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CN206993471U - A kind of plasma producing apparatus corona electrode - Google Patents

A kind of plasma producing apparatus corona electrode Download PDF

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Publication number
CN206993471U
CN206993471U CN201720481904.XU CN201720481904U CN206993471U CN 206993471 U CN206993471 U CN 206993471U CN 201720481904 U CN201720481904 U CN 201720481904U CN 206993471 U CN206993471 U CN 206993471U
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titanium plate
electrode
corona electrode
punching press
etching
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周志华
释延豹
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SHENZHEN TIANJIQUAN HEALTH SCIENCE & TECHNOLOGY GROUP Co Ltd
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Abstract

The utility model provides a kind of plasma producing apparatus corona electrode, and the preparation method of the corona electrode mainly includes:It is cleaned and dried overlay film etch cleaner and dries punching press overlay film;The invention develops a kind of etching, punching press and plated film new technology, the technique is using titanium plate as base material, cylindrical electrode shape is gone out by lithography first, then punching press is carried out to cylindrical electrode to prepare pointed shape, the processing method can ensure that the precision of the processing of each point of discharge, the uniformity of electric discharge is improved, reduces the size of sparking electrode;In addition, corona electrode of the present utility model plates one layer of platinum than the electrode produced by the method for plated film on the Ti electrode surface for having projection, so as to increase the stability of the service life of electrode and electric discharge.

