CN221940662U - Conductive film copper plating system - Google Patents
Conductive film copper plating system Download PDFInfo
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- CN221940662U CN221940662U CN202420562915.0U CN202420562915U CN221940662U CN 221940662 U CN221940662 U CN 221940662U CN 202420562915 U CN202420562915 U CN 202420562915U CN 221940662 U CN221940662 U CN 221940662U
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 229910052802 copper Inorganic materials 0.000 title claims abstract description 78
- 239000010949 copper Substances 0.000 title claims abstract description 78
- 238000007747 plating Methods 0.000 title claims abstract description 73
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 240
- 238000005406 washing Methods 0.000 claims abstract description 190
- 230000009194 climbing Effects 0.000 claims abstract description 69
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 27
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 27
- 238000001035 drying Methods 0.000 claims abstract description 16
- 238000002203 pretreatment Methods 0.000 claims abstract description 12
- 238000005520 cutting process Methods 0.000 claims description 46
- 238000000034 method Methods 0.000 claims description 21
- 230000003064 anti-oxidating effect Effects 0.000 claims description 15
- 238000007667 floating Methods 0.000 claims description 5
- 239000007921 spray Substances 0.000 claims description 5
- 238000009434 installation Methods 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 3
- 229910052741 iridium Inorganic materials 0.000 claims description 3
- GKOZUEZYRPOHIO-UHFFFAOYSA-N iridium atom Chemical compound [Ir] GKOZUEZYRPOHIO-UHFFFAOYSA-N 0.000 claims description 3
- 239000010936 titanium Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 239000007788 liquid Substances 0.000 abstract description 37
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract description 8
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 239000012528 membrane Substances 0.000 abstract description 4
- 239000010408 film Substances 0.000 description 65
- 238000004140 cleaning Methods 0.000 description 7
- 101001121408 Homo sapiens L-amino-acid oxidase Proteins 0.000 description 4
- 102100026388 L-amino-acid oxidase Human genes 0.000 description 4
- 238000009713 electroplating Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 239000002985 plastic film Substances 0.000 description 3
- 229920006255 plastic film Polymers 0.000 description 3
- 239000010409 thin film Substances 0.000 description 3
- 230000000712 assembly Effects 0.000 description 2
- 238000000429 assembly Methods 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- ZACYQVZHFIYKMW-UHFFFAOYSA-N iridium titanium Chemical compound [Ti].[Ir] ZACYQVZHFIYKMW-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- 101000827703 Homo sapiens Polyphosphoinositide phosphatase Proteins 0.000 description 1
- 102100023591 Polyphosphoinositide phosphatase Human genes 0.000 description 1
- 101100012902 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) FIG2 gene Proteins 0.000 description 1
- 101100233916 Saccharomyces cerevisiae (strain ATCC 204508 / S288c) KAR5 gene Proteins 0.000 description 1
- KIWQCVMQMWPCJB-UHFFFAOYSA-N [Ti].[Ir]=O Chemical compound [Ti].[Ir]=O KIWQCVMQMWPCJB-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- 239000007888 film coating Substances 0.000 description 1
- 238000009501 film coating Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- FWFGVMYFCODZRD-UHFFFAOYSA-N oxidanium;hydrogen sulfate Chemical compound O.OS(O)(=O)=O FWFGVMYFCODZRD-UHFFFAOYSA-N 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Landscapes
- Electroplating Methods And Accessories (AREA)
Abstract
本实用新型提供一种导电薄膜镀铜系统。包括:依次连接的前处理槽、第一双联逆流水洗槽、第一水洗爬坡溢流槽、至少一个镀铜槽、至少一个镀铜爬坡溢流槽、第二双联逆流水洗槽、第二水洗爬坡溢流槽、第一抗氧化槽、第二抗氧化槽、烘干箱、风切装置;本实用新型的技术方案,大大减弱了膜在镀铜拉膜线上的带水问题,使前工作槽液体带入后工作槽槽内液体的量降低到最低,延长了各工作槽液的使用寿命,且在传统镀膜拉膜线上创造性的加入了前处理槽和风切装置,创造性的在阴阳极辊处采用了脉冲电源可变化极性模式,阴极采用了稀硫酸洗辊装置,更进一步的避免了膜面污染,提升了产品质量,降低了制造成本。
The utility model provides a conductive film copper plating system. It includes: a pre-treatment tank, a first double countercurrent water washing tank, a first water washing climbing overflow tank, at least one copper plating tank, at least one copper plating climbing overflow tank, a second double countercurrent water washing tank, a second water washing climbing overflow tank, a first antioxidant tank, a second antioxidant tank, a drying box, and a wind shear device connected in sequence; the technical scheme of the utility model greatly reduces the problem of water carrying on the film on the copper plating film drawing line, reduces the amount of liquid brought into the rear working tank by the front working tank liquid to the minimum, prolongs the service life of each working tank liquid, and creatively adds a pre-treatment tank and a wind shear device to the traditional film plating film drawing line, creatively adopts a pulse power supply with a variable polarity mode at the anode and cathode rollers, and adopts a dilute sulfuric acid roller washing device at the cathode, further avoiding membrane surface pollution, improving product quality, and reducing manufacturing costs.
Description
技术领域Technical Field
本实用新型涉及镀膜技术领域,特别是指一种导电薄膜镀铜系统。The utility model relates to the technical field of film plating, in particular to a conductive film copper plating system.
背景技术Background Art
各种类型超薄塑料膜(pp或pet但不限于这两种类型)双面水镀镀铜加工工艺,都是针对1米以上幅宽的单卷磁控膜(已经进行双面磁控镀铜加工)。此种工艺的电镀线生产时,在拉膜过程中塑料膜从前一道槽向下一道后槽传输时,塑料膜上一般会粘附前槽槽液,膜上携带的前槽槽液会瞬间污染后槽槽液,前后槽槽液发生化学反应,极大地降低各槽液有效成分浓度和使用寿命,降低产品质量,增加了生产成本。The double-sided water-plated copper plating process for various types of ultra-thin plastic films (PP or PET but not limited to these two types) is for single-roll magnetron films with a width of more than 1 meter (double-sided magnetron copper plating has been performed). When the electroplating line of this process is produced, when the plastic film is transferred from the previous slot to the next slot during the film drawing process, the front slot liquid will generally adhere to the plastic film, and the front slot liquid carried on the film will instantly contaminate the rear slot liquid. The front and rear slot liquids will react chemically, greatly reducing the concentration of the effective components and service life of each slot liquid, reducing product quality, and increasing production costs.
