CN205170697U - Special slowly -releasing fertilizer granule of flowers - Google Patents
Special slowly -releasing fertilizer granule of flowers Download PDFInfo
- Publication number
- CN205170697U CN205170697U CN201520785696.3U CN201520785696U CN205170697U CN 205170697 U CN205170697 U CN 205170697U CN 201520785696 U CN201520785696 U CN 201520785696U CN 205170697 U CN205170697 U CN 205170697U
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- Prior art keywords
- layer
- slowly
- releasing
- stratum nucleare
- fertilizer
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Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 51
- 239000008187 granular material Substances 0.000 title abstract 3
- DWNBOPVKNPVNQG-LURJTMIESA-N (2s)-4-hydroxy-2-(propylamino)butanoic acid Chemical compound CCCN[C@H](C(O)=O)CCO DWNBOPVKNPVNQG-LURJTMIESA-N 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 239000011159 matrix material Substances 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims description 12
- 239000007800 oxidant agent Substances 0.000 claims description 8
- 230000001590 oxidative effect Effects 0.000 claims description 8
- 239000002131 composite material Substances 0.000 claims description 7
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 230000001105 regulatory effect Effects 0.000 claims description 3
- 239000002689 soil Substances 0.000 abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 9
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 239000013522 chelant Substances 0.000 abstract description 4
- QJZYHAIUNVAGQP-UHFFFAOYSA-N 3-nitrobicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid Chemical compound C1C2C=CC1C(C(=O)O)C2(C(O)=O)[N+]([O-])=O QJZYHAIUNVAGQP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000004021 humic acid Substances 0.000 abstract description 3
- 239000002250 absorbent Substances 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract description 2
- 235000015097 nutrients Nutrition 0.000 description 19
- 229940024606 amino acid Drugs 0.000 description 8
- 235000001014 amino acid Nutrition 0.000 description 8
- 150000001413 amino acids Chemical class 0.000 description 8
- 238000010521 absorption reaction Methods 0.000 description 5
- 239000011573 trace mineral Substances 0.000 description 5
- 235000013619 trace mineral Nutrition 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 230000003111 delayed effect Effects 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229930182817 methionine Natural products 0.000 description 2
- MTCFGRXMJLQNBG-REOHCLBHSA-N (2S)-2-Amino-3-hydroxypropansäure Chemical compound OC[C@H](N)C(O)=O MTCFGRXMJLQNBG-REOHCLBHSA-N 0.000 description 1
- PRPINYUDVPFIRX-UHFFFAOYSA-N 1-naphthaleneacetic acid Chemical compound C1=CC=C2C(CC(=O)O)=CC=CC2=C1 PRPINYUDVPFIRX-UHFFFAOYSA-N 0.000 description 1
- 239000004475 Arginine Substances 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical group [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000040710 Chela Species 0.000 description 1
- 229930191978 Gibberellin Natural products 0.000 description 1
- 239000004471 Glycine Substances 0.000 description 1
- ODKSFYDXXFIFQN-BYPYZUCNSA-P L-argininium(2+) Chemical compound NC(=[NH2+])NCCC[C@H]([NH3+])C(O)=O ODKSFYDXXFIFQN-BYPYZUCNSA-P 0.000 description 1
- HNDVDQJCIGZPNO-YFKPBYRVSA-N L-histidine Chemical compound OC(=O)[C@@H](N)CC1=CN=CN1 HNDVDQJCIGZPNO-YFKPBYRVSA-N 0.000 description 1
- FFEARJCKVFRZRR-BYPYZUCNSA-N L-methionine Chemical compound CSCC[C@H](N)C(O)=O FFEARJCKVFRZRR-BYPYZUCNSA-N 0.000 description 1
- COLNVLDHVKWLRT-QMMMGPOBSA-N L-phenylalanine Chemical compound OC(=O)[C@@H](N)CC1=CC=CC=C1 COLNVLDHVKWLRT-QMMMGPOBSA-N 0.000 description 1
- AYFVYJQAPQTCCC-GBXIJSLDSA-N L-threonine Chemical compound C[C@@H](O)[C@H](N)C(O)=O AYFVYJQAPQTCCC-GBXIJSLDSA-N 0.000 description 1
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 1
- XUYPXLNMDZIRQH-LURJTMIESA-N N-acetyl-L-methionine Chemical compound CSCC[C@@H](C(O)=O)NC(C)=O XUYPXLNMDZIRQH-LURJTMIESA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- MTCFGRXMJLQNBG-UHFFFAOYSA-N Serine Natural products OCC(N)C(O)=O MTCFGRXMJLQNBG-UHFFFAOYSA-N 0.000 description 1
- AYFVYJQAPQTCCC-UHFFFAOYSA-N Threonine Natural products CC(O)C(N)C(O)=O AYFVYJQAPQTCCC-UHFFFAOYSA-N 0.000 description 1
- 239000004473 Threonine Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 235000018660 ammonium molybdate Nutrition 0.000 description 1
