CY1113696T1 - 1η-αζολυλο-μεθυλ-αμιδια, μεθοδος για την παρασκευη τους και η χρησιμοποιηση τους σαν αναστολεις νιτροποιησης - Google Patents
1η-αζολυλο-μεθυλ-αμιδια, μεθοδος για την παρασκευη τους και η χρησιμοποιηση τους σαν αναστολεις νιτροποιησηςInfo
- Publication number
- CY1113696T1 CY1113696T1 CY20131100150T CY131100150T CY1113696T1 CY 1113696 T1 CY1113696 T1 CY 1113696T1 CY 20131100150 T CY20131100150 T CY 20131100150T CY 131100150 T CY131100150 T CY 131100150T CY 1113696 T1 CY1113696 T1 CY 1113696T1
- Authority
- CY
- Cyprus
- Prior art keywords
- alkyl
- cycloalkyl
- stands
- aryl
- nitrification
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/12—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to ring carbon atoms
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/16—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D249/00—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms
- C07D249/02—Heterocyclic compounds containing five-membered rings having three nitrogen atoms as the only ring hetero atoms not condensed with other rings
- C07D249/08—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/20—Reduction of greenhouse gas [GHG] emissions in agriculture, e.g. CO2
- Y02P60/21—Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Hydrogenated Pyridines (AREA)
- Pyridine Compounds (AREA)
Abstract
Περιγράφονται Ν-(1Η-αζολυλο-μεθυλ)αμίδια του γενικού τύπου (I), όπου Α = CH, C-αλογόνο, C-C1-C4-αλκύλιο ή C-C3-C8-κυκλοαλκύλιο ή είναι Ν , R1 και R2 ανεξάρτητα μεταξύ τους στέκουν για Η, C1-C4-αλκύλιο ή C3-C8-κυκλοαλκύλιο, R3 στέκει για C1-C4-αλκύλιο, C3-C8-κυκλοαλκύλιο ή C6-C10-αρύλιο ή Η, R4 στέκει για C1-C20-αλκύλιο, C3-C8-κυκλοαλκύλιο, C6-C10-αρύλιο ή αρυλαλκύλιο με C1-C4-αλκυλικές και C6-C10-αρυλικές ομάδες, όπου οι αρυλικές ρίζες από R4 ενδεχομένως μπορούν να υποκαθίστανται μονά ή πολλαπλά με C1-C4-αλκυλοσουλφονύλιο, C1-C4-αλκοξυ, C1-C4-ακύλιο, αλογόνο, υδροξύλιο, κυανό, νίτρο, καρβοξύλιο ή C1-C5-καρβοξυαλκύλιο, ή στέκει για NHR3 ή για τον τύπο (I) με τις αναφερόμενες για R1, R2, R3 και Α ρίζες, όπου R3 και R4 μαζί μπορούν να σχηματίζουν μία αιθυλενική γέφυρα και Β στέκει για οξυγόνο ή θείο. Οι ενώσεις σύμφωνα με την εφεύρεση είναι κατάλληλες για την αναστολή ή τη ρύθμιση της νιτροποίησης, όπου εκτός από την εξαιρετική ανασταλτική για νιτροποίηση δράση έχουν μια μικρή τάση για υδρόλυση και λόγω των υδρόφοβων ιδιοτήτων τους μπορούν να παρέχονται καλά πάνω στην επιφάνεια των λιπασμάτων, π.χ. κόκκους λιπασμάτων.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10343277A DE10343277A1 (de) | 2003-09-18 | 2003-09-18 | N-(1H-Azolyl-methyl)amide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| EP04763137A EP1663997B1 (de) | 2003-09-18 | 2004-07-08 | 1h-azolyl-methyl-amide, verfahren zu ihrer herstellung und ihre verwendung als nitrifikationsinhibitoren |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CY1113696T1 true CY1113696T1 (el) | 2016-06-22 |
Family
ID=34352943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CY20131100150T CY1113696T1 (el) | 2003-09-18 | 2013-02-19 | 1η-αζολυλο-μεθυλ-αμιδια, μεθοδος για την παρασκευη τους και η χρησιμοποιηση τους σαν αναστολεις νιτροποιησης |
Country Status (8)
| Country | Link |
|---|---|
| EP (1) | EP1663997B1 (el) |
| CY (1) | CY1113696T1 (el) |
| DE (1) | DE10343277A1 (el) |
| DK (1) | DK1663997T3 (el) |
| ES (1) | ES2397025T3 (el) |
