CN221802661U - Tank armor protective layer - Google Patents
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Abstract
Description
技术领域Technical Field
本申请涉及一种坦克装甲防护式的防护层,属于防护装备领域。The present application relates to a tank armor protection type protective layer, belonging to the field of protective equipment.
背景技术Background Art
头盔是日常生活中常见的防护工具,其中头盔外壳的防护性能是头盔的重要性能,但目前头盔外壳主要为单一的塑料或单一的纤维增强树脂基复合材料。外壳为单一的塑料时,其刚性差,靠增加厚度提高刚性便增加了产品重量,由此增加了头/颈部的负担,且老化后受撞击极易造成分裂,使体验的舒适性和安全感变差;外壳为单一的纤维增强树脂基复合材料时,受剪切外力时易脆断,安全防穿刺效果差。因此头盔外壳的安全性依旧有待提高。Helmets are common protective tools in daily life, and the protective performance of the helmet shell is an important performance of the helmet. However, the current helmet shell is mainly made of a single plastic or a single fiber-reinforced resin-based composite material. When the shell is made of a single plastic, its rigidity is poor. Increasing the rigidity by increasing the thickness will increase the weight of the product, thereby increasing the burden on the head/neck. It is also very easy to split when hit after aging, which makes the comfort and sense of security worse. When the shell is made of a single fiber-reinforced resin-based composite material, it is easy to break when subjected to shear force, and the safety and anti-puncture effect is poor. Therefore, the safety of the helmet shell still needs to be improved.
发明内容Summary of the invention
为了提升防护装备尤其是头盔的防护性能。本申请提供一种坦克装甲防护式的防护层。In order to improve the protective performance of protective equipment, especially helmets, the present application provides a tank armor protection type protective layer.
根据本申请的一个方面,提供了一种坦克装甲防护式的防护层,包括n层坦克装甲防护式层,n选自1~50之间的正整数;According to one aspect of the present application, there is provided a tank armor protection type protective layer, comprising n layers of tank armor protection type layers, where n is selected from a positive integer between 1 and 50;
n为1时所述坦克装甲防护式层被粘结卸力吸能防护层包覆;When n is 1, the tank armor protection layer is covered by a bonding force-unloading energy-absorbing protection layer;
每层坦克装甲防护式层之间通过粘结卸力吸能防护层相互粘结。Each layer of tank armor protection is bonded to each other through a bonding force-discharging and energy-absorbing protective layer.
具体地,由外至内依次为第一坦克装甲防护式层、第一粘结卸力吸能防护层第二坦克装甲防护式层、第二粘结卸力吸能防护层、第三坦克装甲防护式层,依此类推。Specifically, from outside to inside, they are the first tank armor protection layer, the first bonding force unloading energy absorption protection layer, the second tank armor protection layer, the second bonding force unloading energy absorption protection layer, the third tank armor protection layer, and so on.
所述坦克装甲防护式层的材料选自纤维增强树脂、PC材料、ABS材料、PP材料、芳纶纤维(如凯夫拉)、超高分子量PE、尼龙纤维、碳纤维、玻璃纤维等中的至少一种;The material of the tank armor protection layer is selected from at least one of fiber-reinforced resin, PC material, ABS material, PP material, aramid fiber (such as Kevlar), ultra-high molecular weight PE, nylon fiber, carbon fiber, glass fiber, etc.;
可选地,所述纤维增强树脂包括纤维和树脂;Optionally, the fiber-reinforced resin comprises fibers and resin;
所述纤维选自碳纤维、玻璃纤维、芳纶纤维、超高分子量PE、尼龙纤维中的至少一种;The fiber is selected from at least one of carbon fiber, glass fiber, aramid fiber, ultra-high molecular weight PE, and nylon fiber;
所述树脂选自EPOXY树脂、PC树脂、酚酫树脂中的至少一种。The resin is selected from at least one of EPOXY resin, PC resin and phenolic resin.
可选地,相邻的两层坦克装甲防护式层的材料不同。Optionally, two adjacent tank armor protection layers are made of different materials.
可选地,最外层的坦克装甲防护式层的材料不为凯夫拉。Optionally, the material of the outermost tank armor protective layer is not Kevlar.