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- ODKSFYDXXFIFQN-UHFFFAOYSA-N arginine Natural products OC(=O)C(N)CCCNC(N)=N ODKSFYDXXFIFQN-UHFFFAOYSA-N 0.000 description 1
- 235000003704 aspartic acid Nutrition 0.000 description 1
- CKLJMWTZIZZHCS-REOHCLBHSA-N aspartic acid group Chemical group N[C@@H](CC(=O)O)C(=O)O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 125000005619 boric acid group Chemical group 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000013270 controlled release Methods 0.000 description 1
- 229910000365 copper sulfate Inorganic materials 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000003448 gibberellin Substances 0.000 description 1
- IXORZMNAPKEEDV-OBDJNFEBSA-N gibberellin A3 Chemical class C([C@@]1(O)C(=C)C[C@@]2(C1)[C@H]1C(O)=O)C[C@H]2[C@]2(C=C[C@@H]3O)[C@H]1[C@]3(C)C(=O)O2 IXORZMNAPKEEDV-OBDJNFEBSA-N 0.000 description 1
- 229960002989 glutamic acid Drugs 0.000 description 1
- HNDVDQJCIGZPNO-UHFFFAOYSA-N histidine Natural products OC(=O)C(N)CC1=CN=CN1 HNDVDQJCIGZPNO-UHFFFAOYSA-N 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 239000003621 irrigation water Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L magnesium sulphate Substances [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000000618 nitrogen fertilizer Substances 0.000 description 1
- 230000000050 nutritive effect Effects 0.000 description 1
- COLNVLDHVKWLRT-UHFFFAOYSA-N phenylalanine Natural products OC(=O)C(N)CC1=CC=CC=C1 COLNVLDHVKWLRT-UHFFFAOYSA-N 0.000 description 1
- 239000002686 phosphate fertilizer Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000003375 plant hormone Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
Landscapes
- Fertilizers (AREA)
Abstract
The utility model relates to a special slowly -releasing fertilizer granule of flowers, including shell, intermediate level and stratum nucleare there is the intermediate level outer combination of stratum nucleare of slowly -releasing fertilizer granule, combines to have the shell outside the intermediate level, the stratum nucleare is the regulator layer, the preferential regulator layer that combines to have the plant regulator in the three dimensional structure of water absorbent resin base member network and constitute of adopting in regulator layer, the compound fertilizer efficiency layer in intermediate level, compound fertilizer efficiency layer is preferential adopts in humic acid soil matrix matter microelement in the kilnitamin chelate and the compound fertilizer efficiency layer that constitutes, the shell is slowly -releasing accuse layer, the preferential slowly -releasing accuse layer of gathering winter propylhomoserin layer and constituting of adopting in slowly -releasing accuse layer.
Description
Technical field
The utility model relates to agricultural fertilizer and delays, releases control carrier, the particularly slow-release fertilizer dedicated particle of a kind of flowers.
Background technology
For a long time, at China's agriculture field, long-term existence and is used the low problem of straight fertilizer, a fertilizer and fertilizer nutrient utilization, according to the literature, the this season utilization ratio of nitrogenous fertilizer is about 30%-40%, the this season utilization ratio of phosphate fertilizer is 10%-25%, and the utilization ratio of potash fertilizer is 50%-60%, traces it to its cause, be the water-soluble height of common fertilizer, nutrients release block, release period is shorter, causes fertilizer nutrient release period, releasing degree and crop not to match caused to the absorption phase of nutrient and demand.
In recent years, domesticly have employed that number of mechanisms water-solublely to be delayed common fertilizer, controlled release controls, fertilizer product and poly-winter propylhomoserin resin are organically combined, using poly-winter propylhomoserin resin as the carrier delaying, release the release of control fertilizer nutrient, to the release of fertilizer nutrient effectively can be delayed, make the release period of fertilizer nutrient, burst size and crop substantially identical to the absorption phase of nutrient, demand, improve the utilization ratio of fertilizer nutrient, improve the usefulness such as soil moisture content, water-retentivity, reduce production cost, improve the earning rate of farm crop.
