CN217438095U - A cracking system for cracking polymers - Google Patents
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Abstract
Description
技术领域technical field
本实用新型涉及废弃物处理技术领域,具体是指一种实现裂解高聚物的裂解系统。The utility model relates to the technical field of waste treatment, in particular to a cracking system for realizing cracking of high polymers.
背景技术Background technique
目前国内外用于高聚物裂解的裂解反应器主要有列管式裂解反应器、流化床裂解反应器、槽式旋转裂解反应器、离心刮板成膜热裂解装置。这几种裂解反应器存在以下不足:At present, the cracking reactors used for polymer cracking at home and abroad mainly include tubular cracking reactors, fluidized bed cracking reactors, groove rotary cracking reactors, and centrifugal scraper film-forming thermal cracking devices. These cracking reactors have the following shortcomings:
采用立管式裂解反应器,石油或高聚物在裂解过程容易造成列管式裂解反应器结碳,导致裂解不完全,甚至裂解反应很难进行。Using the vertical tube cracking reactor, the petroleum or high polymer is easy to cause carbon formation in the tubular cracking reactor during the cracking process, resulting in incomplete cracking, and even the cracking reaction is difficult to carry out.
用流化床裂解反应器进行废塑料的裂解,效果不佳,由于塑料在过程会产生高粘度油状或蜡状物,使加热载体的流动性变差,影响裂解效果,还需要不断补充新的加热载体。Using a fluidized bed cracking reactor for the cracking of waste plastics is not effective. Since the plastics will produce high-viscosity oily or waxy substances in the process, the fluidity of the heating carrier will be deteriorated and the cracking effect will be affected. It is necessary to continuously replenish new ones. Heat the carrier.
国内也有用槽式旋转裂解反应器裂解废塑料,存在反应周期长,反应不完全,设备结碳,终端产物为难以处理的粘稠焦化物,二次污染污染严重,设备占地面积大。There are also trough-type rotary cracking reactors used in China to crack waste plastics. There are long reaction periods, incomplete reactions, carbon formation in equipment, and the end product is viscous coke that is difficult to handle. The secondary pollution is serious and the equipment occupies a large area.
目前比较理想废塑料裂解设备是离心刮板成膜热裂解装置,具有反应速度快,不易结碳, 100%有效转化,无二次污染,克服了前几种裂解反应器的缺点和不足,但这种裂解装置处理量小,只能在50~60公斤/小时。At present, the ideal waste plastic cracking equipment is a centrifugal scraper film-forming thermal cracking device, which has the advantages of fast reaction speed, not easy to form carbon, 100% effective conversion, no secondary pollution, and overcomes the shortcomings and deficiencies of the previous cracking reactors. This kind of cracking device has a small processing capacity, which can only be 50-60 kg/hour.
上述这些裂解反应器都不适用聚氯乙烯(PVC)的裂解处理,热裂解过程会产生氯化氢 (HCl)气体而腐蚀设备,污染环境。None of the above-mentioned cracking reactors is suitable for the cracking treatment of polyvinyl chloride (PVC), and the thermal cracking process will generate hydrogen chloride (HCl) gas, which will corrode equipment and pollute the environment.
实用新型内容Utility model content
本实用新型的目的是克服了上述现有技术的缺点,提供了一种裂解时间短、反应完全、不易结碳、无二次污染、可以大量无害化处理含氯聚合物的实现裂解高聚物的裂解系统,设备占地面积小。The purpose of this utility model is to overcome the shortcomings of the above-mentioned prior art, and to provide a cracking high polymer with short cracking time, complete reaction, not easy to form carbon, no secondary pollution, and a large amount of harmless treatment of chlorine-containing polymers. The pyrolysis system of the material is small, and the equipment occupies a small area.
为了实现上述目的,本实用新型的实现裂解高聚物的裂解系统具有如下构成:In order to achieve above-mentioned purpose, the cracking system that realizes cracking high polymer of the present invention has the following composition:
该实现裂解高聚物的裂解系统,其主要特点是,所述的裂解系统包括预处理单元和裂解单元,所述的预处理单元包括压缩式进料装置、第一挤出装置、第二挤出装置,所述的压缩式进料装置的出料口与所述的第一挤出装置的进料口相连通,所述的第一挤出装置的出料口与所述的第二挤出装置的进料口相连接,所述的裂解单元包括三个或三个以上的膜式裂解反应腔,所述的第二挤出装置的出料口与所述的裂解单元中的三个或三个以上的膜式裂解反应腔相连通。所述的第一挤出装置和第二挤出装置、均设置有第一加热元件。The main feature of the cracking system for cracking high polymers is that the cracking system includes a pretreatment unit and a cracking unit, and the pretreatment unit includes a compression feeding device, a first extrusion device, and a second extrusion device. The outlet of the compression feeding device is communicated with the inlet of the first extrusion device, and the outlet of the first extrusion device is connected to the second extrusion device. The feed port of the outlet device is connected, the cracking unit includes three or more membrane cracking reaction chambers, and the discharge port of the second extrusion device is connected to three of the cracking units. Or three or more membrane cleavage reaction chambers are connected. The first extrusion device and the second extrusion device are both provided with a first heating element.
较佳地,所述的第一挤出装置的出料口通过连接装置与所述的第二挤出装置的进料口相连接,所述的连接装置设置有圆柱形上部、圆锥形下部,所述的圆柱形上部的顶端设置的排气口,所述的圆柱形上部设置有第一连接口,所述的第一连接口与所述的第一挤出装置的出料口可滑动地密封连接,所述的圆锥形下部的底端设置有第二连接口,所述的第二连接口与所述的第二挤出装置的进料口相连通,所述的第一挤出装置和/或第二挤出装置设置有排出加热产生的废气的排气口。所述连接装置圆锥形下部设置有加热流动的膏状高聚物的第三加热元件。Preferably, the discharge port of the first extrusion device is connected with the feed port of the second extrusion device through a connecting device, and the connecting device is provided with a cylindrical upper part and a conical lower part, The top end of the cylindrical upper part is provided with an exhaust port, the cylindrical upper part is provided with a first connection port, and the first connection port and the discharge port of the first extrusion device are slidable Sealed connection, the bottom end of the conical lower part is provided with a second connection port, the second connection port is communicated with the feed port of the second extrusion device, the first extrusion device And/or the second extrusion device is provided with an exhaust port for discharging exhaust gas generated by heating. The conical lower part of the connecting device is provided with a third heating element for heating the flowing paste-like high polymer.
较佳地,所述的第一挤出装置包括第一减速机、第一联轴器、第一轴承箱和第一螺筒,所述的第一减速机、第一联轴器、第一轴承箱、第一挤出装置的进料口、第一螺筒和第一挤出装置的出料口依次相连接,所述的第二挤出装置包括第二减速机、第二联轴器、第二轴承箱和第二螺筒,所述的第二减速机、第二联轴器、第二轴承箱、第二挤出装置的进料口、第二螺筒和第二挤出装置的出料口依次相连接,所述的第一螺筒和第二螺筒内分别设置有与所述的第一轴承箱和第二轴承箱相连接的第一螺杆和第二螺杆,所述的第一螺筒和第二螺筒中均设置有排气孔。Preferably, the first extrusion device includes a first reducer, a first coupling, a first bearing housing and a first screw barrel, and the first reducer, the first coupling, the first The bearing box, the feeding port of the first extruding device, the first screw barrel and the discharging port of the first extruding device are connected in sequence, and the second extruding device includes a second reducer, a second coupling , the second bearing box and the second screw barrel, the second reducer, the second coupling, the second bearing box, the feed port of the second extrusion device, the second screw barrel and the second extrusion device The discharge ports are connected in sequence, the first screw barrel and the second screw barrel are respectively provided with a first screw and a second screw connected with the first bearing housing and the second bearing housing. Both the first screw barrel and the second screw barrel are provided with exhaust holes.
