CN204365111U - A low-temperature plasma deodorization device - Google Patents
A low-temperature plasma deodorization device Download PDFInfo
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- CN204365111U CN204365111U CN201420656660.0U CN201420656660U CN204365111U CN 204365111 U CN204365111 U CN 204365111U CN 201420656660 U CN201420656660 U CN 201420656660U CN 204365111 U CN204365111 U CN 204365111U
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Abstract
本实用新型提供了一种低温等离子体除异味装置,属于污染空气净化技术领域,具体的讲是一种对垃圾填埋场、化工厂、药厂等异味有害气体消除的装置。其包括气体收集口、引风机、微孔膜除尘器、一级喷淋塔、停机控制装置、低温等离子体净化仓、二级喷淋塔、蓄水箱、潜水泵、放空口及管路等组成。本实用新型部件紧凑、占地面积小、适用范围广、工作效率高、能耗低,去除氨-硫化氢等异味有害气体的效率可达到98%以上,具有良好的经济效益、社会效益及环境效益。
The utility model provides a low-temperature plasma odor removal device, which belongs to the technical field of polluted air purification, and is specifically a device for eliminating odorous and harmful gases in landfills, chemical plants, pharmaceutical plants, etc. It includes a gas collection port, an induced draft fan, a microporous membrane dust collector, a primary spray tower, a shutdown control device, a low-temperature plasma purification chamber, a secondary spray tower, a water storage tank, a submersible pump, a vent and pipelines. The utility model has compact components, small footprint, wide application range, high working efficiency, low energy consumption, and the efficiency of removing odorous and harmful gases such as ammonia-hydrogen sulfide can reach more than 98%, with good economic benefits, social benefits and environmental benefits.
Description
技术领域technical field
本实用新型属于污染空气净化技术领域,具体涉及一种对包括垃圾填埋场、化工厂、药厂等场所排放的异味有害气体净化装置。The utility model belongs to the technical field of polluted air purification, and in particular relates to a device for purifying odorous and harmful gases discharged from landfills, chemical plants, pharmaceutical factories and other places.
背景技术Background technique
随着社会工业化的发展,环境问题日渐突出。在整个大气污染中,异味有害气主要来源于石油化工、污水处理、垃圾填埋、化学制药、电子工业、皮革加工等生产过程中,不仅污染车间环境,危害岗位工作人员身体健康,而且是诱发光化学烟雾的主要前体污染物,对城市空气质量构成了严重的威胁。由于工业异味有害气体具有风量大、浓度低、多组分复合污染的特点,且气体风量与浓度波动较大,其治理难度相对较大。传统方法通常采用吸收、冷凝、催化燃烧、活性炭吸附、生物法及等离子体氧化法等几种方式。在废气净化的过程中,催化燃烧法净化效率高,但缺点是设备体积较大,一次性投资及设备运行能耗较大。吸附法主要用活性炭吸附,净化效果理想,但活性炭吸附饱和后需要再生,再生后的废气仍需处理。吸收法、冷凝法应用范围受限。生物法投资和运行费用较低,但运行操作复杂、占地面积较大,存在二次污染的可能性。等离子体氧化法对废气的去除效率虽然高,但缺点是等离子体自由基反应过程中同时产生O3有害副产物。因此,申请人提出一种低温等离子体与微孔膜、喷淋吸收相结合净化装置与方法,在达到较高去除效果的同时抑制二次污染。With the development of social industrialization, environmental problems have become increasingly prominent. In the whole air pollution, the odor and harmful gas mainly come from the production process of petrochemical industry, sewage treatment, landfill, chemical pharmaceutical, electronic industry, leather processing, etc., which not only pollutes the workshop environment, endangers the health of the staff at the post, but also induces The main precursor pollutants of photochemical smog pose a serious threat to urban air quality. Due to the characteristics of large air volume, low concentration, and multi-component compound pollution, industrial odor and harmful gases have large fluctuations in air volume and concentration, and its treatment is relatively difficult. Traditional methods usually adopt several methods such as absorption, condensation, catalytic combustion, activated carbon adsorption, biological method and plasma oxidation method. In the process of exhaust gas purification, the catalytic combustion method has high purification efficiency, but the disadvantage is that the equipment is large in size, and the one-time investment and equipment operation consume a lot of energy. The adsorption method mainly uses activated carbon for adsorption, and the purification effect is ideal, but the activated carbon needs to be regenerated after the adsorption is saturated, and the regenerated waste gas still needs to be treated. The scope of application of absorption method and condensation method is limited. The investment and operating costs of the biological method are relatively low, but the operation is complicated, the floor area is large, and there is a possibility of secondary pollution. Although the plasma oxidation method has high removal efficiency of exhaust gas, its disadvantage is that harmful by-products of O3 are produced simultaneously during the plasma radical reaction process. Therefore, the applicant proposes a purification device and method combining low-temperature plasma, microporous membrane, and spray absorption, which can suppress secondary pollution while achieving a high removal effect.
