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CN209307143U - A zero-discharge system for high-salt and high-turbidity industrial wastewater - Google Patents

A zero-discharge system for high-salt and high-turbidity industrial wastewater Download PDF

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CN209307143U
CN209307143U CN201822057602.7U CN201822057602U CN209307143U CN 209307143 U CN209307143 U CN 209307143U CN 201822057602 U CN201822057602 U CN 201822057602U CN 209307143 U CN209307143 U CN 209307143U
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water
sand filter
capacitive deionization
tank
water inlet
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徐斌
张毅敏
吴文倩
张书陵
许雪婷
彭福全
孔明
朱月明
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Nanjing Institute of Environmental Sciences MEP
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Abstract

本实用新型公开了一种高盐高浊工业废水零排放系统,包括沿废水流经方向依次连通的进水水箱、絮凝沉淀系统、砂滤装置和电吸附系统;其中,电吸附系统包括若干个连通的电容去离子装置;还包括反冲洗系统和热蒸发结晶系统;反冲洗系统与砂滤装置和电容去离子装置连通,对砂滤装置和电容去离子装置进行反冲洗处理;热蒸发结晶系统与砂滤装置和电容去离子装置连通,对砂滤装置和电容去离子装置进行反冲洗后的浓水进行热蒸发处理。本实用新型能够实现快速、高效的脱盐除浊,整套系统能稳定运行,能耗低。

The utility model discloses a zero-discharge system for high-salt and high-turbidity industrial waste water, which comprises a water inlet tank, a flocculation sedimentation system, a sand filter device and an electric adsorption system successively connected along the direction of waste water flow; wherein, the electric adsorption system includes several A connected capacitive deionization device; also includes a backwash system and a thermal evaporation crystallization system; the backwash system is connected with the sand filter device and the capacitive deionization device, and backwashes the sand filter device and the capacitive deionization device; the thermal evaporation crystallization system It communicates with the sand filter device and the capacitive deionization device, and performs thermal evaporation treatment on the concentrated water after backwashing by the sand filter device and the capacitive deionization device. The utility model can realize fast and efficient desalination and turbidity removal, and the whole system can run stably with low energy consumption.

Description

一种高盐高浊工业废水零排放系统A zero-discharge system for high-salt and high-turbidity industrial wastewater

技术领域technical field

本实用新型属于水处理领域,涉及一种高盐高浊污水处理,尤其涉及一种高盐高浊工业废水零排放系统。The utility model belongs to the field of water treatment, and relates to the treatment of high-salt and high-turbidity sewage, in particular to a zero-discharge system for high-salt and high-turbidity industrial waste water.

背景技术Background technique

工业废水是造成水污染的主要来源,高盐高浊废水是工业废水中常见的废水之一,具有浊度高、含盐量高、盐成分复杂等特点。目前节能减排形势日趋严峻,各项环保法律法规逐渐完善,工业企业迫切需要通过技术工艺提升将废水进行处理并实现零排放,减少对环境的污染,实现社会、经济和环境效益相统一。Industrial wastewater is the main source of water pollution. High-salt and high-turbidity wastewater is one of the common wastewater in industrial wastewater. It has the characteristics of high turbidity, high salt content, and complex salt composition. At present, the situation of energy saving and emission reduction is becoming increasingly severe, and various environmental protection laws and regulations are gradually improving. Industrial enterprises urgently need to process wastewater through technological improvement to achieve zero discharge, reduce environmental pollution, and achieve social, economic and environmental benefits.

针对高盐高浊工业废水,国内外常规的处理方法包括膜处理法、电化学技术和热处理法等。但是单一的处理方法处理能力有限,除浊脱盐效果不理想,存在着许多局限性。中国专利授权号CN205856210U公开了一种纳滤-电吸附-反渗透去除高浓度含盐废水装置,用其脱除高浓度含盐废水中盐类物质,再生回用。但是该处理方案未考虑到纳滤膜、反渗透膜、电吸附装置污染后反冲洗水的处理。以及为对整个运行系统进行水质实时监控,确保处理效果达标。中国专利公布号CN107399864 A公开了一种高含盐含油废水综合处理系统及工艺,该专利将砂滤装置、超滤装置和膜电容去离子装置结合在一起处理高含盐含油废水,但是该专利未考虑到膜组件和电吸附装置的污染问题,以及未设计水质保障装置确保在水质不达标情况下进行应急处理。中国专利公布号CN107381923A公开了基于膜电容去离子和膜蒸馏的海水淡化处理装置及其方法,膜蒸馏法目前尚未成熟,耗能高,应用于工业废水处理领域容易造成膜污染,产水通量较低。For high-salt and high-turbidity industrial wastewater, conventional treatment methods at home and abroad include membrane treatment, electrochemical technology and heat treatment. However, the treatment capacity of a single treatment method is limited, and the effect of removing turbidity and desalination is not ideal, and there are many limitations. Chinese Patent Grant No. CN205856210U discloses a nanofiltration-electric adsorption-reverse osmosis device for removing high-concentration saline wastewater, which is used to remove salt substances in high-concentration saline wastewater for regeneration and reuse. However, this treatment plan does not take into account the treatment of backwash water after contamination by nanofiltration membranes, reverse osmosis membranes, and electro-adsorption devices. And in order to monitor the water quality of the entire operation system in real time to ensure that the treatment effect is up to standard. Chinese Patent Publication No. CN107399864 A discloses a comprehensive treatment system and process for high-salt and oily wastewater. This patent combines a sand filter device, an ultrafiltration device and a membrane capacitive deionization device to treat high-salt and oily wastewater. However, the patent The pollution of membrane modules and electro-adsorption devices is not considered, and the water quality assurance device is not designed to ensure emergency treatment when the water quality is not up to standard. Chinese Patent Publication No. CN107381923A discloses a seawater desalination treatment device and method based on membrane capacitive deionization and membrane distillation. Membrane distillation is currently immature and consumes high energy. It is easy to cause membrane pollution when used in the field of industrial wastewater treatment, and the water flux is low. lower.

