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CN208350645U - Raman spectrometer probe - Google Patents

Raman spectrometer probe Download PDF

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Publication number
CN208350645U
CN208350645U CN201821085335.8U CN201821085335U CN208350645U CN 208350645 U CN208350645 U CN 208350645U CN 201821085335 U CN201821085335 U CN 201821085335U CN 208350645 U CN208350645 U CN 208350645U
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China
Prior art keywords
light source
raman spectrometer
accommodating space
holder
spectroscope
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CN201821085335.8U
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Chinese (zh)
Inventor
郑上仁
沈峰民
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Jasmat Optics Corp
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Jasmat Optics Corp
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Abstract

本申请公开了一种拉曼光谱仪探头,包括一光源模块、一分光模块和一聚焦模块。分光模块设置在一容置空间内,光源模块相邻于包围容置空间的一第一侧壁设置,聚焦模块相邻于包围容置空间且相对于第一侧壁的一第二侧壁设置。光源模块的光源在垂直于光源模块的光束发射口的朝向的一第一方向上为可移动的。分光模块具有一分光镜固定座和一立于分光镜固定座上的分光镜,分光镜的一镜面朝向光源模块而另一镜面朝向聚焦模块,分光镜固定座设置在容置空间内且为可转动的,分光镜固定座的转动轴的轴向和光束发射口的朝向垂直且和第一方向垂直。

This application discloses a Raman spectrometer probe, which includes a light source module, a light splitting module and a focusing module. The light splitting module is arranged in an accommodating space, the light source module is arranged adjacent to a first side wall surrounding the accommodating space, and the focusing module is arranged adjacent to a second side wall surrounding the accommodating space and relative to the first side wall. . The light source of the light source module is movable in a first direction perpendicular to the direction of the beam emission port of the light source module. The spectroscope module has a spectroscope holder and a spectroscope standing on the spectroscope holder. One mirror surface of the spectroscope faces the light source module and the other mirror surface faces the focusing module. The spectroscope holder is set in the accommodation space and is removable. Rotating, the axial direction of the rotation axis of the spectroscope holder is perpendicular to the direction of the beam emission port and perpendicular to the first direction.

Description

A kind of Raman spectrometer probe
Technical field
The application belongs to optical measurement field, specifically, being related to a kind of Raman spectrometer probe.
Background technique
Known spectral analysis is to know its composition according to the spectrum measured for substance, and Raman spectrometer (Raman Spectrometer) is to be incident upon with laser light on the test substance including solid, liquid and powder, makes determinand Matter inspires scattering light, and then measures to the Raman spectrum (Raman Spectra) of scattering light.In existing technology, utilize It is to be connected with two on probe to carry out remote sampling through a probe when Raman spectrometer carries out spectrum measuring to test substance Beam optical fiber, wherein a branch of optical fiber focuses on laser light on test substance, another beam optical fiber is then collected from test substance excitation Raman diffused light (Raman Scattering Light) with Raman spectrum.Raman spectrometer and probe can not have to engagement Together, it remotely to be measured, or is bonded together to carry out proximity measurement.
However, either remotely measurement or proximity measure, the Raman diffused light for being excited collected from test substance Optical coupled effect between optical fiber and Raman spectrometer is simultaneously bad, causes the spectrum signal resolution ratio measured poor, and can not Obtain good measurement.Therefore, the optical coupled degree between Raman spectrometer and probe how is improved, it is optimal to obtain Raman spectrum measurement is the utility model technical task to be solved.
Utility model content
In view of the above problem, the utility model provides a kind of Raman spectrometer probe, to a Raman spectrometer coupling It connects, measures the Raman spectrum of a test substance.So-called coupling is comprising being directly connected to and being indirectly connected with.
