CN220619984U - Reclamation system to improve nitrate removal efficiency - Google Patents
Reclamation system to improve nitrate removal efficiency Download PDFInfo
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- CN220619984U CN220619984U CN202322116911.8U CN202322116911U CN220619984U CN 220619984 U CN220619984 U CN 220619984U CN 202322116911 U CN202322116911 U CN 202322116911U CN 220619984 U CN220619984 U CN 220619984U
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- 229910002651 NO3 Inorganic materials 0.000 title claims abstract description 26
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 title claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000006004 Quartz sand Substances 0.000 claims abstract description 21
- 239000003673 groundwater Substances 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 241000894006 Bacteria Species 0.000 claims abstract description 9
- 239000004576 sand Substances 0.000 claims description 17
- 238000007664 blowing Methods 0.000 claims description 8
- 230000035699 permeability Effects 0.000 claims description 8
- 230000005012 migration Effects 0.000 claims description 5
- 238000013508 migration Methods 0.000 claims description 5
- 239000004568 cement Substances 0.000 claims description 2
- 239000011083 cement mortar Substances 0.000 claims description 2
- 239000002002 slurry Substances 0.000 claims description 2
- 241000894007 species Species 0.000 claims 1
- 238000005507 spraying Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 abstract description 4
- 244000005700 microbiome Species 0.000 abstract description 4
- 230000000813 microbial effect Effects 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 229910052799 carbon Inorganic materials 0.000 description 11
- 230000000694 effects Effects 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910052760 oxygen Inorganic materials 0.000 description 6
- 239000001301 oxygen Substances 0.000 description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000013505 freshwater Substances 0.000 description 4
- 150000002823 nitrates Chemical class 0.000 description 4
- 239000013535 sea water Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 238000005336 cracking Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000032258 transport Effects 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005842 biochemical reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000001546 nitrifying effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000029058 respiratory gaseous exchange Effects 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 241001148471 unidentified anaerobic bacterium Species 0.000 description 1
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- Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
- Biological Treatment Of Waste Water (AREA)
Abstract
Description
技术领域Technical field
本实用新型涉及一种填海造陆系统,尤其涉及一种提高硝酸盐去除效率的填海造陆系统。The utility model relates to a sea reclamation and land creation system, in particular to a sea reclamation and land creation system that improves nitrate removal efficiency.
背景技术Background technique
吹沙填海是通过将沙子吹到目标区域,将原先被海水淹没的地方堆填成沙地,再采用夯实固化等方式实现造陆。但是,该方法没有具体考虑填海区具体的渗透系数,而沿海含水层的渗透系数会对营养盐、污染物等溶质运移产生很大的影响。Sand blowing and reclamation is to create land by blowing sand to the target area, filling the area that was originally flooded by seawater into sand, and then compacting and solidifying it. However, this method does not specifically consider the specific permeability coefficient of the reclamation area, and the permeability coefficient of coastal aquifers will have a great impact on the migration of solutes such as nutrients and pollutants.
同时,沿海地区农业向水体排放大量的氮,以硝酸盐为代表的污染物通过降雨入渗、河道排放等途径进入地下水流动,对沿海生态产生不利影响。硝酸盐物质对于地下水环境的破坏力度较大,且影响深远,逐渐成为现阶段水资源的重要问题。At the same time, agriculture in coastal areas discharges large amounts of nitrogen into water bodies, and pollutants represented by nitrates enter groundwater flow through rainfall infiltration, river discharge, etc., causing adverse effects on coastal ecology. Nitrate substances cause great damage to the groundwater environment and have far-reaching impacts. They have gradually become an important issue in water resources at this stage.
海岸带含水层水文地质条件复杂,反应性溶质运移研究难度大,针对人类活动影响下的沿海含水层生化反应研究更是少之又少,因此,如何在填海造陆的情况下提高硝酸盐去除效率依旧是科研人员需要攻克的难题之一。The hydrogeological conditions of coastal aquifers are complex, and it is difficult to study the transport of reactive solutes. There are even fewer studies on the biochemical reactions of coastal aquifers under the influence of human activities. Therefore, how to increase nitrates during land reclamation Removal efficiency is still one of the difficult problems that researchers need to overcome.
实用新型内容Utility model content
实用新型目的:本实用新型的目的是提供一种具有较好脱氮效果的提高硝酸盐去除效率的填海造陆系统。Purpose of the utility model: The purpose of the utility model is to provide a land reclamation system with good denitrification effect and improved nitrate removal efficiency.