较佳地,所述的压缩式进料装置包括圆柱形上部筒体和圆柱形下部筒体,所述的圆柱形上部筒体的直径大于所述的圆柱形下部筒体的直径,所述的压缩式进料装置设置有搅拌结构,所述的搅拌结构包括搅拌轴和组合叶片,所述的组合叶片包括与所述的圆柱形上部筒体相对应的矩形叶片和与所述的圆柱形下部筒体相对应的螺旋叶片。Preferably, the compression feeding device includes a cylindrical upper cylinder and a cylindrical lower cylinder, the diameter of the cylindrical upper cylinder is larger than the diameter of the cylindrical lower cylinder, and the cylindrical upper cylinder has a diameter larger than that of the cylindrical lower cylinder. The compression feeding device is provided with a stirring structure, the stirring structure includes a stirring shaft and a combination blade, and the combination blade includes a rectangular blade corresponding to the cylindrical upper body and a cylindrical lower part The helical blade corresponding to the cylinder.
较佳地,所述的第二挤出装置的出料口通过分流头与所述的裂解单元中的三个或三个以上的膜式裂解反应腔相连通。所述的分流头包括连接弯管、壳体,所述的连接弯管一端与所述的第二挤出装置的出料口相连通,所述的连接弯管的另一端与所述的分流头的壳体的进口端部相连接,所述的壳体的进口端部设置有多孔圆板,所述的壳体的内部设置有锥芯以及围绕所述的锥芯设置的隔板,所述的隔板将所述的壳体内部空间分隔成对应于所述的膜式裂解反应腔的数目的隔室,所述的壳体的出口端部设置有对应于所述的膜式裂解反应腔的数目的排料口;所述的壳体设置有第二加热元件。Preferably, the discharge port of the second extrusion device is communicated with three or more membrane cracking reaction chambers in the cracking unit through a split head. The diverter head includes a connecting elbow and a shell, one end of the connecting elbow is communicated with the discharge port of the second extrusion device, and the other end of the connecting elbow is connected to the shunt. The inlet end of the shell of the head is connected with the inlet end of the shell, and the inlet end of the shell is provided with a porous circular plate, and the interior of the shell is provided with a cone core and a baffle plate arranged around the cone core. Described baffle divides described shell interior space into the compartment corresponding to the number of described membrane cracking reaction chamber, and the outlet end of described shell is provided with corresponding to described membrane cracking reaction. The number of discharge openings in the cavity; the casing is provided with a second heating element.
较佳地,所述的裂解单元还包括油气收集装置,所述的油气收集装置的数目对应于所述的膜式裂解反应腔的数目,所述的油气收集装置还包括与所述的膜式裂解反应腔相连接的第一油气输送支管、与所述的第一油气输送支管出气口相连接的催化吸附塔、与所述的催化吸附塔相连接的第二油气输送支管、与所述第二油气输送支管出口相连接的第一冷凝器、与所述的第一冷凝器相连接的第三油气输送支管、与所述的第三油气输送支管出口相连接的接收罐,所述的膜式裂解反应腔出气口通过第一油气输送支管与所述的催化吸附塔底部进气口相连通,所述的催化吸附塔出气口通过第二油气输送支管与所述的第一冷凝器顶部进气口相连通,所述的第一冷凝器顶部气液出口通过第三油气输送支管与所述的接收罐侧面气液进口相连通,所述的接收罐顶部出气口与燃总管相连通,所述的第一冷凝器的底部冷凝液出口与冷凝液总管连通。Preferably, the cracking unit further includes an oil and gas collection device, the number of the oil and gas collection devices corresponds to the number of the membrane cracking reaction chambers, and the oil and gas collection device also includes and the membrane type. The first oil and gas transportation branch pipe connected with the cracking reaction chamber, the catalytic adsorption tower connected with the gas outlet of the first oil and gas transportation branch pipe, the second oil and gas transportation branch pipe connected with the catalytic adsorption tower, and the The first condenser connected to the outlet of the second oil and gas delivery branch pipe, the third oil and gas delivery branch pipe connected to the first condenser, the receiving tank connected to the outlet of the third oil and gas delivery branch pipe, the membrane The air outlet of the type cracking reaction chamber is communicated with the air inlet at the bottom of the catalytic adsorption tower through the first oil and gas conveying branch pipe, and the air outlet of the catalytic adsorption tower is connected to the top of the first condenser through the second oil and gas conveying branch pipe. The gas port is communicated with each other, the gas-liquid outlet on the top of the first condenser is communicated with the gas-liquid inlet on the side of the receiving tank through the third oil and gas conveying branch pipe, and the gas outlet on the top of the receiver tank is communicated with the main combustion pipe, so The bottom condensate outlet of the first condenser is communicated with the condensate main pipe.
更佳地,所述的脱蜡炉包括脱蜡炉筒体、第四减速机、刮刀搅拌,所述的刮刀搅拌包括主轴、刮刀架、刮刀、底刮刀、底轴、高温滑动轴承,所述的刮刀架固定在主轴上,所述的刮刀悬挂在刮刀架上,所述的底刮刀装在刮刀架底部。More preferably, the dewaxing furnace includes a dewaxing furnace cylinder, a fourth reducer, and scraper stirring. The scraper stirring includes a main shaft, a scraper frame, a scraper, a bottom scraper, a bottom shaft, and a high-temperature sliding bearing. The scraper frame is fixed on the main shaft, the scraper is suspended on the scraper frame, and the bottom scraper is installed at the bottom of the scraper frame.
更佳地,所述的催化吸附塔包括上端盖、第一中间段、第二中间段、下端盖、上栅格、下栅格,所述的上端盖、第一中间段、第二中间段、下端盖,自上而下依次连接成塔体,所述的上栅格和所述的下栅格自上而下依次固定在塔体内。More preferably, the catalytic adsorption tower includes an upper end cover, a first middle section, a second middle section, a lower end cover, an upper grid, and a lower grid, the upper end cover, the first middle section, and the second middle section. and lower end caps, which are connected in sequence from top to bottom to form a tower body, and the upper grid and the lower grid are sequentially fixed in the tower body from top to bottom.
较佳地,所述的膜式裂解反应腔包括反应腔筒体、第三减速机、带鳞片搅拌,所述的带鳞片搅拌包括搅拌轴、分配盘、灯笼架、活动鳞片,所述的灯笼架固定在所述的搅拌轴上,所述的活动鳞片固定在灯笼架上,所述的活动鳞片能自由转动;所述的反应腔筒体通过设置第四加热元件自上而下分别形成第一温度区反应腔筒体、第二温度区反应腔筒体、第三温度区反应腔筒体。Preferably, the membrane-type cracking reaction chamber includes a reaction chamber cylinder, a third reducer, and agitation with scales, and the agitation with scales includes a stirring shaft, a distribution plate, a lantern frame, and movable The frame is fixed on the stirring shaft, the movable scales are fixed on the lantern frame, and the movable scales can rotate freely; the reaction chamber cylinder is formed by setting the fourth heating element from top to bottom. A temperature zone reaction chamber cylinder, a second temperature zone reaction chamber cylinder, and a third temperature zone reaction chamber cylinder.
