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CN206497882U - Nano metal substrate for ultra fine-line FPC and COF material - Google Patents

Nano metal substrate for ultra fine-line FPC and COF material Download PDF

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Publication number
CN206497882U
CN206497882U CN201720125606.7U CN201720125606U CN206497882U CN 206497882 U CN206497882 U CN 206497882U CN 201720125606 U CN201720125606 U CN 201720125606U CN 206497882 U CN206497882 U CN 206497882U
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layer
thickness
copper foil
metal level
ultrathin nanometer
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CN201720125606.7U
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林志铭
李韦志
李建辉
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Asia Electronic Material Co Ltd
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Asia Electronic Material Co Ltd
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Abstract

The utility model discloses a kind of nano metal substrate for ultra fine-line FPC and COF material; including polyimide layer, the ultrathin nanometer metal level and protection film layer of the polyimide layer at least one side are formed at, the ultrathin nanometer metal level is between the polyimide layer and the protection film layer;The thickness of the polyimide layer is 5 50um;The thickness of the ultrathin nanometer metal level is 0.09 0.8um;The thickness of the protection film layer is 6 60um;The polyimide layer is polyimide layer of the surface roughness between 80 800nm;The ultrathin nanometer metal level is sputtered layer or electrodeposited coating.The utility model has splendid resistance to ion transport, dimensional stability, resistance to chemical reagents, heat resisting and adhesion;Suitable for laser processing, it is adaptable to processing blind hole by laser/micropore, and pin hole is not likely to produce, is adapted to fine rule road etching, is difficult lateral erosion;The utility model is designed using Nanometer Copper, meets the demand of substrate graph thinning development.

