CN2893937Y - fuel cell device - Google Patents
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- CN2893937Y CN2893937Y CNU2006200015173U CN200620001517U CN2893937Y CN 2893937 Y CN2893937 Y CN 2893937Y CN U2006200015173 U CNU2006200015173 U CN U2006200015173U CN 200620001517 U CN200620001517 U CN 200620001517U CN 2893937 Y CN2893937 Y CN 2893937Y
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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Abstract
本实用新型提供一种燃料电池装置,是至少包括:一个以上的膜电极组,其中该膜电极组是至少包含:一阳极电极、一质子交换膜及一阴极电极。以及,一个以上的双面流道板,是设置于该膜电极组的一侧,其中该双面流道板是使用一波形结构。
The utility model provides a fuel cell device, which at least comprises: one or more membrane electrode groups, wherein the membrane electrode group at least comprises: an anode electrode, a proton exchange membrane and a cathode electrode. And at least one double-sided flow channel plate is arranged on one side of the membrane electrode group, wherein the double-sided flow channel plate uses a corrugated structure.
Description
技术领域technical field
本新型涉及一种燃料电池,且特别是一种具有双面流道板的燃料电池装置。The present invention relates to a fuel cell, and in particular to a fuel cell device with a double-sided flow channel plate.
背景技术Background technique
燃料电池是一种将储存在燃料和氧化剂中的化学能通过电极反应直接转化为电能的发电装置。燃料电池的种类相当多,而且分类的方式也各有所不同,若依质子交换膜性质不同加以区分,有碱性燃料电池、磷酸燃料电池、质子交换膜燃料电池、熔融碳酸盐燃料电池、固态氧化物燃料电池等五种不同质子交换膜的燃料电池。A fuel cell is a power generation device that directly converts chemical energy stored in fuel and oxidant into electrical energy through electrode reactions. There are quite a lot of types of fuel cells, and the classification methods are also different. If they are distinguished according to the properties of proton exchange membranes, there are alkaline fuel cells, phosphoric acid fuel cells, proton exchange membrane fuel cells, molten carbonate fuel cells, Fuel cells with five different proton exchange membranes, including solid oxide fuel cells.
于传统燃料电池结构中,流道板是置于膜电极组(MEA)的两端,其所使用的材质应具备高导电性、高强度、易加工、重量轻和成本低廉等特性,目前制作流道板的材料有石墨、铝及不锈钢,通常是采用石墨制成。在流道板上加工流道,作为供应燃料与气体的信道,使反应物能经由流道到达扩散层,而进入作用层参与反应。另外,流道板也具有传导电流的功能,使反应所产生的电流得以应用,因此又称为电流收集板(current collect plate)。In the traditional fuel cell structure, the flow channel plate is placed at both ends of the membrane electrode assembly (MEA), and the material used should have the characteristics of high conductivity, high strength, easy processing, light weight and low cost. The material of the runner plate is graphite, aluminum and stainless steel, usually made of graphite. The flow channel is processed on the flow channel plate as a channel for supplying fuel and gas, so that the reactants can reach the diffusion layer through the flow channel, and then enter the active layer to participate in the reaction. In addition, the runner plate also has the function of conducting current, so that the current generated by the reaction can be applied, so it is also called a current collect plate.
然而,传统的流道板(如:石墨板)通常是采单面流道设计,而且其本身的体积大,重量不够轻盈,导电能力也有待加强。而传统的燃料电池堆(stack),则由于是采用此种笨重的单面流道板所堆栈而成,导致燃料电池堆整体的体积与重量皆因而加倍,相当不利于整合至便携式的消费性电子产品,而且整体的集电能力也差强人意。However, traditional runner plates (such as graphite plates) are usually designed with single-sided runners, and they are bulky, not light enough, and their electrical conductivity needs to be strengthened. However, the traditional fuel cell stack (stack) is formed by stacking such bulky single-sided flow channel plates, which doubles the overall volume and weight of the fuel cell stack, which is not conducive to integration into portable consumer devices. Electronic products, and the overall power collection capacity is not satisfactory.
