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CN219929704U - Double-grounding-electrode multi-high-voltage and low-temperature plasma pesticide wastewater treatment device - Google Patents

Double-grounding-electrode multi-high-voltage and low-temperature plasma pesticide wastewater treatment device Download PDF

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CN219929704U
CN219929704U CN202320730665.2U CN202320730665U CN219929704U CN 219929704 U CN219929704 U CN 219929704U CN 202320730665 U CN202320730665 U CN 202320730665U CN 219929704 U CN219929704 U CN 219929704U
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temperature plasma
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medium
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张静
刘宪廷
张丝雨
沈欣军
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Shenyang University of Technology
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Shenyang University of Technology
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Abstract

The utility model provides a double-grounding-electrode high-voltage extremely-low-temperature plasma pesticide wastewater treatment device, which comprises; a reactor housing; the internal electrode medium cylinder is arranged in the reactor shell and is connected with the reactor shell; the inner grounding electrode is inserted into the inner grounding electrode medium cylinder and connected with the grounding electrode; the high-voltage electrode medium cylinder is connected with the reactor shell; each high-voltage electrode is inserted into the high-voltage electrode medium barrel and connected with the high-voltage electrode medium barrel; the external grounding electrode is arranged on the outer side of the reactor shell and is connected with the reactor shell; the spraying device is connected with the upper end of the reactor shell; the circulating device is arranged between the reactor shell and the spraying device and is respectively connected with the reactor shell and the spraying device through connecting pipelines. The utility model increases the volume and the output power of the low-temperature plasma reactor by arranging the internal grounding electrode, the plurality of high-voltage electrodes and the external grounding electrode, thereby increasing the degradation capability to pesticide wastewater.

Description

一种双接地极多高压极低温等离子体农药废水处理装置A double grounded pole multi-high voltage and extremely low temperature plasma pesticide wastewater treatment device

技术领域Technical field

本实用新型属于废水处理设备技术领域,尤其涉及一种双接地极多高压极低温等离子体农药废水处理装置。The utility model belongs to the technical field of wastewater treatment equipment, and particularly relates to a double grounded pole multi-high voltage and extremely low temperature plasma pesticide wastewater treatment device.

背景技术Background technique

清洁的水对人类生存乃至整个生态系统都起着至关重要的作用,但农药在水中的残留严重的影响了水的质量,令人担忧。人类长期饮用含有农药的水后会导致农药模拟人体激素,降低人体免疫力,破坏激素平衡,引发生殖相关问题,造成致癌影响,并降低智力,特别是对处于身体发育阶段的儿童。与水接触的等离子体放电是一种很有前途的新技术,因为它能产生广泛的氧化物质。Clean water plays a vital role in human survival and even the entire ecosystem, but pesticide residues in water seriously affect the quality of water, which is worrying. Long-term drinking of water containing pesticides will cause pesticides to simulate human hormones, reduce human immunity, disrupt hormone balance, cause reproductive-related problems, cause carcinogenic effects, and reduce intelligence, especially for children in the physical development stage. Plasma discharge in contact with water is a promising new technology because it can produce a wide range of oxidizing species.

传统的农药废水处理装置所具有的放电间隙小,使得低温等离子体反应器体积小,输出功率小和能量利用率低。The traditional pesticide wastewater treatment device has a small discharge gap, which makes the low-temperature plasma reactor small in size, low in output power and low in energy utilization.

为此,针对上述的技术问题,有必要研究一种双接地极多高压极低温等离子体农药废水处理装置。For this reason, in view of the above technical problems, it is necessary to study a double grounded pole high-pressure and extremely low-temperature plasma pesticide wastewater treatment device.

实用新型内容Utility model content

本实用新型的目的是提供一种双接地极多高压极低温等离子体农药废水处理装置,内接地极-多个高压电极-外接地极的排列能够增大反应器内接地极和高压电极之间的放电间隙,以解决现有技术中低温等离子体反应器产生等离子体的体积小,输出功率小和能量利用率低的技术问题。The purpose of this utility model is to provide a double grounded pole multi-high voltage and extremely low temperature plasma pesticide wastewater treatment device. The arrangement of the inner ground pole - multiple high voltage electrodes - the external ground pole can increase the distance between the ground pole and the high voltage electrode in the reactor. The discharge gap is used to solve the technical problems in the existing technology that the plasma generated by the low-temperature plasma reactor is small, the output power is small, and the energy utilization rate is low.

本实用新型提供了一种双接地极多高压极低温等离子体农药废水处理装置,包括低温等离子体反应器、喷雾装置和循环装置,低温等离子体反应器壳体;内接地极介质筒,设于低温等离子体反应器壳体内,并与低温等离子体反应器壳体相连接;内接地极,插接于内接地极介质筒内部,并与接地极相连接;高压电极介质筒,多个高压电极介质筒设置在内接地极介质筒与低温等离子体反应器壳体之间,并且与低温等离子体反应器壳体相连接;高压电极,每个高压电极插接于高压电极介质筒的内部,并且与高压电极介质筒相连接;外接地极,设置在低温等离子体反应器壳体的外侧,并与低温等离子体反应器壳体相连接;喷雾装置,设置于靠近低温等离子体反应器壳体的一侧,并与低温等离子体反应器壳体的上端相连接;循环装置,设置于低温等离子体反应器壳体与喷雾装置之间,并通过连接管路分别与低温等离子体反应器壳体、喷雾装置相连接。The utility model provides a double-grounded multi-high-pressure and extremely low-temperature plasma pesticide wastewater treatment device, which includes a low-temperature plasma reactor, a spray device and a circulation device, a low-temperature plasma reactor shell; an inner ground-pole dielectric cylinder, located in Inside the low-temperature plasma reactor shell and connected to the low-temperature plasma reactor shell; the inner ground electrode is inserted into the inner ground electrode dielectric cylinder and connected to the ground electrode; the high-voltage electrode dielectric cylinder contains multiple high-voltage electrodes The dielectric cylinder is arranged between the inner ground electrode dielectric cylinder and the low-temperature plasma reactor shell, and is connected to the low-temperature plasma reactor shell; high-voltage electrodes, each high-voltage electrode is plugged into the interior of the high-voltage electrode dielectric cylinder, and It is connected to the high-voltage electrode dielectric cylinder; the external ground electrode is arranged outside the low-temperature plasma reactor shell and connected to the low-temperature plasma reactor shell; the spray device is arranged close to the low-temperature plasma reactor shell. One side is connected to the upper end of the low-temperature plasma reactor shell; the circulation device is arranged between the low-temperature plasma reactor shell and the spray device, and is connected to the low-temperature plasma reactor shell and the spray device through connecting pipes. Spray device is connected.