所述坦克装甲防护式层的厚度为0.05~3mm;The thickness of the tank armor protection layer is 0.05 to 3 mm;
可选地,所述坦克装甲防护式层的厚度为0.2~2mm。Optionally, the thickness of the tank armor protection layer is 0.2 to 2 mm.
可选地,最外层的坦克装甲防护式层要比内层的坦克装甲防护式层更厚。Optionally, the outermost tank armor protection layer is thicker than the inner tank armor protection layer.
可选地,外层的坦克装甲防护式层要比内层的坦克装甲防护式层更厚。Optionally, the outer tank armor protection layer is thicker than the inner tank armor protection layer.
所述粘结卸力吸能防护层含有粘结材料、韧性增强材料和吸能材料。The bonding force-unloading energy-absorbing protective layer contains bonding material, toughness-enhancing material and energy-absorbing material.
所述粘结卸力吸能防护层中,所述韧性增强材料和吸能材料的质量含量为不超过85%;In the bonding unloading energy absorbing protective layer, the mass content of the toughness enhancing material and the energy absorbing material is no more than 85%;
可选地,所述韧性增强材料的质量含量为20~75%;Optionally, the mass content of the toughness enhancing material is 20 to 75%;
可选地,所述吸能材料的质量含量为30~85%。Optionally, the mass content of the energy absorbing material is 30-85%.
所述粘结材料选自聚氨酯、聚丙烯、PA、PES、TPU、EVA、PO、EAA等中的至少一种;所述粘结材料具有单一材质或同时具备粘连性和吸能性的复合材质。The bonding material is selected from at least one of polyurethane, polypropylene, PA, PES, TPU, EVA, PO, EAA, etc.; the bonding material has a single material or a composite material with both adhesion and energy absorption properties.
所述粘结材料的重均分子量为5000~3500000。优选地,所述粘结材料的重均分子量为30000~150000。The weight average molecular weight of the bonding material is 5000 to 3500000. Preferably, the weight average molecular weight of the bonding material is 30000 to 150000.
所述韧性增强材料和吸能材料选自分散颗粒和/或网片状材料;The toughness enhancing material and energy absorbing material are selected from dispersed particles and/or mesh-like materials;
所述分散颗粒选自有机、无机或金属的中空珠或发泡体。The dispersed particles are selected from organic, inorganic or metal hollow beads or foams.
所述分散颗粒选自热固性树脂中空微珠、中空玻璃珠、中空钛珠、钛微发泡体、铝微发泡体中的至少一种;The dispersed particles are selected from at least one of thermosetting resin hollow microspheres, hollow glass beads, hollow titanium beads, titanium microfoams, and aluminum microfoams;
所述网片状材料选自超高分子量PE、芳纶纤维、尼龙纤维中的至少一种。The mesh material is selected from at least one of ultra-high molecular weight PE, aramid fiber, and nylon fiber.
根据本申请的另一个方面,提供一种上述的坦克装甲防护式的防护层的制备方法,包括以下步骤:According to another aspect of the present application, a method for preparing the above-mentioned tank armor protection type protective layer is provided, comprising the following steps:
将韧性增强材料和吸能材料浸渍于粘结材料中,得到粘结卸力吸能防护层,通过粘结卸力吸能防护层将坦克装甲防护式层粘结起来,得到所述坦克装甲防护式的防护层。The toughness enhancing material and the energy absorbing material are impregnated into the bonding material to obtain a bonding force unloading energy absorbing protective layer, and the tank armor protective layer is bonded together through the bonding force unloading energy absorbing protective layer to obtain the tank armor protective protective layer.
根据本申请的另一个方面,提供一种上述的坦克装甲防护式的防护层的应用,用于防护装备的外壳。According to another aspect of the present application, there is provided an application of the above-mentioned tank armor protection type protective layer for the outer shell of protective equipment.
所述防护装备包括头盔、护肘、护臂、护膝、护颈、护胫、护踝、防护背心、防护裤、防护鞋。The protective equipment includes a helmet, elbow pads, arm guards, knee pads, neck guards, shin guards, ankle guards, protective vests, protective pants, and protective shoes.