实用新型内容Utility Model Content
本实用新型是提供一种导电薄膜镀铜系统,用以解决电镀线拉膜过程中膜带水比较严重,前槽槽液会瞬间污染后槽槽液,降低产品质量的问题。The utility model provides a conductive film copper plating system, which is used to solve the problem that the film carries water seriously during the film drawing process of the electroplating line, the front tank liquid will instantly pollute the rear tank liquid, and the product quality is reduced.
为解决上述技术问题,本新型的技术方案如下:To solve the above technical problems, the technical solution of this novel invention is as follows:
一种导电薄膜镀铜系统,包括:依次连接的前处理槽、第一双联逆流水洗槽、第一水洗爬坡溢流槽、至少一个镀铜槽、至少一个镀铜爬坡溢流槽、第二双联逆流水洗槽、第二水洗爬坡溢流槽、第一抗氧化槽、第二抗氧化槽、烘干箱;A conductive film copper plating system, comprising: a pre-treatment tank, a first double countercurrent water washing tank, a first water washing climbing overflow tank, at least one copper plating tank, at least one copper plating climbing overflow tank, a second double countercurrent water washing tank, a second water washing climbing overflow tank, a first antioxidant tank, a second antioxidant tank, and a drying box connected in sequence;
所述前处理槽与所述第一双联逆流水洗槽连接处设置有第一截水辊组件;A first water cut-off roller assembly is provided at the connection between the pre-treatment tank and the first double countercurrent water washing tank;
所述第一双联逆流水洗槽与所述第一水洗爬坡溢流槽连接处设置有第二截水辊组件;A second water cut-off roller assembly is provided at the connection between the first double countercurrent water washing tank and the first water washing climbing overflow tank;
所述第一水洗爬坡溢流槽与所述镀铜槽连接处设置有第三截水辊组件;A third water cut-off roller assembly is provided at the connection between the first water washing climbing overflow trough and the copper plating trough;
所述镀铜槽与所述镀铜爬坡溢流槽连接处设置有第四截水辊组件;A fourth water cut-off roller assembly is provided at the connection between the copper plating tank and the copper plating climbing overflow tank;
所述镀铜爬坡溢流槽与所述第二双联逆流水洗槽连接处设置有第五截水辊组件;A fifth water cut-off roller assembly is provided at the connection between the copper plating climbing overflow trough and the second double countercurrent water washing trough;
所述第二双联逆流水洗槽与所述第二水洗爬坡溢流槽连接处设置有第六截水辊组件;A sixth water cut-off roller assembly is provided at the connection between the second double countercurrent water washing tank and the second water washing climbing overflow tank;
所述第二水洗爬坡溢流槽与所述第一抗氧化槽连接处设置有第七截水辊组件;A seventh water cut-off roller assembly is provided at the connection between the second water washing climbing overflow trough and the first anti-oxidation trough;
所述第一抗氧化槽与所述第二抗氧化槽连接处设置有第八截水辊组件;An eighth water cut-off roller assembly is provided at the connection between the first anti-oxidation groove and the second anti-oxidation groove;
所述第二抗氧化槽与所述烘干箱连接处设置有第九截水辊组件;A ninth water cut-off roller assembly is provided at the connection between the second anti-oxidation tank and the drying box;
所述第九截水辊组件一端设置有风切装置;A wind shear device is provided at one end of the ninth water cut-off roller assembly;
所述导电薄膜镀铜系统中装置安装高度自左往右逐渐上升。The installation height of the device in the conductive film copper plating system gradually increases from left to right.
可选的,所述第一水洗爬坡溢流槽结构高度沿着导电薄膜运行方向均匀变化。Optionally, the structural height of the first water washing climbing overflow trough varies uniformly along the running direction of the conductive film.
可选的,所述第一双联逆流水洗槽包括第一水洗槽、第二水洗槽;Optionally, the first double countercurrent water washing tank includes a first water washing tank and a second water washing tank;
所述第一水洗槽与所述第二水洗槽依次连接;The first water washing tank is connected to the second water washing tank in sequence;
所述第一水洗槽与所述第二水洗槽连接处设置有第十截水辊组件。A tenth water-cutting roller assembly is provided at the connection between the first water washing tank and the second water washing tank.
可选的,所述镀铜爬坡溢流槽结构高度沿着导电薄膜运行方向均匀变化。Optionally, the height of the copper-plated climbing overflow trough structure changes uniformly along the running direction of the conductive film.
可选的,所述第二双联逆流水洗槽包括第三水洗槽、第四水洗槽;Optionally, the second double countercurrent water washing tank includes a third water washing tank and a fourth water washing tank;
所述第三水洗槽与所述第四水洗槽依次连接;The third water washing tank is connected to the fourth water washing tank in sequence;
所述第三水洗槽与所述第四水洗槽连接处设置有第十一截水辊组件。An eleventh water cut-off roller assembly is provided at the connection between the third water washing tank and the fourth water washing tank.
可选的,所述第二水洗爬坡溢流槽结构高度沿着导电薄膜运行方向均匀变化。Optionally, the structural height of the second water washing climbing overflow trough varies uniformly along the running direction of the conductive film.
可选的,所述第二抗氧化槽结构高度沿着导电薄膜运行方向均匀变化。Optionally, the structural height of the second anti-oxidation groove varies uniformly along the running direction of the conductive film.
