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CN206529367U - A kind of processing of high slat-containing wastewater and resource recovery device - Google Patents

A kind of processing of high slat-containing wastewater and resource recovery device Download PDF

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Publication number
CN206529367U
CN206529367U CN201720180191.3U CN201720180191U CN206529367U CN 206529367 U CN206529367 U CN 206529367U CN 201720180191 U CN201720180191 U CN 201720180191U CN 206529367 U CN206529367 U CN 206529367U
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China
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water
tank
pole
pipeline
pump
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Expired - Fee Related
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CN201720180191.3U
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Chinese (zh)
Inventor
刘瑞聪
于德强
赵凤美
王云钟
柯爌琼
徐凯
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QINGDAO NORTH ENERGY AND ENVIRONMENT CO., LTD.
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Qingdao Bluevale Chemical Co Ltd
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Abstract

The utility model discloses the processing of high slat-containing wastewater and recycling retracting device, including wastewater tank, the first elevator pump, cartridge filter, pole-reversing electroosmosis system, regulating reservoir, coagulative precipitation tank, concentrated water water tank, the second elevator pump, evaporated crystallization device, fresh water tanks, grug feeding jar, counter-infiltration system and water producing tank;Wastewater tank water side is sequentially connected the first elevator pump and cartridge filter by pipeline, cartridge filter water side is connected with pole-reversing electroosmosis system, pole-reversing electroosmosis system concentrated water output end is connected with regulating reservoir, coagulative precipitation tank, concentrated water water tank, the second elevator pump and evaporated crystallization device successively, pole-reversing electroosmosis system fresh water output end is connected with fresh water tanks and counter-infiltration system successively, grug feeding jar output end is connected on the pipeline between fresh water tanks and counter-infiltration system, and counter-infiltration system production water water side is connected with water producing tank.Device stable effluent quality;Realize the zero-emission of waste water.