更佳地,所述的裂解单元还包括脱蜡炉、与所述的脱蜡炉相连接第五油气输送支管、与所述的第五油气输送支管出口相连接的催化闪蒸塔、与所述的催化闪蒸塔相连接的第六油气输送支管、与所述的第六油气输送支管出口相连接的第二冷凝器、与所述的第二冷凝器相下出口相连接的气液分离罐、与所述的气液分离罐底部出料口相连接的第七液体输送支管、与所述的气液分离罐侧面排气口相连接第八燃气输送支管、伸缩管,所述的脱蜡炉的进料口通过伸缩管与所述的膜式裂解反应腔的出料口相连通,所述的脱蜡炉出气口通过所述第五油气输送支管与所述的催化闪蒸塔进口相连通,所述的催化闪蒸塔出气口通过所述第六油气输送支管与所述的第二冷凝器进口相连通,所述的第二冷凝器底部出口与所述气液分离罐上部进气口直接相连通,所述的气液分离罐侧面排气口通过所述的第八燃气输送支管与排气总管相连通;所述的脱蜡炉设置有第四电感加热元件,所述的催化闪蒸塔设置有第六加热元件。Preferably, the cracking unit further comprises a dewaxing furnace, a fifth oil and gas transmission branch pipe connected to the dewaxing furnace, a catalytic flash tower connected to the outlet of the fifth oil and gas transmission branch pipe, and a fifth oil and gas transmission branch pipe connected to the dewaxing furnace. The sixth oil and gas transport branch pipe that is connected to the catalytic flash tower, the second condenser that is connected to the outlet of the sixth oil and gas transport branch pipe, and the gas-liquid separation that is connected to the lower outlet of the second condenser The tank, the seventh liquid conveying branch pipe connected with the discharge port at the bottom of the gas-liquid separation tank, the eighth gas conveying branch pipe and the telescopic pipe connected with the exhaust port on the side of the gas-liquid separation tank. The feeding port of the wax furnace is communicated with the feeding port of the membrane cracking reaction chamber through a telescopic tube, and the gas outlet of the dewaxing furnace is connected to the inlet of the catalytic flash tower through the fifth oil and gas conveying branch pipe. The outlet of the catalytic flash tower is communicated with the inlet of the second condenser through the sixth oil and gas transport branch pipe, and the outlet at the bottom of the second condenser is connected to the upper inlet of the gas-liquid separation tank. The gas port is directly connected, and the side exhaust port of the gas-liquid separation tank is communicated with the exhaust main pipe through the eighth gas conveying branch pipe; the dewaxing furnace is provided with a fourth inductive heating element, and the The catalytic flash column is provided with a sixth heating element.
更佳地,所述的脱蜡炉底部的排料口与碳黑冷却机的进料口相连接,所述的碳黑冷却机出料口与碳黑收集箱相连接,所述的碳黑收集箱的上部设置有氮气进口,所述的碳黑冷却机包括第四减速机、第三联轴器、第三轴承箱、第三螺筒,并依次相连接,通过支架固定在底座,第三螺筒内装有与第三联轴器相连的螺杆,第三螺筒外壁设置有冷却水箱。More preferably, the discharge port at the bottom of the dewaxing furnace is connected with the feed port of the carbon black cooler, the discharge port of the carbon black cooler is connected with the carbon black collection box, and the carbon black The upper part of the collection box is provided with a nitrogen inlet, and the carbon black cooler includes a fourth reducer, a third coupling, a third bearing box, and a third screw barrel, which are connected in sequence and fixed on the base through a bracket. The three screw barrels are equipped with a screw rod connected with the third coupling, and the outer wall of the third screw barrel is provided with a cooling water tank.
更佳地,所述的催化闪蒸塔包括外壳上端、第一外壳中段、第二外壳中段、外壳下端、第一栅格、第二栅格,第一伞罩、第二伞罩,所述的外壳上端、所述的第一外壳中端、所述的第二外壳中端、所述的外壳下端自上而下依次连接成塔体,所述的催化闪蒸塔下端设置有第六加热元件,所述的第一栅格、所述的第二栅格、所述的第一伞罩和所述的第二伞罩自上而下依次固定在塔体内。More preferably, the catalytic flash tower comprises the upper end of the shell, the middle section of the first shell, the middle section of the second shell, the lower end of the shell, the first grid, the second grid, the first umbrella cover, the second umbrella cover, the The upper end of the outer shell, the middle end of the first outer shell, the middle end of the second outer shell, and the lower end of the outer shell are sequentially connected from top to bottom to form a tower body, and the lower end of the catalytic flash tower is provided with a sixth heating Components, the first grid, the second grid, the first umbrella cover and the second umbrella cover are sequentially fixed in the tower body from top to bottom.
较佳地,所述的压缩式进料装置、所述的第一挤出装置、所述的第二挤出装置、安装在高于所述的膜式裂解反应腔的平台上,所述的接收罐、所述的第一冷凝器、所述的催化吸附塔、所述的膜式裂解反应腔,所述的第二冷凝器、所述的催化闪蒸塔、所述的气液分离罐、所述的脱蜡炉、所述的碳黑冷却机,依次自上而下组装在同一撬块支架上。Preferably, the compression feeding device, the first extrusion device, the second extrusion device are installed on a platform higher than the membrane cracking reaction chamber, and the Receiving tank, the first condenser, the catalytic adsorption tower, the membrane cracking reaction chamber, the second condenser, the catalytic flash tower, the gas-liquid separation tank , The dewaxing furnace and the carbon black cooler are sequentially assembled on the same skid support from top to bottom.
本实用新型的一种实现裂解高聚物的裂解系统,适应性强,不仅能处理废塑料(PE、PP、 PS),还能处理废机油、渣油等高聚物,而且还能处理含氯的聚氯乙烯,在有处理能力大,反应速度快,有效转化率接近100%,设备筒壁不结碳,无二次污染,适应常年连续生产等优点。规模可达8~30吨/日,克服目前国内外废塑料处理设备的反应周期长,油化率低,有固体废物和废水排放,结碳严重,清理困难而造成二次污染的缺点。采用本实用新型的实现裂解高聚物的裂解系统,裂解时间短,反应完全,不易结碳,无二次污染,可以无害化处理含氯聚合物,占地面积小,应用范围广。The cracking system of the utility model for realizing cracking of high polymers has strong adaptability, and can not only process waste plastics (PE, PP, PS), but also process high polymers such as waste oil and residual oil, and can also process high polymers containing waste plastics (PE, PP, PS). Chlorine-based polyvinyl chloride has the advantages of large processing capacity, fast reaction speed, effective conversion rate close to 100%, no carbon formation on the barrel wall of the equipment, no secondary pollution, and is suitable for continuous production all year round. The scale can reach 8 to 30 tons/day, which overcomes the shortcomings of the current domestic and foreign waste plastic treatment equipment, such as long reaction period, low oil conversion rate, solid waste and waste water discharge, serious carbon deposition, and difficulty in cleaning, resulting in secondary pollution. The cracking system for realizing cracking of high polymers of the utility model has the advantages of short cracking time, complete reaction, no carbon formation, no secondary pollution, harmless treatment of chlorine-containing polymers, small footprint and wide application range.
附图说明Description of drawings
图1为本实用新型的实现裂解高聚物的裂解系统的第一实施方式的结构剖视图。FIG. 1 is a structural cross-sectional view of the first embodiment of the cracking system for realizing cracking of high polymers according to the present invention.
图2为本实用新型的实现裂解高聚物的裂解系统的第一实施方式的俯视图。FIG. 2 is a top view of the first embodiment of the cracking system for cracking high polymers according to the present invention.
图3为本实用新型的实现裂解高聚物的裂解系统中的压缩式进料斗的结构剖视图。FIG. 3 is a structural cross-sectional view of a compression feed hopper in a cracking system for cracking high polymers according to the present invention.
图4为本实用新型的实现裂解高聚物的裂解系统中的第一挤出装置的结构剖视图。4 is a structural cross-sectional view of the first extrusion device in the cracking system for realizing cracking of high polymers according to the present invention.
图5为本实用新型的实现裂解高聚物的裂解系统中的第二挤出装置的结构剖视图。5 is a structural cross-sectional view of the second extrusion device in the cracking system for cracking high polymers according to the present invention.