Description

Nano metal substrate for ultra fine-line FPC and COF material
Technical field
The utility model belongs to electric substrate technical field, more particularly to a kind of to be used for ultra fine-line FPC and COF material Nano metal substrate.
Background technology
FPC (Flexible Printed Circuit), i.e. flexible printed circuit board, are commonly called as " soft board ", with it is light, thin, Short, small the advantages of, it is widely adopted in the small-sized electronic products such as mobile phone, digital camera, digital camera, and COF (Chip On Film, chip on film encapsulation) technology is to make encapsulation chip carrier by chip and flexible PCB electricity with flexible PCB The technology that road is combined.As electronic product tends to microminaturization development, FPC or COF flexible PCBs are functionally required to more Developing direction that is powerful and tending to high frequency, high density and graph thinning.
Flexibility coat copper plate is the baseplate material of FPC or COF processing, and the high density of flexibility coat copper plate, the performance of graph thinning It is largely dependent on the processing technology of thin copper foil part.
Processing of the current substrate manufacturer to thin copper foil part mainly uses two class methods:One is sputtering method/copper-plating method, and two are Carrier copper foil method.
Sputtering method/copper-plating method, using PI (polyimides) films as base material, alloy of the sputter containing chromium is used as intermediary on PI films Layer, then sputter copper metal are crystal seed layer, and then electro-coppering thickens layers of copper.But general PI film surface roughnesses are in 10-20nm, Adhesion is not good, it is necessary to be surface-treated to PI films with plasma-based or short wavelength ultraviolet, but the PI films after processing are to follow-up Heat treatment requirements are high, and otherwise adhesion deterioration is peeled off;Further, since the surface of PI films has certain roughness, in very thin copper Surface easily produces pin hole when paper tinsel is electroplated;And the thin copper foil that this method is made often results in etching in COF or FPC etch process Not exclusively, circuit root residual minim obtains the problem of chromium metal can cause Ion transfer, and influences fine rule road COF or FPC Quality.
And carrier copper foil method, although carrier layer protects copper foil not injured, pressure wound, but may be difficult to peel off when peeling off, and makes Into processing difficulties, and the stress-retained copper foil that easily causes when peeling off is deformed and the change of size harmomegathus, in addition, extra thin copper foil price It is expensive and be difficult to obtain, add extra thin copper foil processing and be difficult, so existing copper thickness is difficult to be less than less than 6 μm.
Utility model content
The utility model is mainly solving the technical problems that provide a kind of nanometer for ultra fine-line FPC and COF material Metal substrate, with splendid resistance to ion transport, dimensional stability, resistance to chemical reagents, heat resisting and adhesion;It is applicable In laser processing, it is adaptable to processing blind hole by laser/micropore, and pin hole is not likely to produce, is adapted to fine rule road etching, is difficult lateral erosion;This Utility model is designed using Nanometer Copper, meets the demand of substrate graph thinning development.
In order to solve the above technical problems, the technical scheme that the utility model is used is:There is provided a kind of for superfine wire The nano metal substrate of road FPC and COF material, including polyimide layer, it is formed at the super of the polyimide layer at least one side Thin nano metal layer and protection film layer, the ultrathin nanometer metal level between the polyimide layer and the protection film layer it Between;
The thickness of the polyimide layer is 5-50um;
The thickness of the ultrathin nanometer metal level is 0.09-0.8um;
The thickness of the protection film layer is 6-60um;
The polyimide layer is polyimide layer of the surface roughness between 80-800nm;
The ultrathin nanometer metal level is sputtered layer or electrodeposited coating.
Further say, the nano metal substrate is by polyimide layer, is formed at the polyimide layer any surface Ultrathin nanometer metal level and the one side nano metal substrate that is constituted of protection film layer.
Further say, the nano metal substrate be by polyimide layer, to be formed at the polyimide layer two-sided The double-face nanometer metal substrate that ultrathin nanometer metal level and protection film layer are constituted.
Further say, the thickness of the polyimide layer is 25-50um, and the thickness of the ultrathin nanometer metal level is 0.09-0.2um, the thickness of the protection film layer is 28-60um.