Description

A kind of plasma producing apparatus corona electrode
Technical field
Plasma discharge technical field is the utility model is related to, more particularly to a kind of plasma producing apparatus corona Electrode.
Background technology
Plasma is that complete ionization or partial ionization, charge number are bordering on equal positive negative charged particles and neutral particle Material aggregation state.Plasma can produce active component, cause conventional chemical to be difficult to the physical change and change realized in reacting Learn reaction.Atmospheric non-equilibrium plasma because its temperature is low, and rich in high energy electron, ion, excited atom, molecule and Free radical isoreactivity species, these active components are easy to the substance reaction with contacting, therefore are widely used in material modification, water Processing, purification of air, disinfectant fresh-keeping, biologic medical etc..
2006, Fridman reported that low temperature plasma has the function that to remarkably promote blood coagulation first, it is indicated that low temperature etc. from Daughter is used for the benefit of blood coagulation actual treatment.By research closely about ten years, people's plasma promotes the mechanism of blood coagulation to have The understanding that is apparent from.Researcher also found that Topically active plasma composition can efficiently reduce the bacterium on wound face Amount, stimulated by the depth of electric field, promote blood microcirculation, improve the oxygen of wound tissue and the supply of nutrition.Profound The reduction of blood microcirculation and local bacterial is stimulated, activation body causes the self-healing ability of damage to chronic disease.
Because lower temperature plasma technology treat wound has compared to conventional medicament, quick, the advantage such as have no side effect, Therefore there are good market prospects.Corona discharge is because its is simple in construction, be easy to equipment miniaturization and plasma can be directly It is applied on skin, is likely to become the mainstream technology of following Related product.However, the electric discharge device of current application is all fixed electricity Pole structure, fine wire is as corona electrode, it is easy to be broken, the life-span mostly at three to six months, such as:Chinese invention patent Application No. 200710038821.4, denomination of invention《Assembly modular type systyle electrostatic field device》.Zigzag or prong shape knot Although the corona electrode of structure is not easily broken, tip long-time is discharged, heating and ion sputtering double action, is caused sophisticated easy In passivation, micro-arc discharge phenomenon also easily occurs.Slim banding corona electrode is not easy to break, and can obtain similar fine wire Discharge effect, still, breach easily occurs in band electrode, forms local micro discharge, such as:Please number be in Chinese invention patent 200910263798.8 denomination of invention《Metal tape -- plate structure reactor》.Four kinds of presently most used corona electrodes of the above are equal The problem of Uniform discharge is also poor and electrode life is short be present, often only some months is, it is necessary to inspect periodically and change corona Electrode, maintenance cost is high, once safeguarding not in time, fracture of wire occurs and fails, or local micro discharge occurs, and seriously constrains it Popularization and application, therefore, it is most important to develop a kind of corona discharge electrode of long-life.
The content of the invention
The purpose of this utility model seeks to provide a kind of plasma producing apparatus corona electrode, the utility model system There is the advantages of Uniform discharge is good, and discharge life is long and stability is good for the corona electrode gone out.
To achieve the above object, the utility model is achieved by the following scheme:
A kind of plasma producing apparatus corona electrode, it is characterised in that the electrode includes:One piece of thickness is 1~2mm Titanium plate, the sheet titanium plate (1) being sized to;To the cylindrical electrode gone out by etching and processing on titanium plate (1) surface Shape punching press, extrude pointed shape (2);Metastable TiH2 films are precipitated on titanium plate surface;TiH2 films on titanium plate surface One layer of platinum of upper plating, i.e., described corona electrode.
The thickness of described titanium plate is 1.5mm.
A height of 150 μm -300 μm of described pointed shape (2).
A kind of plasma producing apparatus corona electrode, it is characterised in that the preparation method of the electrode includes following step Suddenly:
(1) titanium plate that one piece of thickness is 1~2mm, the sheet titanium plate being sized to are taken;
(2) the sheet titanium plate of step (1) is placed in the ultrasonic cleaning tank for filling 4wt%-7wt%NaOH solution and surpassed Sound is cleaned, and cleaning is first rinsed after terminating with deionized water, is then dried up titanium plate with the compressed gas of cleaning;
(3) one layer of negative photoresist is coated in the titanium plate surface that step (2) obtains, mask is placed in photoresist afterwards On, and carry out the exposure of photoresist;
(4) the unexposed photoresist in step (3) titanium plate surface is washed away, and is carved using plasma etching technology on titanium plate surface Lose required pattern, the etching depth of the etching is 50~300 μm;
(5) photoresist on titanium plate surface is removed, then the titanium plate after etching is placed in ultrasonic cleaning tank and carries out ultrasound clearly 40~60min is washed, and cleaning is first rinsed after terminating with deionized water, then titanium plate is dried up with the compressed gas of cleaning;
(6) punching press is carried out to the position of titanium plate surface exposure, cylindrical end face pressure is gone out pointed shape;
(7) it is first 3 with volume ratio by the titanium plate after punching press:1 HNO3- HF mixed solutions are embathed to remove titanium-based table The oxide layer in face and other metal impurities, it is then 3 with volume ratio:1 HCl-H2SO4Solution performs etching to titanium plate surface So as to its surface roughening and make titanium plate surface precipitate metastable TiH2Film, afterwards using PdCl2Solution soaks one section of titanium plate Time so that titanium plate activation, is cleaned with deionized water after activation, is dried up titanium plate with compressed gas;
(8) dry titanium plate is put into coating bath, one layer of platinum is plated on titanium plate surface using platiniferous plating solution, then by after plated film Titanium plate material cleans up, and is dried up with compressed gas, is placed in 60~120min of thermal decomposition in 400~600 DEG C of atmosphere afterwards, finally Cool down and produce the corona electrode.
