CN206996259U - A kind of spuious flue gas during smelting wet dedusting of atm number, desulphurization system - Google Patents
A kind of spuious flue gas during smelting wet dedusting of atm number, desulphurization system Download PDFInfo
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Abstract
本实用新型公开了一种大气量杂散冶炼烟气湿法除尘、脱硫系统。脱硫剂以氧化镁吸收为主,氢氧化钠为辅,根据烟气二氧化硫浓度及时对氢氧化钠加入量进行调节;脱硫吸收塔采用“吸收‑除尘‑除雾‑排空”一体化结构;脱硫吸收塔入口安装高温烟气降温装置;在脱硫吸收塔底部增加侧向搅拌装置和曝气氧化装置,可有效的使吸收塔内微溶的亚硫酸镁充分转化成易溶的硫酸镁,避免了烟尘、氧化镁杂质等不溶物的沉积。通过对脱硫液采用压滤的方式可实现不溶物与硫酸镁溶液的分离。处理成本低,效果显著。可满足复杂冶炼烟气高温时段、大气量、高浓度二氧化硫排放等特殊时段烟气的处理。
The utility model discloses a large-volume stray smelting flue gas wet dust removal and desulfurization system. The desulfurization agent is mainly absorbed by magnesium oxide, supplemented by sodium hydroxide, and the amount of sodium hydroxide added is adjusted in time according to the concentration of sulfur dioxide in the flue gas; the desulfurization absorption tower adopts an integrated structure of "absorption-dust removal-mist removal-evacuation"; Install a high-temperature flue gas cooling device at the entrance of the absorption tower; add a side stirring device and an aeration oxidation device at the bottom of the desulfurization absorption tower, which can effectively convert the slightly soluble magnesium sulfite in the absorption tower into easily soluble magnesium sulfate, avoiding the Deposition of insoluble matter such as soot and magnesium oxide impurities. The separation of insoluble matter and magnesium sulfate solution can be realized by adopting pressure filtration to the desulfurization liquid. The treatment cost is low and the effect is remarkable. It can meet the treatment of flue gas in special periods such as complex smelting flue gas high temperature period, atmospheric volume, high concentration sulfur dioxide emission, etc.
Description
技术领域technical field
本实用新型属于属于冶炼、化工领域,涉及一种一种大气量杂散冶炼烟气湿法除尘、脱硫系统。The utility model belongs to the fields of smelting and chemical industry, and relates to a system for wet dust removal and desulfurization of stray smelting flue gas with large volume.
背景技术Background technique
在冶炼过程中,常常会产生大量含SO2的低浓度冶炼杂散烟气,主要包括各炉窑生产过程中,厂房内逸散收集烟气、检修保温烟气、进、出料外逸烟气、低浓度高温冶炼烟气等。其特点是气量大、以低浓度SO2为主存在高浓时段、以低温为主存在高温时段(正常烟气温度约为40-55℃,特殊情况高达280℃),且烟气中还伴大量、多种有毒、有害重金属物质。按新环保法的规定,此类烟气必须全时段达标排放、所产废水必须达标处理。During the smelting process, a large amount of low-concentration smelting stray flue gas containing SO 2 is often produced, mainly including flue gas collected in the factory building during the production process of each kiln, flue gas from maintenance and heat preservation, and flue gas from entering and exiting materials. gas, low-concentration high-temperature smelting flue gas, etc. It is characterized by large gas volume, high-concentration periods dominated by low - concentration SO2, and high-temperature periods dominated by low temperatures (normal flue gas temperature is about 40-55°C, and in special cases as high as 280°C), and the flue gas is accompanied by A large number and variety of toxic and harmful heavy metal substances. According to the provisions of the new environmental protection law, this kind of flue gas must be discharged up to the standard all the time, and the waste water produced must be treated up to the standard.
传统采用分段治理的方法进行处理,先将复杂烟气进行湿法洗涤预处理,去除烟气所带的烟尘,降低温度,再对净化后烟气脱硫、除雾,排空。此法效果明显,但工艺过程复杂,设备投资和运行费过高,经济性欠佳,而且还产生大量酸性废水,处理成本较高。Traditionally, the method of segmented treatment is used for treatment. First, the complex flue gas is subjected to wet scrubbing pretreatment to remove the smoke and dust carried by the flue gas, lower the temperature, and then desulfurize, defog and empty the purified flue gas. This method has obvious effects, but the process is complicated, the equipment investment and operating costs are too high, the economy is not good, and a large amount of acidic wastewater is produced, and the treatment cost is high.
实用新型内容Utility model content
本实用新型目的是针对传统工艺存在的不足,结合大气量、复杂低浓度冶炼烟气的特点,提供一种用氧化镁作为脱硫剂的低成本处理复杂冶炼烟气的“吸收-除尘-除雾-排空”一体化、全时段达标治理系统。The purpose of this utility model is to aim at the deficiencies of the traditional process, combined with the characteristics of large volume, complex and low-concentration smelting flue gas, to provide a low-cost "absorption-dust-removal-mist removal" that uses magnesium oxide as a desulfurizer to process complex smelting flue gas -Emptying" integrated, full-time compliance management system.
