CN222008080U - Hydrogen production device from seawater - Google Patents
Hydrogen production device from seawater Download PDFInfo
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- CN222008080U CN222008080U CN202420220783.3U CN202420220783U CN222008080U CN 222008080 U CN222008080 U CN 222008080U CN 202420220783 U CN202420220783 U CN 202420220783U CN 222008080 U CN222008080 U CN 222008080U
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- mass transfer
- transfer layer
- hydrogen
- seawater
- anion
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- 239000001257 hydrogen Substances 0.000 title claims abstract description 85
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 85
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 84
- 239000013535 sea water Substances 0.000 title claims abstract description 59
- 238000004519 manufacturing process Methods 0.000 title abstract description 32
- 238000012546 transfer Methods 0.000 claims abstract description 69
- 239000003792 electrolyte Substances 0.000 claims abstract description 33
- 150000001450 anions Chemical class 0.000 claims abstract description 28
- 150000001768 cations Chemical class 0.000 claims abstract description 28
- 150000002500 ions Chemical class 0.000 claims abstract description 28
- 239000013505 freshwater Substances 0.000 claims abstract description 26
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001301 oxygen Substances 0.000 claims abstract description 20
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 20
- 239000012528 membrane Substances 0.000 claims abstract description 16
- 238000005868 electrolysis reaction Methods 0.000 claims description 17
- 239000003054 catalyst Substances 0.000 claims description 9
- 229910052697 platinum Inorganic materials 0.000 claims description 9
- 239000007772 electrode material Substances 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 7
- 229910052707 ruthenium Inorganic materials 0.000 claims description 5
- 229910002056 binary alloy Inorganic materials 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000002952 polymeric resin Substances 0.000 claims description 3
- 229920003002 synthetic resin Polymers 0.000 claims description 3
- 229910002058 ternary alloy Inorganic materials 0.000 claims description 3
- 229910000929 Ru alloy Inorganic materials 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 9
- 239000012535 impurity Substances 0.000 description 8
- 238000010586 diagram Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 230000002378 acidificating effect Effects 0.000 description 5
- 238000011033 desalting Methods 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 125000000129 anionic group Chemical group 0.000 description 3
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 3
- 239000000920 calcium hydroxide Substances 0.000 description 3
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 3
- 125000002091 cationic group Chemical group 0.000 description 3
- 238000010276 construction Methods 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000010612 desalination reaction Methods 0.000 description 3
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- 238000001556 precipitation Methods 0.000 description 3
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000009849 deactivation Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 229910052741 iridium Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- -1 or Ru Inorganic materials 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 230000002035 prolonged effect Effects 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
Landscapes
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Abstract
The utility model relates to the field of electrolytic water hydrogen production, and discloses a seawater hydrogen production device, which comprises an ion filter layer, wherein a positive electrode, at least one group of anion mass transfer layers and cation mass transfer layers, a negative electrode, concentrated water channels positioned at two sides of the anion mass transfer layers and the cation mass transfer layers and a fresh water channel positioned between the anion mass transfer layers and the cation mass transfer layers are sequentially arranged in the ion filter layer; the built-in electrolyte is divided into an anode chamber and a cathode chamber by a proton exchange membrane, the anode chamber and the cathode chamber are connected with a fresh water channel, a hydrogen evolution electrode and a hydrogen outlet are arranged in the cathode chamber, and an oxygen evolution electrode and an oxygen outlet are arranged in the anode chamber. The utility model can improve the service life of equipment and the purity of hydrogen.
Description
Technical Field
The utility model relates to the field of hydrogen production by water electrolysis, in particular to a seawater hydrogen production device.
Background
With the increasing consumption of fossil fuel, the reserves are increasingly reduced, and the resources are exhausted in the last day, so that a new hydrogen production energy source which does not depend on fossil fuel and is rich in reserves is urgently needed to be searched, and the hydrogen production scheme with one of the most market prospects is water electrolysis hydrogen production.
