CN205388991U - Water hydrogen power train - Google Patents
Water hydrogen power train Download PDFInfo
- Publication number
- CN205388991U CN205388991U CN201520867277.4U CN201520867277U CN205388991U CN 205388991 U CN205388991 U CN 205388991U CN 201520867277 U CN201520867277 U CN 201520867277U CN 205388991 U CN205388991 U CN 205388991U
- Authority
- CN
- China
- Prior art keywords
- hydrogen
- methanol
- energy
- water
- gasification
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 331
- 239000001257 hydrogen Substances 0.000 title claims abstract description 296
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 296
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 229910001868 water Inorganic materials 0.000 title claims abstract description 53
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 207
- 238000004519 manufacturing process Methods 0.000 claims abstract description 86
- 238000000926 separation method Methods 0.000 claims abstract description 58
- 239000007789 gas Substances 0.000 claims abstract description 44
- 230000007246 mechanism Effects 0.000 claims abstract description 40
- 239000012528 membrane Substances 0.000 claims abstract description 40
- 239000002994 raw material Substances 0.000 claims abstract description 32
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 15
- 238000002955 isolation Methods 0.000 claims abstract description 15
- SWELZOZIOHGSPA-UHFFFAOYSA-N palladium silver Chemical compound [Pd].[Ag] SWELZOZIOHGSPA-UHFFFAOYSA-N 0.000 claims abstract description 14
- 238000002309 gasification Methods 0.000 claims description 71
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 48
- 239000000446 fuel Substances 0.000 claims description 39
- 239000003054 catalyst Substances 0.000 claims description 38
- 238000003860 storage Methods 0.000 claims description 38
- 239000001301 oxygen Substances 0.000 claims description 34
- 229910052760 oxygen Inorganic materials 0.000 claims description 34
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 33
- 238000010438 heat treatment Methods 0.000 claims description 32
- 229910002092 carbon dioxide Inorganic materials 0.000 claims description 24
- 239000007788 liquid Substances 0.000 claims description 23
- 239000007787 solid Substances 0.000 claims description 22
- 239000001569 carbon dioxide Substances 0.000 claims description 20
- 238000002407 reforming Methods 0.000 claims description 12
- 239000012295 chemical reaction liquid Substances 0.000 claims description 11
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 238000004146 energy storage Methods 0.000 claims description 9
- GBMDVOWEEQVZKZ-UHFFFAOYSA-N methanol;hydrate Chemical compound O.OC GBMDVOWEEQVZKZ-UHFFFAOYSA-N 0.000 claims description 8
- 230000009471 action Effects 0.000 claims description 7
- 230000005540 biological transmission Effects 0.000 claims description 6
- 239000000919 ceramic Substances 0.000 claims description 4
- 238000010248 power generation Methods 0.000 claims 9
- 229910001316 Ag alloy Inorganic materials 0.000 claims 1
- PIYVNGWKHNMMAU-UHFFFAOYSA-N [O].O Chemical compound [O].O PIYVNGWKHNMMAU-UHFFFAOYSA-N 0.000 claims 1
- 230000005611 electricity Effects 0.000 abstract description 9
- 230000001105 regulatory effect Effects 0.000 abstract description 9
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract description 2
- 238000001651 catalytic steam reforming of methanol Methods 0.000 abstract 1
- 238000012546 transfer Methods 0.000 description 19
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium Substances [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 14
- 230000006698 induction Effects 0.000 description 12
- 230000006835 compression Effects 0.000 description 10
- 238000007906 compression Methods 0.000 description 10
- 239000010949 copper Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 10
- 238000009826 distribution Methods 0.000 description 9
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 7
- 238000010586 diagram Methods 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 229910001404 rare earth metal oxide Inorganic materials 0.000 description 6
- 229910000314 transition metal oxide Inorganic materials 0.000 description 6
- 239000006200 vaporizer Substances 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- 229910052802 copper Inorganic materials 0.000 description 4
- 238000010304 firing Methods 0.000 description 4
- 229910052763 palladium Inorganic materials 0.000 description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 230000003139 buffering effect Effects 0.000 description 3
- 239000003990 capacitor Substances 0.000 description 3
- 229910001882 dioxygen Inorganic materials 0.000 description 3
- 238000012423 maintenance Methods 0.000 description 3
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
- 238000007747 plating Methods 0.000 description 3
- 239000010970 precious metal Substances 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- 230000002269 spontaneous effect Effects 0.000 description 3
- 238000001771 vacuum deposition Methods 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000002283 diesel fuel Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003502 gasoline Substances 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 239000002341 toxic gas Substances 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- SAZUGELZHZOXHB-UHFFFAOYSA-N acecarbromal Chemical compound CCC(Br)(CC)C(=O)NC(=O)NC(C)=O SAZUGELZHZOXHB-UHFFFAOYSA-N 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000006837 decompression Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T30/00—Transportation of goods or passengers via railways, e.g. energy recovery or reducing air resistance
Landscapes
- Hydrogen, Water And Hydrids (AREA)
Abstract
The utility model discloses a no exhaust emissions's water hydrogen power train, including power car, non - power car, the power car is equipped with methyl alcohol hydrogen production system, hydrogen generates electricity system, motor generator, methyl alcohol hydrogen production system utilizes methanol steam reforming preparation hydrogen, and hydrogen obtains the hydrogen of high -purity through the membrane separation device who plates palladium -silver, and the hydrogen that acquires passes through the electricity generation of hydrogen generates electricity system, and the electric energy that sends supplies motor generator work, methyl alcohol hydrogen production system includes reservoir, and reservoir is equipped with isolation mechanism, isolation mechanism regulating unit, and isolation mechanism divide into two at least regions with reservoir, and isolation mechanism regulating unit adjusts the position of isolation mechanism in reservoir, adjusts each regional size. The utility model discloses energy crisis is solved as the energy of car to usable methyl alcohol, reduces and avoids vehicle emissions even. The utility model discloses water hydrogen power train can collect the tail gas CO2 who discharges, and as the raw materials of subsequent handling, no harmful gas discharges, effective environmental protection.
