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CN210775318U - Flexible three-electrode sodium ion detection device - Google Patents

Flexible three-electrode sodium ion detection device Download PDF

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CN210775318U
CN210775318U CN201921571791.8U CN201921571791U CN210775318U CN 210775318 U CN210775318 U CN 210775318U CN 201921571791 U CN201921571791 U CN 201921571791U CN 210775318 U CN210775318 U CN 210775318U
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吴幸
张嘉言
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East China Normal University
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Abstract

本实用新型公开了一种柔性三电极钠离子检测装置,该装置包括柔性三电极钠离子检测传感器、信号处理模块、数据显示模块及供电模块。柔性三电极钠离子检测传感器中构成与钠离子浓度线性相关的等效电阻,可以输出与不同钠离子浓度相对应的检测信号;信号处理模块由文氏振荡转换电路、波形整形电路构成,可将检测信号转化为正弦波,然后将正弦波转化为方波信号;数据显示模块由单片机、移动终端组成,单片机上搭载有数码管显示电路、蓝牙数据发送电路,可将方波信号频率换算为对应钠离子浓度,并在数码管和移动终端上显示。本实用新型在柔性衬底(优选但不限于聚对苯二甲酸类塑料PET)上制备电极,低制造成本、重量轻、灵敏度高。

Figure 201921571791

The utility model discloses a flexible three-electrode sodium ion detection device, which comprises a flexible three-electrode sodium ion detection sensor, a signal processing module, a data display module and a power supply module. The flexible three-electrode sodium ion detection sensor forms an equivalent resistance linearly related to the concentration of sodium ions, and can output detection signals corresponding to different concentrations of sodium ions; the signal processing module is composed of a Venturi oscillation conversion circuit and a waveform shaping circuit, which can convert The detection signal is converted into a sine wave, and then the sine wave is converted into a square wave signal; the data display module consists of a single-chip microcomputer and a mobile terminal. The single-chip microcomputer is equipped with a digital tube display circuit and a Bluetooth data transmission circuit, which can convert the frequency of the square wave signal to the corresponding The sodium ion concentration is displayed on the nixie tube and mobile terminal. The utility model prepares electrodes on a flexible substrate (preferably but not limited to polyethylene terephthalate plastic PET), and has the advantages of low manufacturing cost, light weight and high sensitivity.

Figure 201921571791

Description

一种柔性三电极钠离子检测装置A flexible three-electrode sodium ion detection device

技术领域technical field

本实用新型涉及用于钠离子含量检测的电子设备,尤其是一种柔性三电极钠离子检测装置。The utility model relates to electronic equipment for detecting sodium ion content, in particular to a flexible three-electrode sodium ion detecting device.

背景技术Background technique

钠离子的摄入对人体维持正常的生理机能有着重要的意义,但钠离子不宜摄入过多,世界卫生组织建议人体每天摄入的钠离子量不应超过1700毫克,过多钠离子摄入将会对人体代谢等方面产生不良影响。因此,对摄入钠离子含量进行监测十分有必要。柔性钠离子检测系统便于对人体每日摄入的钠离子含量进行监测,并通过蓝牙模块在移动终端(手机)上进行实时数据显示,避免出现钠离子摄入过多或摄入不足的情况,帮助人们更加健康的生活。The intake of sodium ions is of great significance to the maintenance of normal physiological functions of the human body, but the intake of sodium ions should not be too much. The World Health Organization recommends that the daily intake of sodium ions should not exceed 1700 mg. Excessive intake of sodium ions It will have adverse effects on human metabolism and other aspects. Therefore, it is necessary to monitor the intake of sodium ions. The flexible sodium ion detection system is convenient for monitoring the daily intake of sodium ions by the human body, and displays real-time data on the mobile terminal (mobile phone) through the Bluetooth module to avoid excessive or insufficient intake of sodium ions. Help people live healthier lives.