图6为本实用新型的实现裂解高聚物的裂解系统中的刮板总成的结构剖视图。6 is a structural cross-sectional view of the scraper assembly in the cracking system for cracking high polymers according to the present invention.
图7为图6的C—C的局部放大剖视图。FIG. 7 is a partial enlarged cross-sectional view of CC in FIG. 6 .
图8为本实用新型的实现裂解高聚物的裂解系统中的第一分流头的结构剖视图。FIG. 8 is a cross-sectional view of the structure of the first split head in the cracking system for cracking high polymers according to the present invention.
图9为图8的E—E的局部放大剖视图。FIG. 9 is a partial enlarged cross-sectional view taken along line E-E of FIG. 8 .
图10为本实用新型的实现裂解高聚物的裂解系统中的搅拌总成的结构剖视图。10 is a structural cross-sectional view of the stirring assembly in the cracking system for cracking high polymers according to the present invention.
图11为图10的D—D的局部放大剖视图。FIG. 11 is a partial enlarged cross-sectional view of D-D in FIG. 10 .
图12为本实用新型的实现裂解高聚物的裂解系统中的碳黑冷却机的结构剖视图。12 is a structural cross-sectional view of a carbon black cooler in a cracking system for cracking high polymers according to the present invention.
图13为本实用新型的实现裂解高聚物的裂解系统中的连接装置的结构剖视图。Fig. 13 is a structural cross-sectional view of the connecting device in the cracking system for realizing cracking of high polymers according to the present invention.
图14为本实用新型的实现裂解高聚物的裂解系统的第二实施方式的俯视图。FIG. 14 is a top view of the second embodiment of the cracking system for cracking high polymers according to the present invention.
图15为本实用新型的实现裂解高聚物的裂解系统中的第二分流头的剖视图。FIG. 15 is a cross-sectional view of the second split head in the cracking system for cracking high polymers according to the present invention.
图16为本实用新型的实现裂解高聚物的裂解系统中的接收罐的剖视图。16 is a cross-sectional view of a receiving tank in the cracking system for cracking high polymers according to the present invention.
图17为本实用新型的实现裂解高聚物的裂解系统中的碳黑收集箱的剖视图。17 is a cross-sectional view of the carbon black collection box in the cracking system for cracking high polymers according to the present invention.
图18为本实用新型的实现裂解高聚物的裂解系统中的催化吸闪蒸塔的剖视图。18 is a cross-sectional view of the catalytic absorption flash tower in the cracking system for cracking high polymers according to the present invention.
图19为本实用新型的实现裂解高聚物的裂解系统中的催化附塔的剖视图。FIG. 19 is a cross-sectional view of the catalytic attachment tower in the cracking system for cracking high polymers according to the present invention.
附图标记:Reference number:
1、2、10 第一冷凝器1, 2, 10 First condenser
3 接收罐3 receiving tanks
4、11、12 催化吸附塔4, 11, 12 Catalytic adsorption tower
5a、5b、5c 搅拌5a, 5b, 5c stirring
6 第二冷凝器6 Second condenser
7 气液分离罐7 Gas-liquid separation tank
8 催化闪蒸塔8 Catalytic flash tower
9 第六加热元件9 Sixth heating element
13 第一分流头13 First split head
14a、14b、14c 膜式裂解反应腔14a, 14b, 14c Membrane lysis reaction chamber
15 压缩式进料装置15 Compression feeder
16 第一挤出装置16 The first extrusion device
17 连接装置17 Connections
18 第二挤出装置18 Second extrusion device
19 油储罐19 Oil storage tank
20 脱蜡炉20 Dewaxing furnace
21 组合阀21 Combination valve
22 碳黑冷却机22 Carbon Black Cooler
23、24、25 气动组合阀23, 24, 25 Pneumatic combination valve
26 碳粉收集箱26 Toner collection box
27 刮刀搅拌27 spatula stirring
28 油储槽28 Oil storage tank
29 燃气压缩机29 Gas compressor
30 液化气储罐30 LPG storage tanks
a 第一减速机a First reducer
b 第一联轴器b first coupling
c 第一轴承箱c first bearing housing
d 第一挤出装置的进料口d The feed port of the first extrusion device
e 第一螺杆e first screw
f 第一挤出装置的排气口f Exhaust port of the first extrusion unit
g 第一螺筒g First screw barrel
h、r 第一加热元件h, r first heating element
i 第一挤出装置的出料口i The discharge port of the first extrusion device
j 第一固定架j The first fixing frame
k 第一底座k first base
l 第二减速机l Second reducer
m 第二联轴器m Second coupling
n 第二轴承箱n Second bearing housing
o 第二挤出装置的进料口o Feed port of the second extrusion unit
p 第二螺杆p Second screw
q 第二螺筒q Second screw barrel
s 第二挤出装置的出料口s The outlet of the second extrusion unit
t 第二固定架t Second holder
x 第二底座x Second base
λ、η、α 第四加热元件λ, η, α Fourth heating element
d1 连接弯管d1 connecting elbow
d2 多孔圆板d2 perforated disc
d3 盖板d3 cover
d4 隔板d4 bulkhead
d5 第二加热元件d5 Second heating element
d6 锥芯d6 cone
d7 壳体d7 shell
d8 第一分流头的排料口d8 The discharge port of the first split head
h1 碳黑冷却机的进料口h1 Feed port of carbon black cooler
h2 碳黑冷却机的出料口h2 Discharge port of carbon black cooler
b1 膜式裂解反应腔的筒体b1 The barrel of the membrane cracking reaction chamber
b2 脱蜡炉筒体b2 Dewaxing furnace barrel
t3 第三加热元件t3 Third heating element
t4 第四加热元件t4 Fourth heating element
t5 第五加热元件t5 Fifth heating element
A 支架A bracket
B 第四联轴器B Fourth Coupling
C 轴承盒C Bearing box
D 搅拌轴D stirring shaft
E 圆柱形上部筒体E Cylindrical upper barrel
F 矩形叶片F rectangular blade
H 第五减速机H fifth reducer
J 圆柱形下部筒体J Cylindrical lower barrel
K 螺旋叶片K helical blade
S 主轴S Spindle
T 分配盘T distribution plate
U 灯笼架U lantern stand
V 活动鳞片V Active Scales
W 底轴W Bottom shaft
X 出料底刮板X discharge bottom scraper
Y 高温滑动轴承Y High temperature plain bearing
B1 圆柱形上部的排气口B1 Cylindrical upper exhaust port
B2 连接装置的筒体B2 Connection device barrel
B3 第一连接口B3 first connector
B4 第二连接口B4 Second connector
C1 外壳上端C1 upper end of shell
C2 第一栅格C2 first grid
C3 第一外壳中段C3 first shell middle section
C4 第二外壳中段C4 Second Shell Middle Section
C5 第二栅格C5 Second Grid
C6 第一伞形罩C6 first umbrella cover
C7 第二伞形罩C7 Second umbrella cover
C8 催化闪蒸塔的外壳下端Lower shell end of C8 catalytic flash column
F1 上端盖F1 upper end cap
F2 上栅格F2 up grid
F3 第一中间段F3 first middle section
F4 第二中间段F4 Second Intermediate Section
F5 下栅格F5 down grid
F6 下端盖F6 lower end cap
H1 第四减速机H1 fourth reducer
H2 第三联轴器H2 Third Coupling
H3 第三轴承箱H3 third bearing housing
H4 第三螺筒H4 Third screw barrel
H5 支架H5 bracket
H6 冷却水箱H6 cooling water tank
H7 底座H7 base
H9 螺杆H9 screw
J1 第三减速机J1 third reducer
L1 主轴L1 spindle
L2 刮刀架L2 scraper holder
L3 刮刀L3 scraper
L4 出料底刮刀L4 discharge bottom scraper
L5 底轴L5 bottom shaft
L6 高温滑动轴承L6 high temperature plain bearing
N1 接收罐的顶部排气口Top vent for N1 receiver tank
N2、N3、N4 油气进口N2, N3, N4 oil and gas imports
N5、N6 接收罐出口N5, N6 receiving tank outlet
S4 隔板S4 bulkhead
S5 锥芯S5 cone
S7 壳体S7 housing
T1 箱盖T1 case cover
T2 碳黑收集箱的进料口Feed port for T2 carbon black collection box
T3 箱体T3 cabinet
T4 小车T4 trolley
T5 氮气进口T5 nitrogen inlet
Z1 排料支管Z1 discharge branch
Z2 第一油气输送支管Z2 first oil and gas delivery branch
Z3 第二油气输送支管Z3 Second oil and gas pipeline
Z4 第三油气输送支管Z4 The third oil and gas pipeline
Z5 第四油气输送支管Z5 Fourth oil and gas pipeline
Z6 第五油气输送支管Z6 fifth oil and gas pipeline
Z7 液封管Z7 Liquid Sealing Tube
Z8 尾气支管Z8 exhaust manifold
Z9 底部伸缩管Z9 bottom telescopic tube
Z10 燃气总管Z10 Gas Main
具体实施方式Detailed ways
为了能够更清楚地描述本实用新型的技术内容,下面结合具体实施例来进行进一步的描述。In order to describe the technical content of the present invention more clearly, further description will be given below with reference to specific embodiments.
