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CN209308753U - A low-temperature flue gas cogeneration system for alumina process roasting - Google Patents

A low-temperature flue gas cogeneration system for alumina process roasting Download PDF

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CN209308753U
CN209308753U CN201822119824.7U CN201822119824U CN209308753U CN 209308753 U CN209308753 U CN 209308753U CN 201822119824 U CN201822119824 U CN 201822119824U CN 209308753 U CN209308753 U CN 209308753U
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heat exchanger
water
flue gas
outlet
low
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白彦江
鱼洋
樊旭
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In Color Twelve Metallurgical Chongqing Energy Saving Technology Co Ltd
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Abstract

本实用新型提出了一种氧化铝工艺焙烧低温烟气热电联产系统,包括发电子系统和再加热子系统,所述发电子系统包括与焙烧炉烟气总管连通的一级换热器,所述一级换热器的进烟口与焙烧炉烟气总管的排烟口连通,所述发电子系统中的工质为低沸点有机物;所述再加热子系统包括与一级换热器的出烟口连接的二级换热器,所述二级换热器的内网水出水口连接中间换热器的热侧进水口,所述中间换热器的冷侧出水口连接二级换热器的内网水进水口,所述中间换热器的冷侧进水口连通赤泥洗水循环系统的出水口,所述中间换热器的热侧出水口连通赤泥洗水循环系统的进水口。本实用新型设计合理,能够充分利用氧化铝焙烧炉中的低温烟气的余热增加企业的经济效益。

The utility model proposes a low-temperature flue gas cogeneration system for alumina process roasting, which includes a power generation sub-system and a reheating sub-system. The smoke inlet of the primary heat exchanger is connected with the smoke exhaust port of the flue gas main pipe of the roaster, and the working fluid in the power generation subsystem is a low-boiling organic substance; the reheating subsystem includes a A secondary heat exchanger connected to the smoke outlet, the internal network water outlet of the secondary heat exchanger is connected to the hot side water inlet of the intermediate heat exchanger, and the cold side water outlet of the intermediate heat exchanger is connected to the secondary heat exchanger The inner network water inlet of the heat exchanger, the cold side water inlet of the intermediate heat exchanger is connected to the water outlet of the red mud washing water circulation system, and the hot side water outlet of the intermediate heat exchanger is connected to the water inlet of the red mud washing water circulation system . The utility model has a reasonable design and can make full use of the waste heat of the low-temperature flue gas in the alumina roasting furnace to increase the economic benefits of the enterprise.

Description

一种氧化铝工艺焙烧低温烟气热电联产系统A low-temperature flue gas cogeneration system for alumina process roasting

技术领域technical field

本实用新型涉及工业烟气回收利用技术领域,具体涉及一种氧化铝工艺焙烧低温烟气热电联产系统。The utility model relates to the technical field of industrial flue gas recovery and utilization, in particular to a low-temperature flue gas cogeneration system for alumina process roasting.

背景技术Background technique

铝具有重量轻、不易腐蚀、可导电、以延伸等优点,广泛应用于航空航天、交通运输、建筑器材等领域,是仅次于钢铁的第二大金属材料。氧化铝焙烧工艺在冶金工业中广泛应用,在氧化铝焙烧工艺中,产生的焙烧炉烟气约为150℃,其中水含量约49%,露点温度约80℃,含有大量水蒸气汽化潜热,虽然存在着大量的能源消耗及广泛的余热分布,但是由于温度偏低,目前没有得到很好的回收利用。如何有效对烟气余热进行回收利用,不仅能够为企业来带经济效益,还能促进我国铝业金工业在环境保护和资源综合利用方面的发展。Aluminum has the advantages of light weight, non-corrosion, electrical conductivity, and stretchability. It is widely used in aerospace, transportation, and construction equipment. It is the second largest metal material after steel. The alumina roasting process is widely used in the metallurgical industry. In the alumina roasting process, the smoke generated from the roaster is about 150°C, the water content is about 49%, and the dew point temperature is about 80°C. It contains a large amount of latent heat of vaporization. Although There is a large amount of energy consumption and extensive waste heat distribution, but due to the low temperature, it has not been well recycled at present. How to effectively recycle the waste heat of flue gas can not only bring economic benefits to enterprises, but also promote the development of my country's aluminum industry in terms of environmental protection and comprehensive utilization of resources.