本实用新型的技术方案是:一种大气量杂散冶炼烟气湿法除尘、脱硫系统,该系统设备包括:脱硫吸收塔、烟气输送风机、除雾器、湿式电除尘器、多层喷淋装置、均流提效塔盘、空气喷枪、侧向搅拌装置、喷淋层控制阀、入口SO2浓度检测仪、出口SO2浓度检测仪、吸收塔循环泵、氧化风机、氢氧化钠自控调节阀、氢氧化钠储罐、氢氧化镁浆液泵、氢氧化镁浆液槽、氧化镁熟化泵、氧化镁熟化槽、脱硫液储存池、压滤机、脱硫液压滤泵、烟囱、氢氧化镁浆液喷淋装置;脱硫吸收塔入口烟道前端设置烟气输送风机,脱硫吸收塔塔体中下部烟气进口处安装氢氧化镁浆液喷淋装置,烟气进气管上安装入口SO2浓度检测仪,氢氧化钠储罐通过泵、管道连通入脱硫吸收塔下部且连通的管道上设有氢氧化钠自控调节阀,出口SO2浓度检测仪设在烟囱内,入口SO2浓度检测仪和出口SO2浓度检测仪分别与氢氧化钠自控调节阀信号联锁;所述脱硫吸收塔塔体内部自上而下分别设置除雾器、多层喷淋装置、均流提效塔盘;所述脱硫吸收塔塔体内部的除雾器上方设置湿式电除尘器,湿式电除尘器上方为烟囱;所述脱硫吸收塔底部设置氧化曝气装置,所述氧化曝气装置包括氧化风机、空气喷枪、曝气空气主管、曝气空气支管,曝气空气主管置于塔内浆液层中部,一端与氧化风机连接,另一端通过曝气氧化支管与空气喷枪连接,所述脱硫吸收塔底部还设置侧向搅拌装置;氧化镁熟化槽通过管道与氧化镁熟化泵连接,所述氧化镁熟化泵出口连至氢氧化镁浆液槽,氢氧化镁浆液槽通过氢氧化镁浆液泵为烟气入口处氢氧化镁浆液喷淋装置供液和脱硫吸收塔补充氢氧化镁浆液且为脱硫吸收塔补充氢氧化镁浆液的管道上设有阀;位于脱硫吸收塔底部的吸收塔循环泵出口,分出两个支路,一路连至多层喷淋装置,每层分别由喷淋层控制阀进行调节控制,另一路连至脱硫液储存池且连接管路上设阀;所述脱硫液储存池经脱硫液压滤泵与压滤机连接。The technical scheme of the utility model is: a large amount of stray smelting flue gas wet dust removal and desulfurization system, the system equipment includes: desulfurization absorption tower, flue gas conveying fan, mist eliminator, wet electrostatic precipitator, multi-layer Shower device, flow equalization efficiency tray, air spray gun, side stirring device, spray layer control valve, inlet SO2 concentration detector, outlet SO2 concentration detector, absorption tower circulation pump, oxidation fan, sodium hydroxide automatic control Regulating valve, sodium hydroxide storage tank, magnesium hydroxide slurry pump, magnesium hydroxide slurry tank, magnesium oxide aging pump, magnesium oxide aging tank, desulfurization liquid storage tank, filter press, desulfurization hydraulic filter pump, chimney, magnesium hydroxide Slurry spraying device; the flue gas conveying fan is installed at the front end of the inlet flue of the desulfurization absorption tower, the magnesium hydroxide slurry spraying device is installed at the flue gas inlet of the middle and lower part of the desulfurization absorption tower body, and the inlet SO 2 concentration detector is installed on the flue gas inlet pipe The sodium hydroxide storage tank is connected to the lower part of the desulfurization absorption tower through pumps and pipelines, and the connected pipeline is equipped with a sodium hydroxide self - control regulating valve. The outlet SO2 concentration detector is set in the chimney, the inlet SO2 concentration detector and the outlet SO2 concentration detector. 2 The concentration detectors are respectively interlocked with the signals of the sodium hydroxide self-control regulating valve; the inside of the desulfurization absorption tower is equipped with a demister, a multi-layer spray device, and a flow-equalizing efficiency tray from top to bottom; the desulfurization A wet electrostatic precipitator is installed above the mist eliminator inside the absorption tower body, and a chimney is arranged above the wet electrostatic precipitator; an oxidation aeration device is installed at the bottom of the desulfurization absorption tower, and the oxidation aeration device includes an oxidation fan, an air spray gun, an aeration Air main pipe, aeration air branch pipe, the aeration air main pipe is placed in the middle of the slurry layer in the tower, one end is connected to the oxidation fan, and the other end is connected to the air spray gun through the aeration oxidation branch pipe, and the bottom of the desulfurization absorption tower is also equipped with lateral stirring Device; the magnesium oxide aging tank is connected to the magnesium oxide aging pump through a pipeline, and the outlet of the magnesium oxide aging pump is connected to the magnesium hydroxide slurry tank, and the magnesium hydroxide slurry tank is the magnesium hydroxide slurry at the flue gas inlet through the magnesium hydroxide slurry pump. There is a valve on the pipeline for supplying liquid to the spraying device and replenishing magnesium hydroxide slurry for the desulfurization absorption tower and replenishing magnesium hydroxide slurry for the desulfurization absorption tower; the outlet of the circulation pump of the absorption tower located at the bottom of the desulfurization absorption tower is divided into two branches, One way is connected to the multi-layer spraying device, each layer is adjusted and controlled by the spray layer control valve, and the other way is connected to the desulfurization liquid storage tank with a valve on the connecting pipeline; the desulfurization liquid storage tank is passed through the desulfurization hydraulic filter pump and pressure filter. machine connection.
