CN205209921U - RIM testing arrangement - Google Patents
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- CN205209921U CN205209921U CN201520888260.7U CN201520888260U CN205209921U CN 205209921 U CN205209921 U CN 205209921U CN 201520888260 U CN201520888260 U CN 201520888260U CN 205209921 U CN205209921 U CN 205209921U
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- 238000012360 testing method Methods 0.000 title claims abstract description 94
- 239000004567 concrete Substances 0.000 claims abstract description 37
- 229920001971 elastomer Polymers 0.000 claims abstract description 16
- 238000005192 partition Methods 0.000 claims description 5
- 238000009434 installation Methods 0.000 claims 7
- 238000007599 discharging Methods 0.000 claims 4
- 238000005266 casting Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 6
- 238000007789 sealing Methods 0.000 abstract description 3
- 239000003792 electrolyte Substances 0.000 abstract description 2
- 238000002474 experimental method Methods 0.000 abstract description 2
- 238000005868 electrolysis reaction Methods 0.000 abstract 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 14
- 238000009792 diffusion process Methods 0.000 description 14
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 12
- 238000000034 method Methods 0.000 description 6
- 238000010998 test method Methods 0.000 description 6
- XMBWDFGMSWQBCA-UHFFFAOYSA-M iodide Chemical compound [I-] XMBWDFGMSWQBCA-UHFFFAOYSA-M 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 235000009518 sodium iodide Nutrition 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229940006461 iodide ion Drugs 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000011150 reinforced concrete Substances 0.000 description 3
- 229920002379 silicone rubber Polymers 0.000 description 3
- 239000004945 silicone rubber Substances 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 230000004907 flux Effects 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 238000009489 vacuum treatment Methods 0.000 description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- 229930091051 Arenine Natural products 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000004574 high-performance concrete Substances 0.000 description 1
- -1 iodide ions Chemical class 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 230000010220 ion permeability Effects 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- JLKDVMWYMMLWTI-UHFFFAOYSA-M potassium iodate Chemical compound [K+].[O-]I(=O)=O JLKDVMWYMMLWTI-UHFFFAOYSA-M 0.000 description 1
- 239000001230 potassium iodate Substances 0.000 description 1
- 235000006666 potassium iodate Nutrition 0.000 description 1
- 229940093930 potassium iodate Drugs 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
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Abstract
Description
[技术领域][technical field]
本实用新型涉及混凝土表层碘离子渗透测试,尤其涉及一种RIM测试装置。The utility model relates to an iodine ion penetration test on the concrete surface, in particular to a RIM test device.
[背景技术][Background technique]
钢筋混凝土结构结合了钢筋与混凝土的优点,造价较低,是土木工程结构设计中的首选形式,其应用范围非常广泛,是最常用的结构形式。但这并不说明钢筋混凝土结构是十全十美的。事实上,混凝土应用于土木工程的100多年间,大量的钢筋混凝土结构由于各种各样的原因而提前失效,达不到预定的服役年限,其中有的是由于结构设计的抗力不足造成的,有的是由于使用荷载的不利变化引起的,但更多的是由于结构的耐久性不足导致的。特别是沿海及近海地区的混凝土结构,由于海洋环境对混凝土的腐蚀,导致钢筋锈蚀而使结构发生早期损坏,降低了结构的耐久性能,这已成为实际工程中的重要问题。目前,在实验室有许多试验方法可以评价混凝土抗氯离子扩散的性能,各种渗透性试验方法所研究的渗透过程、所依据的原理各不相同,其最终目的都是计算氯离子的扩散系数,从而有助于结构寿命的准确预测。因此,国内外相关研究主要集中在氯离子扩散系数上,但内含氯离子混凝土结构扩散系数的测定还有待解决。Reinforced concrete structure combines the advantages of steel bars and concrete, and has a low cost. It is the preferred form in the design of civil engineering structures. Its application range is very wide and it is the most commonly used structural form. But this does not mean that the reinforced concrete structure is perfect. In fact, during the more than 100 years when concrete was used in civil engineering, a large number of reinforced concrete structures failed prematurely due to various reasons, and did not reach the scheduled service life. Caused by unfavorable changes in service loads, but more often due to insufficient durability of the structure. Especially for concrete structures in coastal and offshore areas, due to the corrosion of concrete by the marine environment, the corrosion of steel bars leads to early damage to the structure and reduces the durability of the structure. This has become an important problem in practical engineering. At present, there are many test methods in the laboratory to evaluate the performance of concrete against the diffusion of chloride ions. The permeation process studied by various permeability test methods and the principles on which they are based are different. The ultimate goal is to calculate the diffusion coefficient of chloride ions. , thus contributing to the accurate prediction of the structural life. Therefore, relevant research at home and abroad mainly focuses on the diffusion coefficient of chloride ions, but the determination of the diffusion coefficient of concrete structures containing chloride ions remains to be resolved.
