CN2492947Y - Amorphous Aluminum Indium Gallium Nitride Light Emitting Diode Device - Google Patents
Amorphous Aluminum Indium Gallium Nitride Light Emitting Diode Device Download PDFInfo
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- AJGDITRVXRPLBY-UHFFFAOYSA-N aluminum indium Chemical compound [Al].[In] AJGDITRVXRPLBY-UHFFFAOYSA-N 0.000 title claims description 7
- 229910002601 GaN Inorganic materials 0.000 title abstract description 9
- JMASRVWKEDWRBT-UHFFFAOYSA-N Gallium nitride Chemical compound [Ga]#N JMASRVWKEDWRBT-UHFFFAOYSA-N 0.000 title abstract description 9
- 150000001875 compounds Chemical class 0.000 claims abstract description 72
- 239000004065 semiconductor Substances 0.000 claims abstract description 72
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 239000000758 substrate Substances 0.000 claims abstract description 7
- 229910052594 sapphire Inorganic materials 0.000 claims abstract description 4
- 239000010980 sapphire Substances 0.000 claims abstract description 4
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 claims 2
- 229910052733 gallium Inorganic materials 0.000 claims 2
- 239000013078 crystal Substances 0.000 abstract description 42
- 238000001947 vapour-phase growth Methods 0.000 abstract description 6
- AUCDRFABNLOFRE-UHFFFAOYSA-N alumane;indium Chemical compound [AlH3].[In] AUCDRFABNLOFRE-UHFFFAOYSA-N 0.000 abstract 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 4
- 229910021529 ammonia Inorganic materials 0.000 description 3
- KWYKSRAECRPMIS-UHFFFAOYSA-N azane;hydrazine Chemical compound N.NN KWYKSRAECRPMIS-UHFFFAOYSA-N 0.000 description 3
- XCZXGTMEAKBVPV-UHFFFAOYSA-N trimethylgallium Chemical compound C[Ga](C)C XCZXGTMEAKBVPV-UHFFFAOYSA-N 0.000 description 3
- JTHLJMVZBVXXSE-UHFFFAOYSA-N C1(C=CC=C1)[Mg]C1C=CC=C1.[Mg] Chemical compound C1(C=CC=C1)[Mg]C1C=CC=C1.[Mg] JTHLJMVZBVXXSE-UHFFFAOYSA-N 0.000 description 2
- HBCLZMGPTDXADD-UHFFFAOYSA-N C[Zn](C)C Chemical compound C[Zn](C)C HBCLZMGPTDXADD-UHFFFAOYSA-N 0.000 description 2
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 238000000137 annealing Methods 0.000 description 2
- 229910052790 beryllium Inorganic materials 0.000 description 2
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 description 2
- 229910052793 cadmium Inorganic materials 0.000 description 2
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 2
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 2
- 238000010894 electron beam technology Methods 0.000 description 2
- BLJHFCVPKWOHJX-UHFFFAOYSA-N ethylgallium Chemical compound CC[Ga] BLJHFCVPKWOHJX-UHFFFAOYSA-N 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052711 selenium Inorganic materials 0.000 description 2
- 239000011669 selenium Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052714 tellurium Inorganic materials 0.000 description 2
- PORWMNRCUJJQNO-UHFFFAOYSA-N tellurium atom Chemical compound [Te] PORWMNRCUJJQNO-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- RGGPNXQUMRMPRA-UHFFFAOYSA-N triethylgallium Chemical compound CC[Ga](CC)CC RGGPNXQUMRMPRA-UHFFFAOYSA-N 0.000 description 2
- IBEFSUTVZWZJEL-UHFFFAOYSA-N trimethylindium Chemical compound C[In](C)C IBEFSUTVZWZJEL-UHFFFAOYSA-N 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 238000005253 cladding Methods 0.000 description 1