可选地,低温等离子体反应器壳体包括:底座,内部设有第一空腔;法兰,设置在底座的顶部,并与底座的上表面相连接;外介质,设置在法兰的上部,并与法兰相连接,外介质内部设有第二空腔;第一卡套座,设置在法兰的中部,并与法兰相连接,且连通第一空腔和第二空腔;第二卡套座,设置在第一卡套座与外介质之间,并与法兰相连接,且连通第一空腔和第二空腔,第二卡套座的数量与高压电极介质筒的数量相同;低温等离子体反应器出水口,设于法兰上,并靠近第二卡套座。Optionally, the low-temperature plasma reactor shell includes: a base with a first cavity inside; a flange, which is disposed on the top of the base and connected to the upper surface of the base; and an external medium, which is disposed on the upper part of the flange. , and is connected to the flange, and a second cavity is provided inside the external medium; the first ferrule seat is arranged in the middle of the flange, is connected to the flange, and communicates with the first cavity and the second cavity; The second ferrule holder is arranged between the first ferrule holder and the external medium, is connected to the flange, and communicates with the first cavity and the second cavity. The number of the second ferrule holder is determined by the number of the high-voltage electrode dielectric cylinder. The number is the same; the water outlet of the low-temperature plasma reactor is located on the flange and is close to the second ferrule seat.

可选地,还包括:填料层,设置于外介质的内部,并与外介质相连接。Optionally, it also includes: a filler layer, which is arranged inside the outer medium and connected with the outer medium.

可选地,内接地极介质筒包括:第一卡套,设置于内接地极介质筒的外表面,并与第一卡套座相适配。Optionally, the inner ground electrode dielectric cylinder includes: a first ferrule, which is disposed on the outer surface of the inner ground electrode dielectric cylinder and is adapted to the first ferrule holder.

可选地,高压电极介质筒包括:第二卡套,设置于高压电极介质筒的外表面,并与第二卡套座相适配。Optionally, the high-voltage electrode dielectric cylinder includes: a second ferrule, which is disposed on the outer surface of the high-voltage electrode dielectric cylinder and is adapted to the second ferrule holder.

可选地,喷雾装置包括:装置主体,设置于靠近外介质的一侧;喷头,设置于外介质与装置主体之间,并与外介质的上端相连接;喷雾装置进水口,设置于装置主体靠近循环装置的侧面,并通过连接管路与循环装置相连接。Optionally, the spray device includes: a device body, located on the side close to the external medium; a nozzle, located between the external medium and the device body, and connected to the upper end of the external medium; and a spray device water inlet, located on the device body. Close to the side of the circulation device and connected to the circulation device through connecting pipes.

可选地,循环装置包括:循环装置主体;循环装置进水口,设置于循环装置主体的侧面,并通过连接管路与低温等离子体反应器出水口相连接;循环装置出水口,与循环装置进水口相邻设置,并通过连接管路与喷雾装置进水口相连接。Optionally, the circulation device includes: a circulation device main body; a circulation device water inlet, which is disposed on the side of the circulation device body and is connected to the low-temperature plasma reactor water outlet through a connecting pipe; and a circulation device water outlet, which is connected to the circulation device inlet. The water inlets are arranged adjacent to each other and are connected to the water inlet of the spray device through connecting pipes.

可选地,高压电极通过并联连接到电源上。Optionally, the high-voltage electrodes are connected in parallel to the power supply.

可选地,内接地极和外接地极通过并联连接到接地极上。Optionally, the inner ground electrode and the outer ground electrode are connected to the ground electrode in parallel.

相较于现有技术,本实用新型提供了一种双接地极多高压极低温等离子体农药废水处理装置,本实用新型中的低温等离子体反应器形成了内接地极-多个高压电极-外接地极的排列,增加了低温等离子体反应器中等离子体的产生空间,进而增加低温等离子体反应器的体积,内接地极-多个高压电极-外接地极的排列增加了反应器放电的稳定性,进而增加了反应器的输出功率和能量利用率,这样更有利于在低温等离子体反应器中产生OH-、O2-、H+活性离子和O3、H2O2活性分子,这些活性离子和活性分子具有很强的氧化性,伴有喷雾装置和填料的设置即增加了自由基与废水的接触比表面积和接触时间,进而通过这些活性离子和活性分子的强氧化性降解污染物,增加了对农药废水的降解能力。Compared with the existing technology, this utility model provides a double grounding pole multi-high voltage and extremely low temperature plasma pesticide wastewater treatment device. The low temperature plasma reactor in the utility model forms an internal grounding pole - multiple high voltage electrodes - an external connection. The arrangement of the ground electrode increases the plasma generation space in the low-temperature plasma reactor, thereby increasing the volume of the low-temperature plasma reactor. The arrangement of the inner ground electrode - multiple high-voltage electrodes - the external ground electrode increases the stability of the reactor discharge. properties, thereby increasing the output power and energy utilization of the reactor, which is more conducive to the production of OH - , O 2- , H + active ions and O 3 , H 2 O 2 active molecules in the low-temperature plasma reactor. Active ions and active molecules have strong oxidizing properties. The setting of spray devices and fillers increases the contact surface area and contact time between free radicals and wastewater, thereby degrading pollutants through the strong oxidation of these active ions and active molecules. , increasing the degradation ability of pesticide wastewater.