实用新型内容Utility model content

本实用新型提供一种高盐高浊工业废水零排放系统,以克服现有技术的缺陷。The utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater to overcome the defects of the prior art.

为实现上述目的,本实用新型提供一种高盐高浊工业废水零排放系统,包括沿废水流经方向依次连通的进水水箱、絮凝沉淀系统、砂滤装置和电吸附系统;其中,电吸附系统包括若干个连通的电容去离子装置;还包括反冲洗系统和热蒸发结晶系统;反冲洗系统与砂滤装置和电容去离子装置连通,对砂滤装置和电容去离子装置进行反冲洗处理;热蒸发结晶系统与砂滤装置和电容去离子装置连通,对砂滤装置和电容去离子装置进行反冲洗后的浓水进行热蒸发处理。In order to achieve the above purpose, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which includes a water inlet tank, a flocculation sedimentation system, a sand filter device and an electro-adsorption system sequentially connected along the direction of waste water flow; wherein, the electro-adsorption The system includes several connected capacitive deionization devices; it also includes a backwashing system and a thermal evaporation crystallization system; the backwashing system is connected with the sand filter device and the capacitive deionization device, and backwashes the sand filter device and the capacitive deionization device; The thermal evaporation crystallization system is connected with the sand filter device and the capacitive deionization device, and performs thermal evaporation treatment on the concentrated water after the backwash of the sand filter device and the capacitive deionization device.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:还包括PLC控制系统和砂滤电导率仪;砂滤电导率仪与砂滤装置连通,检测砂滤装置处理后废水的电导率;电吸附系统还包括若干个电导率仪和进水电磁阀门;电导率仪与电容去离子装置一一对应、并连通,电导率仪检测与其相通的电容去离子装置的处理后废水的电导率;进水电磁阀门与电容去离子装置一一对应、并设置在其进水管路上,控制电容去离子装置的进水量;PLC控制系统监测砂滤电导率仪和电导率仪的数据,控制进水电磁阀门的开关。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which can also have the following features: it also includes a PLC control system and a sand filter conductivity meter; the sand filter conductivity meter is connected with the sand filter device to detect sand The conductivity of the wastewater treated by the filter device; the electro-adsorption system also includes several conductivity meters and water inlet solenoid valves; the conductivity meter corresponds to and communicates with the capacitive deionization device one by one, and the conductivity meter detects the capacitive deionization device connected to it. The conductivity of the treated wastewater in the device; the water inlet electromagnetic valve corresponds to the capacitive deionization device one by one, and is set on the water inlet pipeline to control the water inflow of the capacitive deionization device; the PLC control system monitors the sand filter conductivity meter and conductivity The data of the rate meter controls the switch of the water inlet solenoid valve.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:其中,电吸附系统还包括若干个中间水箱;中间水箱与电容去离子装置一一对应、并与其出口连通,电容去离子装置处理后的废水流入中间水箱;电导率仪与中间水箱连通,测量其内废水的电导率。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which can also have the following characteristics: wherein, the electrosorption system also includes several intermediate water tanks; the intermediate water tanks correspond to the capacitance deionization device one by one, and The outlet is connected, and the wastewater treated by the capacitive deionization device flows into the intermediate water tank; the conductivity meter is connected with the intermediate water tank to measure the conductivity of the wastewater in it.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:其中,电容去离子装置和中间水箱的数量均为三个,分别为沿废水流入方向依次连通的一级电容去离子装置、一级中间水箱、二级电容去离子装置、二级中间水箱、三级电容去离子装置和三级中间水箱;进水电磁阀门的数量为三个,分别为一级进水电磁阀门、二级进水电磁阀门和三级进水电磁阀门,分别设置在一级电容去离子装置、二级电容去离子装置和三级电容去离子装置的进水管路上,控制其进水量;电导率仪的数量为三个,分别为一级电导率仪、二级电导率仪和三级电导率仪,分别与一级中间水箱、二级中间水箱和三级中间水箱连通,测量其内废水的电导率;三级中间水箱与反冲洗系统连通,为其提供反冲洗清水;电吸附系统还包括出水电磁阀门,设置在三级中间水箱的出水管路上,控制反冲洗系统的反冲洗清水量;PLC控制系统监测砂滤电导率仪、一级电导率仪、二级电导率仪和三级电导率仪的数据,并控制一级进水电磁阀门、二级进水电磁阀门、三级进水电磁阀门和出水电磁阀门的开关。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which may also have the following characteristics: wherein, there are three capacitive deionization devices and three intermediate water tanks, which are respectively connected sequentially along the direction of wastewater inflow. The first-stage capacitive deionization device, the first-stage intermediate water tank, the second-stage capacitive deionization device, the second-stage intermediate water tank, the third-stage capacitive deionization device, and the third-stage intermediate water tank; the number of water inlet electromagnetic valves is three, respectively The water inlet solenoid valve, the secondary water inlet solenoid valve and the tertiary water inlet solenoid valve are respectively set on the water inlet pipelines of the first-stage capacitive deionization device, the second-stage capacitive deionization device and the third-stage capacitive deionization device to control the water inlet Water volume; the number of conductivity meters is three, namely the first-level conductivity meter, the second-level conductivity meter and the third-level conductivity meter, which are respectively connected with the first-level intermediate water tank, the second-level intermediate water tank and the third-level intermediate water tank. The electrical conductivity of the wastewater in it; the three-stage intermediate water tank is connected with the backwash system to provide it with backwash clean water; the electro-adsorption system also includes a water outlet electromagnetic valve, which is set on the outlet pipe of the three-stage intermediate water tank to control the backwash system. Washing water volume; PLC control system monitors the data of the sand filter conductivity meter, the first-level conductivity meter, the second-level conductivity meter and the third-level conductivity meter, and controls the first-level water inlet electromagnetic valve, the second-level water inlet electromagnetic valve, Three-stage water inlet solenoid valve and water outlet solenoid valve switch.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:其中,反冲洗系统包括反冲洗水箱和若干个反冲洗水泵,反冲洗水箱与砂滤装置和电容去离子装置分别连通,并通过相应的反冲洗水泵向其泵入反冲洗清水。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which can also have the following characteristics: wherein, the backwashing system includes a backwashing water tank and several backwashing water pumps, a backwashing water tank, a sand filter device and a capacitor The deionization devices are connected separately, and the backwash clean water is pumped into them through the corresponding backwash water pump.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:其中,热蒸发结晶系统冷凝产生的冷凝水输送至反冲洗系统回用。Furthermore, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which may also have the following feature: wherein, the condensed water produced by condensation in the thermal evaporation crystallization system is transported to the backwashing system for reuse.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:还包括浓水水箱和浓水水箱泵;浓水水箱与砂滤装置和电容去离子装置连通,接收储存砂滤装置和电容去离子装置进行反冲洗处理后的浓水;浓水水箱还与热蒸发结晶系统连通,通过浓水水箱泵向其输送待处理浓水。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which may also have the following features: it also includes a concentrated water tank and a concentrated water tank pump; the concentrated water tank is connected with a sand filter device and a capacitive deionization device, Receiving and storing the concentrated water after backwashing by the sand filter device and the capacitive deionization device; the concentrated water tank is also connected with the thermal evaporation crystallization system, and the concentrated water to be treated is delivered to it through the concentrated water tank pump.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:其中,絮凝沉淀系统包括沉淀池、污泥泵和污泥干化池;沉淀池分别与进水水箱和砂滤装置连通,沉淀池内投放絮凝剂,去除废水中的悬浮物和油脂类物质,絮凝沉淀处理后的废水输送至砂滤装置;沉淀池与污泥干化池连通,污泥泵设置于沉淀池和污泥干化池之间,将沉淀池沉淀下来的污泥泵入污泥干化池。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which can also have the following characteristics: wherein, the flocculation and sedimentation system includes a sedimentation tank, a sludge pump and a sludge drying tank; The water tank is connected to the sand filter device, flocculant is put into the sedimentation tank to remove suspended solids and grease substances in the wastewater, and the wastewater after flocculation and sedimentation treatment is transported to the sand filter device; the sedimentation tank is connected to the sludge drying tank, and the sludge pump is set Between the sedimentation tank and the sludge drying tank, the sludge settled in the sedimentation tank is pumped into the sludge drying tank.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:还包括进水泵,设置在进水水箱和絮凝沉淀系统之间,将进水水箱中的废水泵入絮凝沉淀系统。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which may also have the following characteristics: it also includes an inlet pump, which is arranged between the inlet water tank and the flocculation and sedimentation system, and pumps the waste water in the inlet water tank into the flocculation and sedimentation system.