Wherein, the time being cleaned by ultrasonic in the step (2) is 30~40min, and temperature control is at 35 DEG C~60 DEG C.
HNO is used in the step (7)3The time that-HF mixed solutions are embathed to titanium plate is 30~60min, temperature Control is at 35~70 DEG C.
HCl-H is used in the step (7)2SO4The temperature that solution performs etching be 60~80 DEG C, the time be 20~ 40min。
PdCl in the step (7)2The concentration of solution is 0.1g/L, using PdCl2The time of solution immersion for 20~ 50min。
Platiniferous plating solution is the Pt (NO that concentration is 0.5g/L in the step (8)2)2(NH3)2Solution, used during platinum plating Reducing agent be the hydrazine hydrate that concentration is 12g/L and/or the hydroxylamine hydrochloride that concentration is 5g/L, the control of platinum plating process temperature 40~ 60℃。
In addition, the corona electrode that the preparation method is prepared is also claimed in the utility model.
And the utility model also protects application of the corona electrode in plasma producing apparatus;The plasma Body generating means is used for the treatment of traumatic wounds.
The beneficial effects of the utility model are:The utility model develops a kind of etching, punching press and plated film new technology, should Technique goes out cylindrical electrode shape by lithography first using titanium plate as base material, then to cylindrical electrode carry out punching press with Pointed shape is prepared, the processing method can ensure that the precision of the processing of each point of discharge, improve the uniformity of electric discharge, and reduction is put The size of electrode;In addition, the utility model also plates one layer of platinum by the method for plated film on the Ti electrode surface for having projection, so as to Increase the service life of electrode and the stability of electric discharge.
Below in conjunction with accompanying drawing, the utility model is described in further detail by specific embodiment
Brief description of the drawings
The flow chart that Fig. 1 the utility model corona electrode makes;
The top view of electrode made by Fig. 2 the utility model;
The front view of electrode made by Fig. 3 the utility model;
Embodiment
The technical scheme in the embodiment of the utility model will be clearly and completely described below, it is clear that described Embodiment is only the utility model part of the embodiment, rather than whole embodiments.Based on the implementation in the utility model Example, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, is belonged to The scope of the utility model protection.
Embodiment 1
A kind of plasma producing apparatus corona electrode, the preparation method of the electrode, comprises the following steps:
(1) titanium plate that one piece of thickness is about 1.5mm is taken, the sheet titanium plate 1 being sized to;
(2) plate of sheet titanium 1 of step (1) is placed in the ultrasonic cleaning tank for filling 5wt%NaOH solution and carries out ultrasound clearly Wash, cleaning is first rinsed after terminating with deionized water, is then dried up titanium plate with the compressed gas of cleaning;The ultrasonic cleaning Time be 35min, temperature control is at 50 DEG C;
(3) one layer of negative photoresist is coated in the titanium plate surface that step (2) obtains, mask is placed in photoresist afterwards On, and carry out the exposure of photoresist;
(4) the unexposed photoresist in step (3) titanium plate surface is washed away, and is carved using plasma etching technology on titanium plate surface Lose required pattern, the etching depth of the etching is about 200 μm;
(5) photoresist on titanium plate surface is removed, then the titanium plate after etching is placed in ultrasonic cleaning tank and carries out ultrasound clearly 50min is washed, and cleaning is first rinsed after terminating with deionized water, then titanium plate is dried up with the compressed gas of cleaning;
(6) punching press is carried out to the position of titanium plate surface exposure, cylindrical end face pressure is gone out pointed shape 2;
(7) it is first 3 with volume ratio by the titanium plate after punching press:1 HNO3- HF mixed solutions are embathed to remove titanium-based table The oxide layer in face and other metal impurities, the time embathed are 45min, then temperature control uses volume ratio at 50 DEG C For 3:1 HCl-H2SO4Solution is performed etching to titanium plate surface so as to its surface roughening and make titanium plate surface precipitated phase to stable TiH2Film, the temperature of the etching is 70 DEG C, time 30min, afterwards using PdCl2Solution immersion titanium plate for a period of time with Activate titanium plate, the PdCl2The concentration of solution is 0.1g/L, using PdCl2The time of solution immersion is 30min, after activation Cleaned with deionized water, dried up titanium plate with compressed gas;
(8) dry titanium plate is put into coating bath, one layer of platinum is plated on titanium plate surface using platiniferous plating solution, then by after plated film Titanium plate material cleans up, and is dried up with compressed gas, is placed in afterwards in 500 DEG C of atmosphere and thermally decomposes 90min, finally cools down and produces institute State corona electrode;Platiniferous plating solution is the Pt (NO that concentration is 0.5g/L2)2(NH3)2Solution, the reducing agent used during platinum plating for Concentration is 12g/L hydrazine hydrate, and platinum plating process temperature is controlled at 50 DEG C.
Embodiment 2
A kind of plasma producing apparatus corona electrode, the preparation method of the preparation method of the electrode, including following step Suddenly:
(1) titanium plate that one piece of thickness is about 1mm is taken, the sheet titanium plate 1 being sized to;
(2) the sheet titanium plate of step (1) is placed in the ultrasonic cleaning tank for filling 4wt%NaOH solution and carries out ultrasound clearly Wash, cleaning is first rinsed after terminating with deionized water, is then dried up titanium plate with the compressed gas of cleaning;The ultrasonic cleaning Time be 30min, temperature control is at 35 DEG C;
(3) one layer of negative photoresist is coated in the titanium plate surface that step (2) obtains, mask is placed in photoresist afterwards On, and carry out the exposure of photoresist;
(4) the unexposed photoresist in step (3) titanium plate surface is washed away, and is carved using plasma etching technology on titanium plate surface Lose required pattern, the etching depth of the etching is about 150 μm;
(5) photoresist on titanium plate surface is removed, then the titanium plate after etching is placed in ultrasonic cleaning tank and carries out ultrasound clearly 40min is washed, and cleaning is first rinsed after terminating with deionized water, then titanium plate is dried up with the compressed gas of cleaning;
