CN207973833U - It is used to prepare the retort of activated carbon fibre - Google Patents
It is used to prepare the retort of activated carbon fibre Download PDFInfo
- Publication number
- CN207973833U CN207973833U CN201820252441.4U CN201820252441U CN207973833U CN 207973833 U CN207973833 U CN 207973833U CN 201820252441 U CN201820252441 U CN 201820252441U CN 207973833 U CN207973833 U CN 207973833U
- Authority
- CN
- China
- Prior art keywords
- retort
- charing
- activated carbon
- carbon fibre
- condenser
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 60
- 239000000835 fiber Substances 0.000 title claims abstract description 34
- 239000002912 waste gas Substances 0.000 claims abstract description 25
- 238000010521 absorption reaction Methods 0.000 claims abstract description 19
- 239000007789 gas Substances 0.000 claims description 35
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000007921 spray Substances 0.000 claims description 15
- 239000006096 absorbing agent Substances 0.000 claims description 14
- 238000012856 packing Methods 0.000 claims description 10
- 241000628997 Flos Species 0.000 claims description 4
- 239000004744 fabric Substances 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 239000003610 charcoal Substances 0.000 claims 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 35
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 17
- 239000008246 gaseous mixture Substances 0.000 abstract description 9
- 238000003763 carbonization Methods 0.000 abstract description 2
- 239000011269 tar Substances 0.000 description 23
- 238000000197 pyrolysis Methods 0.000 description 8
- 238000001816 cooling Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000009833 condensation Methods 0.000 description 4
- 230000005494 condensation Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 229910001220 stainless steel Inorganic materials 0.000 description 4
- 239000010935 stainless steel Substances 0.000 description 4
- 238000009835 boiling Methods 0.000 description 3
- 238000000605 extraction Methods 0.000 description 3
- 230000008676 import Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000000746 purification Methods 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 238000001994 activation Methods 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000007380 fibre production Methods 0.000 description 2
- 239000003546 flue gas Substances 0.000 description 2
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000011148 porous material Substances 0.000 description 2
- 230000002269 spontaneous effect Effects 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 238000004887 air purification Methods 0.000 description 1
- 239000004917 carbon fiber Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011280 coal tar Substances 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Landscapes
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
- Carbon And Carbon Compounds (AREA)
- Inorganic Fibers (AREA)
Abstract
The utility model belongs to carbonization device technical field, more particularly to a kind of retort being used to prepare activated carbon fibre, it is divided into multistage warm area in the charing furnace body, it is formed with charing chamber in each warm area, and it is formed with fireproof heat insulating divider wall between two neighboring charing chamber, the delivery port for being connected to each charing chamber is provided on the fireproof heat insulating divider wall, the both ends of the retort are respectively arranged with entrance and exit, each charing intracavitary be connected to there are one waste gas absorption pipe and an air inlet pipe, multiple waste gas absorption pipes pass through one end of the retort inlet porting and have been sequentially communicated condenser and wind turbine.The utility model retort via condenser after handling, condensable pyrolytic tar makes pyrolytic tar liquefaction discharge, while the nitrogen in gaseous mixture can continue to be used by air inlet pipe feeding charing cavity circulation by condenser output, to reduce nitrogen consumption, stablize charing furnace atmosphere.
Description
Technical field
The utility model belongs to carbonization device technical field more particularly to a kind of charing being used to prepare activated carbon fibre
Stove.
Background technology
The i.e. fibrous activated carbon of activated carbon fibre (ACF), has because it is with big specific surface and developed pore structure
High absorption property, ACF can be the forms such as felt, paper, specially-shaped body, be widely used in air purification, water purification, electronics member device
The directions such as part, catalyst carrier.
Production equipment for activated carbon fibre includes catalyst impregnating mechanism, retort, activation furnace three parts composition.Have
Machine fiber carries out Pintsch process in retort under inert atmosphere, non-carbon components gradually escapes, to obtain high carbon element content
Carbon fibe, and obtain in subsequent activation process high specific surface and flourishing pore structure.