- NOVHEGOWZNFVGT-UHFFFAOYSA-N hydrazine Chemical compound NN.NN NOVHEGOWZNFVGT-UHFFFAOYSA-N 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- ZBZHVBPVQIHFJN-UHFFFAOYSA-N trimethylalumane Chemical compound C[Al](C)C.C[Al](C)C ZBZHVBPVQIHFJN-UHFFFAOYSA-N 0.000 description 1
- JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical compound C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 description 1
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Abstract
Description
发明领域field of invention
本实用新型涉及一种非晶系AlInGaN(氮化铝铟镓)发光二极管装置,其是将非晶系氮化铝铟镓(AlInGaN)发光二极管组件的第一p型非晶系化合物半导体层上依序形成一p型单晶或多晶系化合物半导体层、一单晶或多晶系化合物半导体杂质掺杂层、一p/n单晶或多晶系化合物半导体层及一n型单晶或多晶系化合物半导体层,在n型非晶系化合物半导体层上依序形成一p/n单晶或多晶系化合物半导体层、一单晶或多晶系化合物半导体杂质掺杂层、一第二p型单晶或多晶系化合物半导体层及一第一p型单晶或多晶系化合物半导体层。The utility model relates to an amorphous system AlInGaN (aluminum indium gallium nitride) light-emitting diode device, which is formed on the first p-type amorphous compound semiconductor layer of the amorphous system aluminum indium gallium nitride (AlInGaN) light-emitting diode assembly sequentially forming a p-type single crystal or polycrystalline compound semiconductor layer, a single crystal or polycrystalline compound semiconductor impurity-doped layer, a p/n single crystal or polycrystalline compound semiconductor layer, and an n-type single crystal or The polycrystalline compound semiconductor layer is formed sequentially on the n-type amorphous compound semiconductor layer with a p/n single crystal or polycrystalline compound semiconductor layer, a single crystal or polycrystalline compound semiconductor impurity-doped layer, and a first Two p-type single crystal or polycrystalline compound semiconductor layers and a first p-type single crystal or polycrystalline compound semiconductor layer.
背景技术Background technique
目前,传统的非晶系AlInGaN发光二极管装置,请参阅图1、图2,其中图1所示是在一p型氮化镓基板100依序形成一第一p型非晶系化合物半导体层102、一第二p型非晶系化合物半导体层104、一非晶系化合物半导体杂质掺杂层106、一p/n非晶系化合物半导体层108及一n型非晶系化合物半导体层110;At present, the traditional amorphous AlInGaN light-emitting diode device, please refer to FIG. 1 and FIG. 2, wherein FIG. 1 shows that a first p-type amorphous compound semiconductor layer 102 is sequentially formed on a p-type gallium nitride substrate 100. , a second p-type amorphous compound semiconductor layer 104, an amorphous compound semiconductor impurity-doped layer 106, a p/n amorphous compound semiconductor layer 108, and an n-type amorphous compound semiconductor layer 110;
图2所示是在一蓝宝石基板200上依序形成一n型非晶系化合物半导体层202、一p/n非晶系化合物半导体层204、一非晶系化合物半导体杂质掺杂层206、一第二p型非晶系化合物半导体层208及一第一p型非晶系化合物半导体层210;As shown in FIG. 2, an n-type amorphous
通过在其间提供p/n接面,以实现高发光率与降低成本。By providing p/n junctions therebetween, high luminous efficiency and cost reduction can be achieved.
但是,其并不能适用在单晶系或多晶系AlInGaN发光二极管。However, it cannot be applied to single crystal or polycrystalline AlInGaN light emitting diodes.
发明内容Contents of the invention
本实用新型旨在针对上述装置作更进一步改良设计,其是在非晶系AlInGaN发光二极管装置的第一p型非晶系化合物半导体层上依序形成一p型单晶或多晶系化合物半导体层、一单晶或多晶系化合物半导体杂质掺杂层、一p/n单晶或多晶系化合物半导体层及一n型单晶或多晶系化合物半导体层。The utility model aims to further improve the design of the above-mentioned device, which is to sequentially form a p-type single crystal or polycrystalline compound semiconductor on the first p-type amorphous compound semiconductor layer of the amorphous AlInGaN light-emitting diode device layer, a single crystal or polycrystalline compound semiconductor impurity-doped layer, a p/n single crystal or polycrystalline compound semiconductor layer, and an n-type single crystal or polycrystalline compound semiconductor layer.
