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CN205275333U - Oil field extraction water composite treatment system - Google Patents

Oil field extraction water composite treatment system Download PDF

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CN205275333U
CN205275333U CN201520984710.2U CN201520984710U CN205275333U CN 205275333 U CN205275333 U CN 205275333U CN 201520984710 U CN201520984710 U CN 201520984710U CN 205275333 U CN205275333 U CN 205275333U
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oil
inorganic carbon
pipeline
carbon film
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王丽莉
闫旭涛
朱瑞龙
杨鸿鹰
王玲燕
沈哲
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Shaanxi Chemical Research Institute Co ltd
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Shaanxi Research Design Institute of Petroleum and Chemical Industry
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Abstract

本实用新型属于水处理技术领域,具体提供了一种油田采出水复合处理系统,该系统包括油水分离器、缓冲水箱、无机碳膜处理器、积水箱、过滤吸附处理器、反洗泵以及净化水罐,将油水分离后通过无机碳膜处理,之后再过滤吸附,使产水中的浮油及乳化油能够完全去除,对水中溶解油去除效果较好,产水中残留的溶解油含量极低,本实用新型的操作运行简单、维护方便,成本低,不需要PH调节剂、絮凝剂及混凝剂等化学药剂,无二次污染,环境污染小。

The utility model belongs to the technical field of water treatment, and specifically provides a composite treatment system for oilfield produced water, which includes an oil-water separator, a buffer water tank, an inorganic carbon film processor, a water storage tank, a filter adsorption processor, a backwash pump and Purify the water tank, separate the oil from water and treat it with an inorganic carbon membrane, and then filter and absorb, so that the slick oil and emulsified oil in the product water can be completely removed, the effect of removing dissolved oil in the water is better, and the residual dissolved oil content in the product water is extremely low , The utility model is simple in operation, convenient in maintenance, low in cost, does not need chemical agents such as pH regulators, flocculants and coagulants, has no secondary pollution, and has little environmental pollution.

Description

一种油田采出水复合处理系统A composite treatment system for oilfield produced water

技术领域technical field

本实用新型涉及一种油田采出水的处理系统,属于水处理技术领域。The utility model relates to a treatment system for oilfield produced water, which belongs to the technical field of water treatment.

背景技术Background technique

由于油田污水成分比较复杂,主要含有油、悬浮物、岩石碎屑、腐蚀产物、气体及细菌微生物等,油分含量及油在水中存在形式也不相同,在实际应用中通常采用单一的水处理方法往往效果不佳,有局限性,因此需要两三种以上方法联合使用。Due to the complex composition of oilfield sewage, which mainly contains oil, suspended solids, rock debris, corrosion products, gas and bacterial microorganisms, etc., the oil content and the form of oil in water are also different. In practical applications, a single water treatment method is usually adopted. Often the effect is not good and there are limitations, so two or more methods need to be used in combination.

油田的水质特点、生产方式、环境情况以及处理水的用途的不同,油田污水处理工艺差别较大,但主要是通过破乳和去除分散油、重力沉降分离、气浮浮选分离、粗过滤、精细过滤及膜处理等工艺流程,工艺流程长,过程繁琐,较难控制,水质波动较大,还需要结合破乳剂、絮凝剂、助凝剂化学药剂的化学处理方法才能使出水水质达到标准要求,这又造成水的二次污染,且目前的传统处理工艺对水中污油的去除主要是针对浮油、分散油及乳化油,对于水中所存在的溶解态油很难去除,产水中的油含量虽然可以达到小于5.0mg/L,但难以达到小于1.0mg/L的要求。The water quality characteristics, production methods, environmental conditions and uses of treated water in oilfields are different, and oilfield sewage treatment processes are quite different, but the main methods are through demulsification and removal of dispersed oil, gravity sedimentation separation, air flotation separation, coarse filtration, Processes such as fine filtration and membrane treatment are long, cumbersome, difficult to control, and the water quality fluctuates greatly. It also needs chemical treatment methods combined with demulsifiers, flocculants, and coagulant aids to make the effluent water quality meet the standard requirements. , which causes secondary pollution of water, and the current traditional treatment process for the removal of dirty oil in water is mainly for slick oil, dispersed oil and emulsified oil, it is difficult to remove the dissolved oil in water, and the oil in produced water Although the content can reach less than 5.0mg/L, it is difficult to meet the requirement of less than 1.0mg/L.