技术方案:本实用新型所述的提高硝酸盐去除效率的填海造陆系统,沿地下水流动方向依次包括原始含水层、垫层、吹填区;所述垫层内沿横向间隔设置有用于为反硝化菌提供生长空间并过滤地下水的石英砂墙;所述吹填区包括用于降低水流流速延长硝酸盐在含水层中停留时间的防渗层。Technical solution: The sea reclamation and land reclamation system for improving nitrate removal efficiency described in this utility model sequentially includes an original aquifer, a cushion layer, and a blowing and reclamation area along the direction of groundwater flow; the cushion layer is provided with transverse intervals for providing reaction Quartz sand walls provide growth space for nitrifying bacteria and filter groundwater; the blow-fill area includes an anti-seepage layer used to reduce the flow rate of water and prolong the residence time of nitrates in the aquifer.
其中,所述石英砂墙的宽度为1.5~2m;相邻两个石英砂墙的横向间距为5~10m。石英砂墙布置的间隔满足其能在地下水流动方向上能起到足够的过滤作用,同时合适的宽度既能够保证微生物生长,又能保证成本不会过高。Wherein, the width of the quartz sand wall is 1.5-2m; the lateral spacing between two adjacent quartz sand walls is 5-10m. The intervals between the quartz sand walls are such that they can play a sufficient filtering role in the direction of groundwater flow. At the same time, the appropriate width can not only ensure the growth of microorganisms, but also ensure that the cost is not too high.
其中,所述吹填区还包括沙层,所述防渗层沿沙层纵向间隔设置。Wherein, the blowing and filling area also includes a sand layer, and the anti-seepage layer is arranged at longitudinal intervals along the sand layer.
其中,防渗层的高度为0.6~1.2m;相邻两个防渗层之间的纵向间距为2~2.5m。混凝土防渗层的高度保证其有适当的强度和弹性模量,有效预防其在后期使用中开裂,依据含水层海边界的水流特征和潮汐振幅设置防渗层间距,保证在低潮位附近的淡水排出口处、高潮位附近的海水循坏入口处都设有防渗层。Among them, the height of the anti-seepage layer is 0.6~1.2m; the longitudinal spacing between two adjacent anti-seepage layers is 2~2.5m. The height of the concrete anti-seepage layer ensures that it has appropriate strength and elastic modulus, effectively preventing cracking during later use. The anti-seepage layer spacing is set based on the flow characteristics and tidal amplitude of the aquifer sea boundary to ensure fresh water near the low tide level. Anti-seepage layers are installed at the discharge outlet and at the seawater circulation inlet near high tide.
其中,所垫层包括卵石,所述卵石之间分散有碳颗粒;所述的垫层采用粒径不大于0.1m的人造卵石。所述垫层的厚度为0.5~1m。Wherein, the cushion layer includes pebbles, and carbon particles are dispersed between the pebbles; the cushion layer uses artificial pebbles with a particle size of no more than 0.1m. The thickness of the cushion layer is 0.5-1m.
其中,所述吹填区的渗透系数小于原始含水层,用于增加陆源硝酸盐物质的迁移时间。Wherein, the permeability coefficient of the reclamation area is smaller than the original aquifer, which is used to increase the migration time of terrestrial nitrate substances.
其中,所述防渗层为混凝土浇筑层;利用高压空气将水泥浆或水泥砂浆喷射到沙子表面,形成均匀而致密的混凝土浇注层。Wherein, the anti-seepage layer is a concrete pouring layer; high-pressure air is used to spray cement slurry or cement mortar onto the sand surface to form a uniform and dense concrete pouring layer.