可选的,所述镀铜槽中间隔设置有阴极辊、阳极辊;Optionally, a cathode roller and an anode roller are arranged at intervals in the copper plating tank;
根据预设工艺要求,通过脉冲整流器,调整所述阴极辊、所述阳极辊的极性;According to preset process requirements, the polarities of the cathode roller and the anode roller are adjusted through a pulse rectifier;
所述阴极辊两侧设置有第十二截水辊组件。A twelfth water-cutting roller assembly is arranged on both sides of the cathode roller.
可选的,所述阴极辊上部与下部均匀设置有喷淋装置,用于去掉所述阴极辊表面被镀上的浮铜。Optionally, spray devices are evenly arranged on the upper and lower parts of the cathode roller to remove floating copper plated on the surface of the cathode roller.
可选的,所述阴极辊为铜辊,所述阳极辊为钛镀铱不溶性阳极辊。Optionally, the cathode roller is a copper roller, and the anode roller is an insoluble anode roller plated with iridium and titanium.
本实用新型的上述方案至少包括以下有益效果:The above solution of the utility model includes at least the following beneficial effects:
本实用新型的上述方案,包括:依次连接的前处理槽、第一双联逆流水洗槽、第一水洗爬坡溢流槽、至少一个镀铜槽、至少一个镀铜爬坡溢流槽、第二双联逆流水洗槽、第二水洗爬坡溢流槽、第一抗氧化槽、第二抗氧化槽、烘干箱;所述前处理槽与所述第一双联逆流水洗槽连接处设置有第一截水辊组件;所述第一双联逆流水洗槽与所述第一水洗爬坡溢流槽连接处设置有第二截水辊组件;所述第一水洗爬坡溢流槽与所述镀铜槽连接处设置有第三截水辊组件;所述镀铜槽与所述镀铜爬坡溢流槽连接处设置有第四截水辊组件;所述镀铜爬坡溢流槽与所述第二双联逆流水洗槽连接处设置有第五截水辊组件;所述第二双联逆流水洗槽与所述第二水洗爬坡溢流槽连接处设置有第六截水辊组件;所述第二水洗爬坡溢流槽与所述第一抗氧化槽连接处设置有第七截水辊组件;所述第一抗氧化槽与所述第二抗氧化槽连接处设置有第八截水辊组件;所述第二抗氧化槽与所述烘干箱连接处设置有第九截水辊组件;所述第九截水辊组件一端设置有风切装置,所述导电薄膜镀铜系统中装置安装高度自左往右逐渐上升。本实用新型的技术方案,大大减弱了膜在镀铜拉膜线上的带水问题,使前工作槽液体带入后工作槽槽内液体的量降低到最低,延长了各工作槽液的使用寿命,且在传统镀膜拉膜线上创造性的加入了前处理槽和风切装置,创造性的在阴阳极辊处采用了脉冲电源可变化极性模式,阴极采用了稀硫酸洗辊装置,更进一步的避免了膜面污染,提升了产品质量,降低了制造成本。The above scheme of the utility model includes: a pre-treatment tank, a first double countercurrent water washing tank, a first water washing climbing overflow tank, at least one copper plating tank, at least one copper plating climbing overflow tank, a second double countercurrent water washing tank, a second water washing climbing overflow tank, a first antioxidant tank, a second antioxidant tank, and a drying box connected in sequence; a first water cut-off roller assembly is provided at the connection between the pre-treatment tank and the first double countercurrent water washing tank; a second water cut-off roller assembly is provided at the connection between the first double countercurrent water washing tank and the first water washing climbing overflow tank; a third water cut-off roller assembly is provided at the connection between the first water washing climbing overflow tank and the copper plating tank; a third water cut-off roller assembly is provided at the connection between the copper plating tank and the copper plating climbing overflow tank A fourth water-cutting roller assembly is provided; a fifth water-cutting roller assembly is provided at the connection between the copper plating climbing overflow trough and the second double countercurrent water washing trough; a sixth water-cutting roller assembly is provided at the connection between the second double countercurrent water washing trough and the second water washing climbing overflow trough; a seventh water-cutting roller assembly is provided at the connection between the second water washing climbing overflow trough and the first antioxidant trough; an eighth water-cutting roller assembly is provided at the connection between the first antioxidant trough and the second antioxidant trough; a ninth water-cutting roller assembly is provided at the connection between the second antioxidant trough and the drying box; a wind shear device is provided at one end of the ninth water-cutting roller assembly, and the installation height of the device in the conductive film copper plating system gradually increases from left to right. The technical solution of the utility model greatly reduces the problem of water carrying in the membrane on the copper plating film drawing line, reduces the amount of liquid in the front working tank brought into the liquid in the rear working tank to a minimum, and extends the service life of the liquid in each working tank. In addition, a pretreatment tank and a wind cutting device are creatively added to the traditional film coating film drawing line, and a pulse power supply with changeable polarity mode is creatively adopted at the anode and cathode rollers, and a dilute sulfuric acid roller washing device is adopted at the cathode, which further avoids membrane surface contamination, improves product quality, and reduces manufacturing costs.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1是本实用新型的实施例一种导电薄膜镀铜系统的侧视图;FIG1 is a side view of a conductive film copper plating system according to an embodiment of the present utility model;
图2是图1中截水辊组件示意图;FIG2 is a schematic diagram of the water cut-off roller assembly in FIG1 ;
图3是图1中阴极辊与喷淋装置组合使用示意图;FIG3 is a schematic diagram of the combined use of the cathode roller and the spray device in FIG1;
图4是图1中风切装置示意图;FIG4 is a schematic diagram of the wind cutting device in FIG1 ;
附图标记说明:Description of reference numerals:
1、前处理槽;2、第一双联逆流水洗槽;3、第一水洗爬坡溢流槽;4、镀铜槽;5、镀铜爬坡溢流槽;6、第二双联逆流水洗槽;7、第二水洗爬坡溢流槽;8、第一抗氧化槽;9、第二抗氧化槽;10、烘干箱;11、第一截水辊组件;12、第二截水辊组件;13、第三截水辊组件;14、第四截水辊组件;15、第五截水辊组件;16、第六截水辊组件;17、第七截水辊组件;18、第八截水辊组件;19、第九截水辊组件;20、风切装置;21、第一水洗槽;22、第二水洗槽;23、第十截水辊组件;30、阴极辊;31、阳极辊;32、第十二截水辊组件;33、喷淋装置;61、第三水洗槽62、第四水洗槽;63、第十一截水辊组件;71、放卷系统;72、收卷系统。1. Pretreatment tank; 2. First double countercurrent water washing tank; 3. First water washing climbing overflow tank; 4. Copper plating tank; 5. Copper plating climbing overflow tank; 6. Second double countercurrent water washing tank; 7. Second water washing climbing overflow tank; 8. First antioxidant tank; 9. Second antioxidant tank; 10. Drying box; 11. First water cut-off roller assembly; 12. Second water cut-off roller assembly; 13. Third water cut-off roller assembly; 14. Fourth water cut-off roller assembly; 15. Fifth water cut-off roller assembly; 16. Six water-cutting roller assembly; 17, seventh water-cutting roller assembly; 18, eighth water-cutting roller assembly; 19, ninth water-cutting roller assembly; 20, wind cutting device; 21, first water washing tank; 22, second water washing tank; 23, tenth water-cutting roller assembly; 30, cathode roller; 31, anode roller; 32, twelfth water-cutting roller assembly; 33, spraying device; 61, third water washing tank 62, fourth water washing tank; 63, eleventh water-cutting roller assembly; 71, unwinding system; 72, winding system.
