CN206109216U - But golden low -emissivity coated glass of tempering - Google Patents
But golden low -emissivity coated glass of tempering Download PDFInfo
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- CN206109216U CN206109216U CN201621064518.2U CN201621064518U CN206109216U CN 206109216 U CN206109216 U CN 206109216U CN 201621064518 U CN201621064518 U CN 201621064518U CN 206109216 U CN206109216 U CN 206109216U
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- layer
- glass
- film
- film layer
- silicon nitride
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- 239000011521 glass Substances 0.000 title claims abstract description 77
- 238000005496 tempering Methods 0.000 title claims abstract description 22
- 229910052581 Si3N4 Inorganic materials 0.000 claims abstract description 31
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 claims abstract description 30
- 229910018487 Ni—Cr Inorganic materials 0.000 claims abstract description 29
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 claims abstract description 29
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000758 substrate Substances 0.000 claims abstract description 22
- 229910052709 silver Inorganic materials 0.000 claims abstract description 21
- 239000004332 silver Substances 0.000 claims abstract description 21
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000010936 titanium Substances 0.000 claims abstract description 3
- 229910052719 titanium Inorganic materials 0.000 claims abstract description 3
- 230000003647 oxidation Effects 0.000 claims abstract 2
- 238000007254 oxidation reaction Methods 0.000 claims abstract 2
- 239000010408 film Substances 0.000 claims description 86
- 230000005855 radiation Effects 0.000 claims description 31
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 14
- 239000007888 film coating Substances 0.000 claims description 12
- 238000009501 film coating Methods 0.000 claims description 12
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 7
- 229910052737 gold Inorganic materials 0.000 claims description 7
- 239000010931 gold Substances 0.000 claims description 7
- 239000010409 thin film Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 3
- 239000010703 silicon Substances 0.000 claims description 3
- 229910052710 silicon Inorganic materials 0.000 claims description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 12
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 abstract description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 4
- 239000001301 oxygen Substances 0.000 abstract description 4
- 229910052760 oxygen Inorganic materials 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 3
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 abstract description 2
- 229910001415 sodium ion Inorganic materials 0.000 abstract description 2
- 239000010410 layer Substances 0.000 description 59
- 239000007789 gas Substances 0.000 description 10
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 8
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 229910052786 argon Inorganic materials 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000005329 float glass Substances 0.000 description 2
- 238000013003 hot bending Methods 0.000 description 2
- 229910001120 nichrome Inorganic materials 0.000 description 2
- 230000000007 visual effect Effects 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- FUWMBNHWYXZLJA-UHFFFAOYSA-N [Si+4].[O-2].[Ti+4].[O-2].[O-2].[O-2] Chemical compound [Si+4].[O-2].[Ti+4].[O-2].[O-2].[O-2] FUWMBNHWYXZLJA-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002346 layers by function Substances 0.000 description 1
- 238000001755 magnetron sputter deposition Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Surface Treatment Of Glass (AREA)
- Laminated Bodies (AREA)
Abstract
The utility model belongs to a single silver -colored low -emissivity coated glass provides a but golden low -emissivity coated glass of tempering. The but golden low -emissivity coated glass of tempering who provides has glass substrate (1), silverskin layer (5) have been plated on glass substrate (1), glass substrate (1) and silverskin layer (5) between outwards plated silicon nitride rete I (2), oxidation titanium film layer (3) and nickel chromium film layer I (4) in proper order by glass substrate (1), the skin of silverskin layer (5) has still plated nickel chromium film layer II (6) and silicon nitride rete II (7), silicon nitride rete II (7) lies in outmostly, coated glass's colour is golden. The utility model discloses existing effect has protected the silverskin layer of the in -process that is heated not oxidated, and the reflected colour of effectively having adjusted final products again is for golden, and the low -emissivity coated glass that six tunic structures are formed can be able to bear or endure 650 C and control high temperature to can block the rete combination that sodium ion in the external oxygen, glass etc. Corrodes to the silverskin layer.
Description
Technical field
This utility model belongs to a kind of single silver low-radiation coated glass, relate generally to it is a kind of can tempering golden low radiation plating
Film glass.
