CN209264720U - Apparatus for In Situ Nitrogen Mineralization Rate Determination in Forest Ecosystem Soil - Google Patents
Apparatus for In Situ Nitrogen Mineralization Rate Determination in Forest Ecosystem Soil Download PDFInfo
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 title claims abstract description 66
- 239000002689 soil Substances 0.000 title claims abstract description 50
- 229910052757 nitrogen Inorganic materials 0.000 title claims abstract description 33
- 238000011065 in-situ storage Methods 0.000 title claims abstract description 16
- 230000033558 biomineral tissue development Effects 0.000 title claims abstract description 13
- 239000006004 Quartz sand Substances 0.000 claims abstract description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 14
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003456 ion exchange resin Substances 0.000 claims abstract description 13
- 229920003303 ion-exchange polymer Polymers 0.000 claims abstract description 13
- 230000000903 blocking effect Effects 0.000 claims description 28
- 239000004677 Nylon Substances 0.000 claims description 9
- 229920001778 nylon Polymers 0.000 claims description 9
- 229910000831 Steel Inorganic materials 0.000 claims description 7
- 238000005259 measurement Methods 0.000 claims description 7
- 239000010959 steel Substances 0.000 claims description 7
- 238000007789 sealing Methods 0.000 claims description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 abstract description 22
- 239000011707 mineral Substances 0.000 abstract description 22
- 239000011347 resin Substances 0.000 abstract description 9
- 229920005989 resin Polymers 0.000 abstract description 9
- 238000001556 precipitation Methods 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 abstract 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 abstract 1
- 238000002386 leaching Methods 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- MMDJDBSEMBIJBB-UHFFFAOYSA-N [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] Chemical compound [O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[NH6+3] MMDJDBSEMBIJBB-UHFFFAOYSA-N 0.000 description 4
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 4
- -1 ammonium ions Chemical class 0.000 description 4
- 229910002651 NO3 Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005070 sampling Methods 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- 208000036828 Device occlusion Diseases 0.000 description 1
- 239000002390 adhesive tape Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000003729 cation exchange resin Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000012943 hotmelt Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
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Abstract
Description
技术领域technical field
本实用新型属于土壤检测领域,尤其涉及一种用于森林生态系统土壤原位氮矿化速率测定的装置。The utility model belongs to the field of soil detection, in particular to a device for measuring the in-situ nitrogen mineralization rate of forest ecosystem soil.
背景技术Background technique
目前,土壤氮素流失的计算主要依赖于打取特定层次的土壤,利用KCL溶液浸提各层土壤的硝态氮和铵态氮,通过对各层土壤中硝态氮和铵态氮的含量进行比较,对氮素流失情况进行评价。这种方法不仅费时费力,而且如果样品测定不及时,硝态氮和铵态氮会发生相互转化,易产生误差;同时样品难以混匀,取样测定时与田间实际情况有一定偏差。后来研究者通过田旁修渗漏池,渗漏计以及土层中放置托盘和接液瓶,通过抽液管连接地面的采样瓶、接液瓶和真空泵等来获得土壤渗漏液,室内通过装填土柱,应用基础数据构建相应模型,对农田氮素流失进行模拟。这些试验设计存在共性问题是不仅投资较大和试验成本高;而且土柱模拟和修渗漏池对原状土结构有一定破坏,渗漏计扰乱试验田土层,试验过程复杂,渗漏液收集过程中容易会出现导液管堵塞,渗漏液体积难以计算,真空泵的压力不易控制等问题,影响试验进程;以上试验测定均是模拟结果,距离真值还有距离,很大程度上限制了氮素流失研究的深入发展。At present, the calculation of soil nitrogen loss mainly depends on extracting specific layers of soil, using KCL solution to extract the nitrate nitrogen and ammonium nitrogen in each layer of soil, and by analyzing the content of nitrate nitrogen and ammonium nitrogen in each layer of soil To compare and evaluate the nitrogen loss. This method is not only time-consuming and labor-intensive, but if the sample is not measured in time, nitrate nitrogen and ammonium nitrogen will be transformed into each other, which is prone to errors; at the same time, the sample is difficult to mix, and there is a certain deviation between the sampling and measurement and the actual situation in the field. Later, the researchers repaired the seepage pond by the field, placed the seepage meter and placed trays and liquid receiving bottles in the soil layer, and connected the sampling bottles, liquid receiving bottles and vacuum pumps on the ground through the pumping pipe to obtain soil seepage. Fill the soil column, apply the basic data to construct the corresponding model, and simulate the loss of nitrogen in the farmland. The common problems in these test designs are not only large investment and high test cost; but also the soil column simulation and repair of seepage tanks have certain damage to the original soil structure. It is easy to cause catheter blockage, difficult to calculate the volume of leakage, and difficult to control the pressure of the vacuum pump, etc., which will affect the test process; the above test measurements are all simulation results, and there is still a distance from the true value, which greatly limits the nitrogen In-depth development of churn research.