实用新型内容Utility model content
本实用新型的目的在于提供一种低温等离子体除异味装置,该装置结构简单、适用范围广、工作效率高、能耗低,去除氨-硫化氢等异味有害气体的效率可达到98%以上。The purpose of the utility model is to provide a low-temperature plasma deodorization device, which has a simple structure, wide application range, high work efficiency, low energy consumption, and the efficiency of removing ammonia-hydrogen sulfide and other odorous and harmful gases can reach more than 98%.
本实用新型的目的是通过以下技术方案实现的:The purpose of this utility model is achieved by the following technical solutions:
一种低温等离子体除异味装置,其特征在于:A low-temperature plasma deodorization device, characterized in that:
包括气体收集口、引风机、微孔膜除尘器、一级喷淋塔、停机控制装置、低温等离子体净化仓、二级喷淋塔、蓄水箱、潜水泵、放空口及管路等组成。Including gas collection port, induced draft fan, microporous membrane dust collector, first-level spray tower, shutdown control device, low-temperature plasma purification chamber, second-level spray tower, water storage tank, submersible pump, vent and pipeline, etc. .
所述气体收集口与引风机进风口连接,引风机出风口与微孔膜除尘器进气口连接,微孔膜除尘器出气口与一级喷淋塔的左下方进气口连接,一级喷淋塔顶部出气口与低温等离子体净化仓进气口连接,低温等离子体净化仓出气口与二级喷淋塔左下方进气口连接,最后由二级喷淋塔顶部放空口向外界排放达标气体。The gas collection port is connected to the air inlet of the induced fan, the air outlet of the induced fan is connected to the air inlet of the microporous membrane dust collector, and the air outlet of the microporous membrane dust collector is connected to the lower left air inlet of the first-stage spray tower. The air outlet at the top of the spray tower is connected to the air inlet of the low-temperature plasma purification chamber, and the air outlet of the low-temperature plasma purification chamber is connected to the air inlet at the lower left of the secondary spray tower, and finally discharged to the outside from the vent at the top of the secondary spray tower standard gas.
所述一级喷淋塔、二级喷淋塔右下方出水口分别与蓄水箱连接,蓄水箱中的潜水泵出水口由PVC分流管分别连接至一级喷淋塔、二级喷淋塔右上方的喷淋器上,实现喷淋水循环过程。The water outlets at the bottom right of the first-level spray tower and the second-level spray tower are respectively connected to the water storage tank, and the water outlet of the submersible pump in the water storage tank is respectively connected to the first-level spray tower and the second-level spraying tower by PVC shunt pipes. On the sprinkler at the upper right of the tower, the spray water circulation process is realized.
所述一级喷淋塔、二级喷淋塔进水管上各有一个电动阀门,由时间继电器控制二级喷淋塔上的电动阀门比一级喷淋塔上的电动阀门延时30-60秒开启。There is an electric valve on the water inlet pipe of the first-level spray tower and the second-level spray tower, and the electric valve on the second-level spray tower is delayed by 30-60 hours than the electric valve on the first-level spray tower by a time relay. seconds to turn on.
所述停机控制装置是一种燃爆气体检测报警及温度控制装置,其检测探头嵌入在距低温等离子体净化仓进气口前端5倍管径远的管道内。The shutdown control device is an explosion gas detection alarm and temperature control device, and its detection probe is embedded in a pipe 5 times the diameter from the front end of the air inlet of the low-temperature plasma purification chamber.
所述微孔膜除尘器是一种聚四氟乙烯微孔薄膜滤袋。The microporous membrane dust collector is a polytetrafluoroethylene microporous membrane filter bag.
所述低温等离子体净化仓,其主要由箱体,电源、金属筒,金属丝,固定棒、抽屉式支架构成。The low-temperature plasma purification chamber is mainly composed of a box body, a power supply, a metal cylinder, a metal wire, a fixing rod, and a drawer-type bracket.
所述电源位于箱体一侧,电源两极分别穿过箱体连接金属筒的外壁和金属丝两端。The power supply is located on one side of the box body, and the two poles of the power supply respectively pass through the box body and connect to the outer wall of the metal cylinder and the two ends of the metal wire.
所述固定棒置于金属筒两端,将金属丝贯穿并固定在金属筒的轴心位置。The fixing rods are placed at both ends of the metal cylinder, and the metal wire is passed through and fixed at the axial center of the metal cylinder.
所述固定棒为中间穿孔,外径略小于金属筒内径,厚度2-5cm的棒体硅橡胶。The fixing rod is perforated in the middle, the outer diameter is slightly smaller than the inner diameter of the metal cylinder, and the thickness is 2-5cm.