申请号为CN 201410606969.3,发明名称为一种钠离子传感器及其制造方法,该钠离子传感器利用基板、第一钠离子选择电极、第二钠离子选择电极及盐桥构成的电路对钠离子进行识别。申请号为CN 201010193003.3,发明名称为一种全固态钾离子传感器及其制备方法,使用了基板、钾离子选择电极和外参比电极对钾离子进行检测。在现有的关于离子检测的技术方案里,主要是通过制备离子选择电极来实现金属离子的检测,针对钠离子的检测传感器种类较少,且尚不可定量测定钠离子浓度。除此之外,目前钠离子检测装置结构复杂,不能同时显示所测溶液中钠离子的浓度,数据显示不直观。更为重要的是,目前市面上缺乏一种柔性的钠离子检测装置。The application number is CN 201410606969.3, and the name of the invention is a sodium ion sensor and a manufacturing method thereof. The sodium ion sensor uses a circuit composed of a substrate, a first sodium ion selective electrode, a second sodium ion selective electrode and a salt bridge to identify sodium ions . The application number is CN 201010193003.3, and the name of the invention is an all-solid-state potassium ion sensor and its preparation method, which use a substrate, a potassium ion selective electrode and an external reference electrode to detect potassium ions. In the existing technical solutions for ion detection, the detection of metal ions is mainly realized by preparing ion-selective electrodes. There are few types of detection sensors for sodium ions, and the concentration of sodium ions cannot be quantitatively determined. In addition, the current sodium ion detection device has a complex structure, cannot display the concentration of sodium ions in the measured solution at the same time, and the data display is not intuitive. More importantly, there is currently a lack of a flexible sodium ion detection device on the market.

实用新型内容Utility model content

本实用新型的目的是提供一种柔性三电极钠离子检测装置,可实时检测钠离子含量并完成检测数据的显示。该装置中柔性三电极钠离子检测传感器中构成了电阻值可随待测钠离子浓度变化而变化的等效电阻,并将检测信号传输至信号处理模块;信号处理模块将输入的信号转化为方波信号并传输至数据显示模块;数据显示模块将方波信号换算为待测钠离子溶液的浓度值,并显示在数码管和移动终端上,完成数据的分析与显示;供电模块为柔性三电极钠离子传感器、信号处理模块、数据显示模块供电。The purpose of the utility model is to provide a flexible three-electrode sodium ion detection device, which can detect the sodium ion content in real time and complete the display of detection data. The flexible three-electrode sodium ion detection sensor in the device constitutes an equivalent resistance whose resistance value can change with the change of the sodium ion concentration to be measured, and transmits the detection signal to the signal processing module; the signal processing module converts the input signal into square The wave signal is transmitted to the data display module; the data display module converts the square wave signal into the concentration value of the sodium ion solution to be tested, and displays it on the digital tube and mobile terminal to complete the analysis and display of the data; the power supply module is a flexible three-electrode Power supply for sodium ion sensor, signal processing module and data display module.

实现本实用新型目的的具体技术方案是:The concrete technical scheme that realizes the purpose of the present utility model is:

一种柔性三电极钠离子检测装置,特点是:该装置包括柔性三电极钠离子检测传感器、信号处理模块、数据显示模块、供电模块,所述柔性三电极钠离子检测传感器、信号处理模块、数据显示模块依次相连,供电模块分别连接柔性三电极钠离子检测传感器、信号处理模块及数据显示模块;其中:A flexible three-electrode sodium ion detection device is characterized in that: the device comprises a flexible three-electrode sodium ion detection sensor, a signal processing module, a data display module, and a power supply module, the flexible three-electrode sodium ion detection sensor, a signal processing module, a data The display modules are connected in sequence, and the power supply module is respectively connected with the flexible three-electrode sodium ion detection sensor, the signal processing module and the data display module; wherein:

所述三电极钠离子检测传感器以柔性材料为衬底,衬底厚度为40-60微米,在衬底上设置有三电极钠离子检测电路;The three-electrode sodium ion detection sensor uses a flexible material as a substrate, the thickness of the substrate is 40-60 microns, and a three-electrode sodium ion detection circuit is arranged on the substrate;

所述信号处理模块包括文氏振荡电路和波形整形电路,文氏振荡电路与波形整形电路连接;The signal processing module includes a Wien oscillation circuit and a waveform shaping circuit, and the Wien oscillation circuit is connected with the waveform shaping circuit;

所述数据显示模块由单片机及移动终端组成,单片机上搭载有数码管显示电路及蓝牙数据发送电路;单片机内设有数模转换模块。The data display module is composed of a single-chip microcomputer and a mobile terminal. The single-chip microcomputer is equipped with a digital tube display circuit and a bluetooth data transmission circuit; and a digital-to-analog conversion module is arranged in the single-chip microcomputer.