Description
Technical field
This utility model belongs to electric vehicle engineering field, relates to a kind of electric automobile, particularly relates to the water hydrogen power train of a kind of emission-free discharge.
Background technology
Auto industry is the second largest industry being only second to petrochemical industry in the world, at present, major part automobile, all with gasoline, diesel oil for fuel, not only consumes substantial amounts of petroleum resources, and nitrogen oxides contained in vehicle exhaust, hydrocarbons, carbon monoxide etc. causes the severe contamination of air.In order to keep the sustainable development of national economy, protecting human residential environment and ensure energy resource supply, countries in the world government puts into substantial amounts of human and material resources one after another and seeks to solve the various approach of these problems.
Currently mainly have an approach two kinds energy-conservation, a kind of be representative with Toyota hybrid vehicle, the pure electric automobile that another kind is is representative with tesla.The starting of hybrid vehicle is slow, and fuel is still gasoline or diesel oil, it is impossible to the problem inherently solving resource, pollution.Pure electric automobile needs specific charging pile, it is more difficult to universal, and flying power is poor.
Fuel cell is a kind of efficient generating apparatus that the chemical energy of fuel and oxidant is directly changed in electrochemical reaction mode electric energy without combustion process, and its work process is not limited by Carnot cycle, and conversion efficiency is high, almost without pollutant emission.Not only can protect environment but also energy shortage can be alleviated and readjust the energy structure with the FC-EV that fuel cell is power, it has also become one of important trend of future automobile development, be world today's energy and the focus of field of traffic exploitation.
Fuel cell can be divided into five classes such as alkaline fuel cell, phosphoric acid fuel cell, molten carbonate fuel cell, SOFC, Proton Exchange Membrane Fuel Cells by electrolyte classification.And the requirement of automobile fuel battery is: can work at normal temperatures, electric current density is high, and non-maintaining property is good, and resistance to vibration is good with resistance to impact, it is possible to carry out high efficiency operating from underload to high load capacity.Proton Exchange Membrane Fuel Cells (PEMFC) disclosure satisfy that these performance requirements, therefore becomes also the most ripe vehicle fuel battery with fastest developing speed.Fuel cell car based on PEMFC needs hydrogen as fuel, since fuel cell is born, hydrogen source problem and fuel cell itself are the core technologies of no less important, and the research and development of hydrogen source have become fuel cell car and moved towards business-like important step from demonstration.
Utility model content
Technical problem to be solved in the utility model is: provide the water hydrogen power train of a kind of emission-free discharge, and available methanol, as the energy of automobile, solves energy crisis, reduces vehicular discharge.
For solving above-mentioned technical problem, this utility model adopts the following technical scheme that
A kind of water hydrogen power train of emission-free discharge, including: power car, non-powered car, power car is provided with hydrogen production by methanol system, hydrogen gas generating system, genemotor, hydrogen production by methanol system, hydrogen gas generating system, genemotor are arranged in power car, and hydrogen production by methanol system, hydrogen gas generating system, genemotor are sequentially connected with；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen and stores container, stores container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described storage container is arranged at the rear portion of power car；The middle part storing container is provided with dividing plate, and the side of dividing plate arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Dividing plate is connected to pushing mechanism, and when the liquid stored in container reduces or carbon dioxide increases up to impose a condition, pushing mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases the volume in storage carbon dioxide region；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen stores container, storage container is connected with hydrogen producer respectively；Store the first alcohol and water storing liquid in container；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects storage container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from the first gasification pipe；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs the required energy；
The initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator；
Described catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide.Wherein precious metals pt content accounts for the 0.5%～2% of catalyst gross mass, Pd content accounts for the 1%～5% of catalyst gross mass, the oxide of Cu accounts for the 5%～15% of catalyst gross mass, the oxide of Fe accounts for the 2%～10% of catalyst gross mass, the oxide of Zn accounts for the 10%～25% of catalyst gross mass, rare-earth oxide accounts for the 5%～45% of catalyst gross mass, and all the other are transition metal oxide；
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 55-80 part of ZnO, 0.5-3 part of CuO, 3-18 part of 3-17 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3；
Described solid hydrogen stores and stores solid hydrogen in container, and when hydrogen generating system starts, by gasifying, solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, as the startup energy of hydrogen producer；
First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 300 DEG C～420 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is run by the maintenance hydrogen producer that burns；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and is easily separated, for the difference of inside and outside pressure of membrane separation device of separating hydrogen gas be more than or equal to 0.7MPa；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%；
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；This barometric information received from gas pressure sensor is compared by described microprocessor with setting threshold interval；When the pressure data received is higher than the maximum setting threshold interval, microprocessor controls valve positioner and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, is that the firing equipment that needs of hydrogen manufacturing subsystem is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, hydrogen, oxygen gas and water is collected respectively from expellant gas, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generating system, the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycling；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is then separated from water by hydrogen respectively, oxygen is separated from water；
Described hydrogen gas generating system includes fuel cell, and fuel cell includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor.