Background technology
Low radiation coated glass is referred in Float Glass Surface deposition layer of metal silver as functional layer, in sunlight
Far infrared near infrared ray and living environment plays reflection, so as to reduce glass to ultrared absorption and radiance,
So referred to as low radiation coated glass；This kind of glass can be not only used for family's window, it can also be used to shop, office building and high-grade guest
The glass curtain wall in shop and the place that other need.
General low radiation coated glass production out after, it is impossible to carry out tempering or hot bending again and process, otherwise silver layer
Can be oxidized or corrode, so as to limit the use range of coated glass, especially have the engineer-to-order of shape-designing at some
In.And now can tempering the low radiation coated glass improvement that passes through technique, can accomplish can be cut again after plated film, grind, wash,
Tempering or the operation such as hot bending, hollow.
But, currently on the market can the low radiation coated glass reflection colour of tempering compare limitation, more with royal purple, bluish grey be
It is main, and have the radiation coated glass capable of being toughened of colden visual appearance tone also more rare, the selectivity of downstream producer and client
It is relatively simple.With continuous pursuit of the people to glass curtain wall color, conventional reflected colour radiation coated glass capable of being toughened is
The market demand cannot be met.And golden radiation coated glass capable of being toughened not only has low, attractive in appearance radiance, pure color, sense
Official is great the advantages of shake noticeable effect, but also can strange land processing, the features such as reduce the production cost of downstream producer.
The many complementary picture effects to add the thin film of copper target or gold target deposition to reach gold of existing similar manufacturer, but it is raw
Produce relatively costly.I is taken charge of then using conventional target, is adjusted by thicknesses of layers, gas ratio etc., then can be produced with gold
The radiation coated glass capable of being toughened of tone.Production cost is not only reduced, and new market segment has been opened up for company.
Therefore, develop the low radiation coated glass product with golden reflected colour to the popularization in market, lifting company and
Processing enterprise's efficiency and benefit are significant.
Utility model content
For solve above-mentioned technical problem, this utility model purpose be propose it is a kind of can tempering golden low radiation plated film glass
Glass.
The purpose of this utility model can adopt the following technical scheme that to realize：
It is a kind of can tempering golden low radiation film coating glass, described coated glass has glass substrate；Described glass
Silver film is coated with substrate；Silicon nitride film layer I, titanium oxide layer and nickel chromium triangle are coated between described glass substrate and silver film
Film layer I；Described silicon nitride film layer I, titanium oxide layer and nickel chromium triangle film layer I is outwards set gradually by glass substrate；The silverskin
The outer layer of layer is also coated with nickel chromium triangle film layer II and silicon nitride film layer II；Described silicon nitride film layer II is located at outermost layer；It is plated in described
Silicon nitride film layer I, titanium oxide layer, nickel chromium triangle film layer I, silver film, nickel chromium triangle film layer II and silicon nitride film layer II in glass substrate
The low radiation coated glass that composition is made up of six film structures；The color of the coated glass is gold.
The thickness of the silicon nitride film layer I is 176.0nm～193.5nm.
The thickness of the titanium oxide layer is 88nm～95nm.
The thickness of the nickel chromium triangle film layer I is 5.0nm～8.2nm.
The thickness of the silver film is 96.0nm～103.6nm.
The thickness of the nickel chromium triangle film layer II is 5.0nm～10.5nm.
The thickness of the silicon nitride film layer II is 198nm～217.7nm.
The utility model proposes it is a kind of can tempering golden low radiation film coating glass, coat six in the glass substrate
Tunic layer, constitutes a kind of low radiation coated glass being made up of six film structures, by six film structures constitute it is low-emission coated
Glass controls the thickness of film layer by target, has both effectively protected the silver film in thermal histories not aoxidized, and effectively adjusts
The reflected colour of final products is gold, and the low radiation coated glass of six film structures composition can be resistant to 650 °C or so high temperature, and
The film layer combination that sodium ion in extraneous oxygen, glass etc. is corroded silver film can be stopped, the product has colden visual appearance tone
And can after plated film again tempering the characteristics of.
