CN222204933U - Self-sustaining electro-Fenton coupling biological membrane sewage treatment system - Google Patents
Self-sustaining electro-Fenton coupling biological membrane sewage treatment system Download PDFInfo
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- CN222204933U CN222204933U CN202420486390.7U CN202420486390U CN222204933U CN 222204933 U CN222204933 U CN 222204933U CN 202420486390 U CN202420486390 U CN 202420486390U CN 222204933 U CN222204933 U CN 222204933U
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
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- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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Abstract
本实用新型公开了一种自维持电芬顿耦合生物膜污水处理系统，包括协同处理池，所述协同处理池的池体底部铺设有曝气装置，协同处理池池体内设置有填料模块，且填料模块置于曝气装置上方，协同处理池池体内位于填料模块两侧分别设置有阳极部件和阴极部件。本实用新型采用电芬顿耦合生物膜技术高效处理水体中的新型污染物，氧气在电能作用下，在催化电极中转化成H2O2，H2O2在电极的催化作用下产生电子，电子能对难降解有机污染物进行矿化降解，实现深度去除。
The utility model discloses a self-sustaining electro-Fenton coupled biofilm sewage treatment system, comprising a coordinated treatment pool, an aeration device is laid at the bottom of the pool body of the coordinated treatment pool, a filler module is arranged in the pool body of the coordinated treatment pool, and the filler module is placed above the aeration device, and an anode component and a cathode component are arranged on both sides of the filler module in the pool body of the coordinated treatment pool. The utility model adopts electro-Fenton coupled biofilm technology to efficiently treat new pollutants in water bodies, oxygen is converted into H2O2 in the catalytic electrode under the action of electric energy, and H2O2 generates electrons under the catalytic action of the electrode, and the electrons can mineralize and degrade the difficult-to-degrade organic pollutants to achieve deep removal.
Description
Technical Field
The utility model relates to a self-maintaining electro-Fenton coupling biological membrane sewage treatment system, and belongs to the technical field of sewage treatment.
Background
At present, novel pollutants are of widespread international interest. Novel contaminants (CECs) refer to chemicals that are environmentally persistent, bioaccumulative, and biotoxic. The new pollutants mainly comprise environmental Endocrine Disruptors (EDCs), medicines and personal care products (PPCPs), antibiotic Resistance Genes (ARGs) and the like, and are detected in water supply, sewage and sludge anaerobic digestion systems, estuaries and coastal areas. Such substances present a relatively hidden environment from health risks and present a risk to environmental safety even when entering the environment at low doses.
With the development of modern technology, new pollutants are increasingly being detected in water environments. Because the traditional water treatment method can not well remove novel pollutants, we propose a self-sustaining electro-Fenton coupling biological membrane sewage treatment system for efficiently treating novel pollutants in water, and improving the degradation efficiency of organic matters and the water outlet safety.
Disclosure of utility model
The utility model aims to provide a self-maintaining electro-Fenton coupling biological membrane sewage treatment system, which adopts an electro-Fenton coupling biological membrane technology, can efficiently treat novel pollutants in a water body, achieves the effect of denitrification and dephosphorization, improves the degradation efficiency of organic matters, and ensures the safety of water outlet.
In order to solve the technical problems, the self-maintenance electro-Fenton coupling biological membrane sewage treatment system comprises a cooperative treatment tank, wherein an aeration device is paved at the bottom of a tank body of the cooperative treatment tank, a filler module is arranged in the tank body of the cooperative treatment tank and is arranged above the aeration device, the aeration device is connected with an air compressor for aeration, anode parts and cathode parts are respectively arranged at two sides of the filler module in the tank body of the cooperative treatment tank, the anode parts and the cathode parts are arranged at two sides of the filler module in a flat plate shape in parallel, and the anode parts and the cathode parts are electrically connected with a power supply system.
The self-maintenance electro-Fenton coupling biological membrane sewage treatment system comprises a photovoltaic device, a storage battery, an inverter and an automatic controller, wherein the photovoltaic device is electrically connected with the storage battery through the inverter, the photovoltaic device generates electricity through solar energy, the photovoltaic device is converted into direct current through the inverter and stored in the storage battery, the storage battery is electrically connected with an anode part and a cathode part through the automatic controller, the anode of the storage battery is correspondingly connected with the anode part, and the cathode of the storage battery is correspondingly connected with the cathode part.
