK).flpHMepu noKasHBaioT, ^ το Msuccmaaji contains B: a.xo.Ji β npe, zyiaraeMOM cnocooee, HocTHraioT πρκ HcnojiBaoBaHHH 62.6% ajmena. hBpeMeHH peaKUHH 2,5, jihoo 93,4 ^ ajuieHa η ΒρβΜβΗΗ η, ÄajiBHeHiiiee j ^ ejimieHne npo ^ ojiEiiTejiBHOcTH ripouecca 5j6 ν BejTGT κ cMojiooÖpasor.aiöiK).

McnojiB3OBaHHe cMecH ajiJiepia c MeTHjiauemjreHOM BaeT ,uocTHK6H::e Büxo,iia 49,6$ n 67,8$ npi τβχ κβ BpeMenax KOHTaKTa.McnojiB3OBaHHe cMecH ajiJiepia c MeTHjiauemjreHOM BaeT, uocTHK6H :: e BuXo, iia 49.6 $ n 67.8 $ npi τβχ κβ BpeMenax KOHTaKTa.

CpaBHHTeJIBHHH ΠρΗΜβρ HJUIWCTpHpyθT, MTO BKXOÄH B ΤβΧCpaBHHTeJIBHHH ΠρΗΜβρ HJUIWCTpHpyθT, MTO BKXOÄH B ΤβΧ

Ke ycJiOBHHX cocTaBJiHiOT TOJi&KO 39,6$ H 47,9$.Ke ycJiOBHHX cocTaBJiHiOT TOJi & KO $ 39.6 H $ 47.9.

"Hi0OHSJtLHBIf90 HHH9ÄHHQ B8-SH BffOXHS"Hi0OHSJtLHBIf90 HHH9ÄHHQ B8-SH BffOXHS

(HHH9ffBII H iHtfOSHdll O0OK? 9Π1Η90 9HH 9HHTOSJC 13 *0ΗβΗΛΗ9φφβ 99H9W i9BH9i0dU ΟΟ9Ϊ1θίΠ XBdiCo,B(i9IIW91 XHMSHH 99ΙΤ0ρ Hd[I(HHH9ffBII H iHtfOSHdll O 0 OK? 9Π1Η90 9HH 9HHTOSJC 13 * 0ΗβΗΛΗ9φφβ 99H9W i9BH9i0dU ΟΟ9Ϊ1θίΠ XBdiCo, B (19IIW91 XHMSHH 99ΙΤ0ρ Hd [I

•KHHBaO8BdpOOIfOWO J,9hO B8 19WBU IiOOH• KHHBaO8BdpOOIfOWO J, 9hO B8 19WBU IiOOH

·βΗΛΜ9ΙΡ90 ΒΗ91Πω.θϊΙΒΙΓΗΛΘΜ HHHBHOS^IfOUOH Hd]J ·ΟΗβΗΙΗΘΠ"ΟΟ 99If-Oj)HBH J,9BM9J,0dU ΟΟΘΪΙΟαΠ WOH9IfHiOOBIfKJiOW O BH91TFB H09W0 H· ΒΗΛΜ9ΙΡ90 ΒΗ91Πω.θϊΙΒΙΓΗΛΘΜ HHHBHOS ^ IfOUOH Hd] J · ΟΗβΗΙΗΘΠ "ΟΟ 99If-Oj) HBH J, 9BM9J, 0dU ΟΟΘΪΙΟαΠ WOH9IfHiOOBIfKJiOW O BH91TFB H09W0 H

W0.H9IfIfB O XHHSOIfOA XHHHBSBMiC S OiIxW0.H9IfIfB O XHHSOIfOA XHHHBSBMiC S OiIx

Claims (2)