Description

A kind of processing of high slat-containing wastewater and resource recovery device
Technical field
The utility model belongs to technical field of sewage, and in particular to a kind of processing of high slat-containing wastewater and resource reclaim Device, is particularly suitable for the processing of low COD high slat-containing wastewater.
Background technology
With the extensive development of China's industry, substantial amounts of industrial wastewater is generated.Wherein, some industry (plating, heat The industries such as electricity, oil exploitation) industrial wastewater in containing substantial amounts of high slat-containing wastewater (when the concentration of salt>When 1%, referred to as height contains Salt waste water), substantial amounts of inorganic ion, such as Na have been dissolved in waste water+、Ca2+、Mg2+、Cl-、SO4 2-Deng, but content of organics It is less.For high saliferous, low COD waste water, a kind of processing side of high slat-containing wastewater disclosed in Chinese patent CN200810225941 Method, is firstly added the pH that NaOH adjusts waste water, carries out coagulating kinetics, reduces the hardness of waste water, then carry out nanofiltration processing, Reverse-osmosis treated and multiple-effect evaporation concentration, reverse osmosis produced water can be with reuses, and the solid content that multiple-effect evaporation is obtained can be according to The disposal standard of solid waste is burned or filled.The method of wastewater treatment is efficient, economical, it is possible to achieve wastewater membrane is treated " zero-emission " of journey, it removes the calcium ion and magnesium ion of the easy fouling in waste water by coagulating sedimentation.
In recent years, electric drive membrane technology is led with being widely used in Industrial Wastewater Treatment, desalinization, medical waste water processing etc. Domain, the processing to brine waste achieves good effect.As every profession and trade is got over to the quality and horsepower requirements of product material Come higher, the superiority of homogeneous electric drive film is increasingly displayed.Homogeneous electric drive film disclosure satisfy that the processing of a variety of feed liquids It is required that, current efficiency high, energy consumption low, selective penetrated property good, the rate of recovery high the features such as small with membrane surface resistance.Electric drive film is transported The concentrated water produced during row can be reclaimed salts resources after evaporative crystallization.Counter-infiltration is that current research is more ripe One membrane separation technique, is widely used in the multiple fields such as chemical industry, food, pharmacy, municipal water supply and wastewater treatment.Electric drive The production water of film can further be handled by reverse osmosis process, and water outlet can be used as industrial water reuse.
The content of the invention
The purpose of this utility model is processing and the resource recovery device for providing a kind of high slat-containing wastewater, solves existing High-salt wastewater complex process in processing procedure, high energy consumption, it is difficult to realize Automated condtrol, the problems such as effluent quality is unstable.
In order to solve the above problems, processing and the recycling retracting device of the high slat-containing wastewater that the utility model is related to, bag Include wastewater tank, the first elevator pump, cartridge filter, pole-reversing electroosmosis system, regulating reservoir, coagulative precipitation tank, concentrated water water tank, Second elevator pump, evaporated crystallization device, fresh water tanks, grug feeding jar, counter-infiltration system and water producing tank;Wastewater tank water side leads to Piping is sequentially connected the first elevator pump and cartridge filter, and cartridge filter water side is connected with pole-reversing electroosmosis system, falls Pole electrodialysis system concentrated water output end is filled with regulating reservoir, coagulative precipitation tank, concentrated water water tank, the second elevator pump and evaporative crystallization successively Connection is put, pole-reversing electroosmosis system fresh water output end is connected with fresh water tanks and counter-infiltration system successively, grug feeding jar output end connects It is connected on the pipeline between fresh water tanks and counter-infiltration system, counter-infiltration system production water water side is connected with water producing tank.
The pole-reversing electroosmosis system that the utility model is related to auto switching polarity of electrode and while can change dense, light automatically Flow direction;Pole-reversing electroosmosis system uses homogeneous ion-exchange membrane.