The self-maintenance electro-Fenton coupling biological membrane sewage treatment system further comprises a direct current power supply, wherein the direct current power supply is electrically connected with the anode part and the cathode part through the automatic controller, the positive electrode of the direct current power supply is correspondingly connected with the anode part, the negative electrode of the direct current power supply is correspondingly connected with the cathode part, and the direct current power supply is a standby power supply for preventing the shortage of electric quantity of the storage battery.
The self-maintenance electro-Fenton coupling biological membrane sewage treatment system further comprises an adjusting tank, wherein the adjusting tank is arranged at the front end of the cooperative treatment tank and is used for adjusting water quality so as to meet the required proper pH condition, and the pH range is 2-5.
The self-maintenance electro-Fenton coupling biological membrane sewage treatment system is characterized in that a pH detection device, an automatic dosing device and a stirring device are arranged in the regulating tank, the pH value of sewage is detected through the pH detection device, and the automatic dosing device pumps acid and alkali solution under the stirring of the stirring device according to the monitoring number to regulate the pH value.
The self-maintaining electro-Fenton coupling biological membrane sewage treatment system further comprises a water inlet buffer tank, wherein the water inlet buffer tank is arranged at the front end of the regulating tank, and organic wastewater generated in a certain period of time is discharged into the water inlet buffer tank to be fully mixed so as to reduce the impact of water quality and water quantity impact on the reaction system.
In the self-sustaining electro-Fenton coupled biological membrane sewage treatment system, the cathode component is a Cu-C3N4 electrode, and the anode component is a graphene electrode.
The self-maintaining electro-Fenton coupling biological membrane sewage treatment system is characterized in that the filler module adopts iron-carbon electrolytic filler.
Compared with the prior art, the water inlet buffer tank provided by the utility model discharges the organic wastewater generated in a certain period of time into the water inlet buffer tank for full mixing so as to reduce the impact of water quality and water quantity impact on a reaction system, and the water quality is regulated by the regulating tank so as to meet the required proper pH condition; the utility model adopts the electro-Fenton coupling biological film technology to efficiently treat novel pollutants in water, oxygen is converted into H 2O2,H2O2 in a catalytic electrode under the action of electric energy to generate electrons under the catalytic action of the electrode, and the electrons can mineralize and degrade the organic pollutants difficult to degrade to realize deep removal.
Drawings
Fig. 1 is a schematic diagram of the system of the present utility model.
The reference sign is 1-synergistic treatment tank, 2-aeration device, 3-filler module, 4-anode part, 5-cathode part, 6-power supply system, 7-photovoltaic device, 8-storage battery, 9-inverter, 10-automatic controller, 11-DC power supply, 12-regulating tank, 13-pH detection equipment, 14-automatic dosing equipment, 15-stirring device and 16-water inlet buffer tank.
The utility model is further described below with reference to the drawings and the detailed description.
Detailed Description
The embodiment 1 of the utility model relates to a self-maintenance electro-Fenton coupling biological membrane sewage treatment system, which comprises a cooperative treatment tank 1, wherein an aeration device 2 is paved at the bottom of a tank body of the cooperative treatment tank 1, a filler module 3 is arranged in the tank body of the cooperative treatment tank 1, the filler module 3 is arranged above the aeration device 2, an anode part 4 and a cathode part 5 are respectively arranged at two sides of the filler module 3 in the tank body of the cooperative treatment tank 1, and the anode part 4 and the cathode part 5 are electrically connected with a power supply system 6.