At present, there are two types of water electrolysis to obtain hydrogen energy:
The method is to directly utilize fresh water resources such as river water, lake water and the like in nature to carry out electrolytic hydrogen production, and the report issued by WMO on global water resource status shows that the fresh water resources on the earth only account for 2.53 percent of the total water quantity, wherein 68.7 percent of the fresh water resources belong to solid glaciers, only 1 percent of the fresh water resources can be directly utilized, and about 0.026 percent of the fresh water resources belong to places where the fresh water is buried in the ground. Fresh water reserves only account for 2.53% of the total global water, and are distributed in mountain and north and south polar regions which are difficult to use. The fresh water which can be directly utilized by human beings accounts for only 0.3 percent of the total fresh water. Thus, fresh water resource hydrogen production faces the problem of water resource shortage.
The other is hydrogen production by seawater, wherein the seawater accounts for 96.5% of the total water content of the earth, and the seawater is very complex in composition and contains more than 90 chemical substances and elements unlike fresh water. The large amount of ions, microorganisms, particles and the like contained in the seawater can cause problems of side reaction competition, catalyst deactivation, membrane blockage and the like in the process of preparing hydrogen.
In order to produce hydrogen by using seawater, the current most mature technical route is to produce hydrogen by desalting the seawater and then electrolyzing the seawater by establishing a desalting treatment system at a coastline, and to establish a seawater desalting plant at the coast, thereby greatly improving the cost in the aspects of construction, operation, manpower, maintenance and the like; and the in-situ integrated ocean green hydrogen production system is difficult to be formed by large-scale utilization of offshore wind power coupling, and the stable storage of renewable energy sources, the construction of a multi-energy complementary energy source system and an offshore energy ecological floating island are difficult to realize. The technology seriously depends on large-scale desalting equipment, has complex process flow and occupies a large amount of land resources, and further increases the hydrogen production cost and the engineering construction difficulty.
The existing seawater hydrogen production technology is a seawater desalination-free in-situ direct electrolytic hydrogen production method, wherein seawater passes through a solution mass transfer layer, the solution mass transfer layer blocks solid impurities in the seawater, the physical state of liquid, gas and liquid of the seawater is changed to pass through the solution mass transfer layer, ion impurities in the solution mass transfer layer are filtered, and then the solution mass transfer layer and electrolyte in an electrolytic tank form electrolyte to carry out electrolysis in an ion exchange mode, so that hydrogen and oxygen are generated.
The solution mass transfer layer is used for filtering impurities and ions in seawater, the efficiency is extremely low, the residue in filtered water is relatively large, and the water quality is poor. And the ion precipitation or marine microorganism growth barrier layer is easy to scale and block, which seriously affects the service life of the equipment.
Electrolyte and filtered water are used in the electrolytic tank to form electrolyte for electrolysis, K 2CO3、KOH、NaOH、Ca(OH)2、Na2CO3 and the like are used as electrolyte in the prior art, the electrolyte is alkaline or acidic, and corrosion equipment reduces service life of the equipment and increases cost.
The hydrogen generated by electrolysis of the acidic or alkaline electrolyte has a large amount of residual alkaline or acidic gas, and the process difficulty is increased by secondary purification.
Disclosure of utility model
In view of the above, the technical problem to be solved by the present utility model is to provide a seawater hydrogen production device, which solves at least one of the technical problems existing in the prior art to a certain extent.
In order to solve the technical problems, the technical scheme of the embodiment of the seawater hydrogen production device provided by the utility model is as follows:
a seawater hydrogen plant, comprising:
The ion filter layer is internally provided with a positive electrode, at least one group of anion mass transfer layer, a cation mass transfer layer, a negative electrode, concentrated water channels positioned at two sides of the anion mass transfer layer and the cation mass transfer layer and a fresh water channel positioned between the anion mass transfer layer and the cation mass transfer layer in sequence;
the built-in electrolyte is divided into an anode chamber and a cathode chamber by a proton exchange membrane, the anode chamber and the cathode chamber are connected with the fresh water channel, a hydrogen evolution electrode and a hydrogen outlet are arranged in the cathode chamber, and an oxygen evolution electrode and an oxygen outlet are arranged in the anode chamber.
Further, the proton exchange membrane allows only hydrogen protons to pass through.
Preferably, the anion mass transfer layer and the cation mass transfer layer comprise a plurality of groups, and the anion mass transfer layer and the cation mass transfer layer are arranged at intervals and fixed by using high polymer resin.
Preferably, the thickness of the anion mass transfer layer is 0.001 um-10000 um; and/or the thickness of the cation mass transfer layer is 0.001 um-10000 um.
