CN210595643U - System for zero release of power plant's whole factory waste water and resource utilization - Google Patents
System for zero release of power plant's whole factory waste water and resource utilization Download PDFInfo
- Publication number
- CN210595643U CN210595643U CN201920880780.1U CN201920880780U CN210595643U CN 210595643 U CN210595643 U CN 210595643U CN 201920880780 U CN201920880780 U CN 201920880780U CN 210595643 U CN210595643 U CN 210595643U
- Authority
- CN
- China
- Prior art keywords
- tank
- water
- reverse osmosis
- power plant
- treatment system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000002351 wastewater Substances 0.000 title claims abstract description 54
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 141
- 229910001868 water Inorganic materials 0.000 claims abstract description 141
- 238000002425 crystallisation Methods 0.000 claims abstract description 50
- 230000008025 crystallization Effects 0.000 claims abstract description 50
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 39
- 230000023556 desulfurization Effects 0.000 claims abstract description 39
- 150000003839 salts Chemical class 0.000 claims abstract description 39
- 239000010865 sewage Substances 0.000 claims abstract description 28
- 238000004065 wastewater treatment Methods 0.000 claims abstract description 28
- 238000001223 reverse osmosis Methods 0.000 claims description 56
- 238000005189 flocculation Methods 0.000 claims description 47
- 230000016615 flocculation Effects 0.000 claims description 47
- 239000013505 freshwater Substances 0.000 claims description 33
- 238000001728 nano-filtration Methods 0.000 claims description 30
- 239000013535 sea water Substances 0.000 claims description 27
- 238000004062 sedimentation Methods 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 23
- 238000005352 clarification Methods 0.000 claims description 21
- 239000012528 membrane Substances 0.000 claims description 21
- 238000000108 ultra-filtration Methods 0.000 claims description 19
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 16
- 238000001704 evaporation Methods 0.000 claims description 16
- 230000008020 evaporation Effects 0.000 claims description 16
- 239000010802 sludge Substances 0.000 claims description 13
- 238000004519 manufacturing process Methods 0.000 claims description 11
- 230000001105 regulatory effect Effects 0.000 claims description 11
- 238000003860 storage Methods 0.000 claims description 11
- 230000009615 deamination Effects 0.000 claims description 9
- 238000006481 deamination reaction Methods 0.000 claims description 9
- 239000003546 flue gas Substances 0.000 claims description 9
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 8
- 235000008733 Citrus aurantifolia Nutrition 0.000 claims description 7
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 7
- 235000011941 Tilia x europaea Nutrition 0.000 claims description 7
- 238000005261 decarburization Methods 0.000 claims description 7
- 239000004571 lime Substances 0.000 claims description 7
- 230000003647 oxidation Effects 0.000 claims description 7
- 238000007254 oxidation reaction Methods 0.000 claims description 7
- 238000004064 recycling Methods 0.000 claims description 7
- 238000004140 cleaning Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 4
- 238000001914 filtration Methods 0.000 claims description 4
- 230000003197 catalytic effect Effects 0.000 claims description 3
- 239000008235 industrial water Substances 0.000 claims description 3
- 238000001471 micro-filtration Methods 0.000 claims description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical class [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 abstract description 20
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract description 18
- 230000008901 benefit Effects 0.000 abstract description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract description 9
- 238000011084 recovery Methods 0.000 abstract description 4
- 239000007787 solid Substances 0.000 abstract description 2
- 238000001556 precipitation Methods 0.000 description 11
- 239000011780 sodium chloride Substances 0.000 description 9
- 238000010586 diagram Methods 0.000 description 7
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 229910052749 magnesium Inorganic materials 0.000 description 6
- 239000011777 magnesium Substances 0.000 description 6
- 238000010612 desalination reaction Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 4
- 239000003513 alkali Substances 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
- 229910052791 calcium Inorganic materials 0.000 description 4
- 239000002244 precipitate Substances 0.000 description 4
- 239000002893 slag Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 208000005156 Dehydration Diseases 0.000 description 3
- 239000013064 chemical raw material Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 229910001385 heavy metal Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000013049 sediment Substances 0.000 description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 description 2
- 238000005262 decarbonization Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 241000700605 Viruses Species 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000909 electrodialysis Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 230000003311 flocculating effect Effects 0.000 description 1
- 239000002920 hazardous waste Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 229910017053 inorganic salt Inorganic materials 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000010908 plant waste Substances 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002910 solid waste Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
Images
Landscapes
- Separation Using Semi-Permeable Membranes (AREA)
Abstract
The utility model discloses a system of power plant's whole factory waste water zero release and utilization. The system for zero discharge of wastewater and resource utilization of the whole power plant comprises a circulating water sewage treatment system, a desulfurization wastewater treatment system and a crystallization salt making system. The utility model discloses a processing system has advantages such as high efficiency, reliable, economy. Use the utility model discloses a system treatment power plant's whole factory waste water, substep recovery water, calcium carbonate dense solution and NaCl salt when realizing the waste water zero release of whole factory, realize the zero release of water and the utilization of water and solid useless in the true sense.