Further, counter-infiltration system includes high-pressure pump and reverse osmosis membrane assembly device, the processing of high slat-containing wastewater and money Source retracting device also includes the purging system that cleaning pump, cleaning water tank and water pump are constituted, and purging system is realized to counter-infiltration The cleaning of system and frequently pole-reversing electroosmosis system, grug feeding jar output end is connected to the pipeline between fresh water tanks and high-pressure pump On, high pressure pump output terminal is connected with reverse osmosis membrane assembly device water inlet end and cleaning pump pipeline at output respectively by threeway I, First valve is set on the pipeline that threeway I is connected with high-pressure pump, in threeway I with setting the on the pipeline that is connected of cleaning pump output terminal Two valves, water producing tank is connected with reverse osmosis membrane assembly device fresh water outlet end and water pump water inlet end pipeline respectively by threeway II Connect, the 3rd valve is set on the pipeline that threeway II is connected with reverse osmosis membrane assembly device fresh water outlet end, in threeway II with taking 4th valve is set on the pipeline of water feeding of water pump end connection, and water intaking pump output terminal is connected with cleaning water tank, cleans water tank by the Five valves and cleaning pump water inlet end downlink connection, cleaning water tank respectively by pipeline and reverse osmosis membrane assembly device fresh water outlet end and Reverse osmosis membrane assembly device concentrated water water side connect, cleaning pump output terminal by threeway III respectively with the second valve and extremely electricity Electrodialysis system membrane stack water inlet end is connected, and the is set on the pipeline that threeway III is connected with pole-reversing electroosmosis system membrane stack water inlet end Six valves, pole-reversing electroosmosis system membrane stack fresh water output end and pole-reversing electroosmosis system membrane stack concentrated water output end by pipeline with Clean water tank connection.
Compared with prior art, the utility model has advantages below:(1) frequently pole-reversing electroosmosis and counter-infiltration two are used Person combines processing high-salt wastewater, compared to individually using a kind of reduction of PROCESS FOR TREATMENT energy consumption;(2) during by traditional handicraft preceding The calcium ions and magnesium ions of processing are held, will be reprocessed by electrodialysis system after the calcium ions and magnesium ions concentration in raw water, reducing needs processing Water, and then reduce medicament use and regulating reservoir and coagulative precipitation tank capital cost;(3) connection of electrodialysis and counter-infiltration Close technique and easily realize Automated condtrol, device stable effluent quality;(4) whole process realizes the zero-emission of waste water;(5) it is clear The system of washing can be counter-infiltration system and frequently pole-reversing electroosmosis cleaning systems simultaneously, save equipment cost.
Brief description of the drawings:
Fig. 1 is processing and the recycling retracting device structural representation for the high slat-containing wastewater that the utility model is related to.
Embodiment
The utility model is described further with reference to the accompanying drawings and detailed description:
Embodiment 1:
As shown in figure 1, the processing for the high slat-containing wastewater that the present embodiment is related to and recycling retracting device, including waste water water storage Case 1, the first elevator pump 2, cartridge filter 3, pole-reversing electroosmosis system 4, regulating reservoir 8, coagulative precipitation tank 9, concentrated water water tank 5, Two elevator pumps 6, evaporated crystallization device 7, fresh water tanks 11, grug feeding jar 12, counter-infiltration system and water producing tank 18;Wastewater tank 1 Water side is sequentially connected the first elevator pump 2 and cartridge filter 3, the water side of cartridge filter 3 and pole-reversing electroosmosis by pipeline The water inlet end of system 4 connect, the concentrated water output end of pole-reversing electroosmosis system 4 successively with regulating reservoir 8, coagulative precipitation tank 9, concentrated water water tank 5, Second elevator pump 6 and evaporated crystallization device 7 are connected, the fresh water output end of pole-reversing electroosmosis system 4 successively with fresh water tanks 11 and anti- Osmosis system is connected, and the output end of grug feeding jar 12 is connected on the pipeline between fresh water tanks 11 and counter-infiltration system, counter-infiltration system System production water water side is connected with water producing tank 18.
Further, the pole-reversing electroosmosis system 4 that the present embodiment is related to being capable of auto switching polarity of electrode and simultaneously automatic Change dense, light flow direction;Pole-reversing electroosmosis system 4 uses homogeneous ion-exchange membrane, useless after the processing of cartridge filter 3 Water enters pole-reversing electroosmosis system 4, and the polarization layer that amberplex surface is destroyed in the presence of polarity of electrode is frequently switched is kept away Exempt to precipitate fouling.