优选的,所述多层喷淋装置有三层。Preferably, the multi-layer spraying device has three layers.
优选的,所述氧化曝气装置设置三套,空气喷枪在同一圆周上相隔120度布置。Preferably, there are three sets of oxidation aeration devices, and the air spray guns are arranged on the same circumference at intervals of 120 degrees.
优选的,所述侧向搅拌装置设置三套,搅拌叶位于空气喷枪下方。Preferably, there are three sets of lateral stirring devices, and the stirring blades are located below the air spray gun.
本实用新型的技术效果是:本系统所采用的脱硫剂以氢氧化镁吸收为主,氢氧化钠为辅,根据烟气SO2浓度及时对氢氧化钠加入量进行调节;所采用的脱硫吸收塔采用“吸收-除尘-除雾-排空”一体化结构,有效的将烟气中SO2吸收、除尘、除雾、排空等功能集于一体,缩短工艺流程,减少一次投资;脱硫吸收塔入口安装高温烟气降温装置,增加了对间断性高温冶炼烟气的适应性;在脱硫吸收塔底部增加侧向搅拌装置和曝气氧化装置,可有效的使吸收塔内微溶的亚硫酸镁充分转化成易溶的硫酸镁,避免了烟尘、氧化镁杂质等不溶物的沉积。通过对脱硫液采用压滤的方式可实现不溶物与硫酸镁溶液的分离,硫酸镁清液可用作硫酸系统补水或硫酸镁产品的生产。The technical effect of the utility model is: the desulfurization agent used in this system is mainly absorbed by magnesium hydroxide, supplemented by sodium hydroxide, and the amount of sodium hydroxide added is adjusted in time according to the concentration of SO2 in the flue gas ; The tower adopts an integrated structure of "absorption-dust removal-fog removal - evacuation", which effectively integrates the functions of SO2 absorption, dust removal, fog removal, and emptying in the flue gas, shortens the process flow, and reduces one-time investment; desulfurization absorption A high-temperature flue gas cooling device is installed at the entrance of the tower, which increases the adaptability to intermittent high-temperature smelting flue gas; a side stirring device and an aeration oxidation device are added at the bottom of the desulfurization absorption tower, which can effectively make the slightly soluble sulfurous acid in the absorption tower Magnesium is fully converted into easily soluble magnesium sulfate, avoiding the deposition of insoluble matter such as soot and magnesium oxide impurities. The separation of insoluble matter and magnesium sulfate solution can be realized by adopting pressure filtration to the desulfurization liquid, and the magnesium sulfate clear liquid can be used for replenishment of sulfuric acid system or production of magnesium sulfate products.
本系统使用氢氧化镁做为脱硫剂,全时段达标治理方法处理复杂冶炼烟气,处理成本低,效果显著。可满足复杂冶炼烟气高温时段、大气量、高浓度SO2排放等特殊时段烟气的处理,可有效分离出脱硫液中的有毒、有害重金属和氧化镁中的不溶物,回收硫酸镁清液可用作硫酸系统补水或硫酸镁产品的生产,经济效益、环境效益显著。This system uses magnesium hydroxide as a desulfurizer, and the full-time standard treatment method handles complex smelting flue gas, with low treatment cost and remarkable effect. It can meet the complex smelting flue gas high-temperature period, atmospheric volume, high-concentration SO2 emission and other special period flue gas treatment. It can effectively separate toxic and harmful heavy metals in desulfurization liquid and insoluble substances in magnesium oxide. Recovery of magnesium sulfate clear liquid can be It is used for supplementing water in sulfuric acid system or producing magnesium sulfate products, which has remarkable economic and environmental benefits.
附图说明Description of drawings
图1为本发明的设备组成及流程图;Fig. 1 is equipment composition and flow chart of the present invention;
图中,1—脱硫吸收塔;2—烟气输送风机;3—除雾器;4—湿式电除尘器;5—多层喷淋装置; 6—均流提效塔盘;7—空气喷枪;8—侧向搅拌装置;9—喷淋层控制阀;10—入口SO2浓度检测仪;11—出口SO2浓度检测仪;12—吸收塔循环泵;13—氧化风机;14—氢氧化钠自控调节阀;15—氢氧化钠储罐;16—氢氧化镁浆液泵;17—氢氧化镁浆液槽;18—氧化镁熟化泵;19—氧化镁熟化槽;20—脱硫液储存池;21—压滤机;22—脱硫液压滤泵;23—烟囱;24—氢氧化镁浆液喷淋装置。In the figure, 1—desulfurization absorption tower; 2—flue gas conveying fan; 3—mist eliminator; 4—wet electrostatic precipitator; 5—multi-layer spraying device; ; 8—side stirring device; 9—spray layer control valve; 10—inlet SO 2 concentration detector; 11—outlet SO 2 concentration detector; 12—absorption tower circulation pump; 13—oxidation fan; 14—hydrogen oxidation Sodium self-control regulating valve; 15—sodium hydroxide storage tank; 16—magnesium hydroxide slurry pump; 17—magnesium hydroxide slurry tank; 18—magnesia aging pump; 19—magnesia aging tank; 20—desulfurization liquid storage tank; 21—filter press; 22—hydraulic filter pump for desulfurization; 23—chimney; 24—magnesium hydroxide slurry spraying device.
