CN206362861U - A resistance testing device for lithium-ion battery pole piece coating material - Google Patents
A resistance testing device for lithium-ion battery pole piece coating material Download PDFInfo
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- 238000012360 testing method Methods 0.000 title claims abstract description 63
- 239000000463 material Substances 0.000 title claims abstract description 26
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 229910001416 lithium ion Inorganic materials 0.000 title claims abstract description 21
- 239000011248 coating agent Substances 0.000 title claims abstract description 7
- 238000000576 coating method Methods 0.000 title claims abstract description 7
- 239000000523 sample Substances 0.000 claims abstract description 41
- 230000008021 deposition Effects 0.000 claims 3
- 238000012827 research and development Methods 0.000 abstract description 11
- 238000011156 evaluation Methods 0.000 abstract description 4
- 238000002474 experimental method Methods 0.000 abstract description 4
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000002482 conductive additive Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 239000007774 positive electrode material Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 238000012795 verification Methods 0.000 description 1
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Abstract
Description
技术领域technical field
本实用新型涉及一种锂离子电池检测装置,特别是涉及一种锂离子电池极片涂布材料的电阻测试装置。The utility model relates to a lithium-ion battery testing device, in particular to a resistance testing device for a lithium-ion battery pole piece coating material.
背景技术Background technique
锂离子电池内阻是指电池在工作时,电流流过电池内部所受到的阻力。有欧姆内阻与极化内阻两部分组成。电池内阻大,会导致电池放电工作电压降低,放电时间缩短。内阻大小主要受电池的材料、制造工艺、电池结构等因素的影响。是衡量电池性能的一个重要参数。锂离子电池行业的研发人员会在电池设计的时候就会考虑锂离子电池的内阻。因此,在锂离子电池设计的时候,其正负极材料都会加入适量的导电添加剂,来降低锂离子电池的内阻。在保证电池容量和电性能的前提下,尽可能把电池内阻降低。然而,通过制作成电池来评测材料体系的导电性能,制作电池周期较长,且制作电池需要花费成本较大。The internal resistance of a lithium-ion battery refers to the resistance encountered by the current flowing through the interior of the battery when the battery is working. It is composed of two parts: ohmic internal resistance and polarization internal resistance. The large internal resistance of the battery will reduce the working voltage of the battery and shorten the discharge time. The internal resistance is mainly affected by factors such as battery material, manufacturing process, and battery structure. It is an important parameter to measure battery performance. R&D personnel in the lithium-ion battery industry will consider the internal resistance of lithium-ion batteries when designing batteries. Therefore, when designing a lithium-ion battery, an appropriate amount of conductive additives will be added to the positive and negative electrode materials to reduce the internal resistance of the lithium-ion battery. Under the premise of ensuring the battery capacity and electrical performance, the internal resistance of the battery should be reduced as much as possible. However, the electrical conductivity of the material system is evaluated by making a battery, which takes a long period of time to make a battery, and the cost of making a battery is relatively high.
发明内容Contents of the invention
本实用新型的目的就是针对上述问题,提供一种锂离子电池极片涂布材料的电阻测试装置。The purpose of this utility model is to provide a resistance testing device for lithium-ion battery pole piece coating materials to solve the above problems.
本实用新型所采用的技术方案是:一种锂离子电池极片涂布材料的电阻测试装置,包括:一个测试台、数块测试导电块、一个内阻测试仪和测试样品膜片,测试台上端设有平面工作台,工作台中部设有横向的样品放置区,样品放置区的长边边沿设有刻度尺,工作台面下设有内阻测试仪,内阻测试仪探针通过导线连接测试导电块,测试时测试样品横向的样品放置区,测试导电块按设定的间距放在测试样品上。The technical scheme adopted by the utility model is: a resistance test device for coating materials of lithium-ion battery pole pieces, including: a test bench, several test conductive blocks, an internal resistance tester and a test sample diaphragm, and a test bench There is a flat workbench at the upper end, a horizontal sample placement area in the middle of the workbench, a scale is provided on the long side of the sample placement area, and an internal resistance tester is installed under the worktable, and the probe of the internal resistance tester is tested by wire connection. The conductive block is the sample placement area in the lateral direction of the test sample during the test, and the test conductive block is placed on the test sample at a set interval.