In one embodiment, a kind of Raman spectrometer probe provided by the utility model includes a pedestal, forms an accommodating Space;The light source in light source fixing seat is arranged in a light source fixing seat and one in one light source module, and light source fixing seat has one Beam emissions mouth, the setting of light source fixing seat is located at outside accommodating space on the base and beam emissions mouth and the one of encirclement accommodating space The first side wall is adjacent, light source fixing seat in one and beam emissions mouth towards being moveable on vertical first direction;One is poly- Burnt module is arranged in outside accommodating space and adjacent with a second sidewall of accommodating space is surrounded, second sidewall and the first side wall phase It is right;One first condenser lens, setting is adjacent with second sidewall in accommodating space, and couples with focus module;One second focuses Lens, be arranged in accommodating space and with surround a third side wall of accommodating space it is adjacent, third side wall to and Raman spectrum Instrument coupling;With a spectral module, with a spectroscope fixing seat and one tool there are two back to one first mirror surface and one second mirror The spectroscope in face, spectroscope are stood in spectroscope fixing seat, and spectroscope fixing seat is arranged in accommodating space, and the first mirror surface is neighbouring The first side wall and towards beam emissions mouth, the second mirror surface plate on the first mirror surface adjacent to second sidewall and towards the first condenser lens There is antireflective optical film, reflective foil, the positive normal of the second mirror surface and the direction of beam emissions mouth are coated on the second mirror surface Between angle be 44 degree to 46 degree, spectroscope fixing seat is in being rotatable, the rotation of spectroscope fixing seat in accommodating space The axial direction of axis and the direction of beam emissions mouth are vertical and vertical with first direction.
In one embodiment, a first positioning hole is formed in light source fixing seat, and corresponding first positioning hole is formed on pedestal One first screw hole, first positioning hole are greater than the aperture of the first screw hole in the aperture on first direction.
In one embodiment, the periphery of spectroscope fixing seat forms two two-phases for being located at spectroscope fixing seat along outer rim The second location hole of opposite side, the line at the center of second location hole and are formed perpendicular to the positive normal of the second mirror surface on pedestal Second screw hole of corresponding second location hole, second location hole are greater than the second spiral shell in the aperture in the rotation direction of spectroscope fixing seat The aperture in hole.
In one embodiment, first positioning hole is equal to the aperture of first screw hole in beam emissions mouth towards upper aperture, or Second location hole is equal to the aperture of the second screw hole in the aperture in the radial direction of spectroscope fixing seat.
In one embodiment, the shape of spectroscope fixing seat is discoid and second location hole a side in indent.
In one embodiment, light source fixing seat can deviate to the right in a second direction or micro- to the left a little in a first direction Width deviates on a third direction.
In one embodiment, circular groove is formed on the bottom of accommodating space, and spectroscope fixing seat is arranged in circular groove.
In one embodiment, the probe of Raman spectrometer provided by this creation further include a setting in accommodating space and between Optical filter between spectral module and the second condenser lens, to filter out the Rayleigh scattering light through the second mirror-reflection.
Optionally, the first condenser lens and the second condenser lens are convex lens.
Can far, light source is a laser optical diode, and the emission wavelength of light source be 532nm, 785nm and 1064nm wherein One of.
In conclusion according to Raman spectrometer described in each embodiment of this creation pop one's head in, eliminate optical fiber use and Change the combination for adopting spectral module, light source module and focus module, and in being respectively provided with rotation on spectral module and light source module Adjustment mechanism and moving adjusting mechanism, so that there is optimal optical coupled effect between Raman spectrometer probe and Raman spectrometer Fruit simultaneously makes the optical coupled correction between Raman spectrometer probe and Raman spectrometer more easy.Therefore, this creation is mentioned Raman spectrometer probe out, improves the measurement precision of Raman spectrometer and reduces comprising the non-Raman such as Rayleigh scattering light Light is scattered for spectrometric interference, is more suitable for scientific research and on-line checking.
In order to make the above-mentioned features and advantages of the utility model more obvious and understandable, special embodiment below, and appended by cooperation Schema is described in detail below.
Detailed description of the invention
Fig. 1 is the stereochemical structure schematic top plan view of the Raman spectrometer probe of an embodiment of the present invention.
Fig. 2 is the planar structure schematic top plan view of the Raman spectrometer probe of an embodiment of the present invention.
Fig. 3 is the light splitting path floor map of the Raman spectrometer probe of an embodiment of the present invention.