抗氯离子渗透的能力是评价高性能混凝土耐久性的一项有效指标,目前测量混凝土渗透系数最常用的方法是非稳态电迁移试验(RCM),该方法最初由Tang建立,后来形成Build492规范。但是当混凝土内部含有氯离子且含量过多的时候,结构内含氯离子也会在电场作用下迁移,并且会和指示剂发生反应。这两种作用都会影响到RCM实验结果的准确性,当内含氯离子超出一定限值,采用RCM的实验方法将不能测出结构的氯离子扩散系数,需要采用新型的RIM测试方法。The ability to resist chloride ion penetration is an effective indicator for evaluating the durability of high-performance concrete. At present, the most commonly used method for measuring the permeability coefficient of concrete is the unsteady electromigration test (RCM). This method was originally established by Tang and later formed the Build492 specification. However, when the concrete contains too much chloride ions, the chloride ions in the structure will also migrate under the action of an electric field and react with the indicator. These two effects will affect the accuracy of the RCM test results. When the chloride ion contained exceeds a certain limit, the RCM test method will not be able to measure the chloride ion diffusion coefficient of the structure, and a new RIM test method is required.
RIM测试即非稳态碘离子快速扩散(RapidIodineMigration,RIM)测试。然而,目前RIM测试设备依然使用的是RCM测试设备。The RIM test is an unsteady iodine ion rapid diffusion (RapidIodineMigration, RIM) test. However, the current RIM test equipment still uses RCM test equipment.
专利号为CN200820302173.9的发明公开了一种混凝土RCM氯离子扩散系数&电通量多功能测试仪,包括RCM氯离子扩散系数测试设备、电通量测试设备和测试主机;RCM氯离子扩散系数测试设备包括至少一个装有阴极电解液的溶液器皿(10),阴极电解液(11)中置有阴极(18);溶液器皿的内部有一斜面,斜面上置有一个倾斜的有机硅橡胶套(16),有机硅橡胶套由支架(12)支撑,其内部装有混凝土试件(25)和阳极电解液(14),混凝土试件(25)固定于有机硅橡胶套底部,阳极电解液中置有阳极(15)和温度传感器(13)。The invention with the patent number CN200820302173.9 discloses a concrete RCM chloride ion diffusion coefficient & electric flux multifunctional tester, including RCM chloride ion diffusion coefficient test equipment, electric flux test equipment and a test host; RCM chloride ion diffusion coefficient The test equipment comprises at least one solution vessel (10) containing catholyte, and a cathode (18) is placed in the catholyte (11); the inside of the solution vessel has an inclined surface, and an inclined silicone rubber sleeve ( 16), the silicone rubber sleeve is supported by the bracket (12), and the concrete specimen (25) and the anolyte (14) are housed inside it, and the concrete specimen (25) is fixed on the bottom of the silicone rubber sleeve, and the anolyte An anode (15) and a temperature sensor (13) are provided.
因为RIM测试方法需要引入碘离子的药品是NaI,NaI不同于RCM测试方法引入氯离子的Nacl。碘化钠具有潮解性,在湿空气中吸收水分而结块。与空气接触,能使碘游离析出,见光易分解。因此使用上述的RCM氯离子扩散系数测试设备做RIM测试可靠度不高,测试数据不能满足精度要求。Because the RIM test method needs to introduce iodide ion into the drug is NaI, NaI is different from the RCM test method to introduce chloride ion Nacl. Sodium iodide is deliquescent, and it absorbs moisture in humid air and agglomerates. In contact with air, iodine can be separated and separated, and it is easy to decompose when exposed to light. Therefore, the reliability of the RIM test using the above-mentioned RCM chloride ion diffusion coefficient test equipment is not high, and the test data cannot meet the accuracy requirements.