| PL (1) | PL1663997T3 (el) |
| PT (1) | PT1663997E (el) |
| WO (1) | WO2005035509A1 (el) |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE102006015704B4 (de) | 2006-04-04 | 2018-07-19 | Skw Stickstoffwerke Piesteritz Gmbh | Neue 1,2-Bis-(azol-1-yl)-ethan-1,2-diole als Zwischenprodukte zur Synthese von Agrochemikalien und Verfahren zu ihrer Herstellung |
| DE102008020785B4 (de) | 2008-04-25 | 2021-11-04 | Skw Stickstoffwerke Piesteritz Gmbh | Verwendung von einfachen Derivaten von 5-Amino-1,2,4-thiadiazol zur Hemmung bzw. Steuerung der Nitrifikation |
| DE102008057718B4 (de) | 2008-11-17 | 2020-02-06 | Skw Stickstoffwerke Piesteritz Gmbh | Verfahren zur regioselektiven Herstellung von N-(1H-Pyrazolylmethyl)-amiden |
| DE102011120098B4 (de) | 2011-12-02 | 2021-02-11 | Skw Stickstoffwerke Piesteritz Gmbh | N-(1H-Pyrazolyl-methyl)formamide, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| DE102013012498A1 (de) | 2013-07-26 | 2015-01-29 | Skw Stickstoffwerke Piesteritz Gmbh | Verwendung von einfachen 1,2,4-Triazol-Derivaten als Mittel zur Verbesserung der Trockenstresstoleranz |
| DE102013021933A1 (de) | 2013-12-20 | 2015-06-25 | Skw Stickstoffwerke Piesteritz Gmbh | Verwendung von Pyrazol-Derivaten als Mittel zur Verbesserung der Trockenstresstoleranz |
| US9932278B2 (en) * | 2015-03-12 | 2018-04-03 | Advansix Resins & Chemicals Llc | Granulator feed apparatus |
| DE102016106592A1 (de) | 2016-04-11 | 2017-10-12 | Skw Stickstoffwerke Piesteritz Gmbh | Verfahren zur Herstellung von N-((3(5)-Methyl-1H-pyrazol-1-yl)methyl)acetamid (MPA) |
| DE102017005463A1 (de) | 2017-06-08 | 2018-12-13 | Skw Stickstoffwerke Piesteritz Gmbh | Zusammensetzungen mit N-((3(5)-Methyl-1H-pyrazol-1-yl)methyl)acetamid und deren Vewendung zur Herstellung von lagerfähigen Fertigdüngemitteln mit dualer Stickstoffstabilisierung |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3635690A (en) | 1968-05-16 | 1972-01-18 | Dow Chemical Co | Soil treating method and composition for conserving nitrogen in soil by addition of a pyrazole thereto |
| US3697244A (en) | 1968-10-15 | 1972-10-10 | Dow Chemical Co | Crop culture with 4h-1,2,4-triazoles |
| DE2648008C3 (de) | 1976-10-23 | 1980-09-04 | Basf Ag, 6700 Ludwigshafen | Acetanilide |
| DE2742583A1 (de) | 1977-09-22 | 1979-04-05 | Bayer Ag | N-substituierte halogenacetanilide, verfahren zu ihrer herstellung sowie ihre verwendung als herbizide |
| DE2745833C2 (de) | 1977-10-12 | 1986-10-16 | VEB Fahlberg-List Chemische und pharmazeutische Fabriken, DDR 3013 Magdeburg | Mittel zur Hemmung bzw. Regelung der Nitrifikation von Ammoniumstickstoff in Kulturböden |
| SU666174A1 (ru) | 1977-11-21 | 1979-06-05 | Предприятие П/Я А-7253 | -Ди- 3(5)-метилпиразолилметилен-1 -тиомочевина в качестве активатора солевой вулканизации каучука,выполненного на основе бутадиена и соединений,содержащих сложноэфирные ненасыщенные группировки |
| DE2828222A1 (de) | 1978-06-28 | 1980-01-10 | Bayer Ag | Gegenmittel zum schutz von kulturpflanzen vor schaedigungen durch herbizide |
| DE2849442A1 (de) | 1978-11-15 | 1980-05-29 | Basf Ag | Verfahren zur herstellung weitgehend reiner pyrazolverbindungen |
| DE3409317A1 (de) | 1984-03-14 | 1985-09-19 | Basf Ag, 6700 Ludwigshafen | Nitrifikationsinhibierende 1-hydroxipyrazol-derivate |
| US4523940A (en) | 1984-06-25 | 1985-06-18 | The Dow Chemical Company | Soil treating method and composition for conserving nitrogen in soil |
