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CN209401796U - battery pack - Google Patents

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Publication number
CN209401796U
CN209401796U CN201822179977.0U CN201822179977U CN209401796U CN 209401796 U CN209401796 U CN 209401796U CN 201822179977 U CN201822179977 U CN 201822179977U CN 209401796 U CN209401796 U CN 209401796U
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heat
battery pack
cell
side contact
heat transfer
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金井俊典
广濑克昌
古川裕一
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Resonac Holdings Corp
Resonac Corp
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Showa Denko KK
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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Abstract

The utility model provides a kind of battery apparatus can be cooling well by all monocell efficiency for constituting battery pack or heated.Battery apparatus (1) has the heat-conduction component (7) for transmitting cold energy or thermal energy possessed by the interior heat transfer medium flowed of heat transfer medium logical circulation road (6) of heat transmitter (4) to each monocell (3) of battery pack (2).In heat-conduction component (7), contact portion (15) are flanked by the 1st monocell, 1st linking part (18) and the 2nd linking part (19) form the variant part (10) with spring, 1st monocell flanks contact portion (15) and contacts with the 1st heating surface (13) of monocell (3), the heat transmitter that 1st monocell is flanked contact portion (15) and contacted with the heat-transfer area (5) of heat transmitter (4) by the 1st linking part (18) flanks contact portion (17) connection, the 2nd monocell contacted with the 2nd heating surface (14) of monocell (3) is flanked contact portion (16) and heat transmitter flanks contact portion (17) connection by the 2nd linking part (19).

Description

电池组装置battery pack

技术领域technical field

本实用新型涉及电池组装置。The utility model relates to a battery pack device.

本说明书和权利要求的范围中,“铝”包括纯铝和铝合金。In the scope of the specification and claims, "aluminum" includes pure aluminum and aluminum alloys.

背景技术Background technique

例如作为混合动力汽车、电动汽车等的电动机驱动用电池装置,使用将例如由锂离子二次电池等各种二次电池构成的多个小型单电池串联或并联而成的电池组形态的电池装置。特别是电动汽车为了延长续航距离而需求电池组的大容量化,因此多个电池组以串联或并联的方式被组合。For example, as a battery device for driving a motor of a hybrid vehicle, an electric vehicle, etc., a battery device in the form of a battery pack in which a plurality of small cells composed of various secondary batteries such as lithium-ion secondary batteries are used in series or in parallel is used. . In particular, electric vehicles require a larger capacity of battery packs in order to extend the cruising distance, so a plurality of battery packs are combined in series or in parallel.

然而,二次电池的性能、寿命会根据使用温度而变化,因此为了长时间效率良好地使用,需要在适当的温度下使用。However, the performance and life of the secondary battery vary depending on the use temperature, so it is necessary to use it at an appropriate temperature in order to use it efficiently for a long period of time.

因此,以减小上述那样的电池组中所有单电池的温度差为目的,提出了一种具备金属制冷却部件的冷却装置,该金属制冷却部件的顶壁外表面成为平坦的传热面,并且内部具有流通制冷剂的制冷剂通路(参照专利文献1)。Therefore, in order to reduce the temperature difference of all the single cells in the battery pack as described above, a cooling device provided with a metal cooling member whose top wall outer surface is a flat heat transfer surface has been proposed. In addition, it has a refrigerant passage through which a refrigerant flows (refer to Patent Document 1).

专利文献1记载的冷却装置中,电池组隔着由硅树脂等合成树脂构成的热传导片载置于冷却部件的传热面上,通过从流通于冷却部件的制冷剂通路中的制冷剂经由冷却部件的顶壁和热传导片传递到电池组的冷能将电池组冷却,为了提高电池组的冷却效率,需要提高冷却部件的传热面与热传导片的密合性以及电池组的受热面与热传导片的密合性。In the cooling device described in Patent Document 1, the battery pack is placed on the heat transfer surface of the cooling member through a heat conduction sheet made of synthetic resin such as silicone resin, and is cooled by the refrigerant flowing through the refrigerant passage of the cooling member. The cold energy transferred to the battery pack by the top wall of the component and the heat conduction sheet cools the battery pack. In order to improve the cooling efficiency of the battery pack, it is necessary to improve the adhesion between the heat transfer surface of the cooling component and the heat conduction sheet, as well as the heat receiving surface and heat conduction of the battery pack. The tightness of the sheet.

然而,上述电池组中,有时各单电池发生变形,或者至少一部分的单电池在上下方向上偏移而使受热面产生段差。因此,为了吸收这些变形、段差,提高电池组的受热面与热传导片的密合性,需要使热传导片的壁厚较厚。但是,由于由合成树脂构成的热传导片的热传导率较低,因此如果增厚热传导片的壁厚,电池组的受热面与冷却部件的传热面之间的热传导性降低,无法效率良好地冷却电池组的单电池。However, in the battery pack described above, each unit cell may be deformed, or at least a part of the unit cells may be shifted in the vertical direction, resulting in a step difference in the heating surface. Therefore, in order to absorb these deformations and step differences and improve the adhesion between the heat receiving surface of the battery pack and the heat conduction sheet, it is necessary to increase the wall thickness of the heat conduction sheet. However, since the thermal conductivity of the thermal conduction sheet made of synthetic resin is low, if the thickness of the thermal conduction sheet is increased, the thermal conductivity between the heat receiving surface of the battery pack and the heat transfer surface of the cooling member will decrease, and efficient cooling will not be possible. Single cells of the battery pack.

在先技术文献prior art literature

专利文献1:日本特许第6020942号公报Patent Document 1: Japanese Patent No. 6020942

发明内容Contents of the invention

本实用新型的目的是解决上述问题,提供一种能够将构成电池组的所有单电池效率良好地冷却或加热的电池组装置。An object of the present invention is to solve the above problems and provide a battery pack device capable of efficiently cooling or heating all single cells constituting the battery pack.

本实用新型为达成上述目的,包含以下技术方案。In order to achieve the above object, the utility model includes the following technical solutions.

1)一种电池组装置,包含电池组、传热器和热传导部件,所述电池组由多个方形单电池构成,所述传热器在外部具有传热面,并且在内部具有流通传热介质的传热介质流通路,所述热传导部件将在传热器的传热介质流通路内流动的传热介质所具有的冷能或热能向电池组的各单电池传递,构成电池组的所有单电池,以一个面朝向传热器的传热面侧并且在与传热器的传热面之间空出间隔的状态层叠配置,热传导部件由第1单电池侧接触部、第2单电池侧接触部和传热器侧接触部构成,所述第1单电池侧接触部与单电池的朝向传热器侧的第1受热面接触,所述第2单电池侧接触部与单电池的邻接第1受热面的第2受热面接触,所述传热器侧接触部在两个单电池侧接触部之间以从单电池向传热器侧突出的方式设置,并与传热器的传热面接触,热传导部件的第1单电池侧接触部和传热器侧接触部通过与两者一体化的第1连结部连结,热传导部件的第2单电池侧接触部和传热器侧接触部通过与两者一体化的第2连结部连结,通过第1单电池侧接触部、第1连结部和第2连结部形成变形部,所述变形部具有弹簧弹性,并且在受到使单电池的所述第1受热面与传热器的传热面接近的力时发生弹性变形。1) A battery pack device comprising a battery pack, a heat spreader and a heat transfer member, the battery pack is composed of a plurality of prismatic single cells, the heat spreader has a heat transfer surface on the outside, and has a flow heat transfer inside The heat transfer medium flow path of the medium, the heat conduction part transfers the cold energy or heat energy of the heat transfer medium flowing in the heat transfer medium flow path of the heat exchanger to each single cell of the battery pack, forming all the components of the battery pack The single cells are stacked with one surface facing the heat transfer surface side of the heat spreader and spaced from the heat transfer surface of the heat spreader. The side contact part and the heat spreader side contact part are constituted, the first cell side contact part is in contact with the first heat receiving surface of the cell facing the heat spreader side, and the second cell side contact part is in contact with the cell side contact part. The second heat receiving surface adjacent to the first heat receiving surface is in contact, and the heat spreader side contact portion is provided between the two single cell side contact portions in a manner protruding from the single cell to the heat spreader side, and is connected to the heat spreader The heat transfer surface is in contact, the first cell side contact part of the heat conduction member and the heat exchanger side contact part are connected by the first connecting part integrated with the two, and the second cell side contact part of the heat conduction member is connected to the heat exchanger side. The contact part is connected by the second connecting part which is integrated with both, and the deformation part is formed by the first cell side contact part, the first connecting part and the second connecting part, and the deformation part has spring elasticity, and when subjected to the Elastic deformation occurs when the first heat receiving surface of the battery approaches the heat transfer surface of the heat spreader.

2)根据上述1)记载的电池组装置,通过热传导部件的第1连结部、第2连结部和传热器侧接触部,形成以传热器侧接触部为顶点的大致V字形的变形部。2) The battery pack device according to the above 1), wherein a substantially V-shaped deformed portion with the heat spreader-side contact portion as an apex is formed by the first connecting portion, the second connecting portion, and the heat spreader-side contact portion of the heat conduction member. .