在本申请中,EPOXY树脂为环氧树脂;In the present application, EPOXY resin is epoxy resin;
PC为聚碳酸酯树脂;PC is polycarbonate resin;
ABS为丙烯腈-丁二烯-苯乙烯共聚物;ABS is acrylonitrile-butadiene-styrene copolymer;
PP为聚丙烯;PP is polypropylene;
PA为聚酰胺树脂;PA is polyamide resin;
PES为聚醚砜;PES is polyethersulfone;
TPU为热塑性聚氨酯弹性体;TPU is thermoplastic polyurethane elastomer;
EVA为乙烯-醋酸乙烯酯共聚物;EVA is ethylene-vinyl acetate copolymer;
PO为聚烯烃共聚物;PO is a polyolefin copolymer;
EAA为乙烯-丙烯酸共聚物;EAA is ethylene-acrylic acid copolymer;
PE为聚乙烯。PE is polyethylene.
本申请能产生的有益效果包括:The beneficial effects of this application include:
1)本申请所提供的坦克装甲防护式的防护层,使用具有一定吸能效果的粘结材料形成的粘接层具有一定粘流性、韧性及吸能性,在发生穿刺的过程中,可以产生错位移动,进而提升防护能力。1) The tank armor protection type protective layer provided in the present application uses an adhesive layer formed by an adhesive material with a certain energy absorption effect, which has a certain viscosity, toughness and energy absorption. During the puncture process, it can produce dislocation movement, thereby improving the protection capability.
2)本申请所提供的坦克装甲防护式的防护层,在添加多层坦克装甲防护式的防护层后,会进一步提升吸能效果,可以进一步的提升坦克装甲防护式能力。2) The tank armor protection type protective layer provided in this application will further enhance the energy absorption effect after adding multiple layers of tank armor protection type protective layer, and can further enhance the tank armor protection type capability.
3)本申请所提供的坦克装甲防护式的防护层的制备方法,制备工艺简单。3) The method for preparing the tank armor protection type protective layer provided in the present application has a simple preparation process.
附图说明BRIEF DESCRIPTION OF THE DRAWINGS
图1为本申请实施例1制备的坦克装甲防护式的防护层的结构示意图。FIG1 is a schematic diagram of the structure of the tank armor protection type protective layer prepared in Example 1 of the present application.
部件和附图标记列表:List of parts and reference numerals:
1、第一坦克装甲防护式层,2、粘结卸力吸能防护层,3、第二坦克装甲防护式层。1. The first tank armor protection layer, 2. The bonding force unloading energy absorption protection layer, 3. The second tank armor protection layer.
具体实施方式DETAILED DESCRIPTION
下面结合实施例详述本申请,但本申请并不局限于这些实施例。The present application is described in detail below with reference to embodiments, but the present application is not limited to these embodiments.
如无特别说明,本申请的实施例中的原料均通过商业途径购买。Unless otherwise specified, the raw materials in the examples of this application were purchased through commercial channels.
在本实施例中,聚氨酯粘接剂购自乐瑞固,均分子量为30000~100000;纤维增强树脂根据US9840058B2中的制备方法得到;PC材料、ABS材料、PP材料等均通过商业途径购买。In this embodiment, the polyurethane adhesive is purchased from Leroyol, and the average molecular weight is 30,000-100,000; the fiber-reinforced resin is obtained according to the preparation method in US9840058B2; PC materials, ABS materials, PP materials, etc. are all purchased through commercial channels.
实施例1Example 1
使用平均分子量为30000的聚氨酯材料1000g含浸300g中空玻璃微珠和700g凯夫拉织物片材制成所需的粘接材料,将以纤维增强树脂(具体为碳纤维、玻璃纤维、凯夫拉纤维混杂增强环氧树脂。)为材料的第一坦克装甲防护式层1与以PC材料为材料的第二坦克装甲防护式层3粘结成型,得到形成第一坦克装甲防护式层1、粘接层2和第二坦克装甲防护式层3依次粘接的坦克装甲防护式的防护层,如图1所示。The required bonding material is made by impregnating 300g of hollow glass microspheres and 700g of Kevlar fabric sheets with 1000g of polyurethane material with an average molecular weight of 30,000, and bonding the first tank armor protective layer 1 made of fiber reinforced resin (specifically carbon fiber, glass fiber, Kevlar fiber mixed reinforced epoxy resin) and the second tank armor protective layer 3 made of PC material to obtain a tank armor protective layer in which the first tank armor protective layer 1, the adhesive layer 2 and the second tank armor protective layer 3 are bonded in sequence, as shown in Figure 1.