新型内容new content
本新型的主要目的是提供一种燃料电池装置,不但可让燃料电池本身的体积及重量大幅减少,亦可增进流道板的集电功能。The main purpose of the present invention is to provide a fuel cell device, which can not only greatly reduce the volume and weight of the fuel cell itself, but also improve the current collecting function of the flow channel plate.
为达成本新型上述目的,本新型提供一种燃料电池装置,是至少包括:一个以上的膜电极组,其中该膜电极组是至少包含:一阳极电极、一质子交换膜及一阴极电极;一个以上的双面流道板,是设置于该膜电极组的一侧,其中该双面流道板是使用一波形结构。In order to achieve the above-mentioned purpose of the present model, the present model provides a fuel cell device, which at least includes: more than one membrane electrode group, wherein the membrane electrode group at least includes: an anode electrode, a proton exchange membrane and a cathode electrode; a The above double-sided flow channel plate is arranged on one side of the membrane electrode group, wherein the double-sided flow channel plate uses a corrugated structure.
1.本新型燃料电池装置使用一种具有波形结构的双面流道板,可让燃料电池(特别是燃料电池堆)整体的体积及重量皆大幅减少,此有利于将燃料电池整合至便携式的消费性电子产品。1. The new fuel cell device uses a double-sided flow channel plate with a corrugated structure, which can greatly reduce the overall volume and weight of the fuel cell (especially the fuel cell stack), which is conducive to integrating the fuel cell into a portable consumer electronics.
2.本新型燃料电池装置利用双面流道板板体本身的刚性,因而可将集电片制造为极薄的结构,可让燃料电池本身的体积及重量大幅减少。2. The new fuel cell device utilizes the rigidity of the double-sided flow channel plate itself, so the current collector can be made into an extremely thin structure, which can greatly reduce the volume and weight of the fuel cell itself.
3.本新型燃料电池装置所使用的双面流道板可通过使用具有抗化性非导体的工程塑料材质的板体,再设置导电材料的集电片,如此不但可让燃料电池的重量轻而具有可携带的便利性,且同时使双面流道板具有良好的集电功能。3. The double-sided flow channel plate used in the new fuel cell device can use a chemical-resistant non-conductive engineering plastic plate body, and then set a conductive material collector sheet, which not only makes the fuel cell lighter in weight And it has the convenience of being portable, and at the same time makes the double-sided flow channel plate have a good current collecting function.
4.本新型燃料电池装置所使用的双面流道板可有效防止燃料(如:甲醇)或电化学反应生成物对集电片的表面进行破坏,因而降低燃料电池的汰换率。4. The double-sided flow channel plate used in the new fuel cell device can effectively prevent fuel (such as: methanol) or electrochemical reaction products from damaging the surface of the current collector, thereby reducing the replacement rate of the fuel cell.
为使熟悉该项技术人士了解本新型的目的、特征及功效,兹通过下述具体实施例,并配合附图,对本新型详加说明如后。In order to make those skilled in the art understand the purpose, features and effects of the present invention, the present invention will be described in detail as follows through the following specific embodiments, together with the accompanying drawings.
附图说明Description of drawings
图1是本新型燃料电池装置的一具体实施例基本部分的立体组合图;Fig. 1 is a three-dimensional assembled view of the basic parts of a specific embodiment of the novel fuel cell device;
图2A是本新型燃料电池装置的另一具体实施例基本部分的立体组合图;Fig. 2A is a three-dimensional assembled view of the basic parts of another specific embodiment of the new fuel cell device;
图2B是本新型图2A的立体分解图;Fig. 2B is a three-dimensional exploded view of Fig. 2A of the present invention;
图3A是本新型燃料电池装置的又一具体实施例基本部分的立体组合图;Fig. 3A is a three-dimensional assembled view of the basic parts of another specific embodiment of the new fuel cell device;
图3B是本新型图3A的立体分解图;Fig. 3B is a three-dimensional exploded view of Fig. 3A of the present invention;
图4A显示本新型燃料电池装置所使用的双面流道板的细部结构剖面示意图;FIG. 4A shows a schematic cross-sectional view of the detailed structure of the double-sided flow channel plate used in the novel fuel cell device;
图4B显示图4A双面流道板的变化实施例的剖面示意图;Fig. 4B shows a schematic cross-sectional view of a variant embodiment of the double-sided flow channel plate in Fig. 4A;
图5是图2A燃料电池装置的变化实施例基本部分的立体分解图。Fig. 5 is a three-dimensional exploded view of the essential part of a variant embodiment of the fuel cell device in Fig. 2A.