本实用新型的另一目的,在于提供一可完成高发光率效果的发光二极管组件结构,其是将非晶系AlInGaN发光二极管装置之n型非晶系化合物半导体层上依序形成一p/n单晶或多晶系化合物半导体层、一单晶或多晶系化合物半导体杂质掺杂层、一第二p型单晶或多晶系化合物半导体层及一第一p型单晶或多晶系化合物半导体层。Another object of the present invention is to provide a light-emitting diode component structure that can achieve high luminous efficiency effects, which is to sequentially form a p/n on the n-type amorphous compound semiconductor layer of the amorphous AlInGaN light-emitting diode device. Single crystal or polycrystalline compound semiconductor layer, a single crystal or polycrystalline compound semiconductor impurity-doped layer, a second p-type single crystal or polycrystalline compound semiconductor layer and a first p-type single crystal or polycrystalline compound semiconductor layer.
为实现上述目的,本实用新型提出一种非晶系氮化铝铟镓发光二极管装置,其在一p型氮化镜基板上依序形成一第一p型非晶系化合物半导体层、一第二p型单晶或多晶系化合物半导体层、一单晶或多晶系化合物半导体杂质掺杂层、一p/n单晶或多晶系化合物半导体层及一n型单晶或多晶系化合物半导体层;In order to achieve the above object, the utility model proposes an amorphous aluminum indium gallium nitride light-emitting diode device, which sequentially forms a first p-type amorphous compound semiconductor layer, a first Two p-type single crystal or polycrystalline compound semiconductor layers, a single crystal or polycrystalline compound semiconductor impurity-doped layer, a p/n single crystal or polycrystalline compound semiconductor layer, and an n-type single crystal or polycrystalline compound semiconductor layer compound semiconductor layer;
借此,以形成发光二极管组件结构,达成高发光率效果。In this way, the light-emitting diode assembly structure is formed to achieve the effect of high luminous efficiency.
一种非晶系氮化铝铟镓发光二极管装置,其在一蓝宝石基材上依序形成一第一n型非晶系化合物半导体层、一p/n单晶或多晶系化合物半导体层、一单晶或多晶系化合物半导体杂质掺杂层、一第二p型单晶或多晶系化合物半导体层及一第一p型单晶或多晶系化合物半导体层。An amorphous aluminum indium gallium nitride light-emitting diode device, which sequentially forms a first n-type amorphous compound semiconductor layer, a p/n single crystal or polycrystalline compound semiconductor layer on a sapphire substrate, A single crystal or polycrystalline compound semiconductor impurity-doped layer, a second p-type single crystal or polycrystalline compound semiconductor layer and a first p-type single crystal or polycrystalline compound semiconductor layer.
借此,以形成发光二极管组件结构,达成高发光率效果。In this way, the light-emitting diode assembly structure is formed to achieve the effect of high luminous efficiency.
综上所述,通过本实用新型非晶系AlInGaN发光二极管装置的结构,可形成高发光率。To sum up, through the structure of the amorphous AlInGaN light emitting diode device of the present invention, high luminous efficiency can be formed.
附图说明:Description of drawings:
图1、图2是传统非晶系AlInGaN发光二极管装置的示意图;Figures 1 and 2 are schematic diagrams of conventional amorphous AlInGaN light-emitting diode devices;
图3是本实用新型第一实施组件的结构图;Fig. 3 is a structural diagram of the first implementation assembly of the utility model;
图4是本实用新型第二实施组件的结构图。Fig. 4 is a structural diagram of the second implementation assembly of the utility model.
具体实施方式Detailed ways
为完成上述目的与结构,本实用新型所采用的技术手段及其功效,现结合附图就本实用新型的实施例详细说明其结构及功能如下,以便完全了解。In order to accomplish the above-mentioned purpose and structure, the technical means adopted by the utility model and its effects, the structure and functions of the utility model are described in detail below in conjunction with the accompanying drawings, so as to fully understand.