实用新型内容Utility model content
本实用新型的目的在于提供一种测定结果准确的用于森林生态系统土壤原位氮矿化速率测定的装置,其技术方案如下:The purpose of this utility model is to provide a kind of device that is used for the in-situ nitrogen mineralization rate measurement of forest ecological system soil with accurate measurement result, and its technical scheme is as follows:
用于森林生态系统土壤原位氮矿化速率测定的装置,包括可自上而下依次对接的上堵盖、主管体和下堵盖,主管体的下端设有可穿过地表的坡口结构,上堵盖和下堵盖内填充有自下而上层叠分布的石英砂层、滤网和离子交换树脂层。上端的离子交换树脂可阻止降水中铵根离子和硝酸根离子,或土壤水流动过程中的矿质氮的输入,避免其他外部矿质氮进入培养的土柱中,下端的离子交换树脂可以吸附培养土柱中淋溶下来的矿质氮;上端的石英砂可阻止培养土柱中的矿质氮扩散至土柱上端的树脂,下端的石英砂可阻止土柱外的矿质氮扩散至土柱下端的树脂中,从而可最大限度地使土柱在自然状态下原位培养,可较为精确的测定和计算培养的土柱中实际的矿质氮量和矿质速率。A device for measuring the in-situ nitrogen mineralization rate of soil in forest ecosystems, including an upper block cover, a main body and a lower block cover that can be connected sequentially from top to bottom, and the lower end of the main body is provided with a groove structure that can pass through the ground surface , the upper blocking cover and the lower blocking cover are filled with quartz sand layers, filter screens and ion exchange resin layers distributed from bottom to top. The ion exchange resin at the upper end can prevent the input of ammonium ions and nitrate ions in precipitation, or mineral nitrogen during the flow of soil water, and prevent other external mineral nitrogen from entering the cultivated soil column, and the ion exchange resin at the lower end can absorb the cultivated soil The mineral nitrogen leached from the column; the quartz sand at the upper end can prevent the mineral nitrogen in the cultivation soil column from diffusing to the resin at the upper end of the soil column, and the quartz sand at the lower end can prevent the mineral nitrogen outside the soil column from diffusing into the resin at the lower end of the soil column , so that the soil column can be cultivated in situ in the natural state to the greatest extent, and the actual mineral nitrogen content and mineral rate in the cultivated soil column can be measured and calculated more accurately.
进一步地,上堵盖、主管体和下堵盖均为PVC管,上堵盖的上端口和下堵盖的下端口各自捆扎蒙设有尼龙网或钢丝网材质的封口件。Further, the upper blocking cover, the main body and the lower blocking cover are all PVC pipes, and the upper port of the upper blocking cover and the lower port of the lower blocking cover are respectively bundled with a sealing piece made of nylon mesh or steel wire mesh.