Description
Technical Field
The utility model relates to a system of power plant's whole factory waste water zero release and utilization.
Background
The salt content of the desulfurization wastewater of the power plant is 30000-60000mg/L, and at present, the desulfurization wastewater is comprehensively utilized by adopting systems such as a slag salvaging machine, and because the salt content of the wastewater is too high, the risk of equipment corrosion and the like exists. In order to ensure the safe operation of equipment, power plants are seeking other treatment ways for desulfurization wastewater. Through implementing the waste water zero release engineering of whole factory, realize the whole water structure optimization of whole factory and to the whole recycle of circulating water blowdown water, desulfurization waste water and other high salt waste water, will thoroughly solve the problem that the salt content of the outer waste water of power plant exceeds standard and the water potential safety hazard problem of desulfurization waste water at present.
The conventional power plant wastewater treatment process has high medicament cost and complex working procedures, and is difficult to completely realize zero discharge of wastewater, and finally the obtained salt is mixed salt and can only be used as hazardous waste landfill. Two sets of evaporative crystallization devices are required for salt separation, so that the investment and cost of the system are increased.
The implementation of the whole plant wastewater zero-discharge project has important practical significance in that the power plant can obtain good social benefits and environmental benefits and also can obtain certain economic benefits.
SUMMERY OF THE UTILITY MODEL
An object of the utility model is to provide a system of whole factory waste water zero discharge of power plant and utilization, substep recovery water, calcium carbonate, NaCl crystal salt when realizing the waste water zero release of whole factory of power plant, realized the zero release of water and the utilization of solid useless resources in the true sense.
The utility model adopts the technical proposal that:
a system for zero discharge and resource utilization of wastewater of a whole plant of a power plant comprises a circulating water sewage treatment system, a desulfurization wastewater treatment system and a crystallization salt making system.
Furthermore, among this kind of system, circulating water blowdown water processing system includes the one-level flocculation and precipitation pond, second grade flocculation and precipitation pond, tertiary flocculation and precipitation pond, equalizing basin, multi-media filter, ozone catalytic oxidation tower, biological activity carbon filter, self-cleaning filter, ultrafiltration device, reverse osmosis unit, flocculation basin, micro-filtration device, sea water reverse osmosis unit that connect gradually through the pipeline.
Furthermore, among this kind of system, desulfurization effluent disposal system includes the retaining equalizing basin, one-level softening tank, tubular filtration membrane device, second grade softening clarification tank, tertiary softening clarification tank, multi-media filter, ozone advanced oxidation tower, activated carbon bed, ultrafiltration device, one-level nanofiltration device, second grade nanofiltration device, sea water reverse osmosis unit, homogeneous phase membrane ED (electrodialysis) device, decarbonization deamination device, buffer pool that connect gradually through the pipeline.
Furthermore, in the system, the crystallization salt preparation system comprises an evaporation crystallization device, a centrifugal dehydrator, a drying fluidized bed and a salt bin which are sequentially connected through pipelines.
Preferably, a concentrated water outlet of a seawater reverse osmosis device of the circulating water sewage treatment system is connected with a water storage regulating reservoir of the desulfurization wastewater treatment system; the buffer tank of the desulfurization wastewater treatment system is connected with the evaporative crystallization device of the crystallization salt production system.
Preferably, in the system for zero discharge and resource utilization of the wastewater of the whole power plant, the primary flocculation sedimentation tank and the primary softening tank are respectively connected with a lime feeding device; the secondary flocculation sedimentation tank and the secondary softening clarification tank are respectively connected with a flue gas pipe; the third-stage flocculation sedimentation tank and the third-stage softening clarification tank are respectively connected with a sodium carbonate feeding device.
Preferably, in the system for zero discharge and resource utilization of wastewater of the whole plant of the power plant, sludge outlets of the second-stage flocculation sedimentation tank, the third-stage flocculation sedimentation tank, the second-stage softening clarification tank and the third-stage softening clarification tank are respectively connected with a sludge concentration tank, and the sludge concentration tank is connected with a wet desulphurization system of the power plant.