Preferably, the hydrogen evolution electrode material is Pt, or Ir, or Ru, or a binary alloy of any two of Pt, ir and Ru, or a ternary alloy of Pt, ir and Ru.
Further, a catalyst is doped in the hydrogen evolution electrode material for improving the electrolysis rate.
Preferably, the catalyst is Ru, or RuO 2 made by thermal oxidation.
According to the seawater hydrogen production device disclosed by the embodiment of the utility model, seawater directly passes through the ion filter layer to directly absorb seawater, ion impurities contained in the seawater are desalted and purified, finally, hydrogen is prepared in the inner electrolyte layer without electrolyte by means of the chemical principle of electrolysis, the seawater is captured by the pressure difference of seawater, a complete seawater hydrogen production system is formed, the problems of short service life of equipment caused by poor water quality and electrolyte corrosion due to low permeation filtration efficiency can be solved, alkaline or acid electrolyte is not needed to be formed by using electrolyte, the purpose of directly producing hydrogen in situ by using natural seawater can be achieved by using only the water electrolyte, the problems of membrane failure, catalyst deactivation, low conversion efficiency, alkaline precipitation, toxic gas and the like of the device due to complex seawater components are solved, and the produced hydrogen has higher purity and the specific beneficial effects are further analyzed as follows:
1. The ion filter layer in the seawater hydrogen production device of the embodiment of the utility model is sequentially provided with the positive electrode, at least one group of anion mass transfer layer, cation mass transfer layer, the negative electrode, concentrated water channels positioned at the two sides of the anion mass transfer layer and the cation mass transfer layer and fresh water channels positioned between the anion mass transfer layer and the cation mass transfer layer, so that after the positive electrode and the negative electrode are electrified, each electrode can suck out ions with the opposite electrical characteristics, and compared with the seawater desalination scheme of ion interception, the utility model uses the ion mass transfer layer which only can penetrate ions to discharge concentrated ion water along with seawater, thus fundamentally solving the problem of ion precipitation blockage of the ion mass transfer layer;
2. The built-in electrolyte layer in the seawater hydrogen production device is divided into the anode chamber and the cathode chamber by the proton exchange membrane, the hydrogen evolution electrode and the hydrogen outlet are arranged in the cathode chamber, the oxygen evolution electrode and the oxygen outlet are arranged in the anode chamber, and an electrolyte such as K 2 CO3、KOH、NaOH、Ca(OH)2、Na2 CO3 is not needed by adopting an electrolysis mode of the proton exchange membrane and the electrode, so that the electrolyte is not alkaline or acidic, equipment cannot be corroded, the service life of the equipment is prolonged, the maintenance cost of the equipment is reduced, and the purity of the generated hydrogen is far higher than that of the hydrogen generated by using the electrolyte for electrolysis.
Drawings
FIG. 1 is a general schematic diagram of the present hydrogen plant using novel seawater;
FIG. 2 is a schematic diagram of the removal of impurity ions from the filter media layer in a seawater hydrogen plant of the present utility model;
FIG. 3 is a schematic diagram of electrolytic hydrogen production with built-in electrolyte in the seawater hydrogen production plant of the present utility model;
Wherein the above figures include the following reference numerals:
100. A seawater inlet;
200. Ion filter layer 201, positive electrode 202, anion mass transfer layer 203, cation mass transfer layer 204, negative electrode 205, concentrated water channel 206, fresh water channel;
300. Built-in electrolyte layer, 301. Proton exchange membrane, 302. Anode chamber, 303. Cathode chamber, 304. Hydrogen evolution electrode, 305. Hydrogen outlet, 306. Oxygen evolution electrode, 307. Oxygen outlet.
Detailed Description
In order to make the objects and technical solutions of the present utility model more apparent, the present utility model will be further described in detail below with reference to the accompanying drawings and examples. It should be understood that the specific embodiments described herein are for purposes of illustration only and are not intended to limit the scope of the utility model.
It should be noted that, without conflict, the embodiments of the present utility model and features of the embodiments may be combined with each other. The utility model will be described in detail below with reference to the drawings in connection with embodiments.
Unless defined otherwise, all technical and scientific terms used herein have the same meaning as commonly understood by one of ordinary skill in the art to which this application belongs.