进一步地,主管体的两端分别设置有外螺纹,上堵盖的下端口和下堵盖上端口分别设置有外螺纹,上堵盖和下堵盖各自通过转接套连接主管体,转接套的两端分别设置有内螺纹,所述滤网固设在转接套的中部且隔设在两端内螺纹之间,转接套一端的内螺纹连接在主管体端部的外螺纹上,另一端的内螺纹连接上堵盖或下堵盖。Further, the two ends of the main pipe body are respectively provided with external threads, the lower port of the upper block cap and the upper port of the lower block cap are respectively provided with external threads, and the upper block cap and the lower block cap are respectively connected to the main pipe body through an adapter sleeve. Both ends of the sleeve are respectively provided with internal threads, the filter screen is fixed in the middle of the adapter sleeve and separated between the internal threads at both ends, and the internal thread at one end of the adapter sleeve is connected to the external thread at the end of the main body , the inner thread at the other end is connected to the upper or lower blocking cap.
进一步地,滤网为100-150目的钢丝网或尼龙网。Further, the filter screen is 100-150 mesh steel wire mesh or nylon mesh.
附图说明Description of drawings
为了更清楚地说明本实用新型实施例的技术方案,下面将对实施例中所需要使用的附图作简单地介绍,显而易见地,下面描述中的附图仅仅是本实用新型的实施例,对于本领域普通技术人员来讲,在不付出创造性劳动性的前提下,还可以根据这些附图获得其它的附图;In order to more clearly illustrate the technical solutions of the embodiments of the utility model, the accompanying drawings that need to be used in the embodiments will be briefly introduced below. Obviously, the accompanying drawings in the following description are only embodiments of the utility model. Those of ordinary skill in the art can also obtain other drawings based on these drawings without paying creative labor;
图1是实施例1中装置的结构示意图;Fig. 1 is the structural representation of device in embodiment 1;
图2是实施例2中装置的结构示意图。Figure 2 is a schematic structural view of the device in Example 2.
具体实施方式Detailed ways
为了使本实用新型的技术目的、技术方案和有益效果更加清楚,下面结合附图和具体实施例对本实用新型的技术方案作出进一步的说明。In order to make the technical purpose, technical solution and beneficial effect of the utility model clearer, the technical solution of the utility model is further described below in conjunction with the accompanying drawings and specific embodiments.
实施例1,参见图1,示出了本实用新型中用于森林生态系统土壤原位氮矿化速率测定的装置结构示意图,其主要采用PVC管材加工而成。该装置包括可自上而下依次对接的上堵盖1、主管体2和下堵盖3,主管体2采用直套筒且下端设有可穿过地表的坡口结构,上堵盖1和下堵盖3内填充有自下而上层叠分布的石英砂层4、滤网5和离子交换树脂层6。上堵盖的上端口和下堵盖的下端口各自捆扎蒙设有尼龙网材质的封口件7。Embodiment 1, referring to FIG. 1 , shows a schematic diagram of the structure of the device for measuring the in-situ nitrogen mineralization rate of forest ecosystem soil in the utility model, which is mainly processed by PVC pipe. The device includes an upper block cover 1, a main pipe body 2 and a lower block cover 3 which can be docked sequentially from top to bottom. The lower plug 3 is filled with quartz sand layer 4 , filter screen 5 and ion exchange resin layer 6 stacked and distributed from bottom to top. The upper port of the upper blocking cover and the lower port of the lower blocking cover are respectively bundled with a sealing member 7 of nylon mesh material.