[发明内容][Content of the invention]
本实用新型要解决的技术问题是提供一种测试数据可靠度较高的RIM测试装置。The technical problem to be solved by the utility model is to provide a RIM test device with high test data reliability.
为了解决上述技术问题,本实用新型采用的技术方案是,一种RIM测试装置,包括测试主机、密封箱体和至少一个装有阴极电解液的试验槽,阴极电解液中置有阴极;试验槽内部有一斜面,斜面上置有倾斜的橡胶套,橡胶套内部装有混凝土试件和阳极电解液,混凝土试件固定于橡胶套底部,阳极电解液中置有阳极,阳极和阴极分别与测试主机连接;所述的试验槽布置在密封箱体中,密封箱体的箱壁上包括通线孔,阳极和阴极与测试主机连接的电线穿过密封箱体的通线孔。In order to solve the above-mentioned technical problems, the technical solution adopted by the utility model is, a kind of RIM test device, comprises test main frame, sealed casing and at least one test cell that catholyte is housed, is equipped with negative electrode in catholyte; Test cell There is an inclined surface inside, and an inclined rubber sleeve is placed on the inclined surface. The concrete specimen and the anolyte are installed inside the rubber sleeve. The concrete specimen is fixed at the bottom of the rubber sleeve, and the anode is placed in the anolyte. Connection; the test tank is arranged in a sealed box, and the wall of the sealed box includes a wire hole, and the wires connecting the anode and the cathode to the test host pass through the wire hole of the sealed box.
以上所述的RIM测试装置,密封箱体内装有温度控制系统,温度控制系统包括微型空调和温度测定计。In the RIM testing device described above, a temperature control system is housed in the sealed box, and the temperature control system includes a micro air conditioner and a thermometer.
以上所述的RIM测试装置,试验槽的顶部装有盖板,盖板上包括通线孔,阳极和阴极与测试主机连接的电线穿过盖板上的通线孔。In the RIM test device described above, a cover plate is installed on the top of the test tank, and the cover plate includes a wire hole, and the wires connecting the anode and the cathode to the test host pass through the wire hole on the cover plate.
以上所述的RIM测试装置,试验槽底面为坡面,试验槽的底部接排液管,排液管的入口位于坡面的低点部位;排液管穿过密封箱体的侧壁,排液管的出口装有阀门。In the RIM test device described above, the bottom surface of the test tank is a slope, and the bottom of the test tank is connected to the drain pipe, and the inlet of the drain pipe is located at the low point of the slope; the drain pipe passes through the side wall of the sealed box, and the drain The outlet of the liquid pipe is equipped with a valve.
以上所述的RIM测试装置,每个试验槽包括复数块隔板,隔板将试验槽分隔成复数个试样固定槽,每个试样固定槽的斜面上置有所述的橡胶套。In the RIM test device described above, each test tank includes a plurality of partitions, the partitions divide the test tank into a plurality of sample fixing slots, and the rubber sleeve is placed on the slope of each sample fixing slot.
以上所述的RIM测试装置,包括复数个试验槽,试验槽通过螺钉可拆卸地固定在密封箱体的底板上。The above-mentioned RIM test device includes a plurality of test slots, and the test slots are detachably fixed on the bottom plate of the sealed box by screws.
以上所述的RIM测试装置,所述的测试主机为非稳态扩散系数试验仪。In the above-mentioned RIM test device, the test host is an unsteady-state diffusion coefficient tester.
本实用新型的RIM测试装置采用密闭的试验的环境,不仅可以保证电解液不发生分解,而且可以单独控制箱体内部温度,测试数据较为准确,可靠度较高。The RIM test device of the utility model adopts a closed test environment, which not only can ensure that the electrolyte does not decompose, but also can independently control the internal temperature of the box, and the test data is more accurate and the reliability is higher.
[附图说明][Description of drawings]
下面结合附图和具体实施方式对本实用新型作进一步详细的说明。Below in conjunction with accompanying drawing and specific embodiment, the utility model is described in further detail.
图1是本实用新型实施例RIM测试装置的主视图。Fig. 1 is the front view of the RIM testing device of the embodiment of the present invention.
图2是本实用新型实施例RIM测试装置的俯视图。Fig. 2 is a top view of the RIM testing device of the embodiment of the present invention.
图3是本实用新型实施例RIM测试装置的右视图。Fig. 3 is a right view of the RIM testing device of the embodiment of the present invention.