附图说明Description of the drawings

通过参考附图阅读下文的详细描述,本实用新型示例性实施方式的上述以及其他目的、特征和优点将变得易于理解。在附图中,以示例性而非限制性的方式示出了本实用新型的若干实施方式,相同或对应的标号表示相同或对应的部分,其中:The above and other objects, features and advantages of exemplary embodiments of the present invention will become readily understood by reading the following detailed description with reference to the accompanying drawings. In the drawings, several embodiments of the present invention are shown in an illustrative and non-restrictive manner, and the same or corresponding reference numerals represent the same or corresponding parts, wherein:

图1为本实用新型的双接地极多高压极低温等离子体农药废水处理装置的结构示意图;Figure 1 is a schematic structural diagram of the utility model's double grounded multi-pole high-pressure and extremely low-temperature plasma pesticide wastewater treatment device;

图2为本实用新型的双接地极多高压极低温等离子体农药废水处理装置的主视示意图;Figure 2 is a schematic front view of the double-grounded multi-pole high-pressure and extremely low-temperature plasma pesticide wastewater treatment device of the present invention;

图3为本实用新型的双接地极多高压极低温等离子体农药废水处理装置的俯视示意图;Figure 3 is a schematic top view of the utility model's double-grounded multi-pole high-pressure and extremely low-temperature plasma pesticide wastewater treatment device;

图4为本实用新型的双接地极多高压极低温等离子体农药废水处理装置中内接地极和内接地介质筒的结构示意图;Figure 4 is a schematic structural diagram of the inner ground electrode and the inner ground dielectric cylinder in the double ground pole multi-high voltage and extremely low temperature plasma pesticide wastewater treatment device of the present invention;

图5为本实用新型的双接地极多高压极低温等离子体农药废水处理装置中高压电极和高压电极介质筒的结构示意图;Figure 5 is a schematic structural diagram of the high-voltage electrode and the high-voltage electrode dielectric cylinder in the double-grounded multi-high-voltage and extremely low-temperature plasma pesticide wastewater treatment device of the present invention;

图6为本实用新型的双接地极多高压极低温等离子体农药废水处理装置中法兰的结构示意图。Figure 6 is a schematic structural diagram of the flange in the double grounded multi-pole high-pressure and extremely low-temperature plasma pesticide wastewater treatment device of the present invention.

附图标号说明:Explanation of reference numbers:

1、低温等离子体反应器;2、喷雾装置;3、循环装置;4、接地极;5、底座;6、内接地极介质筒;7、内接地极;8、低温等离子体反应器出水口;9、高压电极;10、法兰;11、高压电极介质筒;12、外接地极;13、填料层;14、喷头;15、喷雾装置进水口;16、循环装置进水口;17、循环装置出水口;18、电源;19、第一卡套;20、第二卡套、21、外介质;22、出口;23、第一卡套座;24、第二卡套座;25、固定孔。1. Low-temperature plasma reactor; 2. Spray device; 3. Circulation device; 4. Ground electrode; 5. Base; 6. Internal ground electrode dielectric cylinder; 7. Internal ground electrode; 8. Water outlet of low-temperature plasma reactor ; 9. High-voltage electrode; 10. Flange; 11. High-voltage electrode dielectric cylinder; 12. External ground electrode; 13. Filling layer; 14. Nozzle; 15. Water inlet of spray device; 16. Water inlet of circulation device; 17. Circulation Device water outlet; 18, power supply; 19, first card sleeve; 20, second card sleeve, 21, external medium; 22, outlet; 23, first card sleeve seat; 24, second card sleeve seat; 25, fixed hole.

具体实施方式Detailed ways

下面将参照附图更详细地描述本公开的示例性实施方式。虽然附图中显示了本公开的示例性实施方式,然而应当理解,可以以各种形式实现本公开而不应被这里阐述的实施方式所限制。相反,提供这些实施方式是为了能够更透彻地理解本公开,并且能够将本公开的范围完整的传达给本领域的技术人员。若未特别指明,实施例中所用的技术手段为本领域技术人员所熟知的常规手段。Exemplary embodiments of the present disclosure will be described in more detail below with reference to the accompanying drawings. Although exemplary embodiments of the present disclosure are shown in the drawings, it should be understood that the disclosure may be embodied in various forms and should not be limited to the embodiments set forth herein. Rather, these embodiments are provided to provide a thorough understanding of the disclosure, and to fully convey the scope of the disclosure to those skilled in the art. Unless otherwise specified, the technical means used in the examples are conventional means well known to those skilled in the art.

需要注意的是,除非另有说明,本实用新型使用的技术术语或者科学术语应当为本实用新型所属领域技术人员所理解的通常意义。在本文中,诸如“第一”和“第二”等之类的关系术语仅仅用来将一个实体或者操作与另一个实体或操作区分开来,而不一定要求或者暗示这些实体或操作之间存在任何这种实际的关系或者顺序。术语“连接”、“相连”等术语应作广义理解,例如,可以是固定连接,也可以是可拆卸连接,或成一体;可以是机械连接,也可以是电连接;可以是直接连接,也可以是通过中间媒介间接相连。术语“包括”、“包含”或者其任何其他变体意在涵盖非排他性的包含,从而使得包括一系列要素的过程、方法、物品或者设备不仅包括那些要素,而且还包括没有明确列出的其他要素,或者是还包括为这种过程、方法、物品或者设备所固有的要素。在没有更多限制的情况下,由语句“包括……”限定的要素,并不排除在包括所述要素的过程、方法、物品或者设备中还存在另外的相同要素。It should be noted that, unless otherwise stated, the technical terms or scientific terms used in the present invention should have the usual meanings understood by those skilled in the art to which the present invention belongs. In this document, relational terms such as "first" and "second" are merely used to distinguish one entity or operation from another entity or operation and do not necessarily require or imply that there is a relationship between these entities or operations. There is no such actual relationship or sequence. The terms "connection" and "connected" should be understood in a broad sense. For example, it can be a fixed connection, a detachable connection, or an integrated connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or a direct connection. It can be indirectly connected through an intermediary. The terms "comprises," "comprises," or any other variation thereof are intended to cover a non-exclusive inclusion such that a process, method, article or apparatus including a list of elements includes not only those elements but also others not expressly listed elements, or elements inherent to such process, method, article or equipment. Without further limitation, an element defined by the statement "comprising..." does not exclude the presence of additional identical elements in a process, method, article, or device that includes the stated element.