所述的内阻测试仪设有四个探针,其中两个为电压信号测试探针,另两个电流信号测试探针。The internal resistance tester is provided with four probes, two of which are voltage signal test probes, and the other two are current signal test probes.
本实用新型的有益效果:本发明能测量出锂离子电池材料的电阻,计算出材料的电阻率,能够快速评价锂离子电池材料体系的导电性能,缩短材料体系的评价周期,缩短电池研发的周期,减少实验投入,降低研发成本。Beneficial effects of the utility model: the invention can measure the resistance of the lithium-ion battery material, calculate the resistivity of the material, quickly evaluate the conductivity of the lithium-ion battery material system, shorten the evaluation cycle of the material system, and shorten the cycle of battery research and development , reduce experimental investment and reduce research and development costs.
附图说明Description of drawings
图1为本实用新型其中一个实施例的示意图。Fig. 1 is a schematic diagram of one embodiment of the present invention.
具体实施方式detailed description
下面将结合本实用新型实施例中的附图,对本实用新型实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本实用新型的一部分实施例,而不是全部的实施例。基于本实用新型中的实施例,本领域普通技术人员在没有做出创造性劳动的前提下所获得的所有其他实施例,都属于本实用新型保护的范围。The technical solutions in the embodiments of the present invention will be clearly and completely described below in conjunction with the accompanying drawings in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of them. Example. Based on the embodiments of the present utility model, all other embodiments obtained by persons of ordinary skill in the art without making creative efforts belong to the scope of protection of the present utility model.
如图1所示,本实用新型包括:一个测试台1、数块测试导电块3、一个内阻测试仪2和测试样品膜片4,测试台上端设有平面工作台11,工作台中部设有横向的样品放置区111,样品放置区的长边边沿设有刻度尺,工作台面下设有内阻测试仪2,内阻测试仪探针通过导线连接测试导电块,测试时测试样品横向的样品放置区,测试导电块按设定的间距放在测试样品上。As shown in Figure 1, the utility model includes: a test bench 1, several test conductive blocks 3, an internal resistance tester 2 and a test sample diaphragm 4, the upper end of the test bench is provided with a plane workbench 11, and the middle part of the workbench is provided with There is a horizontal sample placement area 111, a scale is provided on the long edge of the sample placement area, and an internal resistance tester 2 is provided under the work surface, and the probe of the internal resistance tester is connected to the test conductive block by a wire, and the lateral direction of the sample is tested during the test. In the sample placement area, the test conductive blocks are placed on the test sample at a set interval.
内阻测试仪设有四个探针21,其中两个为电压信号测试探针,另两个电流信号测试探针。本发明能测量出锂离子电池材料的电阻,计算出材料的电阻率,能够快速评价锂离子电池材料体系的导电性能,缩短材料体系的评价周期,缩短电池研发的周期,减少实验投入,降低研发成本。The internal resistance tester is provided with four probes 21, two of which are voltage signal test probes, and the other two are current signal test probes. The invention can measure the resistance of the lithium-ion battery material, calculate the resistivity of the material, quickly evaluate the conductivity of the lithium-ion battery material system, shorten the evaluation cycle of the material system, shorten the cycle of battery research and development, reduce experimental investment, and reduce research and development cost.
