Atmosphere pollution is the focus of world many countries environmental protection always, and the flue gas desulfurization technique that various countries successively develop has reached kind more than 200.But, can commercial Application have only kind more than ten.Tail gas for the waste incineration generation, except that containing conventional coal-fired flue-gas pollutant such as nitrogen oxide, oxysulfide, fine grained and heavy metal, also contain harmful substances such as more substantial simple substance chlorine, hydrogen chloride, dioxin, conventional desulfurization and dedusting technology can not satisfy the strict purification of garbage incinerating tail gas requirement.Existing external garbage incinerating tail gas purification techniques mostly adopts wet method, as U.S. Pat 4789532 are the sour gas that adopt in the conventional spray lime slurry absorption tail gas, as sulfur dioxide, hydrogen chloride, simple substance chlorine etc., behind reactor, connect the sack cleaner dedusting then.Though said apparatus can be removed sour gas and flying dust in the tail gas, exist equipment investment and operating cost height, floor space big, can not effectively remove heavy metal and the fine grain problem of dioxin that waste incineration produces.
At above-mentioned problems of the prior art, the purpose of this utility model provides a kind ofly invests that operating cost is low, floor space is little, is used for the device of comprehensive garbage incinerating tail gas purifying.Use this device, can make processing step simply, not only the effect of sour gas and flying dust is remarkable in the cleaning of off-gas, more outstanding is that it can effectively remove heavy metal and the dioxin fine grained that waste incineration produces.
In order to reach above-mentioned goal of the invention, the technical solution of the utility model realizes as follows: the device that is used for comprehensive garbage incinerating tail gas purifying, it comprises with the calcium base and removes the fluid bed clarifier that agent and adsorbent are the bed material, with the gas-solid separator that high efficiency cyclonic dust collector, electrostatic precipitator, sack cleaner or their combinations are formed, have the surge bunker and the mixing granulation device of feed and discharge device.Its design feature is: the arrival end of described fluid bed clarifier is provided with de Laval noz(zle) and the bed material inlet that tail gas is quickened.The de Laval noz(zle) other end and garbage incinerating tail gas inlet join.Bed material inlet joins with the outlet of mixing granulation device.The mixing granulation device is equipped with a plurality of batching inlets and joins with batcher.The batcher other end and surge bunker join.Surge bunker top and side top are equipped with gas-solid separator and discharge machine.Gas-solid separator top and side top are equipped with clean gas outlet and horizontal connection tube.The port of export of the horizontal connection tube other end and fluid bed clarifier joins.
According to above-mentioned technical scheme, a plurality of batching inlets of described mixing granulation device are admission port, active carbon material inlet and pulverized limestone material inlet; Thin, the thick hyperbola pipe in two ends in the middle of the shape of described de Laval noz(zle) is.
The utility model compared with prior art has the following advantages and good effect:
(1) on conventional dry recirculating fluidized bed flue gases purification basis, characteristics and purification requirement according to the garbage incinerating tail gas pollutant, organically combine integrated by recirculating fluidized bed clarifier, gas-solid separator and mixing granulation device, utilize the calcium base to remove agent and react the sour gas of removing in the tail gas, add adsorbents such as flying dust and active carbon simultaneously and effectively remove heavy metal and dioxin.Not only technology is simple, and compact equipment is reduced investment outlay and floor space, and good tail gas purification effect, satisfies environmental requirement fully, realizes the garbage incinerating tail gas qualified discharge.
(2) use the mixing granulation device to carry out granulation, can be according to exhaust temperature, pollutant levels and air velocity, in time regulate the addition of fresh material, adding speed, parameters such as granulation size, formation has the particle that enriches activated adoption position and pore structure, helps the optimum state and the best purification efficient of assurance system operation, improve the utilization rate of additive simultaneously, reduce its operating cost.
(3) in removing the process of pollutant, the bed material keeps the relatively dry state, has effectively avoided corrosive pipeline and blockage problem in the wet cleaning system.
(4) owing to adopt dry-type circulating fluidized bed tail gas clean-up technology, the required moisture of system is few, and product is dry state, has reduced water consumption, has avoided the water pollution problems in the wet method, and has reduced the processing cost of product.
The utility model is described in further detail below in conjunction with accompanying drawing and concrete embodiment.
Referring to accompanying drawing, from the garbage incinerating tail gas that combustion apparatus comes out, by gas inlet 13,, two ends thick hyperbola pipe thin through the centre is after de Laval noz(zle) 1 quickens, to enter fluid bed clarifier 2.Tail gas drives in fluid bed clarifier 2 and removes the bed that agent and flying dust, acticarbon form by the calcium base and expect fluidisation together, and fluidizing velocity fully conducts heat and mass transfer simultaneously up to the 5-10 meter per second.In this process, sour gas such as sulfur dioxide, sulfur trioxide, hydrogen chloride, simple substance chlorine and nitrogen oxide etc. and calcium base alkali compounds generation neutralization reaction in the tail gas generate solid calcium salt.Simultaneously ultra-fine grains such as heavy metal in the tail gas and dioxin are in that to expect to be adsorbed in the abundant mixed process agent flying dust and active carbon adsorbed and remove with bed.Solid particle after reaction and the absorption enters gas-solid separator 4 with air-flow through horizontal transition pipe 3, in gas-solid separator 4, use deduster, this deduster can be that sack cleaner, cyclone dust collectors, electrostatic precipitator or their organic assembling body realize that gas and the efficient of solid particle separate, dust removal efficiency is up to 99.9%, go forward side by side one-step removal acidic gas in flue gas, dioxin and heavy metal.The utility model desulfuration efficiency can reach more than 95%, and dechlorination efficiency is greater than 97%, and heavy metal and dioxin removal efficiency are all greater than 90%.Purified gas is discharged into chimney by clean gas outlet 14 through air-introduced machine.Gas-solid separator 4 removes the solid particle that gets off, complete reaction removes the agent particle and also do not have the agent particle that removes of complete reaction to enter surge bunker 5.Solid material in the surge bunker 5 enters mixing granulation device 8 by batcher 7 more than 90%, and all the other materials that do not circulate are discharged grey storehouse by discharge machine 6 and further handled.Enter in the mixing granulation device 8 recycle stock with from the pulverized limestone of pulverized limestone material inlet 9, the active carbon of active carbon material inlet 10 and the abundant mixing granulation of water of admission port 11, particle size range is 200-300um, maximum is no more than 500um.Mixed material after the granulation is as the bed material of recirculating fluidized bed clarifier 2, and enters in the fluid bed clarifier 2 via bed material inlet 12 by mixing granulation device 8 and to recycle.