本实用新型提供了一种双接地极多高压极低温等离子体农药废水处理装置,包括低温等离子体反应器1、喷雾装置2和循环装置3,反应器壳体;内接地极介质筒6,设于反应器壳体内,并与反应器壳体相连接;内接地极7,插接于内接地极介质筒6内部,并与内接地极7相连接;高压电极介质筒11,多个高压电极介质筒11设置在内接地极介质筒6与反应器壳体之间,并且与反应器壳体相连接;高压电极9,每个高压电极9插接于高压电极介质筒11的内部,并且与高压电极介质筒11相连接;外接地极12,设置在反应器壳体的外侧,并与反应器壳体相连接;喷雾装置2,设置于靠近反应器壳体的一侧,并与反应器壳体的上端相连接;循环装置3,设置于反应器壳体与喷雾装置2之间,并通过连接管路分别与反应器壳体、喷雾装置2相连接。The utility model provides a double grounded pole multi-high-pressure and extremely low-temperature plasma pesticide wastewater treatment device, which includes a low-temperature plasma reactor 1, a spray device 2 and a circulation device 3, a reactor shell; an inner grounded pole medium cylinder 6, in the reactor shell and connected to the reactor shell; the inner ground electrode 7 is inserted into the inner ground electrode dielectric cylinder 6 and connected to the inner ground electrode 7; the high-voltage electrode dielectric cylinder 11 has multiple high-voltage electrodes The dielectric cylinder 11 is arranged between the inner ground electrode dielectric cylinder 6 and the reactor shell, and is connected to the reactor shell; high-voltage electrodes 9, each high-voltage electrode 9 is plugged into the interior of the high-voltage electrode dielectric cylinder 11, and is connected to the reactor shell. The high-voltage electrode dielectric cylinder 11 is connected; the external ground electrode 12 is arranged outside the reactor shell and connected to the reactor shell; the spray device 2 is arranged on the side close to the reactor shell and connected to the reactor shell. The upper end of the shell is connected; the circulation device 3 is arranged between the reactor shell and the spray device 2, and is connected to the reactor shell and the spray device 2 through connecting pipelines.

本实施例中的低温等离子体反应器1形成了内接地极7-多个高压电极9-外接地极12的排列,增加了低温等离子体反应器1中等离子体的产生空间,进而增加低温等离子体反应器的体积,多个电极的排列增加了低温等离子体反应器1放电的稳定性,进而增加了低温等离子体反应器1的输出功率和能量利用率,这样更有利于在低温等离子体反应器中产生OH-、O2-、H+活性离子和O3、H2O2活性分子,这些活性离子和活性分子具有很强的氧化性,伴有喷雾装置2和填料层13的设置即增加了自由基与废水的接触比表面积和接触时间,进而通过这些活性离子和活性分子的强氧化性降解污染物,增加了对农药废水的降解能力。The low-temperature plasma reactor 1 in this embodiment forms an arrangement of an internal ground electrode 7 - a plurality of high-voltage electrodes 9 - an external ground electrode 12, which increases the plasma generation space in the low-temperature plasma reactor 1, thereby increasing the number of low-temperature plasmas. The volume of the reactor and the arrangement of multiple electrodes increase the discharge stability of the low-temperature plasma reactor 1, thereby increasing the output power and energy utilization of the low-temperature plasma reactor 1, which is more conducive to low-temperature plasma reactions. OH - , O 2- , H + active ions and O 3 , H 2 O 2 active molecules are generated in the device. These active ions and active molecules have strong oxidizing properties. With the setting of the spray device 2 and the packing layer 13, that is It increases the contact specific surface area and contact time between free radicals and wastewater, thereby degrading pollutants through the strong oxidation of these active ions and active molecules, and increasing the degradation ability of pesticide wastewater.

示例性地,喷雾装置2里面装有废水,通过喷头14均匀的进入到低温等离子体反应器1中。通过喷雾的形式能够让废水变成细小雾滴喷出,均匀的与低温等离子体反应器1内产生的带电粒子和紫外光等进行反应,并能增大反应接触的比表面积,更均匀地接受等离子体的电子轰击。喷入的小雾滴会通过填料层13,填料层13的加入不仅提高了活性粒子与废水中污染物分子的接触比表面积,还将废水中的污染物分子细化,使传质效果和净化能力都大大提高。填料层13在等离子体区发生极化,导致电场增强,有利于高能电子的产生。填料层13的加入还能抵抗水质波动,保证水质稳定,为废水的降解提供吸附作用,增加废水的降解效率。低温等离子体反应器1通过产生大量的离子、高能电子、激发态原子或分子等活性粒子降解水中的农药污染物,并且活化填料层13中吸附的污染物。For example, the spray device 2 is filled with wastewater, which evenly enters the low-temperature plasma reactor 1 through the nozzle 14 . Through the form of spray, the wastewater can be sprayed into fine droplets, which can evenly react with the charged particles and ultraviolet light generated in the low-temperature plasma reactor 1, and can increase the specific surface area of the reaction contact and receive it more evenly. Electron bombardment of plasma. The sprayed small mist droplets will pass through the filler layer 13. The addition of the filler layer 13 not only increases the contact surface area between the active particles and the pollutant molecules in the wastewater, but also refines the pollutant molecules in the wastewater, improving the mass transfer effect and purification. Abilities are greatly improved. The filler layer 13 is polarized in the plasma region, resulting in an enhanced electric field, which is conducive to the generation of high-energy electrons. The addition of the filler layer 13 can also resist water quality fluctuations, ensure stable water quality, provide adsorption for the degradation of wastewater, and increase the degradation efficiency of wastewater. The low-temperature plasma reactor 1 degrades pesticide pollutants in the water by generating a large number of active particles such as ions, high-energy electrons, excited atoms or molecules, and activates the adsorbed pollutants in the filler layer 13 .