The aeration device 2 positioned below the filler module 3 in the synergistic treatment tank 1 is used for aeration, the aeration rate is adjusted according to the concentration of pollutants, O 2 is under the action of electric energy, water in a catalytic electrode is converted into H 2O2,H2O2 to generate OH under the catalytic action of the electrode, the OH can mineralize and degrade refractory organic pollutants, the deep removal is realized, and the reaction is as follows:
O2+2H2O+2e-→H2O2+2OH-
Fe2++H2O→Fe3++·OH+OH-
Fe3++e-→Fe2+
Novel contaminant + & OH- & gtoxidation intermediates
Oxidation intermediate + & OH- & gtCO 2+H2 O+ inorganic ion
The embodiment 2 of the utility model relates to a self-maintenance electro-Fenton coupling biological membrane sewage treatment system, which comprises a cooperative treatment tank 1, wherein an aeration device 2 is paved at the bottom of a tank body of the cooperative treatment tank 1, a filler module 3 is arranged in the tank body of the cooperative treatment tank 1, the filler module 3 is arranged above the aeration device 2, an anode part 4 and a cathode part 5 are respectively arranged at two sides of the filler module 3 in the tank body of the cooperative treatment tank 1, and the anode part 4 and the cathode part 5 are electrically connected with a power supply system 6.
The aeration device 2 positioned below the filler module 3 in the synergistic treatment tank 1 is used for aeration, the aeration rate is adjusted according to the concentration of pollutants, O 2 is under the action of electric energy, water in the catalytic electrode is converted into H 2O2,H2O2 to generate OH under the catalytic action of the electrode, and the OH can mineralize and degrade the organic pollutants difficult to degrade, so that deep removal is realized.
The power supply system 6 comprises a photovoltaic device 7, a storage battery 8, an inverter 9 and an automatic controller 10, wherein the photovoltaic device 7 is electrically connected with the storage battery 8 through the inverter 9, the storage battery 8 is electrically connected with the anode part 4 and the cathode part 5 through the automatic controller 10, the positive electrode of the storage battery 8 is correspondingly connected with the anode part 4, the negative electrode of the storage battery 8 is correspondingly connected with the cathode part 5, the power supply system 6 further comprises a direct current power supply 11, the direct current power supply 11 is electrically connected with the anode part 4 and the cathode part 5 through the automatic controller 10, the positive electrode of the direct current power supply 11 is correspondingly connected with the anode part 4, and the negative electrode of the direct current power supply 11 is correspondingly connected with the cathode part 5.
The power supply system 6 supplies power to the anode part 4 and the cathode part 5, the automatic controller 10 realizes automatic control operation, a solar power supply system is constructed through the photovoltaic device 7, the storage battery 8, the inverter 9 and the automatic controller 10, the energy is saved, the environment is protected, the physicochemical properties of refractory organic matters are considered, the system analysis and the energy balance are carried out on the reaction system, the device debugging and the optimization are carried out by combining the local latitude, the illumination, the climate and the conversion efficiency of photovoltaic power generation, and the low concentration and the high toxicity in water are safely, efficiently and economically eliminated.
The embodiment 3 of the utility model relates to a self-maintaining electro-Fenton coupling biological membrane sewage treatment system, which comprises a cooperative treatment tank 1, wherein an aeration device 2 is paved at the bottom of a tank body of the cooperative treatment tank 1, a filler module 3 is arranged in the tank body of the cooperative treatment tank 1, the filler module 3 is arranged above the aeration device 2, an anode part 4 and a cathode part 5 are respectively arranged at two sides of the filler module 3 in the tank body of the cooperative treatment tank 1, the anode part 4 and the cathode part 5 are electrically connected with a power supply system 6, the cathode part 5 is a Cu-C3N4 electrode, and the anode part 4 is a graphene electrode.
The aeration device 2 positioned below the filler module 3 in the synergistic treatment tank 1 is used for aeration, the aeration rate is adjusted according to the concentration of pollutants, O 2 is under the action of electric energy, water in the catalytic electrode is converted into H 2O2,H2O2 to generate OH under the catalytic action of the electrode, and the OH can mineralize and degrade the organic pollutants difficult to degrade, so that deep removal is realized.
The water quality control device comprises a water quality control device, a water quality control device and a reaction system, and is characterized by further comprising an adjusting tank 12, wherein the adjusting tank 12 is arranged at the front end of the synergistic treatment tank 1, a pH detection device 13, an automatic dosing device 14 and a stirring device 15 are arranged in the adjusting tank 12, the adjusting tank 12 is used for performing water quality control so as to meet required proper pH conditions, the pH range is 2-5, the pH detection device is used for detecting the pH value of sewage, the automatic dosing device pumps acid and alkali solution under the stirring of the stirring device according to the monitoring number to perform pH control, the water quality control device further comprises a water inlet buffer tank 16, and the water inlet buffer tank 16 is arranged at the front end of the adjusting tank 12 and is used for discharging organic wastewater generated in a certain period into the water inlet buffer tank 16 to be fully mixed so as to reduce the impact of the water quality and water quantity to the reaction system.