请参阅图3,是本实用新型非晶系AlInGaN发光二极管装置的第一实施例的结构图。其是在一p型氮化镓基板100上,用汽相成长等方式依序成长一第一p型非晶系化合物半导体层102、一第二p型单晶或多晶系化合物半导体层103、一单晶或多晶系化合物半导体杂质掺杂层105、一p/n单晶或多晶系化合物半导体层107及一n型单晶或多晶系化合物半导体层109。Please refer to FIG. 3 , which is a structural view of the first embodiment of the amorphous AlInGaN light emitting diode device of the present invention. On a p-type gallium nitride substrate 100, a first p-type amorphous compound semiconductor layer 102 and a second p-type single crystal or polycrystalline compound semiconductor layer 103 are sequentially grown by means of vapor phase growth or the like. , a single crystal or polycrystalline compound semiconductor impurity-doped layer 105 , a p/n single crystal or polycrystalline compound semiconductor layer 107 and an n-type single crystal or polycrystalline compound semiconductor layer 109 .
其中第一p型非晶系化合物半导体层102作为缓冲层;第二p型单晶或多晶系化合物半导体层103作为下侧覆盖层,单晶或多晶系化合物半导体杂质掺杂层105作为发光层;p/n单晶或多晶系化合物半导体层107作为上侧覆盖层;n型单晶或多晶系化合物半导体层109作为电极,并提供p/n接面。Wherein the first p-type amorphous compound semiconductor layer 102 is used as a buffer layer; the second p-type single crystal or polycrystalline compound semiconductor layer 103 is used as the lower side cladding layer, and the single crystal or polycrystalline compound semiconductor impurity doped layer 105 is used as The light emitting layer; the p/n single crystal or polycrystalline compound semiconductor layer 107 serves as an upper cover layer; the n-type single crystal or polycrystalline compound semiconductor layer 109 serves as an electrode and provides a p/n junction.
上述p型杂质可为锌、镁、铍、锶及/或镉。n型杂质可为硅、锗、锡、硫、碲及/或硒。且在加入杂质后,可进行温度600-1200℃,1-50分钟的加热,退火或是电子束射击步骤(electron-beam shooting)。The p-type impurities mentioned above can be zinc, magnesium, beryllium, strontium and/or cadmium. The n-type impurities can be silicon, germanium, tin, sulfur, tellurium and/or selenium. And after the impurity is added, heating at a temperature of 600-1200° C. for 1-50 minutes, annealing or electron-beam shooting can be performed.
另外汽相成长气体包含氨(ammonia)、联胺(hydrazine)或氨一联胺(ammonia-hydrazine)结合三甲基铝(trimethyl aluminum),并加入三甲基镓(trimethyl gallium)及/或三乙基镓(triethylgallium)。或是汽相成长气体包含混合后使用的二乙基锌(diethyl-zinc)、三甲基锌(trimethyl-zinc)、三甲基铟(trimethyl-indium)、环戊二烯基镁(cyclopentadienyl-magnesium)。In addition, the vapor phase growth gas includes ammonia, hydrazine, or ammonia-hydrazine combined with trimethyl aluminum, and trimethyl gallium and/or trimethyl gallium are added. Ethyl gallium (triethylgallium). Or the vapor phase growth gas contains diethyl-zinc, trimethyl-zinc, trimethyl-indium, cyclopentadienyl magnesium (cyclopentadienyl- Magnesium).
请参阅图4,是本实用新型非晶系AlInGaN发光二极管装置的第二实施例的结构图。其是在一蓝宝石基材200上,用汽相成长等方式依序成长一第一n型非晶系化合物半导体层202、一p/n单晶或多晶系化合物半导体层203、一单晶或多晶系化合物半导体杂质掺杂层205、一第二p型单晶或多晶系化合物半导体层207及一第一p型单晶或多晶系化合物半导体层209。Please refer to FIG. 4 , which is a structural diagram of a second embodiment of the amorphous AlInGaN light emitting diode device of the present invention. On a
其中,n型非晶系化合物半导体层202作为缓冲层;p/n单晶或多晶系化合物半导体层203作为下侧覆盖层;单晶或多晶系化合物半导体杂质掺杂层205作为发光层;第二p型单晶或多晶系化合物半导体层207作为上侧覆盖层;第一p型单晶或多晶系化合物半导体层209作为电极层并提供p/n接面。Wherein, the n-type amorphous
上述D型杂质可为锌、镁、铍、锶及/或镉。n型杂质可为硅、锗、锡、硫、碲及/或硒。且在加入杂质后,可进行温度600-1200℃,1-50分钟的加热,退火或是电子束射击步骤(electron-beam shooting)。The above-mentioned D-type impurities may be zinc, magnesium, beryllium, strontium and/or cadmium. The n-type impurities can be silicon, germanium, tin, sulfur, tellurium and/or selenium. And after the impurity is added, heating at a temperature of 600-1200° C. for 1-50 minutes, annealing or electron-beam shooting can be performed.