符号说明Symbol Description
燃料电池装置(1)、(2)、(3) 膜电极组(10)、(20)、(30)Fuel cell device (1), (2), (3) Membrane electrode group (10), (20), (30)
阳极电极(100)、(200)、(300) 质子交换膜(102)、(202)、(302)Anode electrode (100), (200), (300) Proton exchange membrane (102), (202), (302)
阴极电极(104)、(204)、(304) 槽沟(120)、(220)、(320)、(322)Cathode electrode (104), (204), (304) Groove (120), (220), (320), (322)
双面流道板(12)、(22)、(32) 基板(24)Double-sided runner plate (12), (22), (32) Substrate (24)
渠道(240) 进口(240a)Channel (240) Import (240a)
电路组件(26) 引线(28)Circuit Assembly(26) Leads(28)
板体(40) 集电片(42)Plate body(40) Collector sheet(42)
金属层(42a) 电路组件(44)metal layer (42a) circuit assembly (44)
具体实施方式Detailed ways
图1显示本新型燃料电池装置的一具体实施例基本部分的立体组合图。Fig. 1 shows a three-dimensional assembled view of the basic parts of a specific embodiment of the new fuel cell device.
参考图1所显示,本新型的燃料电池装置(1)是单一燃料电池,其是至少包括:膜电极组(10)、双面流道板(12)。其中,膜电极组(10)是至少包含:阳极电极(100)、质子交换膜(102)以及阴极电极(104)。双面流道板(12)是设置于膜电极组(10)的一侧,而且双面流道板(12)是使用一波形结构。如图1所显示,本新型燃料电池装置可通过一供给机制来使得燃料通过槽沟(120)来与膜电极组(10)进行电化学反应,因而产生电力。As shown in Fig. 1, the fuel cell device (1) of the present invention is a single fuel cell, which at least includes: a membrane electrode group (10), and a double-sided flow channel plate (12). Wherein, the membrane electrode group (10) at least includes: an anode electrode (100), a proton exchange membrane (102) and a cathode electrode (104). The double-sided flow channel plate (12) is arranged on one side of the membrane electrode group (10), and the double-sided flow channel plate (12) uses a corrugated structure. As shown in FIG. 1 , the fuel cell device of the present invention can make the fuel pass through the groove ( 120 ) to perform an electrochemical reaction with the membrane electrode group ( 10 ) through a supply mechanism, thereby generating electricity.