图4是图2中的A向剖视图。Fig. 4 is a cross-sectional view taken along line A in Fig. 2 .
图5是图4中的B向剖视图。Fig. 5 is a cross-sectional view along B direction in Fig. 4 .
图6是图4中的C向剖视图。Fig. 6 is a sectional view taken along direction C in Fig. 4 .
[具体实施方式][detailed description]
本实用新型实施例RIM测试装置的结构如图1至图6所示,包括作为测试主机的非稳态扩散系数试验仪200和试验设备200,试验设备200包括塑料制成的密封箱体1和三个装有阴极电解液的试验槽2,三个试验槽2并列布置,每个试验槽2通过4个螺钉20可拆卸地固定在密封箱体1的底板上。在试验槽发生故障或者需要清理可松动螺钉20,将试验槽取出。The structure of the utility model embodiment RIM testing device is as shown in Figure 1 to Figure 6, comprises the non-steady-state diffusion coefficient tester 200 and test equipment 200 as test host computer, and test equipment 200 comprises the sealing box body 1 that plastics is made and Three test tanks 2 filled with catholyte are arranged side by side, and each test tank 2 is detachably fixed on the bottom plate of the sealed box 1 by four screws 20 . When the test tank breaks down or the loose screw 20 needs to be cleaned, the test tank is taken out.
试验槽2由硬化塑料制成。每个试验槽2中有两块隔板203,隔板203将试验槽2分隔成三个试样固定槽。The test tank 2 is made of hardened plastic. There are two partitions 203 in each test tank 2, and the partitions 203 divide the test tank 2 into three sample fixing tanks.
每个试样固定槽中有一个支架,支架上有30°的斜面201,斜面201上置有倾斜的橡胶套3,橡胶套3内部装有混凝土试件300和阳极电解液,混凝土试件300固定于橡胶套3底部,阴极电解液中置有阴极匙;阳极电解液中置有阳极匙,阳极匙和阴极匙分别与非稳态扩散系数试验仪200连接。There is a bracket in each sample fixing groove, and there is a 30° inclined plane 201 on the bracket, and an inclined rubber sleeve 3 is placed on the inclined plane 201, and the concrete specimen 300 and the anolyte are housed inside the rubber sleeve 3, and the concrete specimen 300 It is fixed on the bottom of the rubber sleeve 3, and the cathode spoon is placed in the catholyte;
三个试验槽2布置在密封箱体1中,试验槽2的顶部装有盖板201,盖板201上有三个通线孔202。密封箱体1的顶板101整体式,可通过一旋转轴打开,顶板101上有9个通线孔102,阳极匙和阴极匙的电线4穿过盖板201上的通线孔202和密封箱体1的通线孔102与非稳态扩散系数试验仪200连接。Three test tanks 2 are arranged in the sealed box body 1 , and a cover plate 201 is installed on the top of the test tank 2 , and there are three through-wire holes 202 on the cover plate 201 . The top plate 101 of the sealed box 1 is integral and can be opened by a rotating shaft. There are nine wire holes 102 on the top plate 101. The wires 4 of the anode spoon and the cathode spoon pass through the wire holes 202 on the cover plate 201 and the sealed box The through hole 102 of the body 1 is connected with an unsteady state diffusion coefficient tester 200 .
试验槽2底面为5°的坡面,便于废液从坡面低点的废液口通过重力排出,试验槽2底部坡面低点的废液口接排液管6;排液管6穿过密封箱体1的侧壁伸到外面,排液管6的出口装有阀门7。The bottom surface of the test tank 2 is a slope of 5°, which is convenient for the waste liquid to be discharged by gravity from the waste liquid port at the low point of the slope surface. The waste liquid port at the low point of the slope surface at the bottom of the test tank 2 is connected to the drain pipe 6; The side wall of the sealed casing 1 extends to the outside, and the outlet of the discharge pipe 6 is equipped with a valve 7 .
密封箱体1内装有温度控制系统,温度控制系统包括微型空调5和温度测定计8,可以控制箱体在密封条件下达到实验所需要的温度。提供良好的RIM实验试液存放和反应环境。A temperature control system is housed in the sealed box body 1, and the temperature control system includes a micro-air conditioner 5 and a thermometer 8, which can control the box body to reach the temperature required for the experiment under the sealed condition. Provide a good RIM experimental test solution storage and reaction environment.