Poly-winter propylhomoserin resin, as one water suction, water-holding agent, is administered in soil and not only fully can absorbs irrigation water or natural precipitation water, prevent Water deep leaching and loss, improve the utilization ratio of water, and the formation of soil agreegate can be promoted, improve Pore structure in soil, prevent erosion.Therefore, poly-winter propylhomoserin resin is widely used in agricultural, field of forestry.But, soil water content and validity thereof are also depended in the performance of fertilizer efficiency, interaction is there is between water, fertilizer, therefore, research and development have the delaying of water retaining function, release the production practical problemss that control fertilizer is the urgent solution of needs, therefore, the research about poly-winter propylhomoserin resin fertilizer comes into one's own day by day.
Summary of the invention
The purpose of this utility model is to provide the slow-release fertilizer dedicated particle of a kind of flowers, to the release of fertilizer nutrient effectively can be delayed, make the release period of fertilizer nutrient, burst size and crop substantially identical to the absorption phase of nutrient, demand, improve the utilization ratio of fertilizer nutrient.
In order to realize above-mentioned target, the technical solution adopted in the utility model is: the slow-release fertilizer dedicated particle of a kind of flowers, comprise shell, middle layer and stratum nucleare, middle layer is combined with outside the stratum nucleare of described slow release fertilizer particle, shell is combined with outside middle layer, described stratum nucleare is for regulating oxidant layer, and described adjustment oxidant layer preferentially adopts and in the three-dimensional structure network of water-absorbing resin matrix, is combined with plant modifying agent and the adjustment oxidant layer that forms; Described middle layer composite fertilizer active layer, composite fertilizer's active layer that described composite fertilizer active layer preferentially adopts kilnitamin chelating medium trace element in humic acid soil matrix matter and forms; Described shell is slowly-releasing control layer, the slowly-releasing control layer that described slowly-releasing control layer preferentially adopts poly-winter propylhomoserin layer to form.
Described absorbent resin matrix is the superpolymer with three-dimensional net structure, and its water-retaining capacity can reach the hundred times even several thousand times of own wt, comprises the superpolymer such as sodium polyacrylate, polyvinyl alcohol.
Described plant modifying agent adopts the composition of Plant hormones regulators,gibberellins, Nafusaku.
Described chelating amino acids medium trace element adopts complex amino acid aqueous solution 50-60 part, moderate-element compound 30-40 part, and trace element 10 parts forms through chelating technique.Wherein, complex amino acid aqueous solution Determination of Free Amino Acids is >=29%, and the kind of described aminoacids complex is the composition of aspartic acid, Threonine, Serine, L-glutamic acid, glycine, propylhomoserin, phenylalanine, Methionin, arginine, Histidine, methionine(Met); Described moderate-element compound is the composition of calcium chloride, magnesium chloride, anhydrous magnesium sulfate, ammonium sulfate; Described trace element is the composition of boric acid, zinc sulfate, copper sulfate, ferrous sulfate, four water ammonium molybdates, manganous sulfate.
In described aminoacid chelating microelement solution, also can add and comprise nitrogen, phosphorus (P
2o
5), the basic fertilizer of potassium.
The beneficial effect that the utility model realizes: the release that effectively can delay fertilizer nutrient, make the release period of fertilizer nutrient, burst size and crop substantially identical to the absorption phase of nutrient, demand, improve the utilization ratio of fertilizer nutrient, improve the usefulness such as soil moisture content, water-retentivity, reduce production cost, improve the earning rate of flower crop, there is huge economic benefit, social benefit and environmental benefit, for developing water-saving planting and improving the ecological environment, tool is of great significance.
Accompanying drawing explanation
Fig. 1 is the structural representation of the slow-release fertilizer dedicated particle of a kind of flowers.
In figure, 1 is stratum nucleare, and 2 is middle layers, and 3 is shells.
