CN209612678U - A kind of pipeline static mixing mineralization device - Google Patents
A kind of pipeline static mixing mineralization device Download PDFInfo
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- CN209612678U CN209612678U CN201920232469.6U CN201920232469U CN209612678U CN 209612678 U CN209612678 U CN 209612678U CN 201920232469 U CN201920232469 U CN 201920232469U CN 209612678 U CN209612678 U CN 209612678U
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Abstract
Description
技术领域technical field
本实用新型属于矿山设备浮选技术领域,尤其涉及一种管道静态混合矿化装置。The utility model belongs to the technical field of flotation of mining equipment, in particular to a pipeline static mixing mineralization device.
背景技术Background technique
在矿物分选中,微细粒矿物的浮选回收一直是矿物加工领域的难题。随着矿产资源的贫细杂化,细粒级的矿石所占比重不断提高,此外,磨矿环节在磨细矿石的同时产生了大量的次生细泥,这导致了浮选过程中微细粒矿石占有一定的比例。然而微细粒矿物由于体积微小,在调浆过程中与浮选药剂的碰撞几率小,使得浮选药剂无法很好地与矿物颗粒作用,导致含有有价金属的微细粒矿物在浮选过程中无法粘附气泡而大量损失在尾矿中,造成了资源的大量流失。In mineral sorting, the flotation recovery of fine-grained minerals has always been a difficult problem in the field of mineral processing. With the poor and fine hybridization of mineral resources, the proportion of fine-grained ore continues to increase. In addition, the grinding process produces a large amount of secondary fine mud while grinding the ore, which leads to fine particle size in the flotation process. Ore occupies a certain proportion. However, due to the small size of the fine-grained minerals, the probability of collision with the flotation reagents during the slurry mixing process is small, so that the flotation reagents cannot interact with the mineral particles well, resulting in the fine-grained minerals containing valuable metals. Adhering to air bubbles results in a large amount of loss in the tailings, resulting in a large loss of resources.
增大颗粒的表观粒径是实现微细粒矿物有效分选的主要途径之一。增大颗粒的表观粒径,实现微细粒矿物的常规浮选,主要途径是在矿浆充分分散的前提下,使微细粒矿物选择性疏水化,形成聚团,然后再用适当方法加以分离,相关的工艺统称为“疏水絮凝分选法”,如剪切絮凝浮选等。剪切絮凝理论基本思想是在细粒悬浮体系中加入表面活性剂(捕收剂),然后通过高速搅拌产生足够大的剪切力,使吸附有表面活性剂的微细粒矿物水化膜破裂而聚集成团,从而增大其表观直径,再用泡沫浮选法将絮体浮出。为形成足够大的剪切力,传统的搅拌器在运行时搅拌桨需要很高的转速,然而高转速需要很高的能量消耗,同时对设备的磨损也很严重。而静态混合器是将静态混合元件以一定的排列方式固定在管路中所形成的管道式混合器。它的内部没有运动部件,主要运用流体流动和内部单元实现各种流体的混合。静态混合器与其它设备相比较具有效率高、能耗低、体积小等优点。Enlarging the apparent particle size of particles is one of the main ways to achieve effective separation of fine-grained minerals. To increase the apparent particle size of the particles and realize the conventional flotation of fine-grained minerals, the main way is to make the fine-grained minerals selectively hydrophobized under the premise that the pulp is fully dispersed to form agglomerates, and then separate them by appropriate methods. The related processes are collectively referred to as "hydrophobic flocculation separation method", such as shear flocculation flotation and so on. The basic idea of shear flocculation theory is to add surfactants (collectors) to the fine particle suspension system, and then generate sufficient shear force through high-speed stirring, so that the microfine mineral hydration film adsorbed by surfactants is broken and Aggregate into clusters to increase their apparent diameter, and then use froth flotation to float the flocs out. In order to form a large enough shearing force, the traditional agitator needs a very high rotation speed when the stirring blade is running. However, the high rotation speed requires high energy consumption, and the wear on the equipment is also very serious. The static mixer is a pipeline mixer formed by fixing the static mixing elements in the pipeline in a certain arrangement. It has no moving parts inside and mainly uses fluid flow and internal units to achieve the mixing of various fluids. Compared with other equipment, the static mixer has the advantages of high efficiency, low energy consumption and small volume.
