CN205419926U - Low energy consumption enhanced nitrogen removal phosphorus removal device - Google Patents
Low energy consumption enhanced nitrogen removal phosphorus removal device Download PDFInfo
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- CN205419926U CN205419926U CN201620199720.XU CN201620199720U CN205419926U CN 205419926 U CN205419926 U CN 205419926U CN 201620199720 U CN201620199720 U CN 201620199720U CN 205419926 U CN205419926 U CN 205419926U
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Abstract
本实用新型涉及一种低能耗强化脱氮除磷装置,其特征在于包括产甲烷厌氧反应器,异化铁还原反应器、厌氧氨氧化反应器和曝气生物滤池,各反应器依次相接,各反应器依次对有机物,磷和氮进行主要去除,最后由曝气生物滤池充氧并进一步确保出水水质。其有益效果为:主要在厌氧环境下进行污染物的去除,能耗低;针对有机物、氮和磷,有相对应的反应器进行针对性的去除,去除效果好。
The utility model relates to a low energy consumption enhanced denitrification and dephosphorization device, which is characterized in that it comprises a methane-producing anaerobic reactor, a dissimilation iron reduction reactor, anaerobic ammonium oxidation reactor and an aerated biological filter. Next, each reactor performs main removal of organic matter, phosphorus and nitrogen in turn, and finally the biological aerated filter is oxygenated to further ensure the quality of the effluent. The beneficial effect is that the pollutants are mainly removed in an anaerobic environment, and the energy consumption is low; for organic matter, nitrogen and phosphorus, there are corresponding reactors for targeted removal, and the removal effect is good.
Description
技术领域 technical field
本实用新型涉及环境工程水处理领域中的强化脱氮除磷,特别是涉及一种低能耗强化脱氮除磷装置。 The utility model relates to the enhanced nitrogen and phosphorus removal in the field of environmental engineering water treatment, in particular to a low energy consumption enhanced nitrogen and phosphorus removal device.
背景技术 Background technique
氮、磷元素是引起水体富营养化的主要元素,应用最广的脱氮除磷工艺为厌氧/缺氧/好氧工艺(A/A/O工艺),但该工艺设有污泥外回流,硝化液内回流和需要大量曝气,能耗高,且因为不能同时满足除磷所需的聚磷菌和脱氮所需的硝化菌的泥龄需求,难以同时实现很好的脱氮除磷效果。 Nitrogen and phosphorus are the main elements that cause eutrophication of water bodies. The most widely used nitrogen and phosphorus removal process is the anaerobic/anoxic/aerobic process (A/A/O process). Backflow, backflow in the nitrifying liquid and the need for a large amount of aeration, high energy consumption, and because the sludge age requirements of the phosphorus accumulating bacteria required for phosphorus removal and the nitrifying bacteria required for denitrification cannot be met at the same time, it is difficult to achieve good denitrification at the same time phosphorus removal effect.
从低能耗考虑,厌氧工艺不需要曝气,可节省能耗。在厌氧工艺中,水解酸化-产甲烷可去除有机物;异化铁还原一方面可以提高污水处理系统对难降解有机物的降解效率,另一方面可以利用反应器内溶出的三价铁和二价铁,与磷酸盐的沉淀作用改善污水处理系统的除磷效果;而在低有机物环境下,厌氧氨氧化有很强的脱氮效果;厌氧出水中溶解氧浓度为零或很小,不可直接排放,需曝气充氧,利用曝气生物滤池为厌氧出水充氧,同时曝气生物滤池可同时实现有机物、氮和磷的去除,进一步确保出水水质。上述几种工艺的组合,厌氧阶段去除大部分有机物,到曝气生物滤池时负荷小耗氧少,可为低能耗的脱氮除磷提供可能。 Considering low energy consumption, the anaerobic process does not require aeration, which can save energy consumption. In the anaerobic process, hydrolytic acidification-methanization can remove organic matter; dissimilatory iron reduction can improve the degradation efficiency of the sewage treatment system for refractory organic matter on the one hand, and on the other hand can utilize the ferric and ferrous iron dissolved in the reactor , and the precipitation of phosphate improves the phosphorus removal effect of the sewage treatment system; and in the environment of low organic matter, anaerobic ammonium oxidation has a strong denitrification effect; the dissolved oxygen concentration in the anaerobic effluent is zero or very small, so it cannot be directly Emission requires aeration and oxygenation, and the biological aerated filter is used to oxygenate the anaerobic effluent. At the same time, the biological aerated filter can simultaneously remove organic matter, nitrogen and phosphorus, and further ensure the quality of the effluent. The combination of the above several processes removes most of the organic matter in the anaerobic stage, and when it reaches the biological aerated filter, the load is small and the oxygen consumption is small, which can provide the possibility of nitrogen and phosphorus removal with low energy consumption.
