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CN208156704U - A kind of RFID tag - Google Patents

A kind of RFID tag Download PDF

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Publication number
CN208156704U
CN208156704U CN201820630769.5U CN201820630769U CN208156704U CN 208156704 U CN208156704 U CN 208156704U CN 201820630769 U CN201820630769 U CN 201820630769U CN 208156704 U CN208156704 U CN 208156704U
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Prior art keywords
rfid tag
paper
graphene
antenna
rfid
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CN201820630769.5U
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Chinese (zh)
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刘磊
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Hua Ruimo Shi Danyang Co Ltd
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Hua Ruimo Shi Danyang Co Ltd
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Abstract

A kind of RFID tag, the RFID tag includes paper base material, graphene antenna, conducting resinl, RFID chip, adhesive and ground paper layer, the graphene antenna is arranged on the paper base material, the RFID chip is combined with the graphene antenna by the conducting resinl, and the RFID chip is combined with the ground paper layer by the adhesive.The RFID tag of the application is easy to be torn damage, so as to prevent fake producer from it is taken off and being transferred on counterfeit and shoddy goods from genuine piece, realizes anti-fake purpose.

Description

A kind of RFID tag
Technical field
This application involves but be not limited to technical field of RFID, be more particularly without limitation, to a kind of RFID tag.
Background technique
Radio frequency identification (Radio Frequency Identification, RFID) technology is a kind of contactless automatic Identification technology, the automatic identification of multiple target is realized by radio frequency signal, and obtains Item Information, and identification process can be realized entirely Automation, can operate at a variety of environment.RFID electronic label is mainly used in article mark, anti-fake and certification etc., Middle antiforge function can effectively prevent spreading unchecked for counterfeit and shoddy goods, be particularly suitable for wine, tobacco, cosmetics, food, drug, treasure The fields such as treasured it is anti-fake.But common article tag is usually easily artificially replaced by fake producer, how electronic tag realizes anti-rotation It moves and tamper-evident is very crucial.
Currently used RFID tag generallys use metal antenna, such as the preparation of aluminium, copper, silver.Common preparation method packet Include etching method, ink-jet printing, cross cutting method, thermoprint method, galvanoplastic, electroless plating method, silk screen and gravure printing method etc..Wherein, it loses Lithography has many advantages, such as that at low cost, easy to operate, precision is high, speed of production is fast, but exist pollution is big, waste is serious, carrier by The problem of limit.Meanwhile etching method needs strong acid solution to corrode unprotected metal layer and strong base solution removal protective layer, therefore It need to be using macromolecule membrane as antenna substrate.However, the toughness of polymer base material and metal antenna is stronger, it is difficult to be torn damage, Therefore it needs metal antenna being transferred to paper base material by polymer base material and increases die cut, but this method significantly increases Preparation cost, and the effect is unsatisfactory for anti-transfer.When these electronic tag tear-offs, by being die cut or adhesive is influenced, some Can whole uncover, some only destroy the part of label, still can normal use, anti-fake purpose can not be played.Print process It is common RFID antenna preparation method, directly antenna can be printed on paper base material.Common RFID mode of printing includes Intaglio printing, orifice plate printing and ink jet printing etc..Its aperture plate mode of printing is divided into silk-screen printing and openworking template printing etc. again. But mainly for the preparation of silver-colored antenna and copper antenna, it is low achievable that this is mainly due to the fusing points of nano silver and Nanometer Copper for printing process Low-temperature sintering, but the preparation cost of silver-colored antenna and copper antenna is much higher than aluminum antenna, and copper antenna is easy to oxidize leads to electric conductivity It can decline rapidly.
Utility model content
It is the general introduction to the theme being described in detail herein below.This general introduction is not the protection model in order to limit claim It encloses.
Graphene is a kind of two-dimensional carbon nanomaterial, has the characteristics that corrosion-resistant, good conductivity, high mechanical properties.Stone Black alkene can be divided into two class of graphene film and graphene sheet layer, and wherein graphene film, which is usually used in touch screen and solar battery etc., needs greatly The field of area membrane material, graphene sheet layer is applied than wide, including the fields such as composite material, catalysis, new energy.According to not Graphene sheet layer can be divided into single-layer graphene, few layer graphene (number of plies is less than 10 layers), the graphene microchip (number of plies by stack pile More than 10 layers, thickness is in 3.4-100 nanometer range).Graphene sheet layer can using oxidation-reduction method, the direct stripping method of liquid phase, The preparation of the methods of electrochemical stripping method.Wherein, oxidation-reduction method handles original graphite powder using strong acid and strong oxidizer, then leads to It crosses removing and reduction finally obtains the graphene oxide of reduction.But the material structure and performance for the graphene that oxidation-reduction method obtains All have a certain impact.The direct stripping means of liquid phase removes graphite using physical force in the liquid phase, and obtains structure and property Less graphene sheet layer can be destroyed, therefore conductivity is higher, is suitble to the application in terms of conduction.
This application provides a kind of RFID tag, the RFID tag be easy is torn damage, so as to prevent fake producer by its It takes off and is transferred on counterfeit and shoddy goods from genuine piece, realize anti-fake purpose.