Further say, the ultrathin nanometer metal level is the multilayer that copper foil layer or copper foil layer are constituted with another metal level Alloying metal layer, another metal level refers to silver layer, nickel dam, layers of chrome, palladium layers, aluminium lamination, titanium layer, layers of copper, molybdenum layer, indium layer, platinum At least one of layer and layer gold, wherein, the thickness of the copper foil layer is 0.09-0.2um, and the thickness of another metal level is 0.005-0.015um。
Further say, the ultrathin nanometer metal level is one kind in following six kinds of structures:
First, a Rotating fields:It is made up of individual layer copper foil layer, the thickness of the copper foil layer is 0.1-0.2um;
2nd, two stacking structure:It is made up of copper foil layer and the nickel dam for being formed at copper foil layer any surface, the thickness of the copper foil layer Spend for 0.09-0.15um, the thickness of the nickel dam is 0.005-0.015um;
3rd, two stacking structure:It is made up of copper foil layer and the silver layer for being formed at copper foil layer any surface, the thickness of the copper foil layer For 0.09-0.15um, the thickness of the silver layer is 0.005-0.015um;
4th, three stacking structure:By copper foil layer and it is formed at and the laminated nickel dam of copper foil and is formed at copper foil layer another side Silver layer is constituted, and the thickness of the copper foil layer is 0.09-0.15um, and the thickness of the nickel dam and the silver layer is respectively 0.005- 0.015um;
5th, three stacking structure:It is made up of copper foil layer and the nickel dam for being respectively formed in copper foil layer two sides, the thickness of the copper foil layer Spend for 0.09-0.15um, the thickness of nickel dam is respectively 0.005-0.015um described in two sides;
6th, three stacking structure:By copper foil layer and it is formed at and the laminated layers of copper of copper foil and is formed at copper foil layer another side Nickel dam is constituted, and the thickness of the copper foil layer is 0.09-0.15um, and the thickness of the layers of copper and the nickel dam is respectively 0.005- 0.015um。
Further say, the protection film layer is carrier layer, the carrier layer is by pet layer (poly terephthalic acid second Diester) and be formed at the low adhesion layer on a surface of the pet layer and constitute, the carrier layer passes through the low adhesion layer The ultrathin nanometer layer on surface of metal is covered on, wherein, the thickness of the pet layer is 23-50um, the thickness of the low adhesion layer For 5-10um.
Further say, the protection film layer is photopolymer layer, the photopolymer layer includes photosensitive resin layer and light-transmissive film layer, institute State the one side covering light-transmissive film layer of photosensitive resin layer and another side is covered on the ultrathin nanometer layer on surface of metal.
The beneficial effects of the utility model at least have it is following some:
First, because polyimide layer of the present utility model uses PI of the surface roughness between 80-800nm Film, the PI films are a kind of PI resins of process roughening treatment, can increase the adhesion with metal alloy, and its surface coarsening Processing also passes through surface corona or plasma-based processing, can be lifted surface can, increase polyimide layer and ultrathin nanometer metal level it Between adhesion;
2nd, the utility model ultrathin nanometer metal level includes the multilayer alloying metal that copper foil layer is constituted with another metal level Layer, the resistance to ion transport being designed with beneficial to raising nano metal substrate of alloy-layer, improves the graph thinning of FPC or COF materials Quality and insulating properties;
3rd, protection film layer of the present utility model can select carrier layer or photopolymer layer, and carrier film or dry film are suitable for half Addition process technique, the slim highdensity graph thinning line requirements of the more applicable FPC or COF materials of technology of semi-additive process;And carry Body film and dry film can protect not injured, pressure wound and the oxidation before FPC or the addition processing procedures of COF half of ultrathin nanometer metal level;
When protection film layer selects carrier layer, carrier layer is made up of pet layer and low adhesion layer, and carrier layer passes through low Adhesion layer is covered on ultrathin nanometer layer on surface of metal, and PET temperature tolerance is in 180-220, and DEG C heat resisting is good;Low adhesion layer Off-type force be only 1-5g, therefore carrier layer is easily stripped, and does not easily cause the viscous glutinous copper particle of nano metal substrate after stripping In in carrier film, the small ultrathin nanometer metal level that do not result in of residual stress is deformed during stripping, and the dimensional stability of substrate is not influenceed, Be conducive to use and the lifting yield of Downstream processing;