但混合器内部单元组件的设计对混合器的效果起到至关重要的作用,专利201220559884.0公开了一种管式静态混合器,混合单元包括平行的两排以上且纵横交错的条板,4-12个混合单元设置在管体液体混合段内,且各混合单元的条板沿管体截面依次斜置和平行间隔设置。上述专利的静态混合器仍然不够完善,流体在管体内的混合分割和移位不够充分,导致混合效果不佳,无法实现浮选药剂与微细颗粒矿物的充分作用。However, the design of the internal unit components of the mixer plays a crucial role in the effect of the mixer. Patent 201220559884.0 discloses a tubular static mixer. The mixing unit includes more than two parallel rows of criss-cross strips, 4- Twelve mixing units are arranged in the liquid mixing section of the pipe body, and the slats of each mixing unit are arranged obliquely and at intervals in parallel along the cross section of the pipe body. The static mixer of the above-mentioned patent is still not perfect, and the mixing, division and displacement of the fluid in the tube body are not sufficient, resulting in poor mixing effect, and cannot realize the full effect of the flotation agent and fine particle minerals.
实用新型内容Utility model content
本申请旨在至少解决现有技术中存在的技术问题之一。为此,本实用新型的目的之一在于提供一种管道静态混合矿化装置,该管道静态混合矿化装置可以利用管体内大量规律排布的混合单元和螺纹收缩器实现对微细粒矿物与浮选药剂的充分混合,具有混合均匀、能耗低、工作稳定性强等优点。This application aims to solve at least one of the technical problems existing in the prior art. For this reason, one of the purposes of this utility model is to provide a pipeline static mixing and mineralization device, which can utilize a large number of regularly arranged mixing units and thread shrinkers in the pipeline to realize the separation of fine grained minerals and floating minerals. The full mixing of selected agents has the advantages of uniform mixing, low energy consumption, and strong working stability.
为解决上述技术问题,本申请采用如下技术方案:In order to solve the above technical problems, the application adopts the following technical solutions:
一种管道静态混合矿化装置,包括管体和设置于所述管体内的至少两个混合单元,所述管体一端与喷枪对接,另一端为出口端,所述混合单元包括平行的两排以上且纵横交错的条板,且各混合单元的条板沿管体轴向依次斜置和平行间隔设置,所述管体内位于相邻两混合单元之间还设有螺纹收缩器,螺纹收缩器呈中空管体状,包括朝向管体出口方向顺次连接的收缩段、平直段和扩散段,所述平直段的内壁上设有轴向延伸的螺纹。A pipeline static mixing and mineralization device, comprising a pipe body and at least two mixing units arranged in the pipe body, one end of the pipe body is connected to a spray gun, and the other end is an outlet end, and the mixing units include two parallel rows The above and crisscross slats, and the slats of each mixing unit are arranged obliquely and parallelly spaced along the axial direction of the pipe body, and the pipe body is located between two adjacent mixing units. A threaded retractor is also provided. It is in the shape of a hollow tube body, and includes a constriction section, a straight section and a divergence section sequentially connected towards the outlet of the tube body, and the inner wall of the straight section is provided with axially extending threads.
进一步的,相邻两个螺纹收缩器的螺纹旋向相反。Further, the threads of two adjacent thread retractors have opposite directions of rotation.
进一步的,所述喷枪的轴线与所述管体的轴线重合。Further, the axis of the spray gun coincides with the axis of the pipe body.
进一步的,所述收缩段、平直段和扩散段的长度比例为1:2:1。Further, the length ratio of the contracted section, the straight section and the diffused section is 1:2:1.