具体实施方式detailed description
结合附图说明对本发明的技术方案做进一步说明。The technical solution of the present invention will be further described in conjunction with the accompanying drawings.
如图所示,一种大气量杂散冶炼烟气湿法除尘、脱硫系统,其处理过程设置的设备包括:脱硫吸收塔1、烟气输送风机2、除雾器3、湿式电除尘器4、多层喷淋装置5、均流提效塔盘6、空气喷枪7、侧向搅拌装置8、喷淋层控制阀9、入口SO2浓度检测仪10、出口SO2浓度检测仪11、吸收塔循环泵12、氧化风机13、氢氧化钠自控调节阀14、氢氧化钠储罐15、氢氧化镁浆液泵16、氢氧化镁浆液槽17、氧化镁熟化泵18、氧化镁熟化槽19、脱硫液储存池20、压滤机21、脱硫液压滤泵22、烟囱23、氢氧化镁浆液喷淋装置24;脱硫吸收塔1入口烟道前端设置烟气输送风机2,脱硫吸收塔1塔体中下部烟气进口处安装氢氧化镁浆液喷淋装置24,烟气进气管上安装入口SO2浓度检测仪10,氢氧化钠储罐15通过泵、管道连通入脱硫吸收塔1下部且连通的管道上设有氢氧化钠自控调节阀14,出口SO2浓度检测仪11设在烟囱23内,入口SO2浓度检测仪10和出口SO2浓度检测仪11分别与氢氧化钠自控调节阀14信号联锁;所述脱硫吸收塔1塔体内部自上而下分别设置除雾器3、多层喷淋装置5、均流提效塔盘6;所述脱硫吸收塔1塔体内部的除雾器3上方设置湿式电除尘器4,湿式电除尘器上方为烟囱23;所述脱硫吸收塔1底部设置氧化曝气装置,所述氧化曝气装置包括氧化风机13、空气喷枪7、曝气空气主管、曝气空气支管,曝气空气主管置于塔内浆液层中部,一端与氧化风机13连接,另一端通过曝气氧化支管与空气喷枪7连接,所述脱硫吸收塔1底部还设置侧向搅拌装置8;氧化镁熟化槽19通过管道与氧化镁熟化泵18连接,所述氧化镁熟化泵18出口连至氢氧化镁浆液槽17,氢氧化镁浆液槽17通过氢氧化镁浆液泵16为烟气入口处氢氧化镁浆液喷淋装置24供液和脱硫吸收塔1补充氢氧化镁浆液且为脱硫吸收塔1补充氢氧化镁浆液的管道上设有阀25;位于脱硫吸收塔1底部的吸收塔循环泵12出口,分出两个支路,一路连至多层喷淋装置5,每层分别由喷淋层控制阀9进行调节控制,另一路连至脱硫液储存池20且连接管路上设阀;所述脱硫液储存池20经脱硫液压滤泵22与压滤机21连接。As shown in the figure, a large amount of stray smelting flue gas wet dedusting and desulfurization system, the equipment set up in the processing process includes: desulfurization absorption tower 1, flue gas conveying fan 2, mist eliminator 3, wet electrostatic precipitator 4 , multi-layer spray device 5, flow equalization and efficiency improvement tray 6, air spray gun 7, side stirring device 8, spray layer control valve 9 , inlet SO2 concentration detector 10, outlet SO2 concentration detector 11 , absorption Tower circulation pump 12, oxidation fan 13, sodium hydroxide self-control regulating valve 14, sodium hydroxide storage tank 15, magnesium hydroxide slurry pump 16, magnesium hydroxide slurry tank 17, magnesium oxide aging pump 18, magnesium oxide aging tank 19, Desulfurization liquid storage tank 20, filter press 21, desulfurization hydraulic filter pump 22, chimney 23, magnesium hydroxide slurry spray device 24; flue gas conveying fan 2 is installed at the front end of the entrance flue of desulfurization absorption tower 1, and the tower body of desulfurization absorption tower 1 A magnesium hydroxide slurry spray device 24 is installed at the flue gas inlet in the middle and lower part, an inlet SO2 concentration detector 10 is installed on the flue gas inlet pipe, and the sodium hydroxide storage tank 15 is connected to the lower part of the desulfurization absorption tower 1 through a pump and a pipeline. The pipeline is provided with a sodium hydroxide self-control regulating valve 14, the outlet SO2 concentration detector 11 is located in the chimney 23, the inlet SO2 concentration detector 10 and the outlet SO2 concentration detector 11 are respectively connected with the sodium hydroxide self-control regulating valve 14 signal Interlocking; the inside of the desulfurization absorption tower 1 is equipped with a demister 3, a multi-layer spray device 5, and a flow-equalizing efficiency tray 6 from top to bottom; the defogging inside the desulfurization absorption tower 1 A wet electrostatic precipitator 4 is arranged above the device 3, and a chimney 23 is arranged above the wet electrostatic precipitator; an oxidation aeration device is arranged at the bottom of the desulfurization absorption tower 1, and the oxidation aeration device includes an oxidation blower 13, an air spray gun 7, an aeration air Main pipe, aeration air branch pipe, the main pipe of aeration air is placed in the middle of the slurry layer in the tower, one end is connected to the oxidation fan 13, and the other end is connected to the air spray gun 7 through the aeration oxidation branch pipe. The bottom of the desulfurization absorption tower 1 is also provided with a lateral Stirring device 8; Magnesium oxide ripening tank 19 is connected with magnesium oxide ripening pump 18 by pipeline, and described magnesium oxide ripening pump 18 outlets are connected to magnesium hydroxide slurry tank 17, and magnesium hydroxide slurry tank 17 is by magnesium hydroxide slurry pump 16 