When protection film layer selects photopolymer layer, photopolymer layer includes photosensitive resin layer and light-transmissive film layer, the one of photosensitive resin layer Face covers light-transmissive film layer and another side is covered on ultrathin nanometer layer on surface of metal, by ultraviolet irradiation, in photosensitive resin layer Part resin crosslinks curing reaction, forms a kind of material of stabilization and is attached in plate face, then develop, demoulding, needed for producing Circuit, thus it is high using dry film imaging reliability, it is possible to reduce Downstream processing process, it is allowed to be directly used in the erosion of exposure imaging circuit Carve, be advantageously implemented mechanization and automation;
4th, when low adhesion layer selects high temperature resistant silicon glue adhesion layer or acrylic acid adhesion layer, its adherence is splendid, and high temperature is high The wet lower interface with ultrathin nanometer metal level will not delamination/separate;
5th, nano metal substrate of the present utility model will not be crimped, and dimensional stability is excellent, be adapted to laser processing, Suitable for micropore/blind hole and the requirement of any hole shape;And multiple sputter or multi-layer plating alloy are used, plating aspect copper is uniform, no Pin hole is also easy to produce, is adapted to fine rule road etching, is difficult lateral erosion;
6th, the thickness of ultrathin nanometer metal level of the present utility model be 0.1-0.2um, line width/line-spacing can to 15/15um, Even 10/10um or lower line requirements, the graph thinning that the design of Nanometer Copper meets FPC or COF substrates is required.
Brief description of the drawings
Fig. 1 is the structural representation of the utility model embodiment (by taking double-face nanometer metal substrate as an example);
Fig. 2 is the structural representation of the utility model carrier layer;
Fig. 3 is the structural representation of the utility model photopolymer layer;
Fig. 4 is the first schematic diagram in six kinds of structures of the utility model ultrathin nanometer metal level;
Fig. 5 is second of schematic diagram in six kinds of structures of the utility model ultrathin nanometer metal level;
Fig. 6 is the third schematic diagram in six kinds of structures of the utility model ultrathin nanometer metal level;
Fig. 7 is the 4th kind of schematic diagram in six kinds of structures of the utility model ultrathin nanometer metal level;
Fig. 8 is the 5th kind of schematic diagram in six kinds of structures of the utility model ultrathin nanometer metal level;
Fig. 9 is the 6th kind of schematic diagram in six kinds of structures of the utility model ultrathin nanometer metal level;
The mark of each part is as follows in accompanying drawing:
100- polyimide layers;
200- ultrathin nanometer metal levels;
201- copper foil layers, 202- nickel dams, 203- silver layers, 204- layers of copper;
300- protection film layers;
301-PET layers, the low adhesion layers of 302-, 303- photosensitive resin layers and 304- light-transmissive film layers.
Embodiment
Preferred embodiment of the present utility model is described in detail below in conjunction with the accompanying drawings, so that advantage of the present utility model It can be easier to be readily appreciated by one skilled in the art with feature, so as to make protection domain of the present utility model apparent clear and definite Define.
Embodiment:A kind of nano metal substrate for ultra fine-line FPC and COF material, the utility model includes polyamides Imine layer 100, the ultrathin nanometer metal level 200 and protection film layer 300 for being formed at least one side of polyimide layer 100, institute Ultrathin nanometer metal level 200 is stated between the polyimide layer 100 and the protection film layer 300;
The thickness of the polyimide layer 100 is 5-50um;
The thickness of the ultrathin nanometer metal level 200 is 0.09-0.8um;
The thickness of the protection film layer 300 is 6-60um;
The polyimide layer 100 is polyimide layer of the surface roughness between 80-800nm.The utility model Polyimide layer is using roughness in 80-800nm PI films, and optimization is between 80-400nm, the roughness of general PI films For 10-20nm, adhesion is not good, the PI films are a kind of PI resins of process roughening treatment, can increase and be connect with metal alloy Put forth effort, and the PI films also pass through surface corona or plasma-based processing, can lift surface energy, and increase polyimide layer is received with ultra-thin The adhesion of rice metal level.
The ultrathin nanometer metal level 200 is sputtered layer or electrodeposited coating.