Usual retort is the tunnel-type of both ends open, and organic fiber is driven in stove with ceramic roller, completes entire cracking
Process.Wherein Pintsch process gas complicated components, ingredient is close with coal tar, such as cannot in time be excluded out of retort, it will to
The low-temperature space of retort is spread, and is condensed into liquid therewith, and dropping onto carbon fiber surface keeps Carbon fibe brittle, disconnected to occur
It splits, can not ensure the continuity of production.
Exhaust outlet mostly is opened up in the side of retort or top under normal circumstances, and with mixed in air-introduced machine extraction retort
Close gas, and keep being continually fed into for high pure nitrogen, to maintain the positive pressure environment in stove, will not outside air enter in stove and cause
Organic fiber spontaneous combustion.The gaseous mixture of air-introduced machine discharge is the gaseous mixture of nitrogen and high temperature pyrolysis gas, is given up through mating as exhaust gas
It is discharged after gas processing system.
Nitrogen gas generating system continue working is needed under the production model, to ensure enough nitrogen supply (NS)s, in addition low temperature nitrogen into
Entering the temperature fluctuation that can be caused after retort in retort, required electrical heating radiant tube works under high-output power for a long time,
The lost of life.The exhaust-gas treatment difficulty of low oxygen content is larger, easily causes environmental pollution.In addition the absorbing quantity fluctuation of waste discharge blower fan
Or the supply variation of protection gas be easy to cause the raising of retort internal oxygen content, leads to raw material spontaneous combustion.
Utility model content
The utility model for the above technical issues, proposes a kind of retort being used to prepare activated carbon fibre.
In order to achieve the above object, the technical solution adopted in the utility model is:
A kind of retort being used to prepare activated carbon fibre, including furnace body is carbonized, it is divided into the charing furnace body more
Grade warm area is each formed with charing chamber in the warm area, and is formed with fireproof heat insulating divider wall, institute between two neighboring charing chamber
The delivery port being provided on fireproof heat insulating divider wall for being connected to each charing chamber is stated, the both ends of the retort are set respectively
It is equipped with entrance and exit, is increased successively by the temperature of entrance to multiple warm areas of outlet, each charing intracavitary is communicated with
One waste gas absorption pipe and an air inlet pipe, multiple waste gas absorption pipes pass through the retort inlet porting one end and according to
Secondary to be communicated with condenser and wind turbine, the output end of the wind turbine is connected with the inlet end of multiple air inlet pipe, multiple described
The outlet side of air inlet pipe is connected with the corresponding charing chamber.
The waste gas absorption pipe is by, through being purified by condenser, exhaust gas is nitrogen after the exhaust gas extraction of each charing intracavitary
With the gaseous mixture of high temperature pyrolysis gas, wherein high temperature pyrolysis gas are containing tar flue gas.Due to tar in activated carbon fibre production process
Main component is water, accounts for 85% of tar component or more, and in addition there are including acid, alcohol, ester, aldehyde, phenol, aromatic hydrocarbon
More than 200 plant component, so the primary and foremost purpose of tar purifying equipment is the purification of water vapour.Therefore after being handled via condenser,
Condensable pyrolytic tar, make pyrolytic tar liquefaction discharge, while the nitrogen in gaseous mixture can continue by condenser output by into
Tracheae is sent into charing cavity circulation and is used, and to reduce nitrogen consumption, stablizes charing furnace atmosphere.The wherein described waste gas absorption pipe and
Air inlet pipe is stainless steel screwed tube or stainless steel tube.
The exhaust gas generated in each warm area is cold through the feeding recirculated water cooling condenser progress of low temperature warm area by waste gas absorption pipe
Solidifying, higher boiling pyrolysis gas is in a liquid state tar after cooling, imports storage tank and is collected.Condensed exhaust gas is sent again through wind turbine
Enter into retort.
As preferred:The air inlet pipe is passed through by one end of retort inlet porting and stretches to each charing intracavitary.
As preferred:The bottom of the condenser is provided with pyrolytic tar floss hole.Condensation is provided on the condenser
Water out and condensation water inlet.