Preferably, in the circulating water sewage treatment system, fresh water outlets of the reverse osmosis device and the seawater reverse osmosis device are respectively connected with a fresh water comprehensive recycling system; a concentrated water outlet of the reverse osmosis device is connected with a water inlet of the flocculation tank; the water inlet of the reverse osmosis device is connected with the fresh water outlet of the ultrafiltration device.
Preferably, in the circulating water sewage treatment system, concentrated water outlets of the multi-medium filter, the biological activated carbon filter, the self-cleaning filter and the ultrafiltration device are respectively connected with a water inlet of the three-stage flocculation sedimentation tank.
Preferably, in the circulating water sewage treatment system, the sludge outlet of the primary flocculation sedimentation tank is also connected with a concentration tank, and the concentration tank is connected with a dehydrator.
Preferably, in the circulating water sewage treatment system, the flocculation tank is connected with a double-alkali adding device, and the double alkali is sodium hydroxide and calcium hydroxide.
Preferably, in the desulfurization wastewater treatment system, a water inlet of the primary nanofiltration device is respectively connected with a fresh water outlet of the ultrafiltration device and a concentrated water outlet of the secondary nanofiltration device, a concentrated water outlet of the primary nanofiltration device is connected with a water storage regulating reservoir, and a fresh water outlet of the primary nanofiltration device is connected with a water inlet of the secondary nanofiltration device; the fresh water outlet of the second-stage nanofiltration device is connected with the water inlet of the seawater reverse osmosis device.
Preferably, in the desulfurization wastewater treatment system, a fresh water outlet of the seawater reverse osmosis device is connected with the industrial water system, and a concentrated water outlet of the seawater reverse osmosis device is connected with a water inlet of the homogeneous membrane ED device.
Preferably, in the desulfurization wastewater treatment system, a fresh water outlet of the homogeneous membrane ED device is connected with a water inlet of a reverse osmosis device in the circulating water sewage treatment system, and a concentrated water outlet of the homogeneous membrane ED device is connected with a water inlet of the decarburization deamination device.
Preferably, in the desulfurization wastewater treatment system, concentrated water outlets of the multi-media filter, the activated carbon bed and the ultrafiltration device are respectively connected with a water inlet of the three-stage softening clarification tank.
Preferably, in the desulfurization wastewater treatment system, the sludge in the primary softening tank is collected, conveyed to a dehydrator, dewatered and transported to an outside; the effluent of the dehydrator flows back to the water storage adjusting tank.
Preferably, among the desulfurization wastewater treatment system, decarbonization deamination device still is connected with overhauls reserve pond, overhauls reserve pond and is connected with the evaporation crystallization device of crystallization salt manufacturing system.
Preferably, in the crystallization salt production system, a fresh water outlet of the evaporative crystallization device is connected with a water inlet of a reverse osmosis device in the circulating water sewage treatment system.
Preferably, in the salt-making crystallization system, the evaporative crystallization device is a multiple-effect evaporation device, a single-effect evaporation device, an MVR (mechanical vapor recompression) evaporation device or a TVR (thermal vapor recompression) evaporation device.
Preferably, in the crystallization salt manufacturing system, the evaporation crystallization device is also connected with a slag dragging system.
Preferably, in the crystallization salt-making system, the effluent of the centrifugal dehydrator is refluxed to the evaporation crystallization device.
The main problem of the circulating water sewage is that the salt content is high, and if the circulating water sewage is used as circulating water supplement water, the salt content of the circulating water sewage needs to be reduced. Consequently the utility model discloses a reverse osmosis technology for processing system is as desalination technique, and reverse osmosis membrane device goes out water quality of water is fine, has not only removed the inorganic salt of the overwhelming majority, has also got rid of all kinds of organic pollutants, colloid, silica, virus, bacterium etc. and has very high clearance to various impurity in the aquatic moreover, therefore reverse osmosis membrane goes out water quality of water and can reach high standard water quality of water index, and reverse osmosis membrane goes out water and is fit for high-end water needs, improves the value of utilization of water resource. The key to reverse osmosis desalination system design is the choice of pretreatment. By adopting a reverse osmosis desalination process, incoming water is pretreated, and after three-stage softening, flocculating and precipitating treatment, substances such as magnesium, sulfate radicals, fluorine, heavy metals, suspended matters and the like in wastewater are removed. After the filtration treatment, the desalination treatment is carried out by first-stage reverse osmosis and seawater reverse osmosis. And (4) conveying the reverse osmosis effluent to a comprehensive recycling system, and allowing the seawater reverse osmosis concentrated water to enter a desulfurization wastewater treatment system.