3)根据上述1)或2)记载的电池组装置,电池组的单电池中,与设有端子的第1端面相反侧的第2端面朝向传热器的传热面侧,单电池的第2端面成为所述第1受热面,单电池的侧面中的在层叠方向上成对的两个面之中的任一面成为所述第2受热面,在各单电池配置有一个热传导部件,除了一端的热传导部件以外的其它热传导部件的第2单电池侧接触部,配置于电池组的相邻的单电池之间。3) The battery pack device according to the above 1) or 2), wherein, among the unit cells of the battery pack, the second end face opposite to the first end face provided with the terminal faces the heat transfer surface side of the heat exchanger, and the second end face of the unit cell The two end faces serve as the first heat-receiving surface, and any one of the two faces in the stacking direction of the side surfaces of the unit cells serves as the second heat-receiving surface, and one heat conduction member is disposed on each unit cell, except The second battery-side contact portion of the heat-conducting member other than the heat-conducting member at one end is disposed between adjacent battery cells of the battery pack.

4)根据上述1)或2)记载的电池组装置,电池组的单电池中,与设有端子的第1端面相反侧的第2端面朝向传热器的传热面侧,单电池的第2端面成为所述第1受热面,单电池的侧面中的在与层叠方向正交的方向上成对的两个面成为所述第2受热面,在各单电池配置有两个热传导部件,两个热传导部件的第1单电池侧接触部与各单电池的第1受热面接触,并且两个热传导部件的第2单电池侧接触部与各单电池的第2受热面接触。4) The battery pack device according to the above 1) or 2), wherein, among the unit cells of the battery pack, the second end face opposite to the first end face provided with the terminal faces the heat transfer surface side of the heat exchanger, and the second end face of the unit cell The two end faces serve as the first heat receiving surfaces, and the two faces of the side surfaces of the unit cells that are paired in a direction perpendicular to the stacking direction serve as the second heat receiving surfaces, and two heat conduction members are arranged on each unit cell, The first cell side contact portions of the two heat conduction members are in contact with the first heat receiving surface of each cell, and the second cell side contact portions of the two heat conduction members are in contact with the second heat receiving surface of each cell.

5)根据上述1)或2)记载的电池组装置,电池组的单电池的侧面中的在与层叠方向正交的方向上成对的两个面之中的任一面成为所述第1受热面,单电池的侧面中的在层叠方向上成对的两个面之中的任一面成为所述第2受热面,在各单电池配置有一个热传导部件,除了一端的热传导部件以外的其它热传导部件的第2单电池侧接触部配置于电池组的相邻的单电池之间。5) The battery pack device according to the above 1) or 2), wherein any one of two faces of the side surfaces of the single cells of the battery pack that are paired in a direction perpendicular to the stacking direction becomes the first heat-receiving face. One of the two faces that are paired in the stacking direction on the side surfaces of the unit cells becomes the second heat receiving surface, and one heat conduction member is arranged on each unit cell, and the other heat conduction members except the heat conduction member at one end The second cell-side contact portion of the component is disposed between adjacent cells of the battery pack.

6)根据上述1)~5)的任一项记载的电池组装置,传热器具有一个传热面,仅在传热器的设有传热面的一侧配置有电池组。6) The battery pack device according to any one of 1) to 5) above, wherein the heat spreader has one heat transfer surface, and the battery pack is arranged only on the side of the heat spreader where the heat transfer surface is provided.

7)根据上述1)~5)的任一项记载的电池组装置,传热器具有彼此朝向相反侧的两个传热面,在传热器的两侧配置有电池组。7) The battery pack device according to any one of 1) to 5) above, wherein the heat spreader has two heat transfer surfaces facing opposite sides, and the battery pack is arranged on both sides of the heat spreader.

8)根据上述1)~7)的任一项记载的电池组装置,所述碳粒子由选自碳纳米管、石墨烯、石墨粒子和碳纤维之中的至少一种构成。8) The battery pack device according to any one of 1) to 7) above, wherein the carbon particles are composed of at least one selected from carbon nanotubes, graphene, graphite particles, and carbon fibers.

9)根据上述1)~8)的任一项记载的电池组装置,所述复合体的复合材料由铝基体和分散于铝基体中的碳粒子构成。9) The battery pack device according to any one of 1) to 8) above, wherein the composite material of the composite body is composed of an aluminum matrix and carbon particles dispersed in the aluminum matrix.

10)根据上述9)记载的电池组装置,所述复合体的复合材料具有在构成所述铝基体的铝材料中使所述碳粒子沿面方向分散的多个碳粒子分散层、以及由构成所述铝基体的铝材料形成的多个铝层,所述碳粒子分散层和所述铝层在所述复合体的厚度方向上交替层叠排列。10) The battery pack device according to the above 9), wherein the composite material of the composite has a plurality of carbon particle dispersed layers in which the carbon particles are dispersed in the plane direction in the aluminum material constituting the aluminum matrix, and A plurality of aluminum layers formed of the aluminum material of the aluminum matrix, the carbon particle dispersion layer and the aluminum layer are alternately stacked and arranged in the thickness direction of the composite body.

11)根据上述1)~10)的任一项记载的电池组装置,所述热传导部件是在所述复合体的两面通过接合剂层接合有单层或多层的树脂薄膜层而形成的层叠材料。11) The battery pack device according to any one of 1) to 10) above, wherein the thermally conductive member is a laminate formed by bonding a single or multiple resin film layers to both surfaces of the composite body via an adhesive layer. Material.

12)根据上述11)记载的电池组装置,所述树脂薄膜层是聚对苯二甲酸乙二醇酯薄膜和尼龙薄膜的多层的树脂薄膜层,所述尼龙薄膜配置于复合体侧。12) The battery pack device according to the above 11), wherein the resin film layer is a multilayer resin film layer of a polyethylene terephthalate film and a nylon film, and the nylon film is disposed on the composite side.

13)根据上述11)或12)记载的电池组装置,所述接合剂层是聚氨酯系接合剂层。13) The battery pack device according to the above 11) or 12), wherein the adhesive layer is a polyurethane adhesive layer.

根据上述1)~13)的电池组装置,在传热器的传热介质流通路中流通传热介质,由此将传热介质所具有的冷能或热能经由热传导部件的传热器侧接触部、第1连结部和第1单电池侧接触部传递到单电池的第1受热面,并且经由传热器侧接触部、第2连结部和第2单电池侧接触部传递到单电池的第2受热面,将单电池冷却或加热。热传导部件由第1单电池侧接触部、第2单电池侧接触部和传热器侧接触部构成,所述第1单电池侧接触部与单电池的朝向传热器侧的第1受热面接触,所述第2单电池侧接触部与单电池的邻接第1受热面的第2受热面接触,所述传热器侧接触部在两个单电池侧接触部之间以从单电池向传热器侧突出的方式设置,并与传热器的传热面接触,热传导部件的第1单电池侧接触部和传热器侧接触部通过与两者一体化的第1连结部连结,热传导部件的第2单电池侧接触部和传热器侧接触部通过与两者一体化的第2连结部连结,通过第1单电池侧接触部、第1连结部和第2连结部形成变形部,所述变形部具有弹簧弹性,并且在受到使单电池的所述第1受热面与传热器的传热面接近的力时发生弹性变形,因此即使电池组的各单电池发生变形、或者一部分单电池的第1受热面与其它单电池的第1受热面发生偏移错位,通过变形部弹性变形,能够防止在电池组的各单电池的第1受热面与热传导部件的第1单电池侧接触部之间发生接触不良,其结果能够抑制电池组的各单电池与传热器的传热面之间的经由热传导部件的热传导性的降低。因此,能够将构成电池组的所有单电池效率良好地冷却或加热。According to the battery pack devices of 1) to 13) above, the heat transfer medium flows through the heat transfer medium passage of the heat transfer device, thereby bringing the cold energy or heat energy of the heat transfer medium into contact with the heat transfer device side via the heat transfer member. part, the first connecting part and the first cell side contact part to the first heat receiving surface of the cell, and through the heat spreader side contact part, the second connecting part and the second cell side contact part to the The second heating surface cools or heats the cells. The heat conduction member is composed of a first cell-side contact portion, a second cell-side contact portion, and a heat spreader-side contact portion, and the first cell-side contact portion is in contact with the first heat-receiving surface of the cell facing the heat spreader side. contact, the second cell-side contact portion is in contact with the second heat-receiving surface of the cell adjacent to the first heat-receiving surface, and the heat spreader-side contact portion is between the two cell-side contact portions so as to extend from the cell to the The side of the heat spreader is arranged in a protruding manner and is in contact with the heat transfer surface of the heat spreader. The first cell-side contact portion of the heat conduction member and the heat spreader side contact portion are connected by a first connecting portion integrated with the two, The second cell-side contact portion and the heat spreader-side contact portion of the heat conduction member are connected by the second connecting portion integrated with both, and the deformation is formed by the first cell-side contact portion, the first connecting portion, and the second connecting portion The deformation part has spring elasticity, and elastically deforms when receiving the force that brings the first heat receiving surface of the unit cell close to the heat transfer surface of the heat spreader, so even if each unit cell of the battery pack is deformed, Or the first heating surface of some single cells is offset and misaligned with the first heating surfaces of other single cells, and the elastic deformation of the deformation part can prevent the first heating surface of each single cell of the battery pack from the first heating surface of the heat conduction member. A poor contact occurs between the battery-side contact portions, and as a result, a decrease in thermal conductivity via the thermally conductive member between each unit cell of the battery pack and the heat transfer surface of the heat spreader can be suppressed. Therefore, it is possible to efficiently cool or heat all the cells constituting the battery pack.