进一步,本实用新型提供一种高盐高浊工业废水零排放系统,还可以具有这样的特征:还包括沉淀水泵,设置在絮凝沉淀系统和砂滤装置之间,将絮凝沉淀系统处理后的废水泵入砂滤装置。Further, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which may also have such a feature: it also includes a sedimentation pump, which is arranged between the flocculation sedimentation system and the sand filter device, and the wastewater treated by the flocculation sedimentation system Pump into sand filter unit.

本实用新型的有益效果在于:本实用新型提供一种高盐高浊工业废水零排放系统,包括进水水箱、絮凝沉淀系统、电吸附系统、砂滤装置、反冲洗系统、热蒸发结晶系统和PLC控制系统。其中絮凝沉淀系统和砂滤装置去除工业废水中的悬浮物和有机物,为电吸附系统做预处理。反冲洗系统用以清洗砂滤装置和电吸附系统,延长系统使用寿命,保证其脱盐除浊效果。热蒸发结晶系统将整套系统反冲洗产生的高含盐的浓水浓缩制备成废盐处理。电吸附系统吸附去除工业废水中的盐离子。PLC控制系统对整套系统进行实时智能监控,对未达标的处理系统进行应急处理,保证运行的稳定性。本实用新型提供的高盐高浊工业废水零排放系统能够实现快速、高效的脱盐除浊,整套系统能稳定运行,采用热蒸发结晶工艺和电容去离子吸附工艺能耗低,对实际生产应用有很好的借鉴意义。The beneficial effects of the utility model are: the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, including a water inlet tank, a flocculation sedimentation system, an electric adsorption system, a sand filter device, a backwash system, a thermal evaporation crystallization system and PLC control system. Among them, the flocculation sedimentation system and sand filter device remove suspended solids and organic matter in industrial wastewater, and do pretreatment for the electro-adsorption system. The backwashing system is used to clean the sand filter device and the electric adsorption system, prolong the service life of the system, and ensure its desalination and turbidity removal effect. The thermal evaporation crystallization system concentrates the high-salt concentrated water produced by the backwash of the entire system to prepare waste salt for treatment. The electro-adsorption system adsorbs and removes salt ions in industrial wastewater. The PLC control system conducts real-time intelligent monitoring of the entire system, and performs emergency treatment for the processing system that does not meet the standards to ensure the stability of operation. The zero-discharge system for high-salt and high-turbidity industrial wastewater provided by the utility model can realize fast and efficient desalination and turbidity removal, and the whole system can run stably. The thermal evaporation crystallization process and capacitive deionization adsorption process are adopted with low energy consumption, which is beneficial to actual production and application. Very good reference.

附图说明Description of drawings

图1是高盐高浊工业废水零排放系统的示意图。Figure 1 is a schematic diagram of a zero-discharge system for high-salt and high-turbidity industrial wastewater.

具体实施方式Detailed ways

以下结合附图来说明本实用新型的具体实施方式。The specific embodiment of the utility model is described below in conjunction with accompanying drawing.