Aiming at the characteristics of high salt content, high hardness, serious organic pollution, complex components and the like of the desulfurization wastewater, a three-stage softening reaction is adopted to remove substances such as magnesium, sulfate radicals, heavy metals and the like. Organic matters in the wastewater are removed through ozone advanced oxidation. Calcium, magnesium, sulfate radicals and the like in the wastewater are further removed from the ultrafiltration effluent through two-stage nanofiltration, the effluent subjected to the second-stage nanofiltration mainly contains NaCl, and then the desulfurization wastewater is subjected to decrement concentration and salt separation through a seawater reverse osmosis and homogeneous membrane ED device. And the high-salt concentrated solution is subjected to decarburization and deamination treatment and then passes through an evaporative crystallization device to finally form high-purity sodium chloride crystal salt which is used as a chemical raw material for resource utilization.
The utility model has the advantages that:
the utility model discloses a processing system has advantages such as high efficiency, reliable, economy. Use the utility model discloses a system treatment power plant waste water of making perfect factory, the flue gas after the desulfurization of softening part power plant replaces partial sodium carbonate, makes the pharmaceutical cost practice thrift about 75%. Meanwhile, 60-70% of sulfate radicals can be removed from the softened part, the purity and concentration of NaCl are further improved after the NaCl is treated by subsequent nanofiltration and ED devices, and the investment and cost of an evaporative crystallization system are reduced. The calcium carbonate precipitate generated in the softening process can be reused in a wet desulphurization system in the power plant. The method has the advantages that the zero discharge of the wastewater of the whole plant is realized, and simultaneously, the water, the calcium carbonate concentrated solution and the NaCl salt are recycled step by step, so that the zero discharge of the water and the resource utilization of the water and the solid waste are realized in a real sense.
The utility model discloses a concrete advantage as follows:
(1) lime is added into the wastewater in the first-stage softening flocculation precipitation step to remove substances such as magnesium, sulfate radicals, fluorine, heavy metals and the like, so that the content of the sulfate radicals in the water is reduced. Flue gas is added in the second-stage flocculation precipitation, so that the adding amount of sodium carbonate in the subsequent third-stage softening is reduced, and the operation cost of a softening and clarifying unit is reduced.
(2) The three-stage softening and clarifying device further removes suspended matters, hardness and the like in the wastewater, simultaneously realizes resource recovery of calcium carbonate, reduces adverse effects of calcium, magnesium and the like on subsequent devices, and the calcium carbonate separated in the step can be reused in a wet desulphurization system in a power plant.
(3) The desulfurization wastewater advanced treatment system realizes concentration of salinity and reduction of wastewater by jointly using two-stage nanofiltration, seawater reverse osmosis and homogeneous membrane ED devices, greatly reduces the content of sodium sulfate in high-salt concentrated solution, improves the purity of sodium chloride, simplifies an evaporative crystallization system, and saves investment and cost of the system.
Drawings
FIG. 1 is a schematic diagram of the system for zero discharge of wastewater and resource utilization in a whole plant of a power plant;
FIG. 2 is a schematic view of a circulating water blowdown water treatment system;
FIG. 3 is a schematic diagram of a desulfurization wastewater treatment system;
FIG. 4 is a schematic diagram of a crystallization salt production system;
FIG. 5 is a schematic diagram of a crystallization salt production system with an evaporative crystallization device being an MVR evaporative crystallization device.
Detailed Description
The present invention will be described in further detail with reference to specific examples. The starting materials or the apparatuses used in the examples were obtained from conventional commercial sources unless otherwise specified. The utility model discloses each system, equipment or device "be connected", "connect" if do not have special explanation, be through connections such as pipeline, belong to the conventional technique in this field.
Examples
Referring to the attached figure 1, the system for zero discharge of wastewater and resource utilization of the whole plant of the power plant comprises a circulating water sewage treatment system, a desulfurization wastewater treatment system and a crystallization salt making system. Wherein, the schematic diagram of the circulating water sewage treatment system can be seen in attached figure 2, the schematic diagram of the desulfurization wastewater treatment system can be seen in attached figure 3, and the schematic diagram of the crystallization salt preparation system can be seen in attached figure 4.
