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CN208627007U - A system for cyclic desulfurization by magnesium method and preparation of magnesium sulfate by utilizing flue gas heat source - Google Patents

A system for cyclic desulfurization by magnesium method and preparation of magnesium sulfate by utilizing flue gas heat source Download PDF

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Publication number
CN208627007U
CN208627007U CN201821262614.7U CN201821262614U CN208627007U CN 208627007 U CN208627007 U CN 208627007U CN 201821262614 U CN201821262614 U CN 201821262614U CN 208627007 U CN208627007 U CN 208627007U
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flue gas
magnesium sulfate
desulfurization
condenser
magnesium
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CN201821262614.7U
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史月涛
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Shandong University
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Shandong University
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals

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Abstract

The utility model relates to carry out magnesium processes circulation desulfurization using flue gas heat source and prepare magnesium sulfate system, belong to flue gas desulfurization technique field.The system comprises desulfurizing tower, heating device, deduster, condenser, slurry pool, low-pressure heater, sparge pipe, gas inlet, exhanst gas outlet, Adlerika imports, steam outlet;The deduster, gas inlet connection, exhanst gas outlet are connect with desulfurizing tower lower part;The connection of the bottom of Adlerika import and desulfurizing tower;Steam outlet in heating device is connect with condenser;The condenser, slurry pool, sparge pipe are sequentially connected, and the top of desulfurizing tower is protruded into one end of sparge pipe;Low-pressure heater and condenser are connected with each other.The utility model is using the subsequent evaporation crystallization treatment technique with substituted sulfuric acid magnesium solution by the way of flue gas heat exchange, not only simplify the preparation process of desulfuration byproduct, the energy consumption in evaporative crystallization processing is saved, and realizes the effective use of residual heat resources, flue gas is made to have obtained high value added utilization.