如图1所示,本实用新型提供一种高盐高浊工业废水零排放系统,包括沿废水流经方向依次连通的进水水箱100、絮凝沉淀系统、砂滤装置300和电吸附系统,还包括反冲洗系统、浓水水箱600、热蒸发系结晶系统700和PLC控制系统800。As shown in Figure 1, the utility model provides a zero-discharge system for high-salt and high-turbidity industrial wastewater, which includes a water inlet tank 100, a flocculation and sedimentation system, a sand filter device 300, and an electric adsorption system connected sequentially along the direction of wastewater flow. It includes backwashing system, concentrated water tank 600, thermal evaporation crystallization system 700 and PLC control system 800.

进水水箱100和絮凝沉淀系统之间设置有进水泵110,进水泵110将进水水箱100中的废水泵入絮凝沉淀系统。A water inlet pump 110 is arranged between the water inlet tank 100 and the flocculation sedimentation system, and the water inlet pump 110 pumps the waste water in the water inlet tank 100 into the flocculation sedimentation system.

絮凝沉淀系统包括沉淀池200、污泥泵210和污泥干化池220。The flocculation and sedimentation system includes a sedimentation tank 200 , a sludge pump 210 and a sludge drying tank 220 .

其中,沉淀池200分别与进水水箱100和砂滤装置300连通。废水由进水水箱100流入沉淀池200,进行沉降处理。沉淀池200内投放絮凝剂,去除废水中的悬浮物和油脂类物质。沉淀池200和砂滤装置300之间设置有沉淀水泵230,将沉淀池200处理后的废水泵入砂滤装置300。Wherein, the sedimentation tank 200 communicates with the water inlet tank 100 and the sand filter device 300 respectively. The waste water flows into the sedimentation tank 200 from the water inlet tank 100 for sedimentation treatment. A flocculant is placed in the sedimentation tank 200 to remove suspended solids and grease substances in the wastewater. A sedimentation water pump 230 is provided between the sedimentation tank 200 and the sand filter device 300 to pump the wastewater treated in the sedimentation tank 200 into the sand filter device 300 .

沉淀池200与污泥干化池220连通,污泥泵210设置于沉淀池200和污泥干化池220之间,将沉淀池200沉淀下来的污泥泵入污泥干化池220。污泥干化池220对污泥进行干化处理,干化后的污泥可委外处置或进行其他后处理操作。The sedimentation tank 200 communicates with the sludge drying tank 220 , and the sludge pump 210 is arranged between the sedimentation tank 200 and the sludge drying tank 220 , and pumps the sludge settled in the sedimentation tank 200 into the sludge drying tank 220 . The sludge drying tank 220 performs drying treatment on the sludge, and the dried sludge can be outsourced for disposal or other post-processing operations.

砂滤装置300对废水进行砂滤处理,进一步去除废水中的悬浮物。砂滤装置300内下部滤料为直径1-2mm的石榴石滤料,上部滤料为直径0.5-1.2mm的石英砂滤料。The sand filter device 300 performs sand filter treatment on the wastewater to further remove suspended solids in the wastewater. The lower filter material in the sand filter device 300 is a garnet filter material with a diameter of 1-2 mm, and the upper filter material is a quartz sand filter material with a diameter of 0.5-1.2 mm.

本系统还包括砂滤电导率仪310,砂滤电导率仪310与砂滤装置300连通,检测砂滤装置300处理后废水的电导率。The system also includes a sand filter conductivity meter 310 . The sand filter conductivity meter 310 is connected to the sand filter device 300 to detect the conductivity of the wastewater treated by the sand filter device 300 .

电吸附系统包括三组电容去离子装置、中间水箱、进水电磁阀门和电导率仪,分别为沿废水流入方向依次连通的一级电容去离子装置410、一级中间水箱411、二级电容去离子装置420、二级中间水箱421、三级电容去离子装置430和三级中间水箱431;三个进水电磁阀门分别为一级进水电磁阀门412、二级进水电磁阀门422和三级进水电磁阀门432,分别设置在一级电容去离子装置410、二级电容去离子装置420和三级电容去离子装置430的进水管路上,控制其进水量;三个电导率仪分别为一级电导率仪413、二级电导率仪423和三级电导率仪433,分别与一级中间水箱411、二级中间水箱421和三级中间水箱431连通,测量其内废水的电导率。The electro-adsorption system includes three sets of capacitive deionization devices, intermediate water tanks, water inlet electromagnetic valves and conductivity meters, which are respectively the primary capacitive deionization device 410, the primary intermediate water tank 411, and the secondary capacitive deionization device connected sequentially along the direction of wastewater inflow. Ionization device 420, secondary intermediate water tank 421, tertiary capacitive deionization device 430 and tertiary intermediate water tank 431; the three water inlet solenoid valves are respectively primary water inlet electromagnetic valve 412, secondary water inlet electromagnetic valve 422 and third stage The water inlet electromagnetic valve 432 is respectively arranged on the water inlet pipelines of the first-stage capacitive deionization device 410, the second-stage capacitive deionization device 420 and the third-stage capacitive deionization device 430 to control the water inflow; the three conductivity meters are respectively a The first-level conductivity meter 413, the second-level conductivity meter 423 and the third-level conductivity meter 433 are respectively connected with the first-level intermediate water tank 411, the second-level intermediate water tank 421 and the third-level intermediate water tank 431 to measure the conductivity of the waste water therein.

三级中间水箱431与反冲洗系统连通,为其提供反冲洗清水。The tertiary intermediate water tank 431 communicates with the backwashing system to provide clean water for backwashing.

电吸附系统还包括出水电磁阀门434,设置在三级中间水箱431的出水管路上,控制反冲洗系统的反冲洗清水量。The electro-adsorption system also includes a water outlet electromagnetic valve 434, which is arranged on the water outlet pipeline of the three-stage intermediate water tank 431, and controls the amount of clean water for backwashing of the backwashing system.