In the present utility model, unless otherwise indicated, terms of orientation such as "upper, lower, left, right" and the like are used generally with respect to the orientation shown in the drawings or with respect to the orientation of the component itself in terms of vertical, vertical or gravitational force; also, for ease of understanding and description, "inner and outer" refers to inner and outer relative to the profile of each component itself, but the above-mentioned orientation terms are not intended to limit the present utility model.
Fig. 1 is a schematic diagram of an example of a seawater hydrogen plant according to the present utility model, please refer to fig. 1, wherein 100 is a seawater inlet, and the seawater hydrogen plant includes:
The ion filter layer 200 is internally provided with a positive electrode 201, at least one group of anion mass transfer layer 202, a cation mass transfer layer 203, a negative electrode 204, concentrated water channels 205 positioned at two sides of the anion mass transfer layer 202 and the cation mass transfer layer 203 and a fresh water channel 206 positioned between the anion mass transfer layer 202 and the cation mass transfer layer 203 in sequence;
the built-in electrolyte 300 is divided into an anode chamber 302 and a cathode chamber 303 by a proton exchange membrane 301, the anode chamber 302 and the cathode chamber 303 are connected with a fresh water channel 301, a hydrogen evolution electrode 304 and a hydrogen outlet 305 are arranged in the cathode chamber 303, and an oxygen evolution electrode 306 and an oxygen outlet 307 are arranged in the anode chamber 302.
The ion filter layer in the seawater hydrogen production device of the embodiment of the utility model is sequentially provided with the positive electrode, at least one group of anion mass transfer layer, cation mass transfer layer, the negative electrode, concentrated water channels positioned at the two sides of the anion mass transfer layer and the cation mass transfer layer and fresh water channels positioned between the anion mass transfer layer and the cation mass transfer layer.
The built-in electrolyte layer in the seawater hydrogen production device is divided into the anode chamber and the cathode chamber by the proton exchange membrane, the hydrogen evolution electrode and the hydrogen outlet are arranged in the cathode chamber, the oxygen evolution electrode and the oxygen outlet are arranged in the anode chamber, and an electrolyte such as K 2 CO3、KOH、NaOH、Ca(OH)2、Na2 CO3 is not needed by adopting an electrolysis mode of the proton exchange membrane and the electrode, so that the electrolyte is not alkaline or acidic, equipment cannot be corroded, the service life of the equipment is prolonged, the maintenance cost of the equipment is reduced, and the purity of the generated hydrogen is far higher than that of the hydrogen generated by using the electrolyte for electrolysis.
As shown in fig. 1, the ion filter layer 200 of the embodiment of the utility model is used for desalinating seawater, the built-in electrolyte layer 300 is used for electrolytically producing hydrogen from the desalinated fresh water, and the specific use method and the working process are as follows:
S101, providing seawater to the positive electrode 201 of the ion filter layer 200 when passing through the ion filter layer 200, for example
The positive voltage of 25VDC and the negative electrode 204 provide negative voltage of 25VDC, for example, the anionic impurities in the seawater are absorbed by the positive electrode 201 and permeate the anionic mass transfer layer 203 and then are discharged through the concentrated water channel 205, the cationic impurities are absorbed by the negative electrode 204 and permeate the cationic mass transfer layer 203 and then are also discharged through the concentrated water channel 205, and fresh water is obtained through the fresh water channel 206 between the anionic mass transfer layer 202 and the cationic mass transfer layer 203;
The water quality comparison test of the seawater desalination scheme and other seawater desalination schemes in the embodiment is as follows:
S102, introducing positive voltage of 1.6V for example to the oxygen evolution electrode 306, introducing negative voltage of 1.6V for example to the hydrogen evolution electrode 304, allowing fresh water to enter the built-in electrolyte 300, electrolyzing in the anode chamber 302 through the oxygen evolution electrode 306 to decompose water molecules into hydrogen protons and oxygen, collecting the oxygen through the oxygen outlet 307, then transmitting the hydrogen protons to the cathode chamber 303 through the proton exchange membrane 301, generating hydrogen on the hydrogen evolution electrode 304, and collecting the hydrogen through the hydrogen outlet 305, wherein the reaction formula is as follows:
Anode chamber: 2H 2O-4e-=O2 ≡ +4H+;
cathode chamber: 4h++4e- = 2H 2 ≡;
The working principle of the step can be seen from a schematic diagram of electrolytic hydrogen production of an internal electrolyte layer in the seawater hydrogen production device of the utility model shown in fig. 3;
the hydrogen production scheme of this embodiment has the following advantages compared with other hydrogen production schemes:
In the above-mentioned step S103, in order to maintain the pressure difference of seawater as the water in the built-in electrolyte 300 is continuously consumed by electrolysis, seawater continuously enters the built-in electrolyte 300 through the ion filter layer 200 to be replenished, thus forming an automatic electrolyte replenishing hydrogen production system.