Specific embodiment
The utility model discloses a kind of Raman spectrometer probe, wherein the relative theory of so-called Raman spectrometer and side Method can be illustrated for those of ordinary skill in the art, therefore with following description, no longer make complete description.Meanwhile with hereafter Middle compareed attached drawing, it is intended that expression meaning related with the utility model feature does not also need complete according to actual size Whole drafting is formerly stated.
Fig. 1 is the stereochemical structure schematic top plan view of the Raman spectrometer probe of an embodiment of the present invention.Please refer to figure 1, in an embodiment, a kind of light source modules that Raman spectrometer probe 10 pedestal 100 and be fixed on pedestal 100 with one 101, a spectral module 102 and a focus module 103.Light source module 101 has a beam emissions mouth 1010, beam emissions mouth 1010 direction is indicated with I.An accommodating space 1001 is formed on pedestal 100, spectral module 102 is arranged in accommodating space 1001 It is interior, light source module 101 and focus module 103 be arranged in accommodating space 1001 it is outer and respectively with surround two of accommodating space 1001 An opposite the first side wall 1001a and a second sidewall 1001b is adjacent, so that two opposite sides of spectral module 102 are right respectively Answer ground optical light source module 101 and focus module 103.In addition, surrounding a third side wall 1001c of accommodating space 1001 then with one Raman spectrometer 20 couples.In the present embodiment, Raman spectrometer probe 10 also has one first condenser lens 104, an optical filter 105 and one second condenser lens 106, the setting of the first condenser lens 104 it is adjacent with second sidewall 1001b in accommodating space 1001 And coupled with focus module 103, the second condenser lens 106 is arranged in accommodating space 1001 and surrounds the of accommodating space 1001 Three side wall 1001c are adjacent, and optical filter 105 is arranged in accommodating space 1001 and between spectral module 102 and the second condenser lens Between 106.Raman spectrometer probe 10 and Raman spectrometer 20 carry out after coupling to fill the sample 30 of test substance to one Raman spectrum measures, and test substance includes solid, liquid and powder.Spectral module 102 is configured at light source module 101 and focuses mould Between block 103, sequentially pass through spectral module 102 and focus module 103 in order to the transmitting light beam of the beam emissions mouth of light source module 101 After focus on sample 30.The above so-called coupling includes being directly connected to and being indirectly connected with.
Please continue to refer to Fig. 1, there is light source module 101 a light source fixing seat 1011 and one to be arranged in light source fixing seat 1011 On light source (not shown), light source fixing seat 1011 is arranged outside accommodating space 1001, and beam emissions to emit light beam Mouth 1010 is adjacent with the first side wall 1001a of accommodating space 1001 is surrounded.Light source fixing seat 1011 be arranged on pedestal 100 and in Be on one first direction D1 it is moveable, the beam emissions mouth 1010 of first direction D1 and light source module 101 it is vertical towards I, Relative position between light source module 101 and spectral module 102 is adjusted.In one embodiment, light source can be one Laser optical diode (Laser Diode) is fixed on light source fixing seat 1011 using an adhesion material to emit a laser beam On, the direction of the launch of the collimated light beam L towards collimation shown in I and Fig. 2 and 3 of the beam emissions mouth 1010 of light source module 101 It is identical.In addition, forming at least one first positioning hole 1012 in light source fixing seat 1011, and it is fixed to correspond to first on pedestal 100 The first screw hole 100a is formed at the setting in position hole 1012.Also settable alignment mark (not shown) is solid for light source on pedestal 100 Alignment when reservation 1011 is disposed thereon.First positioning hole 1012 is in the aperture on first direction D1 greater than the first screw hole 100a's Aperture and be equal to the aperture of the first screw hole 100a in the aperture on the direction I, in order to Raman spectrometer probe setter using extremely After a few screw (not shown) is by first positioning hole 1012 and corresponding first screw hole 100a, light source fixing seat 1011 is locked Gu on pedestal 100, and the movement using light source fixing seat 1011 in the pore diameter range of first positioning hole 1012, along first Direction D1 adjusts light source fixing seat 1011 and light source in the allocation position on pedestal 100.In one embodiment, light source fixing seat 1011 Shape be, for example, L font or T font, the shape of first positioning hole 1012 is, for example, ellipse, and the shape of the first screw hole 100a Shape is, for example, circle.