Specifically, this application provides a kind of RFID tag, the RFID tag includes paper base material, graphene antenna, leads Electric glue, RFID chip, adhesive and ground paper layer, the graphene antenna are arranged on the paper base material, the RFID chip with The graphene antenna is combined by the conducting resinl, and the RFID chip is mutually tied with the ground paper layer by the adhesive It closes.
In some embodiments, the raw material for preparing the graphene antenna may include graphene sheet layer, for bonding Polymer and the conductive filler in addition to graphene, by the weight of the graphene antenna be 100% in terms of, the graphene film The weight of layer accounts for 10%~60%, and the weight of the polymer accounts for 20%~70%, the conductive filler in addition to graphene Weight account for 0~40%.
It in some embodiments, is the weight of the graphene sheet layer in terms of 100% by the weight of the graphene antenna 20%~50% can be accounted for, the weight of the polymer can account for 30%~60%, the conductive filler in addition to graphene Weight can account for 5%~30%.
In some embodiments, the graphene sheet layer can handle original graphite or be changed by the direct stripping method of liquid phase Property graphite is prepared.
Optionally, the direct stripping method of the liquid phase can be fluid jet, ball-milling method, sand-blast or shearing method.
In some embodiments, the average thickness of the graphene sheet layer can be with < 20nm, and average transverse can be with ≥10μm。
The thickness and size distribution ranges of the graphene sheet layer obtained due to the direct stripping method of liquid phase are wider, and the application passes through Selection thickness is less than the graphene sheet layer of 20nm, average-size more than or equal to 10 μm and is used to prepare RFID label antenna, realizes The reduction of production cost, and electric conductivity, information receive the performances such as distance and meet requirement.
In some embodiments, the polymer can be selected from natural macromolecular material, synthesis high molecular material and change In property high molecular material any one or more.
Optionally, the polymer can be selected from epoxy resin, phenolic resin, polyester resin, unsaturated polyester resin, have Machine silicone resin, fluorocarbon resin, acrylic resin, acrylate quasi-oligomer and activated monomer, alkyd resin, vinylite, Appointing in synthetic cellulose resin, polyamide, vinyl chloride-vinyl acetate resin, polyurethane resin, polyvinylidene fluoride resin and synthetic rubber Meaning is one or more of.
In some embodiments, the conductive filler in addition to graphene can be selected from carbon black, graphite, carbon nanometer In pipe, carbon fiber, nano silver and Nanometer Copper any one or more.
In some embodiments, the thickness of the graphene antenna can be 5~50 μm, length can for 5mm~ 200mm, width can be 5mm~200mm.
In some embodiments, the paper base material can be in natural fiber paper, synthetic fibre paper and extrusion coating paper Any one or more.
In some embodiments, the conducting resinl can be anisotropy conductiving glue, for example, anisotropy elargol etc..
In some embodiments, the adhesive can appoint in hot melt adhesive, solvent adhesive, emulsion glue and pressure sensitive adhesive Meaning is one or more of.
In some embodiments, the ground paper layer can be in Ge Laxin paper, silicone oil paper, coating paper and leaching membrane paper Any one or more.
The RFID tag of the application can be prepared by the following method:
The raw material for preparing graphene antenna is uniformly mixed with solvent, obtains graphene ink;
The graphene ink is printed on paper base material surface, dries, graphene antenna is obtained, by the graphene antenna Cut into the coiled material of one fixed width;
The conducting resinl on the designated position point of graphene antenna coiled material, by RFID chip package in the designated position;
The RFID antenna of packaged chip is bonded on ground paper layer by adhesive, obtains label coiled material;
By the label coiled material shape by die-cutting, the RFID tag is obtained.
In some embodiments, silk screen print method, openworking template print process or gravure printing method can be used described Graphene ink is printed on paper base material surface.
In some embodiments, the printing equipment used can be porous printing equipment (for example, screen printing apparatus) Or gravure printing apparatus.
In some embodiments, it can be dried by the way of electric heating and/or infrared heating, optionally, be added Hot temperature can be 70~120 DEG C.
The RFID tag of the application can be widely used in the fields such as drinks, tobacco, cosmetics, food, electronic license plate, realize Product back-tracing, positioning, statistics, anti-fake multipurpose.
Meanwhile the RFID tag of the application can also realize real-time tracking, express statistic, the depth encryption of article, trace to the source Purpose, have broad application prospects.
Other features and advantage will illustrate in the following description, also, partly become from specification It obtains it is clear that being understood and implementing the application.The purpose of the application and other advantages can be by specifications, right Specifically noted structure is achieved and obtained in claim and attached drawing.
Detailed description of the invention
Attached drawing is used to provide to further understand technical scheme, and constitutes part of specification, with this The embodiment of application is used to explain the technical solution of the application together, does not constitute the limitation to technical scheme.
Fig. 1 is the schematic diagram of the section structure of the RFID tag of the embodiment of the present application.
Fig. 2 is the schematic shapes of the graphene antenna in the embodiment of the present application 1.
Fig. 3 is the stereoscopic schematic diagram of the RFID tag semi-finished product of the embodiment of the present application 1.
Fig. 4 is the schematic shapes of the graphene antenna in the embodiment of the present application 2.
Fig. 5 is the schematic shapes of the graphene antenna in the embodiment of the present application 3.
Specific embodiment
For the purposes, technical schemes and advantages of the application are more clearly understood, below in conjunction with attached drawing to the application Embodiment be described in detail.It should be noted that in the absence of conflict, in the embodiment and embodiment in the application Feature can mutual any combination.