As preferred:It is described charing intracavitary by entrance to outlet direction be arranged in order be provided with it is multiple for convey it is organic
The live-roller of fiber, the live-roller and the delivery port are respectively positioned on same straight line, in order to by the organic fiber by entering
Mouth is inputted and is exported by outlet after passing sequentially through multiple delivery ports.
As preferred:The quantity of the condenser is multiple, and is in series between multiple condensers.
As preferred:The air inlet of the waste gas absorption pipe and the gas outlet of the air inlet pipe are in rake cloth wind structure.
As preferred:It is connected with spray absorber between the condenser and wind turbine.
As preferred:Packing layer and nozzle are provided in the spray absorber, the nozzle is located at the top of packing layer,
The nozzle is communicated with water tank by circulating pump, be provided on the spray absorber between the nozzle and packing layer exhaust gas into
Mouthful, waste gas outlet, the exhaust gas inlet and the condenser are provided on the spray absorber below described filler layer
Output end is connected, and the waste gas outlet is connect with the wind turbine.
Compared with prior art, it is with advantageous effect the advantages of the utility model:
1, the retort provided by the utility model for being used to prepare activated carbon fibre can be cold after being handled via condenser
Solidifying pyrolytic tar makes pyrolytic tar liquefaction discharge, while the nitrogen in gaseous mixture can continue to pass through air inlet pipe by condenser output
It is sent into charing cavity circulation to use, to reduce nitrogen consumption, stablizes charing furnace atmosphere.
2, the retort provided by the utility model for being used to prepare activated carbon fibre solves environmental issue from discharge source,
And tar byproduct can be obtained.
3, the retort provided by the utility model for being used to prepare activated carbon fibre leads to the exhaust gas generated in each warm area
It crosses waste gas absorption pipe and is sent into recirculated water cooling condenser through low temperature warm area and condensed, higher boiling pyrolysis gas is in a liquid state coke after cooling
Oil imports storage tank and is collected, energy saving.
4, the retort provided by the utility model for being used to prepare activated carbon fibre makes in retort there are circulated air, to promote
Make uniformity of temperature profile in each warm area.
Description of the drawings
Fig. 1 is a kind of structural schematic diagram of the embodiment for the retort that the utility model is used to prepare activated carbon fibre;
Fig. 2 is the structural representation of the another embodiment for the retort that the utility model is used to prepare activated carbon fibre
Figure;
In above each figure:1, furnace body is carbonized;2, chamber is carbonized;3, fireproof heat insulating divider wall;4, delivery port;5, entrance;6、
Outlet;7, waste gas absorption pipe;8, air inlet pipe;9, wind turbine;10, condenser;101, condensation-water drain;102, water inlet is condensed;11、
Pyrolytic tar floss hole;12, live-roller;13, spray absorber;14, packing layer;15, nozzle;16, water tank;17, exhaust gas inlet;
18, waste gas outlet;19, circulating pump.
Specific implementation mode
In the following, the utility model is specifically described by illustrative embodiment.It should be appreciated, however, that not having
In the case of being further discussed below, element, structure and features in an embodiment can also be advantageously incorporated into other implementations
In mode.
Embodiment:As shown in Figure 1, a kind of retort being used to prepare activated carbon fibre, including charing furnace body 1, it is described
It is divided into multistage warm area in charing furnace body 1, charing chamber 2, and shape between two neighboring charing chamber 2 is formed in each warm area
At there is fireproof heat insulating divider wall 3, the conveying for being connected to each charing chamber 2 is provided on the fireproof heat insulating divider wall 3
Mouthfuls 4, the both ends of the retort are respectively arranged with entrance 5 and outlet 6, by entrance 5 to multiple warm areas of outlet 6 temperature successively
It increases, there are one waste gas absorption pipe 7 and an air inlet pipe 8, multiple waste gas absorption pipes for connection in each charing chamber 2
7 pass through the retort inlet porting 5 one end and be sequentially communicated condenser 10 and wind turbine 9, the output end of the wind turbine 9 with
The inlet end of multiple air inlet pipe 8 is connected, and the outlet side of multiple air inlet pipe 8 is connected with the corresponding charing chamber 2
It is logical.