发明内容 Contents of the invention
为强化脱氮除磷,同时降低能耗,本实用新型采用一种低能耗强化脱氮除磷装置,可实现低能耗下的有效脱氮除磷。 In order to strengthen nitrogen and phosphorus removal while reducing energy consumption, the utility model adopts a low energy consumption enhanced nitrogen and phosphorus removal device, which can realize effective nitrogen and phosphorus removal under low energy consumption.
本实用新型所采用的技术方案是:一种低能耗强化脱氮除磷装置包括产甲烷厌氧反应器,异化铁还原反应器、厌氧氨氧化反应器和曝气生物滤池,产甲烷厌氧反应器的出水口连接异化铁还原反应器的进水口,异化铁还原反应器的出水口连接厌氧氨氧化反应器的进水口,厌氧氨氧化反应器的出水口连接曝气生物滤池进水口。 The technical solution adopted in the utility model is: a low energy consumption enhanced nitrogen and phosphorus removal device includes a methane-producing anaerobic reactor, a dissimilation iron reduction reactor, anaerobic ammonium oxidation reactor and an aerated biological filter, and a methane-producing anaerobic reactor The water outlet of the oxygen reactor is connected to the water inlet of the dissimilation iron reduction reactor, the water outlet of the dissimilation iron reduction reactor is connected to the water inlet of the anammox reactor, and the water outlet of the anammox reactor is connected to the biological aerated filter water intake.
所述产甲烷厌氧反应器和厌氧氨氧化反应器为升流式厌氧污泥床反应器,设有三相分离器,而异化铁还原反应器中部有四分之一到三分之一反应器高度厚的三价铁填料层。 The methanogenic anaerobic reactor and the anammox reactor are upflow anaerobic sludge bed reactors with a three-phase separator, and the middle part of the dissimilated iron reduction reactor has a quarter to a third The reactor height is thick with ferric iron packing layer.
其中产甲烷厌氧反应器主要用于有机物的大部分去除和有机氮向氨氮的转化;异化铁还原反应器主要用于化学除磷,同时进一步去除有机物、提高氧化还原电位和提供铁元素,为厌氧氨氧化提供合适的条件;厌氧氨氧化反应器主要用于脱氮;曝气生物滤池用于保证出水中有足够的溶解氧,同时进一步保证出水达标。 Among them, the methanogenic anaerobic reactor is mainly used for the removal of most of the organic matter and the conversion of organic nitrogen to ammonia nitrogen; the dissimilation iron reduction reactor is mainly used for chemical phosphorus removal, while further removing organic matter, increasing the oxidation-reduction potential and providing iron, for Anaerobic ammonium oxidation provides suitable conditions; anaerobic ammonium oxidation reactor is mainly used for denitrification; biological aerated filter is used to ensure sufficient dissolved oxygen in the effluent, while further ensuring that the effluent meets the standard.
其有益效果为:(1)主要在厌氧环境下进行污染物的去除,节约能耗;(2)针对有机物、氮和磷,有相对应的反应器进行针对性的去除,去除效果好。 The beneficial effects are as follows: (1) Pollutants are mainly removed in an anaerobic environment, saving energy; (2) For organic matter, nitrogen and phosphorus, there are corresponding reactors for targeted removal, and the removal effect is good.