实用新型内容Utility model content

本实用新型旨在至少解决现有技术中存在的技术问题,特别创新地提出了一种氧化铝工艺焙烧低温烟气热电联产系统,以对氧化铝工业中的低温烟气余热再回收利用。The utility model aims to at least solve the technical problems existing in the prior art, and particularly innovatively proposes a low-temperature flue gas cogeneration system for alumina process roasting, so as to recycle the waste heat of low-temperature flue gas in the alumina industry.

为了实现本实用新型的上述目的,本实用新型提供了一种氧化铝工艺焙烧低温烟气热电联产系统,包括发电子系统和再加热子系统,所述发电子系统包括与焙烧炉烟气总管连通的一级换热器,所述一级换热器的进烟口与焙烧炉烟气总管的排烟口连通,所述一级换热器用于将焙烧炉烟气总管排出的烟气与一级换热器的内网水进行换热,所述一级换热器的高温供水口连通蒸发器的热源进水口,所述蒸发器的热源出水口连通预热器的热源进水口,所述预热器的热源出水口连通一级换热器的低温回水口,所述预热器的工质进口连通工质泵的工质出口,所述预热器的工质出口与蒸发器的工质进口相连,所述蒸发器的工质出口连通到发电机组的工质进口,所述发电机组的工质出口连接到冷凝器的工质进口,所述冷凝器的工质出口连接到工质泵的工质进口;In order to achieve the above purpose of the utility model, the utility model provides a low-temperature flue gas cogeneration system for alumina roasting, including a power generation sub-system and a reheating sub-system. A connected primary heat exchanger, the smoke inlet of the primary heat exchanger communicates with the smoke exhaust port of the flue gas main pipe of the roaster, and the primary heat exchanger is used to connect the flue gas discharged from the flue gas main pipe of the roaster with the The internal network water of the primary heat exchanger performs heat exchange, the high temperature water supply port of the primary heat exchanger is connected to the heat source water inlet of the evaporator, and the heat source water outlet of the evaporator is connected to the heat source water inlet of the preheater, so The heat source water outlet of the preheater is connected to the low-temperature return water port of the primary heat exchanger, the working fluid inlet of the preheater is connected to the working fluid outlet of the working fluid pump, and the working fluid outlet of the preheater is connected to the evaporator The working fluid inlet is connected, the working fluid outlet of the evaporator is connected to the working fluid inlet of the generator set, the working fluid outlet of the generator set is connected to the working fluid inlet of the condenser, and the working fluid outlet of the condenser is connected to the working fluid inlet The working fluid inlet of the pump;

所述再加热子系统包括与一级换热器的出烟口连接的二级换热器,所述二级换热器用于将一级换热器排出的烟气与二级换热器的内网水进行换热,所述二级换热器的内网水出水口连接中间换热器的热侧进水口,所述中间换热器的冷侧出水口连接二级换热器的内网水进水口,所述中间换热器的冷侧进水口连通赤泥洗水循环系统的出水口,所述中间换热器的热侧出水口连通赤泥洗水循环系统的进水口,所述中间换热器用于将二级换热器的内网水和赤泥洗水进行换热。The reheating subsystem includes a secondary heat exchanger connected to the smoke outlet of the primary heat exchanger, and the secondary heat exchanger is used to combine the flue gas discharged from the primary heat exchanger with the exhaust gas of the secondary heat exchanger. The internal network water is used for heat exchange, the internal network water outlet of the secondary heat exchanger is connected to the hot side water inlet of the intermediate heat exchanger, and the cold side water outlet of the intermediate heat exchanger is connected to the inner network of the secondary heat exchanger. Net water inlet, the cold side water inlet of the intermediate heat exchanger is connected to the water outlet of the red mud washing water circulation system, the hot side water outlet of the intermediate heat exchanger is connected to the water inlet of the red mud washing water circulation system, and the middle The heat exchanger is used to exchange heat between the internal network water of the secondary heat exchanger and the red mud washing water.