如图1、图2、图13所示,为本实用新型提供一种实现裂解高聚物的裂解系统的一种具体实施方式,包括进行裂解反应的裂解单元以及用于在进行裂解反应之前处理高聚物的预处理单元,所述的预处理单元包括压缩式进料装置15、第一挤出装置16、第二挤出装置18、第一分流头13,所述的压缩式进料装置15的出料口与所述的第一挤出装置16的进料口相连通,所述的第一挤出装置16的出料口与所述连接装置17的中部进料口相连通,所述连接装置17的底部出料口与所述的第二挤出装置18的进料口相连通,所述的第二挤出装置18的出料口与所述的第一分流头13进料口相连通,所述的第一分流头13的出口与所述的裂解单元相连通,所述的第一挤出装置16和第二挤出装置18均设置有第一加热元件h、r,所述的第一挤出装置16设置有排出加热产生的废气的排气口f。其中第一加热元件h、r可以为三组加热元件例如电感加热线圈。As shown in Figure 1, Figure 2, Figure 13, a specific embodiment of a cracking system for realizing a cracking polymer is provided for the utility model, including a cracking unit for carrying out a cracking reaction and a process for performing the cracking reaction. The pretreatment unit of the polymer, the pretreatment unit includes a
在一种较佳地实施方式中,所述的第一挤出装置16的出料口i通过连接装置17与所述的第二挤出装置18的进料口o相连接,如图13所示,所述的连接装置17的筒体B2设置有圆柱形上部、圆锥形下部,所述的圆柱形上部的顶端设置有排气口B1,所述的圆柱形上部设置有第一连接口B3,所述的第一连接口B3与所述的第一挤出装置16的出料口i可滑动地密封连接,所述的圆锥形下部的底端设置有第二连接口B4,所述的第二连接口B4与所述的第二挤出装置18的进料口o相连通。In a preferred embodiment, the outlet i of the
其中,连接装置17的外壁绕有第三加热元件例如电感线圈,第一连接口B3具有填料盒,与第一挤出装置16的出料口i相连。连接装置17的圆柱形上部的顶端设置有排气口B1,与氯化氢处理装置进气口连接,且连接装置17外壁设置的第三加热元件t3使连接装置保持聚氯乙烯脱氯的温度260℃,氯化氢从排气孔B1被连续抽出。连接装置17内脱去氯化氢的熔融状态的废高聚物从连接装置17底部第二连接口B4进入第二挤出装置18。Wherein, the outer wall of the
在一种较佳地实施方式中,如图4所示,所述的第一挤出装置16包括依次相连接的第一减速机a、第一联轴器b、第一轴承箱c、第一挤出装置16的进料口d、第一螺筒g、第一挤出装置16的出料口i,所述的第一螺筒g内设置有与所述的第一轴承箱c相连接的第一螺杆e。如图5所示,所述的第二挤出装置18包括依次相连接的第二减速机l、第二联轴器m、第二轴承箱n、第二挤出装置18的进料口o、第二螺筒q、第二挤出装置18的出料口s,所述的第二螺筒q内设置有与所述的第二轴承箱n相连接的第二螺杆p。In a preferred embodiment, as shown in FIG. 4 , the
在一种较佳地实施方式中,如图4所示,所述的第一挤出装置16中的第一螺筒g中部设置有排气孔f,排气孔f内装有排气元件。In a preferred embodiment, as shown in FIG. 4 , a vent hole f is provided in the middle of the first screw barrel g in the
如图4、图5所示,第一挤出装置16还设置有第一固定架j、第一底座k,第二挤出装置 18还设置有第二固定架t、第二底座x。As shown in Figures 4 and 5, the
第一挤出装置16的第一螺筒g在连接装置的第一连接口B3里可以自由滑动又不漏气,消除第一挤出装置16因受热膨胀产生的推力,第一螺筒g外的加热元件h用来加热第一挤出装置16里面的废塑料碎片,第一挤出装置16的第一螺杆e旋转时,废塑料碎片向前移动,在移动过程中被加热熔化、升温,在加热过程中产生的水蒸气和空气从第一螺筒g中部的排气孔内的排气元件排出,进入吸收单元处理。当熔化加热废塑料中的含氯塑料碎片被加热到脱氯温度180~260℃时,熔化的聚氯乙烯被脱去氯离子生成氯化氢,经连接装置17排入氯化氢吸收处理系统。当第二螺杆p转动时,熔融废塑料继续向前移动,同时被第二螺筒q外的第一加热元件r加热升温到进料温度360℃。The first screw barrel g of the
在一种较佳地实施方式中,如图3所示,所述的压缩式进料装置15包括圆柱形上部筒体 E和圆柱形下部筒体J,所述的圆柱形上部筒体E的直径大于所述的圆柱形下部筒体J的直径,所述的压缩式进料装置设置有搅拌结构,所述的搅拌结构包括搅拌轴D和组合叶片,所述的组合叶片包括与所述的圆柱形上部筒体相对应的矩形叶片F和与所述的圆柱形下部筒体相对应的螺旋叶片K。In a preferred embodiment, as shown in FIG. 3 , the
如图3所示,压缩式进料装置15中,搅拌轴D依次连接有第五减速机H、第四联轴器B、轴承盒C和支架A。当搅拌轴D转动时,在矩形叶片F的作用下,物料向压缩式进料装置 15的中心移动,被移动到中心的物料又被旋转的螺旋叶片K压入第一挤出装置16的进料口 d。As shown in FIG. 3 , in the
在一种较佳地实施方式中,如图1和图14所示,所述的裂解单元包括三个或三个以上的膜式裂解反应腔,所述的第二挤出装置18的出料口s通过第一分流头13与所述的裂解单元中的三个14a、14b、14c或三个以上的膜式裂解反应腔相连通。如图1和2所示,在本实施例中,显示了裂解单元包括三个膜式裂解反应腔14a、14b、14c的情形,如图14所示,为本实用新型的第二实施例,显示了裂解单元包括四个膜式裂解反应腔的情形。In a preferred embodiment, as shown in FIG. 1 and FIG. 14 , the cracking unit includes three or more membrane cracking reaction chambers, and the discharge of the
在一种较佳地实施方式中,如图8所示,所述的第一分流头13包括连接弯管d1、壳体 d7,所述的连接弯管d1一端与所述的第二挤出装置18的出料口相连通,所述的连接弯管d1 的另一端与所述的第一分流头的壳体d7的进口端部相连接,所述的壳体d7的进口端部设置有多孔圆板d2,所述的壳体的内部设置有锥芯d6以及围绕所述的锥芯d6设置的隔板d4,所述的隔板d4用于将所述的壳体d7内部空间分隔成对应于所述的膜式裂解反应腔的数目的隔室,所述的壳体d7的出口端部设置有对应于所述的膜式裂解反应腔的数目的排料口d8;所述的壳体设置有第二加热元件d5。In a preferred embodiment, as shown in FIG. 8 , the
如图9和图15所示,显示了所述的隔板将壳体内部空间分隔成三个和四个隔室的情形,对应的膜式裂解反应腔分别为三个和四个。可以根据实际处理量和其他需要,设置其他数目的膜式裂解反应腔和隔室、排料口。如图15是分成四格的情形,壳体S7内部设置有锥芯S6 以及围绕锥芯设置的隔板S4,所述隔板S4将壳体S7内部空间分隔成四个隔室。As shown in FIG. 9 and FIG. 15 , it is shown that the partition plate divides the inner space of the shell into three and four compartments, and the corresponding membrane cracking reaction chambers are three and four, respectively. Other numbers of membrane cracking reaction chambers, compartments, and discharge ports can be set according to the actual processing capacity and other needs. As shown in FIG. 15 , in the case of being divided into four compartments, the casing S7 is provided with a cone core S6 and a partition S4 arranged around the cone core, and the partition plate S4 divides the internal space of the casing S7 into four compartments.