具体实施方式DETAILED DESCRIPTION
下面将参照附图更详细地描述本公开的示例性实施例。虽然附图中显示了本公开的示例性实施例,然而应当理解,可以以各种形式实现本公开而不应被这里阐述的实施例所限制。相反,提供这些实施例是为了能够更透彻地理解本公开,并且能够将本公开的范围完整的传达给本领域的技术人员。The exemplary embodiments of the present disclosure will be described in more detail below with reference to the accompanying drawings. Although the exemplary embodiments of the present disclosure are shown in the accompanying drawings, it should be understood that the present disclosure can be implemented in various forms and should not be limited by the embodiments set forth herein. On the contrary, these embodiments are provided to enable a more thorough understanding of the present disclosure and to fully convey the scope of the present disclosure to those skilled in the art.
如图1至图4所示,本实用新型的实施例提出一种导电薄膜镀铜系统,包括:依次连接的前处理槽1、第一双联逆流水洗槽2、第一水洗爬坡溢流槽3、至少一个镀铜槽4、至少一个镀铜爬坡溢流槽5、第二双联逆流水洗槽6、第二水洗爬坡溢流槽7、第一抗氧化槽8、第二抗氧化槽9、烘干箱10;As shown in Figures 1 to 4, an embodiment of the utility model provides a conductive film copper plating system, comprising: a pretreatment tank 1, a first double countercurrent water washing tank 2, a first water washing climbing overflow tank 3, at least one copper plating tank 4, at least one copper plating climbing overflow tank 5, a second double countercurrent water washing tank 6, a second water washing climbing overflow tank 7, a first antioxidant tank 8, a second antioxidant tank 9, and a drying box 10 connected in sequence;
所述前处理槽1与所述第一双联逆流水洗槽2连接处设置有第一截水辊组件11;A first water cut-off roller assembly 11 is provided at the connection between the pre-treatment tank 1 and the first double countercurrent washing tank 2;
所述第一双联逆流水洗槽2与所述第一水洗爬坡溢流槽3连接处设置有第二截水辊组件12;A second water cut-off roller assembly 12 is provided at the connection between the first double countercurrent water washing tank 2 and the first water washing climbing overflow tank 3;
所述第一水洗爬坡溢流槽3与所述镀铜槽4连接处设置有第三截水辊组件13;A third water cut-off roller assembly 13 is provided at the connection between the first water washing climbing overflow trough 3 and the copper plating trough 4;
所述镀铜槽4与所述镀铜爬坡溢流槽5连接处设置有第四截水辊组件14;A fourth water cut-off roller assembly 14 is provided at the connection between the copper plating tank 4 and the copper plating climbing overflow tank 5;
所述镀铜爬坡溢流槽5与所述第二双联逆流水洗槽6连接处设置有第五截水辊组件15;A fifth water cut-off roller assembly 15 is provided at the connection between the copper plating climbing overflow trough 5 and the second double countercurrent water washing trough 6;
所述第二双联逆流水洗槽6与所述第二水洗爬坡溢流槽7连接处设置有第六截水辊组件16;A sixth water cut-off roller assembly 16 is provided at the connection between the second double countercurrent water washing tank 6 and the second water washing climbing overflow tank 7;
所述第二水洗爬坡溢流槽7与所述第一抗氧化槽8连接处设置有第七截水辊组件17;A seventh water cut-off roller assembly 17 is provided at the connection between the second water washing climbing overflow trough 7 and the first anti-oxidation trough 8;
所述第一抗氧化槽8与所述第二抗氧化槽9连接处设置有第八截水辊组件18;An eighth water cut-off roller assembly 18 is provided at the connection between the first anti-oxidation tank 8 and the second anti-oxidation tank 9;
所述第二抗氧化槽9与所述烘干箱10连接处设置有第九截水辊组件19;A ninth water cut-off roller assembly 19 is provided at the connection between the second anti-oxidation tank 9 and the drying box 10;
所述第九截水辊组件19一端设置有风切装置20;A wind shear device 20 is provided at one end of the ninth water cut-off roller assembly 19;
所述导电薄膜镀铜系统中装置安装高度自左往右逐渐上升。The installation height of the device in the conductive film copper plating system gradually increases from left to right.