Furthermore, the proton exchange membrane only allows hydrogen protons to pass through, and the proton exchange membrane only allows hydrogen protons to pass through and is matched with the electrode to carry out electrolysis, so that the seawater hydrogen production device can further improve the electrolysis efficiency.
Preferably, the anion mass transfer layer 202 and the cation mass transfer layer 203 comprise a plurality of groups, the anion mass transfer layer 202 and the cation mass transfer layer 203 are arranged at intervals and fixed by using a polymer resin, and the specific structure refers to a schematic diagram of removing impurity ions by the ion mass transfer layer in fig. 2, wherein the anion mass transfer layer 202 and the cation mass transfer layer 203 comprise three groups.
Preferably, the thickness of the anion mass transfer layer is 0.001um to 10000um; and/or the thickness of the cation transfer layer is 0.001um to 10000um.
Preferably, the hydrogen evolution electrode material is Pt, or Ir, or Ru, or a binary alloy of any two of Pt, ir and Ru, or a ternary alloy of Pt, ir and Ru.
Further, a catalyst is incorporated into the hydrogen evolution electrode material for enhancing the rate of electrolysis.
Preferably, the catalyst is Ru or RuO 2 prepared by thermal oxidation, and the RuO 2 is used as the catalyst to further improve the corrosion resistance of the hydrogen evolution electrode material.
The foregoing is merely exemplary embodiments of the present utility model, and it should be particularly pointed out that the above embodiments should not be construed as limiting the utility model, but that several modifications and adaptations of the utility model can be made by one skilled in the art without departing from the spirit and scope of the utility model.
Claims (7)
1. A seawater hydrogen plant, comprising:
The ion filter layer is internally provided with a positive electrode, at least one group of anion mass transfer layer, a cation mass transfer layer, a negative electrode, concentrated water channels positioned at two sides of the anion mass transfer layer and the cation mass transfer layer and a fresh water channel positioned between the anion mass transfer layer and the cation mass transfer layer in sequence;
the built-in electrolyte is divided into an anode chamber and a cathode chamber by a proton exchange membrane, the anode chamber and the cathode chamber are connected with the fresh water channel, a hydrogen evolution electrode and a hydrogen outlet are arranged in the cathode chamber, and an oxygen evolution electrode and an oxygen outlet are arranged in the anode chamber.
2. The seawater hydrogen plant of claim 1, wherein: the proton exchange membrane allows only hydrogen protons to pass through.
3. The seawater hydrogen plant of claim 1, wherein: the anion mass transfer layer and the cation mass transfer layer comprise a plurality of groups, are mutually arranged at intervals and are fixed by using high polymer resin.
4. The seawater hydrogen plant of claim 1, wherein: the thickness of the anion mass transfer layer is 0.001-10000 um; and/or the thickness of the cation mass transfer layer is 0.001 um-10000 um.
5. The seawater hydrogen plant of claim 1, wherein: the hydrogen evolution electrode material is Pt, ir, ru, binary alloy of any two of Pt, ir and Ru, or ternary alloy of Pt, ir and Ru.
6. The seawater hydrogen plant of claim 5, wherein: the hydrogen evolution electrode material is doped with a catalyst for improving the electrolysis rate.
7. The seawater hydrogen plant of claim 6, wherein: the catalyst is Ru or RuO 2 prepared by thermal oxidation.
Priority Applications (1)
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CN202420220783.3U CN222008080U (en) | 2024-01-29 | 2024-01-29 | Hydrogen production device from seawater |
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CN202420220783.3U CN222008080U (en) | 2024-01-29 | 2024-01-29 | Hydrogen production device from seawater |
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