示例性地,内接地极7是螺旋状、网状或直线状中的任一种,本实用新型选用螺旋状作为内接地极7,螺旋状的内接地极7的设置能够增加内接地极7介质筒在空气中的暴露面积,进而增加低温等离子体反应器1中的功率因数和放电功率,增加臭氧等自由基的产生量。内接地极7的材质是铜丝、不锈钢丝、镍铬合金丝中的任一种。内接地极介质筒6是玻璃、石英或陶瓷等绝缘材料制成,内接地极7置于内接地极介质筒6内,内接地极7与内接地极介质筒6均可拆卸。Illustratively, the inner ground electrode 7 is any one of a spiral shape, a mesh shape, or a linear shape. The utility model selects a spiral shape as the inner ground electrode 7 . The arrangement of the spiral inner ground electrode 7 can increase the number of internal ground electrodes 7 The exposed area of the dielectric cylinder in the air further increases the power factor and discharge power in the low-temperature plasma reactor 1, and increases the production of free radicals such as ozone. The material of the inner ground electrode 7 is any one of copper wire, stainless steel wire, and nickel-chromium alloy wire. The inner ground electrode dielectric cylinder 6 is made of insulating materials such as glass, quartz or ceramics. The inner ground electrode 7 is placed in the inner ground electrode dielectric cylinder 6. Both the inner ground electrode 7 and the inner ground electrode dielectric cylinder 6 are detachable.

示例性地,外接地极12是螺旋状、网状、或铝箔片状中的任一种,外接地极12材质是铜丝、不锈钢丝、镍铬合金丝种的任一种。外接地极12紧密的包裹在外介质21上,紧密包裹一圈。外介质21是玻璃、石英或陶瓷中的任一种,即外介质21采用绝缘材料制成,且外介质21为可拆卸结构。内接地极7和外接地极12同时存在,进而增加低温等离子体反应器1内的放电区域,进而增加放电能力,增大反应的体积。For example, the external ground electrode 12 is in the shape of a spiral, a mesh, or an aluminum foil sheet, and the material of the external ground electrode 12 is any type of copper wire, stainless steel wire, or nickel-chromium alloy wire. The external ground electrode 12 is tightly wrapped around the outer medium 21 in a tight circle. The external medium 21 is any one of glass, quartz or ceramic, that is, the external medium 21 is made of insulating material, and the external medium 21 has a detachable structure. The inner ground electrode 7 and the outer ground electrode 12 exist at the same time, thereby increasing the discharge area in the low-temperature plasma reactor 1, thereby increasing the discharge capacity and increasing the volume of the reaction.

示例性地,高压电极9是螺旋状、网状或直线状中的任一种,本实用新型选用直线状作为高压电极9,直线状高压电极9的设置增加了其与内接地极介质筒6和外介质21之间放电气隙的均匀度。Illustratively, the high-voltage electrode 9 is any one of a spiral shape, a mesh shape, or a linear shape. In the present invention, a linear shape is selected as the high-voltage electrode 9. The arrangement of the linear high-voltage electrode 9 increases the distance between the linear high-voltage electrode 9 and the inner ground electrode dielectric cylinder 6. and the uniformity of the discharge gap between the external medium 21 and the external medium 21 .

示例性地,高压电极9材质是铜丝、不锈钢丝、镍铬合金丝中的任一种。For example, the material of the high-voltage electrode 9 is any one of copper wire, stainless steel wire, and nichrome wire.

示例性地,本实施例对高压电极9的个数不做具体限定,本实施例由四个高压电极9并联组成,四个高压电极9呈同心圆排列,并联连接到电源18上,高压电极9个数的增加增大了低温等离子体反应器1的输出功率和放电能力,进而增大了对废水的降解能力。Illustratively, this embodiment does not specifically limit the number of high-voltage electrodes 9. This embodiment consists of four high-voltage electrodes 9 connected in parallel. The four high-voltage electrodes 9 are arranged in concentric circles and are connected in parallel to the power supply 18. The high-voltage electrodes 9 The increase in the number of 9 increases the output power and discharge capacity of the low-temperature plasma reactor 1, thereby increasing the degradation ability of wastewater.

示例性地,以内接地极7作为圆心,将四个高压电极9按同心圆排列安装到低温等离子体反应器1中,外介质21也以内接地极7为圆心设置,且内接地极7和高压电极9均可拆卸。形成内接地极7-多个高压电极9-外接地极12的排列。同样地,按照相同的排列方式进行延展以达到增大低温等离子体反应器1体积的目的,增大低温等离子体反应器1的输出功率和对废水的降解能力,增大对废水的处理量。在反应降解的过程中,使低温等离子体反应器1产生更多的自由基、高能电子和紫外光,进而以达到增大降解污染物的效果。For example, with the inner ground electrode 7 as the center of the circle, four high-voltage electrodes 9 are arranged in concentric circles and installed in the low-temperature plasma reactor 1. The external medium 21 is also arranged with the inner ground electrode 7 as the center of the circle, and the inner ground electrode 7 and the high voltage The electrodes 9 are all removable. An arrangement of the inner ground electrode 7 - the plurality of high voltage electrodes 9 - the external ground electrode 12 is formed. Similarly, the extension is carried out in the same arrangement to increase the volume of the low-temperature plasma reactor 1, increase the output power of the low-temperature plasma reactor 1 and its ability to degrade wastewater, and increase the treatment capacity of wastewater. During the reaction and degradation process, the low-temperature plasma reactor 1 generates more free radicals, high-energy electrons and ultraviolet light, thereby increasing the effect of degrading pollutants.