与现有技术相比,本实用新型具有以下有益效果:Compared with the prior art, the utility model has the following beneficial effects:
(1)一级喷淋塔中的水首先对废气进行预处理,充分吸收挥发有机物,并可以阻止管道附着物燃烧回燃。同时可以加湿被处理的废气,有利于在等离子体处理中产生一定浓度的羟基自由基,增强等离子体废气降解作用。二级喷淋塔一方面能够吸收部分由低温等离子放电产生的臭氧和活性粒子,增加水的氧化性,减小最终臭氧排放;另一方面可将臭氧和活性粒子充分溶解到水中,这样不仅增强了总体处理的效果,还进一步利用了臭氧和自由基等强氧化性对残余废气和水溶物继续反应,对等离子体废气处理起到了补充作用。二级喷淋塔中的水再抽到一级喷淋塔中,不但起到了节约用水的目的,而且二级喷淋塔中的水具有一定氧化性和化学反应活性,可以起到比纯水更好的预处理效果;(1) The water in the primary spray tower first pre-treats the exhaust gas, fully absorbs volatile organic compounds, and can prevent the pipeline attachments from burning back. At the same time, it can humidify the exhaust gas to be treated, which is conducive to the generation of a certain concentration of hydroxyl radicals in the plasma treatment and enhances the degradation of the plasma exhaust gas. On the one hand, the two-stage spray tower can absorb part of the ozone and active particles produced by low-temperature plasma discharge, increase the oxidation of water, and reduce the final ozone emission; on the other hand, it can fully dissolve ozone and active particles into the water, which not only enhances the In order to ensure the overall treatment effect, the strong oxidizing properties such as ozone and free radicals are further used to continue to react with residual waste gas and water-soluble substances, which plays a supplementary role in plasma waste gas treatment. The water in the secondary spray tower is then pumped into the primary spray tower, which not only saves water, but also the water in the secondary spray tower has certain oxidative and chemical reactivity, which can play a role in comparison with pure water. Better preprocessing effect;
(2)采用聚四氟乙烯微孔薄膜滤袋作为微孔膜除尘器,不仅可有效的滤除待处理异味有害气体中参杂的和PM2.5相当的杂质,还可以降低气体的流速,延长待处理气体在低温等离子净化仓中滞留时间,增强处理效果;(2) Using polytetrafluoroethylene microporous membrane filter bag as a microporous membrane dust collector, it can not only effectively filter out impurities equivalent to PM2.5 in the odorous and harmful gas to be treated, but also reduce the flow rate of the gas, Prolong the residence time of the gas to be treated in the low-temperature plasma purification chamber to enhance the treatment effect;
(3)本装置具有部件紧凑、占地面积小、适用范围广、工作效率高、能耗低,去除氨-硫化氢等异味有害气体的效率可达到98%以上、工作噪音低等特点。(3) The device has the characteristics of compact components, small footprint, wide application range, high working efficiency, low energy consumption, the efficiency of removing ammonia-hydrogen sulfide and other odorous and harmful gases can reach more than 98%, and low working noise.
附图说明Description of drawings
图1为本实用新型的结构示意框图Fig. 1 is a structural schematic block diagram of the utility model
具体实施方式Detailed ways
下面结合附图1对本实用新型做进一步描述:Below in conjunction with accompanying drawing 1 the utility model is described further:
一种低温等离子体除异味装置,如图1所示,其包括气体收集口(1)、引风机(2)、微孔膜除尘器(3)、一级喷淋塔(4)、停机控制装置(5)、低温等离子体净化仓(6)、二级喷淋塔(7)、蓄水箱(8)、潜水泵(9)、放空口(10)及管路等组成。所述气体收集口(1)与引风机(2)的进风口连接,引风机(2)的出风口与微孔膜除尘器(3)的进气口连接,微孔膜除尘器(3)的出气口与一级喷淋塔(4)的左下方进气口连接,一级喷淋塔(4)的顶部出气口与低温等离子体净化仓(6)的进气口连接,低温等离子体净化仓(6)的出气口与二级喷淋塔(7)的左下方进气口连接,最后由二级喷淋塔(7)的顶部放空口(10)向外界排放达标气体。其中,一级喷淋塔(4)、二级喷淋塔(7)的右下方出水口分别与蓄水箱(8)的任意一侧连接,蓄水箱(8)中的潜水泵(9)的出水口由PVC分流管分别连接至一级喷淋塔(4)、二级喷淋塔(7)右上方的喷淋器上,实现喷淋水循环过程。一级喷淋塔(4)、二级喷淋塔(7)的进水管上还各设有一个电动阀门,由时间继电器控制二级喷淋塔(7)上的电动阀门比一级喷淋塔(4)上的电动阀门延时30-60秒开启。停机控制装置(5)的检测探头嵌入在距低温等离子体净化仓(6)的进气口前端5倍管径远的管道内。A low-temperature plasma deodorization device, as shown in Figure 1, comprises a gas collection port (1), an induced draft fan (2), a microporous membrane dust collector (3), a primary spray tower (4), a shutdown control It consists of a device (5), a low-temperature plasma purification chamber (6), a secondary spray tower (7), a water storage tank (8), a submersible pump (9), an air vent (10) and pipelines. The gas collection port (1) is connected with the air inlet of the induced draft fan (2), and the air outlet of the induced draft fan (2) is connected with the air inlet of the microporous membrane dust collector (3), and the microporous membrane dust collector (3) The gas outlet