The magnesium hydroxide slurry spraying device 24 at the flue gas inlet is used to supply liquid to the desulfurization absorption tower 1 to supplement the magnesium hydroxide slurry, and a valve 25 is provided on the pipeline for replenishing the magnesium hydroxide slurry to the desulfurization absorption tower 1; The outlet of the absorption tower circulation pump 12 is divided into two branches, one of which is connected to the multi-layer spray device 5, each layer is adjusted and controlled by the spray layer control valve 9, and the other is connected to the desulfurization liquid storage tank 20 and connected to the pipeline A valve is provided; the desulfurization liquid storage pool 20 is connected to a filter press 21 through a desulfurization hydraulic filter pump 22 .
工艺流程包括:大气量的杂散冶炼烟气经烟气输送风机2增压后,经氢氧化镁浆液喷淋装置24预处理后,从脱硫吸收塔1中下部进入塔体,经均流提效塔盘6与来自多层喷淋装置5自上而下的氢氧化镁浆液逆向接触脱硫,脱硫烟气经除雾器3、湿式电除尘器4除雾后经塔顶上部烟囱23排空;在脱硫吸收塔1塔槽内,氢氧化镁浆液经侧向搅拌装置8充分搅动,有效阻止了不溶颗粒的沉积,同时脱硫后形成的亚硫酸镁在氧化曝气装置的氧化下,逐渐生成溶解度高的硫酸镁溶液;入口SO2浓度检测仪10和出口SO2浓度检测仪11分别与氢氧化钠自控调节阀14信号联锁,当入口SO2浓度或出口SO2浓度超过设定值时,自动开启氢氧化钠自控调节阀14,向脱硫吸收塔1加入氢氧化钠溶液,确保烟气达标排放;吸收塔循环泵12把塔内氢氧化镁浆液输送至三层喷淋装置5,氢氧化镁浆液分别由每层都有的喷淋层控制阀9进行调节控制,可根据杂散冶炼烟气SO2浓度、气量大小调节喷淋的层数;当氢氧化镁浆液趋于饱和时,通过吸收塔循环泵12输送至脱硫液储存池20(打开连通脱硫液储存池20管上阀门,此阀门在氢氧化镁浆液未饱和时处于关闭中),进入脱硫液储存池20的浆液经脱硫液压滤泵22输送至压滤机21进行压滤,富含有毒、有害不溶性物质作为滤饼单独处理,硫酸镁清液可用作硫酸系统补水或硫酸镁产品的生产;外购合格的氧化镁粉卸入氧化镁熟化槽19内并加入水,在蒸汽加热、搅拌条件下进行熟化,熟化合格后经氧化镁熟化泵18输送到氢氧化镁浆液槽17待用,经氢氧化镁浆液泵16输送至烟气入口处氢氧化镁浆液喷淋装置24,对烟气进行预处理,同时根据饱和脱硫液排放情况,及时打开进液管上的阀门对脱硫吸收塔1内浆液进行补充。The process flow includes: After the large amount of stray smelting flue gas is pressurized by the flue gas conveying fan 2, after being pretreated by the magnesium hydroxide slurry spraying device 24, it enters the tower body from the middle and lower part of the desulfurization absorption tower 1, and is extracted by equal flow. The effect tray 6 is in reverse contact with the magnesium hydroxide slurry from the multi-layer spraying device 5 for desulfurization, and the desulfurized flue gas is demisted by the demister 3 and the wet electrostatic precipitator 4, and then emptied through the upper chimney 23 on the top of the tower ; In the desulfurization absorption tower 1 tower tank, the magnesium hydroxide slurry is fully stirred by the lateral stirring device 8, effectively preventing the deposition of insoluble particles, and the magnesium sulfite formed after desulfurization is gradually generated under the oxidation of the oxidation aeration device Magnesium sulfate solution with high solubility; inlet SO2 concentration detector 10 and outlet SO2 concentration detector 11 are respectively interlocked with sodium hydroxide self - control regulating valve 14 signal, when inlet SO2 concentration or outlet SO2 concentration exceeds the set value , automatically open the sodium hydroxide self-control regulating valve 14, and add sodium hydroxide solution to the desulfurization absorption tower 1 to ensure that the flue gas is discharged up to the standard; the absorption tower circulation pump 12 transports the magnesium hydroxide slurry in the tower to the three-layer spray device 5, hydrogen The magnesium oxide slurry is regulated and controlled by the spray layer control valve 9 that each layer has respectively, and the number of spraying layers can be adjusted according to the stray smelting flue gas SO2 concentration and gas volume ; when the magnesium hydroxide slurry tends to be saturated, It is transported to the desulfurization liquid storage pool 20 through the absorption tower circulation pump 12 (open the valve on the pipe connected to the desulfurization liquid storage pool 20, and the valve is closed when the magnesium hydroxide slurry is not saturated), and the slurry entering the desulfurization liquid storage pool 20 is desulfurized The hydraulic filter pump 22 is transported to the filter press 21 for pressure filtration. The rich in toxic and harmful insoluble substances are processed separately as filter cakes. The magnesium sulfate clear liquid can be used as water replenishment in the sulfuric acid system