实用新型内容Utility model content

本实用新型的目的是针对现有的油田采出水的处理工艺中处理设备多,工艺路线长且过于复杂,操作控制难,出水水质波动大等技术问题,提供了一种油田采出水复合处理系统。The purpose of this utility model is to provide a complex treatment system for oilfield produced water in view of the technical problems in the existing oilfield produced water treatment process, such as many processing equipment, long and complicated process route, difficult operation and control, and large fluctuation of effluent water quality. .

为了实现上述目的,本实用新型所采用的技术方案是该油田采出水复合处理系统,包括油水分离器、缓冲水箱、无机碳膜处理器、积水箱、过滤吸附处理器、反洗泵以及净化水罐;In order to achieve the above purpose, the technical solution adopted by the utility model is the oilfield produced water composite treatment system, including oil-water separator, buffer water tank, inorganic carbon film processor, water storage tank, filter adsorption processor, backwash pump and purification pitcher;

其中油水分离器的出水口通过管道与缓冲水箱的进水口连通,缓冲水箱的出水口通过管道与无机碳膜处理器的进水口连通,无机碳膜处理器的过滤水口通过管道与积水箱的进水口连通、浓水出口通过管道与油水分离器的进水口连通,积水箱的出水口通过管道与过滤吸附处理器的进水口连通,过滤吸附处理器的出水口与净化水罐的进水口连通,净化水罐的净化水出口与净化水管道连通、反洗水出口通过反洗泵与无机碳膜处理器的反洗水入口连通。Wherein the water outlet of the oil-water separator is connected with the water inlet of the buffer water tank through the pipeline, the water outlet of the buffer water tank is connected with the water inlet of the inorganic carbon film processor through the pipeline, and the filter water port of the inorganic carbon film processor is connected with the water storage tank through the pipeline The water inlet is connected, the concentrated water outlet is connected with the water inlet of the oil-water separator through the pipeline, the water outlet of the storage tank is connected with the water inlet of the filter adsorption processor through the pipeline, and the water outlet of the filter adsorption processor is connected with the water inlet of the purified water tank connected, the purified water outlet of the purified water tank is connected with the purified water pipeline, and the backwash water outlet is connected with the backwash water inlet of the inorganic carbon film processor through the backwash pump.

上述无机碳膜处理器的无机碳膜膜孔径为0.01~0.6μm,跨膜压差为0.05~0.5MPa。The pore diameter of the inorganic carbon membrane of the above-mentioned inorganic carbon membrane processor is 0.01-0.6 μm, and the transmembrane pressure difference is 0.05-0.5 MPa.

上述过滤吸附处理器的压差为0.02~0.1MPa,过滤吸附处理器的滤速为3~12m/h。The pressure difference of the filter adsorption processor is 0.02-0.1 MPa, and the filtration rate of the filter adsorption processor is 3-12 m/h.

上述过滤吸附处理器的过滤材料是由白垩与硅藻土按照质量比为1:3~1:8的比例混合后在850~1150℃焙烧40~90min制成。The filter material of the filter adsorption processor is made by mixing chalk and diatomaceous earth according to the mass ratio of 1:3-1:8, and then roasting at 850-1150° C. for 40-90 minutes.