The embodiment of the present application also provides a kind of RFID tags, as shown in Figure 1, the RFID tag is by paper base material 1, graphite Alkene antenna 2, conducting resinl 3, RFID chip 4, adhesive 5 and ground paper layer 6 are constituted, wherein:The graphene antenna 2 passes through print process It is printed on the paper base material 1, the RFID chip 4 is encapsulated on the graphene antenna 2 by the conducting resinl 3, is encapsulated The graphene antenna of RFID chip is bonded on the ground paper layer 6 by the adhesive 5.
Embodiment 1
The graphene antenna of the RFID tag of the present embodiment includes 40 parts by weight of graphite alkene lamellas, 50 parts by weight of polyurethane trees Rouge and 10 parts by weight of carbon nanotubes.Graphene sheet layer is prepared using the fluid jet in the direct stripping method of liquid phase, and average thickness is 2.5nm, average transverse are 10 μm.
The size of graphene antenna is length × wide=27mm × 15mm, and with a thickness of 15 μm, shape is as shown in Figure 2.
The ground paper layer of the RFID tag of the present embodiment uses Ge Laxin paper, and adhesive uses hot melt adhesive, and conducting resinl is using each Anisotropy elargol, paper base material use natural fiber paper.
The size of RFID tag is length × wide=30mm × 18mm.
The RFID tag of the present embodiment can be prepared by the following method:
Step 1:Graphene sheet layer, polyurethane resin and carbon nanotube are uniformly mixed with solvent, obtain graphene oil Ink;
Step 2:Using silk screen print method, by the graphene ink by having designed in roll-to-roll screen printing apparatus On paper base material surface, and in the electrical drying cabin for being heated to 100 DEG C, drying forms graphene antenna to good graphic printing, benefit The graphene antenna is cut into the coiled material that width is 15mm with cutting machine;
Step 3:Using chip encapsulating device on the designated position point of graphene antenna coiled material anisotropy conductiving glue, Then by RFID chip package in the designated position, Fig. 3 is structural schematic diagram (the RFID mark of the RFID tag semi-finished product after encapsulation Signing semi-finished product includes:Paper base material 1, graphene antenna 2 and RFID chip 4);
Step 4:It is using compounding machine that the RFID antenna and ground paper layer that have encapsulated chip is compound by hot melt adhesive;
Step 5:Using die-cutting machine will be completed step 4 label coiled material carry out shape by die-cutting, obtain RFID tag at Product.
Embodiment 2
The graphene antenna of the RFID tag of the present embodiment includes 30 parts by weight of graphite alkene lamellas, 40 weight of polyester resins With 30 part by weight of carbon black, for graphene sheet layer using the ball-milling method preparation in the direct stripping method of liquid phase, average thickness 14nm is average Lateral dimension is 22 μm.
The size of graphene antenna is length × wide=30mm × 15mm, and with a thickness of 50 μm, shape is as shown in Figure 4.
The ground paper layer of the RFID tag of the present embodiment uses silicone oil paper, and adhesive uses polyurethane adhesive, and conducting resinl is using each Anisotropy elargol, paper base material use synthetic fibre paper.
The size of RFID tag is length × wide=35mm × 20mm.
The RFID tag of the present embodiment can be prepared by the following method:
Step 1:Graphene sheet layer, polyester resin and carbon black are uniformly mixed with solvent, obtain graphene ink;
Step 2:Using gravure printing method, by graphene ink by designed in roll-to-roll gravure printing apparatus Graphic printing forms graphene antenna on paper base material surface, and drying in the drying cabin for being heated to 70 DEG C of infrared heating, Graphene antenna is cut into the coiled material that width is 15mm using cutting machine;
Step 3:Using chip encapsulating device on the designated position point of graphene antenna coiled material anisotropy elargol, so Afterwards by RFID chip package in the designated position;
Step 4:It is using compounding machine that the RFID antenna and ground paper layer that have encapsulated chip is compound by polyurethane adhesive;
Step 5:Using die-cutting machine will be completed step 4 label coiled material carry out shape by die-cutting, obtain RFID tag at Product.
Embodiment 3
The graphene antenna of the RFID tag of the present embodiment includes 50 parts by weight of graphite alkene lamellas, 50 parts by weight vinyl chloride-vinyl acetate resins Particle, graphene are 19 μ using the sand-blast preparation in the direct stripping method of liquid phase, average thickness 18nm, average transverse m。
The size of graphene antenna is length × wide=20mm × 20mm, and with a thickness of 20 μm, shape is as shown in Figure 5.
The ground paper layer of the RFID tag of the present embodiment uses leaching membrane paper, and adhesive uses epoxide-resin glue, and conducting resinl uses Anisotropy elargol, paper base material use extrusion coating paper.
The size of RFID tag is length × wide=30mm × 30mm.
The RFID tag of the present embodiment can be prepared by the following method:
Step 1:Graphene sheet layer, vinyl chloride-vinyl acetate resin are uniformly mixed with solvent, obtain graphene ink;
Step 2:Using openworking template print process, by graphene ink by designed in roll-to-roll printing equipment Graphic printing on paper base material surface, and be heated to 120 DEG C electric heating and infrared heating associated with dry in drying cabin and formed Graphene antenna is cut into the coiled material that width is 20mm using cutting machine by graphene antenna;
Step 3:Using chip encapsulating device on the designated position point of graphene antenna coiled material anisotropy elargol, so Afterwards by RFID chip package in the designated position;
Step 4:It is using compounding machine that the RFID antenna and ground paper layer that have encapsulated chip is compound by epoxide-resin glue;
Step 5:Using die-cutting machine will be completed step 4 label coiled material carry out shape by die-cutting, obtain RFID tag at Product.
Although embodiment disclosed by the application is as above, the content only for ease of understanding the application and use Embodiment is not limited to the application.Technical staff in any the application fields, is taken off not departing from the application Under the premise of the spirit and scope of dew, any modification and variation, but the application can be carried out in the form and details of implementation Scope of patent protection, still should be subject to the scope of the claims as defined in the appended claims.