The embodiment 4 of the utility model relates to a self-maintenance electro-Fenton coupling biological membrane sewage treatment system, which comprises a cooperative treatment tank 1, wherein an aeration device 2 is paved at the bottom of a tank body of the cooperative treatment tank 1, a filler module 3 is arranged in the tank body of the cooperative treatment tank 1, the filler module 3 adopts iron-carbon electrolysis filler, the filler module 3 is arranged above the aeration device 2, an anode part 4 and a cathode part 5 are respectively arranged at two sides of the filler module 3 in the tank body of the cooperative treatment tank 1, and the anode part 4 and the cathode part 5 are electrically connected with a power supply system 6.
The aeration device 2 positioned below the filler module 3 in the synergistic treatment tank 1 is used for aeration, the aeration rate is adjusted according to the concentration of pollutants, O 2 is under the action of electric energy, water in the catalytic electrode is converted into H 2O2,H2O2 to generate OH under the catalytic action of the electrode, and the OH can mineralize and degrade the organic pollutants difficult to degrade, so that deep removal is realized.
The power supply system 6 comprises a photovoltaic device 7, a storage battery 8, an inverter 9 and an automatic controller 10, wherein the photovoltaic device 7 is electrically connected with the storage battery 8 through the inverter 9, the storage battery 8 is electrically connected with the anode part 4 and the cathode part 5 through the automatic controller 10, the positive electrode of the storage battery 8 is correspondingly connected with the anode part 4, the negative electrode of the storage battery 8 is correspondingly connected with the cathode part 5, the power supply system 6 further comprises a direct current power supply 11, the direct current power supply 11 is electrically connected with the anode part 4 and the cathode part 5 through the automatic controller 10, the positive electrode of the direct current power supply 11 is correspondingly connected with the anode part 4, and the negative electrode of the direct current power supply 11 is correspondingly connected with the cathode part 5.
The power supply system 6 supplies power to the anode part 4 and the cathode part 5, the automatic controller 10 realizes automatic control operation, a solar power supply system is constructed through the photovoltaic device 7, the storage battery 8, the inverter 9 and the automatic controller 10, the energy is saved, the environment is protected, the physicochemical properties of refractory organic matters are considered, the system analysis and the energy balance are carried out on the reaction system, the device debugging and the optimization are carried out by combining the local latitude, the illumination, the climate and the conversion efficiency of photovoltaic power generation, and the low concentration and the high toxicity in water are safely, efficiently and economically eliminated.
The water quality control device comprises a water quality control device, a water quality control device and a reaction system, and is characterized by further comprising an adjusting tank 12, wherein the adjusting tank 12 is arranged at the front end of the synergistic treatment tank 1, a pH detection device 13, an automatic dosing device 14 and a stirring device 15 are arranged in the adjusting tank 12, the adjusting tank 12 is used for performing water quality control so as to meet required proper pH conditions, the pH range is 2-5, the pH detection device is used for detecting the pH value of sewage, the automatic dosing device pumps acid and alkali solution under the stirring of the stirring device according to the monitoring number to perform pH control, the water quality control device further comprises a water inlet buffer tank 16, and the water inlet buffer tank 16 is arranged at the front end of the adjusting tank 12 and is used for discharging organic wastewater generated in a certain period into the water inlet buffer tank 16 to be fully mixed so as to reduce the impact of the water quality and water quantity to the reaction system.