一级换热器用于回收焙烧炉烟气总管中烟气的显热,产生热水,作为热源驱动发电机组发电。工质泵用于为工质提供流动的压力,工质在工质泵的压力驱动下,先后经过预热器和蒸发器,被热水加热形成气态工质,进入发电机组并推动发电机组做功发电,经发电机组排出后继续进入冷凝器,经冷凝器冷凝成液态工质,回到工质泵继续循环,以此完成对烟气显热的发电作用。The primary heat exchanger is used to recover the sensible heat of the flue gas in the flue gas main pipe of the roaster to generate hot water, which is used as a heat source to drive the generator set to generate electricity. The working medium pump is used to provide flowing pressure for the working medium. Driven by the pressure of the working medium pump, the working medium passes through the preheater and the evaporator successively, is heated by hot water to form a gaseous working medium, enters the generator set and drives the generator set to do work Power generation, after being discharged by the generator set, it continues to enter the condenser, condenses into a liquid working medium through the condenser, and returns to the working medium pump to continue circulation, so as to complete the power generation of the sensible heat of the flue gas.

二级换热器用于回收从一级换热器中排出的烟气的潜热,产生热水。中间换热器用于将二级换热器中内网水的热量传递给赤泥洗水,加热后的赤泥洗水供后续工艺使用,以此完成利用烟气潜热继续加热赤泥洗水。The secondary heat exchanger is used to recover the latent heat of the flue gas discharged from the primary heat exchanger to generate hot water. The intermediate heat exchanger is used to transfer the heat of the internal network water in the secondary heat exchanger to the red mud washing water, and the heated red mud washing water is used for subsequent processes, so as to complete the use of flue gas latent heat to continue heating the red mud washing water.

上述方案中:所述一级换热器和二级换热器的内网水均为碱性水。碱性水相比纯净水不会产生由于收吸收烟气中的酸性成分后对设备造成酸蚀的现象,延长设备使用周期。In the above scheme: the internal network water of the primary heat exchanger and the secondary heat exchanger are both alkaline water. Compared with pure water, alkaline water will not cause acid corrosion to equipment due to the absorption of acidic components in flue gas, prolonging the service life of equipment.

上述方案中:所述中间换热器为板式换热器。板式换热器的热传系数高,传递给赤泥洗水的过程中损能较少,尽可能减少能量损耗,提高回收利用率。In the above solution: the intermediate heat exchanger is a plate heat exchanger. The heat transfer coefficient of the plate heat exchanger is high, and the energy loss in the process of transferring to the red mud washing water is less, so as to reduce energy loss as much as possible and improve the recycling rate.

上述方案中:所述发电机组为透平发电机组。与螺杆膨胀机相比,最大膨胀比较大,能够充分利用热源及工质发电,提高发电量。In the above solution: the generator set is a turbo generator set. Compared with the screw expander, the maximum expansion ratio is relatively large, which can make full use of the heat source and working fluid to generate electricity and increase the power generation.

上述方案中:所述发电子系统中的工质为低沸点有机物。其沸点满足能被一级内网水的热能加热成为气态工质。也就是说,其沸点低于一级内网水的温度。In the above scheme: the working fluid in the power generation sub-system is a low-boiling organic substance. Its boiling point is enough to be heated by the heat energy of the first-level internal network water to become a gaseous working fluid. That is to say, its boiling point is lower than the temperature of the first-level internal network water.

综上所述,由于采用了上述技术方案,本实用新型的有益效果是:能够充分利用氧化铝焙烧炉中的低温烟气的余热进行两次回收利用,增加企业的经济效益,保护环境;设计合理,对烟气的回收部分采用直接换热的方式,能够最大程度吸收烟气中的水蒸气汽化潜热,对赤泥洗水的加热部分采用间接换热的方式,通过中间换热器能够避免赤泥洗水中偏铝酸与酸性物质接触,充分回收热量的同时避免结垢。In summary, due to the adoption of the above technical solution, the beneficial effects of the utility model are: the waste heat of the low-temperature flue gas in the alumina roasting furnace can be fully utilized for two recycling, increasing the economic benefits of the enterprise and protecting the environment; Reasonable, the direct heat exchange method is adopted for the recovery part of the flue gas, which can absorb the latent heat of vaporization in the flue gas to the greatest extent, and the indirect heat exchange method is adopted for the heating part of the red mud washing water, and the intermediate heat exchanger can avoid The meta-aluminic acid in the red mud washing water is in contact with the acidic substances to fully recover heat and avoid scaling.