Please continue to refer to Fig. 1, spectral module 102 has a spectroscope fixing seat 1023 and a spectroscope 1024, spectroscope 1024 stand on the middle position in spectroscope fixing seat 1023.Spectroscope fixing seat 1023 and spectroscope 1024 are arranged at accommodating The inside in space 1001, spectroscope fixing seat 1023 are detachably arranged in accommodating space 1001.The bottom of accommodating space 1001 It can be further formed a groove 10011, and spectroscope fixing seat 1023 is detachably arranged in groove 10011 and in groove 10011 are rotated up in the side perpendicular to spectroscope fixing seat 1023.
Fig. 2 is the planar structure schematic top plan view of the Raman spectrometer probe of an embodiment of the present invention.Fig. 3 is this reality The light splitting path floor map popped one's head in the Raman spectrometer of a novel embodiment.Implement referring to Fig. 2 and Fig. 3, one Example in, spectroscope 1024 tool there are two it is parallel to each other but back to the first mirror surface 10241 and the second mirror surface 10242, the first mirror surface The 10241 neighbouring the first side wall 1001a for surrounding accommodating space 1001 and the beam emissions mouth 1010 towards light source module 101, and The neighbouring second sidewall 1001b for surrounding accommodating space 1001 of second mirror surface 10242 and the first condenser lens 104 of direction, the first mirror Anti-reflection coating (Anti-Reflective Coating) or antireflective optical film, the second mirror surface 10242 are coated on face 10241 On post reflective foil (Reflective Optical Film), divide to the light to the second mirror surface of directive 10242 Light.The material and optical characteristics of anti-reflection coating and reflective foil are depending on actual demand, the utility model system not subject to the limits. First condenser lens 104 and the second condenser lens 106 can select convex lens to focus the light beam passed through, and the ruler of lens Very little and focal length depending on demand, the utility model system not subject to the limits.Optical filter 105 swashs to filter out the test substance of sample 30 Hair but non-other scattering light for belonging to Raman diffused light, such as Rayleigh scattering light (Rayleigh Scattering Light), choosing With depend on light source module 101 light source type, as long as can achieve the purpose that filter out non-category Raman diffused light, optical filter 105 Material and the wave-length coverage that filters out can be there are many selecting, the utility model system not subject to the limits.In one embodiment, first is focused Each setting that adhesion material is fixed on accommodating space 1001 can be selected in lens 104, optical filter 105 and the second condenser lens 106 On position, selected adhesion material is, for example, UV cured glue (UV glue) or epoxy resin (epoxy), and the utility model is not It limits herein.
Please continue to refer to Fig. 2 and Fig. 3, in an embodiment, the beam emissions mouth of light source module 101 launches the parallel of collimation Light beam L, the beam emissions mouth of the positive normal N and collimated light beam L of the second mirror surface 10242 of spectroscope 1024 direction between Angle theta 1 is preferably 44 to 46 degree.When collimated light beam L passes through spectral module 102, due to the antireflection on the first mirror surface 10241 The antireflection of film acts on, and most collimated light beam L can focus on sample by spectroscope 1024 and by the first condenser lens 104 The surface of product 30.The test substance of sample 30 can generate scattering light S after being excited by collimated light beam L, scattering light S meeting incidence first is poly- Focus lens 104 simultaneously become collimated light beam, and scattering light S includes Raman diffused light S1 and Rayleigh scattering light S2.Most Raman dissipates Light S1 is penetrated to be reflected on the second mirror surface 10242 by reflectance coating and sequentially by focusing after optical filter 105 and the second condenser lens 106 To carry out subsequent spectrum measuring in spectrometer 20, most Rayleigh scattering light S2 reaches packet after penetrating spectroscope 1024 Enclose the inner surface of accommodating space 1001 and the 4th side wall 1001d of neighbouring first mirror surface 10241.It is reflected through the second mirror surface 10242 Scattering light in as contain Rayleigh scattering light person, these Rayleigh scattering lights enter spectrometer 20 before will be filtered out by optical filter 105, Enter the measurement in spectrometer 20 and disturbing Raman spectrum to avoid Rayleigh scattering light.When so-called collimated light beam is laser beam When, the wavelength of selection includes 532nm, 785nm and 1064nm, and when the wavelength of selection is shorter, the intensity of Raman diffused light is bigger.