如图8所示,第一分流头13还设置有盖板d3,排料口d8分别与排料支管Z1相连接,排料支管Z1的另一头又分别与膜式裂解反应腔14a、14b、14c进料口相连接,第一分流头 13把第二挤出装置18的出料口s压出的熔融状态的废塑料,经多孔圆板d2,物料由螺旋运动改变为直线运动,再经隔板d4、锥芯d6、将物料分流,再经三个排料接口d8、三根排料支管Z1分别被压入相应膜式裂解反应腔14a、14b、14c进料口。As shown in FIG. 8 , the
在一种较佳地实施方式中,如图1所示,所述的膜式裂解反应腔14a、14b、14c包括膜式裂解反应腔的筒体b1,所述的膜式裂解反应腔的筒体b1被设置在筒壁上的第四加热元件 t2加热成三个不同温度的区域,低温、中温、高温,自上而下分布。例如,膜式裂解反应腔筒体b1外面分别绕有三组高频电感加热线圈λ、η、α,把筒体自上而下分为高、中、低三个温度区,上部温度为350℃~380℃,中部温度400℃~450℃,下部450℃~500℃,这样使不同的废塑料在不同的温度区域进行裂解,避免裂解温度过高或过低,使底部生成碳黑更细腻。In a preferred embodiment, as shown in FIG. 1 , the membrane
如图1、图2、图6、图7所示,膜式裂解反应腔14a、14b、14c内装有第三减速机J1带动的搅拌5a、5b、5c,如图6所示,所述的搅拌5a、5b、5c,由主轴S、分配盘T、灯笼架 U、活动鳞片V、出料底刮板X、底轴W和高温滑动轴承Y组成,主轴S上自上而下依次固定连接分配盘T、灯笼架U、出料底刮板X、底轴W和高温滑动轴承Y,如图6所示,活动鳞片V以悬挂方式与灯笼架U连接,膜式裂解反应腔14a、14b、14c底部装有气动组合阀23、 24、25、底部伸缩管Z9,膜式裂解反应腔14a、14b、14c,顶部装有带动搅拌5a、5b、5c的第三减速机J1,底部物料出口装有气动组合阀23、24、25,与底部伸缩管Z9连接,底部伸缩管Z9另一头与脱蜡炉20顶部的进料口连接。As shown in Figure 1, Figure 2, Figure 6, Figure 7, the membrane cracking
由第一分流头13的排料口d8排出的热熔的膏状废塑料,经排料支管Z1被压入膜式裂解反应腔14a、14b、14c内的旋转的分配盘T上,在离心力的作用下将其甩向膜式裂解反应腔 14a、14b、14c的高温筒壁上,在重力和旋转的活动鳞片V的共同作用下,筒壁上热熔的膏状废塑料被刮成膜状并向下移动,在向下移动过程中,热熔的膏状废塑料在不同温度的筒壁上瞬间发生热裂解反应,出料底刮板X能将底部的高沸物刮向筒壁而被再加热,产生的油气蒸气从膜式裂解反应腔14a、14b、14c排出,进入催化吸附塔4、11、12进一步裂解并除去有机氯。The hot-melt paste-like waste plastic discharged from the discharge port d8 of the
在一种较佳地实施方式中,如图1、图19所示,所述的裂解单元包括催化吸附塔4、11、 12,所述催化吸附塔由上端盖F1、第一中间段F3、第二中间段F4、下端盖F6、上栅格F2、下栅格F5组成。所述的上端盖F1、所述的第一中间段F3、所述的第二中间段F4、所述的下端盖F6,自上而下依次连接成塔体,所述的上栅格F2、所述的下栅格F5自上而下依次固定在塔体内,所述催化吸附塔的上栅格上装有吸附剂,下栅格上装有催化剂,裂解反应和有机氯去除在同一塔内完成。In a preferred embodiment, as shown in Figure 1 and Figure 19, the cracking unit includes catalytic adsorption towers 4, 11, 12, and the catalytic adsorption tower consists of an upper end cover F1, a first intermediate section F3, The second intermediate section F4, the lower end cover F6, the upper grid F2, and the lower grid F5 are composed. The upper end cover F1, the first middle section F3, the second middle section F4, and the lower end cover F6 are sequentially connected to form a tower body from top to bottom, and the upper grid F2, The lower grid F5 is sequentially fixed in the tower body from top to bottom, the upper grid of the catalytic adsorption tower is equipped with adsorbent, the lower grid is equipped with catalyst, and the cracking reaction and organic chlorine removal are completed in the same tower.