Further, counter-infiltration system includes high-pressure pump 13 and reverse osmosis membrane assembly device 14, the processing of high slat-containing wastewater Also include the purging system that cleaning pump 15, cleaning water tank 16 and water pump 17 are constituted with recycling retracting device, grug feeding jar 12 is defeated Go out end be connected on the pipeline between fresh water tanks 11 and high-pressure pump 13, high pressure pump output terminal by threeway I respectively with counter-infiltration The water inlet end of film component device 14 and the connection of the pipeline at output of cleaning pump 15, set the on the pipeline that threeway I is connected with high-pressure pump One valve 10, sets the second valve 22 on the pipeline that threeway I is connected with the output end of cleaning pump 15, and water producing tank 18 passes through threeway II It is connected respectively with the fresh water outlet end of reverse osmosis membrane assembly device 14 and the water inlet end pipeline of water pump 17, in threeway II and reverse osmosis membrane The 3rd valve 20 is set on the pipeline of the fresh water outlet end of assembly apparatus 14 connection, is connected in threeway II with the water inlet end of water pump 17 4th valve 19 is set on pipeline, and the output end of water pump 17 is connected with cleaning water tank 16, and cleaning water tank 16 passes through the 5th valve 23 With the water inlet end downlink connection of cleaning pump 15, cleaning water tank 16 respectively by pipeline and the fresh water outlet end of reverse osmosis membrane assembly device 14 and The concentrated water water side of reverse osmosis membrane assembly device 14 connect, the output end of cleaning pump 15 by threeway III respectively with the second valve 22 and The membrane stack water inlet end of pole-reversing electroosmosis system 4 is connected, the pipeline being connected in threeway III with the membrane stack water inlet end of pole-reversing electroosmosis system 4 The 6th valve 21 of upper setting, the membrane stack fresh water output end of pole-reversing electroosmosis system 4 and the membrane stack concentrated water output end of pole-reversing electroosmosis system 4 It is connected and (is not drawn into figure) with cleaning water tank by pipeline.
The processing for the high slat-containing wastewater that the present embodiment is related to and resource recycle method, specifically include following steps:
The waste water of high saliferous in wastewater tank 1, low COD is pumped into cartridge filter 3 and goes turbidity removal by (1) first elevator pump 2 The larger particulate of degree, is then delivered in the system of pole-reversing electroosmosis system 4, the salt rejection rate of pole-reversing electroosmosis system 4 is in 60-80% Between, fresh-water recovery rate is between 70%-80%;
(2) enter after pole-reversing electroosmosis system 4, the ion in desalting chamber moves to adjacent concentration in the presence of electric field Salt content is reduced in room, desalting chamber's water, salt content increase in enriched chamber's water;
(3) it is 10-10.5 that enriched chamber's concentrated water water outlet, which enters pH in regulating reservoir 8, regulation regulating reservoir 8, in step (2), then will Water is transported to addition coagulant coagulating sedimentation in coagulative precipitation tank 9, the calcium ion and magnesium ion gone in water removal, it is to avoid it is to evaporation The influence of crystallization apparatus, the water outlet of coagulative precipitation tank 9 enters in concentrated water water tank 5,
(4) desalting chamber's fresh water outlet enters in fresh water tanks 11 in step (2), and high-pressure pump 13 is by the water in fresh water tanks 11 It is pumped into reverse osmosis membrane assembly device 14, at the same time, antisludging agent is added to high-pressure pump 13 and fresh water tanks by grug feeding jar 12 In pipeline between 11, it is to avoid the calcium ions and magnesium ions remained in water are polluted to reverse osmosis membrane, reverse osmosis membrane assembly device 14 is produced Water is transported to stand-by in water producing tank 18, and the concentrated water of reverse osmosis membrane assembly device 14 is transported in concentrated water water tank 5;
(5) needs are shut down periodically right when the processing for the high slat-containing wastewater that the present embodiment is related to is used with recycling retracting device Reverse osmosis membrane assembly device 14 and the membrane stack of frequently pole-reversing electroosmosis system 4 are cleaned,
