CN217042068U - A denitration and efficiency improvement device based on SCR reactor lift and urea direct injection technology - Google Patents
A denitration and efficiency improvement device based on SCR reactor lift and urea direct injection technology Download PDFInfo
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- CN217042068U CN217042068U CN202122008326.7U CN202122008326U CN217042068U CN 217042068 U CN217042068 U CN 217042068U CN 202122008326 U CN202122008326 U CN 202122008326U CN 217042068 U CN217042068 U CN 217042068U
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- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 title claims abstract description 47
- 239000004202 carbamide Substances 0.000 title claims abstract description 47
- 238000002347 injection Methods 0.000 title claims abstract description 44
- 239000007924 injection Substances 0.000 title claims abstract description 44
- 238000005516 engineering process Methods 0.000 title claims abstract description 19
- 230000006872 improvement Effects 0.000 title claims description 6
- 239000003054 catalyst Substances 0.000 claims abstract description 48
- 239000007921 spray Substances 0.000 claims description 20
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 5
- 239000003546 flue gas Substances 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- 239000003638 chemical reducing agent Substances 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 5
- 230000008569 process Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000197 pyrolysis Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 230000009466 transformation Effects 0.000 description 3
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- 239000000809 air pollutant Substances 0.000 description 1
- 231100001243 air pollutant Toxicity 0.000 description 1
- PPBAJDRXASKAGH-UHFFFAOYSA-N azane;urea Chemical compound N.NC(N)=O PPBAJDRXASKAGH-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000005485 electric heating Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
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Abstract
Description
技术领域technical field
本实用新型属于燃煤电厂超低排放环保改造领域,涉及一种基于SCR反应器抬升和尿素直喷技术的脱硝提效装置。The utility model belongs to the field of ultra-low emission environmental protection transformation of coal-fired power plants, and relates to a denitration and efficiency improvement device based on the lifting of an SCR reactor and the direct injection of urea.
背景技术Background technique
目前,SCR脱硝技术已然成为燃煤电厂在全面实施大气污染物超低排放应用上最为广泛和成熟的烟气净化技术,SCR脱硝技术具备脱硝效率高(可高达90%)、二次污染小、技术成熟可靠等优点。At present, SCR denitration technology has become the most widely used and mature flue gas purification technology for coal-fired power plants to fully implement ultra-low emissions of air pollutants. SCR denitration technology has high denitration efficiency (up to 90%), low secondary pollution, The technology is mature and reliable.
国内大部分燃煤电厂在环保改造初期的SCR脱硝工艺催化剂层数按“2+1”模式布置,初装2层,预留1层,部分“W”火焰锅炉环保改造初期的SCR脱硝工艺催化剂层数按“初装3层,预留1层的模式布置。脱硝设计初期基本上都是采用液氨作为SCR脱硝反应的还原剂,NOx排放浓度控制在200mg/m3以内。随着环保形势的严峻,国家出台了NOx排放浓度控制在50mg/m3的超低排放标准,部分地区更是出台了NOx排放浓度控制在30mg/m3的政策要求,因此,原有脱硝装置的脱硝效率无法达到超低排放要求,必须对环保设备进行提效升级改造。In most domestic coal-fired power plants, the number of catalyst layers for SCR denitration process in the initial stage of environmental protection transformation is arranged in a "2+1" mode, with 2 layers initially installed and 1 layer reserved. Some "W" flame boilers in the early stage of environmental protection transformation of SCR denitration process catalysts The number of layers is arranged according to the pattern of "initial installation of 3 layers and reservation of 1 layer. In the initial stage of denitration design, liquid ammonia is basically used as a reducing agent for SCR denitration reaction, and the NOx emission concentration is controlled within 200mg/ m3 . With the environmental protection situation The country has issued an ultra-low emission standard to control the NOx emission concentration at 50mg/m 3 , and some regions have issued a policy requirement to control the NOx emission concentration at 30 mg/m 3 . Therefore, the denitrification efficiency of the original denitrification device cannot be achieved. To meet the ultra-low emission requirements, environmental protection equipment must be upgraded to improve efficiency.
实用新型内容Utility model content
本实用新型的目的在于克服上述现有技术的缺点,提供了一种基于SCR反应器抬升和尿素直喷技术的脱硝提效装置,该装置能够满足超低排放的要求。The purpose of this utility model is to overcome the above-mentioned shortcomings of the prior art, and to provide a denitration and efficiency enhancement device based on the SCR reactor lift and the urea direct injection technology, which can meet the requirements of ultra-low emission.