该装置包含一个一端经过打磨的PVC管(打磨长度0.5-1cm),即主管体2,以便于将其顺利打入森林土壤不同土层中收集原位土壤(PVC管规格为直径5cm左右,壁厚0.5cm左右,长度约10cm,可根据原位矿化的土层的需求调整PVC管长度);两个装有离子交换树脂和石英砂的PVC管(PVC管规格与上述一致,长度约3cm),即上堵盖和下堵盖,该PVC管分为两层,中间用100-150目的滤网5隔开,一端放置一定质量的阴阳离子交换树脂混合物(树脂量可根据原位培养时间调整),剩余空间填满石英砂,两端用上述相同规格的尼龙网或钢丝网封口,以橡皮筋固定尼龙网或者镶嵌的方式固定;主管体2打入相应土层取出后,将上堵盖和下堵盖均以离子交换树脂端向上的方向,用胶带将其与装有土壤的PVC管相连接,再放回原土层进行原位培养,一段时间取出后拆分PVC管,分别提取测定管内土壤和离子交换树脂中的硝态氮和铵态氮(统称矿质氮)含量,定量分析一段时间内土壤的矿化量和矿化速率。The device includes a polished PVC pipe at one end (polished length 0.5-1cm), that is, the main body 2, so that it can be smoothly driven into different soil layers of forest soil to collect in-situ soil (the specification of the PVC pipe is about 5cm in diameter, and the wall The thickness is about 0.5cm, the length is about 10cm, and the length of the PVC pipe can be adjusted according to the needs of the in-situ mineralized soil layer); two PVC pipes filled with ion exchange resin and quartz sand (the specification of the PVC pipe is the same as above, and the length is about 3cm ), that is, the upper blocking cover and the lower blocking cover. The PVC pipe is divided into two layers, separated by a 100-150 mesh filter screen 5 in the middle, and a certain quality of anion-cation exchange resin mixture is placed at one end (the amount of resin can be determined according to the in-situ cultivation time Adjustment), the remaining space is filled with quartz sand, the two ends are sealed with nylon mesh or steel mesh of the same specification as above, and the nylon mesh is fixed with rubber bands or inlaid; after the main body 2 is driven into the corresponding soil layer and taken out, the upper plug Both the cover and the lower blocking cover are connected with the PVC pipe filled with soil with adhesive tape in the direction of the ion exchange resin end upward, and then put back into the original soil layer for in-situ cultivation. After a period of time, the PVC pipe is disassembled and separated. Extract and measure the content of nitrate nitrogen and ammonium nitrogen (collectively referred to as mineral nitrogen) in the soil and ion exchange resin in the tube, and quantitatively analyze the mineralization amount and mineralization rate of the soil within a period of time.
装有离子交换树脂和石英砂的PVC管,上堵盖1和下堵盖3,可在野外试验前在室内完成制作,操作简单,对于在森林生态系统等野外试验场所需大量重复的研究中,可节省在野外的操作时间,提高工作效率;以一定孔径的滤网5封口可使得降水和土壤渗漏水等在土柱中自由流动,通气效果好,且滤网5较为坚固在野外不易腐烂损坏等;上端放置离子交换树脂可阻止降水中铵根离子和硝酸根离子,或土壤水流动过程中的矿质氮的输入,避免其他外部矿质氮进入培养的土柱中,下端的离子交换树脂可以吸附培养土柱中淋溶下来的矿质氮;上端的石英砂可阻止培养土柱中的矿质氮扩散至土柱上端的树脂,下端的石英砂可阻止土柱外的矿质氮扩散至土柱下端的树脂中。这种装置最大限度地使土柱在自然状态下原位培养,可较为精确的测定和计算培养的土柱中实际的矿质氮量和矿质速率;PVC管和滤网5可重复使用,减少污染,节能环保。The PVC pipe equipped with ion exchange resin and quartz sand, the upper blocking cover 1 and the lower blocking cover 3 can be made indoors before the field test, and the operation is simple. It is suitable for a large number of repeated studies in field test sites such as forest ecosystems. In the field, it can save operating time in the field and improve work efficiency; sealing with a filter screen 5 with a certain aperture can make precipitation and soil seepage water flow freely in the soil column, the ventilation effect is good, and the filter screen 5 is relatively strong in the field It is not easy to rot and damage; the ion exchange resin placed on the upper end can prevent the input of ammonium ions and nitrate ions in precipitation, or the input of mineral nitrogen during the flow of soil water, and prevent other external mineral nitrogen from entering the cultivated soil column. The ion exchange at the lower end The resin can absorb the mineral nitrogen leached from the cultivation soil column; the quartz sand at the upper end can prevent the mineral nitrogen in the cultivation soil column from diffusing to the resin at the upper end of the soil column, and the quartz sand at the lower end can prevent the mineral nitrogen outside the soil column from diffusing to the soil In the resin at the lower end of the column. This device maximizes the in-situ cultivation of the soil column in the natural state, and can accurately measure and calculate the actual mineral nitrogen content and mineral rate in the cultivated soil column; the PVC pipe and filter screen 5 can be reused to reduce pollution ,Energy saving and environmental protection.