The cleaning process of reverse osmosis membrane assembly device 14 is:Close the first valve 10, the 3rd valve 20, the 6th valve 21, Five valves 23, reverse osmosis concentrated penstock 28, counter-infiltration cleaning production water return valve 26 and counter-infiltration cleaning concentrating return-flow valve 27, are opened 4th valve 19, starts water pump 17 and water is pumped into cleaning water tank 16 from water producing tank 18, counter-infiltration is added into cleaning water tank 16 Cleaning agents of membrane simultaneously stirs, and then opens the 5th valve 23, the second valve 22, counter-infiltration cleaning production water return valve 26 and reverse osmosis Cleaning concentrating return-flow valve 27, starts cleaning pump 15 thoroughly, cleans rinse water in water tank 16 and is pumped into reverse osmosis membrane assembly device 14 and divides Not Jing Guo counter-infiltration cleaning production water return valve 26 and counter-infiltration cleaning concentrating return-flow valve 27 again return in cleaning water tank 16, repeatedly Circulation is until cleaning is completed, by the cleaning reclaimed water of water tank 16 discharge;
The membrane stack cleaning process of frequently pole-reversing electroosmosis system 4:Close the 3rd valve 20, the 5th valve 23, the second valve 22nd, counter-infiltration cleaning production water return valve 26, counter-infiltration cleaning concentrating return-flow valve 27, the and of frequently pole-reversing electroosmosis system fresh water valve 25 Frequently pole-reversing electroosmosis system concentrated water valve 24, opens the 4th valve 19, starts water pump 17 and water is pumped into cleaning from water producing tank 18 Water tank 16, amberplex cleaning agents of membrane is added into cleaning water tank 16 and is stirred, and then starting cleaning pump 15 will clean Rinse water is pumped into frequently pole-reversing electroosmosis system membrane stack in water tank 16, and the cleaning that frequently pole-reversing electroosmosis system flows out is given up Water is returned in cleaning water tank 16, and repeatedly circulation is completed until cleaning, finally will the reclaimed water discharge of cleaning water tank 16.
Embodiment 2:
The reverse osmosis concentrated water that the present embodiment is produced to certain power plant is handled, reverse osmosis concentrated water:Electrical conductivity is 3000 μ S/ Cm, total hardness is 908mg/L, and COD is 98mg/L.Specific processing method, it is as follows:
(1) first elevator pump 2 is with 60m3/ h flow velocity, cartridge filter 3 is pumped into by reverse osmosis concentrated water in wastewater tank 1 The larger particulate of turbidity is removed, is then delivered in the system of pole-reversing electroosmosis system 4;
(2) enter after pole-reversing electroosmosis system 4, the ion in desalting chamber moves to adjacent concentration in the presence of electric field Salt content is reduced in room, desalting chamber's water, salt content increase in enriched chamber's water, set the salt rejection rate of pole-reversing electroosmosis system 4 as 60%, fresh-water recovery rate is 80%, then enriched chamber's concentrated water water flow is 12m after being handled by pole-reversing electroosmosis system3/ h, electricity Conductance is 9000 μ S/cm, and total hardness is 2728mg/L, and COD is 97mg/L, and desalting chamber's fresh water outlet flow is 48m3/ h, conductance Rate is 1500 μ S/cm, and total hardness is 453mg/L, and COD is 96mg/L;
(3) it is 10-10.5 that enriched chamber's concentrated water water outlet, which enters pH in regulating reservoir 8, regulation regulating reservoir 8, in step (2), then will Water is transported to addition coagulant coagulating sedimentation, the water outlet of coagulative precipitation tank 9 in coagulative precipitation tank 9:Electrical conductivity is 5960 μ S/cm, always Hardness is 62mg/L, and COD is 43mg/L, and the water outlet of coagulative precipitation tank 9 enters in concentrated water water tank 5;
(4) desalting chamber's fresh water outlet enters in fresh water tanks 11 in step (2), and high-pressure pump 13 is by the water in fresh water tanks 11 It is pumped into reverse osmosis membrane assembly device 14, at the same time, antisludging agent is added to high-pressure pump 13 and fresh water tanks by grug feeding jar 12 In pipeline between 11, it is to avoid the calcium ions and magnesium ions remained in water are polluted to reverse osmosis membrane, reverse osmosis membrane assembly device 14 is produced Water is transported to stand-by in water producing tank 18, the producing water water quality of reverse osmosis membrane assembly device 14:Electrical conductivity is 20 μ S/cm, reverse osmosis membrane group The concentrated water of part device 14 is transported in concentrated water water tank 5;
(5) reclaimed water of concentrated water water tank 5 in step (3) and step (4) is pumped into evaporated crystallization device by the second elevator pump 6 7 are evaporated crystallization, crystallize out solid salt recycling, and the distilled water that crystallization is produced is transported to stand-by in water producing tank 18.