Embodiment
Crop is because metallo-chelate quite stable to the reason that metallo-chelate especially easily absorbs.After in polydentate ligand, certain ligating atom is combined with central metal atom, the distance of remaining ligating atom and central atom reduces, and the probability that they are combined with central atom just increases.If wherein there is a coordinate bond to destroy, because other ligating atoms in polydentate ligand still with central atom bonding, the coordination be destroyed is good for more easily recover, the more, in part, available ligating atom just the more for the ligating atom in polydentate ligand, form chela ring just the more, the coordination that same part and central atom are formed is strong just the more, and the chance of part off center atom is just less, and inner complex is just more stable, therefore, crop especially easily absorbs metallo-chelate.
In sum, containing amino acid whose water-soluble fertilizer, utilize chelating amino acids plant nutrient, make inorganic elements become organic chelated state element, the absorption rate of nutritive element is improved further, show as with strong points, fertilizer efficiency is fast, and consumption is few, save manpower, increase yield significantly, and soil can be avoided the fixed action of some nutrient, economical and efficient.
Embodiment 1
Further understanding to do the utility model, now by reference to the accompanying drawings it being explained.
As shown in Figure 1, the slow-release fertilizer dedicated particle of a kind of flowers of the present utility model, comprise shell 3, middle layer 2 and stratum nucleare 1, middle layer 2 is combined with outside the stratum nucleare 1 of described slow release fertilizer particle, shell 3 is combined with outside middle layer 2, described stratum nucleare 1 is for regulating oxidant layer, and described adjustment oxidant layer preferentially adopts and in the three-dimensional structure network of water-absorbing resin matrix, is combined with plant modifying agent and the adjustment oxidant layer that forms; Described middle layer 2 composite fertilizer active layer, composite fertilizer's active layer that described composite fertilizer active layer preferentially adopts kilnitamin chelating medium trace element in humic acid soil matrix matter and forms; Described shell 3 is slowly-releasing control layer, the slowly-releasing control layer that described slowly-releasing control layer preferentially adopts poly-winter propylhomoserin layer to form.
Although the utility model describes concrete case study on implementation; but; scope of the present utility model is not limited to above-mentioned specific embodiment, when not departing from the utility model essence, all falls into protection domain of the present utility model to various modification of the present utility model, change and replacement.
Claims (3)
1. the slow-release fertilizer dedicated particle of flowers, comprise shell (3), middle layer (2) and stratum nucleare (1), it is characterized in that: outside the stratum nucleare (1) of described slow release fertilizer particle, be combined with middle layer (2), shell (3) is combined with outside middle layer (2), described stratum nucleare (1) is for regulating oxidant layer, described middle layer (2) is composite fertilizer's active layer, and described shell (3) is slowly-releasing control layer.
2. the slow-release fertilizer dedicated particle of a kind of flowers according to claim 1, is characterized in that: the adjustment oxidant layer that described stratum nucleare (1) employing is combined with plant modifying agent and forms in the three-dimensional structure network of water-absorbing resin matrix.
3. the slow-release fertilizer dedicated particle of a kind of flowers according to claim 1, is characterized in that: described slowly-releasing control layer adopts poly-winter propylhomoserin layer.
Priority Applications (1)
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CN201520785696.3U CN205170697U (en) | 2015-10-12 | 2015-10-12 | Special slowly -releasing fertilizer granule of flowers |
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CN201520785696.3U CN205170697U (en) | 2015-10-12 | 2015-10-12 | Special slowly -releasing fertilizer granule of flowers |
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CN205170697U true CN205170697U (en) | 2016-04-20 |
Family
ID=55734712
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105900716A (en) * | 2016-06-16 | 2016-08-31 | 深圳爱易瑞科技有限公司 | Ecological garden system |
CN107223380A (en) * | 2017-08-08 | 2017-10-03 | 江西省农业科学院基地管理中心 | Fertilizing and soil loosening device and flowerpot using same |
CN113024315A (en) * | 2021-04-19 | 2021-06-25 | 福州大学 | Coated chelated controlled-release fertilizer and preparation method thereof |
-
2015
- 2015-10-12 CN CN201520785696.3U patent/CN205170697U/en not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105900716A (en) * | 2016-06-16 | 2016-08-31 | 深圳爱易瑞科技有限公司 | Ecological garden system |
CN107223380A (en) * | 2017-08-08 | 2017-10-03 | 江西省农业科学院基地管理中心 | Fertilizing and soil loosening device and flowerpot using same |
CN113024315A (en) * | 2021-04-19 | 2021-06-25 | 福州大学 | Coated chelated controlled-release fertilizer and preparation method thereof |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160420 Termination date: 20191012 |
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CF01 | Termination of patent right due to non-payment of annual fee |