该实施例中,依次连接的前处理槽1、第一双联逆流水洗槽2、第一水洗爬坡溢流槽3、至少一个镀铜槽4、至少一个镀铜爬坡溢流槽5、第二双联逆流水洗槽6、第二水洗爬坡溢流槽7、第一抗氧化槽8、第二抗氧化槽9、烘干箱10;In this embodiment, the pretreatment tank 1, the first double countercurrent water washing tank 2, the first water washing climbing overflow tank 3, at least one copper plating tank 4, at least one copper plating climbing overflow tank 5, the second double countercurrent water washing tank 6, the second water washing climbing overflow tank 7, the first antioxidant tank 8, the second antioxidant tank 9, and the drying box 10 are connected in sequence;
在薄膜系统运行过程中,本实用新型中所用的截水辊组件都如图2所示,通过同步旋转的第一截水辊组件11、第二截水辊组件12、第三截水辊组件13、第四截水辊组件14、第五截水辊组件15、第六截水辊组件16、第七截水辊组件17、第八截水辊组件18、第九截水辊组件19,避免薄膜上的液体流入下一个工序中,进一步保障了截水效果;During the operation of the film system, the water cut-off roller assemblies used in the utility model are shown in FIG. 2 , and the first water cut-off roller assembly 11, the second water cut-off roller assembly 12, the third water cut-off roller assembly 13, the fourth water cut-off roller assembly 14, the fifth water cut-off roller assembly 15, the sixth water cut-off roller assembly 16, the seventh water cut-off roller assembly 17, the eighth water cut-off roller assembly 18, and the ninth water cut-off roller assembly 19 are rotated synchronously to prevent the liquid on the film from flowing into the next process, thereby further ensuring the water cut-off effect;
本实用新型的技术方案,设置截水辊组件进一步降低了薄膜上的液体进入到下一个工序中,大大减弱了拉膜过程中薄膜带水问题,使前工作槽液体随薄膜带入后工作槽槽内液体的量降低到最低,延长了各工作槽液的使用寿命,且在传统电镀线上创造性的加入了前处理槽1和风切装置20,前处理槽1添加了中性前处理液还有纯水,可以洗掉膜面杂质;当薄膜传送至镀铜槽4后,已经得到了充分的清洗,通过风切装置20,使薄膜更加方便沥干水份,风切装置20如图4所示,可以选用塑料吹风罩子,同步连接加气装置至系统中,塑料吹风罩是斜面斜口小面积吹风的,同时创造性的在阴阳极辊处采用了脉冲电源可变化极性模式,阴极采用了稀硫酸洗辊装置,更进一步的避免了膜面污染,提升了产品质量,降低了制造成本。The technical solution of the utility model is to set up a water-cutting roller assembly to further reduce the liquid on the film from entering the next process, greatly reduce the problem of water on the film during the film drawing process, and reduce the amount of liquid in the front working tank brought into the rear working tank along with the film to a minimum, thereby extending the service life of the liquid in each working tank, and creatively add a pretreatment tank 1 and a wind cutting device 20 to the traditional electroplating line. The pretreatment tank 1 adds a neutral pretreatment liquid and pure water to wash away impurities on the film surface; when the film is transmitted to the copper plating tank 4, it has been fully cleaned, and the wind cutting device 20 makes it easier to drain water from the film. The wind cutting device 20 is shown in Figure 4, and a plastic blowing hood can be selected to synchronously connect the gas filling device to the system. The plastic blowing hood has a small area of slanted surface and bevel, and at the same time, a pulse power supply with a changeable polarity mode is creatively adopted at the anode and cathode rollers, and a dilute sulfuric acid roller washing device is adopted at the cathode, which further avoids membrane surface pollution, improves product quality, and reduces manufacturing costs.
本实用新型一可选的实施例,所述第一水洗爬坡溢流槽3结构高度沿着导电薄膜运行方向均匀变化。In an optional embodiment of the utility model, the structural height of the first water washing climbing overflow trough 3 changes uniformly along the running direction of the conductive film.
本实施例中,所述第一水洗爬坡溢流槽3结构高度沿着导电薄膜运行方向均匀变化,可以进一步降低导电薄膜上的液体。In this embodiment, the structural height of the first water washing climbing overflow trough 3 changes evenly along the running direction of the conductive film, which can further reduce the liquid on the conductive film.
本实用新型一可选的实施例,所述第一双联逆流水洗槽2包括第一水洗槽21、第二水洗槽22;In an optional embodiment of the present utility model, the first double countercurrent water washing tank 2 includes a first water washing tank 21 and a second water washing tank 22;
所述第一水洗槽21与所述第二水洗槽22依次连接;The first water washing tank 21 and the second water washing tank 22 are connected in sequence;
所述第一水洗槽21与所述第二水洗槽22连接处设置有第十截水辊组件23。A tenth water-cutting roller assembly 23 is disposed at the connection between the first water washing tank 21 and the second water washing tank 22 .
本实施例中,所述第一双联逆流水洗槽2包括第一水洗槽21、第二水洗槽22;双联水洗是在同一槽内配置两个水槽,通过在两个不同的水槽之间循环洗涤水进行清洗,逆流水洗是通过强制水流逆向通过工件来清洗表面;通过采用第一双联逆流水洗,薄膜清洗效率更高,逆流水洗由于流速高,可以有效地减少残留物的数量,所述第一水洗槽21与所述第二水洗槽22连接处设置有第十截水辊组件23,第一水洗槽21有出水口并位于刚进膜位置,第二水洗槽22有纯水进水口,薄膜一般先接触第一水洗槽21槽液清洗,再接触第二水洗槽22槽液清洗,一般都是第二水洗槽22槽液比第一水洗槽21槽液干净,第一水洗槽21、第二水洗槽22中的洗涤水虽然循环使用,但在第一水洗槽21、第二水洗槽22中间还需要设置第十截水辊组件23,可以降低薄膜表面在第一水洗槽21、第二水洗槽22运行过程中携带不同的液体进入到后续工序中。In this embodiment, the first double countercurrent washing tank 2 includes a first washing tank 21 and a second washing tank 22; double washing is to configure two tanks in the same tank, and wash by circulating washing water between two different tanks, and countercurrent washing is to clean the surface of the workpiece by forcing water to flow in the reverse direction; by adopting the first double countercurrent washing, the film cleaning efficiency is higher, and the countercurrent washing can effectively reduce the amount of residue due to the high flow rate, and the tenth water cut-off roller assembly 23 is provided at the connection between the first washing tank 21 and the second washing tank 22, and the first washing tank 21 has a water outlet The opening is located at the position just entering the film, and the second water washing tank 22 has a pure water inlet. The film is generally first contacted with the tank liquid of the first water washing tank 21 for cleaning, and then contacted with the tank liquid of the second water washing tank 22 for cleaning. Generally, the tank liquid of the second water washing tank 22 is cleaner than the tank liquid of the first water washing tank 21. Although the washing water in the first water washing tank 21 and the second water washing tank 22 is recycled, a tenth water-cutting roller assembly 23 is also required to be arranged between the first water washing tank 21 and the second water washing tank 22 to reduce the film surface from carrying different liquids into subsequent processes during the operation of the first water washing tank 21 and the second water washing tank 22.