本实用新型的油田采出水复合处理系统,主要是利用油水分离、无机碳膜处理,之后利用焙烧的白垩与硅藻土作为过滤材料截留水中残留的悬浮物并将溶解油进行吸附,使出水满足:油含量<1.0mg/L,悬浮物含量<1.0mg/L,粒径中值<1μm的标准要求,本实用新型的处理路线简单、处理时间短,去除效率高,而且充分利用无机碳膜抗污染性强、耐油的特性,对悬浮物和乳化油、浮油进行有效截留、过滤,并且易于冲洗,使用过程中无需停车,保证系统连续运行,本实用新型的操作运行简单、维护方便,成本低,运行稳定,经试验连续运行17天,产水中油含量、悬浮物以及粒径中值含量稳定,而且本实用新型不需要PH调节剂、絮凝剂及混凝剂等化学药剂,无二次污染,环境污染小,使产水中的浮油及乳化油能够完全去除,对水中溶解油去除效果较好,产水中残留的溶解油含量极低,满足《碎屑岩油藏注水水质指标及分析方法》SY/T5329-2012标准的要求。The oilfield produced water composite treatment system of the utility model mainly uses oil-water separation and inorganic carbon film treatment, and then uses roasted chalk and diatomaceous earth as filter materials to intercept the residual suspended matter in the water and absorb the dissolved oil, so that the effluent meets : Oil content < 1.0mg/L, suspended matter content < 1.0mg/L, particle size median < 1μm standard requirements, the utility model has simple processing route, short processing time, high removal efficiency, and fully utilizes the inorganic carbon film Strong anti-pollution and oil-resistant characteristics, effective interception and filtration of suspended solids, emulsified oil, and slick oil, and easy to wash, no need to stop during use, ensuring continuous operation of the system. The utility model is simple in operation and maintenance. Low cost, stable operation, continuous operation for 17 days after the test, stable oil content, suspended solids and median particle size content in the produced water, and the utility model does not require chemical agents such as pH regulators, flocculants and coagulants, without any difference secondary pollution, less environmental pollution, so that the slick oil and emulsified oil in the produced water can be completely removed. Analysis method"SY/T5329-2012 standard requirements.

附图说明Description of drawings

图1为本实用新型的油田采出水复合处理系统结构框图。Fig. 1 is a structural block diagram of the composite treatment system for oilfield produced water of the present utility model.

具体实施方式detailed description

现结合附图和实施例对本实用新型的技术方案进行进一步说明。The technical solution of the utility model is further described in conjunction with the accompanying drawings and embodiments.

由图1可知,该油田采出水复合处理系统是由油水分离器1、缓冲水箱2、无机碳膜处理器3、积水箱4、过滤吸附处理器5、反洗泵7以及净化水罐6通过管道连接构成。It can be seen from Figure 1 that the oilfield produced water composite treatment system is composed of oil-water separator 1, buffer water tank 2, inorganic carbon film processor 3, water storage tank 4, filter adsorption processor 5, backwash pump 7 and purified water tank 6 Constructed by pipe connections.

其中:油水分离器1属于预处理单元,可以采用旋流器或者斜板除油器或者也可以是三相分离器,其属于常用设备,该油水分离器1的进水口与油田采出水来水管道连通,该油水分离器1的出水口通过管道与缓冲水箱2的进水口连通,缓冲水箱2的出水口通过管道与无机碳膜处理器3的进水口连通,无机碳膜处理器3的过滤水出口通过管道与积水箱4的进水口连通,该无机碳膜处理器3的浓水出口通过管道与油水分离器1的进水口连通,将含有悬浮物及浮油的浓水部分返回油水分离器1循环处理,积水箱4的出水口通过管道与过滤吸附处理器5的进水口连通,过滤吸附处理器5的出水口与净化水罐6的进水口连通,净化水罐6的净化水出口与净化水管道连通、反洗水出口通过安装在管道上的反洗泵7与无机碳膜处理器3的反洗水入口连通。Among them: the oil-water separator 1 belongs to the pretreatment unit, which can be a cyclone or an inclined plate degreaser or a three-phase separator, which is a commonly used equipment. The pipeline is connected, and the water outlet of this oil-water separator 1 is communicated with the water inlet of buffer water tank 2 through pipeline, and the water outlet of buffer water tank 2 is communicated with the water inlet of inorganic carbon membrane processor 3 through pipeline, and the filtration of inorganic carbon membrane processor 3 The water outlet is connected to the water inlet of the storage tank 4 through a pipeline, and the concentrated water outlet of the inorganic carbon film processor 3 is connected to the water inlet of the oil-water separator 1 through a pipeline, and the concentrated water part containing suspended solids and slick oil is returned to the oil-water Separator 1 circulation process, the water outlet of storage tank 4 communicates with the water inlet of filter adsorption processor 5 through pipeline, the water outlet of filter adsorption processor 5 communicates with the water inlet of purified water tank 6, the purification of purified water tank 6 The water outlet communicates with the purified water pipeline, and the backwash water outlet communicates with the backwash water inlet of the inorganic carbon film processor 3 through the backwash pump 7 installed on the pipeline.