Described automobile also includes the second genemotor, energy storage units, kinetic energy converting unit, and kinetic energy converting unit, energy storage units, the second genemotor are sequentially connected with；The energy of automobile brake is converted to electric energy and is stored in energy storage units by described kinetic energy converting unit, provides electric energy for the second genemotor；
Described second genemotor is also connected with hydrogen gas generating system, hydrogen gas generating system provide the energy for the second genemotor；
Described automobile also includes road environment induction module, allocation database, hydrogen distribution module；Hydrogen distribution module is connected with road environment induction module, allocation database respectively, according to the hydrogen that the data in the data of road environment induction module sensing and allocation database are each genemotor distribution correspondence；
Described road environment induction module is in order to sense road congestion information, ground flat degree information；Road congestion information is according to automobile real-time speed, acceleration, deceleration frequency, and determines down time；Ground flat degree information is determined according to the obliquity sensor arranged on automobile chassis；
Described allocation database stores some tables of data, tables of data records the data for genemotor, the second genemotor distribution hydrogen that each road congestion information, ground flat degree information are corresponding；In genemotor, the second genemotor, one is used for driving trailing wheel or/and front-wheel, and another is used for driving front-wheel or/and trailing wheel.
A kind of water hydrogen power train of emission-free discharge, including: power car, non-powered car, power car is provided with hydrogen production by methanol system, hydrogen gas generating system, genemotor, hydrogen production by methanol system, hydrogen gas generating system, genemotor are arranged at power car, and hydrogen production by methanol system, hydrogen gas generating system, genemotor are sequentially connected with；
Described hydrogen production by methanol system includes hydrogen manufacturing subsystem, and described hydrogen manufacturing subsystem includes hydrogen producer, membrane separation device；Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber；
Described hydrogen production by methanol system includes storing container, store container and be provided with interrupter, interrupter regulon, storage container is divided at least two region by interrupter, and interrupter regulon regulates interrupter in the position stored in container, regulates the size of regional.
Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for genemotor work.
As a kind of preferred version of the present utility model, the side of described interrupter arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Dividing plate is connected to pushing mechanism, when the liquid stored in container reduces or carbon dioxide increases up to impose a condition, pushing mechanism driving isolation mechanism action, reduces the volume of storage reaction liquid regions, increases the volume in storage carbon dioxide region.
As a kind of preferred version of the present utility model, described hydrogen production by methanol system includes hydrogen manufacturing subsystem, air pressure adjustment subsystem, Collection utilization subsystem, and hydrogen manufacturing subsystem, air pressure adjustment subsystem, hydrogen gas generating system, Collection utilization subsystem are sequentially connected with；
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen and stores container, stores container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen producer includes heat exchanger, vaporizer, reformer chamber；Membrane separation device is arranged in separation chamber, and separation chamber is arranged at the inside of reformer chamber；Described solid hydrogen stores container, storage container is connected with hydrogen producer respectively；Store the first alcohol and water storing liquid in container；
Described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device, the second startup device；Described first starts device includes the first heating arrangements, the first gasification pipe, and the internal diameter of the first gasification pipe is 1～2mm, and the first gasification pipe is closely wound on the first heating arrangements；One end of described first gasification pipe connects storage container, is sent in the first gasification pipe by methanol by raw material conveying device；The other end of the first gasification pipe exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from the first gasification pipe；Described second starts device includes the second gasification pipe, the main body of the second gasification pipe is arranged at described reformer chamber, first gasification pipe is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe；Described reformer chamber inwall is provided with and adds pipe line, adds and is placed with catalyst in pipe line；Described device for rapidly starting by heat described in add pipe line attach most importance to whole room heating；After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs the required energy；
Described solid hydrogen stores and stores solid hydrogen in container, and when hydrogen generating system starts, by gasifying, solid hydrogen is converted to gaseous hydrogen by module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer and starts heat energy, as the startup energy of hydrogen producer；
First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 300 DEG C～420 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 400 DEG C～570 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 350 DEG C～570 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator；
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；
After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is run by the maintenance hydrogen producer that burns；
The hydrogen that described hydrogen producer prepares is delivered to membrane separation device and is easily separated, for the difference of inside and outside pressure of membrane separation device of separating hydrogen gas be more than or equal to 0.7MPa；Described membrane separation device is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%；
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares；
Described air pressure adjustment subsystem includes microprocessor, gas pressure sensor, valve positioner, air outlet valve, outlet pipe；Described gas pressure sensor is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor；This barometric information received from gas pressure sensor is compared by described microprocessor with setting threshold interval；When the pressure data received is higher than the maximum setting threshold interval, microprocessor controls valve positioner and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point, one end of outlet pipe connects air outlet valve simultaneously, the other end connects described hydrogen manufacturing subsystem, is that the firing equipment that needs of hydrogen manufacturing subsystem is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor controls described hydrogen manufacturing subsystem and accelerates the transporting velocity of raw material；
Described Collection utilization subsystem connects the Vent passageway of hydrogen gas generating system, hydrogen, oxygen gas and water is collected respectively from expellant gas, utilize the hydrogen collected, oxygen for hydrogen manufacturing subsystem or/and hydrogen gas generating system, the water collected is as the raw material of hydrogen manufacturing subsystem, thus recycling；
Described Collection utilization subsystem includes hydrogen/oxygen separator, hydrogen water separator, hydrogen check-valves, oxygen water separator, oxygen check valve, by hydrogen and oxygen separation, is then separated from water by hydrogen respectively, oxygen is separated from water.
