CS277304B6 - Process of microbiological conversion of sulfur-containing noxious substances in waste gases - Google Patents
Process of microbiological conversion of sulfur-containing noxious substances in waste gases Download PDFInfo
- Publication number
- CS277304B6 CS277304B6 CS886870A CS687088A CS277304B6 CS 277304 B6 CS277304 B6 CS 277304B6 CS 886870 A CS886870 A CS 886870A CS 687088 A CS687088 A CS 687088A CS 277304 B6 CS277304 B6 CS 277304B6
- Authority
- CS
- Czechoslovakia
- Prior art keywords
- reactor
- sulfur
- liquid
- salts
- harmful substances
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 18
- 239000002912 waste gas Substances 0.000 title claims description 15
- 239000000126 substance Substances 0.000 title claims description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims description 11
- 229910052717 sulfur Inorganic materials 0.000 title claims description 11
- 239000011593 sulfur Substances 0.000 title claims description 11
- 238000006243 chemical reaction Methods 0.000 title claims description 5
- 230000002906 microbiologic effect Effects 0.000 title claims description 3
- 230000001473 noxious effect Effects 0.000 title 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 32
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 claims description 31
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 24
- 239000007789 gas Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 150000003839 salts Chemical class 0.000 claims description 11
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 claims description 10
- 241000894006 Bacteria Species 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000945 filler Substances 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 5
- JJWKPURADFRFRB-UHFFFAOYSA-N carbonyl sulfide Chemical compound O=C=S JJWKPURADFRFRB-UHFFFAOYSA-N 0.000 claims description 5
- 239000013505 freshwater Substances 0.000 claims description 5
- 150000002500 ions Chemical class 0.000 claims description 5
- 238000012856 packing Methods 0.000 claims description 5
- 238000004065 wastewater treatment Methods 0.000 claims description 5
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 4
- 241000888721 Thiobacillaceae Species 0.000 claims description 4
- 244000005700 microbiome Species 0.000 claims description 4
- 239000011573 trace mineral Substances 0.000 claims description 4
- 235000013619 trace mineral Nutrition 0.000 claims description 4
- 239000002351 wastewater Substances 0.000 claims description 4
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 claims description 3
- 239000010802 sludge Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 159000000007 calcium salts Chemical class 0.000 claims description 2
- 238000010926 purge Methods 0.000 claims description 2
- 150000003464 sulfur compounds Chemical class 0.000 claims description 2
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 2
- 150000003568 thioethers Chemical class 0.000 claims description 2
- 229930192474 thiophene Natural products 0.000 claims description 2
- 150000003577 thiophenes Chemical class 0.000 claims description 2
- 241000193830 Bacillus <bacterium> Species 0.000 claims 1
- 239000010796 biological waste Substances 0.000 claims 1
- 239000000920 calcium hydroxide Substances 0.000 claims 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 claims 1
- 239000003518 caustics Substances 0.000 claims 1
- 238000007380 fibre production Methods 0.000 claims 1
- -1 sulphate ions Chemical class 0.000 claims 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 6
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 6
- 238000000926 separation method Methods 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 239000000835 fiber Substances 0.000 description 3
- 230000002503 metabolic effect Effects 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 229920000298 Cellophane Polymers 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000005352 clarification Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000015097 nutrients Nutrition 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 241000605272 Acidithiobacillus thiooxidans Species 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000000721 bacterilogical effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000001175 calcium sulphate Substances 0.000 description 1