另汽相成长气体包含氨(ammonia)、联胺(hydrazine)或氨-联胺(ammonia-hydrazine)结合三甲基铝(trimethyl aluminum),并加入三甲基镓(trimethyl galliuln)及/或三乙基镓(triethyl gallium)。或是汽相成长气体包含混合后使用的二乙基锌(diethyl-zinc)、三甲基锌(trimethyl-zinc)、三甲基铟(trimethyl-indium)、环戊二烯基镁(cyclopentadienyl-magnesium)。Another vapor phase growth gas comprises ammonia (ammonia), hydrazine (hydrazine) or ammonia-hydrazine (ammonia-hydrazine) combined with trimethyl aluminum (trimethyl aluminum), and added trimethyl gallium (trimethyl galliuln) and/or three Ethyl gallium (triethyl gallium). Or the vapor phase growth gas contains diethyl-zinc, trimethyl-zinc, trimethyl-indium, cyclopentadienyl magnesium (cyclopentadienyl- Magnesium).
以上所述,仅为本实用新型的最佳之一具体实施例,但本实用新型的构造特征并不局限于此,任何熟悉该项技术的人在本实用新型的领域内,可轻易思及的变化或修饰皆可被涵盖在本实用新型的权利要求的保护范围内。The above is only one of the best specific embodiments of the present utility model, but the structural features of the present utility model are not limited thereto, any person familiar with this technology can easily think of it in the field of the present utility model All changes or modifications can be covered within the protection scope of the claims of the present utility model.
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| CN100358166C (en) * | 2004-09-16 | 2007-12-26 | 璨圆光电股份有限公司 | Nitride epitaxial layer structure and fabrication method thereof |
| US8222650B2 (en) | 2001-12-24 | 2012-07-17 | Crystal Is, Inc. | Nitride semiconductor heterostructures and related methods |
| US8323406B2 (en) | 2007-01-17 | 2012-12-04 | Crystal Is, Inc. | Defect reduction in seeded aluminum nitride crystal growth |
| CN101331249B (en) * | 2005-12-02 | 2012-12-19 | 晶体公司 | Doped aluminum nitride crystals and methods of making them |
| US9028612B2 (en) | 2010-06-30 | 2015-05-12 | Crystal Is, Inc. | Growth of large aluminum nitride single crystals with thermal-gradient control |
| US9034103B2 (en) | 2006-03-30 | 2015-05-19 | Crystal Is, Inc. | Aluminum nitride bulk crystals having high transparency to ultraviolet light and methods of forming them |
| US9299880B2 (en) | 2013-03-15 | 2016-03-29 | Crystal Is, Inc. | Pseudomorphic electronic and optoelectronic devices having planar contacts |
| US9447521B2 (en) | 2001-12-24 | 2016-09-20 | Crystal Is, Inc. | Method and apparatus for producing large, single-crystals of aluminum nitride |
| US9771666B2 (en) | 2007-01-17 | 2017-09-26 | Crystal Is, Inc. | Defect reduction in seeded aluminum nitride crystal growth |
| US10074784B2 (en) | 2011-07-19 | 2018-09-11 | Crystal Is, Inc. | Photon extraction from nitride ultraviolet light-emitting devices |
| US10446391B2 (en) | 2007-01-26 | 2019-10-15 | Crystal Is, Inc. | Thick pseudomorphic nitride epitaxial layers |
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2001
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