所述三电极钠离子检测电路由导线、左电极、右电极及中间电极组成,连接方式为:在柔性衬底上依次间隔一段距离平行放置左、中间、右三个电极,中间电极与左电极、右电极通过钠离子溶液分别构成两个电流回路,形成两个等效电阻,等效电阻的电阻值将随钠离子浓度变化,进而使三电极钠离子检测电路产生对应不同钠离子浓度的检测信号,中间电极一端通过导线连接供电模块,左电极、右电极一端相互连接,另一端连接信号处理模块中的文氏振荡电路的输入端。The three-electrode sodium ion detection circuit is composed of a wire, a left electrode, a right electrode and a middle electrode. The connection method is as follows: on the flexible substrate, the left, middle and right electrodes are placed in parallel at a distance in sequence, and the middle electrode and the left electrode are placed in parallel. The right electrode forms two current loops through the sodium ion solution, forming two equivalent resistances. The resistance value of the equivalent resistance will change with the concentration of sodium ions, so that the three-electrode sodium ion detection circuit can produce detection corresponding to different concentrations of sodium ions. Signal, one end of the middle electrode is connected to the power supply module through a wire, one end of the left electrode and the right electrode is connected to each other, and the other end is connected to the input end of the Venturi oscillator circuit in the signal processing module.

所述文氏振荡电路将三电极钠离子检测传感器输入的检测信号转换成正弦波信号,然后将正弦波信号传输给波形整形电路的输入端。The Venturi oscillator circuit converts the detection signal input by the three-electrode sodium ion detection sensor into a sine wave signal, and then transmits the sine wave signal to the input end of the waveform shaping circuit.

所述波形整形电路将文氏振荡电路输出正弦波信号转换为方波信号,波形整形电路的输出端与数据显示模块中的单片机信号输入串口相连接,便于单片机利用方波信号完成数据的分析与显示。The waveform shaping circuit converts the sine wave signal output by the Wien oscillating circuit into a square wave signal, and the output end of the waveform shaping circuit is connected with the single-chip signal input serial port in the data display module, so that the single-chip computer can use the square wave signal to complete data analysis and analysis. show.

所述柔性材料PET、PDMS、PI或PEN(优选但不限于聚对苯二甲酸类塑料PET)。The flexible material is PET, PDMS, PI or PEN (preferably but not limited to polyethylene terephthalate plastic PET).

本实用新型的有益效果:The beneficial effects of the present utility model:

本实用新型其结构简单,仅利用钠离子浓度与电路等效电阻之间的线性关系制备柔性三电极钠离子检测传感器,原理及制作简单,其柔性衬底可弯曲、质量轻,能贴合人类口腔皮肤或牙齿表面,方便携带,使用者可以更加便利的进行食物中钠离子含量的检测,本实用新型还可通过搭载的蓝牙模块完成在移动终端上的实时数据显示。The utility model has a simple structure, and only uses the linear relationship between the sodium ion concentration and the circuit equivalent resistance to prepare a flexible three-electrode sodium ion detection sensor. The oral skin or tooth surface is easy to carry, and the user can more conveniently detect the sodium ion content in the food. The utility model can also complete the real-time data display on the mobile terminal through the equipped Bluetooth module.

附图说明Description of drawings

图1为本实用新型结构框图;Fig. 1 is the structural block diagram of the utility model;

图2为本实用新型的柔性三电极钠离子检测传感器结构示意图;2 is a schematic structural diagram of a flexible three-electrode sodium ion detection sensor of the present invention;

图3为三电极钠离子检测电路所形成的等效并联电阻值与钠离子浓度关系曲线图。FIG. 3 is a graph showing the relationship between the equivalent parallel resistance value and the sodium ion concentration formed by the three-electrode sodium ion detection circuit.

具体实施方式Detailed ways

为使本实用新型的目的、技术方案及优点更清晰明了,以下结合附图和实施例,对本实用新型进行进一步详细说明。In order to make the purpose, technical solutions and advantages of the present utility model clearer, the present utility model will be further described in detail below with reference to the accompanying drawings and embodiments.