本实用新型实施例进行RIM测试时,利用上述测试装置和至少一组混凝土试件,每组组混凝土试件包括三块直径100mm,高度50mm圆柱形试件。为测试不同的混凝土,可以制作三组不同的混凝土试件同时进行测试。When carrying out the RIM test in the embodiment of the utility model, the above-mentioned test device and at least one set of concrete test pieces are used, and each set of concrete test pieces includes three cylindrical test pieces with a diameter of 100 mm and a height of 50 mm. In order to test different concretes, three groups of different concrete specimens can be made and tested at the same time.
混凝土试件要进行预处理,预处理包括将上下表面处于干燥状态下的混凝土试件置于真空容器中进行真空处理;真空处理时在5分钟内将真空容器中的气压降至1-5kPa,并应保持在真空度下3个小时;在真空泵仍然运转的情况下,将用饱和氢氧化钙溶液注入真空容器,将试件浸没。在试件浸没,1个小时后真空容器恢复至常压,混凝土试件在常压下浸泡20个小时。Concrete specimens need to be pretreated, and the pretreatment includes placing the concrete specimens with the upper and lower surfaces in a dry state in a vacuum container for vacuum treatment; during vacuum treatment, reduce the air pressure in the vacuum container to 1-5kPa within 5 minutes, And it should be kept under vacuum for 3 hours; while the vacuum pump is still running, inject saturated calcium hydroxide solution into the vacuum container to immerse the test piece. After the specimen is submerged, the vacuum container returns to normal pressure after 1 hour, and the concrete specimen is soaked under normal pressure for 20 hours.
混凝土试件除上、下表面外,四周表面涂覆防水层密封,如涂覆环氧树脂或者石蜡防水层进行密封。In addition to the upper and lower surfaces of the concrete specimen, the surrounding surfaces are sealed with a waterproof layer, such as epoxy resin or paraffin waterproof layer for sealing.
取混凝土较为平整的面为渗透面朝下放置于橡胶套3内。将配置好的阴极电解液和阳极电解液分别灌至指定位置,阴极电解液为质量百分比浓度23.78%的NaI溶液,阳极电解液为摩尔浓度为0.3mol/L的KOH水溶液;并按设定的电压、电流和时间运行非稳态扩散系数试验仪,对混凝土试件进行通电试验。Take the relatively flat surface of the concrete as the permeable surface and place it in the rubber sleeve 3 facing downward. Pour the configured catholyte and anolyte into the designated positions respectively, the catholyte is NaI solution with a mass percentage concentration of 23.78%, and the anolyte is KOH aqueous solution with a molar concentration of 0.3mol/L; and according to the set Voltage, current and time run the non-steady-state diffusion coefficient tester to conduct electrification tests on concrete specimens.
通电试验结束后,将混凝土试件从橡胶套中取出,立即用自来水将混凝土试件的表面冲洗干净,在压力试验机上沿混凝土试件的轴向,将混凝土试件劈成两个半圆柱体;混凝土试件的劈裂面稍干后,先喷射质量百分比为50%的醋酸溶液,先喷射质量百分比为3%的碘酸钾,再喷射质量百分比为5%的淀粉悬浮液。测量碘离子渗透深度。然后测定混凝土试件的碘离子显色深度。After the power-on test, take the concrete specimen out of the rubber sleeve, immediately rinse the surface of the concrete specimen with tap water, and split the concrete specimen into two semi-cylindrical bodies along the axial direction of the concrete specimen on the pressure testing machine. After the split surface of the concrete specimen is slightly dry, the acetic acid solution with a mass percentage of 50% is sprayed first, the potassium iodate sprayed with a mass percentage of 3%, and then the starch suspension with a mass percentage of 5%. Measure the penetration depth of iodide ions. Then measure the iodide ion color depth of the concrete specimen.
碘离子渗透系数测定方法参照NTBuild492-1999.11“ChlorideMigrationCoefficientfromNon-steady-stateMigrationExperiments”方法或普通混凝土长期性能和耐久性能试验方法标准(GB/T50082-2009)。The determination method of the iodide ion permeability coefficient refers to the NTBuild492-1999.11 "ChlorideMigrationCoefficient fromNon-steady-stateMigrationExperiments" method or the standard for the long-term performance and durability of ordinary concrete (GB/T50082-2009).
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