在一种较佳地实施方式中,如图1所示,所述的裂解单元包括脱蜡炉20,所述的脱蜡炉 20的三个进料口分别通过三根底部伸缩管Z9与对应所述的三个膜式裂解反应腔14a、14b、 14c底部的气动组合阀23、24、25出料口相连通,所述的脱蜡炉20设置有第五加热元件例如电感加热线圈。In a preferred embodiment, as shown in FIG. 1 , the cracking unit includes a
如图1、图10、图11所示,脱蜡炉20由筒体b2、刮刀搅拌27、高温滑动轴承L6、组合阀21组成,如图10和图11所示,所述的刮刀搅拌27由主轴L1、刮刀架L2、刮刀L3、底刮刀L4、底轴L5和高温滑动轴承L6组成,主轴L1上自上而下依次固定连接刮刀架L2、底刮刀L4、底轴L5,刮刀L3悬挂在刮刀架L2上,底刮板装在刮刀架L2底部。As shown in Figure 1, Figure 10, Figure 11, the dewaxing
来自膜式裂解反应腔14a、14b、14c底部的物料出口的碳黑粉状物通过组合阀21、底部伸缩管Z9从脱蜡炉20顶部的进料口在重力作用下落入脱蜡炉20,在刮刀搅拌27旋转作用之下,经加热将碳黑粉状物里的高沸物蒸出,得到干燥松散的碳黑产品,脱蜡炉20蒸出的高沸点蒸气进入催化闪蒸塔8进行催化裂解,生成的油气通过第五油气输送支管Z6从第二冷凝器上部油气进口进入第二冷凝器6,冷凝后的油气从第二冷凝器6底部排出,进入气液分离罐7,未冷凝的燃气从气液分离罐7顶部排出,通过第七燃气输送支管与燃气总管Z10连通,冷凝液从气液分离罐7底部流入油储罐19。The carbon black powder from the material outlet at the bottom of the membrane cracking
在一种较佳地实施方式中,如图18所述催化闪蒸塔8由外壳上端、第一外壳中段、第二外壳中段、外壳下端、第一栅格、第二栅格、第一伞形罩C6、第二伞形罩C7组成,所述的外壳上端、所述的第一外壳中段、所述的第二外壳中段、所述的外壳下端自上而下依次连接成塔体,所述的外壳下端设置有第六加热元件9。所述的第一栅格、所述的第二栅格、所述的第一伞形罩、所述的第二伞形罩自上而下依次固定在塔体内。In a preferred embodiment, as shown in FIG. 18, the
所述的催化闪蒸塔8内回流的回流液依次落到第一伞形罩C6、第二伞形罩C7上面,落在第二伞形罩C7回流液在重力的作用下被撒在所述的催化闪蒸塔8的外壳下端C8的高温壳壁上瞬间蒸发,蒸发的油气上升进入催化剂层再次进行裂解。The reflux liquid in the
在一种较佳地实施方式中,如图1和图12所示,所述的脱蜡炉20底部的排料口与碳黑冷却机22的进料口h1相连接,所述的碳黑冷却机22的出料口h2与碳粉收集箱26相连接,所述的碳粉碳黑收集箱26的上部设置有氮气进口T5用以向箱体T3内灌氮气,防止碳黑在高温下自燃。In a preferred embodiment, as shown in Figures 1 and 12, the discharge port at the bottom of the
如图12、图17所示,碳黑冷却机22由第四减速机H1、第三联轴器H2、第三轴承箱H3、进料口h1、第三螺筒H4、支架H5、冷却水箱H6、底座H7、螺杆H9,出料口h2组成,冷却水箱下部设有进水口,上部设有出水口。碳黑收集箱26由箱盖T1、进料口T2、箱体T3、小车T4组成。As shown in Figures 12 and 17, the carbon black cooler 22 consists of a fourth reducer H1, a third coupling H2, a third bearing housing H3, a feed port h1, a third screw barrel H4, a bracket H5, and a cooling water tank H6, base H7, screw H9, and discharge port h2 are composed. The lower part of the cooling water tank is provided with a water inlet, and the upper part is provided with a water outlet. The carbon
如图1、图16所示,在一种较佳地实施方式中,所述的裂解单元包括对应于所述的三个膜式裂解反应腔14a、14b、14c的数目的三个油气收集装置,所述的油气收集装置包括与所述的膜式裂解反应腔相连接的三根第一油气输送支管Z2、与所述的三个第一油气输送支管 Z2的出气口相连接的三个催化吸附塔4、11、12,与所述的催化吸附塔顶部油气出口相连接的三根第二油气输送支管Z3、与三个第二油气输送支管Z3出口相连接的第一冷凝器1、2、 10,与所述的三个第一冷凝器1、2、10的底部相连接的三根第三油气输送支管Z4、与三根第三油气输送支管Z4连接的一个接收罐3、与所述的接收罐3的顶部连接的燃气总管Z10。As shown in FIG. 1 and FIG. 16, in a preferred embodiment, the cracking unit includes three oil and gas collection devices corresponding to the number of the three membrane cracking
其中,所述的接收罐3设有油气进口N2、N3、N4和出口N5、N6,所述的接收罐3的三个油气进口,通过三根第三油气输送支管Z4分别与所述的三个第一冷凝器1、2、10底部油气出口相连通,所述的三个第一冷凝器顶部油气进口通过所述的三根第二油气输送支管Z3 与所述的三个催化吸附塔4、11、12顶部油气出口相连通,所述的三个催化吸附塔4、11、 12底部油气进口通过三根第一油气输送支管Z2与所述的膜式裂解反应腔的三个油气出口相连通。接收罐3顶部排气口N1与燃气总管Z10相连接。Wherein, the receiving
所在一种较佳地实施方式中,所述的压缩式进料装置15、第一挤出装置16、第二挤出装置18、安装在高于膜式裂解反应腔14a、14b、14c的平台上,所述的接收罐3、所述的第一冷凝器1、2、10、所述的催化吸附塔4、11、12、所述的膜式裂解反应腔14a、14b、14c,所述的第二冷凝器6、催化闪蒸塔8、气液分离罐7、脱蜡炉20、碳黑冷却机22,依次自上而下组装在同一撬块支架上。In a preferred embodiment, the
本实用新型提供一种使用实现裂解高聚物的裂解系统的应用过程,具体包括:The utility model provides an application process using a cracking system for realizing cracking of high polymers, which specifically includes:
1)设备预热:首先分别启动各个膜式裂解反应腔的电感加热器,把各个膜式裂解反应腔的筒壁同时分别加热,使筒壁上的温度自上而下逐步升高,上部起始温度为360~400℃,依着筒壁温度升高至下部筒壁450~500℃。当各个膜式裂解反应腔内部温度都达到160~ 200℃,随即同时启动第一挤出装置16和第二挤出装置18的电感加热器,分别加热第一挤出装置16的第一螺筒g和第二挤出装置18的第二螺筒q,使第一挤出装置16的第一螺筒g温度自第一挤出装置的进料口d到第一挤出装置16的出料口i逐步上升,从150~160℃逐步升高至250~260℃,第二挤出装置18的第二螺筒q的温度自第二挤出装置的进料口o到第二挤出装置18的出料口s逐步上升;1) Equipment preheating: First, start the induction heaters of each membrane cracking reaction chamber respectively, and heat the cylinder walls of each membrane cracking reaction chamber at the same time, so that the temperature on the cylinder wall gradually increases from top to bottom, and the upper part starts to increase. The initial temperature is 360-400°C, and increases to 450-500°C in the lower cylinder wall according to the temperature of the cylinder wall. When the internal temperature of each membrane cracking reaction chamber reaches 160-200°C, the induction heaters of the
2)然后,启动压缩式进料装置15的第五减速机H,带动搅拌轴D和固定在搅拌轴D上的矩形叶片F和螺旋叶片K;再分别启动各个膜式裂解反应腔14a、14b、14c顶部的第三减速机J1,带动搅拌5a、5b、5c,使活动鳞片V在每个膜式裂解反应腔内转动,转速在5~40 转/分;随即又启动第一挤出装置16的第一减速机a和第二挤出装置18的第二减速机l,使螺杆在螺筒内转动。2) Then, start the fifth reducer H of the