另外,热传导部件具有碳粒子分散层与铝层交替层叠而成的多层结构,所述碳粒子分散层是在铝材料中分散碳粒子而形成的,因此与专利文献1记载的由合成树脂构成的热传导片相比,热传导率极高,传热器与电池组的单电池之间的热传导性优异。因此,能够将电池组的单电池效率良好地冷却或加热。In addition, the heat conduction member has a multilayer structure in which carbon particle-dispersed layers and aluminum layers are alternately laminated. The carbon particle-dispersed layer is formed by dispersing carbon particles in an aluminum material. The thermal conductivity is extremely high compared to the thermal conduction sheet of the , and the thermal conductivity between the heat spreader and the single cells of the battery pack is excellent. Therefore, it is possible to efficiently cool or heat the single cells of the battery pack.

根据上述2)的电池组装置,能够以比较简单的结构形成变形部。According to the battery pack device of the above-mentioned 2), the deformation portion can be formed with a relatively simple structure.

根据上述7)的电池组装置,能够利用一个传热器冷却多个单电池,使部件数量减少。According to the battery pack device of 7) above, a plurality of single cells can be cooled by one heat spreader, and the number of parts can be reduced.

根据上述8)的电池组装置,能够提高复合体的热传导率。另外,能够切实地进行复合体中的铝与碳粒子的复合化。According to the battery pack device of the above 8), the thermal conductivity of the complex can be improved. In addition, the composite of aluminum and carbon particles in the composite can be reliably performed.

根据上述9)的电池组装置,铝基体中的碳粒子的偏置减少,复合体的热传导性整体均匀。According to the battery pack device of the above 9), the offset of the carbon particles in the aluminum matrix is reduced, and the thermal conductivity of the complex is uniform as a whole.

根据上述10)的电池组装置,复合材料的碳粒子分散层和所述铝层遍及板状复合体的厚度方向的整体交替层叠排列,因此能够尽量减小碳粒子分散层的厚度,并且增加碳粒子分散层的数量,能够有效提高复合体的热传导率。According to the battery pack device of the above 10), the carbon particle dispersed layer of the composite material and the aluminum layer are alternately laminated and arranged throughout the thickness direction of the plate-shaped composite body, so the thickness of the carbon particle dispersed layer can be reduced as much as possible, and the carbon particle can be increased. The number of particle dispersion layers can effectively improve the thermal conductivity of the composite.

根据上述11)的电池组装置,热传导部件是在复合体的两面接合有树脂薄膜层的层叠材料,因此热传导性优异,并且绝缘性、耐穿刺性、耐腐蚀性、耐磨耗性、耐刮擦性、耐水性、耐化学性、防尘性提高,还能赋予足够的弯曲强度和弹簧弹性。According to the battery pack device of the above 11), the thermally conductive member is a laminated material in which resin film layers are bonded to both sides of the composite body, so it has excellent thermal conductivity, insulation, puncture resistance, corrosion resistance, abrasion resistance, and scratch resistance. Scrub resistance, water resistance, chemical resistance, and dust resistance are improved, and sufficient bending strength and spring elasticity can be imparted.

根据上述12)的电池组装置,作为热传导部件使用的层叠材料具备尼龙薄膜,因此能够使耐穿刺性进一步提高,并且由于该尼龙薄膜与聚对苯二甲酸乙二醇酯薄膜组合,因此能够使耐水性提高。According to the battery pack device of the above 12), since the laminated material used as the heat conduction member includes the nylon film, the puncture resistance can be further improved, and since the nylon film is combined with the polyethylene terephthalate film, it is possible to use Improved water resistance.

根据上述13)的电池组装置,作为热传导部件使用的层叠材料中,接合剂层由聚氨酯系接合剂层形成,因此无论树脂薄膜层的树脂种类如何,都能够确保高的接合强度。According to the battery pack device of the above 13), since the adhesive layer is formed of the polyurethane adhesive layer in the laminated material used as the heat conduction member, high adhesive strength can be ensured regardless of the resin type of the resin film layer.

附图说明Description of drawings

图1是部分表示本实用新型的电池组装置的侧面图。FIG. 1 is a side view partially showing a battery pack device of the present invention.

图2是图1的II-II线箭头视图。Fig. 2 is a view of the arrow II-II in Fig. 1 .

图3是表示图1的电池组装置所使用的热传导部件的一部分的放大截面图。3 is an enlarged cross-sectional view showing a part of a heat conduction member used in the battery pack device of FIG. 1 .

图4是表示本实用新型的电池组装置的另一实施方式的与图2相对应的正视图。Fig. 4 is a front view corresponding to Fig. 2 showing another embodiment of the battery pack device of the present invention.

图5是表示本实用新型的电池组装置的另一实施方式的平面图。Fig. 5 is a plan view showing another embodiment of the battery pack device of the present invention.

图6是表示在图1的电池组装置中作为热传导部件使用的层叠材料的第1实施方式的截面图。6 is a cross-sectional view showing a first embodiment of a laminated material used as a heat conduction member in the battery pack device of FIG. 1 .

图7是表示在图1的电池组装置中作为热传导部件使用的层叠材料的第2实施方式的截面图。7 is a cross-sectional view showing a second embodiment of a laminate used as a heat conduction member in the battery pack device of FIG. 1 .

附图标记说明Explanation of reference signs

(1)(30)(40):电池组装置(1)(30)(40): battery pack unit

(2):电池组(2): battery pack

(3):单电池(3): single battery

(4):传热器(4): Heat transfer device

(5):传热面(5): heat transfer surface

(6):传热介质流通路(6): heat transfer medium flow path

(7):热传导部件(7): Heat conduction parts

(8):端子(8): terminal

(9):上端面(第1端面)(9): Upper end face (1st end face)

(10):变形部(10): deformation part

(11):下端面(第2端面)(11): Lower end face (second end face)

(12):侧面(12): side

(12a):第1垂直面(12a): 1st vertical plane

(12b):第2垂直面(12b): Second vertical plane

(13):第1受热面(13): The first heating surface

(14):第2受热面(14): The second heating surface

(15):第1单电池侧接触部(15): 1st cell side contact part

(16):第2单电池侧接触部(16): 2nd cell side contact part

(17):传热器侧接触部(17): Heat transfer side contact part

(18):第1连结部(18): 1st link

(19):第2连结部(19): The second link

(20):复合体(20): Complex

(21):复合材料(21): composite material

(22):铝基体(22): aluminum substrate

(23):碳粒子(23): carbon particles

(24):主面表皮层(24): main surface epidermis

(25):碳粒子分散层(25): Carbon particle dispersion layer

(26):铝层(26): aluminum layer

(27):铝板(27): aluminum plate

(51)(52):层叠材料(51)(52): laminated materials

(61):第1接合剂层(接合剂层)(61): 1st adhesive layer (adhesive layer)

(62):第2接合剂层(接合剂层)(62): The second adhesive layer (adhesive layer)

(63):第3接合剂层(接合剂层)(63): The third adhesive layer (adhesive layer)

(64):第4接合剂层(接合剂层)(64): The 4th adhesive layer (adhesive layer)

(71):第1树脂薄膜层(树脂薄膜层)(71): the first resin film layer (resin film layer)

(72):第2树脂薄膜层(树脂薄膜层)(72): The second resin film layer (resin film layer)

(73):第3树脂薄膜层(树脂薄膜层)(73): The third resin film layer (resin film layer)

(74):第4树脂薄膜层(树脂薄膜层)(74): The 4th resin film layer (resin film layer)

具体实施方式Detailed ways

以下,参照附图对本实用新型的实施方式进行说明。Hereinafter, embodiments of the present invention will be described with reference to the drawings.

以下的说明,在结合各附图的说明中,将各附图的上下作为上下方向。In the following description, in the description with reference to each drawing, the up and down of each drawing is taken as the up and down direction.

另外,所有附图中对相同物质和相同部分附带相同标记。In addition, the same code|symbol is attached|subjected to the same substance and the same part in all drawings.

图1和图2示出本实用新型的电池组装置,图3示出图1和图2的电池组装置所使用的热传导部件的结构。1 and 2 show the battery pack device of the present invention, and FIG. 3 shows the structure of the heat conduction member used in the battery pack device of FIG. 1 and FIG. 2 .

图1和图2中,电池组装置(1)包含电池组(2)、传热器(4)和热传导部件(7),电池组(2)例如由多个方形锂离子二次电池等扁平状方形单电池(3)构成,传热器(4)配置于电池组(2)的下方,在传热器(4)的外部具有传热面(5),并且在传热器(4)的内部具有流通传热介质的传热介质流通路(6),热传导部件(7)将在传热器(4)的传热介质流通路(6)内流动的传热介质所具有的冷能或热能向电池组(2)的各单电池(3)传递。In Fig. 1 and Fig. 2, battery pack device (1) comprises battery pack (2), heat spreader (4) and heat conduction member (7), and battery pack (2) is made of a plurality of square lithium ion secondary batteries etc. flat Shaped square cells (3), the heat spreader (4) is arranged under the battery pack (2), has a heat transfer surface (5) outside the heat spreader (4), and the heat spreader (4) There is a heat transfer medium flow path (6) for the heat transfer medium inside, and the heat conduction member (7) transfers the cold energy of the heat transfer medium flowing in the heat transfer medium flow path (6) of the heat exchanger (4) Or heat energy is transferred to each single cell (3) of the battery pack (2).