or the production of magnesium sulfate products; qualified magnesium oxide is purchased The powder is unloaded into the magnesia aging tank 19 and water is added, and the slaking is carried out under steam heating and stirring conditions. After the slaking is qualified, the magnesia slaking pump 18 is transported to the magnesium hydroxide slurry tank 17 for use, and the magnesium hydroxide slurry pump 16 Transport it to the magnesium hydroxide slurry spraying device 24 at the entrance of the flue gas to pretreat the flue gas. At the same time, according to the discharge of saturated desulfurization liquid, open the valve on the liquid inlet pipe in time to supplement the slurry in the desulfurization absorption tower 1.
进一步的,所述氧化曝气装置设置三套,空气喷枪7在同一圆周上相隔120度布置,使得氧化更快速均匀。Further, there are three sets of oxidation aeration devices, and the air spray guns 7 are arranged on the same circle at intervals of 120 degrees, so that the oxidation is faster and more uniform.
进一步的,所述侧向搅拌装置8设置三套,搅拌叶位于空气喷枪7下方,与空气喷枪7相配合。Further, there are three sets of lateral stirring devices 8 , and the stirring blades are located below the air spray gun 7 and cooperate with the air spray gun 7 .
实施例1Example 1
氢氧化镁浆液制备:先将外购合格的氧化镁粉与新水按一定比例加入氧化镁熟化槽19内,通蒸汽、开搅拌,熟化2h,制成12%的氢氧化镁浆液,经氧化镁熟化泵18输送到氢氧化镁浆液槽17待用。正常生产时,开启侧向搅拌装置8,开启氧化曝气装置,由空气喷枪7鼓入空气。开启吸收塔循环泵12输送氢氧化镁浆液至多层喷淋装置5,调节喷淋层控制阀9,打开三层进行喷淋。冶炼杂散烟气(气量约60万Nm3/h,SO2浓度为1057-3500mg/Nm3,平均约为3000mg/Nm3,温度50±10℃)经烟气输送风机2增压后,从脱硫吸收塔1中下部进入塔体,经均流提效塔盘6分布均匀后与来自多层喷淋装置5自上而下的氢氧化镁浆液逆向接触,氢氧化镁浆液将烟气中的SO2吸收。脱硫后烟气经除雾器3、湿式电除尘器4除雾后经塔顶上部烟囱23排空。通过出口SO2浓度检测仪11时时检测,表明SO2浓度基本保持在150mg/Nm3,满足达标排放标准。塔内脱硫浆液含固量较低,没有沉淀沉于塔底,所有管道均无堵塞现象。当氢氧化镁浆液PH达到6时,吸收塔循环泵12将饱和液输送至脱硫液储存池20,当脱硫吸收塔1内饱和脱硫液排放至0.5米高液位时停止输送饱和液,氢氧化镁浆液泵16向脱硫吸收塔1补充氢氧化镁浆液至工艺要求。脱硫液储存池20至一定液位,开启脱硫液压滤泵22将脱硫液输送至压滤机21进行压滤,富含有毒、有害不溶性物质作为滤饼单独处理,硫酸镁清液可用作硫酸系统补水或硫酸镁产品的生产。Preparation of magnesium hydroxide slurry: First, add the purchased qualified magnesium oxide powder and fresh water into the magnesium oxide aging tank 19 in a certain proportion, pass steam, start stirring, and aging for 2 hours to make 12% magnesium hydroxide slurry, which is oxidized The magnesium slaking pump 18 is delivered to the magnesium hydroxide slurry tank 17 for use. During normal production, the side stirring device 8 is turned on, the oxidation aeration device is turned on, and air is blown in by the air spray gun 7 . Turn on the absorption tower circulation pump 12 to deliver the magnesium hydroxide slurry to the multi-layer spray device 5, adjust the spray layer control valve 9, and open the three layers for spraying. Smelting stray flue gas (gas volume is about 600,000 Nm 3 /h, SO 2 concentration is 1057-3500mg/Nm 3 , average is about 3000mg/Nm 3 , temperature 50±10°C) is pressurized by flue gas conveying fan 2, It enters the tower body from the middle and lower part of the desulfurization absorption tower 1, and after being evenly distributed through the flow-equalizing efficiency tray 6, it is in reverse contact with the magnesium hydroxide slurry from the top to bottom of the multi-layer spraying device 5, and the magnesium hydroxide slurry absorbs the flue gas. of SO 2 absorption. After desulfurization, the flue gas is demisted by the mist eliminator 3 and the wet electrostatic precipitator 4, and then emptied through the upper chimney 23 on the top of the tower. The constant detection by the outlet SO 2 concentration detector 11 shows that the SO 2 concentration is basically maintained at 150 mg/Nm 3 , which meets the discharge standard. The desulfurization slurry in the tower has a low solid content, no sediment sinks to the bottom of the tower, and all pipes are free from clogging. When the pH of the magnesium hydroxide slurry reaches 6, the absorption tower circulating pump 12 transports the saturated liquid to the desulfurization liquid storage tank 20, and when the saturated desulfurization liquid in the desulfurization absorption tower 1 is discharged to a high liquid level of 0.5 meters, the delivery of the saturated liquid is stopped, and the hydrogen oxidization The magnesium slurry pump 16 replenishes the magnesium hydroxide slurry to the desulfurization absorption tower 1 to meet the process requirements. When the desulfurization liquid storage tank 20 reaches a certain level, turn on the desulfurization hydraulic filter pump 22 to transport the desulfurization liquid to the filter press 21 for pressure filtration. The rich in toxic and harmful insoluble substances are treated as filter cakes separately, and the magnesium sulfate clear liquid can be used as sulfuric acid Production of system rehydration or magnesium sulfate products.