Please continue to refer to Fig. 1, the center of spectroscope fixing seat 1023 is equipped with one to accept the bracket of spectroscope 1024 (not Display), bracket can be fixed in a manner of locking in spectroscope fixing seat 1023 or with integrally formed mode and point Light microscopic fixing seat 1023 is integrated, and spectroscope 1024 can be and is fixed in spectroscope fixing seat 1023 with an adhesion material Bracket.In addition, the periphery of spectroscope fixing seat 1023 is formed along outer rim, two apertures are identical and to be located at spectroscope solid The second location hole 1023a and 1023b of the two opposite sides of reservation 1023, the line at the center of second location hole 1023a and 1023b Perpendicular to the positive normal of the second mirror surface 10242, and on the groove 10011 of pedestal 100 correspond to second location hole 1023a and The identical second screw hole 10011a and 10011b in aperture is respectively formed at the setting of 1023b.Second location hole 1023a and 1023b It is greater than the aperture of the second screw hole 10011a and 10011b in the aperture in the rotation direction of spectroscope fixing seat 1023 and second is fixed Position hole 1023a and 1023b in the aperture in the radial direction of spectroscope fixing seat 1023 be equal to the second screw hole 10011a and The aperture of 10011b passes through second location hole using two screw (not shown)s in order to the setter of Raman spectrometer probe respectively After 1023a and 1023b and corresponding second screw hole 10011a and 10011b, spectroscope fixing seat 1023 is locked in groove On 10011, and using spectroscope fixing seat 1023 relative to groove 10011 second location hole 1023a and 1023b aperture model Interior rotation is enclosed, adjusts spectroscope 1024 in the arrangement angles in accommodating space 1001.As shown in Figure 1, in an embodiment, light splitting The shape of mirror fixing seat 1023 be, for example, discoid and groove 10011 shape be, for example, circle, second location hole 1023a and The shape of 1023b is, for example, the ellipse that side is in indent, and the shape of the second screw hole 10011a and 10011b is, for example, circle.
Please continue to refer to Fig. 1, focus module 103 is a column, and section is that round or rectangle is not subject to the limits, both ends point First condenser lens 104 and a protective glass 1031 be not set, and the first condenser lens 104 is arranged in accommodating space 1001 and with the Two side wall 1001b are adjacent, and the focal point that the first condenser lens 104 is arranged in protective glass 1031 measures sample 30 for proximity and keeps away Exempt from sample 30 and damages focus module 103 itself.In one embodiment, the mode that focus module 103 is arranged in protective glass 1031 can be with It is to be fixed using an adhesion material, adhesion material is, for example, UV cured glue (UV glue) or epoxy resin (epoxy).
In one embodiment, in the assembling process of Raman spectrometer probe 10, can first by Raman spectrometer probe 10 and it draw The sample 30 that graceful spectrometer 20 fills test substance to one after coupling carries out Raman spectrum measurement, and sample 30 is in face of protective glass 1031 place, and Raman spectrometer 20 is connected with a remote computer, and the software program setting through remote computer is appropriate The time of integration simultaneously selects real-time continuous measurement mode.Meanwhile spectroscope is allowed to fix using jig clamping spectroscope fixing seat 1023 Seat 1023 is rotated relative to groove 10011, so that the positive normal N and light source of the second mirror surface 10242 of spectroscope 1024 The beam emissions mouth of module 101 towards the angle between I be 44 degree to 46 degree, and the rotation axis of spectroscope fixing seat 1023 It is axial vertical towards I with the beam emissions mouth of first direction D1 and light source module 101.It is subsequent, finely tune spectroscope fixing seat 1023 rotation angle takes screw to be each passed through the second spiral shell when spectrum signal that Raman spectrometer 20 measures is maximum By spectroscope fixing seat 1023 in groove 10011 after hole 10011a and 10011b and corresponding second location hole 1023a and 1023b On.
