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CS211352B2 - Catalytic mixture - Google Patents

Catalytic mixture Download PDF

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Publication number
CS211352B2
CS211352B2 CS764836A CS483676A CS211352B2 CS 211352 B2 CS211352 B2 CS 211352B2 CS 764836 A CS764836 A CS 764836A CS 483676 A CS483676 A CS 483676A CS 211352 B2 CS211352 B2 CS 211352B2
Authority
CS
Czechoslovakia
Prior art keywords
zeolite
antimony
catalyst
zsm
mixture
Prior art date
Application number
CS764836A
Other languages
Czech (cs)
English (en)
Inventor
Stephen A Butter
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Publication of CS211352B2 publication Critical patent/CS211352B2/cs

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/868—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains sulfur as hetero-atom
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/864—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an alcohol
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/86—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon
    • C07C2/862—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms
    • C07C2/865—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation between a hydrocarbon and a non-hydrocarbon the non-hydrocarbon contains only oxygen as hetero-atoms the non-hydrocarbon is an ether
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/123—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of only one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/18—Arsenic, antimony or bismuth
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CS764836A 1975-11-24 1976-07-21 Catalytic mixture CS211352B2 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US05/634,992 US4007231A (en) 1975-11-24 1975-11-24 Selective production of para-xylene

Publications (1)

Publication Number Publication Date
CS211352B2 true CS211352B2 (en) 1982-02-26

Family

ID=24545975

Family Applications (1)

Application Number Title Priority Date Filing Date
CS764836A CS211352B2 (en) 1975-11-24 1976-07-21 Catalytic mixture

Country Status (12)

Country Link
US (4) US4007231A (de)
JP (1) JPS5265229A (de)
BE (1) BE844417A (de)
CA (1) CA1077455A (de)
CS (1) CS211352B2 (de)
DD (1) DD131728A5 (de)
DE (1) DE2633881A1 (de)
FR (1) FR2332057A1 (de)
IT (1) IT1064729B (de)
NL (1) NL182056C (de)
PL (1) PL118516B1 (de)
RO (1) RO71011A (de)

Families Citing this family (38)

* Cited by examiner, † Cited by third party
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US4029716A (en) * 1975-12-08 1977-06-14 Mobil Oil Corporation Selective production of para-xylene
US4049573A (en) * 1976-02-05 1977-09-20 Mobil Oil Corporation Zeolite catalyst containing oxide of boron or magnesium
US4086287A (en) * 1976-07-19 1978-04-25 Mobil Oil Corporation Selective ethylation of mono alkyl benzenes
US4101596A (en) * 1977-01-10 1978-07-18 Mobil Oil Company Low pressure xylene isomerization
US4111845A (en) * 1977-02-11 1978-09-05 Mckay Dwight L Cracking catalyst modified by antimony thiophosphate
US4198317A (en) * 1978-07-25 1980-04-15 Phillips Petroleum Company Passivation of metals which contaminate cracking catalysts with antimony tris (hydrocarbyl sulfonate)
US4257876A (en) * 1978-07-25 1981-03-24 Phillips Petroleum Company Passivation of metals contaminating a cracking catalyst with trihydrocarbylantimony oxide and process for converting hydrocarbons
AU530334B2 (en) * 1978-09-11 1983-07-14 Mobil Oil Corp. Regeneration of zeolite catalyst
US4330396A (en) * 1978-10-18 1982-05-18 Chevron Research Company Cyclic process for upgrading a hydrocarbon or hydrocarbon-forming feed using a ZSM-5 zeolite
DE3061073D1 (en) * 1979-12-13 1982-12-16 Mobil Oil Corp Rejuvenation of alkylation catalyst
CA1148569A (en) * 1980-02-14 1983-06-21 Christine H. Kursewicz Aromatics processing
US4302620A (en) * 1980-10-29 1981-11-24 Mobil Oil Corporation Reactions involving zeolite catalysts modified with group IV A metals
JPS57108023A (en) * 1980-12-26 1982-07-05 Toa Nenryo Kogyo Kk Oligomerization catalyst for isobutene
US4334115A (en) * 1981-06-18 1982-06-08 Phillips Petroleum Company Process for making tert-butyltoluenes
US4431746A (en) * 1981-06-26 1984-02-14 Mobil Oil Corporation Preparing metal-exchanged highly siliceous porous crystalline materials
US4482644A (en) * 1983-04-18 1984-11-13 Exxon Research & Engineering Co. Oxygen-deficient, barium-containing perovskites
US4711970A (en) * 1983-05-10 1987-12-08 Mobil Oil Corporation Catalytic conversion
US4851604A (en) * 1987-09-02 1989-07-25 Mobil Oil Corp. Toluene disproportionation
US4874731A (en) * 1987-10-13 1989-10-17 Uop Catalyst for the isomerization of aromatics
US4929337A (en) * 1988-12-30 1990-05-29 Mobil Oil Corporation Process for catalytic cracking of heavy hydrocarbon feed to lighter products
US4922051A (en) * 1989-03-20 1990-05-01 Mobil Oil Corp. Process for the conversion of C2 -C12 paraffinic hydrocarbons to petrochemical feedstocks
US5030787A (en) * 1990-01-24 1991-07-09 Mobil Oil Corp. Catalytic disproportionation/transalkylation utilizing a C9+ aromatics feed
US6323381B1 (en) * 1992-06-18 2001-11-27 Chevron Corporation Manufacture of high purity benzene and para-rich xylenes by combining aromatization and selective disproportionation of impure toluene
CA2169963C (en) * 1993-10-18 2005-07-05 Ernest W. Valyocsik Synthetic porous crystalline mcm-58, its synthesis and use
US5609751A (en) * 1994-07-26 1997-03-11 Chevron Chemical Company Para-xylene selective reforming/aromatization
JPH10512604A (ja) * 1995-01-13 1998-12-02 アシュランド インコーポレーテッド 炭化水素変換触媒、添加剤およびプロセス
TW504501B (en) * 1995-02-10 2002-10-01 Mobil Oil Corp Process for converting feedstock comprising C9+ aromatic hydrocarbons to lighter aromatic products
US5763714A (en) * 1997-01-08 1998-06-09 Catalytic Distillation Technologies Process and apparatus for the production and recovery of p-xylene
US5942651A (en) * 1997-06-13 1999-08-24 Mobile Oil Corporation Process for converting C9 + aromatic hydrocarbons to lighter aromatic products by transalkylation in the prescence of two zeolite-containing catalysts
US5866736A (en) * 1997-10-14 1999-02-02 Catalytic Distillation Technologies Process for the production of alkyl benzene
US6004452A (en) * 1997-11-14 1999-12-21 Chevron Chemical Company Llc Process for converting hydrocarbon feed to high purity benzene and high purity paraxylene
US6133470A (en) * 1998-07-28 2000-10-17 Mobil Oil Corporation Integration of p-xylene production and subsequent conversion process
JP4823655B2 (ja) * 2005-11-21 2011-11-24 出光興産株式会社 キシレン類の製造方法
MY159574A (en) * 2007-10-31 2017-01-13 Exxonmobil Chemical Patents Inc Heavy aromatics processing catalyst and process of using the same
US8062987B2 (en) * 2009-10-05 2011-11-22 Saudi Basic Industries Corporation Phosphorus-containing zeolite catalysts and their method of preparation
US9278342B2 (en) 2012-07-02 2016-03-08 Saudi Basic Industries Corporation Method of modifying a phosphorus-containing zeolite catalyst
CA3022086A1 (en) 2016-04-25 2017-11-02 Exxonmobil Chemical Patents Inc. Catalytic aromatization
KR102524765B1 (ko) 2017-02-16 2023-04-25 엑손모빌 테크놀로지 앤드 엔지니어링 컴퍼니 경질 파라핀 전환을 위한 고정층 방사류 반응기