The utility model adopts the working principle that when the device is used, organic wastewater generated in a certain period of time is discharged into a water inlet buffer tank 16 to be fully mixed so as to reduce the impact of water quality and water quantity impact on a reaction system, the wastewater in the water inlet buffer tank 16 enters an adjusting tank 12 and is subjected to pH adjustment so as to meet the proper pH condition required by an electro-Fenton reaction, the pH range of the adjusted wastewater is 2-5, the adjusted wastewater enters a synergistic treatment tank 1, the anode part 4 and the cathode part 5 are powered by a photovoltaic power generation technology, an iron-carbon electrolytic filler module 3 is arranged in the synergistic treatment tank 1, aeration is carried out by an aeration device 2, the aeration rate is adjusted according to the concentration of pollutants, O 2 is converted into H 2O2,H2O2 under the action of electric energy, and the H 2O2,H2O2 generates OH under the action of catalysis of the electrode, and the OH can mineralize and degrade refractory organic pollutants to realize deep removal.
Claims (8)
1. The utility model provides a self-sustaining electro-Fenton coupling biomembrane sewage treatment system which is characterized in that, including cooperating processing pond (1), aeration equipment (2) have been laid to the cell body bottom in cooperation processing pond (1), be provided with in cooperation processing pond (1) cell body and pack module (3), and pack module (3) and arrange aeration equipment (2) top in, be provided with positive pole part (4) and negative pole part (5) respectively in cooperation processing pond (1) cell body both sides that lie in packing module (3), positive pole part (4) and negative pole part (5) electricity are connected with power supply system (6).
2. The self-sustaining electro-Fenton coupled biological membrane sewage treatment system according to claim 1, wherein the power supply system (6) comprises a photovoltaic device (7), a storage battery (8), an inverter (9) and an automatic controller (10), the photovoltaic device (7) is electrically connected with the storage battery (8) through the inverter (9), the storage battery (8) is electrically connected with the anode part (4) and the cathode part (5) through the automatic controller (10), the anode of the storage battery (8) is correspondingly connected with the anode part (4), and the cathode of the storage battery (8) is correspondingly connected with the cathode part (5).
3. The self-sustaining electro-Fenton-coupled biological membrane sewage treatment system according to claim 2, wherein the power supply system (6) further comprises a direct current power supply (11), the direct current power supply (11) is electrically connected with the anode part (4) and the cathode part (5) through the automatic controller (10), the positive electrode of the direct current power supply (11) is correspondingly connected with the anode part (4), and the negative electrode of the direct current power supply (11) is correspondingly connected with the cathode part (5).
4. A self-sustaining electro-Fenton coupled biofilm sewage treatment system according to claim 1, further comprising a regulating tank (12), said regulating tank (12) being arranged at the front end of the co-treatment tank (1).
5. The self-sustaining electro-Fenton-coupled biofilm sewage treatment system according to claim 4, wherein a pH detection device (13), an automatic dosing device (14) and a stirring device (15) are arranged in the regulating tank (12).
6. A self-sustaining electro-Fenton coupled biofilm sewage treatment system according to claim 4 or 5, further comprising a water inlet buffer tank (16), said water inlet buffer tank (16) being arranged at the front end of the regulating tank (12).
7. A self-sustaining electro-Fenton-coupled biofilm sewage treatment system according to claim 1, wherein said cathode element (5) is a Cu-C3N4 electrode and said anode element (4) is a graphene electrode.
8. A self-sustaining electro-Fenton-coupled biofilm sewage treatment system according to claim 1, wherein said filler module (3) employs an iron-carbon electrolytic filler.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202420486390.7U CN222204933U (en) | 2024-03-13 | 2024-03-13 | Self-sustaining electro-Fenton coupling biological membrane sewage treatment system |
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| CN202420486390.7U CN222204933U (en) | 2024-03-13 | 2024-03-13 | Self-sustaining electro-Fenton coupling biological membrane sewage treatment system |
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| CN202420486390.7U Active CN222204933U (en) | 2024-03-13 | 2024-03-13 | Self-sustaining electro-Fenton coupling biological membrane sewage treatment system |
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Effective date of registration: 20250618 Address after: 100071 East Automotive Museum Road, Fengtai District, Beijing Building 1, Unit 1, Compound 6 Room 601-1 Patentee after: Huadian Water Technology Co.,Ltd. Country or region after: China Patentee after: HUADIAN WATER CONSERVANCY ZHENGDING CO.,LTD. Address before: 100160 Beijing Fengtai Auto Museum East Road 6 Courtyard 1 Building Unit 601-1 Patentee before: Huadian Water Technology Co.,Ltd. Country or region before: China |
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