图2A是本新型燃料电池装置的另一具体实施例基本部分的立体组合图。图2B是本新型图2A的立体分解图。参考图2A及图2B所显示,本新型的燃料电池装置(2)是一燃料电池堆(stack),其是至少包括:该些膜电极组(20)、双面流道板(22)。其中,膜电极组(20)是至少包含:阳极电极(200)、质子交换膜(202)以及阴极电极(204)。双面流道板(22)是设置于该些膜电极组(20)的一侧,特别是设置于该些膜电极组(20)的该些阳极电极(200)之间,而且双面流道板(22)是使用一波形结构。当然,本新型燃料电池装置(2)中的双面流道板(22)并非仅限定于设置在该些膜电极组(20)的该些阳极电极(200)之间的情况下,其亦可应用于多种变化实施例,例如:可将双面流道板(22)设置于该些膜电极组(20)的该些阴极电极(204)之间,或者可将双面流道板(22)设置于该些膜电极组(20)的该阳极电极(200)与该阴极电极(204)之间。另外如图2A所显示,本新型燃料电池装置可通过一供给机制来使得燃料通过槽沟(220)来与该些膜电极组(20)进行电化学反应,因而产生电力。Fig. 2A is a three-dimensional combined view of the basic parts of another specific embodiment of the fuel cell device of the present invention. FIG. 2B is an exploded perspective view of FIG. 2A of the present invention. Referring to Fig. 2A and Fig. 2B, the fuel cell device (2) of the present invention is a fuel cell stack (stack), which at least includes: the membrane electrode groups (20) and double-sided flow channel plates (22). Wherein, the membrane electrode group (20) at least includes: an anode electrode (200), a proton exchange membrane (202) and a cathode electrode (204). The double-sided flow channel plate (22) is arranged on one side of the membrane electrode groups (20), especially arranged between the anode electrodes (200) of the membrane electrode groups (20), and the two-sided flow The track plate (22) uses a corrugated structure. Of course, the double-sided flow channel plate (22) in the novel fuel cell device (2) is not limited to being arranged between the anode electrodes (200) of the membrane electrode groups (20), it is also It can be applied to a variety of variant embodiments, for example: the double-sided flow channel plate (22) can be arranged between the cathode electrodes (204) of the membrane electrode groups (20), or the double-sided flow channel plate can be (22) arranged between the anode electrode (200) and the cathode electrode (204) of the membrane electrode groups (20). In addition, as shown in FIG. 2A , the fuel cell device of the present invention can make the fuel pass through the groove ( 220 ) to perform electrochemical reaction with the membrane electrode groups ( 20 ) through a supply mechanism, thereby generating electricity.
图3A是本新型燃料电池装置的又一具体实施例基本部分的立体组合图。图3B是本新型图3A的立体分解图。参考图3A及图3B所显示,本新型的燃料电池装置(3)是一燃料电池堆(stack),其是至少包括:该些膜电极组(30)、该些双面流道板(32)。其中,该些膜电极组(30)是设置于该些双面流道板(32)之间,其是至少包含:阳极电极(300)、质子交换膜(302)以及阴极电极(304)。而且,该些双面流道板(32)是使用一波形结构。如第三A图所显示,本新型燃料电池装置可通过一供给机制来使得燃料或空气可以通过槽沟(320)或槽沟(322)来与该些膜电极组(30)进行电化学反应,因而产生电力。Fig. 3A is a three-dimensional assembled view of the basic parts of another specific embodiment of the new fuel cell device. Fig. 3B is an exploded perspective view of Fig. 3A of the present invention. Shown with reference to Fig. 3A and Fig. 3B, the fuel cell device (3) of the present invention is a fuel cell stack (stack), and it is to comprise at least: these membrane electrode groups (30), these double-sided flow channel plates (32 ). Wherein, the membrane electrode groups (30) are arranged between the double-sided channel plates (32), which at least include: an anode electrode (300), a proton exchange membrane (302) and a cathode electrode (304). Moreover, the double-sided flow channel plates (32) use a corrugated structure. As shown in the third figure A, the fuel cell device of the present invention can use a supply mechanism to enable fuel or air to undergo electrochemical reactions with the membrane electrode groups (30) through the grooves (320) or grooves (322) , thus generating electricity.