Referring to fig. 2, the circulating water sewage treatment system in the system comprises a first-stage flocculation sedimentation tank, a second-stage flocculation sedimentation tank, a third-stage flocculation sedimentation tank, a regulating tank, a multi-media filter, an ozone catalytic oxidation tower, a biological activated carbon filter, a self-cleaning filter, an ultrafiltration device, a reverse osmosis device, a flocculation tank, a microfiltration device and a seawater reverse osmosis device which are sequentially connected through pipelines.
In the circulating water sewage treatment system, a first-stage flocculation sedimentation tank is connected with a lime feeding device, a second-stage flocculation sedimentation tank is connected with a flue gas pipe, and a third-stage flocculation sedimentation tank is connected with a sodium carbonate feeding device. The sludge outlet of the primary flocculation sedimentation tank is also connected with a concentration tank and a dehydrator, and the sludge after dehydration treatment is transported outside. And (4) respectively conveying the sediments generated by the second-stage flocculation sedimentation tank and the third-stage flocculation sedimentation tank to a sludge concentration tank, and then conveying the sediments to a wet desulphurization system of a power plant for treatment, such as returning to a desulphurization absorption tower for treatment. The adjusting tank is used for adding acid to adjust the pH value. The fresh water outlet of the ultrafiltration device is connected with the water inlet of the reverse osmosis device. The concentrated water outlet of the reverse osmosis device is connected with the water inlet of the flocculation tank, and the fresh water outlet of the reverse osmosis device is connected with the fresh water comprehensive recycling system. The flocculation tank is connected with a double-alkali adding device, and double alkali (sodium hydroxide and calcium hydroxide) is used for flocculation treatment. The concentrated water outlet of the seawater reverse osmosis device is connected with the water storage regulating tank of the desulfurization wastewater treatment system, and the fresh water outlet of the seawater reverse osmosis device is connected with the fresh water comprehensive recycling system. Concentrated water of the multi-medium filter, the biological activated carbon filter, the self-cleaning filter and the ultrafiltration device respectively flows back to a water inlet of the three-stage flocculation sedimentation tank for circular treatment.
Referring to fig. 3, the desulfurization wastewater treatment system in the system comprises a water storage regulating reservoir, a primary softening reservoir, a tubular filtration membrane device, a secondary softening clarification reservoir, a tertiary softening clarification reservoir, a multi-medium filter, an ozone advanced oxidation tower, an activated carbon bed, an ultrafiltration device, a primary nanofiltration device, a secondary nanofiltration device, a seawater reverse osmosis device, a homogeneous membrane ED device, a decarburization deamination device and a buffer tank which are sequentially connected through pipelines.
In the desulfurization wastewater treatment system, a fresh water outlet of the ultrafiltration device is connected with a water inlet of the primary nanofiltration device. The concentrated water outlet of the first-stage nanofiltration device is connected with the water storage regulating reservoir, and the fresh water outlet of the first-stage nanofiltration device is connected with the water inlet of the second-stage nanofiltration device. The concentrated water outlet of the second-stage nanofiltration device is connected with the water inlet of the first-stage nanofiltration device, and the fresh water outlet of the second-stage nanofiltration device is connected with the water inlet of the seawater reverse osmosis device. The concentrated water outlet of the seawater reverse osmosis device is connected with the water inlet of the homogeneous membrane ED device, and the fresh water outlet of the seawater reverse osmosis device is connected with the industrial water system for recycling. The concentrated water outlet of the homogeneous membrane ED device is connected with the water inlet of the decarburization deamination device, and the fresh water outlet of the homogeneous membrane ED device is connected with the water inlet of the reverse osmosis device in the circulating water sewage treatment system and is subjected to the fresh water synergistic treatment in the salt concentration link. The first-stage softening tank is connected with a lime feeding device, the second-stage softening clarification tank is connected with a flue gas pipe, and the third-stage softening clarification tank is connected with a sodium carbonate feeding device. The sludge outlet of the primary softening tank is also connected with a dehydrator and is transported outside after dehydration; the effluent of the dehydrator flows back to the water storage adjusting tank. And precipitates generated by the second-stage softening clarification tank and the third-stage softening clarification tank are respectively conveyed to a sludge concentration tank and then conveyed to a wet desulphurization system of a power plant for treatment, such as flowing back to a desulphurization absorption tower for treatment. The decarburization deamination device is connected with a standby overhaul pool besides being connected with a buffer pool. And the high-salt concentrated solution output by the buffer tank or the overhaul standby tank is conveyed to an evaporative crystallization device of a crystallization salt manufacturing system for treatment. The concentrated water of the multi-medium filter, the activated carbon bed and the ultrafiltration device respectively flows back to the water inlet of the three-stage softening clarification tank for circular treatment.