As a kind of preferred version of the present utility model, the initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator.
As a kind of preferred version of the present utility model, described catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide；
Wherein, precious metals pt content accounts for the 0.6%～1.8% of catalyst gross mass, Pd content accounts for the 1.1%～4% of catalyst gross mass, the oxide of Cu accounts for the 6%～12% of catalyst gross mass, the oxide of Fe accounts for the 3%～8% of catalyst gross mass, the oxide of Zn accounts for the 8%～20% of catalyst gross mass, and rare-earth oxide accounts for the 6%～40% of catalyst gross mass, and all the other are transition metal oxide.
As a kind of preferred version of the present utility model, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 45-95 part of ZnO, 0.1-5 part of CuO, 2-20 part of 2-20 part2O3, the CeO of 0-5 part2, the La of 0-5 part2O3。
As a kind of preferred version of the present utility model, described hydrogen gas generating system includes fuel cell, and fuel cell includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor.
The beneficial effects of the utility model are in that: the water hydrogen power train of the emission-free discharge that the utility model proposes, and available methanol, as the energy of automobile, solves energy crisis, reduces and even avoids vehicular discharge.The tail gas CO2 of discharge can be collected by this utility model water hydrogen power train, as the raw material of subsequent handling, without noxious gas emission, is even avoided that the discharge of CO2, effectively protects environment.
This utility model device for producing hydrogen volume is little, utilizes distinctive catalyst formulation and palladium film to purify, and the hydrogen of preparation is quickly, stable, purity is high, it is possible to provide stable input energy sources for automobile.
Accompanying drawing explanation
Fig. 1 is the composition schematic diagram of this utility model water hydrogen power train.
Fig. 2 is the composition schematic diagram of this utility model hydrogen generating system, electricity generation system.
Fig. 3 is the operating diagram of Collection utilization subsystem.
Fig. 4 is another composition schematic diagram of this utility model hydrogen generating system, electricity generation system.
Fig. 5 is the composition schematic diagram of hydrogen manufacturing subsystem.
Fig. 6 is another composition schematic diagram of hydrogen manufacturing subsystem.
Fig. 7 is the structural representation of the first startup device.
Fig. 8 is the structural representation storing container.
Fig. 9 is the composition schematic diagram of fuel cell system in this utility model system.
Detailed description of the invention
Preferred embodiment of the present utility model is described in detail below in conjunction with accompanying drawing.
Embodiment one
Refer to Fig. 1, this utility model discloses a kind of water hydrogen power train, including: power car, non-powered car, power car is provided with hydrogen production by methanol system, hydrogen gas generating system, genemotor, and hydrogen production by methanol system, hydrogen gas generating system, genemotor are arranged in power car；Hydrogen production by methanol system, hydrogen gas generating system, genemotor are sequentially connected with.Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for genemotor work.
Refer to Fig. 2 to Fig. 4, described hydrogen production by methanol system includes hydrogen manufacturing subsystem 100, air pressure adjustment subsystem 200, Collection utilization subsystem 400, and hydrogen manufacturing subsystem 100, air pressure adjustment subsystem 200, hydrogen gas generating system 300, Collection utilization subsystem 400 are sequentially connected with.
Described hydrogen manufacturing subsystem 100 utilizes methanol-water to prepare hydrogen, is used for generating electricity to hydrogen gas generating system 300 by transfer conduit real-time Transmission by prepared hydrogen；Described Collection utilization subsystem 400 connects the Vent passageway of hydrogen gas generating system 300, collects hydrogen from expellant gas, or utilizes the hydrogen collected for hydrogen manufacturing subsystem 100 or/and hydrogen gas generating system 300.
Referring to Fig. 5, described solid hydrogen stores container 80, storage container 10 is connected with hydrogen producer 20 respectively；Storing the first alcohol and water storing liquid in container 10, described solid hydrogen stores and stores solid hydrogen in container 80.