进一步的,所述收缩段和扩散段的纵截面为锥形,其锥角为90~100°。Further, the longitudinal sections of the constricting section and the diffusing section are conical, with a cone angle of 90-100°.
进一步的,所述平直段螺纹大径与小径的比值为2:1。Further, the ratio of the major diameter to the minor diameter of the straight section thread is 2:1.
进一步的,所述混合单元的条板与管体轴线的水平夹角为40~45°。Further, the horizontal angle between the slats of the mixing unit and the axis of the pipe body is 40-45°.
与现有技术相比,本实用新型具有如下有益效果:Compared with the prior art, the utility model has the following beneficial effects:
1.利用管体内大量规律排布的混合单元和螺纹收缩器,使流体发生剪切、分流、合流、旋转及变向等运动,从而实现微细粒矿物与浮选药剂的充分混合。1. Using a large number of regularly arranged mixing units and threaded constrictors in the pipe body, the fluid can be sheared, split, merged, rotated and changed direction, so as to realize the full mixing of fine-grained minerals and flotation reagents.
2.可适用于液—液、液—固、液—气相混合。2. Applicable to liquid-liquid, liquid-solid, liquid-gas mixing.
3.分化过程时能使液滴分散到2-5um,不均匀度系数sX≤5%。3. During the differentiation process, the droplets can be dispersed to 2-5um, and the unevenness coefficient sX≤5%.
4.具有混合均匀、无运动构件、维护费用低、能耗低、工作稳定性强等优点。4. It has the advantages of uniform mixing, no moving parts, low maintenance cost, low energy consumption, and strong working stability.
5.可以串联进行使用。5. Can be used in series.
附图说明Description of drawings
图1为本实用新型的结构示意图;Fig. 1 is the structural representation of the utility model;
图2为本实用新型螺纹收缩器结构示意图;Fig. 2 is a structural schematic diagram of the utility model thread retractor;
图3为本实用新型使用示意图。Figure 3 is a schematic view of the utility model.
具体实施方式Detailed ways
下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有作出创造性劳动前提下所获得的所有其他实施例,都属于本实用新型保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. example. Based on the embodiments of the present utility model, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the scope of protection of the present utility model.
参见图1和图2,一种管道静态混合矿化装置,包括管体1、喷枪2、混合单元3、螺纹收缩器4、法兰5,管体1一端与法兰5相连,管体1的另一端与喷枪2相连,喷枪2的另一端也连接有法兰,混合单元3的具体结构与专利201220559884.0中的结构相同,包括平行的两排以上且纵横交错的条板31,若干个混合单元3设置在管体1内,且各混合单元3的条板31沿管体轴向依次斜置和平行间隔设置。至于混合单元的具体数量,本领域技术人员可以根据实际混合需要进行调整。管体1内位于相邻两混合单元之间还设有螺纹收缩器4,螺纹收缩器4呈中空管体状,包括朝向管体出口方向顺次连接的收缩段41、平直段42和扩散段43,平直段42的内壁上设有轴向延伸的螺纹。Referring to Fig. 1 and Fig. 2, a pipeline static mixing and mineralization device includes a pipe body 1, a spray gun 2, a mixing unit 3, a thread constrictor 4, and a flange 5. One end of the pipe body 1 is connected to the flange 5, and the pipe body 1 The other end of the spray gun 2 is connected to the other end of the spray gun 2, and the other end of the spray gun 2 is also connected to a flange. The specific structure of the mixing unit 3 is the same as that in the patent 201220559884.0, including more than two parallel rows of slats 31 criss-crossing, several mixing The units 3 are arranged in the pipe body 1 , and the slats 31 of each mixing unit 3 are arranged obliquely and parallel to each other along the axial direction of the pipe body. As for the specific number of mixing units, those skilled in the art can make adjustments according to actual mixing needs. The pipe body 1 is also provided with a threaded constrictor 4 between two adjacent mixing units. The threaded constrictor 4 is in the shape of a hollow pipe body and includes a constriction section 41, a straight section 42 and a The inner walls of the diffuser section 43 and the straight section 42 are provided with axially extending threads.