为达到上述目的,本实用新型所述的基于SCR反应器抬升和尿素直喷技术的脱硝提效装置包括原脱硝反应器立柱、新增催化剂层立柱、新增催化剂、新增反应器壳体、反应器顶盖及顶部原烟道、新增SCR入口烟道、尿素直喷喷枪及尿素直喷喷枪分配器;In order to achieve the above purpose, the denitration and efficiency improvement device based on the SCR reactor lifting and urea direct injection technology described in the present invention includes the original denitration reactor column, the newly added catalyst layer column, the newly added catalyst, the newly added reactor shell, Reactor top cover and top original flue, newly added SCR inlet flue, urea direct injection spray gun and urea direct injection spray gun distributor;
新增催化剂层立柱竖立固定于原脱硝反应器立柱上,原反应器壳体固定于原脱硝反应器立柱的侧面,新增反应器壳体固定于新增催化剂层立柱的侧面,且新增反应器壳体的底部与原反应器壳体的顶部相连通,结构框架固定于新增反应器壳体内,且新增催化剂位于结构框架上;The new catalyst layer column is erected and fixed on the original denitration reactor column, the original reactor shell is fixed on the side of the original denitration reactor column, the newly added reactor shell is fixed on the side of the newly added catalyst layer column, and the new reaction is added. The bottom of the reactor shell is communicated with the top of the original reactor shell, the structural frame is fixed in the newly added reactor shell, and the newly added catalyst is located on the structural frame;
原SCR入口烟道的出口与新增SCR入口烟道的入口相连通,新增SCR入口烟道的出口经反应器顶盖及顶部原烟道与新增反应器壳体的顶部入口相连通。The outlet of the original SCR inlet flue is connected to the inlet of the newly added SCR inlet flue, and the outlet of the newly added SCR inlet flue is connected to the top inlet of the newly added reactor shell through the reactor top cover and the top original flue.
原SCR入口烟道的底部设置有若干尿素直喷喷枪,其中,尿素直喷喷枪分配器的出口与各尿素直喷喷枪的入口相连通。The bottom of the original SCR inlet flue is provided with several urea direct injection spray guns, wherein the outlet of the urea direct injection spray gun distributor is communicated with the inlet of each urea direct injection spray gun.
所述结构框架包括四根脱硝催化剂支撑主梁以及若干脱硝催化剂支撑次梁,其中,四根脱硝催化剂支撑主梁形成环形框架,各脱硝催化剂支撑次梁固定于所述环形框架内。The structural frame includes four denitration catalyst supporting main beams and several denitration catalyst supporting sub-beams, wherein the four denitration catalyst supporting main beams form an annular frame, and each denitration catalyst supporting sub-beam is fixed in the annular frame.
各脱硝催化剂支撑次梁平行且等间距分布。The supporting secondary beams of each denitration catalyst are parallel and equally spaced.
各尿素直喷喷枪呈阵型分布。The urea direct injection guns are distributed in formation.
各尿素直喷喷枪的喷射方向与烟气的流动方向相同。The injection direction of each urea direct injection gun is the same as the flow direction of the flue gas.
新增反应器壳体的轴线与原反应器壳体的轴线位于同一直线上。The axis of the new reactor shell is on the same line as the axis of the original reactor shell.
结构框架焊接固定于新增反应器壳体内。The structural frame is welded and fixed in the newly added reactor shell.
各脱硝催化剂支撑次梁焊接固定于所述环形框架内。Each denitration catalyst supporting secondary beam is welded and fixed in the annular frame.
本实用新型具有以下有益效果:The utility model has the following beneficial effects:
本实用新型所述的基于SCR反应器抬升和尿素直喷技术的脱硝提效装置在具体操作时,充分利用纵向空间,在原反应器壳体上固定连通新增反应器壳体,然后在新增反应器壳体内增设新增催化剂,实现SCR脱硝工艺从3层催化剂改为4层催化剂同时运行的模式,另外,配合在原SCR入口烟道上采用尿素直喷喷枪,从而达到还原剂扩容的目的。The denitration and efficiency improvement device based on the SCR reactor lifting and the urea direct injection technology of the utility model fully utilizes the vertical space during the specific operation, and the original reactor shell is fixedly connected to the new reactor shell, and then the new reactor shell is connected to the original reactor shell. A new catalyst is added in the reactor shell to realize the SCR denitration process from 3 layers of catalysts to 4 layers of catalysts running at the same time. In addition, a urea direct injection gun is used on the original SCR inlet flue to achieve the purpose of reducing agent capacity expansion.