Description

It is a kind of to carry out magnesium processes circulation desulfurization using flue gas heat source and prepare magnesium sulfate system
Technical field
The utility model relates to flue gas desulfurization technique field more particularly to it is a kind of utilize thermal power generation plant smoke residual heat, Circulation prepares the system that magnesium sulfate follows in magnesium processes sweetening process.
Background technique
Magnesium method flue gas desulphurization technique is a kind of Wet Flue Gas Desulfurization Technique for carrying out flue gas desulfurization as desulfurizing agent using magnesia, The desulphurization mechanism of magnesia is that basic anhydride and water react and generates hydroxide, and hydroxide slurry reabsorbs in flue gas SO2, generate aqueous magnesium sulfite and a small amount of magnesium sulfate.The direct by-product of magnesium method flue gas desulphurization is three water and six water sulfurous acid Magnesium, since there are oxygen (O in flue gas2), magnesium sulfite will be oxidized to magnesium sulfate under certain condition.
Magnesium processes desulfurization technology maturation is reliable, and desulfuration efficiency is high, and byproduct can comprehensively utilize, it is shown that increasing is excellent More property.There is data to show, at present the U.S., Europe, Japanese Thermal Power Plants 80% unit capacity be all made of magnesium processes desulfurization, TaiWan, China 95% unit capacity of power plant is also using magnesium processes desulfurization.Magnesium processes desulfurization has following features: (1) magnesium that magnesium method flue gas desulphurization uses Agent desulfurizing agent is very stronger than reactivity, and much higher than the reactivity of calcium agent 10 times, desirable higher desulfuration efficiency generally exists 95% or more, the consuming cost of desulfurizing agent reduces.(2) while desulfuration operations are stablized, small investment, due to magnesium processes desulfurization by-product Object cigarette magnesium sulfate, magnesium sulfate have higher solubility, so as to avoid its in systems fouling, blocking the problems such as generation.
However, in existing magnesium method flue gas desulphurization technique, it generally first will be in flue gas with desulfurizing agent (such as magnesium hydroxide solution) Sulfur dioxide removal, obtain being post-processed to obtain sulfuric acid magnesium products after Adlerika to it again, what this method generated Problem is: the aqueous solvent in desulfurizing agent largely evaporates in desulfurizing tower, and aqueous solvent not only causes water resource after being discharged with flue gas A large amount of wastes will cause serious plume contamination after being expelled directly out, so that enterprise has to and since smoke moisture is excessive It is additional to install flue gas dehumidification equipment additional, make entire process complications, the high cost of flue gas desulfurization.Therefore, it is necessary to study one kind New magnesium processes desulphurization system, to solve above-mentioned problems of the prior art.
Utility model content
For above-mentioned problems of the prior art, the utility model be intended to provide it is a kind of utilize flue gas heat source carry out magnesium Method circulation desulfurization and prepare magnesium sulfate system.The utility model is realized using heat source abundant in magnesium processes desulfurization technology and flue gas While the circulation of magnesium processes desulfurization carries out and the low cost of magnesium sulfate, high efficiency preparation, the height for also achieving flue gas is additional Value utilizes.
For achieving the above object, specifically, the utility model discloses following technical proposals:
A kind of system for carrying out magnesium processes circulation desulfurization using flue gas heat source and preparing magnesium sulfate, the system comprises: desulfurization Tower, Adlerika pump, heating device, air-introduced machine, deduster, condenser, slurry pool, desulfurizing agent solution pump, low-pressure heater, Booster pump, sparge pipe.
Gas inlet, exhanst gas outlet and Adlerika import, steam outlet are provided on the heating device.
Gas inlet in the deduster, air-introduced machine and heating device is sequentially connected, and the flue gas in heating device goes out Mouth is connected with the lower part of desulfurizing tower.Flue gas (heat source) is sent into heating device by air-introduced machine and is changed after deduster dedusting Heat, the flue gas after heat exchange enters from the lower part of desulfurizing tower carries out desulfurization in desulfurizing tower.
The flue gas comes from thermal power plant, because thermal power plant possesses DEG C various temperature gradients from 100 DEG C to 800 Heat source, residual heat resources are abundant, can cooperate with magnesium processes desulfurization, realize the high value added utilization of flue gas.
The condenser, slurry pool, desulfurizing agent solution pump are sequentially connected, and one end of sparge pipe and desulfurizing agent solution pump connect It connects, the other end protrudes into the top of desulfurizing tower.
Containing desulfurizing agent solution in the slurry pool, desulfurizing agent solution is sent into sparge pipe by desulfurizing agent solution pump, then by Sparge pipe sprays from up to down from the top of desulfurizing tower, and the flue gas after exchanging heat is sailed against the current from the lower part of desulfurizing tower, with desulfurization Agent solution contact, to complete the desulfurization of flue gas, the flue gas after desulfurization is directly by smoke stack emission, and desulfurizing agent solution passes through desulfurization Become congregate of the Adlerika to desulfurizing tower afterwards.
The bottom of Adlerika import, Adlerika pump, desulfurizing tower in the heating device is sequentially connected;Desulfurization The Adlerika of tower bottom is admitted in heating device by Adlerika pump, heating device using in flue gas heat with Adlerika exchanges heat, and the aqueous solvent in Adlerika is by thermal evaporation, thus the magnesium sulfate finished product crystallized;It is preferred that , the part of sulfuric acid magnesium finished product also recyclable Adlerika import to heating device of heating device preparation, with further Heat in magnesium sulfate finished product is recycled.