Description of the drawings
Fig. 1 is structural representation of the present utility model.
In figure：1st, glass substrate, 2, silicon nitride film layer I, 3, titanium oxide layer, 4, nickel chromium triangle film layer I, 5, silver film, 6, nickel
Chromium film layer II, 7, silicon nitride film layer II.
Specific embodiment
This utility model is illustrated with reference to the drawings and specific embodiments；
As shown in figure 1, it is a kind of can tempering golden low radiation film coating glass, described coated glass has glass substrate 1；
Silver film 5 is coated with described glass substrate 1；Be coated between described glass substrate 1 and silver film 5 silicon nitride film layer I 2,
Titanium oxide layer 3 and nickel chromium triangle film layer I 4；Described silicon nitride film layer I 2, titanium oxide layer 3 and nickel chromium triangle film layer I 4 are by glass substrate 1
Outwards set gradually；The outer layer of the silver film 5 is also coated with nickel chromium triangle film layer II 6 and silicon nitride film layer II 7；Described silicon nitride film
Layer II 7 is located at outermost layer；Silicon nitride film layer I 2, titanium oxide layer 3, the nickel chromium triangle film layer I 4, silverskin being plated in the glass substrate
Layer 5, nickel chromium triangle film layer II 6 and silicon nitride film layer II 7 constitute the low radiation coated glass being made up of six film structures；The plated film glass
The color of glass is gold.
The thickness of the silicon nitride film layer I 2 is 176.0nm～193.5nm.
The thickness of the titanium oxide layer 3 is 88nm～95nm.
The thickness of the nickel chromium triangle film layer I 4 is 5.0nm～8.2nm.
The thickness of the silver film 5 is 96.0nm～103.6nm.
The thickness of the nickel chromium triangle film layer II 6 is 5.0nm～10.5nm.
The thickness of the silicon nitride film layer II 7 is 198nm～217.7nm.
This utility model is under high vacuum environment, six layers to be coated with Float Glass Surface with magnetron sputtering coater and is received
The method of rice material membrane, produces a kind of low radiation coated glass with golden reflected colour.
It is described can tempering golden low radiation film coating glass be to complete as follows on factory's plated film machine equipment：First
Coating chamber is evacuated to background vacuum 5 × 10﹣ 4Below Pa, is filled with process gas（Argon, nitrogen, oxygen）, make in plated film room
Process gas pressure is stable 2.5 × 10﹣ 1Pa or so, connects shielding power supply, and target starts sputtering, and fresh glass substrate Jing is clear
Vacuum chamber is entered after washing machine cleaning is qualified, when target, target atom or its compound will deposit to glass surface.
First target target is nonmetallic silicon, and process gas is nitrogen, and silicon nitride film is deposited to into glass surface for the
One tunic, 176.0 to 193.5 nanometers of thickness；Second target target is ceramic titanium, and process gas is oxygen, by thin film of titanium oxide
Silicon nitride surface is deposited to for the second tunic, 88 to 95 nanometers of thickness；3rd target target is nichrome, and process gas is argon
Gas, titania surface is deposited to for third layer film, 5.0 to 8.2 nanometers of thickness by nickel-chromium thin film；4th target target argent,
Process gas is argon, and Ag films are deposited to into nickel chromium triangle surface for the 4th tunic, 96.0 to 103.6 nanometers of thickness；5th target
Target is nichrome, and process gas is argon, and nickel-chromium thin film is deposited to into silver surface for layer 5 film, thickness 5.0 to 10.5
Nanometer；6th target target is silicon, and process gas is nitrogen, and silicon nitride film is deposited to into nickel chromium triangle surface for layer 6 film, thickness
198 to 217.7 nanometers of degree.