The nano metal substrate is by polyimide layer 100, is formed at the ultra-thin of any surface of polyimide layer 100 The one side nano metal substrate that nano metal layer 200 and protection film layer 300 are constituted.
As shown in figure 1, in the present embodiment, the nano metal substrate is by polyimide layer 100, is formed at described gather The double-face nanometer metal substrate that the two-sided ultrathin nanometer metal level 200 of imide layer 100 and protection film layer 300 are constituted.
The thickness of the polyimide layer 100 is 25-50um, and the thickness of the ultrathin nanometer metal level 200 is 0.09- 0.2um, the thickness of the protection film layer 300 is 28-60um.
The ultrathin nanometer metal level 200 be copper foil layer 201 or copper foil layer 201 with another metal level constitute it is how laminated Gold metal layer, another metal level refers to silver layer, nickel dam, layers of chrome, palladium layers, aluminium lamination, titanium layer, layers of copper, molybdenum layer, indium layer, platinum layer At least one of with layer gold, wherein, the thickness of the copper foil layer 201 is 0.09-0.2um, the thickness of another metal level For 0.005-0.015um.
The ultrathin nanometer metal level 200 is one kind in following six kinds of structures:
First, a Rotating fields:As shown in figure 4, being made up of individual layer copper foil layer 201, the thickness of the copper foil layer 201 is 0.1- 0.2um;
2nd, two stacking structure:As shown in figure 5, be made up of copper foil layer 201 and the nickel dam 202 for being formed at copper foil layer any surface, The thickness of the copper foil layer 201 is 0.09-0.15um, and the thickness of the nickel dam 202 is 0.005-0.015um;
3rd, two stacking structure:As shown in fig. 6, be made up of copper foil layer 201 and the silver layer 203 for being formed at copper foil layer any surface, The thickness of the copper foil layer 201 is 0.09-0.15um, and the thickness of the silver layer 203 is 0.005-0.015um;
4th, three stacking structure:As shown in fig. 7, by copper foil layer 201 and being formed at the laminated nickel dam 202 of copper foil and being formed Constituted in the silver layer 203 of copper foil layer another side, the thickness of the copper foil layer 201 is 0.09-0.15um, the nickel dam 202 and institute State the thickness respectively 0.005-0.015um of silver layer 203;
5th, three stacking structure:As shown in figure 8, by copper foil layer 201 and being respectively formed in the structure of nickel dam 202 on copper foil layer two sides Into the thickness of the copper foil layer 201 is 0.09-0.15um, and the thickness of nickel dam 202 is respectively 0.005-0.015um described in two sides;
6th, three stacking structure:As shown in figure 9, by copper foil layer 201 and being formed at the laminated layers of copper 204 of copper foil and being formed Constituted in the nickel dam 202 of copper foil layer another side, the thickness of the copper foil layer 201 is 0.09-0.15um, the layers of copper 204 and institute State the thickness respectively 0.005-0.015um of nickel dam 202.
As shown in Fig. 2 the protection film layer 300 is carrier layer, the carrier layer is by pet layer 301 and is formed at The low adhesion layer 302 on one surface of the pet layer 301 is constituted, and the carrier layer is covered on by the low adhesion layer 302 The surface of ultrathin nanometer metal level 200, wherein, the thickness of the pet layer 301 is 23-50um, the low adhesion layer 302 Thickness is 5-10um, and the off-type force of the low adhesion layer 302 is 1-5g.
When low adhesion layer selects high temperature resistant silicon glue adhesion layer or acrylic acid adhesion layer, its adherence is splendid, hot and humid Under, will not delamination/separate with the interface of ultrathin nanometer metal level.
As shown in figure 3, the protection film layer 300 is photopolymer layer, the photopolymer layer includes photosensitive resin layer 303 and light-transmissive film Layer 304, the one side of the photosensitive resin layer 303 covers the light-transmissive film layer 304 and another side is covered on the ultrathin nanometer gold Belong to the surface of layer 200.
Protection film layer of the present utility model can select carrier layer or photopolymer layer, and carrier film or dry film are suitable for half addition Method technique, the slim highdensity graph thinning line requirements of the more applicable FPC or COF materials of technology of semi-additive process.
Embodiment of the present utility model is the foregoing is only, the scope of the claims of the present utility model is not thereby limited, it is every The equivalent structure transformation made using the utility model specification and accompanying drawing content, or directly or indirectly it is used in other correlations Technical field, is similarly included in scope of patent protection of the present utility model.