本实用新型一可选的实施例,所述镀铜爬坡溢流槽5结构高度沿着导电薄膜运行方向均匀变化,可以进一步降低导电薄膜上的液体。In an optional embodiment of the utility model, the structural height of the copper-plated climbing overflow trough 5 changes evenly along the running direction of the conductive film, which can further reduce the liquid on the conductive film.
本实用新型一可选的实施例,所述第二双联逆流水洗槽6包括第三水洗槽61、第四水洗槽62;In an optional embodiment of the present utility model, the second double countercurrent water washing tank 6 includes a third water washing tank 61 and a fourth water washing tank 62;
所述第三水洗槽61与所述第四水洗槽62依次连接;The third water washing tank 61 is connected to the fourth water washing tank 62 in sequence;
所述第三水洗槽61与所述第四水洗槽62连接处设置有第十一截水辊组件63。An eleventh water-cutting roller assembly 63 is disposed at the connection between the third water-washing tank 61 and the fourth water-washing tank 62 .
本实施例中,所述第二双联逆流水洗槽6包括第三水洗槽61、第四水洗槽62;双联水洗是在同一槽内配置两个水槽,通过在两个不同的水槽之间循环洗涤水进行清洗,逆流水洗是通过强制水流逆向通过工件来清洗表面;通过采用第一双联逆流水洗,薄膜清洗效率更高,逆流水洗由于流速高,可以有效地减少残留物的数量,所述第三水洗槽61与所述第四水洗槽62连接处设置有第十一截水辊组件63。第三水洗槽61有出水口并位于刚进膜位置,第四水洗槽62有纯水进水口,薄膜一般先接触第三水洗槽61槽液清洗,再接触第四水洗槽62槽液清洗,一般都是第四水洗槽62槽液比第三水洗槽61槽液干净,第三水洗槽61、第四水洗槽62中的洗涤水虽然循环使用,但在第三水洗槽61、第四水洗槽62中间还需要设置第十一截水辊组件63,可以降低薄膜表面在所述第三水洗槽61、所述第四水洗槽62运行过程中携带不同的液体进入到后续工序中。In this embodiment, the second double countercurrent water washing tank 6 includes a third water washing tank 61 and a fourth water washing tank 62; the double water washing is to configure two water tanks in the same tank, and wash by circulating washing water between two different water tanks, and the countercurrent water washing is to clean the surface of the workpiece by forcing the water flow to reverse through the workpiece; by adopting the first double countercurrent water washing, the film cleaning efficiency is higher, and the countercurrent water washing can effectively reduce the amount of residue due to the high flow rate, and the eleventh water cut-off roller assembly 63 is provided at the connection between the third water washing tank 61 and the fourth water washing tank 62. The third water washing tank 61 has a water outlet and is located just at the film entry position, and the fourth water washing tank 62 has a pure water inlet. The film is generally first contacted with the tank liquid of the third water washing tank 61 for cleaning, and then contacted with the tank liquid of the fourth water washing tank 62 for cleaning. Generally, the tank liquid of the fourth water washing tank 62 is cleaner than the tank liquid of the third water washing tank 61. Although the washing water in the third water washing tank 61 and the fourth water washing tank 62 is recycled, an eleventh water-cutting roller assembly 63 is also required to be arranged between the third water washing tank 61 and the fourth water washing tank 62, which can reduce the film surface from carrying different liquids into subsequent processes during the operation of the third water washing tank 61 and the fourth water washing tank 62.
本实用新型一可选的实施例,所述第二水洗爬坡溢流槽7结构高度沿着导电薄膜运行方向均匀变化,可以进一步降低导电薄膜上的液体。In an optional embodiment of the utility model, the structural height of the second water washing climbing overflow trough 7 changes evenly along the running direction of the conductive film, which can further reduce the liquid on the conductive film.
本实用新型一可选的实施例,所述第二抗氧化槽9结构高度沿着导电薄膜运行方向均匀变化,可以进一步降低导电薄膜上的液体。In an optional embodiment of the present invention, the structural height of the second anti-oxidation groove 9 changes evenly along the running direction of the conductive film, which can further reduce the liquid on the conductive film.
本实用新型一可选的实施例,所述镀铜槽4中间隔设置有阴极辊30、阳极辊31;In an optional embodiment of the utility model, a cathode roller 30 and an anode roller 31 are arranged in the copper plating tank 4 at intervals;
根据预设工艺要求,通过脉冲整流器,调整所述阴极辊30、所述阳极辊31的极性;According to the preset process requirements, the polarities of the cathode roller 30 and the anode roller 31 are adjusted through a pulse rectifier;
所述阴极辊30两侧设置有第十二截水辊组件32。Twelfth water-cutting roller assemblies 32 are disposed on both sides of the cathode roller 30 .
本实用新型一可选的实施例,所述阴极辊30上部与下部均匀设置有喷淋装置33,用于去掉所述阴极辊30表面被镀上的浮铜。In an optional embodiment of the present invention, spray devices 33 are evenly arranged on the upper and lower parts of the cathode roller 30 to remove the floating copper plated on the surface of the cathode roller 30 .