其中,第一坦克装甲防护式层1的厚度为1.0mm。第二坦克装甲防护式层3的厚度为0.5mm。The thickness of the first tank armor protection layer 1 is 1.0 mm, and the thickness of the second tank armor protection layer 3 is 0.5 mm.
本实施例制备的坦克装甲防护式的防护层用于头盔外壳或护甲护具,使用聚氨酯材料作为粘结材料,其形成的粘接层具有一定粘流性、韧性及吸能性,在发生穿刺的过程中,可以产生错位移动,进而提升坦克装甲防护式能力。本实施例仅说明层数为三层的情况,层数更多时以此类推。The tank armor protective layer prepared in this embodiment is used for the helmet shell or armor and protective gear, and the polyurethane material is used as the bonding material. The bonding layer formed by the polyurethane material has certain viscosity, toughness and energy absorption. During the puncture process, it can produce dislocation movement, thereby improving the tank armor protective capability. This embodiment only describes the case where the number of layers is three, and the same applies when the number of layers is more.
对头盔进行耐穿透性能测试。结果显示:The helmet was tested for penetration resistance. The results showed:
实施例1的头盔进行GJB1564A中Ⅱ类头盔的穿透能量(29.4J)试验,头盔不被穿透,符合技术要求。The helmet of Example 1 was subjected to the penetration energy (29.4 J) test of Class II helmets in GJB1564A, and the helmet was not penetrated, thus meeting the technical requirements.
实施例1的头盔进行T/JSEBA中耐穿刺性能测试,经3.0Kg钢锥落高1.0m,2次,头盔未被穿透,符合标准要求。The helmet of Example 1 was subjected to a puncture resistance test in T/JSEBA. The helmet was not penetrated by a 3.0 kg steel cone falling from a height of 1.0 m for 2 times, thus meeting the standard requirements.
实施例2Example 2
使用平均分子量为30000的聚氨酯材料1000g含浸300g中空玻璃微珠和630g尼龙织物片材(N1260尼龙帘子布)制成所需的粘接材料,将以纤维增强树脂(具体为碳纤维、玻璃纤维、凯夫拉纤维混杂增强环氧树脂。)为材料的第一坦克装甲防护式层1与以凯夫拉纤维增强PC树脂材料为材料的第二坦克装甲防护式层3粘结成型,得到形成第一坦克装甲防护式层1、粘接层2和第二坦克装甲防护式层3依次粘接的坦克装甲防护式的防护层,如图1所示。The required bonding material is made by impregnating 300g hollow glass microspheres and 630g nylon fabric sheet (N1260 nylon cord cloth) with 1000g polyurethane material with an average molecular weight of 30,000, and bonding the first tank armor protection layer 1 made of fiber reinforced resin (specifically carbon fiber, glass fiber, Kevlar fiber mixed reinforced epoxy resin) and the second tank armor protection layer 3 made of Kevlar fiber reinforced PC resin material to obtain a tank armor protection layer in which the first tank armor protection layer 1, the adhesive layer 2 and the second tank armor protection layer 3 are bonded in sequence, as shown in Figure 1.
其中,第一坦克装甲防护式层1的厚度为1.2mm。第二坦克装甲防护式层3的厚度为0.7mm。The thickness of the first tank armor protection layer 1 is 1.2 mm, and the thickness of the second tank armor protection layer 3 is 0.7 mm.
本实施例制备的坦克装甲防护式的防护层用于头盔外壳或护甲护具,使用聚氨酯材料作为粘结材料,其形成的粘接层具有一定粘流性、韧性及吸能性,在发生穿刺的过程中,可以产生错位移动,进而提升坦克装甲防护式能力。本实施例仅说明层数为三层的情况,层数更多时以此类推。The tank armor protective layer prepared in this embodiment is used for the helmet shell or armor and protective gear, and the polyurethane material is used as the bonding material. The bonding layer formed by the polyurethane material has certain viscosity, toughness and energy absorption. During the puncture process, it can produce dislocation movement, thereby improving the tank armor protective capability. This embodiment only describes the case where the number of layers is three, and the same applies when the number of layers is more.