有益效果:本实用新型与现有技术相比,取得如下显著效果:Beneficial effects: Compared with the existing technology, this utility model achieves the following significant effects:
(1)本实用新型的垫层及其横向设置的石英砂墙,与纵向设置的防渗层的配合,保证了反硝化所需的电子供体足够的同时,增加了硝化反硝化的时间,取得很好的脱氮效果,提高了硝酸盐去除效率;(2)石英砂墙布置的间隔满足其能在地下水流动方向上能起到足够的过滤作用,同时合适的宽度既能够保证微生物生长,又能保证成本不会过高;(3)混凝土防渗层的高度保证其有适当的强度和弹性模量,有效预防其在后期使用中开裂,依据含水层海边界的水流特征和潮汐振幅设置防渗层间距,保证在低潮位附近的淡水排出口处、高潮位附近的海水循坏入口处都设有防渗层;(4)原始含水层与吹填区之间的垫层可起到很好的连接固定作用;(5)垫层中的有机碳可增加异养菌的呼吸作用,消耗更多的氧气,为反硝化作用提供有利环境,同时有机碳为反硝化作用提供了足够的电子供体;(6)低渗填海区增加了溶质运移时间,避免反应时间不够导致的除氮效果不佳。(1) The cushion layer of the present utility model and its horizontally arranged quartz sand wall, in cooperation with the vertically arranged anti-seepage layer, ensure that the electron donor required for denitrification is sufficient and at the same time increase the time of nitrification and denitrification. Achieve good denitrification effect and improve nitrate removal efficiency; (2) The intervals between quartz sand walls are such that they can play a sufficient filtering role in the direction of groundwater flow, and the appropriate width can ensure the growth of microorganisms. It can also ensure that the cost will not be too high; (3) The height of the concrete anti-seepage layer ensures that it has appropriate strength and elastic modulus, effectively preventing it from cracking in later use, and is set according to the flow characteristics and tidal amplitude of the aquifer sea boundary. The anti-seepage layer spacing ensures that there are anti-seepage layers at the fresh water outlet near the low tide level and the seawater circulation inlet near the high tide level; (4) The cushion layer between the original aquifer and the blow-filled area can play a role Good connection and fixation effect; (5) The organic carbon in the cushion can increase the respiration of heterotrophic bacteria, consume more oxygen, and provide a favorable environment for denitrification. At the same time, the organic carbon provides enough for denitrification. Electron donor; (6) Low permeability reclamation area increases solute migration time to avoid poor nitrogen removal effect caused by insufficient reaction time.
附图说明Description of the drawings
图1为本实用新型的结构示意图;Figure 1 is a schematic structural diagram of the utility model;
图2为填海造陆后溶质运移的结构示意图。Figure 2 is a schematic structural diagram of solute migration after land reclamation.
具体实施方式Detailed ways
下面结合说明书附图对本实用新型技术方案做进一步说明。The technical solution of the present utility model will be further described below in conjunction with the accompanying drawings of the description.
如图1所示,本实用新型提供了一种提高硝酸盐去除效率的填海造陆系统,沿地下水流动方向依次包括原始含水层1、垫层2、吹填区3。As shown in Figure 1, the utility model provides a land reclamation system that improves nitrate removal efficiency. It includes an original aquifer 1, a cushion layer 2, and a reclamation area 3 along the direction of groundwater flow.
垫层2包括人工卵石层201和填充于人工卵石层内的有机碳颗粒202,在人工卵石层201内沿横向间隔设置有多个石英砂墙203。石英砂墙的宽度为1.5~2m;相邻两个石英砂墙的横向间距为5~10m。The cushion layer 2 includes an artificial pebble layer 201 and organic carbon particles 202 filled in the artificial pebble layer. A plurality of quartz sand walls 203 are arranged at transverse intervals in the artificial pebble layer 201. The width of the quartz sand wall is 1.5~2m; the lateral spacing between two adjacent quartz sand walls is 5~10m.
垫层采用粒径不大于0.1m的人造卵石201,卵石间空隙填充有机碳颗粒202,垫层厚度在0.5~1m。有机碳颗粒为反硝化作用提供了电子供体,低渗透填海区域保证反应能有足够的时间,且填海造陆的成本较小,故经济性好。首先在原始含水层1上方铺设小粒径人造卵石201,起到支撑和扩散应力的作用。在人造卵石间填满有机碳颗粒202,反硝化菌为异养型兼性厌氧菌,在厌氧条件下以NOx-N为电子受体,以有机碳为电子供体。在垫层里添加石英砂,石英砂比表面积大,有利于反硝化菌的生长,石英砂还能起到过滤地下水的作用。由于在该处地下水流动方向近乎水平,所以石英砂墙垂直分布,既能在地下水流动过程中起到很好的过滤作用,也能节省用材。石英砂墙为反硝化菌提供生长空间并且过滤地下水。The cushion layer uses artificial pebbles 201 with a particle size not larger than 0.1m. The gaps between the pebbles are filled with organic carbon particles 202. The thickness of the cushion layer is 0.5-1m. Organic carbon particles provide electron donors for denitrification. The low-permeability reclamation area ensures sufficient time for the reaction, and the cost of reclamation and land reclamation is small, so the economy is good. First, small-size artificial pebbles 201 are laid above the original aquifer 1 to support and diffuse stress. Organic carbon particles 202 are filled between the artificial pebbles. The denitrifying bacteria are heterotrophic facultative anaerobic bacteria that use NOx-N as the electron acceptor and organic carbon as the electron donor under anaerobic conditions. Add quartz sand to the cushion. Quartz sand has a large specific surface area, which is conducive to the growth of denitrifying bacteria. Quartz sand can also filter groundwater. Since the flow direction of groundwater here is almost horizontal, the quartz sand walls are distributed vertically, which not only plays a good filtering role in the flow of groundwater, but also saves materials. Quartz sand walls provide growth space for denitrifying bacteria and filter groundwater.