构成电池组(2)的单电池(3)是具有一定高度(图1的上下方向的尺寸)、一定厚度(图1的左右方向的尺寸)和一定宽度(图2的左右方向的尺寸)的扁平方柱状,具有呈突出状设有一对端子(8)的上端面(9)(第1端面)、下端面(11)(第2端面)和侧面(12),侧面(12)由厚度方向上朝向不同方向(图1的左右方向)的一对第1垂直面(12a)和宽度方向上朝向不同方向(图2的左右方向)的一对第2垂直面(12b)构成。所有单电池(3)以一个面、即下端面(11)朝向传热器(4)的传热面(5)侧并且在与传热器(4)的传热面(5)之间空出间隔的状态沿厚度方向层叠配置,利用端子(8)将所有单电池(3)串联或并联,由此构成电池组(2)。在此,单电池(3)的朝向传热器(4)侧的下端面(11)成为第1受热面(13),与第1受热面(13)相邻的一方(图1的左方)的第1垂直面(12a)成为第2受热面(14)。The single cells (3) constituting the battery pack (2) have a certain height (dimensions in the up-down direction in FIG. 1), a certain thickness (dimensions in the left-right direction in FIG. 1) and a certain width (dimensions in the left-right direction in FIG. 2). Flat square column, with a protruding upper end surface (9) (first end surface), lower end surface (11) (second end surface) and side surface (12) with a pair of terminals (8) protruding, the side surface (12) is defined by the thickness direction A pair of first vertical surfaces (12a) facing different directions (left-right direction in FIG. 1 ) and a pair of second vertical surfaces (12b) facing different directions (left-right direction in FIG. 2 ) in the width direction. All single cells (3) face the heat transfer surface (5) side of the heat exchanger (4) with one surface, that is, the lower end surface (11) and are spaced between the heat transfer surface (5) of the heat exchanger (4). The battery pack (2) is formed by connecting all the single cells (3) in series or in parallel by using the terminal (8) and stacking them in the thickness direction in a spaced state. Here, the lower end surface (11) of the unit cell (3) facing the heat spreader (4) side becomes the first heat receiving surface (13), and the side adjacent to the first heat receiving surface (13) (left side in FIG. 1 ) of the first vertical surface (12a) becomes the second heating surface (14).

传热器(4)是利用金属、例如铝呈扁平状形成的,具有一定高度(图1的上下方向的尺寸)、一定长度(图1的左右方向的尺寸)和一定宽度(图2的左右方向的尺寸),上表面成为传热面(5)。传热介质流通路(6)在传热器(4)的长度方向上延伸,在传热器(4)的宽度方向上并列形成多个。传热介质流通路(6)中流动着向构成电池组(2)的单电池(3)赋予冷能或赋予热能的传热介质。The heat spreader (4) is formed in a flat shape using metal, such as aluminum, and has a certain height (dimensions in the vertical direction of FIG. 1), a certain length (dimensions in the left-right direction of FIG. direction), the upper surface becomes the heat transfer surface (5). The heat transfer medium flow path (6) extends in the longitudinal direction of the heat spreader (4), and is formed in parallel in the width direction of the heat spreader (4). A heat transfer medium that imparts cooling energy or heat energy to the cells (3) constituting the battery pack (2) flows through the heat transfer medium flow path (6).

热传导部件(7)是使用包含复合材料的板状的复合体(20)形成的,所述复合材料是通过铝和碳粒子复合化而形成的,对各单电池(3)的每一个各配置一个热传导部件(7)。热传导部件(7)由与各单电池(3)的朝向传热器(4)侧的第1受热面(13)接触的第1单电池侧接触部(15)、与各单电池(3)的邻接第1受热面(13)的第2受热面(14)接触的第2单电池侧接触部(16)、以及在两个单电池侧接触部(15)(16)之间以从各单电池(3)向传热器(4)侧突出的方式设置的并且与传热器(4)的传热面(5)接触的传热器侧接触部(17)构成。除了一端的热传导部件(7)以外的其它热传导部件(7)的第2单电池侧接触部(16),配置于电池组(2)的相邻的单电池(3)的接近的两个第1垂直面(12a)之间。热传导部件(7)的第1单电池侧接触部(15)和传热器侧接触部(17)通过与两者一体化的第1连结部(18)连结,热传导部件(7)的第2单电池侧接触部(16)和传热器侧接触部(17)通过与两者一体化的第2连结部(19)连结,通过第1单电池侧接触部(15)、第1连结部(18)和第2连结部(19)形成变形部(10),变形部(10)具有弹簧弹性,并且在受到使单电池(3)的第1受热面(13)与传热器(4)的传热面(5)接近的上下方向的力时发生弹性变形。第1连结部(18)、第2连结部(19)和传热器侧接触部(17)成为以传热器侧接触部(17)为顶点的大致V字形。The heat conduction member (7) is formed using a plate-shaped composite body (20) including a composite material formed by compounding aluminum and carbon particles, and is arranged for each unit cell (3). A thermally conductive part (7). The heat conduction member (7) consists of a first cell-side contact portion (15) in contact with the first heat-receiving surface (13) of each cell (3) facing the side of the heat spreader (4), and each cell (3) The second cell-side contact portion (16) that is in contact with the second heat-receiving surface (14) adjacent to the first heat-receiving surface (13), and between the two cell-side contact portions (15) (16) from each The single cell (3) is provided so as to protrude toward the side of the heat spreader (4) and constitutes a heat spreader side contact portion (17) which is in contact with the heat transfer surface (5) of the heat spreader (4). The second cell-side contact portion (16) of the other heat-conducting member (7) except the heat-conducting member (7) at one end is arranged on the two adjacent cells (3) of the battery pack (2). 1 Between the vertical planes (12a). The first cell side contact portion (15) of the heat conduction member (7) and the heat exchanger side contact portion (17) are connected through the first connecting portion (18) integrated with both, and the second contact portion of the heat conduction member (7) The cell side contact part (16) and the heat exchanger side contact part (17) are connected through the second connection part (19) integrated with both, and the first cell side contact part (15), the first connection part (18) and the second connecting portion (19) form a deformation portion (10), the deformation portion (10) has spring elasticity, and is subjected to the first heat receiving surface (13) of the single cell (3) and the heat spreader (4 ) Elastic deformation occurs when the heat transfer surface (5) approaches the force in the up and down direction. The first connection part (18), the second connection part (19) and the heat exchanger side contact part (17) form a substantially V-shape with the heat exchanger side contact part (17) as an apex.

如图3所示,形成热传导部件(7)的复合体(20)由板状的复合材料(21)和铝制的主面表皮层(24)构成,复合材料(21)包含铝基体(22)和分散于铝基体(22)中的碳粒子(23),主面表皮层(24)覆盖复合材料(21)的彼此朝向相反侧的两个主面(21a)。复合材料(21)通过铝和碳粒子(23)复合化而形成。As shown in Figure 3, the complex (20) forming the heat conduction part (7) is composed of a plate-shaped composite material (21) and an aluminum main surface skin layer (24), and the composite material (21) includes an aluminum matrix (22 ) and carbon particles (23) dispersed in the aluminum matrix (22), the main surface skin layer (24) covers the two main surfaces (21a) facing opposite sides of the composite material (21). The composite material (21) is formed by combining aluminum and carbon particles (23).

复合材料(21)以层叠状具备在构成铝基体(22)的铝材料中使碳粒子(23)沿平面方向分散的多个碳粒子分散层(25)、和由构成铝基体(22)的铝材料形成的多个铝层(26)。The composite material (21) is provided with a plurality of carbon particle dispersion layers (25) in which carbon particles (23) are dispersed in the planar direction in the aluminum material constituting the aluminum matrix (22) in a laminated form, and the aluminum matrix (22) is composed of A plurality of aluminum layers (26) formed of aluminum material.

碳粒子分散层(25)和铝层(26)遍及复合材料(21)的厚度方向的整体以交替层叠状态排列,以在上下两端之中的下端存在铝层(26)、在上端存在碳粒子分散层(25)的方式排列。各碳粒子分散层(25)中,碳粒子(23)在铝基体(22)中沿着复合材料(21)的面方向分散,几乎不在复合材料(21)的厚度方向上分散。各铝层(26)中实质不存在碳粒子(23)。多个碳粒子分散层(25)与多个铝层(26)例如通过烧结复合化而接合一体化。对于碳粒子分散层(25)的厚度没有限定,优选为1~100μm。对于铝层(26)的厚度并不限定,优选为5~200μm。The carbon particle dispersion layer (25) and the aluminum layer (26) are arranged in an alternate lamination state throughout the entire thickness direction of the composite material (21), so that the aluminum layer (26) exists at the lower end of the upper and lower ends, and the carbon layer exists at the upper end. The particles are arranged in the form of a dispersion layer (25). In each carbon particle dispersion layer (25), carbon particles (23) are dispersed in the aluminum matrix (22) along the plane direction of the composite material (21), and hardly dispersed in the thickness direction of the composite material (21). Carbon particles (23) do not substantially exist in each aluminum layer (26). The plurality of carbon particle dispersed layers ( 25 ) and the plurality of aluminum layers ( 26 ) are bonded and integrated by, for example, sintering and compositing. The thickness of the carbon particle dispersed layer (25) is not limited, but is preferably 1 to 100 μm. The thickness of the aluminum layer (26) is not limited, but is preferably 5 to 200 μm.