上述的无机碳膜处理器3采用错流方式进行,其过滤材料为复合碳化硅材料制成的多通道膜芯,膜孔径为0.01~0.10μm之间。The above-mentioned inorganic carbon membrane processor 3 adopts a cross-flow method, and its filter material is a multi-channel membrane core made of composite silicon carbide material, and the membrane pore diameter is between 0.01-0.10 μm.

上述过滤吸附处理器5的结构属于普通滤芯过滤器结构,本实用新型的滤芯过滤材料选用烧结的白垩与硅藻土混合物,当来水自上而下经过过滤材料表面时溶解油及微量的悬浮物被吸附、过滤,从而达到净化的效果,本实用新型的白垩与硅藻土的混合质量配比可以在1:3~1:8之间任意选取,本实用新型的白垩与硅藻土按照比例混合后需要在850~1150℃的温度下焙烧40~90min,并制成滤芯状装填在过滤器中。The structure of the above-mentioned filter adsorption processor 5 belongs to the structure of an ordinary filter element filter. The filter element filter material of the present utility model is a mixture of sintered chalk and diatomaceous earth. The substance is adsorbed and filtered, so as to achieve the effect of purification. The mixing mass ratio of the chalk and diatomite of the utility model can be arbitrarily selected between 1:3~1:8. The chalk and diatomite of the utility model are according to After proportional mixing, it needs to be roasted at a temperature of 850-1150°C for 40-90 minutes, and made into a filter element and packed in a filter.

上述系统实现油田采出水复合处理的方法是由以下步骤组成:The method for the above-mentioned system to realize the compound treatment of oilfield produced water is composed of the following steps:

(1)将油田采出水在油水分离器1中停留一定时间后使油与水初步分离,去除掉浮油和硬质悬浮物,使得初步分离水中油含量≤100mg/L,悬浮物含量≤100mg/L;(1) Preliminarily separate the oil and water after the oilfield produced water stays in the oil-water separator 1 for a certain period of time, and remove the slick oil and hard suspended matter, so that the oil content in the preliminary separated water is ≤100mg/L, and the suspended matter content is ≤100mg /L;

(2)初步分离所得除油水经缓冲水箱2缓冲后在无机碳膜处理器3中常温下采用错流过滤方式处理,除掉水体中的浮油、乳化油以及残余悬浮物,使得出水中油含量≤5mg/L,悬浮物含量≤2mg/L,含有悬浮物及浮油的浓水部分出水返回油水分离器1循环处理,过滤后出水输送至积水箱4缓冲;(2) The deoiled water obtained after preliminary separation is buffered by the buffer water tank 2, and then processed by cross-flow filtration at room temperature in the inorganic carbon film processor 3 to remove floating oil, emulsified oil and residual suspended matter in the water body, so that the oil content in the effluent is ≤5mg/L, suspended solids content≤2mg/L, the effluent of concentrated water containing suspended solids and slick oil is returned to oil-water separator 1 for circulation treatment, and the filtered effluent is transported to storage tank 4 for buffering;