Preferably, the heating device is heat exchanger, and the heat exchanger uses dividing wall type structure, the dividing wall type structure Inside is hollow structure, and flue gas passes through from hollow dividing wall type structure, and Adlerika passes through between dividing wall type structure The heat that the wall of dividing wall type structure is completed between flue gas and Adlerika exchanges, and then is dehydrated to Adlerika, Being dehydrated using fume afterheat to Adlerika is advantageous in that: the waste heat in flue gas can not only be efficiently used, and It can be lowered into the flue-gas temperature of desulfurizing tower, to reduce the steaming of moisture in desulfurizing tower (desulfurizing agent solution, Adlerika) Hair amount further decreases the water capacity of discharge flue gas, reduces plume contamination.
The condenser, booster pump, low-pressure heater are sequentially connected, and low-pressure heater is connected with condenser, to be formed It is connected by circulation;Steam outlet in the heating device is connect with condenser.
The water vapour that aqueous solvent in Adlerika after by thermal evaporation is formed enters in condenser from steam outlet, It exchanges heat with the condensed water from low-pressure heater, water vapour is condensed water condensation after heat exchange, is then reintroduced to slurries Chi Zhong is configured to the condensed water that desulfurizing agent solution is recycled, and is heated with desulfurizing agent and is added by pressurization pumped back low pressure Working medium and heat recovery are carried out in hot device, are introduced back into condenser, are recycled after recycling.
It should be understood that the main purpose of the utility model is to realize that magnesium sulfate is prepared same using waste heat in flue gas When, also to realize the circulation of magnesium processes sulfur removal technology, it means that have to realize the sulfuric acid obtained after desulfurizing agent solution and desulfurization Otherwise the recycling of aqueous solution in magnesium solution can not really realize circulation magnesium processes desulfurization this purpose;It is found after analysis: de- The loss of aqueous solvent is concentrated mainly on the sweetening process in desulfurizing tower in sulphur agent solution and Adlerika, because of the smoke temperature of flue gas It is very high, it is directly entered after being contacted in desulfurizing tower with the Adlerika obtained after desulfurizing agent solution and desulfurization, water therein Solution can largely be evaporated, and then be discharged with flue gas, and the residual heat resources in flue gas have both been wasted, and waste a large amount of water money Source, and the water capacity that flue gas is discharged is too big, can generate obviously plume phenomenon in discharge, brings serious vision dirty Dye.
To solve the above-mentioned problems, the present invention just significantly cools down to it first before flue gas enters desulfurizing tower, The waste heat of flue gas is used to heat desulfurization product (magnesium sulfate solution) to prepare magnesium sulfate, to eliminate Adlerika Subsequent processing directly obtains magnesium sulfate finished product, after the flue gas after cooling enters desulfurizing tower, evaporates the ability of aqueous solvent significantly It reduces, the evaporation of aqueous solvent in desulfurizing tower can be effectively reduced, not only reduce the waste of water resource, also reduce discharge flue gas Water capacity, effectively improve pollution caused by flue gas, simultaneously as discharge flue gas water capacity sharp fall, Ke Yizhi Run in sky, is not required to carry out subsequent processing again to avoid plume phenomenon.And after magnesium sulfate solution enters in heating device, it is therein Water-soluble matter is evaporated, exchange heat after be introduced back into slurry pool and recycled, on the one hand heating device can be made full use of to go out The vapor come, realizes energy-saving purpose.On the other hand the recycling for realizing water resource, avoids the wave of water resource Take;As can be seen that the present invention is just with the waste heat in flue gas and simply, circulation, cooling, heat transfer process are efficiently solved The problem of fume afterheat resource and water resource largely wasted in magnesium processes sweetening process, achieves extraordinary synergy.
Compared with prior art, the beneficial effect that the utility model obtains is:
(1) the utility model using with the subsequent evaporation crystallization treatment work by the way of flue gas heat exchange instead of Adlerika Skill not only simplifies the preparation process of desulfuration byproduct, saves the energy consumption in evaporative crystallization processing, and realizes waste heat money The effective use in source, makes flue gas obtain high value added utilization.
(2) heat in the utility model water vapour such as can be used for heating after being exchanged heat the purposes, make waste heat in flue gas again Once it is utilized, meanwhile, condensed water vapour is used again to desulfurization, not only realizes circulation magnesium processes desulfurization, also effective Plume phenomenon is improved, treated after flue gas directly empties by the system of the utility model, and plume phenomenon naked eyes are invisible.
Detailed description of the invention
The accompanying drawings constituting a part of this application is used to provide further understanding of the present application, and the application's shows Meaning property embodiment and its explanation are not constituted an undue limitation on the present application for explaining the application.
Fig. 1 is to carry out magnesium processes circulation desulfurization using flue gas heat source in embodiment 1 and prepare the structural representation of magnesium sulfate system Figure.