附图说明Description of drawings

图1是本实用新型的示意图。Fig. 1 is the schematic diagram of the utility model.

具体实施方式Detailed ways

下面详细描述本实用新型的实施例,所述实施例的示例在附图中示出,其中自始至终相同或类似的标号表示相同或类似的元件或具有相同或类似功能的元件。下面通过参考附图描述的实施例是示例性的,仅用于解释本实用新型,而不能理解为对本实用新型的限制。Embodiments of the present invention are described in detail below, examples of which are shown in the drawings, wherein the same or similar reference numerals represent the same or similar elements or elements having the same or similar functions throughout. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present utility model, but should not be construed as limiting the present utility model.

如图1所示的一种氧化铝工艺焙烧低温烟气热电联产系统,包括发电子系统和再加热子系统,发电子系统包括与焙烧炉烟气总管1连通的一级换热器2,一级换热器2的进烟口与焙烧炉烟气总管1的排烟口连通,一级换热器2用于将焙烧炉烟气总管1排出的烟气与一级换热器2的内网水进行换热,一级换热器2的高温供水口连通蒸发器4的热源进水口,蒸发器4的热源出水口连通预热器8的热源进水口,预热器8的热源出水口连通一级换热器2的低温回水口,预热器8的工质进口连通工质泵7的工质出口,预热器8的工质出口与蒸发器4的工质进口相连,蒸发器4的工质出口连通到发电机组5的工质进口,发电机组5的工质出口连接到冷凝器6的工质进口,冷凝器6的工质出口连接到工质泵7的工质进口,发电子系统中的工质为低沸点有机物;As shown in Figure 1, a low-temperature flue gas cogeneration system for alumina process roasting includes a power generation sub-system and a reheating sub-system. The smoke inlet of the primary heat exchanger 2 is connected with the smoke outlet of the flue gas main pipe 1 of the roaster, and the primary heat exchanger 2 is used to connect the flue gas discharged from the flue gas main pipe 1 of the roaster with the exhaust port of the primary heat exchanger 2 The internal network water is used for heat exchange, the high temperature water supply port of the primary heat exchanger 2 is connected to the heat source water inlet of the evaporator 4, the heat source water outlet of the evaporator 4 is connected to the heat source water inlet of the preheater 8, and the heat source outlet of the preheater 8 The water port is connected to the low-temperature return water port of the primary heat exchanger 2, the working medium inlet of the preheater 8 is connected to the working medium outlet of the working medium pump 7, the working medium outlet of the preheater 8 is connected to the working medium inlet of the evaporator 4, and the evaporation The working medium outlet of the condenser 4 is connected to the working medium inlet of the generator set 5, the working medium outlet of the generator set 5 is connected to the working medium inlet of the condenser 6, and the working medium outlet of the condenser 6 is connected to the working medium inlet of the working medium pump 7 , the working fluid in the power generation subsystem is a low-boiling organic compound;

再加热子系统包括与一级换热器2的出烟口连接的二级换热器3,二级换热器3内设有内网水,二级换热器3的内网水出水口连接中间换热器9的热侧进水口,中间换热器9为水-水换热器,中间换热器9的冷侧出水口连接二级换热器3的内网水进水口,中间换热器9的冷侧进水口连通赤泥洗水循环系统的出水口,中间换热器9的热侧出水口连通赤泥洗谁循环系统的进水口,中间换热器9用于将二级换热器3排出的烟气和赤泥洗水进行换热。The reheating subsystem includes a secondary heat exchanger 3 connected to the smoke outlet of the primary heat exchanger 2, the secondary heat exchanger 3 is provided with internal network water, and the internal network water outlet of the secondary heat exchanger 3 Connect the hot side water inlet of the intermediate heat exchanger 9, the intermediate heat exchanger 9 is a water-water heat exchanger, the cold side water outlet of the intermediate heat exchanger 9 is connected to the internal network water inlet of the secondary heat exchanger 3, and the middle The water inlet on the cold side of the heat exchanger 9 is connected to the water outlet of the red mud washing circulation system, the water outlet on the hot side of the intermediate heat exchanger 9 is connected to the water inlet of the red mud washing circulation system, and the intermediate heat exchanger 9 is used to convert the secondary The flue gas discharged from the heat exchanger 3 exchanges heat with the red mud washing water.