- 235000011132 calcium sulphate Nutrition 0.000 description 1
- ZHZFKLKREFECML-UHFFFAOYSA-L calcium;sulfate;hydrate Chemical compound O.[Ca+2].[O-]S([O-])(=O)=O ZHZFKLKREFECML-UHFFFAOYSA-L 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000036284 oxygen consumption Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/48—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/84—Biological processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Biomedical Technology (AREA)
- Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Molecular Biology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Treating Waste Gases (AREA)
- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT0275287A AT388313B (de) | 1987-10-19 | 1987-10-19 | Verfahren zur mikrobiologischen umwandlung von schwefelhaltigen schadstoffen in abgasen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CS687088A3 CS687088A3 (en) | 1992-08-12 |
| CS277304B6 true CS277304B6 (en) | 1993-01-13 |
Family
ID=3539730
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CS886870A CS277304B6 (en) | 1987-10-19 | 1988-10-18 | Process of microbiological conversion of sulfur-containing noxious substances in waste gases |
Country Status (16)
| Country | Link |
|---|---|
| US (1) | US4968622A (hu) |
| EP (1) | EP0312958B1 (hu) |
| JP (1) | JPH01231925A (hu) |
| CN (1) | CN1013735B (hu) |
| AT (1) | AT388313B (hu) |
| BG (1) | BG51254A3 (hu) |
| BR (1) | BR8805663A (hu) |
| CA (1) | CA1302930C (hu) |
| CS (1) | CS277304B6 (hu) |
| DD (1) | DD275621A5 (hu) |
| DE (1) | DE3880425D1 (hu) |
| ES (1) | ES2040809T3 (hu) |
| HU (1) | HU202770B (hu) |
| PL (1) | PL158304B1 (hu) |
| PT (1) | PT88794B (hu) |
| SU (1) | SU1837945A3 (hu) |
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2655563B1 (fr) * | 1989-12-12 | 1993-10-08 | Saps Anti Corrosion | Procede pour la bioepuration d'effluents gazeux charges en produits polluants et plus particulierement en produits souffres. |
| DE4027220A1 (de) * | 1990-08-24 | 1992-02-27 | Preussag Noell Wassertech | Verfahren und anlage zum biologischen abbau von schwefelwasserstoff |
| DE4027126C1 (hu) * | 1990-08-28 | 1991-12-12 | Eberhard Prof. Dr. 2000 Hamburg De Bock | |
| GB2262457A (en) * | 1991-12-20 | 1993-06-23 | Wrc Process Engineering Limite | Removing h2s from gas |
| US5236677A (en) * | 1992-03-13 | 1993-08-17 | Grupo Cydsa S.A. De C.V. | Biological process for the elimination of sulphur compounds present in gas mixtures |
| WO1994009885A1 (en) * | 1992-11-02 | 1994-05-11 | Bbk Bio Air-Clean Aps | Bio filter |
| JPH10500351A (ja) * | 1994-03-16 | 1998-01-13 | ヴァポ オイ | ガス類を精製する方法と装置 |
| GB2300824B (en) * | 1995-05-10 | 1997-07-16 | Bord Na Mona | An effluent treatment system |
| US5686293A (en) * | 1995-07-07 | 1997-11-11 | Phillips Petroleum Company | Sulfide-oxidizing bacteria |
| US5981266A (en) * | 1996-05-20 | 1999-11-09 | Gas Research Institute | Microbial process for the mitigation of sulfur compounds from natural gas |
| US6013512A (en) * | 1996-11-06 | 2000-01-11 | Turschmid; Krzysztof H. | Method for scrubbing gaseous emissions using bacteria |
| CN1089021C (zh) * | 1997-11-24 | 2002-08-14 | 中国石油化工集团公司 | 含硫恶臭气体的净化方法 |
| US6032613A (en) * | 1998-03-26 | 2000-03-07 | Teepak Investment, Inc. | Biological treatment system for gaseous waste |
| WO2005030369A1 (de) * | 2003-09-24 | 2005-04-07 | Söll Gmbh | Vorrichtung zum reinigen von abgas oder abluft |
| US20080245232A1 (en) * | 2007-04-09 | 2008-10-09 | Thomas Getz | Downflow Biofiltration of Hydrogen Sulfide-Containing Gas |
| TWI478762B (zh) * | 2012-09-19 | 2015-04-01 | Univ Nat Chiao Tung | 降低氣體中硫化氫之系統與方法 |
| CN103272473B (zh) * | 2013-05-29 | 2016-03-30 | 中国科学院生态环境研究中心 | 水微菌活性填料及其制备方法 |
| RU2560406C2 (ru) * | 2013-10-29 | 2015-08-20 | Игорь Анатольевич Мнушкин | Способ переработки природных газов |