附图说明 Description of drawings
图1是低能耗强化脱氮除磷装置整体示意图。 Figure 1 is an overall schematic diagram of a device for enhanced nitrogen and phosphorus removal with low energy consumption.
图中:1.产甲烷厌氧反应器,2.甲烷排气口,3.产甲烷厌氧反应器三相分离器,4.产甲烷厌氧反应器进水口,5.产甲烷厌氧反应器出水口,6.异化铁还原反应器,7.异化铁还原反应器进水口,8.三价铁填料,9.异化铁还原反应器出水口,10.厌氧氨氧化反应器,11.氮气排气口,12.厌氧氨氧化反应器三相分离器,13.厌氧氨氧化反应器进水口,14.厌氧氨氧化反应器出水口,15.连接管路,16.曝气生物滤池,17.曝气生物滤池出水口,18.挂膜填料,19.曝气管,20.曝气生物滤池进水口。 In the figure: 1. Methanogenic anaerobic reactor, 2. Methane exhaust port, 3. Methanogenic anaerobic reactor three-phase separator, 4. Methanogenic anaerobic reactor water inlet, 5. Methanogenic anaerobic reaction 6. Dissimilation iron reduction reactor, 7. Dissimilation iron reduction reactor water inlet, 8. Ferric iron packing, 9. Dissimilation iron reduction reactor outlet, 10. Anammox reactor, 11. Nitrogen exhaust port, 12. Three-phase separator of anammox reactor, 13. water inlet of anammox reactor, 14. outlet of anammox reactor, 15. connecting pipeline, 16. aeration Biological filter, 17. Biological aerated filter water outlet, 18. Hanging film filler, 19. Aeration pipe, 20. Biological aerated filter water inlet.
具体实施方式 detailed description
下面结合附图对本发明进一步说明。 The present invention will be further described below in conjunction with the accompanying drawings.
含有氮磷的污水或废水,首先通过产甲烷厌氧反应器进水口4,进入产甲烷厌氧反应器1,经过里面厌氧污泥的水解酸化和产甲烷,使大分子有机物变成小分子有机物,且大部分被去除,以甲烷的形态从甲烷排气口2排出,同时有机氮转化氨态氮,经过产甲烷厌氧反应器三相分离器3的分离,经过处理的污水或废水经异化铁还原反应器进水口7进入异化铁还原反应器6,里面的异化铁还原菌利用三价铁填料8产生的三价铁离子,进行异化铁还原去除部分有机物,包括难降解有机物,且三价铁离子和还原产物二价铁离子,会与磷酸盐作用产生沉淀进行化学除磷,且经过对三价铁的还原作用,系统氧化还原电位有所上升,有利于后续厌氧氨氧化反应器10中厌氧氨氧化菌的生长。经污水异化铁还原反应器6处理后,污水或废水水质进一步发生变化,有机物浓度降低且含有二价和三价铁离子,经异化铁还原反应器出水口9排出,由厌氧氨氧化反应器进水口13进入厌氧氨氧化反应器10,此时水中有机物浓度低,对自养型的厌氧氨氧化菌影响小,且水中含有二价和三价铁,有助于厌氧氨氧化菌的生长。经厌氧氨氧化反应器10中厌氧氨氧化菌处理后,污水中的氮被大量去除,产生的氮气经氮气排气口11排出。此时水中有机物、氮和磷浓度基本达标,为确保出水水质,同时考虑厌氧出水不能直接排放,需经过曝气充氧。在装置末端加曝气生物滤池16,厌氧氨氧化反应器10的出水经厌氧氨氧化反应器出水口,由曝气生物滤池进水口20进入曝气生物滤池16,因为挂膜填料18上生物膜的存在,在曝气管19充氧的条件下,可同时进行有机物、氮和磷的去除,同时提高水中溶解氧浓度,使其达标排放。整个运行过程中,各阶段的相互配合,可达到良好的有机物降解和脱氮除磷。 Sewage or waste water containing nitrogen and phosphorus first enters the anaerobic reactor 1 through the water inlet 4 of the anaerobic reactor for methane generation, and undergoes hydrolysis and acidification of the anaerobic sludge and methane generation, so that macromolecular organic matter becomes small molecules Most of the organic matter is removed, and it is discharged from the methane exhaust port 2 in the form of methane. At the same time, the organic nitrogen is converted into ammonia nitrogen, and it is separated by the three-phase separator 3 of the methanogenic anaerobic reactor. The treated sewage or waste water is passed through The water inlet 7 of the dissimilation iron reduction reactor enters the dissimilation iron reduction reactor 6, and the dissimilation iron reduction bacteria inside use the ferric ions produced by the ferric filler 8 to perform dissimilation iron reduction to remove some organic matter, including refractory organic matter, and three The valence iron ions and the reduction product divalent iron ions will react with phosphate to produce precipitation for chemical phosphorus removal, and after the reduction of ferric iron, the redox potential of the system will increase, which is beneficial to the subsequent anammox reactor Growth of anammox bacteria in 