在一种可能的实施例中,低温等离子体反应器1壳体包括:底座5,内部设有第一空腔;法兰10,设置在底座5的顶部,并与底座5的上表面相连接;外介质21,设置在法兰10的上部,并与法兰10相连接,外介质21内部设有第二空腔;第一卡套座23,设置在法兰10的中部,并与法兰10相连接,且连通第一空腔和第二空腔;第二卡套座24,设置在第一卡套座23与外介质21之间,并与法兰10相连接,且连通第一空腔和第二空腔,第二卡套座24的数量与高压电极介质筒11的数量相同;低温等离子体反应器出水口8,设于法兰10上,并靠近第二卡套座24。In a possible embodiment, the low-temperature plasma reactor 1 shell includes: a base 5 with a first cavity inside; a flange 10 disposed on the top of the base 5 and connected to the upper surface of the base 5 ; The external medium 21 is arranged on the upper part of the flange 10 and is connected to the flange 10. A second cavity is provided inside the external medium 21; the first ferrule seat 23 is arranged in the middle of the flange 10 and is connected with the flange 10. The flange 10 is connected and communicates with the first cavity and the second cavity; the second ferrule seat 24 is arranged between the first ferrule seat 23 and the external medium 21 and is connected with the flange 10 and communicates with the second ferrule holder 24 . A cavity and a second cavity, the number of the second ferrule holders 24 is the same as the number of high-voltage electrode dielectric cylinders 11; the low-temperature plasma reactor outlet 8 is located on the flange 10 and is close to the second ferrule holder twenty four.

示例性地,内接地极7插接于内接地极介质筒6内,内接地极介质筒6顶部带有弯头,贯穿于外介质21,高压电极9插接于高压电极介质筒11内,外介质21与法兰10一体成型,外介质21通过法兰10固定于底座5上,这样设置,方便低温等离子体反应器1的拆卸。For example, the inner ground electrode 7 is plugged into the inner ground electrode dielectric cylinder 6. The top of the inner ground electrode dielectric cylinder 6 has an elbow and penetrates the outer medium 21. The high-voltage electrode 9 is plugged into the high-voltage electrode dielectric cylinder 11. The external medium 21 and the flange 10 are integrally formed, and the external medium 21 is fixed on the base 5 through the flange 10. This arrangement facilitates the disassembly of the low-temperature plasma reactor 1.

示例性地,法兰10上还设置有固定孔25,便于法兰10与底座5的上表面固定连接,使螺栓穿过固定孔25,对应地,底座5上表面也设有螺栓孔,螺栓孔与固定孔25的位置、尺寸均相互对应,使得法兰10与底座5的上表面固定连接。Exemplarily, the flange 10 is also provided with fixing holes 25 to facilitate the fixed connection between the flange 10 and the upper surface of the base 5 so that bolts can pass through the fixing holes 25. Correspondingly, the upper surface of the base 5 is also provided with bolt holes. The positions and sizes of the holes and the fixing holes 25 correspond to each other, so that the flange 10 is fixedly connected to the upper surface of the base 5 .

在一种可能的实施例中,还包括:填料层13,设置于外介质21的内部,并与外介质21相连接。In a possible embodiment, it also includes: a filler layer 13 disposed inside the outer medium 21 and connected to the outer medium 21 .

示例性地,在外介质21内部安装填料层13,能够增加废水在低温等离子体反应器1内的停留时间,增大能量利用率和废水的降解时长。For example, installing the filler layer 13 inside the outer medium 21 can increase the residence time of the wastewater in the low-temperature plasma reactor 1 and increase the energy utilization rate and the degradation time of the wastewater.

示例性地,废水通过喷头14形成了小雾滴,小雾滴进入到低温等离子体反应器1中,低温等离子体反应器1产生大量的离子、高能电子、激发态原子或分子等活性粒子,进而降解水中的农药污染物,同时进入到填料层13中,填料层13和低温等离子体协同降解废水,填料层13的加入还能抵抗水质波动,保证水质稳定,为废水的降解提供吸附作用,低温等离子体能活化填料层13中吸附的污染物,增加废水的降解效率。For example, the wastewater passes through the nozzle 14 to form small mist droplets, and the small mist droplets enter the low-temperature plasma reactor 1. The low-temperature plasma reactor 1 produces a large number of active particles such as ions, high-energy electrons, excited atoms or molecules, Then the pesticide pollutants in the water are degraded and enter the filler layer 13 at the same time. The filler layer 13 and low-temperature plasma collaboratively degrade the wastewater. The addition of the filler layer 13 can also resist water quality fluctuations, ensure stable water quality, and provide adsorption for the degradation of wastewater. Low-temperature plasma can activate pollutants adsorbed in the filler layer 13 and increase the degradation efficiency of wastewater.

示例性地,低温等离子体反应器1的填料层13上带有五个孔,进而使高压电极介质筒11和内接地极介质筒6能够穿过,这样的构型方便填料层13的拆卸。For example, the filler layer 13 of the low-temperature plasma reactor 1 is provided with five holes, allowing the high-voltage electrode dielectric cylinder 11 and the inner ground electrode dielectric cylinder 6 to pass through. This configuration facilitates the disassembly of the filler layer 13 .

在一种可能的实施例中,内接地极介质筒6包括:第一卡套19,设置于内接地极介质筒6的外表面,并与第一卡套座23相适配。In a possible embodiment, the inner ground electrode dielectric cylinder 6 includes: a first ferrule 19 , which is disposed on the outer surface of the inner ground electrode dielectric cylinder 6 and is adapted to the first ferrule holder 23 .

示例性地,第一卡套19设置在内接地极介质筒6的靠近第一空腔的一端,这样使得内接地极介质筒6在通过第一卡套19与第一卡套座23安装在法兰10上的情况下,内接地极介质筒6位于第二空腔内的部分更多,进而使得内接地极7位于第二空腔内的部分更多,有利于增加低温等离子体反应器1内等离子体的产生空间,进而有利于增强低温等离子体反应器1对于废水的降解能力。Illustratively, the first ferrule 19 is disposed at one end of the inner ground electrode dielectric cylinder 6 close to the first cavity, so that the inner ground electrode dielectric cylinder 6 is installed on the inner ground electrode dielectric cylinder 6 through the first ferrule 19 and the first ferrule seat 23 . In the case of the flange 10, more of the inner ground electrode dielectric cylinder 6 is located in the second cavity, which in turn causes more of the inner ground electrode 7 to be located in the second cavity, which is conducive to increasing the number of low-temperature plasma reactors. The plasma generation space within the reactor 1 is beneficial to enhancing the degradation ability of the low-temperature plasma reactor 1 for wastewater.