复合体(20)的主面表皮层(24)由铝板(27)构成,铝板(27)与复合材料(21)分别形成,并且例如通过烧结与复合材料(21)一体化。即、图3的上侧的主面表皮层(24)与该图上端的碳粒子分散层(25)接合一体化,该图的下侧的主面表皮层(24)与该图下端的铝层(26)接合一体化。再者,下侧的主面表皮层(24)不是必需的。The main surface skin layer ( 24 ) of the composite body ( 20 ) is composed of an aluminum plate ( 27 ) formed separately from the composite material ( 21 ) and integrated with the composite material ( 21 ), for example, by sintering. That is, the main surface skin layer (24) on the upper side of FIG. The layer (26) is bonded and integrated. Furthermore, the lower main surface skin layer (24) is not essential.

对于复合材料(21)所使用的碳粒子的种类没有限定,优选使用具有尽量高的热传导率的碳粒子,即高热传导性的碳粒子。特别是作为碳粒子优选使用天然石墨粒子和人造石墨粒子。作为天然石墨粒子,使用鳞片状石墨粒子等。作为人造石墨粒子,使用各向同性石墨粒子、各向异性石墨粒子、热分解石墨粒子等。碳粒子为天然石墨粒子和人造石墨粒子的情况下,优选使用平均粒径为10μm以上且3mm以下的天然石墨粒子和人造石墨粒子。The type of carbon particles used in the composite material (21) is not limited, but it is preferable to use carbon particles having as high thermal conductivity as possible, that is, carbon particles with high thermal conductivity. In particular, natural graphite particles and artificial graphite particles are preferably used as carbon particles. As the natural graphite particles, flaky graphite particles and the like are used. As the artificial graphite particles, isotropic graphite particles, anisotropic graphite particles, pyrolytic graphite particles, and the like are used. When the carbon particles are natural graphite particles and artificial graphite particles, it is preferable to use natural graphite particles and artificial graphite particles having an average particle diameter of not less than 10 μm and not more than 3 mm.

另外,作为复合材料(21)的碳粒子,也会使用选自碳纤维、碳纳米管和石墨烯之中的至少一种。作为碳纤维,使用沥青系碳纤维、PAN系碳纤维等。作为碳纳米管,使用单层碳纳米管、多层碳纳米管、气相生长碳纤维(VGCF(注册商标))等。碳粒子为碳纤维的情况下,特别优选使用平均纤维长度为10μm以上且2mm以下的短碳纤维。碳粒子为碳纳米管的情况下,特别优选使用平均长度为1μm以上且10μm以下的碳纳米管。In addition, as the carbon particles of the composite material (21), at least one selected from carbon fibers, carbon nanotubes, and graphene may also be used. As the carbon fibers, pitch-based carbon fibers, PAN-based carbon fibers, and the like are used. As the carbon nanotubes, single-walled carbon nanotubes, multiwalled carbon nanotubes, vapor grown carbon fibers (VGCF (registered trademark)) and the like are used. When the carbon particles are carbon fibers, it is particularly preferable to use short carbon fibers having an average fiber length of not less than 10 μm and not more than 2 mm. When the carbon particles are carbon nanotubes, it is particularly preferable to use carbon nanotubes having an average length of not less than 1 μm and not more than 10 μm.

省略图示,复合体(20)的制造方法包括以下工序:将涂布液涂布于由构成铝基体(22)的材料制成的铝箔的一面,得到形成有碳粒子层的涂布箔的工序;形成将多个涂布箔以碳粒子层朝向相同方向的方式层叠的状态的层叠体的工序;在位于该层叠体的层叠方向的一端并且铝箔中的碳粒子层朝向外侧的涂布箔的碳粒子层上,层叠成为一方的主面表皮层(24)的铝板(27),并且在位于所述层叠体的层叠方向的另一端并且没有设置铝箔中的碳粒子层的一侧的表面,层叠成为另一方的主面表皮层(24)的铝板(27)的工序;以及将所述层叠体和成为主面表皮层(24)的铝板(27)通过加压加热烧结装置等在预定的烧结气氛(例如非氧化气氛)中加热烧结,由此将多个涂布箔一并烧结一体化,并且将两个铝板(27)与涂布箔烧结一体化的工序。Not shown, the manufacturing method of the composite (20) includes the following steps: apply the coating liquid to one side of the aluminum foil made of the material constituting the aluminum matrix (22), and obtain the coated foil with the carbon particle layer formed thereon. Process; Process of forming a laminated body in which a plurality of coated foils are laminated with carbon particle layers facing the same direction; Coated foil in which the carbon particle layer in the aluminum foil is positioned at one end of the laminated body in the stacking direction and faces outward On the carbon particle layer of the laminated body, the aluminum plate (27) that becomes one main surface skin layer (24) is laminated, and is positioned at the other end of the stacking direction of the laminated body and does not set the surface of the side of the carbon particle layer in the aluminum foil , the process of laminating the aluminum plate (27) that becomes the other main surface skin layer (24); A process of heating and sintering in a sintering atmosphere (such as a non-oxidizing atmosphere), thereby sintering and integrating a plurality of coated foils, and sintering and integrating two aluminum plates (27) with the coated foils.

涂布液以混合状态含有碳粒子(23)、粘合剂和粘合剂用溶剂,例如可以通过将碳粒子(23)、粘合剂和溶剂放入混合容器内利用搅拌混合器进行搅拌混合而得到。再者,根据需要可以向涂布液添加分散剂、表面调整剂等。The coating solution contains carbon particles (23), a binder, and a solvent for the binder in a mixed state. For example, the carbon particles (23), the binder, and the solvent can be stirred and mixed by a stirring mixer in a mixing container. And get. In addition, a dispersant, a surface conditioner, etc. can be added to a coating liquid as needed.

粘合剂用于对碳粒子(23)赋予向铝箔的一面的附着力,抑制碳粒子(23)从铝箔脱落。粘合剂通常由有机树脂等树脂构成。具体而言,作为粘合剂可以使用聚环氧乙烷、聚乙烯醇、丙烯酸系树脂等。The binder is used to give the carbon particles (23) adhesion to one side of the aluminum foil, and to suppress the carbon particles (23) from falling off from the aluminum foil. The binder is usually made of resin such as organic resin. Specifically, polyethylene oxide, polyvinyl alcohol, acrylic resin, or the like can be used as the binder.

溶剂用于溶解粘合剂。具体而言,作为溶剂可以使用亲水性溶剂(例如异丙醇、水)、有机溶剂等。Solvents are used to dissolve the adhesive. Specifically, as a solvent, a hydrophilic solvent (for example, isopropanol, water), an organic solvent, or the like can be used.

作为搅拌混合器可以使用分散机、行星式搅拌机、珠磨机等。As the stirring mixer, a disperser, a planetary mixer, a bead mill, or the like can be used.

所述层叠体和两个铝板(27)的烧结方法可以从真空热压法、放电等离子烧结法(SPS法)、热等静压烧结法(HIP法)、挤压法、压延法等中选择。再者,放电等离子烧结法也被称为脉冲通电烧结法。The sintering method of the laminated body and the two aluminum plates (27) can be selected from vacuum hot pressing method, spark plasma sintering method (SPS method), hot isostatic pressing sintering method (HIP method), extrusion method, calendering method, etc. . In addition, the spark plasma sintering method is also called a pulse energization sintering method.

存在于层叠体中的粘合剂,在该工序中通过在以层叠体的温度从大致室温上升至层叠体的烧结温度的方式加热层叠体的中途升华或分散等而消失,从层叠体中被除去。The binder present in the laminated body disappears by sublimation or dispersion in the middle of heating the laminated body in such a manner that the temperature of the laminated body rises from approximately room temperature to the sintering temperature of the laminated body in this step, and is removed from the laminated body. remove.

将层叠体和两个铝板(27)烧结的工序中,通过层叠体如上所述被加热,铝箔的金属材料的一部分浸透碳粒子层内,填充到存在于碳粒子层内的细微的空隙(例如碳粒子层中的碳粒子(23)之间的间隙)中,使该空隙大致消失。由此,复合材料(21)的密度上升,并且复合材料(21)的强度提高。In the step of sintering the laminated body and the two aluminum plates (27), the laminated body is heated as described above, and a part of the metal material of the aluminum foil penetrates into the carbon particle layer and fills fine voids (such as In the gap between the carbon particles (23) in the carbon particle layer), the gap is almost eliminated. As a result, the density of the composite material (21) increases, and the strength of the composite material (21) increases.

另外,构成铝箔的材料的一部分浸透碳粒子层内,由此碳粒子层中的碳粒子(23)成为在所得到的复合体(20)的复合材料(21)的铝基体(22)中沿平面方向分散的状态,碳粒子层成为复合材料(21)的碳粒子分散层(25),铝箔成为复合材料(21)的铝层(26)。另外,铝板(27)成为主面表皮层(24)。In addition, a part of the material constituting the aluminum foil permeates into the carbon particle layer, so that the carbon particles (23) in the carbon particle layer become along the aluminum matrix (22) of the composite material (21) of the obtained composite (20). In the state of being dispersed in the plane direction, the carbon particle layer becomes the carbon particle dispersed layer (25) of the composite material (21), and the aluminum foil becomes the aluminum layer (26) of the composite material (21). In addition, the aluminum plate (27) becomes the main surface skin layer (24).

因此,在复合材料(21)中,碳粒子分散层(25)和铝层(26)如上所述遍及复合材料(21)的厚度方向的整体以交替层叠的状态排列。这样制成复合体(20)。Therefore, in the composite material (21), the carbon particle dispersed layers (25) and the aluminum layers (26) are arranged in a state of being alternately laminated throughout the entire thickness direction of the composite material (21) as described above. In this way a complex (20) is produced.