Fig. 2 is to carry out magnesium processes circulation desulfurization using flue gas heat source in embodiment 2 and prepare the structural representation of magnesium sulfate system Figure.
Attached drawing acceptance of the bid note respectively represents: 1- desulfurizing tower, 2- Adlerika pump, 3- heating device, 4- air-introduced machine, 5- dedusting Device, 6- condenser, 7- slurry pool, 8- desulfurizing agent solution pump, 9- low-pressure heater, 10- booster pump, 11- sparge pipe.
Specific embodiment
It is noted that following detailed description is all illustrative, it is intended to provide further instruction to the application.Unless another It indicates, all technical and scientific terms used herein has usual with the application person of an ordinary skill in the technical field The identical meanings of understanding.
It should be noted that term used herein above is merely to describe specific embodiment, and be not intended to restricted root According to the illustrative embodiments of the application.As used herein, unless the context clearly indicates otherwise, otherwise singular Also it is intended to include plural form, additionally, it should be understood that, when in the present specification using term "comprising" and/or " packet Include " when, indicate existing characteristics, step, operation, device, component and/or their combination.
As background technique is introduced, existing magnesium processes sulfur removal technology still has a large amount of wastes, serious of water resource Plume contamination and complex process, it is at high cost the problems such as, therefore, the utility model proposes it is a kind of utilize flue gas heat source carry out Magnesium processes circulation desulfurization and magnesium sulfate system is prepared, the utility model is done further with reference to the accompanying drawings and detailed description Explanation.
Embodiment 1
As shown in Figure 1, a kind of system for carrying out magnesium processes circulation desulfurization using flue gas heat source and preparing magnesium sulfate, the system It include: that desulfurizing tower 1, Adlerika pump 2, heating device 3, air-introduced machine 4, deduster 5, condenser 6, slurry pool 7, desulfurizing agent are molten Liquid pump 8, low-pressure heater 9, booster pump 10, sparge pipe 11.
Gas inlet, exhanst gas outlet and Adlerika import, steam outlet are provided on the heating device 3.
Gas inlet in the deduster 5, air-introduced machine 4 and heating device 3 is sequentially connected, the cigarette in heating device 3 Gas outlet is connected with the lower part of desulfurizing tower.Flue gas is sent into heating device 3 by air-introduced machine 4 and is changed after 5 dedusting of deduster Heat, the flue gas after heat exchange enters from the lower part of desulfurizing tower 1 carries out desulfurization in desulfurizing tower 1.
The condenser 6, slurry pool 7, desulfurizing agent solution pump 8 are sequentially connected, one end of sparge pipe 11 and desulfurizing agent solution 8 connection of pump, the other end protrude into the top of desulfurizing tower 1.
Containing desulfurizing agent solution in the slurry pool 7, desulfurizing agent solution is sent into sparge pipe 11 by desulfurizing agent solution pump 8, Sprayed from up to down by sparge pipe 11 from the top of desulfurizing tower 1 again, and the flue gas after exchanging heat from the lower part of desulfurizing tower 1 adverse current and On, it is contacted with desulfurizing agent solution, to complete the desulfurization of flue gas, the flue gas after desulfurization is directly by smoke stack emission, and desulfurizing agent is molten Liquid becomes Adlerika to the congregate of desulfurizing tower 1 after desulfurization.
The bottom of Adlerika import, Adlerika pump 2, desulfurizing tower 1 in the heating device 3 is sequentially connected; The Adlerika of desulfurization tower bottom is admitted in heating device 3 by Adlerika pump 2, and heating device 3 is using in flue gas Waste heat exchange heat with Adlerika, the magnesium sulfate finished product crystallized after the evaporation of solvent in Adlerika.
The heating device 3 is heat exchanger, and heat exchanger uses dividing wall type structure, and the inside of the dividing wall type structure is hollow Structure, flue gas pass through from hollow dividing wall type structure, and Adlerika passes through dividing wall type structure between dividing wall type structure The heat completed between flue gas and Adlerika of wall exchange, and then Adlerika is dehydrated.
The condenser 6, booster pump 10, low-pressure heater 9 are sequentially connected, and low-pressure heater 9 is connected with condenser 6, from And it is formed and is connected by circulation;Steam outlet in the heating device 6 is connect with condenser 6.Magnesium sulfate after by thermal evaporation is molten Aqueous solvent (water vapour) in liquid enters in condenser 6, exchanges heat with the condensed water from low-pressure heater 9, water after heat exchange Steam is condensed water condensation, is then reintroduced in slurry pool 7, is configured to desulfurizing agent solution with desulfurizing agent and carries out circulation benefit With, and the condensed water being heated is sent back in low-pressure heater 9 by booster pump 10 and carries out working medium and heat recovery, is drawn again after recycling Enter in condenser 6, is recycled.
Embodiment 2
As shown in Fig. 2, a kind of system for carrying out magnesium processes circulation desulfurization using flue gas heat source and preparing magnesium sulfate, the system With embodiment 1,20% magnesium sulfate finished product of heating device preparation is recycled to the Adlerika import of heating device 3, with It improves and is granulated quality and heat recovery.
The foregoing is merely preferred embodiment of the present application, are not intended to limit this application, for those skilled in the art For member, various changes and changes are possible in this application.Within the spirit and principles of this application, it is made it is any modification, Equivalent replacement, improvement etc., should be included within the scope of protection of this application.