实施例Example

参阅图1,本实用新型包括柔性三电极钠离子检测传感器1、信号处理模块2、数据显示模块3及供电模块4,柔性三电极钠离子检测传感器1、信号处理模块2、数据显示模块3依次相连,供电模块4分别连接柔性三电极钠离子检测传感器1、信号处理模块2及数据显示模块3。其中,信号处理模块2包括文氏振荡电路5和波形整形电路6;数据显示模块3包括单片机7和移动终端8,同时单片机7上搭载了数码管显示电路9及蓝牙数据发送电路10;单片机内设有数模转换模块。Referring to FIG. 1, the present utility model includes a flexible three-electrode sodium ion detection sensor 1, a signal processing module 2, a data display module 3 and a power supply module 4, a flexible three-electrode sodium ion detection sensor 1, a signal processing module 2, and a data display module 3 in sequence. The power supply module 4 is respectively connected to the flexible three-electrode sodium ion detection sensor 1 , the signal processing module 2 and the data display module 3 . Among them, the signal processing module 2 includes a Venturi oscillator circuit 5 and a waveform shaping circuit 6; the data display module 3 includes a single-chip microcomputer 7 and a mobile terminal 8, and the single-chip microcomputer 7 is equipped with a digital tube display circuit 9 and a Bluetooth data transmission circuit 10; Equipped with a digital-to-analog conversion module.

参阅图2,本实用新型所述柔性三电极钠离子检测传感器由柔性衬底11(优选但不限于聚对苯二甲酸类塑料PET)、左电极12(优选但不限于银电极)、右电极13(优选但不限于银电极)、中间电极14(优选但不限于银电极)、导线15、导线16、导线17以及导线18。其中,柔性衬底11置于最底层,在柔性衬底上间隔一段距离依次平行放置左电极12、中间电极14、右电极13,并利用导线15将左、右电极相连。中间电极14另一端通过导线16与供电模块相连;左电极12、右电极13的另一端则分别通过导线17、导线18与信号处理模块相连,完成初始数据的采集。Referring to FIG. 2, the flexible three-electrode sodium ion detection sensor of the present invention is composed of a flexible substrate 11 (preferably but not limited to polyethylene terephthalate plastic PET), a left electrode 12 (preferably but not limited to a silver electrode), a right electrode 13 (preferably but not limited to silver electrodes), intermediate electrode 14 (preferably but not limited to silver electrodes), lead 15 , lead 16 , lead 17 , and lead 18 . The flexible substrate 11 is placed on the bottom layer, and the left electrode 12 , the middle electrode 14 , and the right electrode 13 are placed in parallel on the flexible substrate in sequence at a distance, and the left and right electrodes are connected by wires 15 . The other end of the middle electrode 14 is connected to the power supply module through a wire 16; the other ends of the left electrode 12 and the right electrode 13 are respectively connected to the signal processing module through a wire 17 and a wire 18 to complete the initial data acquisition.

本实用新型工作过程为:The working process of the utility model is as follows:

将柔性三电极钠离子检测传感器浸没在待检测的钠离子溶液中,使中间电极和左、右电极之间通过钠离子溶液联通,形成等效电阻,等效电阻值可随待测钠离子溶液的浓度发生改变,进而改变检测信号;检测信号通过左、右电极与信号处理模块之间的导线输入信号处理模块中的文氏振荡电路,并被处理为正弦波信号,传输至波形整形电路;波形整形电路将输入的正弦波信号转化为方波信号,并通过数据接收串口传入数据显示模块中的单片机中;单片机内设有将方波信号转换为钠离子浓度值的数模转换模块,通过数模转换模块获得待测钠离子溶液中钠离子浓度值,并可在单片机搭载的数码管显示电路上显示钠离子浓度,通过单片机上搭载的蓝牙数据发送电路可将钠离子浓度数据无线传输至移动终端,完成对待测钠离子溶液的检测和数据显示。The flexible three-electrode sodium ion detection sensor is immersed in the sodium ion solution to be detected, so that the middle electrode and the left and right electrodes are connected through the sodium ion solution to form an equivalent resistance, and the equivalent resistance value can vary with the sodium ion solution to be measured. The concentration of the ions changes, thereby changing the detection signal; the detection signal is input into the Wien oscillating circuit in the signal processing module through the wire between the left and right electrodes and the signal processing module, and is processed into a sine wave signal and transmitted to the waveform shaping circuit; The waveform shaping circuit converts the input sine wave signal into a square wave signal, and transmits it to the single chip microcomputer in the data display module through the data receiving serial port. The sodium ion concentration value in the sodium ion solution to be tested is obtained through the digital-to-analog conversion module, and the sodium ion concentration can be displayed on the digital tube display circuit mounted on the single-chip microcomputer. The sodium ion concentration data can be wirelessly transmitted through the Bluetooth data transmission circuit mounted on the single-chip microcomputer. To the mobile terminal, the detection and data display of the sodium ion solution to be tested are completed.