| AU4348285A (en) | 1984-06-25 | 1986-01-02 | Dow Chemical Company, The | Pyrazole growth enhancer |
| US4969946A (en) | 1986-01-29 | 1990-11-13 | The Dow Chemical Company | Soil treating method and composition for conserving nitrogen in naturally alkaline soil |
| SU1470737A1 (ru) | 1986-09-19 | 1989-04-07 | Предприятие П/Я Г-4302 | Способ ингибировани нитрификации карбамида в почве |
| DE3704359A1 (de) | 1987-02-12 | 1988-08-25 | Basf Ag | Azolhalbaminal-derivate und ihre verwendung als nitrifikationsinhibitoren |
| DD292232A5 (de) | 1988-10-17 | 1991-07-25 | Stickstoffwerke Ag Wittenberg-Piesteritz,De | Mittel zur hemmung bzw. regelung der nitrifikation von ammoniumstickstoff in kulturboeden |
| DE4018395A1 (de) | 1990-06-08 | 1992-02-20 | Wittenberg Stickstoff Ag | Mittel zur hemmung bzw. regelung der nitrifikation von ammoniumstickstoff in kulturboeden |
| DE4111922A1 (de) | 1991-04-12 | 1992-10-15 | Basf Ag | Verfahren zur herstellung von 1-carbamoyl-pyrazolen |
| DE4128828A1 (de) | 1991-08-30 | 1993-03-04 | Basf Ag | Ammonium- oder harnstoffhaltige duengemittel und verfahren zu ihrer herstellung |
| DE4446194A1 (de) | 1994-12-23 | 1996-06-27 | Basf Ag | Verwendung von Pyrazolderivaten mit hydrophoben Resten als Nitrifikationsinhibitoren |
| DE19503827A1 (de) | 1995-02-06 | 1996-08-08 | Basf Ag | Verwendung von schwerflüchtigen Pyrazolderivaten mit hydrophilen Gruppen als Nitrifikationsinhibitoren |
| DE19631764A1 (de) | 1996-08-06 | 1998-02-12 | Basf Ag | Neue Nitrifikationsinhibitoren sowie die Verwendung von Polysäuren zur Behandlung von Mineraldüngemitteln die einen Nitrifikationsinhibitor enthalten |
| DE19822340B4 (de) | 1998-05-19 | 2008-02-28 | Skw Stickstoffwerke Piesteritz Gmbh | Thermostabile schwerflüchtige Alkyl-1H-1-pyrazolylmethanamin-Derivate und deren Verwendung als Nitrifikationsinhibitoren |
| WO2001079178A1 (de) | 2000-04-14 | 2001-10-25 | Skw Stickstoffwerke Piesteritz Gmbh | 1h-pyrazol-derivate, verfahren zu ihrer herstellung und deren verwendung zur hemmung und steuerung der nitrifikation |
| DE10135423A1 (de) | 2000-08-08 | 2002-02-21 | Piesteritz Stickstoff | 1H-Pyrazol-Derivate, Verfahren zu ihrer Herstellung und ihre Verwendung als Nitrifikationsinhibitoren |
| DE10210409A1 (de) | 2002-03-09 | 2003-09-18 | Feinchemie Schwebda Gmbh | Rein triklines Metazachlor und Verfahren zu seiner Herstellung |
-
2003
- 2003-09-18 DE DE10343277A patent/DE10343277A1/de not_active Withdrawn
-
2004
- 2004-07-08 PL PL04763137T patent/PL1663997T3/pl unknown
- 2004-07-08 DK DK04763137.9T patent/DK1663997T3/da active
- 2004-07-08 WO PCT/EP2004/007528 patent/WO2005035509A1/de active Application Filing
- 2004-07-08 PT PT47631379T patent/PT1663997E/pt unknown
- 2004-07-08 EP EP04763137A patent/EP1663997B1/de not_active Expired - Lifetime
- 2004-07-08 ES ES04763137T patent/ES2397025T3/es not_active Expired - Lifetime
-
2013
- 2013-02-19 CY CY20131100150T patent/CY1113696T1/el unknown
Also Published As
| Publication number | Publication date |
|---|---|
| EP1663997A1 (de) | 2006-06-07 |
| ES2397025T3 (es) | 2013-03-04 |
| DE10343277A1 (de) | 2005-04-21 |
| WO2005035509A1 (de) | 2005-04-21 |
| DK1663997T3 (da) | 2013-01-14 |
| PL1663997T3 (pl) | 2013-04-30 |
| EP1663997B1 (de) | 2012-11-21 |
| PT1663997E (pt) | 2013-01-22 |
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