of the primary spray tower (4) is connected to the lower left air inlet of the primary spray tower (4), and the top gas outlet of the primary spray tower (4) is connected to the air inlet of the low-temperature plasma purification chamber (6). The air outlet of the purification chamber (6) is connected with the lower left air inlet of the secondary spray tower (7), and finally the gas reaching the standard is discharged to the outside from the top vent (10) of the secondary spray tower (7). Wherein, the lower right water outlets of the first-level spray tower (4) and the second-level spray tower (7) are respectively connected with any side of the water storage tank (8), and the submersible pump (9) in the water storage tank (8) ) is connected to the first-level spray tower (4) and the sprinkler on the upper right side of the second-level spray tower (7) respectively by PVC shunt pipes to realize the spray water circulation process. The water inlet pipes of the first-level spray tower (4) and the second-level spray tower (7) are respectively provided with an electric valve, and the electric valve on the second-level spray tower (7) is controlled by a time relay. The electric valve on the tower (4) delays opening in 30-60 seconds. The detection probe of the shutdown control device (5) is embedded in a pipeline 5 times the pipe diameter away from the front end of the air inlet of the low-temperature plasma purification chamber (6).
其工艺流程为首先将从气体收集口(1)收集的异味有害气体由引风机(2)抽送至微孔膜除尘器(3)中进行除杂质,经除尘后的气体再进入一级喷淋塔(4)中进行水洗,吸收部分挥发有机物,吸收液回流至蓄水箱(8)中,未被吸收的异味有害气体进入低温等离子体净化仓(6)中进行异味有害气体的分解,分解后的气体进入到二级喷淋塔(7)进行二次吸收,吸收液回至蓄水箱(8)中,达标气体最后通过装置的放空口(10)排至大气,实现异味有害气体的净化处理过程。The process flow is as follows: firstly, the odorous and harmful gas collected from the gas collection port (1) is pumped by the induced draft fan (2) to the microporous membrane dust collector (3) to remove impurities, and the gas after dust removal enters the first-level spraying The tower (4) is washed with water to absorb part of the volatile organic compounds, and the absorption liquid is returned to the water storage tank (8), and the unabsorbed odorous and harmful gases enter the low-temperature plasma purification chamber (6) to decompose the odorous and harmful gases. The final gas enters the secondary spray tower (7) for secondary absorption, and the absorption liquid returns to the water storage tank (8), and the up-to-standard gas is finally discharged to the atmosphere through the vent (10) of the device to realize the removal of odorous and harmful gases. Purification process.
以上所述,仅为本实用新型较佳的具体实施方式,但本实用新型的保护范围并不局限于此,任何熟悉本技术领域的技术人员在本实用新型披露的技术范围内,根据本实用新型的技术方案及其发明构思加以等同替换或改变,都应涵盖在本实用新型的保护范围之内。The above is only a preferred embodiment of the utility model, but the scope of protection of the utility model is not limited thereto. Any equivalent replacement or change of the new technical solution and its inventive concept shall be covered by the protection scope of the present utility model.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105617826A (en) * | 2016-02-17 | 2016-06-01 | 大连举扬科技股份有限公司 | Low-temperature plasma oil gas ultra-clean emission treatment process and device |
CN109999640A (en) * | 2019-03-27 | 2019-07-12 | 浙江大维高新技术股份有限公司 | Garbage transfer station deodoration system |
WO2021203708A1 (en) * | 2020-04-08 | 2021-10-14 | 浙江大维高新技术股份有限公司 | Landfill leachate stench purification device and process thereof |
-
2014
- 2014-11-02 CN CN201420656660.0U patent/CN204365111U/en not_active Expired - Fee Related
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105617826A (en) * | 2016-02-17 | 2016-06-01 | 大连举扬科技股份有限公司 | Low-temperature plasma oil gas ultra-clean emission treatment process and device |
CN109999640A (en) * | 2019-03-27 | 2019-07-12 | 浙江大维高新技术股份有限公司 | Garbage transfer station deodoration system |
WO2021203708A1 (en) * | 2020-04-08 | 2021-10-14 | 浙江大维高新技术股份有限公司 | Landfill leachate stench purification device and process thereof |
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