3)将废塑料加入压缩式进料装置15,压缩式进料装置15内的废塑料在搅拌轴D和固定在搅拌轴D上的矩形叶片F和螺旋叶片K转动的作用下,废塑料被压入第一挤出装置16的进料口d,废塑料在旋转摩擦力的作用下,以一定速度在第一螺筒g内向前移动,在向前移动同时不断被加热,加热过程产生的水蒸气和进料过程带入的空气在第一挤出装置16设置的排气口排出,去吸收装置处理,当熔融废塑料从第一挤出装置16出料口i排出,进入连接装置17的第一连接口B3时,废塑料已处于热熔状态的膏状物,温度达到250~260℃,并在连接装置17被第三加热元件t3继续加热,此时,废塑料中混杂的含氯废塑料PVC的氯化氢被分解出来,生成的氯化氢从连接装置17的顶部的排气孔排出、被抽至氯化氢吸收处理装置,脱去氯化氢的熔化物从连接装置17下部的出口排出,从第二挤出装置18的进料口o、进入第二挤出装置18,在第二螺杆p转动作用下,热熔状态的膏状物在第二挤出装置18的第二螺筒g内向前移动,并继续被加热,从250~260℃加热到350~365℃,在第二挤出装置18 的第二螺杆p的旋转推动作用下,废塑料热膏状物被压送到第一分流头13,熔化的废塑料膏状物由于在多孔圆板的阻尼作用,由旋转运动变成直线运动,经隔板和锥芯被一分为三,通过三根排料支管Z1分别被压入三个膜式裂解反应腔14a、14b、14c,被压入的废塑料热熔膏状物从膜式裂解反应腔14a、14b、14c顶部的进料口进入已被第四加热元件λ、η、α加热的膜式裂解反应腔14a、14b、14c,落到正在旋转的分配盘T上,在离心力的作用下,废塑料热熔膏状物被甩向膜式裂解反应腔的筒体b1上,在重力和活动鳞片V旋转的作用下,沿筒体b1向下旋转移动,同时,活动鳞片V在离心力的作用下与筒体b1紧贴着旋转,将流下的废塑料热熔膏状物刮成膜状,逐步向下移动,依次经过低温区、中温区和高温区,不同的塑料在不同温度区域瞬间发生热裂解反应,生成的油气从三个膜式裂解反应腔14a、14b、14c 上部排气口排出,经三根第一油气输送支管Z2,分别进入相对应的催化吸附塔4、11、12的催化剂填料层进一步进行催化裂解,热裂解的高沸点长链产物在催化剂的催化作用下生成短链的低沸点油气,低沸点油气从催化层上升至吸附填料层除去有机氯后从三个催化吸附塔4、 11、12顶部排出,经三根第二油气输送支管Z3分别从相对应的三个第一冷凝器1、2、10顶部的油气进口进入第一冷凝器1、2、10,经冷凝后得到优质燃油和燃气通过第三油气输送支管Z4分别从接收罐的三个油气进口N2、N3、N4进入同一个接收罐3,轻质燃油从接收罐3 出料口N6底部流出,经第四油气输送支管Z5流入油储槽28,燃气从接收罐顶部排气口N1 排出,经燃气总管Z10被燃气压缩机29压缩成液化气,进入液化气储罐30,供废塑料干燥和他用。生成的碳黑在旋转的刮刀L3作用下,顺着脱蜡炉20的内壁向下移动到底部,到达底部的碳黑还含有少量蜡油,碳黑被旋转的出料底刮刀L4从三个膜式裂解反应腔14a、14b、 14c底部物料出口排出,各自经三个气动组合阀23、24、25和三根底部伸缩管Z9进入下部的同一个脱蜡炉20,含油的碳黑粉在刮刀L3的旋转作用下,含蜡油碳黑不断从罐体底部中央移向筒壁并沿筒壁向上翻动,反复循环,脱蜡炉20的筒壁温度为450-500±5℃,蒸出的蜡油蒸气进入所述的催化闪蒸塔8的催化剂层也被二次催化裂解成较低沸点的油气,较低沸点蒸气从催化层上升至吸附填料层除去有机氯后从所述的催化闪蒸塔8顶排出,经第二冷凝器 6冷凝后得到的优质基础油直接进入气液分离罐7,液体基础油从气液分离罐7底部排出,经液封管Z7进入油储罐19,尾气从气液分离罐上部排出,经尾气支管Z8与燃气总管连通,所述催化闪蒸塔8内的回流液先后落到所述催化闪蒸塔8的第一伞形罩C6、第二伞形罩C7,随后在重力的作用下撒向所述的催化闪蒸塔外壳下端C8的筒壁上闪蒸,又上升到所述的催化闪蒸塔8的催化层。确保除去含蜡油碳黑的高沸物,得到干燥松散的碳黑粉,干燥的碳黑粉从脱蜡炉20底部的排出口排出,经组合阀21进入碳黑冷却机22,在碳黑冷却机22的螺杆H9和第三螺筒H4内壁的共同作用下,灼热的碳黑粉在向前移动过程在冷却水箱H6的水中被冷却,被冷却后的碳黑粉从碳黑收集箱26的进料口T2进入碳黑收集箱26,所述的碳黑收集箱26由箱体T3、箱盖T1、进料口T2、氮气进口T5、小车T4组成,碳黑收集箱26要事先用氮气置换和碳黑冷却机22的第三螺筒H4外壁用水冷却可以防止碳黑自燃,以免影响碳黑质量。3) Add the waste plastic into the
不同的废塑料经压缩式进料斗(压缩式进料装置)、排气式挤出机(第一挤出装置)、排气罐(连接装置)排气后,熔融物料经由多头压料机头(分流头)分配到各个膜式裂解反应腔内,物料在离心力的作用下被甩至腔内筒壁上,与高温筒壁接触,瞬间发生裂解,裂解蒸汽经相对应的催化吸附塔进一步催化和除去有机氯,再经冷凝器冷凝后得到优质燃油和燃气,碳黑粉经脱蜡炉处理后排出。本实用新型装置处理量大,适用废塑料、渣油等聚合物的裂解。After different waste plastics are exhausted through the compression feeding hopper (compression feeding device), the exhaust extruder (the first extrusion device), and the exhaust tank (connecting device), the molten material passes through the multi-head press. The head (split head) is distributed into each membrane cracking reaction chamber, and the material is thrown to the inner wall of the chamber under the action of centrifugal force, and contacts with the high temperature cylinder wall, cracking occurs instantly, and the cracking steam is further processed by the corresponding catalytic adsorption tower. Catalysis and removal of organic chlorine, and then condensed by a condenser to obtain high-quality fuel oil and gas, and carbon black powder is discharged after being treated by a dewaxing furnace. The device of the utility model has a large processing capacity and is suitable for the cracking of polymers such as waste plastics and residual oil.
本实用新型的一种实现裂解高聚物的裂解系统,适应性强,不仅能处理废塑料(PE、PP、 PS),还能处理废机油、渣油等高聚物,而且还能处理含氯的聚氯乙烯,再有处理能力大,反应速度快,有效转化率接近100%,设备筒壁不结碳,无二次污染,占地面积小,适应常年连续生产等优点。规模可达8~30吨/日,克服目前国内外废塑料处理设备的反应周期长,油化率低,有固体废物和废水排放,结碳严重,清理困难而造成二次污染的缺点。The cracking system of the utility model for realizing cracking of high polymers has strong adaptability, and can not only process waste plastics (PE, PP, PS), but also process high polymers such as waste oil and residual oil, and can also process high polymers containing waste plastics (PE, PP, PS). Chlorine-based polyvinyl chloride has the advantages of large processing capacity, fast reaction speed, effective conversion rate close to 100%, no carbon formation on the wall of the equipment, no secondary pollution, small footprint, and suitable for continuous production all year round. The scale can reach 8 to 30 tons/day, which overcomes the shortcomings of the current domestic and foreign waste plastic treatment equipment, such as long reaction period, low oil conversion rate, solid waste and waste water discharge, serious carbon deposition, and difficulty in cleaning, resulting in secondary pollution.
在此说明书中,本实用新型已参照其特定的实施方式作了描述。但是,很显然仍可以作出各种修改和变换而不背离本实用新型的精神和范围。因此,说明书和附图应被认为是说明性的而非限制性的。In this specification, the invention has been described with reference to specific embodiments thereof. However, it will be apparent that various modifications and changes can still be made without departing from the spirit and scope of the present invention. Accordingly, the specification and drawings are to be regarded in an illustrative rather than a restrictive sense.
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Effective date of registration: 20230824 Address after: 201499 1810, building A1, No. 1588, Wangyuan South Road, Fengxian District, Shanghai (Greenland future center) Patentee after: Shanghai Sen Sen environmental protection equipment Co.,Ltd. Patentee after: BASF AUXILIARY CHEMICALS CO.,LTD. Address before: 201499 1810, building A1, No. 1588, Wangyuan South Road, Fengxian District, Shanghai (Greenland future center) Patentee before: Shanghai Sen Sen environmental protection equipment Co.,Ltd. |