在一种可能的实施例中,高压电极9介质筒包括:第二卡套20,设置于高压电极介质筒11的外表面,并与第二卡套座24相适配。In a possible embodiment, the high-voltage electrode 9 dielectric cylinder includes: a second ferrule 20 , which is disposed on the outer surface of the high-voltage electrode dielectric cylinder 11 and is adapted to the second ferrule seat 24 .

示例性地,第二卡套20设置在内接地极介质筒6的靠近第一空腔的一端,这样使得内接地极介质筒6在通过第二卡套20与第二卡套座24安装在法兰10上的情况下,内接地极介质筒6位于第二空腔内的部分更多,进而使得内接地极7位于第二空腔内的部分更多,有利于增加低温等离子体反应器1内等离子体的产生空间,进而有利于增强低温等离子体反应器1对于废水的降解能力。Illustratively, the second ferrule 20 is disposed at one end of the inner ground electrode dielectric cylinder 6 close to the first cavity, so that the inner ground electrode dielectric cylinder 6 is installed on the inner ground electrode dielectric cylinder 6 through the second ferrule 20 and the second ferrule seat 24 . In the case of the flange 10, more of the inner ground electrode dielectric cylinder 6 is located in the second cavity, which in turn causes more of the inner ground electrode 7 to be located in the second cavity, which is conducive to increasing the number of low-temperature plasma reactors. The plasma generation space within the reactor 1 is beneficial to enhancing the degradation ability of the low-temperature plasma reactor 1 for wastewater.

在一种可能的实施例中,喷雾装置2包括:装置主体,设置于靠近外介质21的一侧;喷头14,设置于外介质21与装置主体之间,并与外介质21的上端相连接;喷雾装置2进水口,设置于装置主体靠近循环装置3的侧面,并通过连接管路与循环装置3相连接。In a possible embodiment, the spray device 2 includes: a device body, disposed on the side close to the external medium 21; a nozzle 14, disposed between the external medium 21 and the device body, and connected to the upper end of the external medium 21 ; The water inlet of the spray device 2 is located on the side of the device body close to the circulation device 3, and is connected to the circulation device 3 through a connecting pipe.

示例性地,喷头14朝向外介质21的设置于外介质21端部的中心位置,这样有利于废水从喷头14喷出后,小雾滴均匀地进入到外介质21的内部,这样有利于增加废水在低温等离子体反应器1内的接触面积,便于废水在低温等离子体反应器1内进行降解。For example, the nozzle 14 is disposed toward the center of the end of the outer medium 21 toward the outer medium 21. This is beneficial to the small mist droplets evenly entering the interior of the outer medium 21 after the wastewater is sprayed from the nozzle 14. This is beneficial to increasing the The contact area of wastewater in the low-temperature plasma reactor 1 facilitates the degradation of wastewater in the low-temperature plasma reactor 1 .

在一种可能的实施例中,循环装置3包括:循环装置主体;循环装置进水口16,设置于循环装置主体的侧面,并通过连接管路与低温等离子体反应器出水口8相连接;循环装置出水口17,与循环装置进水口16相邻设置,并通过连接管路与喷雾装置进水口15相连接。In a possible embodiment, the circulation device 3 includes: a circulation device body; a circulation device water inlet 16, which is provided on the side of the circulation device body and is connected to the low-temperature plasma reactor water outlet 8 through a connecting pipe; The device water outlet 17 is arranged adjacent to the circulation device water inlet 16 and is connected to the spray device water inlet 15 through a connecting pipeline.

示例性地,循环装置3开启,循环装置出水口17通过连接管路与喷雾装置进水口15相连通,使循环装置出水口17的出水进入喷雾装置2内,喷雾装置2内的水通过喷头14,以小雾滴的形式进入到低温等离子体反应器1内,水在低温等离子体反应器1内经过降解后,再经过低温等离子体反应器1内部法兰10上的低温等离子体反应器出水口8进入底座5的第二空腔内,最后再通过连接管路从低温等离子体反应器出水口8回到循环装置3,这样就完成了废水在双接地极多高压极低温等离子体农药废水处理装置内的循环。Illustratively, the circulation device 3 is opened, the water outlet 17 of the circulation device is connected to the water inlet 15 of the spray device through the connecting pipe, so that the water from the water outlet 17 of the circulation device enters the spray device 2, and the water in the spray device 2 passes through the nozzle 14 , enters the low-temperature plasma reactor 1 in the form of small mist droplets. After the water is degraded in the low-temperature plasma reactor 1, it then exits through the low-temperature plasma reactor on the internal flange 10 of the low-temperature plasma reactor 1. The water inlet 8 enters the second cavity of the base 5, and finally returns to the circulation device 3 from the low-temperature plasma reactor outlet 8 through the connecting pipe. In this way, the wastewater is completed in the double grounding pole. The high-pressure and ultra-low temperature plasma pesticide wastewater is Circulation within the processing unit.

示例性地,通过循环装置3的循环作用使低温等离子体反应器1对于废水的降解过程循环发生,进而达到对废水中农药污染物的降解效果。For example, the degradation process of wastewater by the low-temperature plasma reactor 1 is cyclically caused by the circulation of the circulation device 3, thereby achieving the degradation effect of pesticide pollutants in the wastewater.

在一种可能的实施例中,高压电极9通过并联连接到电源18上。In a possible embodiment, the high-voltage electrode 9 is connected to the power supply 18 in parallel.

示例性地,多个高压电极9并联在一起增加了低温等离子体反应器1的放电效应,例如电场强度和电流强度,进而增加了低温等离子体反应器1中O3等自由基的产生量。For example, multiple high-voltage electrodes 9 connected in parallel increase the discharge effect of the low-temperature plasma reactor 1 , such as the electric field intensity and current intensity, thereby increasing the production of free radicals such as O 3 in the low-temperature plasma reactor 1 .

在一种可能的实施例中,内接地极7和外接地极12通过并联连接到接地极4上。In a possible embodiment, the inner ground electrode 7 and the outer ground electrode 12 are connected to the ground electrode 4 in parallel.