(6) punching press is carried out to the position of titanium plate surface exposure, cylindrical end face pressure is gone out pointed shape 2;
(7) it is first 3 with volume ratio by the titanium plate after punching press:1 HNO3- HF mixed solutions are embathed to remove titanium-based table The oxide layer in face and other metal impurities, the time embathed are 30min, then temperature control uses volume ratio at 35 DEG C For 3:1 HCl-H2SO4Solution is performed etching to titanium plate surface so as to its surface roughening and make titanium plate surface precipitated phase to stable TiH2Film, the temperature of the etching is 60 DEG C, time 20min, afterwards using PdCl2Solution immersion titanium plate for a period of time with Activate titanium plate, the PdCl2The concentration of solution is 0.1g/L, using PdCl2The time of solution immersion is 20min, after activation Cleaned with deionized water, dried up titanium plate with compressed gas;
(8) dry titanium plate is put into coating bath, one layer of platinum is plated on titanium plate surface using platiniferous plating solution, then by after plated film Titanium plate material cleans up, and is dried up with compressed gas, is placed in afterwards in 400 DEG C of atmosphere and thermally decomposes 60min, finally cools down and produces institute State corona electrode;Platiniferous plating solution is the Pt (NO that concentration is 0.5g/L2)2(NH3)2Solution, the reducing agent used during platinum plating for Concentration is 5g/L hydroxylamine hydrochloride, and platinum plating process temperature is controlled at 40 DEG C.
Embodiment 3
A kind of plasma producing apparatus corona electrode, the preparation method of the electrode, comprises the following steps:
(1) titanium plate that one piece of thickness is about 2mm is taken, the sheet titanium plate 1 being sized to;
(2) the sheet titanium plate of step (1) is placed in the ultrasonic cleaning tank for filling 7wt%NaOH solution and carries out ultrasound clearly Wash, cleaning is first rinsed after terminating with deionized water, is then dried up titanium plate with the compressed gas of cleaning;The ultrasonic cleaning Time be 40min, temperature control is at 60 DEG C;
(3) one layer of negative photoresist is coated in the titanium plate surface that step (2) obtains, mask is placed in photoresist afterwards On, and carry out the exposure of photoresist;
(4) the unexposed photoresist in step (3) titanium plate surface is washed away, and is carved using plasma etching technology on titanium plate surface Lose required pattern, the etching depth of the etching is about 300 μm;
(5) photoresist on titanium plate surface is removed, then the titanium plate after etching is placed in ultrasonic cleaning tank and carries out ultrasound clearly 60min is washed, and cleaning is first rinsed after terminating with deionized water, then titanium plate is dried up with the compressed gas of cleaning;
(6) punching press is carried out to the position of titanium plate surface exposure, cylindrical end face pressure is gone out pointed shape 2;
(7) it is first 3 with volume ratio by the titanium plate after punching press:1 HNO3- HF mixed solutions are embathed to remove titanium-based table The oxide layer in face and other metal impurities, the time embathed are 60min, then temperature control uses volume ratio at 70 DEG C For 3:1 HCl-H2SO4Solution is performed etching to titanium plate surface so as to its surface roughening and make titanium plate surface precipitated phase to stable TiH2Film, the temperature of the etching is 80 DEG C, time 40min, afterwards using PdCl2Solution immersion titanium plate for a period of time with Activate titanium plate, the PdCl2The concentration of solution is 0.1g/L, using PdCl2The time of solution immersion is 50min, after activation Cleaned with deionized water, dried up titanium plate with compressed gas;
(8) dry titanium plate is put into coating bath, one layer of platinum is plated on titanium plate surface using platiniferous plating solution, then by after plated film Titanium plate material cleans up, and is dried up with compressed gas, is placed in afterwards in 600 DEG C of atmosphere and thermally decomposes 120min, finally cools down and produces The corona electrode;Platiniferous plating solution is the Pt (NO that concentration is 0.5g/L2)2(NH3)2Solution, the reducing agent used during platinum plating The hydroxylamine hydrochloride that the hydrazine hydrate and concentration for being 12g/L for concentration are 5g/L, platinum plating process temperature are controlled at 60 DEG C.
It is obvious to a person skilled in the art that the utility model is not limited to the details of above-mentioned one exemplary embodiment, and And in the case of without departing substantially from spirit or essential attributes of the present utility model, it can realize that this practicality is new in other specific forms Type.Therefore, no matter from the point of view of which point, embodiment all should be regarded as exemplary, and is nonrestrictive, this practicality is new The scope of type limits by appended claims rather than described above, it is intended that the equivalency fallen in claim is contained All changes in justice and scope are included in the utility model.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art It is appreciated that other embodiment.

Claims (3)

1. a kind of plasma producing apparatus corona electrode, it is characterised in that the electrode includes:
The titanium plate that one piece of thickness is 1~2mm, the sheet titanium plate (1) being sized to;
The cylindrical electrode shape punching press gone out by etching and processing to titanium plate (1) surface, extrude pointed shape (2);
Metastable TiH2 films are precipitated on titanium plate surface;
One layer of platinum, i.e., described corona electrode are plated on the TiH2 films on titanium plate surface.
2. corona electrode according to claim 1, it is characterised in that the thickness of described titanium plate is 1.5mm.
3. corona electrode according to claim 1, it is characterised in that a height of 150 μm of -300 μ of described pointed shape (2) m。
CN201720481904.XU 2017-05-03 2017-05-03 A kind of plasma producing apparatus corona electrode Active CN206993471U (en)

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Effective date of registration: 20191104

Address after: 518026, A building, building 19, Shennan international road, Futian, Shenzhen, Futian District, Shenzhen, Guangdong, 1006, China

Patentee after: SHENZHEN TIANJIQUAN HEALTH SCIENCE & TECHNOLOGY GROUP CO., LTD.

Address before: 450008 Zhengzhou City, Jinshui District, Henan Road, No. 71, building No. 6, building No. 88

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