Claims (8)

1.一种利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述系统包括:脱硫塔、加热装置、除尘器、冷凝器、浆液池、低压加热器、喷液管;所述加热装置上设置有烟气进口与烟气出口以及硫酸镁溶液进口、水蒸汽出口;所述除尘器、烟气进口连接,烟气出口与脱硫塔的下部连接;所述硫酸镁溶液进口与脱硫塔的底部连接;所述加热装置中的水蒸汽出口与冷凝器连接;所述冷凝器、浆液池、喷液管依次相连,喷液管的一端伸入脱硫塔的上部;所述低压加热器与冷凝器相互连接,形成循环系统。1. utilize flue gas heat source to carry out magnesium method cycle desulfurization and prepare magnesium sulfate system, it is characterized in that: described system comprises: desulfurization tower, heating device, dust collector, condenser, slurry pool, low pressure heater, spray pipe The heating device is provided with a flue gas inlet, a flue gas outlet, a magnesium sulfate solution inlet, and a water vapor outlet; the dust collector and the flue gas inlet are connected, and the flue gas outlet is connected with the lower part of the desulfurization tower; the magnesium sulfate solution The inlet is connected with the bottom of the desulfurization tower; the water vapor outlet in the heating device is connected with the condenser; the condenser, the slurry tank and the liquid spray pipe are connected in sequence, and one end of the liquid spray pipe extends into the upper part of the desulfurization tower; the The low pressure heater and the condenser are interconnected to form a circulation system. 2.如权利要求1所述的利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述系统还包括引风机,所述除尘器、引风机、加热装置中的烟气进口、脱硫塔依次相连。2. utilizing flue gas heat source to carry out magnesium method cyclic desulfurization and preparing magnesium sulfate system as claimed in claim 1, it is characterized in that: described system also comprises induced draft fan, the flue gas in described dust collector, induced draft fan, heating device The inlet and the desulfurization tower are connected in turn. 3.如权利要求2所述的利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述系统还包括硫酸镁溶液泵,所述硫酸镁溶液进口、硫酸镁溶液泵与脱硫塔的底部相连。3. utilizing the flue gas heat source to carry out magnesium process cycle desulfurization and preparing magnesium sulfate system as claimed in claim 2, it is characterized in that: described system also comprises magnesium sulfate solution pump, described magnesium sulfate solution inlet, magnesium sulfate solution pump and The bottom of the desulfurization tower is connected. 4.如权利要求3所述的利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述系统还包括脱硫剂溶液泵;所述冷凝器、浆液池、脱硫剂溶液泵依次相连,喷液管的一端与脱硫剂溶液泵连接,另一端伸入脱硫塔的上部。4. The system of utilizing flue gas heat source for cyclic desulfurization by magnesium method and preparing magnesium sulfate system as claimed in claim 3, characterized in that: the system further comprises a desulfurizer solution pump; the condenser, the slurry tank, the desulfurizer solution pump Connected in sequence, one end of the liquid spray pipe is connected with the desulfurization agent solution pump, and the other end extends into the upper part of the desulfurization tower. 5.如权利要求4所述的利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述系统还包括增压泵,所述冷凝器、增压泵、低压加热器依次相连,低压加热器与冷凝器相连,从而形成循环系统。5. The system as claimed in claim 4, characterized in that: the system also comprises a booster pump, and the condenser, the booster pump and the low-pressure heater are sequentially Connected, the low-pressure heater is connected with the condenser to form a circulation system. 6.如权利要求1-5任一项所述的利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述加热装置为换热器。6. The system of utilizing flue gas heat source for cyclic desulfurization of magnesium and preparing magnesium sulfate according to any one of claims 1-5, characterized in that: the heating device is a heat exchanger. 7.如权利要求6所述的利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述换热器采用间壁式结构,所述间壁式结构的内部为中空结构,烟气从中空的间壁式结构中通过,硫酸镁溶液位于间壁式结构之间,通过间壁式结构的器壁完成烟气与硫酸镁溶液之间的热量交换。7. The system of utilizing flue gas heat source for cyclic desulfurization by magnesium method and preparing magnesium sulfate system as claimed in claim 6, characterized in that: the heat exchanger adopts a partition structure, and the interior of the partition structure is a hollow structure, and the smoke The gas passes through the hollow partition structure, the magnesium sulfate solution is located between the partition structures, and the heat exchange between the flue gas and the magnesium sulfate solution is completed through the wall of the partition structure. 8.如权利要求6所述的利用烟气热源进行镁法循环脱硫及制备硫酸镁系统,其特征在于:所述加热装置中得到的硫酸镁成品再循环至加热装置的硫酸镁溶液进口。8. The magnesium sulfate cyclic desulfurization and magnesium sulfate preparation system utilizing a flue gas heat source as claimed in claim 6, wherein the magnesium sulfate product obtained in the heating device is recycled to the magnesium sulfate solution inlet of the heating device.
CN201821262614.7U 2018-08-06 2018-08-06 A system for cyclic desulfurization by magnesium method and preparation of magnesium sulfate by utilizing flue gas heat source Expired - Fee Related CN208627007U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108722166A (en) * 2018-08-06 2018-11-02 山东大学 It is a kind of to carry out magnesium processes circulation desulfurization using flue gas heat source and prepare magnesium sulfate system and method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108722166A (en) * 2018-08-06 2018-11-02 山东大学 It is a kind of to carry out magnesium processes circulation desulfurization using flue gas heat source and prepare magnesium sulfate system and method

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