反冲洗系统包括反冲洗水箱500和四个反冲洗水泵510。其中,反冲洗水箱500与砂滤装置300、一级电容去离子装置410、二级电容去离子装置420和三级电容去离子装置430分别连通。四个反冲洗水泵510分别设置在反冲洗水箱500与砂滤装置300、一级电容去离子装置410、二级电容去离子装置420和三级电容去离子装置430连通的管路上,反冲洗水箱500通过反冲洗水泵510向砂滤装置300、一级电容去离子装置410、二级电容去离子装置420和三级电容去离子装置430泵入反冲洗清水,为其提供反冲洗处理。The backwashing system includes a backwashing water tank 500 and four backwashing water pumps 510 . Wherein, the backwash water tank 500 communicates with the sand filter device 300 , the first-stage capacitive deionization device 410 , the second-stage capacitive deionization device 420 and the third-stage capacitive deionization device 430 . Four backwash water pumps 510 are respectively arranged on the pipelines in which the backwash water tank 500 communicates with the sand filter device 300, the first-stage capacitive deionization device 410, the second-stage capacitive deionization device 420, and the third-stage capacitive deionization device 430. 500 pumps backwash clean water into the sand filter device 300, the primary capacitive deionization device 410, the secondary capacitive deionization device 420 and the tertiary capacitive deionization device 430 through the backwash water pump 510 to provide them with backwashing treatment.

浓水水箱600与砂滤装置300、一级电容去离子装置410、二级电容去离子装置420和三级电容去离子装置430分别连通,接收储存其进行反冲洗处理后的浓水。Concentrated water tank 600 communicates with sand filter device 300 , first-stage capacitive deionization device 410 , second-stage capacitive deionization device 420 and third-stage capacitive deionization device 430 to receive and store concentrated water after backwashing.

浓水水箱600还与热蒸发结晶系统700连通,浓水水箱600与热蒸发结晶系统700之间设置有浓水水箱泵610,浓水水箱600通过浓水水箱泵610向热蒸发结晶系统700输送待处理浓水。The concentrated water tank 600 is also connected with the thermal evaporation crystallization system 700, and a concentrated water tank pump 610 is arranged between the concentrated water tank 600 and the thermal evaporation crystallization system 700, and the concentrated water tank 600 is transported to the thermal evaporation crystallization system 700 through the concentrated water tank pump 610 Concentrated water to be treated.

热蒸发结晶系统700对反冲洗处理后的浓水进行热处理,结晶产生的废盐可委外处置或进行其他后处理操作。热蒸发结晶系统700冷凝产生的冷凝水输送至反冲洗水箱500回用。The thermal evaporation and crystallization system 700 heat-treats the concentrated water after backwashing, and the waste salt produced by crystallization can be outsourced for disposal or other post-processing operations. The condensed water generated by condensation in the thermal evaporation crystallization system 700 is sent to the backwash water tank 500 for reuse.

PLC控制系统800监测砂滤电导率仪310、一级电导率仪413、二级电导率仪423和三级电导率仪433的数据,并控制一级进水电磁阀门412、二级进水电磁阀门422、三级进水电磁阀门432和出水电磁阀门434的开关。The PLC control system 800 monitors the data of the sand filter conductivity meter 310, the first-level conductivity meter 413, the second-level conductivity meter 423 and the third-level conductivity meter 433, and controls the first-level water inlet electromagnetic valve 412 and the second-level water inlet electromagnetic valve. Switches of the valve 422, the three-stage water inlet solenoid valve 432 and the water outlet solenoid valve 434.

本实施例中,电吸附系统的级数可根据实际需求而改变设置,即电容去离子装置、中间水箱、进水电磁阀门和电导率仪的数量可以根据废水的含盐量和处理负荷而设制,仅需满足:中间水箱、进水电磁阀门和电导率仪均与电容去离子装置一一对应,进水电磁阀门设置在电容去离子装置的进水管路上,中间水箱与电容去离子装置出口连通,电导率仪与中间水箱连通,测量电容去离子装置处理后废水的电导率。In this embodiment, the number of stages of the electro-adsorption system can be changed according to actual needs, that is, the number of capacitive deionization devices, intermediate water tanks, water inlet electromagnetic valves and conductivity meters can be set according to the salt content of wastewater and the treatment load. It only needs to be satisfied: the intermediate water tank, water inlet electromagnetic valve and conductivity meter are all in one-to-one correspondence with the capacitive deionization device, the water inlet electromagnetic valve is set on the water inlet pipeline of the capacitor deionization device, and the intermediate water tank and the outlet of the capacitor deionization device Connected, the conductivity meter is connected with the intermediate water tank to measure the conductivity of the wastewater treated by the capacitive deionization device.

本系统使用时,进水水箱100中的废水通过进水泵110流入絮凝沉淀系统中的沉淀池200,进行絮凝沉淀处理,去除废水中的悬浮物和油脂类物质。When the system is in use, the waste water in the water inlet tank 100 flows into the sedimentation tank 200 in the flocculation and sedimentation system through the water inlet pump 110, and undergoes flocculation and sedimentation treatment to remove suspended solids and grease substances in the waste water.

絮凝沉淀处理后的废水通过沉淀水泵230流入砂滤装置300,进行砂滤处理,进一步去除悬浮物。The wastewater after flocculation and sedimentation treatment flows into the sand filter device 300 through the sedimentation water pump 230, and is subjected to sand filtration treatment to further remove suspended matter.

砂滤处理后的废水进入电吸附系统,依次流入一级电容去离子装置410、一级中间水箱411、二级电容去离子装置420、二级中间水箱421、三级电容去离子装置430和三级中间水箱431,进行电吸附处理。The waste water treated by sand filtration enters the electro-adsorption system, and then flows into the first-stage capacitive deionization device 410, the first-stage intermediate water tank 411, the second-stage capacitive deionization device 420, the second-stage intermediate water tank 421, the third-stage capacitive deionization device 430 and the third-stage capacitive deionization device. An intermediate water tank 431 is used for electro-adsorption treatment.

电吸附处理后的清水全部流入反冲洗系统中的反冲洗水箱500,为反冲洗系统提供反冲洗清水。All the clean water after electro-adsorption treatment flows into the backwash water tank 500 in the backwash system to provide backwash clean water for the backwash system.