Referring to Fig. 8, described storage container is arranged at the rear portion (partial power car can also be half power car) of power car；The middle part storing container is provided with dividing plate 101, and the side of dividing plate 101 arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state.Dividing plate 101 is connected to pushing mechanism, and when the liquid stored in container reduces or carbon dioxide increases up to impose a condition, pushing mechanism drives dividing plate action, reduces the volume of storage reaction liquid regions, increases the volume in storage carbon dioxide region.So while preparing hydrogen, can collecting the carbon dioxide of release, reduce the discharge of carbon dioxide, the carbon dioxide of collection is also used as the raw material of subsequent handling.The two ends of dividing plate 101 are arranged in chute 102, can slide along chute 102.
When hydrogen generating system starts, by gasifying, by solid hydrogen, the solid hydrogen stored in container 80 is converted to gaseous hydrogen to module, and gaseous hydrogen passes through combustion heat release, provides for hydrogen producer 20 and starts heat energy, as the startup energy of hydrogen producer 20.Certainly, solid hydrogen stores container 80 is not necessaries of the present utility model, it is possible to start hydrogen producer 20 by other energy.
Described raw material conveying device 50 provides power, by the feedstock transportation in storage container 10 to hydrogen producer 20；Described raw material conveying device 50 provides the pressure of 0.15～5MPa (as provided the pressure of 0.2MPa or 1.1MPa or 1.2MPa or 1.5MPa or 5MPa) to raw material so that the hydrogen that hydrogen producer 20 prepares has enough pressure.After described hydrogen producer 20 starts hydrogen manufacturing, the hydrogen partial that hydrogen producer 20 prepares runs (certainly, the operation of hydrogen producer 20 can also pass through other energy) or/and residual air maintains hydrogen producer 20 by burning.
Referring to Fig. 6, described device for rapidly starting provides for hydrogen producer and starts the energy；Described device for rapidly starting includes the first startup device 40, second and starts device 60.
As it is shown in fig. 7, described first startup device 40 includes housing the 41, first heating arrangements the 42, first gasification pipe 43, the internal diameter of the first gasification pipe 43 is 1～2mm, and the first gasification pipe 43 is closely wound on the first heating arrangements 42；First heating arrangements 42 can be electrically heated rod, utilizes alternating current or accumulator, aneroid battery.
One end of described first gasification pipe 43 connects storage container 10, and methanol is admitted in the first gasification pipe 43；The other end of the first gasification pipe 43 exports vaporized methanol, then by ignition mechanism ignition；Or, the other end of the first gasification pipe 43 exports vaporized methanol, and the methanol temperature of output reaches self-ignition point, and methanol is direct spontaneous combustion after exporting from the first gasification pipe 43.
Described second starts device 60 includes the second gasification pipe, and the main body of the second gasification pipe is arranged at described reformer chamber, and the second gasification pipe is reformer chamber heating (can also be the heating of other unit of hydrogen generating system).First gasification pipe 43 is or/and the methanol of the second gasification pipe output heats the second gasification pipe while being reformer chamber heating, by the methanol gasifying in the second gasification pipe.
First, the methanol needing the first gasification pipe 43 output heats the second gasification pipe, the setting time after the methanol producing to gasify can be continued, it is possible to select to close the first startup device 40, and be that the second gasification pipe heats by the methanol of the second gasification pipe output until the second gasification pipe；So can reduce the dependence to extra power further.
In order to improve the firing rate of hydrogen producer, the reformer chamber inwall at described hydrogen producer 20 is provided with and adds pipe line, adds and is placed with catalyst (as can by heating and temperature control at 380 DEG C～480 DEG C) in pipe line；Described device for rapidly starting 40 is attached most importance to the heating of whole room by adding pipe line described in heating, it is possible to improve the efficiency of heating surface.After described hydrogen generating system starts, hydrogen generating system is provided by the hydrogen that hydrogen producer prepares and runs the required energy；At this point it is possible to closedown device for rapidly starting.
In addition, in order to start automobile when there is no other energy, the initial start energy of described device for rapidly starting is that some solar energys start module, and solar energy starts solar panel that module includes being sequentially connected with, solar energy-electric energy change-over circuit, solaode；Solar energy starts module provides electric energy for the first heating arrangements；Or, the initial start energy of described device for rapidly starting is manual generator, and the electric energy sent is stored in battery by manual generator.
First alcohol and water in described storage container is delivered to heat exchanger heat exchange by raw material conveying device, enters vaporizer gasification after heat exchange；Methanol vapor and steam after gasification enter reformer chamber, and it is 320 DEG C～430 DEG C that reformer chamber is provided with catalyst, reformer chamber bottom and middle portion temperature；The temperature on described reformer chamber top is 440 DEG C～560 DEG C；Reformer chamber is connected by connecting line with separation chamber, all or part of top being arranged at reformer chamber of connecting line, and the high temperature that can pass through reformer chamber top continues the heating gas from reformer chamber output；Described connecting line is as the buffering between reformer chamber and separation chamber so that identical or close with the temperature of separation chamber from the temperature of the gas of reformer chamber output；Temperature in described separation chamber is set as 360 DEG C～560 DEG C；It is provided with membrane separator in separation chamber, obtains hydrogen from the aerogenesis end of membrane separator.