包含上述复合材料(21)的复合体(20)的热传导性优异。通过将树脂薄膜层层叠于该复合体(20),能够使热传导部件的绝缘性、耐穿刺性、耐腐蚀性、耐磨耗性、耐水性(耐湿性)、耐化学性、耐刮擦性、防尘性提高,并且赋予足够的弯曲强度和弹簧弹性。本实用新型中,作为热传导部件优选使用在复合体(20)的两面利用接合剂层接合有单层或多层的树脂薄膜层的层叠材料。另外,图3的复合体(20)在铝-碳的复合材料(21)的两面具有铝制的主面表皮层(24),但复合体也可以变更为仅在复合材料(21)的一面具有主面表皮层(24)的复合体、或者由复合材料(21)单独材料构成的复合体。The composite (20) comprising the above composite material (21) is excellent in thermal conductivity. By laminating the resin film layer on the composite (20), the insulation, puncture resistance, corrosion resistance, abrasion resistance, water resistance (moisture resistance), chemical resistance, and scratch resistance of the thermally conductive member can be improved. , Improve dust resistance, and impart sufficient bending strength and spring elasticity. In the present invention, it is preferable to use a laminated material in which single or multiple resin film layers are bonded to both surfaces of the composite ( 20 ) by means of an adhesive layer as the thermally conductive member. In addition, the composite body (20) in Fig. 3 has aluminum main surface skin layers (24) on both sides of the aluminum-carbon composite material (21), but the composite body can also be changed to only one side of the composite material (21) A composite body with a main surface skin layer (24), or a composite body consisting of individual materials of the composite material (21).

以下,参照图6、7对层叠材料的两个实施方式进行详细说明。Hereinafter, two embodiments of the laminated material will be described in detail with reference to FIGS. 6 and 7 .

图6示出层叠材料的第1实施方式。该层叠材料(51)在复合体(20)的第1面层叠有由第1接合剂层(61)接合的第1树脂薄膜层(71),在第2面层叠有由第2接合剂层(62)接合的第2树脂薄膜层(72)。所述第1树脂薄膜层(71)和第2树脂薄膜层(72)不限定于相同种类的树脂薄膜层,可以是不同种类的树脂薄膜层。Fig. 6 shows a first embodiment of the laminated material. The laminated material (51) is laminated with the first resin film layer (71) bonded by the first adhesive layer (61) on the first surface of the composite body (20), and laminated with the second adhesive layer on the second surface. (62) The joined second resin film layer (72). The first resin film layer (71) and the second resin film layer (72) are not limited to the same type of resin film layer, and may be different types of resin film layers.

图7示出层叠材料的第2实施方式。该层叠材料(52)在复合体(20)的两面层叠由多层树脂薄膜层。即、在所述复合体(20)的第1面层叠有由第1接合剂层(61)接合的第1树脂薄膜层(71),在该第1树脂薄膜层(71)的外表面由第3接合剂层(63)接合有与第1树脂薄膜层种类不同的第3树脂薄膜层(73)。另外,在所述复合体(20)的第2面层叠有由第2接合剂层(62)接合的第2树脂薄膜层(72),在该第2树脂薄膜层(72)的外表面由第4接合剂层(64)接合有与第2树脂薄膜层(72)种类不同的第4树脂薄膜层(74)。第1树脂薄膜层(71)和第2树脂薄膜层(73)可以是相同种类的树脂薄膜层,也可以是不同种类的树脂薄膜层。同样,第3树脂薄膜层(73)和第4树脂薄膜层(74)可以是相同种类的树脂薄膜层,也可以是不同种类的树脂薄膜层。另外,多层薄膜层可以为3层以上。另外,第1面侧的树脂薄膜层和第2面侧的树脂薄膜层的层叠数不同的情况也包含在本实用新型的技术范围内。Fig. 7 shows a second embodiment of the laminated material. The laminated material (52) is laminated with multiple resin film layers on both sides of the composite body (20). That is, the first resin film layer (71) joined by the first adhesive layer (61) is laminated on the first surface of the composite (20), and the outer surface of the first resin film layer (71) is formed by A third resin film layer (73) of a different type from the first resin film layer is bonded to the third adhesive layer (63). In addition, a second resin film layer (72) joined by a second adhesive layer (62) is laminated on the second surface of the composite (20), and the outer surface of the second resin film layer (72) is formed by A fourth resin film layer (74) of a different type from the second resin film layer (72) is bonded to the fourth adhesive layer (64). The first resin film layer (71) and the second resin film layer (73) may be the same type of resin film layer, or may be different types of resin film layers. Similarly, the third resin film layer (73) and the fourth resin film layer (74) may be the same type of resin film layer, or may be different types of resin film layers. In addition, the multilayer film layer may be three or more layers. Moreover, the case where the lamination|stacking number of the resin film layer of the 1st surface side and the resin film layer of the 2nd surface side differs also is contained in the technical scope of this invention.

本实用新型中,作为所述第1树脂薄膜层(71)、第2树脂薄膜层(72)、第3树脂薄膜层(73)和第4树脂薄膜层(74),没有特别限定,例如可举出聚对苯二甲酸乙二醇酯(PET)薄膜、尼龙薄膜(其中优选双轴拉伸尼龙薄膜)、聚苯乙烯(PS)薄膜、聚乙烯(PE)薄膜、聚丙烯(PP)薄膜、聚萘二甲酸乙二醇酯(PEN)薄膜、聚酰亚胺(PI)薄膜、聚碳酸酯(PC)薄膜、丙烯酸树脂薄膜、环氧树脂薄膜等。通过将这些树脂薄膜层叠于复合体,能够使热传导部件的绝缘性、耐穿刺性、耐腐蚀性、耐磨耗性、耐水性(耐湿性)、耐化学性、耐刮擦性、防尘性提高,并且赋予足够的弯曲强度和弹簧弹性。另外,图7中层叠的树脂薄膜的情况下,优选将特性不同的树脂薄膜组合。例如,尼龙薄膜的耐穿刺性比其它薄膜优异但吸湿性稍高,因此通过组合耐水性(耐湿性)高的聚对苯二甲酸乙二醇酯薄膜,能够赋予热传导部件这两方的树脂薄膜的优异特性。另外,将尼龙薄膜和聚对苯二甲酸乙二醇酯薄膜层叠的情况下,优选作为层叠体(20)侧的第1树脂薄膜层(71)和第2树脂薄膜层(72)使用尼龙薄膜,作为在外面露出的第3树脂薄膜层(73)和第4树脂薄膜层(74)使用耐水性优异的聚对苯二甲酸乙二醇酯薄膜。In the present utility model, there is no particular limitation as the first resin film layer (71), the second resin film layer (72), the third resin film layer (73) and the fourth resin film layer (74), for example, Examples include polyethylene terephthalate (PET) film, nylon film (of which biaxially stretched nylon film is preferred), polystyrene (PS) film, polyethylene (PE) film, polypropylene (PP) film , Polyethylene naphthalate (PEN) film, polyimide (PI) film, polycarbonate (PC) film, acrylic resin film, epoxy resin film, etc. By laminating these resin films on a composite, the insulation, puncture resistance, corrosion resistance, abrasion resistance, water resistance (moisture resistance), chemical resistance, scratch resistance, and dust resistance of thermally conductive parts can be improved. Improve, and give sufficient bending strength and spring elasticity. In addition, in the case of the laminated resin films shown in FIG. 7, it is preferable to combine resin films having different properties. For example, nylon film has better puncture resistance than other films but slightly higher hygroscopicity. Therefore, by combining a polyethylene terephthalate film with high water resistance (moisture resistance), it is possible to provide both resin films for thermally conductive parts. excellent characteristics. In addition, when a nylon film and a polyethylene terephthalate film are laminated, it is preferable to use a nylon film as the first resin film layer (71) and the second resin film layer (72) on the side of the laminate (20). A polyethylene terephthalate film excellent in water resistance is used as the third resin film layer (73) and the fourth resin film layer (74) exposed outside.

所述第1树脂薄膜层(71)、第2树脂薄膜层(72)、第3树脂薄膜层(73)和第4树脂薄膜层(74)的厚度都优选设定为5μm~200μm的范围,其中特别优选10μm~50μm。The thicknesses of the first resin film layer (71), the second resin film layer (72), the third resin film layer (73) and the fourth resin film layer (74) are all preferably set in the range of 5 μm to 200 μm, Among them, 10 μm to 50 μm is particularly preferable.

作为形成所述第1接合剂层(61)、第2接合剂层(62)、第3接合剂层(63)和第4接合剂层(64)的接合剂,没有特别限定,例如可举出聚氨酯系树脂、烯烃系树脂、乙烯-乙酸乙酯共聚物(EVA)、乙烯-丙烯酸酯共聚物、乙烯-甲基丙烯酸酯共聚物等,也可以使用其它CPP(流延聚丙烯)。其中,优选使用聚氨酯系树脂,该情况下无论树脂薄膜层的树脂种类如何,都能够确保高的接合强度。另外,聚氨酯树脂系接合剂偏移,因此在成本方面也是有利的。The adhesive for forming the first adhesive layer (61), second adhesive layer (62), third adhesive layer (63) and fourth adhesive layer (64) is not particularly limited, for example, Polyurethane-based resins, olefin-based resins, ethylene-ethyl acetate copolymers (EVA), ethylene-acrylate copolymers, ethylene-methacrylate copolymers, etc., and other CPP (cast polypropylene) can also be used. Among them, polyurethane-based resins are preferably used, and in this case, high joint strength can be ensured regardless of the resin type of the resin film layer. In addition, since the urethane resin-based adhesive is offset, it is also advantageous in terms of cost.