实施例2的头盔进行GJB1564A中Ⅱ类头盔的穿透能量(29.4J)试验和T/JSEBA中耐穿刺性能测试,与实施例1结果类似,头盔不被穿透,符合技术要求。The helmet of Example 2 was subjected to the penetration energy test (29.4 J) of Class II helmets in GJB1564A and the puncture resistance test in T/JSEBA. The results were similar to those of Example 1, and the helmet was not penetrated, meeting the technical requirements.
实施例3Example 3
使用平均分子量为30000的聚氨酯材料1000g含浸300g中空玻璃微珠和630g尼龙织物片材(N1260尼龙帘子布)制成所需的粘接材料,将以纤维增强树脂(具体为碳纤维、玻璃纤维、凯夫拉纤维混杂增强环氧树脂。)为材料的第一坦克装甲防护式层1与以凯夫拉纤维增强环氧树脂材料为材料的第二坦克装甲防护式层3粘结成型,得到形成第一坦克装甲防护式层1、粘接层2和第二坦克装甲防护式层3依次粘接的坦克装甲防护式的防护层,如图1所示。The required bonding material is made by impregnating 300g hollow glass microspheres and 630g nylon fabric sheet (N1260 nylon cord cloth) with 1000g polyurethane material with an average molecular weight of 30,000, and bonding the first tank armor protection layer 1 made of fiber reinforced resin (specifically carbon fiber, glass fiber, Kevlar fiber mixed reinforced epoxy resin) and the second tank armor protection layer 3 made of Kevlar fiber reinforced epoxy resin material to obtain a tank armor protection layer in which the first tank armor protection layer 1, the bonding layer 2 and the second tank armor protection layer 3 are bonded in sequence, as shown in Figure 1.
其中,第一坦克装甲防护式层1的厚度为1.0mm。第二坦克装甲防护式层3的厚度为0.8mm。The thickness of the first tank armor protection layer 1 is 1.0 mm, and the thickness of the second tank armor protection layer 3 is 0.8 mm.
本实施例制备的坦克装甲防护式的防护层用于头盔外壳,使用聚氨酯材料作为粘结材料,其形成的粘接层具有一定粘流性、韧性及吸能性,在发生穿刺的过程中,可以产生错位移动,进而提升坦克装甲防护式能力。本实施例仅说明层数为三层的情况,层数更多时以此类推。The tank armor protection type protective layer prepared in this embodiment is used for the helmet shell, and the polyurethane material is used as the bonding material. The bonding layer formed by it has certain viscosity, toughness and energy absorption. During the puncture process, it can produce dislocation movement, thereby improving the tank armor protection type capability. This embodiment only describes the case where the number of layers is three, and the same applies when the number of layers is more.
实施例3的头盔进行GJB1564A中Ⅱ类头盔的穿透能量(29.4J)试验和T/JSEBA中耐穿刺性能测试,与实施例1结果类似,头盔不被穿透,符合技术要求。The helmet of Example 3 was subjected to the penetration energy test (29.4 J) of Class II helmets in GJB1564A and the puncture resistance test in T/JSEBA. The results were similar to those of Example 1, and the helmet was not penetrated, meeting the technical requirements.
以上所述,仅是本申请的几个实施例,并非对本申请做任何形式的限制,虽然本申请以较佳实施例揭示如上,然而并非用以限制本申请,任何熟悉本专业的技术人员,在不脱离本申请技术方案的范围内,利用上述揭示的技术内容做出些许的变动或修饰均等同于等效实施案例,均属于技术方案范围内。The above are only a few embodiments of the present application and do not constitute any form of limitation to the present application. Although the present application is disclosed as above with preferred embodiments, it is not intended to limit the present application. Any technician familiar with the profession, without departing from the scope of the technical solution of the present application, using the technical contents disclosed above to make slight changes or modifications are equivalent to equivalent implementation cases and fall within the scope of the technical solution.
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