本实用新型一可选的实施例,所述阴极辊30为铜辊,所述阳极辊31为钛镀铱不溶性阳极辊。In an optional embodiment of the present invention, the cathode roller 30 is a copper roller, and the anode roller 31 is an insoluble anode roller plated with iridium and titanium.
本实施例中,钛镀铱不溶性阳极辊是指将钛铱材料制成的辊子作为阳极,通过电镀反应,在表面形成一层钛铱薄膜,氧化钛铱薄膜具有优良的耐腐蚀性、耐磨损性和高温稳定性等特点;阴极铜辊是一种用于电解精炼铜和制备氧化铜等领域的铜制品;阴极铜辊通常采用高纯度的无氧铜为原材料加工而成,具有良好的导电、导热和可塑性能,能够承受高温和腐蚀等极端环境;也可以根据需要选用其它材质的阴极和阳极材料;电源采用脉冲电源,阴阳极的极性可根据工艺要求设置定时互换。In this embodiment, the titanium-iridium-plated insoluble anode roller refers to a roller made of titanium-iridium material as an anode, and a layer of titanium-iridium film is formed on the surface through electroplating reaction. The titanium-iridium oxide film has the characteristics of excellent corrosion resistance, wear resistance and high-temperature stability; the cathode copper roller is a copper product used in the fields of electrolytic refining of copper and preparation of copper oxide; the cathode copper roller is usually made of high-purity oxygen-free copper as raw material, has good electrical conductivity, thermal conductivity and plasticity, and can withstand extreme environments such as high temperature and corrosion; cathode and anode materials of other materials can also be selected as needed; the power supply adopts a pulse power supply, and the polarity of the anode and cathode can be set to be interchanged at regular intervals according to process requirements.
本实用新型的工作原理,各种类型塑料超薄膜(pp或pet但不限于这两种类型)通过放卷系统71进行放卷,放卷后的薄膜通过前处理槽1进行出油以及水洗,通过前处理槽1后的薄膜传输至第一双联逆流水洗槽2,双联水洗是在同一槽内配置两个水槽,通过在两个不同的水槽之间循环洗涤水进行清洗,逆流水洗是通过强制水流逆向通过工件来清洗表面;通过采用第一双联逆流水洗,薄膜清洗效率更高,逆流水洗由于流速高,可以有效地减少残留物的数量;The working principle of the utility model is that various types of plastic ultra-thin films (PP or PET but not limited to these two types) are unwound through the unwinding system 71, and the unwound film is deoiled and washed with water through the pre-treatment tank 1, and the film after passing through the pre-treatment tank 1 is transmitted to the first double countercurrent water washing tank 2, and the double water washing is to configure two water tanks in the same tank, and wash by circulating washing water between two different water tanks, and the countercurrent water washing is to force the water flow to reverse through the workpiece to clean the surface; by adopting the first double countercurrent water washing, the film cleaning efficiency is higher, and the countercurrent water washing can effectively reduce the amount of residue due to the high flow rate;
所述前处理槽1与所述第一双联逆流水洗槽2连接处设置有第一截水辊组件11;在薄膜前进运行过程中,使用第一截水辊组件11可以避免前处理槽1中的液体流入到后道工序中,减少后续工序的污染;薄膜通过所述第一双联逆流水洗槽2传递至所述第一水洗爬坡溢流槽3,所述第一双联逆流水洗槽2与所述第一水洗爬坡溢流槽3连接处设置有第二截水辊组件12,所述第一水洗爬坡溢流槽3结构高度沿着导电薄膜运行方向均匀变化,可以更好的减少前道工序中的液体对后道工序的液体造成影响;A first water-cutting roller assembly 11 is provided at the connection between the pre-treatment tank 1 and the first double countercurrent water washing tank 2; during the forward operation of the film, the use of the first water-cutting roller assembly 11 can prevent the liquid in the pre-treatment tank 1 from flowing into the subsequent process, thereby reducing the pollution of the subsequent process; the film is transferred to the first water washing climbing overflow tank 3 through the first double countercurrent water washing tank 2, and a second water-cutting roller assembly 12 is provided at the connection between the first double countercurrent water washing tank 2 and the first water washing climbing overflow tank 3. The structural height of the first water washing climbing overflow tank 3 changes evenly along the running direction of the conductive film, thereby better reducing the influence of the liquid in the previous process on the liquid in the subsequent process;
薄膜通过所述第一水洗爬坡溢流槽3传递至所述镀铜槽4,镀铜槽4内,阴极辊30、阳极辊31通过脉冲整流器联通,阴阳极的极性可根据工艺要求设置定时互换。当脉冲电源供给正向脉冲电流时,阳极辊31接正极,阴极辊30接负极,导通时间:5-10min,可以给薄膜镀铜;脉冲电源供给反向脉冲电流时,阴极辊30接正极,导通时间:5-10s,可以将阴极辊30上的铜电解,辅助稀硫酸水洗喷淋装置,从而达到去除阴极辊30上浮铜的目的,防止被镀铜后膜面被阴极辊30上累积的铜刺破;脉冲电源采用正向脉冲及反向脉冲相互交叉循环,使电流在供电方式正镀和反镀按照时间比例交替进行,持续时间比例可根据工艺要求调整。The film is transferred to the copper plating tank 4 through the first water washing climbing overflow tank 3. In the copper plating tank 4, the cathode roller 30 and the anode roller 31 are connected through a pulse rectifier, and the polarity of the positive and negative electrodes can be set to be exchanged at a fixed time according to the process requirements. When the pulse power supply supplies a positive pulse current, the anode roller 31 is connected to the positive electrode, and the cathode roller 30 is connected to the negative electrode. The conduction time is 5-10min, and the film can be copper plated; when the pulse power supply supplies a reverse pulse current, the cathode roller 30 is connected to the positive electrode, and the conduction time is 5-10s, and the copper on the cathode roller 30 can be electrolyzed, and the dilute sulfuric acid water washing spray device is assisted, so as to achieve the purpose of removing the floating copper on the cathode roller 30 and prevent the copper-plated film surface from being punctured by the accumulated copper on the cathode roller 30; the pulse power supply adopts a forward pulse and a reverse pulse to cross-circulate each other, so that the current is alternately positively plated and reversely plated according to the time ratio in the power supply mode, and the duration ratio can be adjusted according to the process requirements.