实施例2Example 2
非正常生产时,冶炼杂散烟气气量约40万Nm3/h,SO2浓度为6000-8500mg/Nm3,平均约为7000mg/Nm3,温度200-280℃。开启侧向搅拌装置8,开启氧化曝气装置,由空气喷枪7鼓入空气。开启氢氧化镁浆液泵16,输送氢氧化镁浆液至烟气入口氢氧化镁浆液喷淋装置24进行烟气喷淋降温,开启吸收塔循环泵12输送氢氧化镁浆液至喷淋层5,调节各层喷淋层控制阀9,打开二层进行喷淋。冶炼杂散烟气经烟气输送风机2增压后,经氢氧化镁浆液喷淋装置24降温洗涤后,从脱硫吸收塔1中下部进入塔体,经均流提效塔盘6分布均匀后与来自多层喷淋装置5自上而下的氢氧化镁浆液逆向接触,氢氧化镁浆液将烟气中的SO2吸收。脱硫后烟气经除雾器3、湿式电除尘器4除雾后经塔顶上部烟囱23排空。当入口SO2浓度超过设定值6500mg/Nm3或出口SO2浓度超过150mg/Nm3时,延时2秒自动开启氢氧化钠自控调节阀14,向脱硫吸收塔1加入氢氧化钠,经出口SO2浓度检测仪11检测,SO2浓度基本保持在150mg/Nm3,达标排放;当氢氧化镁浆液pH达到6时,吸收塔循环泵12将饱和液输送至脱硫液储存池20,当脱硫吸收塔1内饱和脱硫液排放至0.5米高液位时停止输送饱和液,氢氧化镁浆液泵16向脱硫吸收塔1补充氢氧化镁浆液至工艺要求。脱硫液储存池20至一定液位,开启脱硫液压滤泵22将脱硫液输送压滤机21进行压滤,富含有毒、有害不溶性物质作为滤饼单独处理,硫酸镁清液可用作硫酸系统补水或硫酸镁产品的生产。During abnormal production, the amount of smelting stray flue gas is about 400,000 Nm 3 /h, the concentration of SO 2 is 6000-8500mg/Nm 3 , the average is about 7000mg/Nm 3 , and the temperature is 200-280℃. The side stirring device 8 is turned on, the oxidation aeration device is turned on, and air is blown in by the air spray gun 7 . Turn on the magnesium hydroxide slurry pump 16, deliver the magnesium hydroxide slurry to the magnesium hydroxide slurry spray device 24 at the flue gas inlet to spray the flue gas to cool down, turn on the absorption tower circulation pump 12 to deliver the magnesium hydroxide slurry to the spray layer 5, adjust Each layer of spray layer control valve 9 is opened to spray on the second floor. After the smelting stray flue gas is pressurized by the flue gas conveying fan 2, after being cooled and washed by the magnesium hydroxide slurry spraying device 24, it enters the tower body from the middle and lower part of the desulfurization absorption tower 1, and is evenly distributed by the flow-balancing efficiency tray 6 It is in reverse contact with the magnesium hydroxide slurry from top to bottom from the multi-layer spray device 5 , and the magnesium hydroxide slurry absorbs SO2 in the flue gas. After desulfurization, the flue gas is demisted by the mist eliminator 3 and the wet electrostatic precipitator 4, and then emptied through the upper chimney 23 on the top of the tower. When the inlet SO2 concentration exceeds the set value of 6500mg / Nm3 or the outlet SO2 concentration exceeds 150mg/ Nm3 , the sodium hydroxide self-control regulating valve 14 is automatically opened after a delay of 2 seconds, and sodium hydroxide is added to the desulfurization absorption tower 1. The outlet SO2 concentration detector 11 detects that the SO2 concentration is basically maintained at 150mg/ Nm3 , and the discharge meets the standard; when the pH of the magnesium hydroxide slurry reaches 6, the absorption tower circulation pump 12 transports the saturated liquid to the desulfurization liquid storage tank 20, when When the saturated desulfurization liquid in the desulfurization absorption tower 1 is discharged to a high liquid level of 0.5 meters, the delivery of the saturated liquid is stopped, and the magnesium hydroxide slurry pump 16 replenishes the magnesium hydroxide slurry to the desulfurization absorption tower 1 to meet the process requirements. When the desulfurization liquid storage tank 20 reaches a certain liquid level, turn on the desulfurization hydraulic filter pump 22 to send the desulfurization liquid to the filter press 21 for pressure filtration. The rich in toxic and harmful insoluble substances are treated as filter cakes separately, and the magnesium sulfate clear liquid can be used as a sulfuric acid system. Manufacture of hydration or magnesium sulfate products.