Referring to fig. 4, the crystallization salt production system in the system comprises an evaporative crystallization device, a centrifugal dehydrator, a drying fluidized bed and a salt bin which are sequentially connected through pipelines. The fresh water outlet of the evaporative crystallization device is connected with the water inlet of a reverse osmosis device in the circulating water sewage disposal system, and the water outlet of the evaporative crystallization device is used for circulating water make-up water. The evaporative crystallization device is also connected with a slag dragging system. And the effluent of the centrifugal dehydrator flows back to the evaporation crystallization device. The materials in the salt bin are packed, subpackaged, stored and transported outside.
Referring to fig. 5, when the evaporative crystallization apparatus is specifically selected from the MVR evaporative crystallization apparatus, the crystallization salt production system in such a system comprises a heat exchanger, an evaporative crystallizer, a centrifugal dehydrator, a drying fluidized bed, and a salt bin, which are sequentially connected by a pipeline; the evaporative crystallizer is connected with the heat exchanger through an MVR vapor compressor. The fresh water outlet of the heat exchanger is connected with the water inlet of a reverse osmosis device in the circulating water sewage disposal system, and the water outlet of the heat exchanger is used for circulating water make-up water. The evaporative crystallizer is also connected with a slag dragging system. And the effluent of the centrifugal dehydrator flows back to the evaporation crystallizer. The materials in the salt bin are packed, subpackaged, stored and transported outside.
The processing system through this embodiment handles the whole factory waste water of power plant, and circulating water blowdown water, chemical desalination waste water, the input one-level flocculation and precipitation pond such as smart high salinity waste water in the whole factory waste water of power plant get into circulating water blowdown water processing system and handle. The RO concentrated water and the desulfurization wastewater treated by the seawater reverse osmosis device of the circulating water sewage treatment system are input into a water storage regulating reservoir and enter a desulfurization wastewater treatment system for treatment. And (3) inputting the high-salt concentrated solution obtained by the buffer tank and/or the overhaul standby tank of the desulfurization wastewater treatment system into an evaporative crystallization device, and treating by a crystallization salt preparation system to obtain NaCl crystallized salt.
The treatment system of this embodiment uses first order flocculation and precipitation pond to use lime as softening agent, reacts with magnesium and sulfate radical and generates magnesium hydroxide, calcium sulfate deposit, adds the poly iron and promotes the particulate matter deposit, handles outward after the dehydration. The flue gas desulfurized by the power plant is added into the secondary flocculation sedimentation tank, and CO in the flue gas2React with calcium to generate calcium carbonate precipitate. And adding a small amount of sodium carbonate into the third-stage flocculation precipitation to further remove calcium in the wastewater. 60 to 70 percent of sulfate radical can be removed by the first-stage flocculation precipitation. The cost of the medicament can be saved by about 75 percent. Calcium carbonate precipitates generated by the second-level flocculation precipitation reaction and the third-level flocculation precipitation reaction can be reused in a wet desulphurization system in a power plant after being concentrated by a concentration tank. Fresh water generated by the reverse osmosis device and the seawater reverse osmosis device in the circulating water sewage treatment system is conveyed to a fresh water recovery system for comprehensive recycling. NaCl crystal salt obtained by the crystallization salt-making system can be sold as a chemical raw material.
The utility model discloses a processing system can get rid of 60% ~ 70% sulfate radical through lime softening, and the second grade is softened and is utilized the flue gas to replace partial sodium carbonate, and the agent cost can be practiced thrift about 75% under the condition that the effect satisfies is got rid of to hardness, and the calcium carbonate sediment of formation can be reused in wet desulfurization system in the power plant. The high-purity NaCl high-salt solution can be obtained by the synergistic action of the nanofiltration device, the reverse osmosis device and the homogeneous phase membrane ED device, and can be sold as a chemical raw material after evaporation and crystallization. The whole-plant wastewater realizes the quality-based extraction and resource utilization of wastewater components while realizing zero discharge of water, thoroughly solves the problems of the wastewater of the power plant, and has important economic and environmental benefits.