将需要测试电池材料均匀涂覆在PET绝缘的薄膜上烘烤干,制成15CM*25CM长方形的片状测试样品,将测试样置于绝缘的测试平面上,然后把四个测试冶具按要求放到测试样品上,通过移动其中一个测试冶具,记录相应该的内阻数据。然后通过ρ= Rdw/ L 电阻率公式计算出材料体系的电阻率,对比各材料体系的导电性能差异,筛选出电阻率低的材料体系。测试原理为:跟据ρ= Rdw/ L 电阻率公式,测量定距离的样品的电阻,可拟合计算出电阻率。(ρ-电阻率、R-电阻、d-测试样品厚度、w-测试样品宽度、L-冶具电位距离)。Evenly coat the battery material to be tested on the PET insulating film and bake it dry to make a 15CM*25CM rectangular sheet test sample, place the test sample on the insulating test plane, and then place the four test fixtures as required Go to the test sample, and record the corresponding internal resistance data by moving one of the test fixtures. Then, the resistivity of the material system is calculated by the formula of ρ= Rdw/ L resistivity, and the difference in electrical conductivity of each material system is compared to screen out the material system with low resistivity. The test principle is: According to the resistivity formula of ρ= Rdw/ L, measure the resistance of the sample at a fixed distance, and the resistivity can be calculated by fitting. (ρ-resistivity, R-resistance, d-test sample thickness, w-test sample width, L-tool potential distance).
为了排除测试的误差,提高测试数据的可靠性,数据采集多个数据点。跟据上述测试结果,计算出电阻率为配方五电阻率更小,可排除其它配方,直接 选取配方五进行验证实验。减少了配方筛选实验的次数,从而达到缩短锂离子电池研发周期,减少研发成本投入。此电阻测试装置,操作简单,缩短材料体系的评价周期,减少实验投入,降低研发成本,在锂离子电池研发方面具较高的使用价值。In order to eliminate the error of the test and improve the reliability of the test data, the data is collected with multiple data points. According to the above test results, the calculated resistivity of formula 5 is smaller, and other formulas can be excluded, and formula 5 is directly selected for verification experiments. The number of formula screening experiments is reduced, thereby shortening the research and development cycle of lithium-ion batteries and reducing research and development costs. The resistance testing device is simple to operate, shortens the evaluation cycle of the material system, reduces experiment investment, reduces research and development costs, and has high use value in the research and development of lithium-ion batteries.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN107478906A (en) * | 2017-08-03 | 2017-12-15 | 国联汽车动力电池研究院有限责任公司 | A kind of method for measuring interface resistance between battery pole piece coating and foil |
CN108196123A (en) * | 2017-12-27 | 2018-06-22 | 惠州亿纬锂能股份有限公司 | A kind of evaluation method of lithium ion battery cell internal resistance exception |
CN108226641A (en) * | 2017-12-30 | 2018-06-29 | 湖北金泉新材料有限责任公司 | A kind of test method of anode material for lithium-ion batteries conductivity |
CN113008942A (en) * | 2021-03-04 | 2021-06-22 | 上海恩捷新材料科技有限公司 | Method and system for detecting dispersibility of coating film coating slurry |
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2016
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Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107478906A (en) * | 2017-08-03 | 2017-12-15 | 国联汽车动力电池研究院有限责任公司 | A kind of method for measuring interface resistance between battery pole piece coating and foil |
CN107478906B (en) * | 2017-08-03 | 2020-08-04 | 国联汽车动力电池研究院有限责任公司 | Method for measuring interface resistance between battery pole piece coating and foil |
CN108196123A (en) * | 2017-12-27 | 2018-06-22 | 惠州亿纬锂能股份有限公司 | A kind of evaluation method of lithium ion battery cell internal resistance exception |
CN108196123B (en) * | 2017-12-27 | 2020-07-14 | 惠州亿纬锂能股份有限公司 | Method for judging abnormity of internal resistance of lithium ion battery cell |
CN108226641A (en) * | 2017-12-30 | 2018-06-29 | 湖北金泉新材料有限责任公司 | A kind of test method of anode material for lithium-ion batteries conductivity |
CN108226641B (en) * | 2017-12-30 | 2020-08-11 | 湖北亿纬动力有限公司 | A kind of test method of conductivity of positive electrode material of lithium ion battery |
CN113008942A (en) * | 2021-03-04 | 2021-06-22 | 上海恩捷新材料科技有限公司 | Method and system for detecting dispersibility of coating film coating slurry |
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