为延长设备使用周期,一级换热器2和二级换热器3的内网水均为碱性水,碱性水相比纯净水不会产生由于吸收烟气中的酸性成分后对设备造成酸蚀的现象。In order to prolong the service life of the equipment, the internal network water of the primary heat exchanger 2 and the secondary heat exchanger 3 is alkaline water. cause acid corrosion.

为提高回收利用率,中间换热器9采用板式换热器,板式换热器的热传系数高,传递给赤泥洗水的过程中损能较少,尽可能减少能量损耗。In order to improve the recycling rate, the intermediate heat exchanger 9 adopts a plate heat exchanger. The heat transfer coefficient of the plate heat exchanger is high, and the energy loss in the process of transferring to the red mud washing water is small, so as to reduce energy loss as much as possible.

为提高发电量,发电机组5为透平发电机组,能够充分利用热源及工质发电,且效率均可达到80%以上,长期稳定高效。In order to increase the power generation, the generator set 5 is a turbo generator set, which can make full use of heat sources and working fluids to generate electricity, and the efficiency can reach more than 80%, which is stable and efficient for a long time.

经焙烧炉烟气总管1排出的约150℃烟气进入一级换热器2回收显热,加热一级换热器2的内网水至80℃~120℃,工质泵7驱动工质依次进入预热器8和蒸发器4,工质进入预热器8后在预热器8通过一级换热器2的内网水进行预热,再在蒸发器4中被一级换热器1的内网水加热并形成蒸汽,进入发电机组5并推动发电机组5做功发电。经发电机组5排出后进入冷凝器6冷凝形成液态工质,回到工质泵7继续循环,以此利用烟气显热完成发电作用。The flue gas at about 150°C discharged through the flue gas main pipe 1 of the roaster enters the primary heat exchanger 2 to recover sensible heat, heats the internal network water of the primary heat exchanger 2 to 80°C-120°C, and the working fluid pump 7 drives the working fluid Enter the preheater 8 and the evaporator 4 in turn. After entering the preheater 8, the working fluid is preheated in the preheater 8 through the internal network water of the primary heat exchanger 2, and then is exchanged by the primary heat in the evaporator 4. The water in the internal network of the device 1 is heated and forms steam, which enters the generator set 5 and drives the generator set 5 to generate power. After being discharged from the generator set 5, it enters the condenser 6 to condense to form a liquid working medium, and returns to the working medium pump 7 to continue circulation, so as to complete the power generation by utilizing the sensible heat of the flue gas.

烟气经一级换热器2吸热后温度降低至100℃左右,再进入二级换热器3进行二次利用。二级换热器3吸收烟气中的潜热,以加热二级换热器3中的内网水,并将烟气温度降低至75℃左右再排出。通过中间换热器9将二级换热器3中的内网水与赤泥洗水之间进行换热,加热后的赤泥洗水供后续工艺使用,以此利用烟气潜热完成对赤泥洗水的加热。After the flue gas absorbs heat through the primary heat exchanger 2, the temperature drops to about 100°C, and then enters the secondary heat exchanger 3 for secondary use. The secondary heat exchanger 3 absorbs the latent heat in the flue gas to heat the internal network water in the secondary heat exchanger 3 and lower the temperature of the flue gas to about 75°C before discharging. Through the intermediate heat exchanger 9, heat is exchanged between the internal network water in the secondary heat exchanger 3 and the red mud washing water, and the heated red mud washing water is used for the subsequent process, so that the red mud washing water can be completed by using the latent heat of the flue gas. Heating of mud washing water.

产生的经济效益以年产200万吨氧化铝工艺生产线为例,发电机组装机容量1800kW,年发电量1300万kW·h,加热1500t/h赤泥洗水或3000t/h总分母液至70℃,年供热量180万GJ,实现年节标煤6.5万吨,二氧化碳减排16.2万吨。The economic benefits produced take the alumina process production line with an annual output of 2 million tons as an example. The generator assembly capacity is 1800kW, the annual power generation capacity is 13 million kW·h, and the washing water of 1500t/h red mud or 3000t/h total fraction mother liquor is heated to 70℃ , with an annual heat supply of 1.8 million GJ, an annual saving of 65,000 tons of standard coal, and a reduction of 162,000 tons of carbon dioxide emissions.