图4A显示本新型燃料电池装置所使用的双面流道板(12)、(22)、(32)的细部结构剖面示意图。参考图4A所显示,本新型所使用的双面流道板(12)、(22)、(32)包括:板体(40)是具有至少一个以上的流道结构,其中该些流道结构的设置位置,是对应配合该些膜电极组(10)、(20)、(30)的设置位置,如第四图所显示,该流道结构是一波形结构。该些集电片(42)是一导电材料且该些集电片(42)分别覆盖住板体(40)的该些流道结构,以及该些集电片(42)是固定于板体(40),如图4A所显示,该些集电片(42)同样是使用一波形结构。在材质选用方面,板体(40)的基材可以选择一抗化性非导体工程塑料基板、塑料碳基板、FR4基板、FR5基板、环氧树酯基板、玻纤基板、陶瓷基板、高分子塑化基板以及复合式材料基板等其中一种。而集电片(42)的材质可以是选择一导电性佳的材料,且其表面特别是经过抗腐蚀及/或防酸的处理或其本身即具有该特性的抗化性金属材料(如:不锈钢、钛、金、石墨、碳金属化合物等)。再者,集电片(42)可进一步包含金属层(42a),通过溅镀、喷镀等制程以形成于集电片(42)的表面上,其中金属层(42a)的材质,可以是选择自金、铜、银、碳、高导电性金属等其中一种。FIG. 4A shows a schematic cross-sectional view of the detailed structure of the double-sided flow channel plates (12), (22), and (32) used in the fuel cell device of the present invention. Shown with reference to Fig. 4A, the double-sided flow channel plate (12), (22), (32) used in the present invention comprises: plate body (40) is to have at least one flow channel structure, wherein these flow channel structures The setting positions of the membrane electrode groups (10), (20) and (30) are corresponding to the setting positions of these membrane electrode groups (10), (20), (30). As shown in the fourth figure, the channel structure is a wave structure. These collector sheets (42) are a conductive material and these collector sheets (42) respectively cover the flow channel structures of the plate body (40), and these collector sheets (42) are fixed on the plate body (40), as shown in FIG. 4A, the current collectors (42) also use a wave structure. In terms of material selection, the base material of the plate body (40) can be selected from chemical-resistant non-conductive engineering plastic substrates, plastic carbon substrates, FR4 substrates, FR5 substrates, epoxy resin substrates, glass fiber substrates, ceramic substrates, polymer substrates, etc. One of plasticized substrates and composite material substrates. And the material of current collector sheet (42) can be to select the good material of a conductivity, and its surface especially through anti-corrosion and/or anti-acid treatment or its own promptly has the chemical resistance metal material of this characteristic (as: stainless steel, titanium, gold, graphite, carbon metal compounds, etc.). Moreover, the collector sheet (42) may further include a metal layer (42a), which is formed on the surface of the collector sheet (42) through processes such as sputtering and spraying, wherein the material of the metal layer (42a) may be Choose from one of gold, copper, silver, carbon, highly conductive metals, and more.
图4B显示图4A双面流道板的变化实施例的剖面示意图。如图4B所显示,板体(40)可进一步设置有一个以上的电路组件(44),电路组件(44)可以是一布线(circuitry),且特别是一印刷式布线(printed circuitry),其中电路组件(44)是与集电片(42)作电气连接。FIG. 4B shows a schematic cross-sectional view of a variant embodiment of the double-sided flow channel plate in FIG. 4A . As shown in Figure 4B, the board body (40) can be further provided with more than one circuit assembly (44), and the circuit assembly (44) can be a wiring (circuitry), and particularly a printed wiring (printed circuitry), wherein The circuit assembly (44) is electrically connected with the collector sheet (42).
图5是图2A燃料电池装置的变化实施例基本部分的立体分解图。如图5所显示,本新型的燃料电池装置(2)可进一步包括:基板(24),是具有至少一个以上的中空部,其中该些中空部的设置位置,是对应配合该些膜电极组(20)的设置位置,且使得该些膜电极组(20)及双面流道板(22)能够压合密接至基板(24)上。再者,基板(24)可进一步设置有一个以上的电路组件(26),电路组件(26)可以是一布线(circuitry),且特别是一印刷式布线(printed circuitry),其中电路组件(26)可透过与引线(28)接触,而与双面流道板(22)的该些集电片(42)作电气连接,以使得该些集电片(42)是透过该布线而电气连接成一串联及/或并联电路,因而可将燃料电池堆的各电力产生单元作一连结。而在本新型燃料电池装置(2)的燃料供给机制方面,是可透过设置于基板(24)上的渠道(240)来具体实施。首先,将燃料注入进口(240a),接着燃料沿着渠道(240)行进,最后流至槽沟(220)中,燃料便可因此与该些膜电极组(20)进行电化学反应,因而产生电力。Fig. 5 is a three-dimensional exploded view of the essential part of a variant embodiment of the fuel cell device in Fig. 2A. As shown in Figure 5, the fuel cell device (2) of the present invention may further include: a substrate (24) having at least one hollow portion, wherein the positions of these hollow portions are correspondingly matched with the membrane electrode groups (20), and make the membrane electrode groups (20) and the double-sided flow channel plate (22) can be pressed and tightly connected to the substrate (24). Moreover, the substrate (24) can be further provided with more than one circuit assembly (26), and the circuit assembly (26) can be a wiring (circuitry), and particularly a printed wiring (printed circuitry), wherein the circuit assembly (26 ) can be electrically connected to the current collectors (42) of the double-sided flow channel plate (22) through contact with the lead wire (28), so that the current collectors (42) are connected through the wiring The electrical connections form a series and/or parallel circuit, so that the power generating units of the fuel cell stack can be connected together. In terms of the fuel supply mechanism of the novel fuel cell device (2), it can be implemented through the channels (240) arranged on the substrate (24). First, the fuel is injected into the inlet (240a), then the fuel travels along the channel (240), and finally flows into the groove (220), so that the fuel can electrochemically react with the membrane electrode groups (20), thus generating electricity.