Please refer to Fig. 1, in another embodiment, in the use process of Raman spectrometer probe 10, most Rayleigh dissipates Arrival encirclement accommodating space 1001 and the 4th side wall towards the first mirror surface 10241 after spectroscope 1024 can be penetrated by penetrating light S2 On the inner surface of 1001d, and the configuration of the position of the light emitting angle tolerance of the light source in light source module 101 and light source module 101 is inclined The transmitting light that difference will also result in light source module 101 has part reflection towards the on the first mirror surface 10241 of spectroscope 1024 On the inner surface of 4th side wall 1001d of one mirror surface 10241, these reach the light on the inner surface of the 4th side wall 1001d all Raman spectrometer further may be entered after reflection and the spectrum signal that Raman spectrometer measures is caused to interfere, and then led Cause the spectrum signal measured undesirable.At this point, in the case where spectroscope fixing seat 1023 has been locked in groove 10011, In order to reduce the interference for emitting light of light source module 101, light source fixing seat 1011 is clamped using jig, first by light source fixing seat 1011 along a first direction D1 move a little, it is anti-in the part on the first mirror surface 10241 with the transmitting light for removing light source module 101 It penetrates;Then, light source fixing seat 1011 is deviated to the right to a second direction D2 or inclined a little to the left a little from first direction D1 From on a third direction D3, with the relative position between calibration light source module 101 and spectroscope 1024, while differentiating and being measured The resolution ratio of the Raman spectrum obtained, when the spectrum signal tool optimum resolution that Raman spectrometer 20 measures, that is, Raman When spectrum is sharp keen clean and interference light source minimum, light source is consolidated after taking screw to pass through the first screw hole 100a and first positioning hole 1012 Reservation 1011 is on pedestal 100.
It please refers to Fig. 1, in another embodiment, in the maintenance process of Raman spectrometer probe 10, can first pass through second The screw of screw hole 10011a and 10011b and corresponding second location hole 1023a and 1023b unclamp, and pass through the first screw hole 100a and the screw of first positioning hole 1012 unclamp, then contain after Raman spectrometer probe 10 and Raman spectrometer 20 are coupled to one There is the sample 30 of test substance to carry out Raman spectrum measurement, sample 30 is placed in face of protective glass 1031, and Raman spectrometer 20 It is connected with a remote computer, set the time of integration appropriate through the software program of remote computer and selects real-time continuous amount Survey mode;Then, using jig clamping spectroscope fixing seat 1023 make spectroscope fixing seat 1023 relative to groove 10011 into Row rotation, the rotation angle of fine tuning spectroscope fixing seat 1023 make the positive normal N of the second mirror surface 10242 of spectroscope 1024 And the beam emissions mouth of light source module 101 towards the angle between I at 44 degree to 46 degree, until Raman spectrometer 20 measures Spectrum signal be maximum;Followed by, using jig clamping light source fixing seat 1011 make light source fixing seat 1011 along first Direction D1 is moved a little, light source fixing seat 1011 is deviated to a little from first direction D1 a not ipsilateral second direction D2 or On one third direction D3, until the spectrum signal that Raman spectrometer 20 measures has optimum resolution;Finally, passing through the second spiral shell The screw locking of hole 10011a and 10011b and corresponding second location hole 1023a and 1023b, and pass through the first screw hole 100a With the screw locking of first positioning hole 1012.
In conclusion popping one's head according to Raman spectrometer described in various embodiments of the utility model, making for optical fiber is eliminated With and change the combination for adopting spectral module, light source module and focus module, and be respectively provided on spectral module and light source module Rotation regulating mechanism and moving adjusting mechanism, so that there is optimal optics coupling between Raman spectrometer probe and Raman spectrometer It closes effect and the optical coupled correction that Raman spectrometer is popped one's head between Raman spectrometer is more easy.Therefore, this is practical Novel proposed Raman spectrometer probe, improves the measurement precision of Raman spectrometer and reduces including Rayleigh scattering light Etc. non-Raman diffused light for spectrometric interference, it is more suitable for scientific research and on-line checking.