为防止阴极辊30被重复镀铜(铜上被镀铜后膜面容易被刺破),阴极辊30采用截水辊组件截水,阴极辊30上部与下部设置第十二截水辊组件32,阴极辊30单独采取独立过液槽,上下加喷淋5%-20%稀硫酸溶液喷淋洗辊,去掉阴极辊表面被镀上的浮铜,如此单元重复,被分段的镀铜槽4可以用联通附槽连接,保证整线槽液主盐浓度相同;In order to prevent the cathode roller 30 from being repeatedly copper-plated (the film surface is easily punctured after copper is plated), the cathode roller 30 uses a water-cutting roller assembly to cut water, and a twelfth water-cutting roller assembly 32 is arranged at the upper and lower parts of the cathode roller 30. The cathode roller 30 adopts an independent liquid-passing tank, and 5%-20% dilute sulfuric acid solution is sprayed on the upper and lower parts to wash the roller to remove the floating copper plated on the surface of the cathode roller. In this way, the unit is repeated, and the segmented copper plating tank 4 can be connected with a connecting auxiliary tank to ensure that the main salt concentration of the tank liquid of the whole line is the same;
所述第一水洗爬坡溢流槽3与所述镀铜槽4连接处设置有第三截水辊组件13;薄膜通过所述镀铜槽4传递至所述镀铜爬坡溢流槽5,薄膜在所述镀铜爬坡溢流槽,使薄膜上带水充分回流到镀铜爬坡溢流槽5中,所述镀铜槽4与所述镀铜爬坡溢流槽5连接处设置有第四截水辊组件14;继而薄膜依次通过所述第二双联逆流水洗槽6、所述第二水洗爬坡溢流槽7,所述镀铜爬坡溢流槽5与所述第二双联逆流水洗槽6连接处设置有第五截水辊组件15,所述第二双联逆流水洗槽6与所述第二水洗爬坡溢流槽7连接处设置有第六截水辊组件16;所述第二双联逆流水洗槽6包括第三水洗槽61、第四水洗槽62;所述第三水洗槽61与所述第四水洗槽62依次连接;所述第三水洗槽61与所述第四水洗槽62连接处设置有第十一截水辊组件63。A third water-cutting roller assembly 13 is provided at the connection between the first water-washing climbing overflow trough 3 and the copper-plating trough 4; the film is transferred to the copper-plating climbing overflow trough 5 through the copper-plating climbing overflow trough, and the film is in the copper-plating climbing overflow trough, so that the water on the film fully flows back to the copper-plating climbing overflow trough 5, and a fourth water-cutting roller assembly 14 is provided at the connection between the copper-plating trough 4 and the copper-plating climbing overflow trough 5; then the film passes through the second double countercurrent water-washing trough 6, the second water-washing climbing overflow trough 7, and the copper-plating climbing overflow trough 5 in turn. A fifth water-cutting roller assembly 15 is provided at the connection between the slope overflow trough 5 and the second double countercurrent water washing trough 6, and a sixth water-cutting roller assembly 16 is provided at the connection between the second double countercurrent water washing trough 6 and the second water washing climbing overflow trough 7; the second double countercurrent water washing trough 6 includes a third water washing trough 61 and a fourth water washing trough 62; the third water washing trough 61 and the fourth water washing trough 62 are connected in sequence; an eleventh water-cutting roller assembly 63 is provided at the connection between the third water washing trough 61 and the fourth water washing trough 62.
薄膜依次通过所述第一抗氧化槽8、所述第二抗氧化槽9、所述烘干箱10,所述第一抗氧化槽8、所述第二抗氧化槽9中液体对超薄膜进行多次抗氧化处理;所述第二水洗爬坡溢流槽7与所述第一抗氧化槽8连接处设置有第七截水辊组件17;所述第一抗氧化槽8与所述第二抗氧化槽9连接处设置有第八截水辊组件18;所述第二抗氧化槽9与所述烘干箱10连接处设置有第九截水辊组件19;所述第九截水辊组件19一端设置有风切装置20,The film passes through the first antioxidant trough 8, the second antioxidant trough 9, and the drying box 10 in sequence. The liquids in the first antioxidant trough 8 and the second antioxidant trough 9 perform multiple antioxidant treatments on the ultra-thin film. A seventh water-cutting roller assembly 17 is provided at the connection between the second water-washing climbing overflow trough 7 and the first antioxidant trough 8. An eighth water-cutting roller assembly 18 is provided at the connection between the first antioxidant trough 8 and the second antioxidant trough 9. A ninth water-cutting roller assembly 19 is provided at the connection between the second antioxidant trough 9 and the drying box 10. A wind shear device 20 is provided at one end of the ninth water-cutting roller assembly 19.
在第九截水辊组件19的前后加装风切装置20,充分保证了薄膜膜面风干,尽量避免了薄膜进入烘干箱10工段时带水过多,影响烘干效果,所述烘干箱10用于对超薄膜烘干,前述工序完成后,通过收卷系统72进行收卷,传输至下到工序。Wind shear devices 20 are installed before and after the ninth water-cutting roller assembly 19, which fully ensures that the film surface is air-dried and tries to avoid the film from carrying too much water when entering the drying box 10 section, which affects the drying effect. The drying box 10 is used to dry the ultra-thin film. After the above-mentioned process is completed, it is rolled up by the winding system 72 and transmitted to the next process.
以上所述是本实用新型的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本实用新型所述原理的前提下,还可以作出若干改进和润饰,这些改进和润饰也应视为本实用新型的保护范围。The above is a preferred embodiment of the present invention. It should be pointed out that, for ordinary technicians in this technical field, several improvements and modifications can be made without departing from the principles of the present invention. These improvements and modifications should also be regarded as the protection scope of the present invention.
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