反冲洗系统对砂滤装置300进行反冲洗处理的时间间隔为40min,冲洗时间为40s。The time interval for the backwashing system to backwash the sand filter device 300 is 40 minutes, and the flushing time is 40s.

PLC控制系统监测砂滤电导率仪310、一级电导率仪413、二级电导率仪423和三级电导率仪433的数据。The PLC control system monitors the data of the sand filter conductivity meter 310 , the primary conductivity meter 413 , the secondary conductivity meter 423 and the tertiary conductivity meter 433 .

当一级电导率仪413测得的电导率值大于砂滤电导率仪310测得的电导率值的50%时,PLC控制系统关闭一级进水电磁阀门412和二级进水电磁阀门422,对一级电容去离子装置410进行脱附清洗处理。处理后打开一级进水电磁阀门412,若一级电导率仪413测得的电导率值小于砂滤电导率仪310测得的电导率值的50%,再打开二级进水电磁阀门422;若一级电导率仪413测得的电导率值仍大于砂滤电导率仪310测得的电导率值的50%,则关闭一级进水电磁阀门412,对一级电容去离子装置410继续进行脱附清洗处理,至其处理后废水的电导率值达标。When the conductivity value measured by the primary conductivity meter 413 is greater than 50% of the conductivity value measured by the sand filter conductivity meter 310, the PLC control system closes the primary water inlet electromagnetic valve 412 and the secondary water inlet electromagnetic valve 422 , performing desorption and cleaning treatment on the primary capacitive deionization device 410 . After processing, open the primary water inlet solenoid valve 412, if the conductivity value measured by the primary conductivity meter 413 is less than 50% of the conductivity value measured by the sand filter conductivity meter 310, then open the secondary water inlet solenoid valve 422 If the conductivity value recorded by the first-level conductivity meter 413 is still greater than 50% of the conductivity value measured by the sand filter conductivity meter 310, then close the first-level water inlet electromagnetic valve 412, and the first-level capacitance deionization device 410 Continue the desorption cleaning treatment until the conductivity value of the treated wastewater reaches the standard.

当二级电导率仪423测得的电导率值大于砂滤电导率仪310测得的电导率值的20%时,PLC控制系统关闭二级进水电磁阀门422和三级进水电磁阀门432,对二级电容去离子装置420进行脱附清洗处理。处理后打开二级进水电磁阀门422,若二级电导率仪423测得的电导率值小于砂滤电导率仪310测得的电导率值的20%,再打开三级进水电磁阀门433;若二级电导率仪423测得的电导率值仍大于砂滤电导率仪310测得的电导率值的20%,则关闭二级进水电磁阀门422,对二级电容去离子装置420继续进行脱附清洗处理,至其处理后废水的电导率值达标。When the conductivity value measured by the secondary conductivity meter 423 is greater than 20% of the conductivity value measured by the sand filter conductivity meter 310, the PLC control system closes the secondary water inlet solenoid valve 422 and the third stage water inlet solenoid valve 432 , performing desorption and cleaning treatment on the secondary capacitive deionization device 420 . After processing, open the secondary water inlet solenoid valve 422, if the conductivity value measured by the secondary conductivity meter 423 is less than 20% of the conductivity value measured by the sand filter conductivity meter 310, then open the third stage water inlet solenoid valve 433 If the conductivity value recorded by the secondary conductivity meter 423 is still greater than 20% of the conductivity value recorded by the sand filter conductivity meter 310, then close the secondary water inlet electromagnetic valve 422, and the secondary capacitance deionization device 420 Continue the desorption cleaning treatment until the conductivity value of the treated wastewater reaches the standard.

当三级电导率仪433测得的电导率值大于砂滤电导率仪310测得的电导率值的10%时,PLC控制系统关闭三级进水电磁阀门432和出水电磁阀门434,对三级电容去离子装置430进行脱附清洗处理。处理后打开三级进水电磁阀门432,若三级电导率仪433测得的电导率值小于砂滤电导率仪测得的电导率值的10%,再打开出水电磁阀门434;若三级电导率仪433测得的电导率值仍大于砂滤电导率仪310测得的电导率值的10%,则关闭三级进水电磁阀门432,对三级电容去离子装置430继续进行脱附清洗处理,至其处理后废水的电导率值达标。When the conductivity value measured by the three-stage conductivity meter 433 is greater than 10% of the conductivity value measured by the sand filter conductivity meter 310, the PLC control system closes the three-stage water inlet solenoid valve 432 and the water outlet solenoid valve 434. The first-stage capacitive deionization device 430 performs desorption and cleaning treatment. Open the third-stage water inlet electromagnetic valve 432 after processing, if the conductivity value measured by the third-stage conductivity meter 433 is less than 10% of the conductivity value measured by the sand filter conductivity meter, then open the water outlet electromagnetic valve 434; If the conductivity value measured by the conductivity meter 433 is still greater than 10% of the conductivity value measured by the sand filter conductivity meter 310, then the third-stage water inlet electromagnetic valve 432 is closed, and the third-stage capacitive deionization device 430 is continuously desorbed Cleaning treatment until the conductivity value of the treated wastewater reaches the standard.

其中,一级电容去离子装置410、二级电容去离子装置420、三级电容去离子装置430的脱附清洗处理为反接其外加电源20min,反冲洗系统再对其进行反冲洗10min。Among them, the desorption and cleaning process of the first-stage capacitive deionization device 410, the second-stage capacitive deionization device 420, and the third-stage capacitive deionization device 430 is reversely connected to the external power supply for 20 minutes, and then backwashed by the backwashing system for 10 minutes.