附图说明Description of drawings
图1为本实用新型的结构示意图。Figure 1 is a schematic structural diagram of the utility model.
其中,1为原脱硝反应器立柱、2为新增催化剂层立柱、3为脱硝催化剂支撑主梁、4为脱硝催化剂支撑次梁、5为新增催化剂、6为新增反应器壳体、7为反应器顶盖及顶部原烟道、8为新增SCR入口烟道、9为尿素直喷喷枪、10为尿素直喷喷枪分配器。Among them, 1 is the original denitration reactor column, 2 is the newly added catalyst layer column, 3 is the denitration catalyst supporting main beam, 4 is the denitration catalyst supporting secondary beam, 5 is the newly added catalyst, 6 is the newly added reactor shell, 7 It is the top cover of the reactor and the original flue at the top, 8 is the newly added SCR inlet flue, 9 is the urea direct injection spray gun, and 10 is the urea direct injection spray gun distributor.
具体实施方式Detailed ways
为了使本技术领域的人员更好地理解本实用新型方案,下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分的实施例,不是全部的实施例,而并非要限制本实用新型公开的范围。此外,在以下说明中,省略了对公知结构和技术的描述,以避免不必要的混淆本实用新型公开的概念。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都应当属于本实用新型保护的范围。In order to enable those skilled in the art to better understand the solutions of the present invention, the technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the accompanying drawings in the embodiments of the present invention. Obviously, the described The embodiments are only a part of the embodiments of the present invention, not all of the embodiments, and are not intended to limit the scope of the disclosure of the present invention. Also, in the following description, descriptions of well-known structures and techniques are omitted to avoid unnecessarily obscuring the concepts disclosed in the present invention. Based on the embodiments of the present invention, all other embodiments obtained by persons of ordinary skill in the art without creative work shall fall within the protection scope of the present invention.
在附图中示出了根据本实用新型公开实施例的结构示意图。这些图并非是按比例绘制的,其中为了清楚表达的目的,放大了某些细节,并且可能省略了某些细节。图中所示出的各种区域、层的形状及它们之间的相对大小、位置关系仅是示例性的,实际中可能由于制造公差或技术限制而有所偏差,并且本领域技术人员根据实际所需可以另外设计具有不同形状、大小、相对位置的区域/层。The accompanying drawings show a schematic structural diagram of an embodiment according to the disclosure of the present invention. The figures are not to scale, some details have been exaggerated for clarity, and some details may have been omitted. The shapes of various regions and layers shown in the figures and their relative sizes and positional relationships are only exemplary, and in practice, there may be deviations due to manufacturing tolerances or technical limitations, and those skilled in the art should Regions/layers with different shapes, sizes, relative positions can be additionally designed as desired.
参考图1,本实用新型所述的基于SCR反应器抬升和尿素直喷技术的脱硝提效装置包括原脱硝反应器立柱1、新增催化剂层立柱2、脱硝催化剂支撑主梁3、脱硝催化剂支撑次梁4、新增催化剂、新增反应器壳体6、反应器顶盖及顶部原烟道7、新增SCR入口烟道8、尿素直喷喷枪9及尿素直喷喷枪分配器10;Referring to FIG. 1 , the denitration and efficiency improvement device based on SCR reactor lifting and urea direct injection technology according to the present utility model includes the original denitration reactor column 1, the newly added catalyst layer column 2, the denitration catalyst support main beam 3, the denitration catalyst support Secondary beam 4, new catalyst, new reactor shell 6, reactor top cover and top original flue 7, new SCR inlet flue 8, urea direct injection spray gun 9 and urea direct injection spray gun distributor 10;
新增催化剂层立柱2竖立固定于原脱硝反应器立柱1上,原反应器壳体固定于原脱硝反应器立柱1的侧面,新增反应器壳体6固定于新增催化剂层立柱2的侧面,且新增反应器壳体6的底部与原反应器壳体的顶部相连通,结构框架固定于新增反应器壳体6内,且新增催化剂5位于结构框架上,所述结构框架包括四根脱硝催化剂支撑主梁3以及若干脱硝催化剂支撑次梁4,其中,四根脱硝催化剂支撑主梁3形成环形框架,各脱硝催化剂支撑次梁4固定于所述环形框架内。The newly added catalyst layer column 2 is erected and fixed on the original denitration reactor column 1, the original reactor shell is fixed on the side of the original denitration reactor column 1, and the newly added reactor shell 6 is fixed on the side of the newly added catalyst layer column 2. , and the bottom of the newly added reactor shell 6 is communicated with the top of the original reactor shell, the structural frame is fixed in the newly added reactor shell 6, and the newly added
原SCR入口烟道的出口与新增SCR入口烟道8的入口相连通,新增SCR入口烟道8的出口经反应器顶盖及顶部原烟道7与新增反应器壳体6的顶部入口相连通。The outlet of the original SCR inlet flue is connected with the inlet of the newly added SCR inlet flue 8, and the outlet of the newly added SCR inlet flue 8 is connected to the top of the newly added reactor shell 6 through the reactor top cover and the top original flue 7 The entrance is connected.