本实用新型的工作原理如下:矿浆与浮选药剂混合后,经压力泵进入管道静态混合矿化装置的喷枪2,矿浆经喷枪2高速喷射进入管体1,矿浆经过交替设置的混合单元3和螺纹收缩器4,发生剪切、分流、合流、旋转及变向等运动,最终从管体1一端排出。管道静态混合矿化装置中液液分散过程包含分散混合和分布混合两种行为,其中分散混合是液滴破裂和液滴集聚并最终实现动态平衡的过程,分布混合是两相浓度在空间上最终实现均匀分布的过程。两个过程皆沿着管道静态混合矿化装置的长度方向上不断发展。矿浆在螺纹收缩器4的收缩段41由于管体横截面的缩小导致压力逐渐向动能转化,流速加快,在经过平直段42时矿浆会沿着螺纹发生旋转,使得矿浆充分混合,旋转的矿浆流出螺纹段进入扩散段43,由于扩散段43横截面的突然增大,导致矿浆的动能逐渐转化为压力能,从而进入下一个混合单元。混合单元3和螺纹收缩器4的间隔排布,使得矿浆和浮选药剂都能够得到良好分散,从而实现矿浆与浮选药剂的充分均匀混合。The working principle of the utility model is as follows: After the ore pulp is mixed with the flotation agent, it enters the spray gun 2 of the pipeline static mixing mineralization device through the pressure pump, and the ore pulp enters the pipe body 1 through the spray gun 2 at high speed, and the ore pulp passes through alternately arranged mixing units 3 and The thread constrictor 4 undergoes movements such as shearing, splitting, merging, rotating and changing directions, and is finally discharged from one end of the pipe body 1 . The liquid-liquid dispersion process in the pipeline static mixing mineralization device includes two behaviors: dispersive mixing and distributive mixing. Dispersive mixing is the process of droplet breakup and droplet aggregation and finally achieves dynamic equilibrium. The process of achieving an even distribution. Both processes develop continuously along the length of the pipe static mixing mineralization unit. In the constriction section 41 of the screw constrictor 4, due to the reduction of the cross-section of the pipe body, the pressure is gradually transformed into kinetic energy, and the flow velocity is accelerated. When the pulp passes through the straight section 42, the pulp will rotate along the thread, so that the pulp is fully mixed, and the rotating pulp The flow out of the threaded section enters the diffuser section 43. Due to the sudden increase in the cross-section of the diffuser section 43, the kinetic energy of the slurry is gradually converted into pressure energy, and then enters the next mixing unit. The spaced arrangement of the mixing unit 3 and the threaded constrictor 4 enables both the pulp and the flotation agent to be well dispersed, thereby achieving sufficient and uniform mixing of the ore pulp and the flotation agent.
参见图1和图2,为进一步提高混合效率,相邻两个螺纹收缩器4的螺纹旋向相反,喷枪2的轴线与管体1的轴线重合,收缩段41、平直段42和扩散段43的长度比例为1:2:1,收缩段41和扩散段43的纵截面为锥形,其锥角为90~100°,平直段42螺纹大径与小径的比值为2:1。Referring to Fig. 1 and Fig. 2, in order to further improve the mixing efficiency, the helical direction of two adjacent thread constrictors 4 is opposite, the axis of the spray gun 2 coincides with the axis of the pipe body 1, and the constriction section 41, the straight section 42 and the diffusion section The length ratio of 43 is 1:2:1, the longitudinal section of the constriction section 41 and the diffusion section 43 is conical, and the taper angle is 90-100°, and the ratio of the major diameter to the minor diameter of the straight section 42 is 2:1.