砂滤装置300、一级电容去离子装置410、二级电容去离子装置420和三级电容去离子装置430进行反冲洗处理后的浓水流入浓水水箱600,再由浓水水箱泵610输送至热蒸发结晶系统700,热蒸发结晶系统700对反冲洗浓水进行蒸发结晶热处理。Sand filter device 300, first-stage capacitive deionization device 410, second-stage capacitive deionization device 420, and third-stage capacitive deionization device 430 carry out backwashing. The concentrated water flows into the concentrated water tank 600 and is then transported by the concentrated water tank pump 610. To the thermal evaporation crystallization system 700, the thermal evaporation crystallization system 700 performs evaporation crystallization heat treatment on the backwash concentrated water.

本实施例中,电吸附处理后的清水也可以部分流入反冲洗系统中,剩余部分排至其他所需系统工艺。In this embodiment, part of the clean water after electro-adsorption treatment may also flow into the backwashing system, and the remaining part may be discharged to other required system processes.

Claims (10)

1.一种高盐高浊工业废水零排放系统,其特征在于:1. A zero-discharge system for high-salt and high-turbidity industrial wastewater, characterized in that: 包括沿废水流经方向依次连通的进水水箱、絮凝沉淀系统、砂滤装置和电吸附系统;Including water inlet tanks, flocculation and sedimentation systems, sand filter devices and electro-adsorption systems connected sequentially along the direction of waste water flow; 其中,所述电吸附系统包括若干个连通的电容去离子装置;Wherein, the electrosorption system includes several connected capacitive deionization devices; 还包括反冲洗系统和热蒸发结晶系统;It also includes backwashing system and thermal evaporation crystallization system; 所述反冲洗系统与所述砂滤装置和电容去离子装置连通,对砂滤装置和电容去离子装置进行反冲洗处理;The backwashing system is communicated with the sand filter device and the capacitive deionization device, and backwashes the sand filter device and the capacitive deionization device; 所述热蒸发结晶系统与所述砂滤装置和电容去离子装置连通,对砂滤装置和电容去离子装置进行反冲洗后的浓水进行热蒸发处理。The thermal evaporation crystallization system communicates with the sand filter device and the capacitive deionization device, and performs thermal evaporation treatment on the concentrated water after the sand filter device and the capacitive deionization device are backwashed. 2.根据权利要求1所述的高盐高浊工业废水零排放系统,其特征在于:2. The zero-discharge system for high-salt and high-turbidity industrial wastewater according to claim 1, characterized in that: 还包括PLC控制系统和砂滤电导率仪;It also includes PLC control system and sand filter conductivity meter; 所述砂滤电导率仪与所述砂滤装置连通,检测砂滤装置处理后废水的电导率;The sand filter conductivity meter is connected with the sand filter device to detect the conductivity of the wastewater treated by the sand filter device; 所述电吸附系统还包括若干个电导率仪和进水电磁阀门;The electro-adsorption system also includes several conductivity meters and water inlet electromagnetic valves; 所述电导率仪与所述电容去离子装置一一对应、并连通,电导率仪检测与其相通的电容去离子装置的处理后废水的电导率;The conductivity meter is in one-to-one correspondence with the capacitive deionization device and connected, and the conductivity meter detects the conductivity of the treated wastewater of the capacitive deionization device connected thereto; 所述进水电磁阀门与所述电容去离子装置一一对应、并设置在其进水管路上,控制电容去离子装置的进水量;The water inlet electromagnetic valve corresponds to the capacitive deionization device one by one, and is arranged on its water inlet pipeline to control the water intake of the capacitive deionization device; 所述PLC控制系统监测所述砂滤电导率仪和电导率仪的数据,控制所述进水电磁阀门的开关。The PLC control system monitors the sand filter conductivity meter and the data of the conductivity meter, and controls the switch of the water inlet electromagnetic valve. 3.根据权利要求2所述的高盐高浊工业废水零排放系统,其特征在于:3. The zero-discharge system for high-salt and high-turbidity industrial wastewater according to claim 2, characterized in that: 其中,所述电吸附系统还包括若干个中间水箱;Wherein, the electro-adsorption system also includes several intermediate water tanks; 所述中间水箱与所述电容去离子装置一一对应、并与其出口连通,电容去离子装置处理后的废水流入中间水箱;The intermediate water tank is in one-to-one correspondence with the capacitive deionization device and communicated with its outlet, and the wastewater treated by the capacitive deionization device flows into the intermediate water tank; 所述电导率仪与所述中间水箱连通,测量其内废水的电导率。The conductivity meter communicates with the intermediate water tank to measure the conductivity of the waste water therein. 4.根据权利要求3所述的高盐高浊工业废水零排放系统,其特征在于:4. The zero discharge system for high-salt and high-turbidity industrial wastewater according to claim 3, characterized in that: 其中,所述电容去离子装置和中间水箱的数量均为三个,分别为沿废水流入方向依次连通的一级电容去离子装置、一级中间水箱、二级电容去离子装置、二级中间水箱、三级电容去离子装置和三级中间水箱;Wherein, the number of the capacitive deionization device and the intermediate water tank is three, which are the first-stage capacitive deionization device, the first-stage intermediate water tank, the second-stage capacitive deionization device, and the second-stage intermediate water tank, which are sequentially connected along the direction of wastewater inflow. , Three-stage capacitive deionization device and three-stage intermediate water tank; 所述进水电磁阀门的数量为三个,分别为一级进水电磁阀门、二级进水电磁阀门和三级进水电磁阀门,分别设置在所述一级电容去离子装置、二级电容去离子装置和三级电容去离子装置的进水管路上,控制其进水量;The number of the water inlet electromagnetic valves is three, which are the first-level water inlet electromagnetic valve, the second-level water inlet electromagnetic valve and the third-level water inlet electromagnetic valve, which are respectively arranged in the first-level capacitor deionization device and the second-level capacitor On the water inlet pipeline of the deionization device and the three-stage capacitive deionization device, the water intake is controlled; 所述电导率仪的数量为三个,分别为一级电导率仪、二级电导率仪和三级电导率仪,分别与所述一级中间水箱、二级中间水箱和三级中间水箱连通,测量其内废水的电导率;The