Described reformer chamber is provided with catalyst, and catalyst includes the oxide of Pt, the oxide of Pd, the oxide of Cu, the oxide of Fe, the oxide of Zn, rare-earth oxide, transition metal oxide.Wherein precious metals pt content accounts for the 0.5%～2% of catalyst gross mass, Pd content accounts for the 1%～5% of catalyst gross mass, the oxide of Cu accounts for the 5%～15% of catalyst gross mass, the oxide of Fe accounts for the 2%～10% of catalyst gross mass, the oxide of Zn accounts for the 10%～25% of catalyst gross mass, rare-earth oxide accounts for the 5%～45% of catalyst gross mass, and all the other are transition metal oxide.
Or, described catalyst is copper-based catalysts, including material and mass fraction thereof is: the Al of ZrO, 55-80 part of ZnO, 0.5-3 part of CuO, 3-18 part of 3-17 part2O3, the CeO of 1-3 part2, the La of 1-3 part2O3.As, copper-based catalysts includes material and mass fraction is: the CuO of 10 parts, the ZnO of 10 parts, the ZrO of 2 parts, the Al of 60 parts2O3, the CeO of 2 parts2, the La of 2 parts2O3。
Described raw material conveying device provides power, by the feedstock transportation in storage container to hydrogen producer；Described raw material conveying device provides the pressure of 0.15～5MPa to raw material so that the hydrogen that hydrogen producer prepares has enough pressure；After described hydrogen producer starts hydrogen manufacturing, the hydrogen partial that hydrogen producer prepares is or/and residual air is run by the maintenance hydrogen producer that burns.
The hydrogen that described hydrogen producer 20 prepares is delivered to membrane separation device 30 and is easily separated, for the difference of inside and outside pressure of membrane separation device 30 of separating hydrogen gas be more than or equal to 0.7MPa (the inside and outside pressure such as membrane separation device 30 is 0.7MPa or 1.1MPa or 1.2MPa or 1.5MPa or 5MPa).In the present embodiment, described membrane separation device 30 is the membrane separation device at porous ceramic surface Vacuum Deposition palladium-silver, and film plating layer is palladium-silver, and the mass percent palladium of palladium-silver accounts for 75%～78%, and silver accounts for 22%～25%.
Described hydrogen manufacturing subsystem by prepared hydrogen by transfer conduit real-time Transmission to hydrogen gas generating system；Described transfer conduit is provided with air pressure adjustment subsystem, for adjusting the air pressure in transfer conduit；Described hydrogen gas generating system utilizes the hydrogen gas generation that hydrogen manufacturing subsystem prepares.
As shown in Figure 4, described air pressure adjustment subsystem 200 includes microprocessor 21, gas pressure sensor 22, valve positioner 23, air outlet valve 24, outlet pipe 25.Described gas pressure sensor 22 is arranged in transfer conduit, in order to sense the barometric information in transfer conduit, and sends the barometric information of sensing to microprocessor 21；This barometric information received from gas pressure sensor 22 is compared by described microprocessor 21 with setting threshold interval, and controls the switch of air outlet valve 24 with this.When the pressure data received is higher than the maximum setting threshold interval, microprocessor 21 controls valve positioner 23 and opens the air outlet valve setting time, air pressure in transfer conduit is made to be in set point. preferably, one end of outlet pipe 25 connects air outlet valve 24, the other end connects described hydrogen manufacturing subsystem 100, is that the firing equipment (such as reformer chamber) that needs of hydrogen manufacturing subsystem 100 is heated by burning；When the pressure data received is lower than the minima setting threshold interval, microprocessor 21 controls described hydrogen manufacturing subsystem 100 and accelerates the transporting velocity of raw material, thus improving hydrogen manufacturing speed.
As shown in Figure 3, described Collection utilization subsystem 400 includes hydrogen water separator 401, hydrogen check-valves 402, the Vent passageway of hydrogen gas generating system 300 connects the entrance of hydrogen water separator 401, is provided with hydrogen check-valves 402, it is prevented that hydrogen pours in down a chimney in the pipeline that hydrogen water separator 401 exit connects；Described hydrogen water separator 401 is for separating hydrogen gas and water.Additionally, described Collection utilization subsystem also includes hydrogen/oxygen separator, for separating hydrogen gas and oxygen；Hydrogen/oxygen separator is arranged between described hydrogen gas generating system Vent passageway and hydrogen water separator.
In the present embodiment, described Collection utilization subsystem 400 also includes oxygen water separator 411, oxygen check valve 412, is used for collecting oxygen.The hydrogen that described Collection utilization subsystem 400 is collected and oxygen are for hydrogen manufacturing subsystem 100, it is also possible to for hydrogen gas generating system 300.Additionally, the oxygen collected can be deposited in setting container, for people's oxygen uptake；The water collected can be drunk for people.
Owing to described Collection utilization subsystem includes moisture trap (such as above-mentioned hydrogen water separator, oxygen water separator), therefore water (the ratio also many several times of the moisture in raw material can be collected, because methanol also contains hydrogen atom, water is obtained with oxygen reaction) after preparing hydrogen, water is delivered to hydrogen manufacturing subsystem 100, raw water can recycle, it is not necessary to additionally adds.
Therefore, this utility model system can collect the utility such as hydrogen, oxygen gas and water from the residual air of hydrogen gas generating system, it is possible to improves the generating efficiency of system, simultaneously conservation (water).