参见图3,一种管道静态混合矿化装置的使用方法,矿浆6与浮选药剂7在搅拌桶8中进行混合,经加压泵9进入管道静态混合矿化装置,而后矿浆经充分作用后从管道静态混合矿化装置一端排出,经串联的管道静态混合矿化装置进行再次混合,最终排出混合后的矿浆。Referring to Figure 3, a method of using a pipeline static mixing mineralization device, the ore pulp 6 and the flotation agent 7 are mixed in the mixing tank 8, and then enter the pipeline static mixing mineralization device through the booster pump 9, and then the ore pulp is fully processed It is discharged from one end of the static mixing and mineralizing device of the pipeline, mixed again through the static mixing and mineralizing device of the pipeline in series, and finally the mixed pulp is discharged.
以下将结合具体的应用例对本实用新型作进一步的说明。The utility model will be further described below in conjunction with specific application examples.
应用例1Application example 1
试验物料取自衡阳远景钨业有限责任公司的半风化砂岩钨矿石,其钨矿石嵌布粒度较细。矿石经脱硫后得到浓度为30%左右的矿浆作为实验给矿原料,其WO3品位为0.31%。矿浆加入pH调整剂碳酸钠调节矿浆pH为8.0,然后加入抑制剂水玻璃,随后加入脂肪酸捕收剂GYR,矿浆经预调浆后,经加压泵给入管道静态混合矿化装置进行矿浆与浮选药剂的充分混合调浆。充分调浆后的矿浆进入浮选机进行浮选,经一粗三精三扫,得到最终的钨粗精矿。捕收剂相对原矿的加入量为100g/t,抑制剂相对原矿的加入量为600g/t,pH调整剂碳酸钠相对原矿的加入量为500g/t,浮选温度为25℃。试验获得粗精矿WO3品位5.82%,回收率55.56%(如表1)。The test materials are taken from the semi-weathered sandstone tungsten ore of Hengyang Yuanjing Tungsten Industry Co., Ltd., and the tungsten ore has a finer particle size. After the ore is desulfurized, the pulp with a concentration of about 30% is used as the ore feed material for the experiment, and its WO 3 grade is 0.31%. Add pH regulator sodium carbonate to the pulp to adjust the pH of the pulp to 8.0, then add inhibitor water glass, and then add fatty acid collector GYR. Fully mixing and slurrying of flotation reagents. The fully adjusted ore pulp enters the flotation machine for flotation, and the final tungsten rough concentrate is obtained through one rough, three fine and three sweeps. The amount of collector added relative to the original ore is 100g/t, the amount of inhibitor added relative to the original ore is 600g/t, the amount of pH regulator sodium carbonate added relative to the original ore is 500g/t, and the flotation temperature is 25°C. The crude concentrate WO 3 grade was 5.82%, and the recovery rate was 55.56% (as shown in Table 1).
表1远景钨业钨矿的管道静态混合矿化装置试验结果Table 1 Test results of pipeline static mixed mineralization device of Yuanjing Tungsten Mine
应用例2Application example 2
试验物料取自宁化行洛坑钨矿有限公司,原矿经旋流器分级得到-10um粒级的微细粒钨矿石的矿浆作为实验给矿原料,其浓度为10%左右,其WO3品位为0.14%。矿浆加入pH调整剂碳酸钠调节矿浆pH为9.0,随后加入活化剂硝酸铅,然后加入捕收剂GYR和GYB,矿浆经预调浆后,经加压泵给入管道静态混合矿化装置进行矿浆与浮选药剂的充分混合调浆。充分调浆后的矿浆进入浮选机进行浮选,经一粗两精两扫,得到最终的钨粗精矿。活化剂相对原矿的加入量为200g/t,捕收剂相对原矿的加入量为GYR 50g/t、GYB200g/t,pH调整剂碳酸钠相对原矿的加入量为600g/t,浮选温度为25℃。试验获得粗精矿WO3品位3.16%,回收率52.39%(如表2)。The test material is taken from Ninghuahang Luokeng Tungsten Mine Co., Ltd. The raw ore is graded by a cyclone to obtain a slurry of fine-grained tungsten ore with a particle size of -10um as the raw material for the experiment. The concentration is about 10%, and its WO 3 grade is 0.14%. Add pH regulator sodium carbonate to the pulp to adjust the pH of the pulp to 9.0, then add activator lead nitrate, and then add collectors GYR and GYB. Fully mixed with flotation reagents for pulping. The fully adjusted ore pulp enters the flotation machine for flotation, and the final rough concentrate of tungsten is obtained through one rough, two fine and two sweeps. The amount of activator added to the original ore is 200g/t, the amount of collector added to the original ore is GYR 50g/t, GYB200g/t, the amount of pH regulator sodium carbonate added to the original ore is 600g/t, and the flotation temperature is 25 ℃. The crude concentrate WO 3 grade obtained in the test was 3.16%, and the recovery rate was 52.39% (as shown in Table 2).