作为使用上述接合剂进行层叠时的层叠方法,在湿式的情况下没有特别限定,例如可举出浸涂、旋涂、凹版印刷、模涂、刮涂、3辊(胶印型)、狭缝涂布、辊涂(2辊)、喷涂、幕涂、逆辊涂布、逗号涂布等涂布方法。另外,干式的情况下没有特别限定,例如可举出干式层压法、热层压法、热轧法等。The lamination method in the case of lamination using the above-mentioned adhesive is not particularly limited in the case of a wet method, and examples thereof include dip coating, spin coating, gravure printing, die coating, knife coating, 3-roll (offset type), and slit coating Cloth, roll coating (2 rolls), spray coating, curtain coating, reverse roll coating, comma coating and other coating methods. Moreover, it does not specifically limit in the case of a dry method, For example, a dry lamination method, a thermal lamination method, a hot rolling method, etc. are mentioned.

上述电池组装置(1)中,在将构成电池组(2)的所有单电池(3)冷却的情况下,向传热器(4)的传热介质流通路(6)供给冷却液。这样,在冷却液流通于传热器(4)的传热介质流通路(6)期间,冷却液所具有的冷能经由热传导部件(7)的传热器侧接触部(17)、第1连结部(18)和第1单电池侧接触部(15)传递到单电池(3)的第1受热面(13),并且经由热传导部件(7)的传热器侧接触部(17)、第2连结部(19)和第2单电池侧接触部(16)传递到单电池(3)的第2受热面(14),电池组(2)的所有单电池(3)被冷却。In the battery pack device (1) described above, when cooling all the cells (3) constituting the battery pack (2), cooling liquid is supplied to the heat medium flow path (6) of the heat spreader (4). In this way, when the cooling liquid flows through the heat transfer medium passage (6) of the heat transfer device (4), the cold energy of the cooling liquid passes through the heat transfer side contact part (17) of the heat transfer member (7), the first The connection part (18) and the first cell side contact part (15) are transmitted to the first heat receiving surface (13) of the cell (3), and through the heat transfer part (17) of the heat conduction member (7), The second connection part (19) and the second cell side contact part (16) are transmitted to the second heat receiving surface (14) of the cell (3), and all the cells (3) of the battery pack (2) are cooled.

在寒冷地带,需要在开始使用之前将单电池(3)加热至适当温度的情况下,将作为能够供给热能的传热介质的高温加热液向传热器(4)的传热介质流通路(6)供给。这样,在加热液流通于传热器(4)的传热介质流通路(6)期间,加热液所具有的热能与冷却的情况同样地传递到电池组(2)的单电池(3)的两个受热面(13)(14),电池组(2)的所有单电池(3)被加热至适当温度。In the cold region, when it is necessary to heat the single cell (3) to an appropriate temperature before starting to use, the high-temperature heating liquid, which is a heat transfer medium capable of supplying heat energy, is directed to the heat transfer medium flow path of the heat exchanger (4) ( 6) Supply. In this way, when the heating liquid flows through the heat transfer medium flow path (6) of the heat exchanger (4), the thermal energy of the heating liquid is transferred to the cells (3) of the battery pack (2) in the same manner as in the case of cooling. All single cells (3) of the battery pack (2) are heated to an appropriate temperature on the two heating surfaces (13) (14).

如图1所示,至少一部分单电池(3)在上下方向上偏移错位而在电池组(2)的下表面产生段差的情况下,热传导部件(7)的变形部(10)跟随电池组(2)的下表面的形状发生弹性变形,防止在电池组(2)的各单电池(3)的第1受热面(13)与热传导部件(7)的第1单电池侧接触部(15)之间、以及热传导部件(7)的传热器侧接触部(17)与传热器(4)的传热面(5)之间发生接触不良。因此,能够将构成电池组(2)的所有单电池(3)效率良好地冷却或加热。As shown in Fig. 1, when at least a part of the single cells (3) are shifted and dislocated in the vertical direction and a level difference is generated on the lower surface of the battery pack (2), the deformation part (10) of the heat conduction member (7) follows the battery pack The shape of the lower surface of (2) is elastically deformed to prevent the first heat receiving surface (13) of each unit cell (3) of the battery pack (2) from contacting the first unit cell side (15) of the heat conduction member (7). ) and between the heat transfer side contact portion (17) of the heat conduction member (7) and the heat transfer surface (5) of the heat transfer device (4). Therefore, all the cells (3) constituting the battery pack (2) can be efficiently cooled or heated.

图4示出本实用新型的电池组装置的另一实施方式。FIG. 4 shows another embodiment of the battery pack device of the present invention.

图4所示的电池组装置(30),电池组(2)的单电池(3)的侧面(12)中的两个第2垂直面(12b)分别成为第2受热面(14)。热传导部件(7)相对于各单电池(3)的每一个各配置两个,在各单电池(3)的第1受热面(13)的图4的左右两侧部分分别接触两个热传导部件(7)的第1单电池侧接触部(15),并且在两个第2受热面(14)分别接触一个热传导部件(7)的第2单电池侧接触部(16)。即、图4左侧的热传导部件(7)的第1单电池侧接触部(15)与各单电池(3)的图4左侧部分接触,并且第2单电池侧接触部(16)沿着各单电池(3)的图4左侧的第2受热面(14)面接触,图4右侧的热传导部件(7)的第1单电池侧接触部(15)与各单电池(3)的图4右侧部分接触,并且第2单电池侧接触部(16)沿着各单电池(3)的图4右侧的第2受热面(14)面接触。In the battery pack device (30) shown in Fig. 4, two second vertical surfaces (12b) on the side surfaces (12) of the single cells (3) of the battery pack (2) serve as second heat receiving surfaces (14), respectively. Two heat conduction members (7) are arranged for each unit cell (3), and are in contact with two heat conduction members on the left and right sides of the first heat receiving surface (13) of each unit cell (3) in FIG. 4 . The first cell side contact portion (15) of (7) is in contact with the second cell side contact portion (16) of one heat conducting member (7) on the two second heat receiving surfaces (14). That is, the first cell-side contact portion (15) of the heat conduction member (7) on the left side of FIG. 4 is in contact with each cell (3) on the left side of FIG. The second heat receiving surface (14) on the left side of Fig. 4 of each cell (3) is in surface contact, and the first cell side contact part (15) of the heat conduction member (7) on the right side of Fig. 4 is in contact with each cell (3) ), and the second cell-side contact portion (16) is in surface contact with the second heating surface (14) on the right side of FIG. 4 of each cell (3).

电池组装置(30)的其它结构与图1~图3所示的电池组装置(1)相同。Other configurations of the battery pack device (30) are the same as those of the battery pack device (1) shown in Figs. 1 to 3 .

图5示出本实用新型的电池组装置的另一实施方式。FIG. 5 shows another embodiment of the battery pack device of the present invention.

图5所示的电池组装置(40),传热器(4)具有彼此朝向相反侧(图5的上下两侧)的两个传热面(5),在传热器(4)的两侧分别配置有电池组(2)。另外,各电池组(2)的单电池(3)的侧面(12)中朝向传热器(4)的传热面(5)侧的一方的第2垂直面(12b)(图5上侧的电池组(2)的单电池(3)中朝向下方的第2垂直面(12b)、该图下侧的电池组(2)的单电池(3)中朝向上方的第2垂直面(12b))分别成为第1受热面(13),与第1受热面(13)相邻的一方(图5的右方)的第1垂直面(12a)成为第2受热面(14)。In the battery pack device (40) shown in Fig. 5, the heat spreader (4) has two heat transfer surfaces (5) facing opposite sides (upper and lower sides of Fig. 5 ), and on both sides of the heat spreader (4) The battery packs (2) are respectively arranged on the sides. In addition, among the side surfaces (12) of the unit cells (3) of each battery pack (2), the second vertical surface (12b) facing the side of the heat transfer surface (5) of the heat spreader (4) (the upper side in FIG. 5 The second vertical surface (12b) facing downward in the single cell (3) of the battery pack (2) in the battery pack (2), the second vertical face (12b) facing upward in the single cell (3) of the battery pack (2) on the lower side of the figure )) respectively become the first heating surface (13), and the first vertical surface (12a) adjacent to the first heating surface (13) (right side in Fig. 5) becomes the second heating surface (14).

热传导部件(7)对于两个电池组(2)的各单电池(3)的每一个各配置一个。热传导部件(7)由与各单电池(3)的朝向传热器(4)侧的第1受热面(13)接触的第1单电池侧接触部(15)、与各单电池(3)的邻接第1受热面(13)的第2受热面(14)接触的第2单电池侧接触部(16)、以及在两个单电池侧接触部(15)(16)之间以从各单电池(3)向传热器(4)侧突出的方式设置的并且与传热器(4)的传热面(5)接触的传热器侧接触部(17)构成。除了一端的热传导部件(7)以外的其它热传导部件(7)的第2单电池侧接触部(16),配置于电池组(2)的相邻的单电池(3)的接近的两个第1垂直面(12a)之间。One heat conduction member (7) is provided for each single battery (3) of the two battery packs (2). The heat conduction member (7) consists of a first cell-side contact portion (15) in contact with the first heat-receiving surface (13) of each cell (3) facing the side of the heat spreader (4), and each cell (3) The second cell-side contact portion (16) that is in contact with the second heat-receiving surface (14) adjacent to the first heat-receiving surface (13), and between the two cell-side contact portions (15) (16) from each The single cell (3) is provided so as to protrude toward the side of the heat spreader (4) and constitutes a heat spreader side contact portion (17) which is in contact with the heat transfer surface (5) of the heat spreader (4). The second cell-side contact portion (16) of the other heat-conducting member (7) except the heat-conducting member (7) at one end is arranged on the two adjacent cells (3) of the battery pack (2). 1 Between the vertical planes (12a).