| WO2016007416A1 (en) * | 2014-07-07 | 2016-01-14 | Geosyntec Consultants, Inc. | Biogeochemical transformations of flue gas desulfurization waste using sulfur oxidizing bacteria |
| CN105709592A (zh) * | 2016-04-26 | 2016-06-29 | 杭州奥通环保科技股份有限公司 | 一种粘胶纤维低浓度废气生化处理装置和处理方法 |
| EP3466894B1 (en) | 2017-10-05 | 2020-05-13 | INDIAN OIL CORPORATION Ltd. | Treatment and recovery of caustic from spent caustic through bioelectrochemical process |
| RU2685099C1 (ru) * | 2018-11-06 | 2019-04-16 | Игорь Анатольевич Мнушкин | Производственный кластер |
| CN112843983A (zh) * | 2020-12-31 | 2021-05-28 | 江苏申江环境科技有限公司 | 一种粘胶纤维生产中二硫化碳的回收工艺 |
| RU2760488C1 (ru) * | 2021-03-10 | 2021-11-25 | Общество с ограниченной ответственностью "Газпром переработка" | Способ переработки газа регенерации цеолитов в период остановки на плановый предупредительный ремонт технологических установок аминовой очистки и осушки газа |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2200581A (en) * | 1934-12-24 | 1940-05-14 | Pruss Max | Purification of gases by biological means |
| DE2237929C2 (de) * | 1972-08-02 | 1983-02-03 | Schumacher'sche Fabrik Gmbh & Co Kg, 7120 Bietigheim-Bissingen | Verfahren zum Entfernen von Verunreinigungen aus einem Abgas |
| SE7612503L (sv) | 1975-11-11 | 1977-05-12 | Courtaulds Ltd | Behandling av gaser |
| DE3217923A1 (de) * | 1982-05-13 | 1983-11-17 | Ceilcote Korrosionstechnik GmbH, 6081 Biebesheim | Verfahren und vorrichtung zur reinigung von abluft |
| DE3227678A1 (de) * | 1982-07-24 | 1984-01-26 | Bayer Ag, 5090 Leverkusen | Verfahren zur biologischen reinigung von abluft |
| DE3245713A1 (de) * | 1982-12-10 | 1984-06-14 | Mannesmann Veba Umwelttechnik GmbH, 4690 Herne | Verfahren zur biofiltration |
| NL8303031A (nl) * | 1983-08-31 | 1985-03-18 | Tongeren Ingbureau Bv Van | Werkwijze en inrichting voor het biologisch filtreren van gassen. |
| CA1278761C (en) * | 1985-10-15 | 1991-01-08 | Kerry Lyn Sublette | Microbiological desulfurization of gases |
| US4760027A (en) * | 1986-04-09 | 1988-07-26 | Combustion Engineering, Inc. | Microbiological desulfurization of gases |
-
1987
- 1987-10-19 AT AT0275287A patent/AT388313B/de not_active IP Right Cessation
-
1988
- 1988-10-17 DE DE8888117246T patent/DE3880425D1/de not_active Revoked
- 1988-10-17 ES ES198888117246T patent/ES2040809T3/es not_active Expired - Lifetime
- 1988-10-17 BG BG085724A patent/BG51254A3/xx unknown
- 1988-10-17 EP EP88117246A patent/EP0312958B1/de not_active Revoked
- 1988-10-17 DD DD88320827A patent/DD275621A5/de not_active IP Right Cessation
- 1988-10-17 US US07/258,489 patent/US4968622A/en not_active Expired - Fee Related
- 1988-10-18 CS CS886870A patent/CS277304B6/cs unknown
- 1988-10-18 SU SU884356641A patent/SU1837945A3/ru active
- 1988-10-18 CN CN88107293A patent/CN1013735B/zh not_active Expired
- 1988-10-18 JP JP63260711A patent/JPH01231925A/ja active Pending
- 1988-10-18 PL PL1988275352A patent/PL158304B1/pl unknown
- 1988-10-19 HU HU885343A patent/HU202770B/hu not_active IP Right Cessation
- 1988-10-19 PT PT88794A patent/PT88794B/pt active IP Right Grant
- 1988-10-19 BR BR888805663A patent/BR8805663A/pt not_active Application Discontinuation
- 1988-10-19 CA CA000580638A patent/CA1302930C/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| ATA275287A (de) | 1988-11-15 |
| CA1302930C (en) | 1992-06-09 |
| BG51254A3 (en) | 1993-03-15 |
| CS687088A3 (en) | 1992-08-12 |
| AT388313B (de) | 1989-06-12 |
| CN1013735B (zh) | 1991-09-04 |
| BR8805663A (pt) | 1989-07-18 |
| SU1837945A3 (ru) | 1993-08-30 |
| JPH01231925A (ja) | 1989-09-18 |
| PL275352A1 (en) | 1989-06-12 |
| HUT51172A (en) | 1990-04-28 |
| CN1039190A (zh) | 1990-01-31 |
| PL158304B1 (pl) | 1992-08-31 |
| PT88794B (pt) | 1993-01-29 |
| HU202770B (en) | 1991-04-29 |
| DE3880425D1 (de) | 1993-05-27 |
| ES2040809T3 (es) | 1993-11-01 |
| US4968622A (en) | 1990-11-06 |
| EP0312958B1 (de) | 1993-04-21 |
| DD275621A5 (de) | 1990-01-31 |
| EP0312958A1 (de) | 1989-04-26 |
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