实施例3Example 3
非正常生产时,冶炼杂散烟气气量约40万Nm3/h,SO2浓度为835-2500mg/Nm3,平均约为2000mg/Nm3,温度50±10℃。开启侧向搅拌装置8,开启氧化曝气装置,由空气喷枪7鼓入空气。开启吸收塔循环泵12输送氢氧化镁浆液至喷淋层5,调节单层喷淋层控制阀9,打开二层进行喷淋。冶炼杂散烟气经烟气输送风机2增压后,从脱硫吸收塔1中下部进入塔体,经均流提效塔盘6扩散均匀后与来自多层喷淋装置5自上而下的氢氧化镁浆液逆向接触,氢氧化镁浆液将烟气中的SO2吸收。脱硫后烟气经除雾器3、湿式电除尘器4除雾后经塔顶上部烟囱23排空。通过出口SO2浓度检测仪11时时检测,表明SO2浓度基本保持在150mg/Nm3,满足达标排放标准。塔内脱硫浆液含固量较低,没有沉淀沉于塔底,所有管道均无堵塞现象。当氢氧化镁浆液PH达到6时,吸收塔循环泵12将饱和液输送至脱硫液储存池20,当脱硫吸收塔1内饱和脱硫液排放至0.5米高液位时停止输送饱和液,氢氧化镁浆液泵16向脱硫吸收塔1补充氢氧化镁浆液至工艺要求。脱硫液储存池20至一定液位,开启脱硫液压滤泵22将脱硫液输送压滤机21进行压滤,富含有毒、有害不溶性物质作为滤饼单独处理,硫酸镁清液可用作硫酸系统补水或硫酸镁产品的生产。During abnormal production, the amount of smelting stray flue gas is about 400,000 Nm 3 /h, the concentration of SO 2 is 835-2500mg/Nm 3 , the average is about 2000mg/Nm 3 , and the temperature is 50±10℃. The side stirring device 8 is turned on, the oxidation aeration device is turned on, and air is blown in by the air spray gun 7 . Turn on the absorption tower circulation pump 12 to deliver the magnesium hydroxide slurry to the spray layer 5, adjust the single-layer spray layer control valve 9, and open the second layer for spraying. After being pressurized by the flue gas conveying fan 2, the stray flue gas from smelting enters the tower body from the middle and lower part of the desulfurization absorption tower 1. The magnesium hydroxide slurry is in reverse contact, and the magnesium hydroxide slurry absorbs SO2 in the flue gas. After desulfurization, the flue gas is demisted by the mist eliminator 3 and the wet electrostatic precipitator 4, and then emptied through the upper chimney 23 on the top of the tower. The constant detection by the outlet SO 2 concentration detector 11 shows that the SO 2 concentration is basically maintained at 150 mg/Nm 3 , which meets the discharge standard. The desulfurization slurry in the tower has a low solid content, no sediment sinks to the bottom of the tower, and all pipes are free from clogging. When the pH of the magnesium hydroxide slurry reaches 6, the absorption tower circulating pump 12 transports the saturated liquid to the desulfurization liquid storage tank 20, and when the saturated desulfurization liquid in the desulfurization absorption tower 1 is discharged to a high liquid level of 0.5 meters, the delivery of the saturated liquid is stopped, and the hydrogen oxidization The magnesium slurry pump 16 replenishes the magnesium hydroxide slurry to the desulfurization absorption tower 1 to meet the process requirements. When the desulfurization liquid storage tank 20 reaches a certain liquid level, turn on the desulfurization hydraulic filter pump 22 to send the desulfurization liquid to the filter press 21 for pressure filtration. The rich in toxic and harmful insoluble substances are treated as filter cakes separately, and the magnesium sulfate clear liquid can be used as a sulfuric acid system. Manufacture of hydration or magnesium sulfate products.
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CN112547308A (en) * | 2020-11-24 | 2021-03-26 | 李元芬 | Industrial wet-type electric dust collector |
CN112547308B (en) * | 2020-11-24 | 2023-04-18 | 临沂绿楠环保科技有限公司 | Industrial wet-type electric dust collector |
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