Claims (10)
1. The utility model provides a system for power plant's whole factory waste water zero release and utilization, its characterized in that: comprises a circulating water sewage treatment system, a desulfurization wastewater treatment system and a crystallization salt production system;
the circulating water sewage treatment system comprises a primary flocculation sedimentation tank, a secondary flocculation sedimentation tank, a tertiary flocculation sedimentation tank, a regulating tank, a multi-media filter, an ozone catalytic oxidation tower, a biological activated carbon filter, a self-cleaning filter, an ultrafiltration device, a reverse osmosis device, a flocculation tank, a microfiltration device and a seawater reverse osmosis device which are sequentially connected through pipelines;
the desulfurization wastewater treatment system comprises a water storage regulating tank, a primary softening tank, a tubular filtering membrane device, a secondary softening clarification tank, a tertiary softening clarification tank, a multi-medium filter, an ozone advanced oxidation tower, an activated carbon bed, an ultrafiltration device, a primary nanofiltration device, a secondary nanofiltration device, a seawater reverse osmosis device, a homogeneous membrane ED device, a decarburization deamination device and a buffer tank which are sequentially connected through pipelines;
the crystallization salt-making system comprises an evaporative crystallization device, a centrifugal dehydrator, a drying fluidized bed and a salt bin which are sequentially connected through pipelines;
the concentrated water outlet of the seawater reverse osmosis device of the circulating water sewage treatment system is connected with the water storage regulating tank of the desulfurization wastewater treatment system; the buffer tank of the desulfurization wastewater treatment system is connected with an evaporative crystallization device of a crystallization salt production system;
the primary flocculation sedimentation tank and the primary softening tank are respectively connected with a lime feeding device; the secondary flocculation sedimentation tank and the secondary softening clarification tank are respectively connected with a flue gas pipe; the third-stage flocculation sedimentation tank and the third-stage softening clarification tank are respectively connected with a sodium carbonate feeding device.
2. The system for zero discharge of wastewater and resource utilization in a whole plant of a power plant according to claim 1, characterized in that: and sludge outlets of the second-stage flocculation sedimentation tank, the third-stage flocculation sedimentation tank, the second-stage softening clarification tank and the third-stage softening clarification tank are respectively connected with a sludge concentration tank, and the sludge concentration tank is connected with a wet desulphurization system of a power plant.
3. The system for zero discharge of wastewater and resource utilization in a whole plant of a power plant according to claim 1, characterized in that: in the circulating water sewage treatment system, fresh water outlets of a reverse osmosis device and a seawater reverse osmosis device are respectively connected with a fresh water comprehensive recycling system; a concentrated water outlet of the reverse osmosis device is connected with a water inlet of the flocculation tank; the water inlet of the reverse osmosis device is connected with the fresh water outlet of the ultrafiltration device.
4. The system for zero discharge of wastewater and resource utilization in a whole plant of a power plant according to claim 1, characterized in that: in the circulating water sewage treatment system, concentrated water outlets of the multi-medium filter, the biological activated carbon filter, the self-cleaning filter and the ultrafiltration device are respectively connected with a water inlet of the three-stage flocculation sedimentation tank.
5. The system for zero discharge of wastewater and resource utilization in a whole plant of a power plant according to claim 1, characterized in that: in the desulfurization wastewater treatment system, a water inlet of a primary nanofiltration device is respectively connected with a fresh water outlet of an ultrafiltration device and a concentrated water outlet of a secondary nanofiltration device, the concentrated water outlet of the primary nanofiltration device is connected with a water storage regulating tank, and the fresh water outlet of the primary nanofiltration device is connected with the water inlet of the secondary nanofiltration device; the fresh water outlet of the second-stage nanofiltration device is connected with the water inlet of the seawater reverse osmosis device.
6. The system for zero discharge and resource utilization of wastewater from a whole plant of a power plant according to claim 1 or 5, characterized in that: in the desulfurization wastewater treatment system, a fresh water outlet of a seawater reverse osmosis device is connected with an industrial water system, and a concentrated water outlet of the seawater reverse osmosis device is connected with a water inlet of a homogeneous membrane ED device.
7. The system for zero discharge and resource utilization of wastewater from a whole plant of a power plant according to claim 6, characterized in that: in the desulfurization wastewater treatment system, the fresh water outlet of the homogeneous membrane ED device is connected with the water inlet of a reverse osmosis device in the circulating water sewage treatment system, and the concentrated water outlet of the homogeneous membrane ED device is connected with the water inlet of the decarburization deamination device.