吹填区3包括沙层302,以及沿沙层纵向间隔分布于砂层内的防渗层301,防渗层可降低水流流速,使硝酸盐在含水层中的停留时间更长,从而提高反硝化作用。防渗层的高度为0.6~1.2m;相邻两个防渗层之间的纵向间距为2~2.5m。吹填区的制备过程为:吹填区3为低渗透区,可以利用挖沙船将当地海底的沙水一起吹到目标圈内,用打桩船打桩固边,用夯实机多次压实,采砂船将沙子运到划分好的的填海区域,铺设一层沙后加一层防渗层。吹填区3的渗透系数要小于原始含水层1。The blowing and filling area 3 includes a sand layer 302 and an anti-seepage layer 301 distributed longitudinally along the sand layer in the sand layer. The anti-seepage layer can reduce the water flow rate and make the nitrate stay in the aquifer for a longer period of time, thus increasing the reaction rate. Nitrification. The height of the anti-seepage layer is 0.6~1.2m; the longitudinal spacing between two adjacent anti-seepage layers is 2~2.5m. The preparation process of the blowing and reclamation area is: the blowing and reclamation area 3 is a low permeability area. Sand dredgers can be used to blow the sand and water from the local seabed into the target circle, piling ships can be used to drive piles to fix the edges, and tamping machines can be used to compact them multiple times. The sand ship transports the sand to the designated reclamation area, lays a layer of sand and then adds an anti-seepage layer. The permeability coefficient of the reclamation area 3 is smaller than that of the original aquifer 1.
工作过程:work process:
如图2所示,在海洋驱动力潮10的作用下,海水入侵被分为上部盐水羽4,下部盐水楔5,上盐水羽4又被称为潮间带,是生物化学活动较强烈的区域,上盐水羽4和下部盐水楔5之间为淡水排出通道。潮汐10波动会将溶解性有机碳、氧气6带入上盐水羽4,溶解性有机碳和氧气6发生呼吸作用,消耗氧气。微生物反硝化过程就是在无氧或低氧条件下,将硝酸盐和亚硝酸盐还原成气态氮8的过程,在好氧条件下,反硝化菌生长速率慢,垫层2内添加的有机碳202供应有利于氧气的消耗,为反硝化菌提供有利的无氧条件。石英砂墙203由细小的石英砂颗粒组成,具有巨大的比表面积,可以为微生物提供良好的吸附和生长环境,由此形成的微生物膜可以有效截留和去除从内陆来的硝酸盐7。硝酸盐7在地下淡水的携带下继续向海移动到填海区,此时的地下水流向由水平转为斜上方向海水-含水层边界移动,纵向布置的混凝土防渗层301降低了地下水的流速,增加了硝酸盐的滞留时间,提高反硝化效率。As shown in Figure 2, under the action of the ocean driving force tide 10, the seawater intrusion is divided into an upper saltwater plume 4 and a lower saltwater wedge 5. The upper saltwater plume 4 is also called the intertidal zone, which is an area with strong biochemical activities. area, between the upper salt water plume 4 and the lower salt water wedge 5 is the fresh water discharge channel. Tidal fluctuations will bring dissolved organic carbon and oxygen into the upper salt water plume, and the dissolved organic carbon and oxygen will respire, consuming oxygen. The microbial denitrification process is the process of reducing nitrate and nitrite into gaseous nitrogen 8 under anaerobic or low-oxygen conditions. Under aerobic conditions, the growth rate of denitrifying bacteria is slow, and the organic carbon added in the cushion 2 The supply of 202 is conducive to the consumption of oxygen and provides favorable anaerobic conditions for denitrifying bacteria. The quartz sand wall 203 is composed of fine quartz sand particles and has a huge specific surface area, which can provide a good adsorption and growth environment for microorganisms. The resulting microbial film can effectively intercept and remove nitrates coming from the inland 7 . Nitrate 7 continues to move seaward to the reclamation area, carried by underground fresh water. At this time, the groundwater flow direction changes from horizontal to obliquely upward and moves toward the seawater-aquifer boundary. The vertically arranged concrete anti-seepage layer 301 reduces the flow rate of groundwater. The retention time of nitrate is increased and the denitrification efficiency is improved.
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