10. After being treated by the sewage dissimilation iron reduction reactor 6, the quality of sewage or waste water further changes, the concentration of organic matter decreases and contains divalent and ferric ions, which are discharged through the water outlet 9 of the dissimilation iron reduction reactor, and are discharged by the anaerobic ammonium oxidation reactor The water inlet 13 enters the anammox reactor 10. At this time, the concentration of organic matter in the water is low, which has little influence on the autotrophic anammox bacteria, and the water contains divalent and ferric iron, which helps the anammox bacteria growth. After being treated by the anammox bacteria in the anammox reactor 10 , a large amount of nitrogen in the sewage is removed, and the nitrogen gas produced is discharged through the nitrogen exhaust port 11 . At this time, the concentration of organic matter, nitrogen and phosphorus in the water is basically up to the standard. In order to ensure the quality of the effluent, and considering that the anaerobic effluent cannot be discharged directly, it needs to be aerated and oxygenated. A biological aerated filter 16 is added at the end of the device, and the effluent of the anammox reactor 10 enters the biological aerated filter 16 by the biological aerated filter inlet 20 through the outlet of the anammox reactor, because the film The presence of biofilm on the filler 18 can simultaneously remove organic matter, nitrogen and phosphorus under the condition of oxygenation in the aeration tube 19, and at the same time increase the concentration of dissolved oxygen in the water to make it discharge up to the standard. During the whole operation process, the mutual cooperation of each stage can achieve good organic matter degradation and nitrogen and phosphorus removal.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106698628A (en) * | 2017-01-09 | 2017-05-24 | 华南农业大学 | In-situ continuous removal method and device for eutrophic water phosphorus |
| CN111943444A (en) * | 2020-08-19 | 2020-11-17 | 苏州科技大学 | A sewage treatment device and method for strengthening the autotrophic denitrification and simultaneous phosphorus recovery of municipal sewage |
| CN117682710A (en) * | 2023-12-26 | 2024-03-12 | 湖南军信环保股份有限公司 | Ammonia nitrogen wastewater treatment method and system based on anaerobic ammonium oxidation |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106698628A (en) * | 2017-01-09 | 2017-05-24 | 华南农业大学 | In-situ continuous removal method and device for eutrophic water phosphorus |
| CN106698628B (en) * | 2017-01-09 | 2020-01-17 | 华南农业大学 | In-situ continuous removal method and device for phosphorus in eutrophic water |
| CN111943444A (en) * | 2020-08-19 | 2020-11-17 | 苏州科技大学 | A sewage treatment device and method for strengthening the autotrophic denitrification and simultaneous phosphorus recovery of municipal sewage |
| CN111943444B (en) * | 2020-08-19 | 2021-11-23 | 苏州科技大学 | Sewage treatment device and method for enhancing municipal sewage autotrophic nitrogen removal and synchronous phosphorus recovery |
| CN117682710A (en) * | 2023-12-26 | 2024-03-12 | 湖南军信环保股份有限公司 | Ammonia nitrogen wastewater treatment method and system based on anaerobic ammonium oxidation |
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