尽管已经示出和描述了本实用新型的实施例,本领域的普通技术人员可以理解:在不脱离本实用新型的原理和宗旨的情况下可以对这些实施例进行多种变化、修改、替换和变型,本实用新型的范围由权利要求及其等同物限定。Although the embodiments of the present invention have been shown and described, those skilled in the art can understand that various changes, modifications, substitutions and modifications, the scope of the present invention is defined by the claims and their equivalents.

Claims (5)

1. a kind of alumina technology roasts low-temperature flue gas co-generation unit, it is characterised in that: add including power generation sub-system and again Thermal sub-system, the power generation sub-system include the first-class heat exchanger (2) being connected to baking furnace fume general pipeline (1), and the level-one is changed The smoke inlet of hot device (2) is connected to the smoke outlet of baking furnace fume general pipeline (1), and the first-class heat exchanger (2) is used for roaster The flue gas of flue gas general pipeline (1) discharge and the Intranet water of first-class heat exchanger (2) exchange heat, the high temperature of the first-class heat exchanger (2) Feed water inlet is connected to the heat source water inlet of evaporator (4), the heat source of heat source water outlet connection preheater (8) of the evaporator (4) Water inlet, the low-temperature return water mouth of heat source water outlet connection first-class heat exchanger (2) of the preheater (8), the preheater (8) The sender property outlet of working medium inlet communication working medium pump (7), the sender property outlet of the preheater (8) and the working medium import of evaporator (4) It is connected, the sender property outlet of the evaporator (4) is communicated to the working medium import of generating set (5), the working medium of the generating set (5) Outlet is connected to the working medium import of condenser (6), the sender property outlet of the condenser (6) be connected to the working medium of working medium pump (7) into Mouthful;
The reheating subsystem includes the secondary heat exchanger (3) connecting with the outlet flue of first-class heat exchanger (2), and the second level is changed Hot device (3) is for exchanging heat the Intranet water of flue gas and secondary heat exchanger (3) that first-class heat exchanger (2) are discharged, the second level The hot side water inlet of Intranet water water outlet connection Intermediate Heat Exchanger (9) of heat exchanger (3), the cold side of the Intermediate Heat Exchanger (9) Water outlet connects the Intranet water water inlet of secondary heat exchanger (3), and the cold side water inlet connection red mud of the Intermediate Heat Exchanger (9) is washed The water outlet of water circulation system, the water inlet of the hot side water outlet connection red mud wash water circulatory system of the Intermediate Heat Exchanger (9), The Intermediate Heat Exchanger (9) is for exchanging heat the Intranet water of secondary heat exchanger (3) and red mud wash water.
2. a kind of alumina technology according to claim 1 roasts low-temperature flue gas co-generation unit, it is characterised in that: institute The Intranet water for stating first-class heat exchanger (2) and secondary heat exchanger (3) is alkaline water.
3. a kind of alumina technology according to claim 2 roasts low-temperature flue gas co-generation unit, it is characterised in that: institute Stating Intermediate Heat Exchanger (9) is plate heat exchanger.
4. a kind of alumina technology according to claim 1 roasts low-temperature flue gas co-generation unit, it is characterised in that: institute Stating generating set (5) is turbine power generation unit.
5. a kind of alumina technology according to claim 1 roasts low-temperature flue gas co-generation unit, it is characterised in that: institute Stating the working medium in power generation sub-system is low-boiling-point organic compound.
CN201822119824.7U 2018-12-18 2018-12-18 A low-temperature flue gas cogeneration system for alumina process roasting Expired - Fee Related CN209308753U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114459252A (en) * 2021-12-29 2022-05-10 茌平信发华宇氧化铝有限公司 Comprehensive utilization process for flue gas waste heat of roasting furnace and flue gas treatment device

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114459252A (en) * 2021-12-29 2022-05-10 茌平信发华宇氧化铝有限公司 Comprehensive utilization process for flue gas waste heat of roasting furnace and flue gas treatment device
CN114459252B (en) * 2021-12-29 2023-10-27 茌平信发华宇氧化铝有限公司 A comprehensive utilization process of roasting furnace flue gas waste heat and a flue gas treatment device

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