表2行洛坑钨矿的管道静态混合矿化装置试验结果Table 2 Test results of pipeline static mixed mineralization device in Luokeng Tungsten Mine
应用例3Application example 3
试验物料取自郴州柿竹园有限公司某锡石矿,原矿锡嵌布粒度极细。原矿经脱硫后得到浓度为25%左右的矿浆作为实验给矿原料,其SnO2品位为0.31%。矿浆加入pH调整剂碳酸钠调节矿浆pH为9.0,随后加入活化剂硝酸铅、捕收剂GYB、起泡剂松醇油,矿浆经预调浆后,经加压泵给入管道静态混合矿化装置进行矿浆与浮选药剂的充分混合调浆。充分调浆后的矿浆进入浮选机进行浮选,经一粗两精三扫,得到最终的锡粗精矿。活化剂硝酸铅相对原矿的加入量为250g/t,捕收剂GYB相对原矿的加入量为300g/t,起泡剂松醇油相对原矿的加入量为40g/t,pH调整剂碳酸钠相对原矿的加入量为550g/t,浮选温度为25℃。试验获得粗精矿SnO2品位3.58%,回收率60.92%(如表3)。The test material was taken from a cassiterite mine of Chenzhou Shizhuyuan Co., Ltd., and the particle size of the original ore tin intercalation cloth was extremely fine. After the raw ore is desulfurized, the pulp with a concentration of about 25% is used as the raw material for the experiment, and its SnO 2 grade is 0.31%. Add pH adjuster sodium carbonate to the pulp to adjust the pH of the pulp to 9.0, then add activator lead nitrate, collector GYB, and foaming agent pine alcohol oil. The device fully mixes ore pulp and flotation reagents. The fully adjusted ore pulp enters the flotation machine for flotation, and after one rough, two fine and three sweeps, the final tin rough concentrate is obtained. The amount of activator lead nitrate relative to the raw ore is 250g/t, the amount of collector GYB relative to the raw ore is 300g/t, the foaming agent pine alcohol oil is 40g/t relative to the raw ore, and the pH regulator sodium carbonate is relatively The amount of raw ore added is 550g/t, and the flotation temperature is 25°C. The rough concentrate SnO 2 grade obtained in the test is 3.58%, and the recovery rate is 60.92% (as shown in Table 3).
表3柿竹园锡石矿的管道静态混合矿化装置试验结果Table 3 Test results of pipeline static mixing mineralization device in Shizhuyuan Cassiterite Mine
上述实施例仅仅是清楚地说明本实用新型所作的举例,而非对实施方式的限定。对于所属领域的普通技术人员来说,在上述说明的基础上还可以做出其它不同形式的变化或变动。这里也无需也无法对所有的实施例予以穷举。而由此所引申出的显而易见的变化或变动仍处于本实用新型的保护范围之中。The above-mentioned embodiments are only examples for clearly illustrating the present utility model, rather than limiting the implementation manner. For those of ordinary skill in the art, other changes or changes in different forms can be made on the basis of the above description. It is not necessary and impossible to exhaustively list all the embodiments here. And the obvious changes or changes derived therefrom are still within the protection scope of the present utility model.
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