优选地,实施例2,参见图2,主管体2的两端分别设置有外螺纹,上堵盖1和下堵盖3均包括圆筒状的转接套11,转接套11的两端分别设置有内螺纹,所述滤网5固设在转接套的中部且隔设在两端内螺纹之间,转接套一端的内螺纹连接在主管体端部的外螺纹上,另一端的内螺纹连接上堵盖或下堵盖。网状端盖12的端部选用100-150目的钢丝网或尼龙网。滤网5选用100-150目的钢丝网或尼龙网。这样上堵盖1和下堵盖3均可在主管体2上实现可旋转拆卸,在野外实验时操作更为方便,人们可直接在室内将石英砂和树脂放进两端的装置,野外操作只需直接与主管体1做好连接即可;且通过主管体螺纹的连接,可减少滤液在连接口的流失,增强氮矿化速率测定的精确性。Preferably, in embodiment 2, referring to FIG. 2 , the two ends of the main body 2 are respectively provided with external threads, and the upper blocking cover 1 and the lower blocking cover 3 both include a cylindrical adapter sleeve 11, and the two ends of the adapter sleeve 11 Internal threads are respectively provided, and the filter screen 5 is fixed in the middle of the adapter sleeve and is separated between the internal threads at both ends. The internal thread at one end of the adapter sleeve is connected to the external thread at the end of the main body, and the other end The internal thread is connected to the upper blocking cover or the lower blocking cover. The end of mesh end cap 12 selects 100-150 mesh steel wire mesh or nylon mesh for use. Filter screen 5 selects 100-150 purpose steel wire mesh or nylon mesh for use. In this way, both the upper block cover 1 and the lower block cover 3 can be rotatably disassembled on the main body 2, and it is more convenient to operate during field experiments. People can directly put quartz sand and resin into the devices at both ends indoors. It only needs to be directly connected with the main body 1; and through the connection of the main body thread, the loss of filtrate at the connection port can be reduced, and the accuracy of nitrogen mineralization rate measurement can be enhanced.
其他实施例,上、下堵盖与主管体之间的连接结构也可以采用螺纹连接、卡扣连接、法兰连接等其他可拆卸连接方式,或者采用粘接、铆接、热熔连接等其他一次性连接方式。In other embodiments, the connection structure between the upper and lower blocking caps and the main body can also adopt other detachable connection methods such as threaded connection, buckle connection, flange connection, or other primary connection methods such as bonding, riveting, and hot-melt connection. sexual connection.
最后所应说明的是:上述实施例仅用于说明而非限制本实用新型的技术方案,任何对本实用新型进行的等同替换及不脱离本实用新型精神和范围的修改或局部替换,其均应涵盖在本实用新型权利要求保护的范围之内。Finally, it should be noted that: the above-mentioned embodiments are only used to illustrate and not limit the technical solutions of the present utility model, any equivalent replacement of the present utility model and any modification or partial replacement that does not depart from the spirit and scope of the present utility model shall be Covered within the protection scope of the claims of the present utility model.
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CN109406760A (en) * | 2018-12-23 | 2019-03-01 | 环境保护部南京环境科学研究所 | Device for forest ecosystem soil in-situ nitrogen mineralization rate determination |
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CN109406760A (en) * | 2018-12-23 | 2019-03-01 | 环境保护部南京环境科学研究所 | Device for forest ecosystem soil in-situ nitrogen mineralization rate determination |
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