Claims (7)
1. it is a kind of can tempering golden low radiation film coating glass, described coated glass has glass substrate（1）；Described glass
Substrate（1）On be coated with silver film（5）；It is characterized in that：In described glass substrate（1）With silver film（5）Between be coated with nitridation
Silicon film I（2）, titanium oxide layer（3）With nickel chromium triangle film layer I（4）；Described silicon nitride film layer I（2）, titanium oxide layer（3）And nickel
Chromium film layer I（4）By glass substrate（1）Outwards set gradually；The silver film（5）Outer layer be also coated with nickel chromium triangle film layer II（6）With
Silicon nitride film layer II（7）；Described silicon nitride film layer II（7）Positioned at outermost layer；The silicon nitride film being plated in the glass substrate
Layer I（2）, titanium oxide layer（3）, nickel chromium triangle film layer I（4）, silver film（5）, nickel chromium triangle film layer II（6）With silicon nitride film layer II（7）Structure
The low radiation coated glass of Cheng Youliu film structures composition；The color of the low radiation coated glass is gold.
2. it is as claimed in claim 1 it is a kind of can tempering golden low radiation film coating glass, it is characterised in that：The silicon nitride film
Layer I（2）Thickness be 176.0nm～193.5nm.
3. it is as claimed in claim 1 it is a kind of can tempering golden low radiation film coating glass, it is characterised in that：The oxidation titanium film
Layer（3）Thickness be 88nm～95nm.
4. it is as claimed in claim 1 it is a kind of can tempering golden low radiation film coating glass, it is characterised in that：The nickel-chromium thin film
Layer I（4）Thickness be 5.0nm～8.2nm.
5. it is as claimed in claim 1 it is a kind of can tempering golden low radiation film coating glass, it is characterised in that：The silver film
（5）Thickness be 96.0nm～103.6nm.
6. it is as claimed in claim 1 it is a kind of can tempering golden low radiation film coating glass, it is characterised in that：The nickel chromium triangle film layer
Ⅱ（6）Thickness be 5.0nm～10.5nm.
7. it is as claimed in claim 1 it is a kind of can tempering golden low radiation film coating glass, it is characterised in that：The silicon nitride film
Layer II（7）Thickness be 198nm～217.7nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621064518.2U CN206109216U (en) | 2016-09-20 | 2016-09-20 | But golden low -emissivity coated glass of tempering |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201621064518.2U CN206109216U (en) | 2016-09-20 | 2016-09-20 | But golden low -emissivity coated glass of tempering |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN206109216U true CN206109216U (en) | 2017-04-19 |
Family
ID=58519986
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201621064518.2U Expired - Fee Related CN206109216U (en) | 2016-09-20 | 2016-09-20 | But golden low -emissivity coated glass of tempering |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN206109216U (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108101383A (en) * | 2018-02-27 | 2018-06-01 | 四川南玻节能玻璃有限公司 | One kind can tempering Low-E energy-saving glass |
| US11053164B2 (en) * | 2017-12-08 | 2021-07-06 | Saint-Gobain Glass France | Solar control glass article |
| CN114213038A (en) * | 2022-01-13 | 2022-03-22 | 谷城风雷玻璃有限责任公司 | Temperable low-emissivity coated glass and process |
| CN115291449A (en) * | 2022-08-12 | 2022-11-04 | 台玻(青岛)光电科技有限公司 | Conductive mirror of electrochromic mirror |
-
2016
- 2016-09-20 CN CN201621064518.2U patent/CN206109216U/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US11053164B2 (en) * | 2017-12-08 | 2021-07-06 | Saint-Gobain Glass France | Solar control glass article |
| CN108101383A (en) * | 2018-02-27 | 2018-06-01 | 四川南玻节能玻璃有限公司 | One kind can tempering Low-E energy-saving glass |
| CN108101383B (en) * | 2018-02-27 | 2024-02-13 | 四川南玻节能玻璃有限公司 | Temperable Low-E energy-saving glass |
| CN114213038A (en) * | 2022-01-13 | 2022-03-22 | 谷城风雷玻璃有限责任公司 | Temperable low-emissivity coated glass and process |
| CN115291449A (en) * | 2022-08-12 | 2022-11-04 | 台玻(青岛)光电科技有限公司 | Conductive mirror of electrochromic mirror |
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| Date | Code | Title | Description |
|---|---|---|---|
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170419 Termination date: 20190920 |