In the description of the present invention, it should be noted that term "inner", "outside", "upper", "lower", "front", "rear" etc.
The orientation or positional relationship of instruction is position relationship based on ... shown in the drawings, is merely for convenience of description the utility model and simplification
Description, does not indicate or imply the indicated device or element must have a particular orientation, with specific azimuth configuration and behaviour
Make, therefore should not be understood as limiting the present invention.In addition, term " first ", " second ", " third " are only used for description mesh
, it is not understood to indicate or imply relative importance.
Further as shown in Figure 1:The air inlet pipe 8 is passed through by one end of retort inlet porting 5 and stretches to each charing
In chamber 2.The bottom of the condenser 10 is provided with pyrolytic tar floss hole 11.It is provided with condensation-water drain on the condenser 10
101 and condensation water inlet 102.Be arranged in order by the direction of entrance 5 to outlet 6 in the charing chamber 2 be provided with it is multiple for defeated
The live-roller 12 of organic fiber is sent, the live-roller 12 is respectively positioned on the delivery port 4 on same straight line, in order to have described
Machine fiber is inputted by entrance 5 and is passed sequentially through after multiple delivery ports 4 by 6 output of outlet.The quantity of the condenser 10 be it is multiple,
And it is in series between multiple condensers 10.The air inlet of the waste gas absorption pipe 7 and the gas outlet of the air inlet pipe 8 are in rake
Cloth wind structure.
Further as shown in Figure 2:Spray absorber 13 is connected between the condenser 10 and wind turbine 9.The spray is inhaled
It receives in tower 13 and is provided with packing layer 14 and nozzle 15, the nozzle 15 is located at the top of packing layer 14, and the nozzle 15 is by following
Ring pump 19 is communicated with water tank 16, and exhaust gas inlet 17 is provided on the spray absorber 13 between the nozzle 15 and packing layer 14,
Waste gas outlet 18, the exhaust gas inlet 17 and the condensation are provided on the spray absorber 13 of 14 lower section of described filler layer
The output end of device is connected, and the waste gas outlet 18 is connect with the wind turbine 9.
The use principle of the retort provided by the utility model for being used to prepare activated carbon fibre:
The waste gas absorption pipe 7 is by, through being purified by condenser 10, exhaust gas is after the exhaust gas extraction in each charing chamber 2
The gaseous mixture of nitrogen and high temperature pyrolysis gas, wherein high temperature pyrolysis gas are containing tar flue gas.Due in activated carbon fibre production process
Tar main component is water, accounts for 85% of tar component or more, in addition there are including acid, alcohol, ester, aldehyde, phenol, aromatic hydrocarbon
More than 200 plant component, so the primary and foremost purpose of tar purifying equipment is the purification of water vapour.Therefore it is handled via condenser 10
Afterwards, condensable pyrolytic tar makes pyrolytic tar liquefaction discharge, while the nitrogen in gaseous mixture can continue to be led to by the output of condenser 10
It crosses air inlet pipe 8 and is sent into recycling in charing chamber 2, to reduce nitrogen consumption, stablize charing furnace atmosphere.The wherein described exhaust gas is inhaled
Closed tube 7 and air inlet pipe 8 are stainless steel screwed tube or stainless steel tube.The exhaust gas generated in each warm area is passed through into waste gas absorption
Pipe 7 is sent into recirculated water cooling condenser 10 through low temperature warm area and is condensed, and higher boiling pyrolysis gas is in a liquid state tar after cooling, imports
Storage tank is collected.Condensed exhaust gas is again fed to through wind turbine 9 in retort.
Such as between wind turbine 9 and condenser 10 be arranged spray absorber 13, then exhaust gas under the action of wind turbine according to above-mentioned
It after step is handled via condenser 10, handles via spray absorber 13, conveys remaining nitrogen after removing residual organic substances
Return charing intracavitary.