The foregoing is merely the utility model preferred embodiments, are not intended to limit the utility model entitlement requests range; Those of ordinary skill in the art should can be illustrated and be implemented, therefore is other without departing from the utility model by above description simultaneously The lower equivalent change or modification completed of revealed spirit, should be included in claim.

Claims (10)

1.一种拉曼光谱仪探头,用以和一拉曼光谱仪耦接,量测一待测物质的拉曼光谱,其特征在于,所述拉曼光谱仪探头包括:1. a Raman spectrometer probe, in order to be coupled with a Raman spectrometer, measure the Raman spectrum of a substance to be measured, it is characterized in that, described Raman spectrometer probe comprises: 一基座,形成一容置空间;a base, forming an accommodating space; 一光源模块,具有一光源固定座和一设置在所述光源固定座上的光源,所述光源固定座具有一光束发射口,所述光源固定座设置在所述基座上位于所述容置空间外且所述光束发射口和包围所述容置空间的一第一侧壁相邻,所述光源固定座于一和所述光束发射口的朝向垂直的第一方向上为可移动的;A light source module, which has a light source holder and a light source arranged on the light source holder, the light source holder has a beam emitting port, and the light source holder is arranged on the base and located in the accommodating Outside the space and the light beam emitting port is adjacent to a first side wall surrounding the accommodating space, the light source fixing seat is movable in a first direction perpendicular to the light beam emitting port; 一聚焦模块,设置在所述容置空间外且和包围所述容置空间的一第二侧壁相邻,所述第二侧壁和所述第一侧壁相对;a focusing module disposed outside the accommodating space and adjacent to a second side wall surrounding the accommodating space, the second side wall being opposite to the first side wall; 一第一聚焦透镜,设置在所述容置空间内且和所述第二侧壁相邻,且和所述聚焦模块耦接;a first focusing lens, disposed in the accommodating space and adjacent to the second side wall, and coupled to the focusing module; 一第二聚焦透镜,设置在所述容置空间内且和包围所述容置空间的一第三侧壁相邻,所述第三侧壁用以和所述拉曼光谱仪耦接;和a second focusing lens disposed in the accommodating space and adjacent to a third sidewall surrounding the accommodating space, the third sidewall being used for coupling with the Raman spectrometer; and 一分光模块,具有一分光镜固定座和一具有两个背对的一第一镜面和一第二镜面的分光镜,所述分光镜立于所述分光镜固定座上,所述分光镜固定座设置在所述容置空间内,所述第一镜面邻近所述第一侧壁且朝向所述光束发射口,所述第二镜面邻近所述第二侧壁且朝向所述第一聚焦透镜,所述第一镜面上镀有抗反射光学膜,所述第二镜面上镀有反射光学膜,所述第二镜面的正向法线和所述光束发射口的朝向之间的夹角为44度至46度,所述分光镜固定座于所述容置空间内为可转动的,所述分光镜固定座的转动轴的轴向和所述光束发射口的朝向垂直且和所述第一方向垂直。A beam splitter module, which has a beam splitter holder and a beam splitter with two back-to-back first mirror surfaces and a second mirror surface, the beam splitter stands on the beam splitter holder, and the beam splitter is fixed The seat is arranged in the accommodating space, the first mirror surface is adjacent to the first side wall and faces the beam emitting port, and the second mirror surface is adjacent to the second side wall and faces the first focusing lens , the first mirror surface is coated with an anti-reflection optical film, the second mirror surface is coated with a reflective optical film, and the angle between the forward normal of the second mirror surface and the orientation of the beam emission port is From 44 degrees to 46 degrees, the beam splitter holder is rotatable in the accommodating space, and the axial direction of the rotation axis of the beam splitter holder is perpendicular to the orientation of the beam emitting port and is the same as that of the first beam. One direction is vertical. 2.根据权利要求1所述的拉曼光谱仪探头,其特征在于,所述光源固定座上形成一第一定位孔,且所述基座上形成对应所述第一定位孔的一第一螺孔,所述第一定位孔于所述第一方向上的孔径大于所述第一螺孔的孔径。