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US3126422A (en) * 1964-03-24 Temperature
US2289916A (en) * 1939-04-21 1942-07-14 Universal Oil Prod Co Treatment of hydrocarbons
NL288698A (de) * 1962-02-07 1900-01-01
US3413374A (en) * 1966-05-04 1968-11-26 Toyo Rayon Co Ltd Disproportionation of toluene
US3527825A (en) * 1968-07-03 1970-09-08 Universal Oil Prod Co Transalkylation process
US3598879A (en) * 1968-12-19 1971-08-10 Ashland Oil Inc Alkyl transfer of alkyl aromatics with group i-a,ii-a,iv,or rare earth metals on boria alumina
US3607961A (en) * 1968-12-19 1971-09-21 Ashland Oil Inc Alkyl transfer of alkyl aromatics with group viii metals on boria-alumina
US3720724A (en) * 1970-06-03 1973-03-13 Phillips Petroleum Co Dehydrogenation cyclohexane or mono- or polyalkylcyclohexanes
US3711422A (en) * 1970-09-08 1973-01-16 Phillips Petroleum Co Cracking catalyst restoration with antimony compounds
US3760024A (en) * 1971-06-16 1973-09-18 Mobil Oil Corp Preparation of aromatics
US3756942A (en) * 1972-05-17 1973-09-04 Mobil Oil Corp Process for the production of aromatic compounds
US3899544A (en) * 1974-03-28 1975-08-12 Mobil Oil Corp Conversion of alcohols and ethers to hydrocarbons
US3890218A (en) * 1974-03-29 1975-06-17 Mobil Oil Corp Upgrading aliphatic naphthas to higher octane gasoline
US3965208A (en) * 1975-01-06 1976-06-22 Mobil Oil Corporation Methylation of toluene
US4025458A (en) * 1975-02-18 1977-05-24 Phillips Petroleum Company Passivating metals on cracking catalysts
US3979472A (en) * 1975-03-28 1976-09-07 Mobil Oil Corporation Process for manufacturing hydrocarbons

Also Published As

Publication number Publication date
FR2332057B1 (de) 1980-04-25
US4080395A (en) 1978-03-21
NL182056B (nl) 1987-08-03
DE2633881A1 (de) 1977-06-02
RO71011A (ro) 1982-07-06
JPS5265229A (en) 1977-05-30
NL182056C (nl) 1988-01-04
DD131728A5 (de) 1978-07-19
FR2332057A1 (fr) 1977-06-17
CA1077455A (en) 1980-05-13
US4067919A (en) 1978-01-10
US4007231A (en) 1977-02-08
PL118516B1 (en) 1981-10-31
IT1064729B (it) 1985-02-25
US4080396A (en) 1978-03-21
BE844417A (fr) 1977-01-24
NL7608001A (nl) 1977-05-26

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