Claims (6)

1. a kind of RFID tag, the RFID tag include paper base material, graphene antenna, conducting resinl, RFID chip, adhesive and Ground paper layer, the graphene antenna are arranged on the paper base material, and the RFID chip and the graphene antenna are described in Conducting resinl combines, and the RFID chip is combined with the ground paper layer by the adhesive.
2. RFID tag according to claim 1, wherein the graphene antenna with a thickness of 5~50 μm, length is 5mm~200mm, width are 5mm~200mm.
3. RFID tag according to claim 1, wherein the paper base material be selected from natural fiber paper, synthetic fibre paper and In extrusion coating paper any one or more.
4. RFID tag according to claim 1, wherein the conducting resinl is anisotropy conductiving glue.
5. RFID tag according to claim 1, wherein the adhesive is selected from hot melt adhesive, solvent adhesive, emulsion glue and pressure In quick glue any one or more.
6. RFID tag according to claim 1, wherein the ground paper layer be selected from Ge Laxin paper, silicone oil paper, coating paper and In leaching membrane paper any one or more.
CN201820630769.5U 2018-04-28 2018-04-28 A kind of RFID tag Active CN208156704U (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110165366A (en) * 2019-04-22 2019-08-23 浙江大学 A kind of graphene antenna of thermal transfer and its preparation method and application
WO2023099758A1 (en) * 2021-12-03 2023-06-08 Haydale Graphene Industries Plc Rfid

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110165366A (en) * 2019-04-22 2019-08-23 浙江大学 A kind of graphene antenna of thermal transfer and its preparation method and application
WO2023099758A1 (en) * 2021-12-03 2023-06-08 Haydale Graphene Industries Plc Rfid

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