Described hydrogen manufacturing subsystem utilizes methanol-water to prepare hydrogen, and described hydrogen manufacturing subsystem includes solid hydrogen and stores container, stores container, raw material conveying device, device for rapidly starting, hydrogen producer, membrane separation device；
Described hydrogen gas generating system includes fuel cell, and fuel cell includes some sub-fuel cell modules, and each sub-fuel cell module includes at least one super capacitor；So can export electric energy efficiently, without jumbo lithium battery.
Additionally, described automobile can also include the second genemotor, energy storage units, kinetic energy converting unit, kinetic energy converting unit, energy storage units, the second genemotor are sequentially connected with；The energy of automobile brake is converted to electric energy and is stored in energy storage units by described kinetic energy converting unit, provides electric energy for the second genemotor.Described second genemotor is also connected with hydrogen gas generating system, hydrogen gas generating system provide the energy for the second genemotor.So the energy of skidding consumption can be stored as electric energy, thus the effectively save energy.
Meanwhile, described automobile also includes road environment induction module, allocation database, hydrogen distribution module；Hydrogen distribution module is connected with road environment induction module, allocation database respectively, according to the hydrogen that the data in the data of road environment induction module sensing and allocation database are each genemotor distribution correspondence.
Described road environment induction module is in order to sense road congestion information, ground flat degree information；Road congestion information is according to automobile real-time speed, acceleration, deceleration frequency, and determines down time；Ground flat degree information is determined according to the obliquity sensor arranged on automobile chassis.
Described allocation database stores some tables of data, tables of data records the data (these data according to environmental information power that two genemotors distribution is different, can improve efficiency) for genemotor, the second genemotor distribution hydrogen that each road congestion information, ground flat degree information are corresponding；In genemotor, the second genemotor, one is used for driving trailing wheel or/and front-wheel (such as trailing wheel), and another is used for driving front-wheel or/and trailing wheel (such as front-wheel and trailing wheel).So, it is possible to more efficiently distribute kinetic energy to automobile, improve efficiency, save the energy.
Referring to Fig. 9, in the present embodiment, described hydrogen gas generating system is fuel cell system, and fuel cell system includes: gas supply device, pile 201；Described gas supply device utilizes the gas of compression as power, and automatic transport is to pile 201.
In the present embodiment, gas supply device is compressed gas body feeding 202, and described compression gas enters pile 201 after being delivered to a mixing container 203, one end of mixing container 203 connects air；Natural air is reacted by the power that compression gas produces after entering mixing container 203 in setting ratio inspiration pile, regulates oxygen content.
Described fuel cell system also includes air intake conduit, outlet pipe, and air intake conduit, outlet pipe are all through humidification system 204.The gas of described compression is mainly oxygen (can also be air)；Natural air enters pile 201 with compressed oxygen after mixing container mixing.
Described fuel cell system also includes gas regulating system, and gas regulating system is arranged in mixing container 203；Described gas regulating system includes valve regulated and controls device, and oxygen content sensor is or/and compress gas compression ratio sensor.
Described oxygen content sensor is in order to sense the air of mixing and the content of oxygen in oxygen in mixing container, and the data sensed is sent to valve regulated control device.
Described compression gas compression ratio sensor is in order to sense the compression ratio of compressed oxygen, and the data sensed is sent to valve regulated control device.
Described valve regulated controls device according to oxygen content sensor or/and the sensing result of compression gas compression ratio sensor regulates oxygen delivery valve door, air entrainment valve door, controls the conveying ratio (if natural air ratio can be 0-70%) of compressed oxygen, natural air；Mixing gas is pushed to pile reaction by the power that compressed oxygen produces after entering mixing container, utilizes natural air to do dilution decompression.
Described humidification system 204 includes humidity exchanging container, humidity exchange pipeline, and humidity exchange pipeline is a part for air intake conduit；After described reaction, gas outlet pipe is delivered to humidity exchanging container.
The material of described humidity exchange pipeline is only permeable airtight so that after reaction, gas and natural air carry out humidity exchange, and cannot circulate between gas.Humidity exchange pipeline spiral in humidity exchanging container is arranged, it is possible to sufficiently conducted humidity exchanges.
Embodiment two
A kind of water hydrogen power train, including: power car, non-powered car, power car is provided with hydrogen production by methanol system, hydrogen gas generating system, genemotor, hydrogen production by methanol system, hydrogen gas generating system, genemotor are arranged in power car, and hydrogen production by methanol system, hydrogen gas generating system, genemotor are sequentially connected with；Described hydrogen production by methanol system utilizes preparing hydrogen by reforming methanol-water steam, and hydrogen obtains highly purified hydrogen by being coated with the membrane separation device of palladium-silver, and the hydrogen of acquisition is generated electricity by hydrogen gas generating system, and the electric energy sent is for genemotor work.
Described hydrogen production by methanol system includes storing container, store container and be provided with interrupter, interrupter regulon, storage container is divided at least two region by interrupter, and interrupter regulon regulates interrupter in the position stored in container, regulates the size of regional.