-8--8th- Μ30ΕΡΕΊΈΙΜΗ I. Cnocoo uojiyqeHHH 2-aiiKOKCHiiponeHOBΜ30ΕΡΕΊΈΙΜΗ I. Cnocoo uojiyqeHHH 2-aiiKOKCHiiponeHOB ajTH<£aTireecKHx oirapTOB ο Henpe.nejii»HHM β npHcyTOTBHH KaTaraeaTopa e,HKo3 m&noHH πρκ noBuuieHHofi nepaType η ψήλθηηιι, OTjiHT-iaK)mHitcH τθμ, ^to ο iiejiLio yB^iH^iei^' Bnxo.ua qejieBoro npo^yKTa η npoi;ecca, β Ka^ecrae Henpe^ejitHoro yrjreBOflopo^a ajuieH ΗΛΗ QJUiQii β CMecH c MeTHjraqeTHJi8H0M, H npoqecc B Te^eHHe 2,5-4 η πρκ TeMnepaType 190-24O0C η 41-62 aTM.ajTH <£ aTireecKHx oirapTOB ο Henpe.nejii »HHM β npHcyTOTBHH KaTaraeaTopa e, HKo3 m & noHH πρκ noBuuieHHofi nepaType η ψήλθηηιι, OTjiH T -iaK) mHitcH τθμ, ^ to ο iiejiLio yB ^ iH ^ iei ^ 'Bnxo.ua qejieBoro npo ^ yKTa η npoi; ecca, β Ka ^ ecrae Henpe ^ ejitHoro yrjreBOflopo ^ a ajuieH ΗΛΗ QJUiQii β CMecH c MeTHjraqeTHJi8H0M, H npoqecc B Te ^ eHHe 2,5-4 η πρκ TeMnepaType 190-24O 0 C η 41-62 aTM. MCTO^iHHKH HH^OpMamOI, ΠρΚΗΗΤΗθ BO BHHMaHHe npH 9KC-MCTO ^ iHHKH HH ^ OpMamOI, ΠρΚΗΗΤΗθ BO BHHMaHHe npH 9KC- nepTH3e:nepTH3e: 1. SUJ, 273813.1. SUJ, 273813. 2. ätypHaji oömeä xhmhh, J§ 23, 1953 (MocKBa, Μ.Φ,ΙΙΙοο-2. ätypHaji oömeä xhmhh, J§ 23, 1953 (MocKBa, Μ.Φ, ΙΙΙο- aTieBa "0ηητθ3 Ί ~3aMemeHHux ώηηηλοβηχ ", C.II53).a T heBa "0ηητθ3 Ί ~ 3aMemeHHux ώηηηλοβηχ", C.II53).
DD85281267A 1979-05-10 1985-10-02 PROCESS FOR OBTAINING 2-ALKOXYPROPENES DD263890A3 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BG71894A BG48384A1 (en) 1979-05-10 1985-10-02 Method for preparing of 2- alkoxypropenes
DD85281267A DD263890A3 (en) 1979-05-10 1985-10-02 PROCESS FOR OBTAINING 2-ALKOXYPROPENES
CS857310A CS266243B1 (en) 1979-05-10 1985-10-14 Process for preparing 2-alkoxipropene

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
SU2765706 1979-05-10
DD85281267A DD263890A3 (en) 1979-05-10 1985-10-02 PROCESS FOR OBTAINING 2-ALKOXYPROPENES
CS857310A CS266243B1 (en) 1979-05-10 1985-10-14 Process for preparing 2-alkoxipropene

Publications (1)

Publication Number Publication Date
DD263890A3 true DD263890A3 (en) 1989-01-18

Family

ID=27179550

Family Applications (1)

Application Number Title Priority Date Filing Date
DD85281267A DD263890A3 (en) 1979-05-10 1985-10-02 PROCESS FOR OBTAINING 2-ALKOXYPROPENES

Country Status (3)

Country Link
BG (1) BG48384A1 (en)
CS (1) CS266243B1 (en)
DD (1) DD263890A3 (en)

Also Published As

Publication number Publication date
CS266243B1 (en) 1989-12-13
CS731085A1 (en) 1988-08-16
BG48384A1 (en) 1991-02-15

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