number of the conductivity meter is three, which are respectively the first-level conductivity meter, the second-level conductivity meter and the third-level conductivity meter, which are respectively connected with the first-level intermediate water tank, the second-level intermediate water tank and the third-level intermediate water tank , to measure the conductivity of the wastewater in it; 所述三级中间水箱与所述反冲洗系统连通,为其提供反冲洗清水;The three-stage intermediate water tank communicates with the backwashing system to provide backwashing water; 所述电吸附系统还包括出水电磁阀门,设置在所述三级中间水箱的出水管路上,控制所述反冲洗系统的反冲洗清水量;The electro-adsorption system also includes a water outlet electromagnetic valve, which is arranged on the water outlet pipeline of the three-stage intermediate water tank to control the amount of backwash water in the backwash system; 所述PLC控制系统监测所述砂滤电导率仪、一级电导率仪、二级电导率仪和三级电导率仪的数据,并控制一级进水电磁阀门、二级进水电磁阀门、三级进水电磁阀门和出水电磁阀门的开关。The PLC control system monitors the data of the sand filter conductivity meter, the first-level conductivity meter, the second-level conductivity meter and the third-level conductivity meter, and controls the first-level water inlet electromagnetic valve, the second-level water inlet electromagnetic valve, Three-stage water inlet solenoid valve and water outlet solenoid valve switch. 5.根据权利要求1所述的高盐高浊工业废水零排放系统,其特征在于:5. The zero-discharge system for high-salt and high-turbidity industrial wastewater according to claim 1, characterized in that: 其中,所述反冲洗系统包括反冲洗水箱和若干个反冲洗水泵,反冲洗水箱与所述砂滤装置和电容去离子装置分别连通,并通过相应的反冲洗水泵向其泵入反冲洗清水。Wherein, the backwashing system includes a backwashing water tank and several backwashing water pumps, the backwashing water tank is respectively communicated with the sand filter device and the capacitive deionization device, and backwashing clean water is pumped into it through corresponding backwashing water pumps. 6.根据权利要求1所述的高盐高浊工业废水零排放系统,其特征在于:6. The zero-discharge system for high-salt and high-turbidity industrial wastewater according to claim 1, characterized in that: 其中,所述热蒸发结晶系统冷凝产生的冷凝水输送至所述反冲洗系统回用。Wherein, the condensed water produced by condensation in the thermal evaporation crystallization system is transported to the backwashing system for reuse. 7.根据权利要求1所述的高盐高浊工业废水零排放系统,其特征在于:7. The zero-discharge system for high-salt and high-turbidity industrial wastewater according to claim 1, characterized in that: 还包括浓水水箱和浓水水箱泵;Concentrate tanks and concentrate tank pumps are also included; 所述浓水水箱与所述砂滤装置和电容去离子装置连通,接收储存砂滤装置和电容去离子装置进行反冲洗处理后的浓水;The concentrated water tank is connected with the sand filter device and the capacitive deionization device, and receives and stores the concentrated water after backwashing by the sand filter device and the capacitive deionization device; 所述浓水水箱还与所述热蒸发结晶系统连通,通过所述浓水水箱泵向其输送待处理浓水。The concentrated water tank is also connected with the thermal evaporation crystallization system, and the concentrated water to be treated is delivered to it by the pump of the concentrated water tank. 8.根据权利要求1所述的高盐高浊工业废水零排放系统,其特征在于:8. The zero-discharge system for high-salt and high-turbidity industrial wastewater according to claim 1, characterized in that: 其中,所述絮凝沉淀系统包括沉淀池、污泥泵和污泥干化池;Wherein, the flocculation sedimentation system includes a sedimentation tank, a sludge pump and a sludge drying tank; 所述沉淀池分别与所述进水水箱和砂滤装置连通,沉淀池内投放絮凝剂,去除废水中的悬浮物和油脂类物质,絮凝沉淀处理后的废水输送至砂滤装置;The sedimentation tank is respectively connected with the water inlet tank and the sand filter device, and a flocculant is placed in the sedimentation tank to remove suspended solids and grease substances in the wastewater, and the wastewater after the flocculation and sedimentation treatment is transported to the sand filter device; 所述沉淀池与所述污泥干化池连通,所述污泥泵设置于沉淀池和污泥干化池之间,将沉淀池沉淀下来的污泥泵入污泥干化池。The sedimentation tank communicates with the sludge drying tank, and the sludge pump is arranged between the sedimentation tank and the sludge drying tank, and pumps the sludge settled in the sedimentation tank into the sludge drying tank. 9.根据权利要求1所述的高盐高浊工业废水零排放系统,其特征在于:9. The zero-discharge system for high-salt and high-turbidity industrial wastewater according to claim 1, characterized in that: 还包括进水泵,设置在所述进水水箱和所述絮凝沉淀系统之间,将进水水箱中的废水泵入絮凝沉淀系统。It also includes a water inlet pump, which is arranged between the water inlet water tank and the flocculation sedimentation system, and pumps the waste water in the water inlet water tank into the flocculation sedimentation system. 10.根据权利要求1所述的高盐高浊工业废水零排放系统,其特征在于:10. The zero discharge system for high-salt and high-turbidity industrial wastewater according to claim 1, characterized in that: 还包括沉淀水泵,设置在所述絮凝沉淀系统和砂滤装置之间,将絮凝沉淀系统处理后的废水泵入砂滤装置。It also includes a sedimentation water pump, which is arranged between the flocculation sedimentation system and the sand filter device, and pumps the wastewater treated by the flocculation sedimentation system into the sand filter device.
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Publication number Priority date Publication date Assignee Title
CN109320001B (en) * 2018-12-10 2023-08-22 环境保护部南京环境科学研究所 A zero-discharge system for high-salt and high-turbidity industrial wastewater and its technology

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109320001B (en) * 2018-12-10 2023-08-22 环境保护部南京环境科学研究所 A zero-discharge system for high-salt and high-turbidity industrial wastewater and its technology

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