原SCR入口烟道的底部设置有若干尿素直喷喷枪9,其中,尿素直喷喷枪分配器10的出口与各尿素直喷喷枪9的入口相连通。The bottom of the original SCR inlet flue is provided with several urea direct injection spray guns 9 , wherein the outlet of the urea direct injection spray gun distributor 10 is communicated with the inlet of each urea direct injection spray gun 9 .
需要说明的是,本实用新型具有以下特点:It should be noted that the utility model has the following characteristics:
本实用新型充分利现有SCR装置,在横向空间无法扩张的情况下充分利用纵向空间,使整体改动最小,方案最优化。The utility model makes full use of the existing SCR device, and makes full use of the vertical space under the condition that the horizontal space cannot be expanded, so as to minimize the overall change and optimize the scheme.
本实用新型将新增催化剂层立柱2垂直连接于原脱硝反应器立柱1上,新增催化剂5荷载通过新增催化剂层立柱2传递最终汇至脱硝钢架上。In the utility model, the newly added catalyst layer column 2 is vertically connected to the original denitration reactor column 1, and the load of the newly added
本实用新型选用尿素作为还原剂,与传统的还原剂液氨相比,具有无氨泄漏、不需防火、运行成本低以及占地面积少的优势,且无毒无害。Compared with the traditional reducing agent liquid ammonia, the utility model selects urea as the reducing agent, and has the advantages of no ammonia leakage, no need for fire prevention, low operating cost and less floor space, and is non-toxic and harmless.
本实用新型相比于传统的脱硝尿素热解及水解工艺,烟道尿素热解直喷制氨工艺技术可以节省尿素热解装置及电加热等设备,进一步简化系统设备、降低尿素制氨能耗。Compared with the traditional denitrification urea pyrolysis and hydrolysis process, the utility model can save the urea pyrolysis device and electric heating and other equipment by the flue urea pyrolysis direct injection ammonia production technology, further simplify the system equipment and reduce the energy consumption of urea ammonia production .
本实用新型按一定比例调配计量后的尿素溶液通过尿素直喷喷枪分配器10配置后均分输送至各尿素直喷喷枪9,尿素直喷喷枪9依次并列布置于原SCR入口烟道的底部,尿素直喷喷枪9喷出的尿素液滴流向与烟气流向一致,并与烟气充分混合后在原SCR入口烟道中被加热并分解成氨气作为SCR的还原剂。The urea solution prepared and metered by the utility model according to a certain proportion is distributed through the urea direct injection spray gun distributor 10 and then evenly distributed to each urea direct injection spray gun 9. The urea direct injection spray guns 9 are arranged in sequence at the bottom of the original SCR inlet flue, The urea droplets sprayed by the urea direct injection gun 9 flow in the same direction as the flue gas, and after fully mixing with the flue gas, they are heated in the original SCR inlet flue and decomposed into ammonia gas as the SCR reducing agent.
最后需要说明的是,以上说明本实用新型的技术思想,不能以此限定本实用新型的保护范围,凡依本实用新型专利构思所述的构造、特征及技术思想所做的等效或简单变化,均包括于本实用新型专利的保护范围内。本实用新型所属技术领域的技术人员可以对所描述的具体实例做各种各样的修改或补充或采用类似的方式替代,只要不偏离本实用新型的结构或者超越本权利要求书所定义的范围,均应属于本实用新型的保护范围。Finally, it should be noted that the technical idea of the present utility model is described above, and the protection scope of the present utility model cannot be limited by this. Any equivalent or simple changes made according to the structure, features and technical ideas described in the patent idea of the present utility model , are included in the protection scope of this utility model patent. Those skilled in the art to which the present invention pertains can make various modifications or additions to the specific examples described or substitute in similar ways, as long as they do not deviate from the structure of the present invention or go beyond the scope defined by the claims , should belong to the protection scope of the present utility model.
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