参阅图3,本实用新型所述柔性三电极钠离子检测传感器中间电极和左、右电极通过钠离子溶液联通并构成两个电阻值随钠离子浓度的变化的等效电阻,这两个等效电阻的等效并联电阻Rw与钠离子浓度之间有明显线性关系。先后在钠离子浓度为6‰、12‰、18‰时对等效并联电阻Rw进行了四次测试,分别标示为对照组1-对照组4,并根据所测数据以等效并联电阻Rw的电阻值为纵轴,钠离子浓度S‰为横轴绘制关系图。由附图3可见,当溶液中钠离子浓度升高时,并联等效电阻Rw减小,并联等效电阻值与钠离子浓度有很好的线性关系,可利用等效并联电阻值Rw和线性关系获得相应的待测溶液中钠离子浓度。Referring to FIG. 3, the middle electrode and the left and right electrodes of the flexible three-electrode sodium ion detection sensor of the present invention are connected through the sodium ion solution and constitute two equivalent resistances whose resistance values change with the concentration of sodium ions. There is an obvious linear relationship between the equivalent parallel resistance Rw of the resistor and the concentration of sodium ions. The equivalent parallel resistance Rw was tested for four times when the sodium ion concentration was 6‰, 12‰, and 18‰, which were marked as control group 1-control group 4, and the equivalent parallel resistance Rw was measured according to the measured data. The resistance value is plotted on the vertical axis, and the sodium ion concentration S‰ is plotted on the horizontal axis. It can be seen from Figure 3 that when the sodium ion concentration in the solution increases, the parallel equivalent resistance Rw decreases, and the parallel equivalent resistance value has a good linear relationship with the sodium ion concentration. The equivalent parallel resistance value Rw and linearity can be used. relationship to obtain the corresponding sodium ion concentration in the solution to be tested.

Claims (4)

1. A flexible three-electrode sodium ion detection device is characterized by comprising a flexible three-electrode sodium ion detection sensor, a signal processing module, a data display module and a power supply module, wherein the flexible three-electrode sodium ion detection sensor, the signal processing module and the data display module are sequentially connected, and the power supply module is respectively connected with the flexible three-electrode sodium ion detection sensor, the signal processing module and the data display module; wherein:
the three-electrode sodium ion detection sensor takes a flexible material as a substrate, and a three-electrode sodium ion detection circuit is arranged on the substrate; wherein the thickness of the substrate is 40-60 microns;
the signal processing module comprises a Venturi oscillation circuit and a waveform shaping circuit, and the Venturi oscillation circuit is connected with the waveform shaping circuit;
the data display module consists of a single chip microcomputer and a mobile terminal, and the single chip microcomputer is provided with a nixie tube display circuit and a Bluetooth data transmitting circuit; a digital-to-analog conversion module is arranged in the singlechip.
2. The flexible three-electrode sodium ion detection device according to claim 1, wherein the three-electrode sodium ion detection circuit is composed of a lead, a left electrode, a right electrode and a middle electrode, the left electrode and the right electrode respectively form two current loops through sodium ion solution to form two equivalent resistors, one end of the middle electrode is connected with the power supply module through the lead, one ends of the left electrode and the right electrode are connected with each other, and the other end of the middle electrode is connected with an input end of a Venturi oscillation circuit in the signal processing module.
3. The flexible three-electrode sodium ion detection device according to claim 1, wherein an output end of the Venturi oscillation circuit is connected with an input end of the waveform shaping circuit.
4. The flexible three-electrode sodium ion detection device according to claim 1, wherein an output end of the waveform shaping circuit is connected with a signal input serial port of a single chip microcomputer in the data display module.
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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110596221A (en) * 2019-09-20 2019-12-20 华东师范大学 A flexible three-electrode sodium ion detection device

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110596221A (en) * 2019-09-20 2019-12-20 华东师范大学 A flexible three-electrode sodium ion detection device

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