本新型的燃料电池装置可以是一种采用液态燃料(如:甲醇)的燃料电池、或采用气态燃料的燃料电池、或采用固态燃料的燃料电池等等。最后,归纳本新型的有益效果如下:The fuel cell device of the present invention may be a fuel cell using liquid fuel (such as: methanol), or a fuel cell using gaseous fuel, or a fuel cell using solid fuel, and the like. Finally, the beneficial effects of the present invention are summarized as follows:
1.本新型燃料电池装置使用一种具有波形结构的双面流道板,可让燃料电池(特别是燃料电池堆)整体的体积及重量皆大幅减少,此有利于将燃料电池整合至便携式的消费性电子产品。1. The new fuel cell device uses a double-sided flow channel plate with a corrugated structure, which can greatly reduce the overall volume and weight of the fuel cell (especially the fuel cell stack), which is conducive to integrating the fuel cell into a portable consumer electronics.
2.本新型燃料电池装置利用双面流道板板体本身的刚性,因而可将集电片制造为极薄的结构,可让燃料电池本身的体积及重量大幅减少。2. The new fuel cell device utilizes the rigidity of the double-sided flow channel plate itself, so the current collector can be made into an extremely thin structure, which can greatly reduce the volume and weight of the fuel cell itself.
3.本新型燃料电池装置所使用的双面流道板可通过使用具有抗化性非导体的工程塑料材质的板体,再设置导电材料的集电片,如此不但可让燃料电池的重量轻而具有可携带的便利性,且同时使双面流道板具有良好的集电功能。3. The double-sided flow channel plate used in the new fuel cell device can use a chemical-resistant non-conductive engineering plastic plate body, and then set a conductive material collector sheet, which not only makes the fuel cell lighter in weight And it has the convenience of being portable, and at the same time makes the double-sided flow channel plate have a good current collecting function.
4.本新型燃料电池装置所使用的双面流道板可有效防止燃料(如:甲醇)或电化学反应生成物对集电片的表面进行破坏,因而降低燃料电池的汰换率。4. The double-sided flow channel plate used in the new fuel cell device can effectively prevent fuel (such as: methanol) or electrochemical reaction products from damaging the surface of the current collector, thereby reducing the replacement rate of the fuel cell.
虽然本新型已以具体实施例公开如上,然其所公开的具体实施例并非用以限定本新型,任何熟悉此技术人士,在不脱离本新型的精神和范围内,当可作各种的更动与润饰,其所作的更动与润饰都属于本新型的范畴,本新型的保护范围当以本申请权利要求所界定为准。Although the present invention has been disclosed as above with specific embodiments, the disclosed specific embodiments are not intended to limit the present invention. Any person familiar with this technology may make various modifications without departing from the spirit and scope of the present invention. The changes and modifications made by it all belong to the category of the present model, and the protection scope of the present model should be defined by the claims of the present application as the criterion.
Claims (22)
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