8. The system for zero discharge of wastewater and resource utilization in a whole plant of a power plant according to claim 1, characterized in that: in the desulfurization wastewater treatment system, concentrated water outlets of the multi-media filter, the activated carbon bed and the ultrafiltration device are respectively connected with a water inlet of the three-stage softening clarification tank.
9. The system for zero discharge of wastewater and resource utilization in a whole plant of a power plant according to claim 1, characterized in that: in the crystallization salt-making system, a fresh water outlet of the evaporative crystallization device is connected with a water inlet of a reverse osmosis device in the circulating water sewage treatment system.
10. The system for zero discharge and resource utilization of wastewater from a whole plant of a power plant according to claim 1 or 9, characterized in that: in the crystallization salt-making system, the evaporation crystallization device is a multi-effect evaporation device, a single-effect evaporation device, an MVR evaporation device or a TVR evaporation device.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201920880780.1U CN210595643U (en) | 2019-06-12 | 2019-06-12 | System for zero release of power plant's whole factory waste water and resource utilization |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201920880780.1U CN210595643U (en) | 2019-06-12 | 2019-06-12 | System for zero release of power plant's whole factory waste water and resource utilization |
Publications (1)
Publication Number | Publication Date |
---|---|
CN210595643U true CN210595643U (en) | 2020-05-22 |
Family
ID=70692493
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201920880780.1U Active CN210595643U (en) | 2019-06-12 | 2019-06-12 | System for zero release of power plant's whole factory waste water and resource utilization |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN210595643U (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110316897A (en) * | 2019-06-12 | 2019-10-11 | 北京浦仁美华环保科技股份有限公司 | A kind of system and method for the full factory waste water zero discharge of power plant and resource utilization |
-
2019
- 2019-06-12 CN CN201920880780.1U patent/CN210595643U/en active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110316897A (en) * | 2019-06-12 | 2019-10-11 | 北京浦仁美华环保科技股份有限公司 | A kind of system and method for the full factory waste water zero discharge of power plant and resource utilization |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Xin et al. | A two-stage desalination process for zero liquid discharge of flue gas desulfurization wastewater by chloride precipitation | |
CN105645439B (en) | A kind of system and its technique that potassium sulfate is prepared using high saliferous industrial wastewater | |
CN100450592C (en) | Metal smelting factory sewage reclaiming method based on membrane filtering technique | |
CN110316897A (en) | A kind of system and method for the full factory waste water zero discharge of power plant and resource utilization | |
CN105236627B (en) | Papermaking tail water/recycled water reusing zero-discharge processing method | |
CN111170544A (en) | Activated coke desulfurization, denitrification and gas-rich salt production pretreatment wastewater zero discharge system and method | |
CN110950474A (en) | Phenol-cyanogen wastewater resource zero-discharge method and process | |
CN107721037A (en) | A kind of high ammonia nitrogen desulfurization wastewater processing up to standard and reclaiming system and method | |
CN105923820A (en) | Near zero emission treatment process for flue gas desulfurization waste water | |
CN102976511A (en) | Coking wastewater membrane filtration concentrate recycle method | |
CN104108813A (en) | Refining sewage desalination integrated treatment process and device | |
CN112794500B (en) | Coking wastewater strong brine near-zero emission treatment system and treatment method thereof | |
CN214141977U (en) | Treatment system for treating desulfurization wastewater by using de-hardening electrodialysis | |
CN116282688B (en) | System and method for recycling urea hydrolysis wastewater | |
CN207567040U (en) | A kind of processing up to standard of high ammonia nitrogen desulfurization wastewater and reclaiming system | |
CN112573720A (en) | Thermal power plant desulfurization wastewater zero-discharge system and method | |
CN210595643U (en) | System for zero release of power plant's whole factory waste water and resource utilization | |
CN114516689A (en) | Calcium carbide method polyvinyl chloride mercury-containing wastewater treatment and recycling method and application device thereof | |
CN107055886B (en) | A kind of depth graded divides salt technique | |
CN210559895U (en) | System for zero release of power plant's whole factory waste water and utilization | |
CN113896370A (en) | Novel mine water zero discharge system and method | |
CN211999295U (en) | Zero discharge system for active coke desulfurization and denitrification gas-rich salt-making pretreatment wastewater | |
CN210656480U (en) | Adopt washing cigarette waste water retrieval and utilization processing apparatus of DTRO device | |
CN210559894U (en) | Zero release and resource utilization system of whole factory of power plant waste water | |
CN107055907A (en) | A kind of GTCC power plant wastewater zero discharge processing unit and handling process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
GR01 | Patent grant | ||
GR01 | Patent grant |