(3)积水箱4缓冲后的出水进入过滤吸附处理器5中,自上而下穿过过滤材料,利用过滤材料进行过滤、吸附,过滤掉微量的悬浮物并且将残留的溶解油吸附去除,从而使出水达到油田回注水的标准要求,油含量≤1mg/L,悬浮物含量≤1mg/L,粒径中值<1μm,过滤出水储存在净化水罐6中,部分作为反洗水进入无机碳膜处理器3中进行反洗,其余部分进入注水系统。(3) The outlet water buffered by the storage tank 4 enters the filtration and adsorption processor 5, passes through the filter material from top to bottom, and uses the filter material to filter and absorb, filter out trace suspended matter and remove the residual dissolved oil by adsorption , so that the effluent water meets the standard requirements of oilfield reinjection water, the oil content is ≤1mg/L, the suspended solid content is ≤1mg/L, and the median particle size is <1μm. The filtered water is stored in the purified water tank 6, and part of it enters as backwash water In the inorganic carbon film processor 3, backwash is carried out, and the rest enters the water injection system.

Claims (4)

1. an oil field extracted water Combined Processing system, it is characterised in that comprise water-and-oil separator (1), buffer tank (2), inorganic carbon film treater (3), ponding case (4), filtration and adsorption treatment device (5), purification water pot (6) and backwashing pump (7);
Wherein the water outlet of water-and-oil separator (1) is connected by the water-in of pipeline with buffer tank (2), the water outlet of buffer tank (2) is connected by the water-in of pipeline with inorganic carbon film treater (3), the filtered water outlet of inorganic carbon film treater (3) is connected by the water-in of pipeline with ponding case (4), dense water out is connected by the water-in of pipeline with water-and-oil separator (1), the water outlet of ponding case (4) is connected by the water-in of pipeline with filtration and adsorption treatment device (5), the water outlet of filtration and adsorption treatment device (5) is connected with the water-in of purification water pot (6), purify waste water outlet and the pipeline communication of purifying waste water of purification water pot (6), backwash water outlet is connected by the backwash water entrance of backwashing pump (7) with inorganic carbon film treater (3).
2. oil field extracted water Combined Processing system according to claim 1, it is characterised in that the inorganic carbon film membrane pore size of described inorganic carbon film treater (3) is 0.01��0.6 ��m, and transmembrane pressure is 0.05��0.5MPa.
3. oil field extracted water Combined Processing system according to claim 1, it is characterised in that the pressure reduction of described filtration and adsorption treatment device (5) is 0.02��0.1MPa, and the filtering velocity of filtration and adsorption treatment device (5) is 3��12m/h.
4. oil field extracted water Combined Processing system according to claim 1, it is characterised in that the filtering material of described filtration and adsorption treatment device (5) makes at 850��1150 DEG C of roasting 40��90min after mixing according to the ratio that mass ratio is 1:3��1:8 with diatomite by chalk.
CN201520984710.2U 2015-12-01 2015-12-01 Oil field extraction water composite treatment system Active CN205275333U (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105254054A (en) * 2015-12-01 2016-01-20 陕西省石油化工研究设计院 Oilfield produced water compound treatment system and method
CN107986480A (en) * 2017-12-28 2018-05-04 西安长庆科技工程有限责任公司 A kind of produced water treatment device and technique
CN108002614A (en) * 2018-01-10 2018-05-08 东莞市盛源石油化工有限公司 Oily sewage treatment process

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105254054A (en) * 2015-12-01 2016-01-20 陕西省石油化工研究设计院 Oilfield produced water compound treatment system and method
CN105254054B (en) * 2015-12-01 2017-12-19 陕西省石油化工研究设计院 A kind of oil field extracted water multiple treating system and method
CN107986480A (en) * 2017-12-28 2018-05-04 西安长庆科技工程有限责任公司 A kind of produced water treatment device and technique
CN108002614A (en) * 2018-01-10 2018-05-08 东莞市盛源石油化工有限公司 Oily sewage treatment process

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