电池组装置(40)的其它结构与图1~图3所示的电池组装置(1)相同。Other configurations of the battery pack device (40) are the same as those of the battery pack device (1) shown in Figs. 1 to 3 .

产业可利用性industry availability

本实用新型的电池组装置优选用于例如由锂二次电池构成的电池组。The battery pack device of the present invention is preferably used for a battery pack composed of, for example, a lithium secondary battery.

Claims (10)

1.一种电池组装置,包含电池组、传热器和热传导部件,1. A battery pack device comprising a battery pack, a heat spreader and a heat conduction member, 所述电池组由多个方形单电池构成,The battery pack is composed of a plurality of square cells, 所述传热器在外部具有传热面,并且在内部具有流通传热介质的传热介质流通路,The heat transfer device has a heat transfer surface on the outside and a heat transfer medium flow path through which the heat transfer medium flows inside, 所述热传导部件将在传热器的传热介质流通路内流动的传热介质所具有的冷能或热能向电池组的各单电池传递,The heat conduction member transfers the cold energy or heat energy of the heat transfer medium flowing in the heat transfer medium flow path of the heat exchanger to each unit cell of the battery pack, 所述电池组装置的特征在于,The battery pack device is characterized in that 构成电池组的所有单电池,以一个面朝向传热器的传热面侧并且在与传热器的传热面之间空出间隔的状态层叠配置,All the single cells constituting the battery pack are stacked with one side facing the heat transfer surface side of the heat spreader and spaced from the heat transfer surface of the heat spreader, 热传导部件由第1单电池侧接触部、第2单电池侧接触部和传热器侧接触部构成,The heat conduction member is composed of a first cell-side contact, a second cell-side contact, and a heat spreader-side contact, 所述第1单电池侧接触部与单电池的朝向传热器侧的第1受热面接触,The first cell-side contact portion is in contact with the first heat-receiving surface of the cell facing the heat exchanger, 所述第2单电池侧接触部与单电池的邻接第1受热面的第2受热面接触,The second cell-side contact portion is in contact with a second heat-receiving surface adjacent to the first heat-receiving surface of the cell, 所述传热器侧接触部在两个单电池侧接触部之间以从单电池向传热器侧突出的方式设置,并与传热器的传热面接触,The heat spreader side contact portion is provided between the two single cell side contact portions in a manner protruding from the single cell toward the heat spreader side, and is in contact with the heat transfer surface of the heat spreader, 热传导部件的第1单电池侧接触部和传热器侧接触部通过与两者一体化的第1连结部连结,The first cell-side contact portion and the heat exchanger-side contact portion of the heat conduction member are connected by a first connection portion integrated with both, 热传导部件的第2单电池侧接触部和传热器侧接触部通过与两者一体化的第2连结部连结,The second cell-side contact portion and the heat exchanger-side contact portion of the heat conduction member are connected by a second connection portion integrated with both, 通过第1单电池侧接触部、第1连结部和第2连结部形成变形部,所述变形部具有弹簧弹性,并且在受到使单电池的所述第1受热面与传热器的传热面接近的力时发生弹性变形。The deformation part is formed by the first cell-side contact part, the first connection part and the second connection part, and the deformation part has spring elasticity, and is subjected to heat transfer between the first heat receiving surface of the cell and the heat spreader. Elastic deformation occurs when the surface approaches the force. 2.根据权利要求1所述的电池组装置,其特征在于,2. The battery pack device according to claim 1, wherein: 通过热传导部件的第1连结部、第2连结部和传热器侧接触部,形成以传热器侧接触部为顶点的大致V字形的变形部。A substantially V-shaped deformed portion with the heat spreader-side contact portion as an apex is formed by the first connection portion, the second connection portion, and the heat spreader-side contact portion of the heat conduction member. 3.根据权利要求1或2所述的电池组装置,其特征在于,3. The battery pack device according to claim 1 or 2, wherein: 电池组的单电池中,与设有端子的第1端面相反侧的第2端面朝向传热器的传热面侧,In the single cells of the battery pack, the second end surface opposite to the first end surface provided with the terminal faces the heat transfer surface side of the heat exchanger, 单电池的第2端面成为所述第1受热面,The second end surface of the unit cell becomes the first heating surface, 单电池的侧面中的在层叠方向上成对的两个面之中的任一面成为所述第2受热面,any one of the two faces paired in the stacking direction among the side faces of the cells serves as the second heat receiving face, 在各单电池配置有一个热传导部件,Each cell is equipped with a heat conduction part, 除了一端的热传导部件以外的其它热传导部件的第2单电池侧接触部,配置于电池组的相邻的单电池之间。The second battery-side contact portions of the other heat-conducting members other than the heat-conducting member at one end are disposed between adjacent battery cells of the battery pack. 4.根据权利要求1或2所述的电池组装置,其特征在于,4. The battery pack device according to claim 1 or 2, wherein: 电池组的单电池中,与设有端子的第1端面相反侧的第2端面朝向传热器的传热面侧,In the single cells of the battery pack, the second end surface on the opposite side to the first end surface provided with the terminal faces the heat transfer surface side of the heat exchanger, 单电池的第2端面成为所述第1受热面,The second end surface of the unit cell becomes the first heating surface, 单电池的侧面中的在与层叠方向正交的方向上成对的两个面成为所述第2受热面,Among the side surfaces of the single cells, two surfaces that are paired in a direction perpendicular to the stacking direction serve as the second heat receiving surfaces, 在各单电池配置有两个热传导部件,Each cell is equipped with two heat conduction parts, 两个热传导部件的第1单电池侧接触部与各单电池的第1受热面接触,并且两个热传导部件的第2单电池侧接触部与各单电池的第2受热面接触。The first cell side contact portions of the two heat conduction members are in contact with the first heat receiving surface of each cell, and the second cell side contact portions of the two heat conduction members are in contact with the second heat receiving surface of each cell. 5.根据权利要求1或2所述的电池组装置,其特征在于,5. The battery pack device according to claim 1 or 2, wherein: 电池组的单电池的侧面中的在与层叠方向正交的方向上成对的两个面之中的任一面成为所述第1受热面,Among the side surfaces of the single cells of the battery pack, any one of the two faces that are paired in a direction perpendicular to the stacking direction serves as the first heat receiving face, 单电池的侧面中的在层叠方向上成对的两个面之中的任一面成为所述第2受热面,any one of the two faces paired in the stacking direction among the side faces of the cells serves as the second heat receiving face, 在各单电池配置有一个热传导部件,Each cell is equipped with a heat conduction part, 除了一端的热传导部件以外的其它热传导部件的第2单电池侧接触部配置于电池组的相邻的单电池之间。The second battery-side contacts of the other heat-conducting members other than the heat-conducting member at one end are disposed between adjacent battery cells of the battery pack. 6.根据权利要求1或2所述的电池组装置,其特征在于,6. The battery pack device according to claim 1 or 2, wherein: 传热器具有一个传热面,The heat spreader has a heat transfer surface, 仅在传热器的设有传热面的一侧配置有电池组。The battery pack is arranged only on the heat transfer surface side of the heat transfer device. 7.根据权利要求1或2所述的电池组装置,其特征在于,7. The battery pack device according to claim 1 or 2, wherein 传热器具有彼此朝向相反侧的两个传热面,The heat spreader has two heat transfer faces facing opposite sides of each other, 在传热器的两侧配置有电池组。Battery packs are arranged on both sides of the heat spreader. 8.根据权利要求1或2所述的电池组装置,其特征在于,8. The battery pack device according to claim 1 or 2, wherein: 所述热传导部件具有碳粒子分散层与铝层交替层叠而成的多层结构,The heat conduction member has a multilayer structure in which carbon particle dispersion layers and aluminum layers are alternately laminated, 所述碳粒子分散层是在铝材料中分散碳粒子而形成的。The carbon particle dispersion layer is formed by dispersing carbon particles in an aluminum material. 9.根据权利要求1或2所述的电池组装置,其特征在于,9. The battery pack device according to claim 1 or 2, wherein 所述热传导部件是在复合体的两面通过接合剂层接合有单层或多层的树脂薄膜层而形成的层叠材料。The heat conduction member is a laminated material in which a single or multiple resin film layers are bonded to both surfaces of the composite body via an adhesive layer. 10.根据权利要求9所述的电池组装置,其特征在于,10. The battery pack device according to claim 9, wherein: 所述树脂薄膜层是聚对苯二甲酸乙二醇酯薄膜和尼龙薄膜的多层的树脂薄膜层,The resin film layer is a multilayer resin film layer of polyethylene terephthalate film and nylon film, 所述尼龙薄膜配置于复合体侧。The nylon film is disposed on the complex side.
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