Preferably, the side of described interrupter arranges reaction liquid, and opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Dividing plate is connected to pushing mechanism, when the liquid stored in container reduces or carbon dioxide increases up to impose a condition, pushing mechanism driving isolation mechanism action, reduces the volume of storage reaction liquid regions, increases the volume in storage carbon dioxide region.
Described storage container includes: driving mechanism that container, the space mechanism being arranged in container are connected with space mechanism, control module, induction module.
Container is at least divided into two spaces by described space mechanism；In two spaces, a placing response liquid, opposite side arranges the carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；Control module and connect driving mechanism, induction module respectively.
Described induction module, in order to sense the amount of reaction liquid in container, or/and senses the amount of carbon dioxide of hydrogen gas generating system release, the liquid then compressed or solid-state；And sensed data is sent to controlling module.
The Data Control driving mechanism that described control module senses according to the induction module action to space mechanism；When liquid in liquid container reduces or carbon dioxide increases up to impose a condition, pushing mechanism drives dividing plate action, reduces the volume of reaction liquid, increases the volume of carbon dioxide.
In sum, the water hydrogen power train of the emission-free discharge that the utility model proposes, available methanol, as the energy of automobile, solves energy crisis, reduces and even avoids emission from vehicles.The tail gas CO2 of discharge can be collected by this utility model water hydrogen power train, as the raw material of subsequent handling (preparing methanol) so that the energy recycles；This utility model, without noxious gas emission, is even avoided that the discharge of CO2, effectively protects environment.
Here description of the present utility model and application is illustrative, is not wishing to limit in the above-described embodiments scope of the present utility model.The deformation of embodiments disclosed herein and change are possible, for those skilled in the art embodiment replace and the various parts of equivalence are known.It should be appreciated by the person skilled in the art that when without departing from spirit of the present utility model or substitutive characteristics, this utility model can in other forms, structure, layout, ratio, and realize with other assembly, material and parts.When without departing from this utility model scope and spirit, it is possible to embodiments disclosed herein is carried out other deformation and changes.
Claims (7)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520867277.4U CN205388991U (en) | 2015-11-03 | 2015-11-03 | Water hydrogen power train |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201520867277.4U CN205388991U (en) | 2015-11-03 | 2015-11-03 | Water hydrogen power train |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN205388991U true CN205388991U (en) | 2016-07-20 |
Family
ID=56380934
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201520867277.4U Active CN205388991U (en) | 2015-11-03 | 2015-11-03 | Water hydrogen power train |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN205388991U (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109249944A (en) * | 2018-10-08 | 2019-01-22 | 王树华 | A kind of light-weight environment-friendly carriage body construction |
-
2015
- 2015-11-03 CN CN201520867277.4U patent/CN205388991U/en active Active
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109249944A (en) * | 2018-10-08 | 2019-01-22 | 王树华 | A kind of light-weight environment-friendly carriage body construction |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104986051A (en) | Electric methanol hydrogen transporting tool | |
| CN105270201A (en) | Water hydrogen powered vehicle without exhaust emission | |
| CN106025314A (en) | Movable charging vehicle for electric automobile | |
| CN104986733B (en) | A kind of electronic marine equipment of alcohol hydrogen | |
| CN105390719A (en) | Alcohol hydrogen power generation device and storage apparatus thereof | |
| CN105751914A (en) | Carbon dioxide cycled water-hydrogen-powered transportation means | |
| CN105070931A (en) | Hydrogen production power generation system employing methanol steam | |
| CN204749883U (en) | Mellow wine hydrogen electric transportation instrument | |
| CN105304918A (en) | Water hydrogen power mining machine without tail gas discharging | |
| CN204915340U (en) | Electric motor car of many wheel drives | |
| CN105762383A (en) | Carbon dioxide circulating type water-hydrogen power automobile | |
| CN205365273U (en) | No exhaust emissions's water hydrogen car | |
| CN104986050B (en) | A kind of biogas electric transportation instrument | |
| CN205388991U (en) | Water hydrogen power train | |
| CN205429082U (en) | Electronic bus of mellow wine hydrogen | |
| CN204978283U (en) | Mellow wine hydrogen electric automobile | |
| CN106025300A (en) | Charging system for electric automobile | |
| CN105109355A (en) | Multi-wheel driven electric car and driving method thereof | |
| CN105070930A (en) | Power generation system capable of producing hydrogen from methanol and vapor, and fuel cell system | |
| CN106004494A (en) | Water hydrogen power automobile and air conditioner system thereof | |
| CN106025312A (en) | Water hydrogen-powered vehicle and air conditioning system therefor | |
| CN204927425U (en) | Methanol steam hydrogen production power generation system and its fuel cell system | |
| CN108248403A (en) | Water hydrogen power vehicle | |
| CN105390718A (en) | Water-hydrogen power train without exhaust gas emission | |
| CN105428674A (en) | Water-hydrogen power motorcycle free of exhaust gas emission |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20210918 Granted publication date: 20160720 |
|
| PD01 | Discharge of preservation of patent | ||
| PD01 | Discharge of preservation of patent |
Date of cancellation: 20240918 Granted publication date: 20160720 |
|
| PP01 | Preservation of patent right | ||
| PP01 | Preservation of patent right |
Effective date of registration: 20240918 Granted publication date: 20160720 |