The retort provided by the utility model for being used to prepare activated carbon fibre can be cold after being handled via condenser 10
Solidifying pyrolytic tar makes pyrolytic tar liquefaction discharge, while the nitrogen in gaseous mixture can continue to pass through air inlet by the output of condenser 10
Pipe 8 is sent into charing chamber 2 and is recycled, and to reduce nitrogen consumption, stablizes charing furnace atmosphere, energy saving.From discharge source
Environmental issue is solved, and tar byproduct can be obtained.
Claims (8)
1. a kind of retort being used to prepare activated carbon fibre, including charing furnace body, it is characterised in that:The charing furnace body
Inside it is divided into multistage warm area, is formed with charing chamber in each warm area, and fireproof heat insulating is formed between two neighboring charing chamber
Divider wall is provided with the delivery port for being connected to each charing chamber on the fireproof heat insulating divider wall, the retort
Both ends are respectively arranged with entrance and exit, are increased successively by the temperature of entrance to multiple warm areas of outlet, each charing chamber
Inside there are one waste gas absorption pipe and an air inlet pipe, multiple waste gas absorption pipes to pass through the retort inlet porting for connection
One end and be sequentially communicated condenser and wind turbine, the output end of the wind turbine is connected with the inlet end of multiple air inlet pipe
Logical, the outlet side of multiple air inlet pipe is connected with the corresponding charing chamber.
2. the retort according to claim 1 for being used to prepare activated carbon fibre, it is characterised in that:The air inlet pipe is by charcoal
The one end for changing stove inlet porting passes through and stretches to each charing intracavitary.
3. the retort according to claim 1 for being used to prepare activated carbon fibre, it is characterised in that:The bottom of the condenser
Portion is provided with pyrolytic tar floss hole.
4. the retort according to claim 1 for being used to prepare activated carbon fibre, it is characterised in that:The charing intracavitary by
The direction of entrance to outlet be arranged in order is provided with it is multiple for conveying the live-rollers of organic fiber, the live-roller with it is described defeated
Mouth is sent to be respectively positioned on same straight line, in order to be inputted and passed sequentially through after multiple delivery ports by going out by entrance by the organic fiber
Mouth output.
5. the retort according to claim 1 for being used to prepare activated carbon fibre, it is characterised in that:The number of the condenser
Amount is multiple, and is in series between multiple condensers.
6. the retort according to claim 1 for being used to prepare activated carbon fibre, it is characterised in that:The waste gas absorption pipe
Air inlet and the air inlet pipe gas outlet be in rake cloth wind structure.
7. requiring the retort that 1~6 any one of them is used to prepare activated carbon fibre according to right, it is characterised in that:Institute
It states and is connected with spray absorber between condenser and wind turbine.
8. the retort according to claim 7 for being used to prepare activated carbon fibre, it is characterised in that:The spray absorber
It is inside provided with packing layer and nozzle, the nozzle is located at the top of packing layer, and the nozzle is communicated with water tank by circulating pump, institute
It states and is provided with exhaust gas inlet on the spray absorber between nozzle and packing layer, the spray absorber being located at below described filler layer
On be provided with waste gas outlet, the exhaust gas inlet is connected with the output end of the condenser, the waste gas outlet and the wind
Machine connects.
Priority Applications (1)
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CN201820252441.4U CN207973833U (en) | 2018-02-11 | 2018-02-11 | It is used to prepare the retort of activated carbon fibre |
Applications Claiming Priority (1)
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CN201820252441.4U CN207973833U (en) | 2018-02-11 | 2018-02-11 | It is used to prepare the retort of activated carbon fibre |
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Publication Number | Publication Date |
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ID=63767667
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112760753A (en) * | 2021-01-18 | 2021-05-07 | 荣成碳纤维科技有限公司 | Vertical low-temperature carbonization furnace and production process thereof |
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2018
- 2018-02-11 CN CN201820252441.4U patent/CN207973833U/en active Active
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112760753A (en) * | 2021-01-18 | 2021-05-07 | 荣成碳纤维科技有限公司 | Vertical low-temperature carbonization furnace and production process thereof |
CN112760753B (en) * | 2021-01-18 | 2023-01-17 | 荣成碳纤维科技有限公司 | Vertical low-temperature carbonization furnace and production process thereof |
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