2 . The Raman spectrometer probe according to claim 1 , wherein a first positioning hole is formed on the light source holder, and a first screw corresponding to the first positioning hole is formed on the base. 3 . The diameter of the first positioning hole in the first direction is larger than the diameter of the first screw hole. 3.根据权利要求2所述的拉曼光谱仪探头,其特征在于,所述分光镜固定座的周边沿着外缘形成二分别位于所述分光镜固定座的两相对侧的第二定位孔,所述第二定位孔的中心的连线垂直于所述第二镜面的正向法线,且所述基座上形成对应所述第二定位孔的第二螺孔,所述第二定位孔于所述分光镜固定座的转动方向上的孔径大于所述第二螺孔的孔径。3. The Raman spectrometer probe according to claim 2, wherein the periphery of the spectroscope holder forms two second positioning holes located on two opposite sides of the spectroscope holder along the outer edge, The connecting line of the center of the second positioning hole is perpendicular to the normal line of the second mirror surface, and a second screw hole corresponding to the second positioning hole is formed on the base, and the second positioning hole The aperture in the rotation direction of the beam splitter holder is larger than the aperture of the second screw hole. 4.根据权利要求3所述的拉曼光谱仪探头,其特征在于,所述第一定位孔于所述光束发射口的朝向上的孔径等于所述第一螺孔的孔径,或所述第二定位孔于所述分光镜固定座的径向方向上的孔径等于所述第二螺孔的孔径。4 . The Raman spectrometer probe according to claim 3 , wherein the aperture of the first positioning hole in the upward direction of the beam emission port is equal to the aperture of the first screw hole, or the second The diameter of the positioning hole in the radial direction of the beam splitter fixing seat is equal to the diameter of the second screw hole. 5.根据权利要求3所述的拉曼光谱仪探头,其特征在于,所述分光镜固定座的形状是圆盘状且所述第二定位孔的一侧呈内凹。5 . The Raman spectrometer probe according to claim 3 , wherein the shape of the spectroscope holder is a disc shape, and one side of the second positioning hole is concave. 6 . 6.根据权利要求1所述的拉曼光谱仪探头,其特征在于,所述光源固定座可在所述第一方向上向右微幅偏离至一第二方向上或向左微幅偏离至一第三方向上。6 . The Raman spectrometer probe according to claim 1 , wherein the light source holder can be slightly deviated to the right in the first direction to a second direction or slightly deviated to the left to a 6 . third direction. 7.根据权利要求1所述的拉曼光谱仪探头,其特征在于,所述容置空间的底部形成圆形凹槽,所述分光镜固定座设置在所述圆形凹槽内。7 . The Raman spectrometer probe according to claim 1 , wherein a circular groove is formed at the bottom of the accommodating space, and the spectroscope holder is arranged in the circular groove. 8 . 8.根据权利要求1所述的拉曼光谱仪探头,其特征在于,更包括一设置在所述容置空间内且介于所述分光模块和所述第二聚焦透镜之间的滤光片,用以滤除经所述第二镜面反射的瑞利散射光。8 . The Raman spectrometer probe according to claim 1 , further comprising a filter set in the accommodating space and between the spectroscopic module and the second focusing lens, 8 . It is used to filter out the Rayleigh scattered light reflected by the second specular surface. 9.根据权利要求1所述的拉曼光谱仪探头,其特征在于,所述第一聚焦透镜和所述第二聚焦透镜为凸透镜。9 . The Raman spectrometer probe according to claim 1 , wherein the first focusing lens and the second focusing lens are convex lenses. 10 . 10.根据权利要求1所述的拉曼光谱仪探头,其特征在于,所述光源是一雷射光二极管,且所述光源的发光波长是532nm、785nm和1064nm其中之一。10 . The Raman spectrometer probe according to claim 1 , wherein the light source is a laser light diode, and the emission wavelength of the light source is one of 532 nm, 785 nm and 1064 nm. 11 .
CN201821085335.8U 2018-06-14 2018-07-10 Raman spectrometer probe Expired - Fee Related CN208350645U (en)

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CN115468947A (en) * 2022-11-01 2022-12-13 季华实验室 Raman spectrum cage system and Raman spectrum detection method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN115468947A (en) * 2022-11-01 2022-12-13 季华实验室 Raman spectrum cage system and Raman spectrum detection method

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