Claims (8)

1. a kind of nano metal substrate for ultra fine-line FPC and COF material, it is characterised in that:Including polyimide layer, shape The ultrathin nanometer metal level and protection film layer of polyimide layer at least one side described in Cheng Yu, the ultrathin nanometer metal level is between institute State between polyimide layer and the protection film layer;
The thickness of the polyimide layer is 5-50um;
The thickness of the ultrathin nanometer metal level is 0.09-0.8um;
The thickness of the protection film layer is 6-60um;
The polyimide layer is polyimide layer of the surface roughness between 80-800nm;
The ultrathin nanometer metal level is sputtered layer or electrodeposited coating.
2. the nano metal substrate according to claim 1 for ultra fine-line FPC and COF material, it is characterised in that:Institute Stating nano metal substrate is by polyimide layer, is formed at ultrathin nanometer metal level and the protection of the polyimide layer any surface The one side nano metal substrate that film layer is constituted.
3. the nano metal substrate according to claim 1 for ultra fine-line FPC and COF material, it is characterised in that:Institute Stating nano metal substrate is by polyimide layer, is formed at the polyimide layer two-sided ultrathin nanometer metal level and diaphragm The double-face nanometer metal substrate that layer is constituted.
4. the nano metal substrate according to claim 1 for ultra fine-line FPC and COF material, it is characterised in that:Institute The thickness for stating polyimide layer is 25-50um, and the thickness of the ultrathin nanometer metal level is 0.09-0.2um, the protection film layer Thickness be 28-60um.
5. the nano metal substrate according to claim 1 for ultra fine-line FPC and COF material, it is characterised in that:Institute It is the multilayer alloying metal layer that copper foil layer or copper foil layer are constituted with another metal level, another gold to state ultrathin nanometer metal level Category layer refers at least one of silver layer, nickel dam, layers of chrome, palladium layers, aluminium lamination, titanium layer, layers of copper, molybdenum layer, indium layer, platinum layer and layer gold, Wherein, the thickness of the copper foil layer is 0.09-0.2um, and the thickness of another metal level is 0.005-0.015um.
6. the nano metal substrate according to claim 5 for ultra fine-line FPC and COF material, it is characterised in that:Institute It is one kind in following six kinds of structures to state ultrathin nanometer metal level:
First, a Rotating fields:It is made up of individual layer copper foil layer, the thickness of the copper foil layer is 0.1-0.2um;
2nd, two stacking structure:It is made up of copper foil layer and the nickel dam for being formed at copper foil layer any surface, the thickness of the copper foil layer is 0.09-0.15um, the thickness of the nickel dam is 0.005-0.015um;
3rd, two stacking structure:It is made up of copper foil layer and the silver layer for being formed at copper foil layer any surface, the thickness of the copper foil layer is 0.09-0.15um, the thickness of the silver layer is 0.005-0.015um;
4th, three stacking structure:By copper foil layer and it is formed at and the laminated nickel dam of copper foil and is formed at the silver layer of copper foil layer another side Constitute, the thickness of the copper foil layer is 0.09-0.15um, the thickness of the nickel dam and the silver layer is respectively 0.005- 0.015um;
5th, three stacking structure:It is made up of copper foil layer and the nickel dam for being respectively formed in copper foil layer two sides, the thickness of the copper foil layer is 0.09-0.15um, the thickness of nickel dam is respectively 0.005-0.015um described in two sides;
6th, three stacking structure:By copper foil layer and it is formed at and the laminated layers of copper of copper foil and is formed at the nickel dam of copper foil layer another side Constitute, the thickness of the copper foil layer is 0.09-0.15um, the thickness of the layers of copper and the nickel dam is respectively 0.005- 0.015um。
7. the nano metal substrate according to claim 1 for ultra fine-line FPC and COF material, it is characterised in that:Institute It is carrier layer to state protection film layer, and the carrier layer is by pet layer and is formed at the low of surface of the pet layer and sticks together Layer is constituted, and the carrier layer is covered on the ultrathin nanometer layer on surface of metal by the low adhesion layer, wherein, the PET The thickness of layer is 23-50um, and the thickness of the low adhesion layer is 5-10um.
8. the nano metal substrate according to claim 1 for ultra fine-line FPC and COF material, it is characterised in that:Institute It is photopolymer layer to state protection film layer, and the photopolymer layer includes photosensitive resin layer and light-transmissive film layer, and the one side of the photosensitive resin layer is covered Cover the light-transmissive film layer and another side is covered on the ultrathin nanometer layer on surface of metal.
CN201720125606.7U 2017-02-13 2017-02-13 Nano metal substrate for ultra fine-line FPC and COF material Active CN206497882U (en)

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TW106133369A TWI655095B (en) 2017-02-13 2017-09-28 Nano metal substrate for FPC and COF materials

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602899A (en) * 2017-09-21 2018-01-19 珠海市创元电子材料有限公司 A kind of polyimide film, its manufacture method and application

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Publication number Priority date Publication date Assignee Title
CN109825212A (en) * 2019-03-07 2019-05-31 昆山雅森电子材料科技有限公司 Ultra-thin cover film of LED high reflectivity and preparation method thereof
CN112153800A (en) * 2019-06-27 2020-12-29 昆山雅森电子材料科技有限公司 A kind of double-layer covering film with high reflection performance and preparation method thereof

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JPWO2013183632A1 (en) * 2012-06-07 2016-02-01 タツタ電線株式会社 Shield film and shield printed wiring board

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107602899A (en) * 2017-09-21 2018-01-19 珠海市创元电子材料有限公司 A kind of polyimide film, its manufacture method and application

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