Claims (3)

1. a kind of processing of high slat-containing wastewater and recycling retracting device, it is characterised in that including wastewater tank, the first lifting Pump, cartridge filter, pole-reversing electroosmosis system, regulating reservoir, coagulative precipitation tank, concentrated water water tank, the second elevator pump, evaporative crystallization dress Put, fresh water tanks, grug feeding jar, counter-infiltration system and water producing tank;Wastewater tank water side is sequentially connected first by pipeline and carried Pump and cartridge filter are risen, cartridge filter water side is connected with pole-reversing electroosmosis system, the output of pole-reversing electroosmosis system concentrated water End is connected with regulating reservoir, coagulative precipitation tank, concentrated water water tank, the second elevator pump and evaporated crystallization device successively, pole-reversing electroosmosis system System fresh water output end is connected with fresh water tanks and counter-infiltration system successively, and grug feeding jar output end is connected to fresh water tanks and counter-infiltration On pipeline between system, counter-infiltration system production water water side is connected with water producing tank.
2. the processing of high slat-containing wastewater according to claim 1 and recycling retracting device, it is characterised in that the electric osmose of falling pole Analysis system can auto switching polarity of electrode and simultaneously change dense, light flow direction automatically;Pole-reversing electroosmosis system is using homogeneous Amberplex.
3. the processing of high slat-containing wastewater according to claim 2 and recycling retracting device, it is characterised in that counter-infiltration system System includes high-pressure pump and reverse osmosis membrane assembly device, the processing of high slat-containing wastewater and recycling retracting device also including cleaning pump, Clean the purging system that water tank and water pump are constituted, purging system is realized to counter-infiltration system and frequently pole-reversing electroosmosis system Cleaning, grug feeding jar output end is connected on the pipeline between fresh water tanks and high-pressure pump, and high pressure pump output terminal is distinguished by threeway I It is connected, is set on the pipeline that threeway I is connected with high-pressure pump with reverse osmosis membrane assembly device water inlet end and cleaning pump pipeline at output The first valve is put, the second valve is set on the pipeline that threeway I is connected with cleaning pump output terminal, water producing tank is distinguished by threeway II It is connected with reverse osmosis membrane assembly device fresh water outlet end and water pump water inlet end pipeline, in threeway II and reverse osmosis membrane assembly device The 3rd valve is set on the pipeline of fresh water outlet end connection, the 4th is set on the pipeline that threeway II is connected with water pump water inlet end Valve, water intaking pump output terminal is connected with cleaning water tank, and cleaning water tank passes through the 5th valve and cleaning pump water inlet end downlink connection, cleaning Water tank is connected by pipeline with reverse osmosis membrane assembly device fresh water outlet end and reverse osmosis membrane assembly device concentrated water water side respectively, Cleaning pump output terminal is connected with the second valve and pole-reversing electroosmosis system membrane stack water inlet end respectively by threeway III, in threeway III 6th valve, the output of pole-reversing electroosmosis system membrane stack fresh water are set on the pipeline being connected with pole-reversing electroosmosis system membrane stack water inlet end End and pole-reversing electroosmosis system membrane stack concentrated water output end are connected by pipeline with cleaning water tank.
CN201720180191.3U 2017-02-28 2017-02-28 A kind of processing of high slat-containing wastewater and resource recovery device Expired - Fee Related CN206529367U (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110002654A (en) * 2019-05-13 2019-07-12 浙江嘉化新材料有限公司 A kind of high-salt wastewater discharge treating system

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110002654A (en) * 2019-05-13 2019-07-12 浙江嘉化新材料有限公司 A kind of high-salt wastewater discharge treating system

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Effective date of registration: 20191204

Address after: 266000 room 234, No.68, hailun Road, Sifang District, Qingdao, Shandong Province

Patentee after: QINGDAO NORTH ENERGY AND ENVIRONMENT CO., LTD.

Address before: 266200 Shandong Qingdao blue Silicon Valley core area Pioneer Center

Patentee before: Qingdao bluevale Chemical Co. Ltd.

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CF01 Termination of patent right due to non-payment of annual fee