示例性地,外接地极12和内接地极7通过并联的方式连接到接地极4上,双接地极的结构有利于增大低温等离子体反应器1的体积,增大输出功率,进而增大对废水的降解能力。For example, the external ground electrode 12 and the internal ground electrode 7 are connected to the ground electrode 4 in parallel. The structure of the double ground electrode is conducive to increasing the volume of the low-temperature plasma reactor 1, increasing the output power, and thus increasing the Degradation ability of wastewater.

以上所述,仅为本实用新型的具体实施方式,但本实用新型的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本实用新型揭露的技术范围内,可轻易想到变化或替换,都应涵盖在本实用新型的保护范围之内。因此,本实用新型的保护范围应以所述权利要求的保护范围为准。The above are only specific implementations of the present utility model, but the protection scope of the present utility model is not limited thereto. Any person familiar with the technical field can easily think of changes or modifications within the technical scope disclosed by the present utility model. Replacements shall be covered by the protection scope of the present utility model. Therefore, the protection scope of the present utility model should be subject to the protection scope of the claims.

Claims (9)

1. A double-grounding-electrode high-voltage extremely-low-temperature plasma pesticide wastewater treatment device comprises a low-temperature plasma reactor, a spraying device and a circulating device and is characterized in that the device comprises a plurality of high-voltage extremely-low-temperature plasma pesticide wastewater treatment devices, wherein the low-temperature plasma pesticide wastewater treatment devices are connected with the spraying device;
a reactor housing;
an internal electrode medium cylinder arranged in the reactor shell and connected with the reactor shell;
the inner grounding electrode is inserted into the medium cylinder of the inner grounding electrode and is connected with the grounding electrode;
a plurality of high-voltage electrode medium cylinders disposed between the inner electrode medium cylinder and the reactor housing and connected to the reactor housing;
each high-voltage electrode is inserted into the high-voltage electrode medium barrel and connected with the high-voltage electrode medium barrel;
the external grounding electrode is arranged on the outer side of the reactor shell and is connected with the reactor shell;
the spraying device is arranged on one side close to the reactor shell and is connected with the upper end of the reactor shell;
the circulating device is arranged between the reactor shell and the spraying device and is respectively connected with the reactor shell and the spraying device through connecting pipelines.
2. The dual-grounded extremely high-voltage extremely low-temperature plasma pesticide wastewater treatment apparatus according to claim 1, wherein the reactor housing comprises:
a first cavity is formed in the base;
the flange is arranged at the top of the base and is connected with the upper surface of the base;
the outer medium is arranged at the upper part of the flange and is connected with the flange, and a second cavity is formed in the outer medium;
the first clamping sleeve seat is arranged in the middle of the flange, is connected with the flange and is communicated with the first cavity and the second cavity;
the second clamping sleeve seats are arranged between the first clamping sleeve seats and the external medium, are connected with the flange, are communicated with the first cavity and the second cavity, and are the same as the high-voltage electrode medium cylinders in number;
and the water outlet of the low-temperature plasma reactor is arranged on the flange and is close to the second clamping sleeve seat.
3. The dual-grounded extremely high-voltage extremely low-temperature plasma pesticide wastewater treatment apparatus according to claim 2, further comprising:
the packing layer is arranged in the outer medium and is connected with the outer medium.
4. The dual-grounding-electrode multi-high-voltage extremely low-temperature plasma pesticide wastewater treatment device according to claim 2, wherein the internal grounding electrode medium cartridge comprises:
the first cutting sleeve is arranged on the outer surface of the internal electrode medium cylinder and is matched with the first cutting sleeve seat.
5. The dual-grounded extremely low-voltage plasma pesticide wastewater treatment device according to claim 2, wherein the high-voltage electrode dielectric cartridge comprises:
the second cutting sleeve is arranged on the outer surface of the high-voltage electrode medium cylinder and is matched with the second cutting sleeve seat.
6. The dual-grounded extremely high-voltage extremely low-temperature plasma pesticide wastewater treatment apparatus according to claim 2, wherein the spraying apparatus comprises:
a device body disposed on a side close to the external medium;
the spray head is arranged between the external medium and the device main body and is connected with the upper end of the external medium;
the spraying device water inlet is arranged on the side surface of the device main body, which is close to the circulating device, and is connected with the circulating device through a connecting pipeline.
7. The dual-grounded extremely high-voltage extremely low-temperature plasma pesticide wastewater treatment device according to claim 6, wherein the circulating device comprises:
a circulation device body;
the circulating device water inlet is arranged on the side surface of the circulating device main body and is connected with the low-temperature plasma reactor water outlet through a connecting pipeline;
and the water outlet of the circulating device is arranged adjacent to the water inlet of the circulating device and is connected with the water inlet of the spraying device through a connecting pipeline.
8. The dual grounding most high voltage and extremely low temperature plasma pesticide wastewater treatment device according to claim 1, wherein the high voltage electrodes are connected to a power source in parallel.
9. The dual-grounding-electrode multi-high-voltage and ultra-low-temperature plasma pesticide wastewater treatment device according to claim 1, wherein the internal grounding electrode and the external grounding electrode are connected to the grounding electrode in parallel.
CN202320730665.2U 2023-04-06 2023-04-06 Double-grounding-electrode multi-high-voltage and low-temperature plasma pesticide wastewater treatment device Expired - Fee Related CN219929704U (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202320730665.2U CN219929704U (en) 2023-04-06 2023-04-06 Double-grounding-electrode multi-high-voltage and low-temperature plasma pesticide wastewater treatment device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN202320730665.2U CN219929704U (en) 2023-04-06 2023-04-06 Double-grounding-electrode multi-high-voltage and low-temperature plasma pesticide wastewater treatment device

Publications (1)

Publication Number Publication Date
CN219929704U true CN219929704U (en) 2023-10-31

Family

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN202320730665.2U Expired - Fee Related CN219929704U (en) 2023-04-06 2023-04-06 Double-grounding-electrode multi-high-voltage and low-temperature plasma pesticide wastewater treatment device

Country Status (1)

Country Link
CN (1) CN219929704U (en)

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